KR102100714B1 - 고급 알코올의 제조방법 - Google Patents

고급 알코올의 제조방법 Download PDF

Info

Publication number
KR102100714B1
KR102100714B1 KR1020157002188A KR20157002188A KR102100714B1 KR 102100714 B1 KR102100714 B1 KR 102100714B1 KR 1020157002188 A KR1020157002188 A KR 1020157002188A KR 20157002188 A KR20157002188 A KR 20157002188A KR 102100714 B1 KR102100714 B1 KR 102100714B1
Authority
KR
South Korea
Prior art keywords
catalyst
reagent
group
ethanol
prepared
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020157002188A
Other languages
English (en)
Korean (ko)
Other versions
KR20150088235A (ko
Inventor
리카르도 아르조나 안토린
후안 루이스 산즈 야구에
아벨리노 코르마 카노스
마르셀로 에듀아르도 도미네
페르난도 비달 바레로
프란시스코 안토니오 라드론 데 구에바라 비달
Original Assignee
아벵고아 바이오에너지아 누에바스 테크놀로지아스, 에스. 에이.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 아벵고아 바이오에너지아 누에바스 테크놀로지아스, 에스. 에이. filed Critical 아벵고아 바이오에너지아 누에바스 테크놀로지아스, 에스. 에이.
Publication of KR20150088235A publication Critical patent/KR20150088235A/ko
Application granted granted Critical
Publication of KR102100714B1 publication Critical patent/KR102100714B1/ko
Assigned to 카탈릭스 인코포레이티드 reassignment 카탈릭스 인코포레이티드 권리의 전부이전등록 Assignors: 아벵고아 바이오에너지아 누에바스 테크놀로지아스, 에스. 에이.
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6562—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/896—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
KR1020157002188A 2012-06-29 2013-07-01 고급 알코올의 제조방법 Active KR102100714B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12382261.1 2012-06-29
EP12382261.1A EP2679304A1 (en) 2012-06-29 2012-06-29 Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide
PCT/ES2013/070448 WO2014001597A1 (es) 2012-06-29 2013-07-01 Procedimiento de obtención de alcoholes superiores

Publications (2)

Publication Number Publication Date
KR20150088235A KR20150088235A (ko) 2015-07-31
KR102100714B1 true KR102100714B1 (ko) 2020-04-16

Family

ID=49111231

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020157002188A Active KR102100714B1 (ko) 2012-06-29 2013-07-01 고급 알코올의 제조방법

Country Status (13)

Country Link
US (1) US9475741B2 (cg-RX-API-DMAC7.html)
EP (2) EP2679304A1 (cg-RX-API-DMAC7.html)
KR (1) KR102100714B1 (cg-RX-API-DMAC7.html)
CN (1) CN104736239B (cg-RX-API-DMAC7.html)
BR (1) BR112014032466B1 (cg-RX-API-DMAC7.html)
CA (1) CA2877974C (cg-RX-API-DMAC7.html)
ES (1) ES2545132T3 (cg-RX-API-DMAC7.html)
HU (1) HUE025461T2 (cg-RX-API-DMAC7.html)
IN (1) IN2014MN02648A (cg-RX-API-DMAC7.html)
MX (1) MX346356B (cg-RX-API-DMAC7.html)
RU (1) RU2014152879A (cg-RX-API-DMAC7.html)
WO (1) WO2014001597A1 (cg-RX-API-DMAC7.html)
ZA (1) ZA201409539B (cg-RX-API-DMAC7.html)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2679304A1 (en) 2012-06-29 2014-01-01 Abengoa Bioenergía Nuevas Tecnologías, S. A. Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide
JP6301481B2 (ja) * 2013-09-17 2018-03-28 エルジー・ケム・リミテッド アルカノールの製造方法
HUE043870T2 (hu) 2013-12-27 2019-09-30 Abengoa Bioenergia Nuevas Tecnologias Sa Eljárás nagyobb szénatomszámú alkoholok elõállítására alacsonyabb szénatomszámú alkoholokból Guerbet kondenzációval
CN104892361A (zh) * 2014-03-04 2015-09-09 中国科学院大连化学物理研究所 一种催化转化甲醇制备丙醇的方法
CN104892362A (zh) * 2014-03-04 2015-09-09 中国科学院大连化学物理研究所 一种催化转化甲醇制备丁醇的方法
EP3218339B1 (en) * 2014-11-14 2022-01-05 Abengoa Bioenergía Nuevas Tecnologías, S. A. Process for the preparation of higher alcohols from ethanol and n-hexanol by guerbet condensation
ES2570233B1 (es) * 2014-11-14 2017-02-22 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
ES2570231B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
ES2570227B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
BR112018003036B1 (pt) * 2015-08-19 2021-11-09 Rescurve, Llc Método para produção de um álcool superior
ES2647963B1 (es) 2016-05-26 2018-10-03 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
CN108686671A (zh) * 2018-06-11 2018-10-23 福州大学 一种低温甲醇分解催化剂的制备
CN109529897B (zh) * 2018-12-04 2020-07-31 西南化工研究设计院有限公司 一种生产正丁醇的钯镓双金属催化剂及其制备方法及应用
CN111715252B (zh) * 2019-03-21 2022-03-25 北京大学 一种催化合成有机化合物的方法及其催化剂和应用
BR112023002710A2 (pt) * 2020-09-14 2023-04-25 China Petroleum & Chem Corp Processo para a produção de propanol e/ou isobutanol
CN113019404B (zh) * 2021-03-23 2022-02-18 中国科学院兰州化学物理研究所 用于合成高碳醇的镍基催化剂及其制备方法与应用
CN114588904B (zh) * 2022-03-08 2024-11-26 中国科学院青岛生物能源与过程研究所 Cu基金属氧化物催化剂、其制备方法以及采用其的2,3-丁二醇的合成方法
CN115445630B (zh) * 2022-08-30 2023-11-17 广东工业大学 一种聚丙烯基锡掺杂碳包镍催化剂及其制备方法和应用
CN118059885B (zh) * 2024-01-30 2024-09-27 南京工业大学 一种负载金多相催化剂及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000038832A1 (en) 1998-12-23 2000-07-06 Den Norske Stats Oljeselskap A.S Catalysts consisting of metals on hydrotalcite-based carrier materials, and method for the preparation thereof
WO2009026510A1 (en) 2007-08-22 2009-02-26 E. I. Du Pont De Nemours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5300695A (en) 1992-12-07 1994-04-05 Amoco Corporation Process for preparing alcohols
US5387570A (en) 1993-05-07 1995-02-07 Exxon Research & Engineering Co. Catalysts for iso-alcohol synthesis from CO + H2
WO2006059729A1 (ja) 2004-12-03 2006-06-08 Kabushiki Kaisha Sangi 高分子アルコールの合成法
US7700811B2 (en) 2007-08-22 2010-04-20 E.I. Du Pont De Namours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
US8071823B2 (en) 2008-01-28 2011-12-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
US8071822B2 (en) 2008-01-28 2011-12-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid
US8318989B2 (en) 2008-12-22 2012-11-27 E I Du Pont De Nemours And Company Process for producing guerbet alcohols using water tolerant basic catalysts
EP2679304A1 (en) 2012-06-29 2014-01-01 Abengoa Bioenergía Nuevas Tecnologías, S. A. Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide
US20140179958A1 (en) * 2012-12-20 2014-06-26 Celanese International Corporation Catalysts and processes for producing butanol

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000038832A1 (en) 1998-12-23 2000-07-06 Den Norske Stats Oljeselskap A.S Catalysts consisting of metals on hydrotalcite-based carrier materials, and method for the preparation thereof
WO2009026510A1 (en) 2007-08-22 2009-02-26 E. I. Du Pont De Nemours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst

Also Published As

Publication number Publication date
IN2014MN02648A (cg-RX-API-DMAC7.html) 2015-08-21
BR112014032466B1 (pt) 2021-11-30
MX2015000224A (es) 2015-10-09
RU2014152879A (ru) 2016-08-20
EP2679304A1 (en) 2014-01-01
KR20150088235A (ko) 2015-07-31
BR112014032466A2 (pt) 2017-08-01
US9475741B2 (en) 2016-10-25
ZA201409539B (en) 2015-11-25
EP2767336A1 (en) 2014-08-20
CN104736239A (zh) 2015-06-24
US20150166443A1 (en) 2015-06-18
CA2877974A1 (en) 2014-01-03
CA2877974C (en) 2021-06-22
MX346356B (es) 2017-03-15
CN104736239B (zh) 2018-06-08
ES2545132T3 (es) 2015-09-08
WO2014001597A1 (es) 2014-01-03
HUE025461T2 (en) 2016-02-29
EP2767336B1 (en) 2015-07-01

Similar Documents

Publication Publication Date Title
US9475741B2 (en) Method for obtaining higher alcohols
KR102113105B1 (ko) 고급 알코올을 제조하기 위한 촉매
US8318989B2 (en) Process for producing guerbet alcohols using water tolerant basic catalysts
TWI549751B (zh) 用於將醛類氫化為醇類之促進型銅/鋅催化劑、其製造方法及使用該催化劑將醛類氫化為醇類之方法
JPH0515696B2 (cg-RX-API-DMAC7.html)
CN108136384A (zh) 用于转化乙醇为正丁醇和更高级醇的催化剂组合物
US10207973B2 (en) Method for producing 1-octanol
US10538469B2 (en) Method for producing 1-octanol
EP3878831A1 (en) Improved nickel-copper-manganese-catalyst for the preparation of alcohols by hydrogenation of the corresponding aldehydes and ketones
JPH05200299A (ja) 高度に選択性のモノアルキレングリコール触媒
EP4129963A1 (en) Catalyst, method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate
EP4129962A1 (en) Method for producing isobutylene, method for producing methacrylic acid, and method for producing methyl methacrylate
KR20140146401A (ko) 에탄올로부터 1-부탄올 함유 고급 알코올의 제조방법 및 이를 위한 촉매

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20150127

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20180604

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20191106

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20200108

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20200408

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20200408

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20240404

Start annual number: 5

End annual number: 5