BR112014032466B1 - Catalisador para a obtenção de alcoóis superiores - Google Patents

Catalisador para a obtenção de alcoóis superiores Download PDF

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Publication number
BR112014032466B1
BR112014032466B1 BR112014032466-2A BR112014032466A BR112014032466B1 BR 112014032466 B1 BR112014032466 B1 BR 112014032466B1 BR 112014032466 A BR112014032466 A BR 112014032466A BR 112014032466 B1 BR112014032466 B1 BR 112014032466B1
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BR
Brazil
Prior art keywords
catalyst
list
ethanol
hydrotalcite
carried out
Prior art date
Application number
BR112014032466-2A
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English (en)
Portuguese (pt)
Other versions
BR112014032466A2 (pt
Inventor
Ricardo Arjona Antolín
Juan Luís Yagüe
Avelino Corma Canós
Marcelo Eduardo Domine
Fernando Vidal Barrero
Francisco Antonio Ladrón De Guevara Vidal
Original Assignee
Abengoa Bioenergía Nuevas Tecnologías, S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Abengoa Bioenergía Nuevas Tecnologías, S.A. filed Critical Abengoa Bioenergía Nuevas Tecnologías, S.A.
Publication of BR112014032466A2 publication Critical patent/BR112014032466A2/pt
Publication of BR112014032466B1 publication Critical patent/BR112014032466B1/pt

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6562—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/896—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C07C29/34—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups by condensation involving hydroxy groups or the mineral ester groups derived therefrom, e.g. Guerbet reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
BR112014032466-2A 2012-06-29 2013-07-01 Catalisador para a obtenção de alcoóis superiores BR112014032466B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12382261.1 2012-06-29
EP12382261.1A EP2679304A1 (en) 2012-06-29 2012-06-29 Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide
PCT/ES2013/070448 WO2014001597A1 (es) 2012-06-29 2013-07-01 Procedimiento de obtención de alcoholes superiores

Publications (2)

Publication Number Publication Date
BR112014032466A2 BR112014032466A2 (pt) 2017-08-01
BR112014032466B1 true BR112014032466B1 (pt) 2021-11-30

Family

ID=49111231

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112014032466-2A BR112014032466B1 (pt) 2012-06-29 2013-07-01 Catalisador para a obtenção de alcoóis superiores

Country Status (13)

Country Link
US (1) US9475741B2 (cg-RX-API-DMAC7.html)
EP (2) EP2679304A1 (cg-RX-API-DMAC7.html)
KR (1) KR102100714B1 (cg-RX-API-DMAC7.html)
CN (1) CN104736239B (cg-RX-API-DMAC7.html)
BR (1) BR112014032466B1 (cg-RX-API-DMAC7.html)
CA (1) CA2877974C (cg-RX-API-DMAC7.html)
ES (1) ES2545132T3 (cg-RX-API-DMAC7.html)
HU (1) HUE025461T2 (cg-RX-API-DMAC7.html)
IN (1) IN2014MN02648A (cg-RX-API-DMAC7.html)
MX (1) MX346356B (cg-RX-API-DMAC7.html)
RU (1) RU2014152879A (cg-RX-API-DMAC7.html)
WO (1) WO2014001597A1 (cg-RX-API-DMAC7.html)
ZA (1) ZA201409539B (cg-RX-API-DMAC7.html)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2679304A1 (en) 2012-06-29 2014-01-01 Abengoa Bioenergía Nuevas Tecnologías, S. A. Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide
JP6301481B2 (ja) * 2013-09-17 2018-03-28 エルジー・ケム・リミテッド アルカノールの製造方法
HUE043870T2 (hu) 2013-12-27 2019-09-30 Abengoa Bioenergia Nuevas Tecnologias Sa Eljárás nagyobb szénatomszámú alkoholok elõállítására alacsonyabb szénatomszámú alkoholokból Guerbet kondenzációval
CN104892361A (zh) * 2014-03-04 2015-09-09 中国科学院大连化学物理研究所 一种催化转化甲醇制备丙醇的方法
CN104892362A (zh) * 2014-03-04 2015-09-09 中国科学院大连化学物理研究所 一种催化转化甲醇制备丁醇的方法
EP3218339B1 (en) * 2014-11-14 2022-01-05 Abengoa Bioenergía Nuevas Tecnologías, S. A. Process for the preparation of higher alcohols from ethanol and n-hexanol by guerbet condensation
ES2570233B1 (es) * 2014-11-14 2017-02-22 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
ES2570231B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
ES2570227B1 (es) * 2014-11-14 2017-04-19 Abengoa Bioenergia Nuevas Tecnologias, S.A. Proceso para la preparación de alcoholes superiores a partir de etanol y n-hexanol mediante condensación de guerbet
BR112018003036B1 (pt) * 2015-08-19 2021-11-09 Rescurve, Llc Método para produção de um álcool superior
ES2647963B1 (es) 2016-05-26 2018-10-03 Abengoa Bioenergía Nuevas Tecnologías, S.A. Procedimiento de obtención de 1-octanol
CN108686671A (zh) * 2018-06-11 2018-10-23 福州大学 一种低温甲醇分解催化剂的制备
CN109529897B (zh) * 2018-12-04 2020-07-31 西南化工研究设计院有限公司 一种生产正丁醇的钯镓双金属催化剂及其制备方法及应用
CN111715252B (zh) * 2019-03-21 2022-03-25 北京大学 一种催化合成有机化合物的方法及其催化剂和应用
BR112023002710A2 (pt) * 2020-09-14 2023-04-25 China Petroleum & Chem Corp Processo para a produção de propanol e/ou isobutanol
CN113019404B (zh) * 2021-03-23 2022-02-18 中国科学院兰州化学物理研究所 用于合成高碳醇的镍基催化剂及其制备方法与应用
CN114588904B (zh) * 2022-03-08 2024-11-26 中国科学院青岛生物能源与过程研究所 Cu基金属氧化物催化剂、其制备方法以及采用其的2,3-丁二醇的合成方法
CN115445630B (zh) * 2022-08-30 2023-11-17 广东工业大学 一种聚丙烯基锡掺杂碳包镍催化剂及其制备方法和应用
CN118059885B (zh) * 2024-01-30 2024-09-27 南京工业大学 一种负载金多相催化剂及其制备方法和应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5300695A (en) 1992-12-07 1994-04-05 Amoco Corporation Process for preparing alcohols
US5387570A (en) 1993-05-07 1995-02-07 Exxon Research & Engineering Co. Catalysts for iso-alcohol synthesis from CO + H2
NO312126B1 (no) * 1998-12-23 2002-03-25 Norske Stats Oljeselskap Forbedret fremgangsmåte for fremstilling av katalysatorer bestående av metaller på hydrotalcitt-baserte b¶rermaterialer
WO2006059729A1 (ja) 2004-12-03 2006-06-08 Kabushiki Kaisha Sangi 高分子アルコールの合成法
US7700811B2 (en) 2007-08-22 2010-04-20 E.I. Du Pont De Namours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
WO2009026510A1 (en) 2007-08-22 2009-02-26 E. I. Du Pont De Nemours And Company Catalytic conversion of ethanol to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite catalyst
US8071823B2 (en) 2008-01-28 2011-12-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite/metal carbonate
US8071822B2 (en) 2008-01-28 2011-12-06 E.I. Du Pont De Nemours And Company Catalytic conversion of ethanol and hydrogen to a 1-butanol-containing reaction product using a thermally decomposed hydrotalcite containing the anion of ethylenediaminetetraacetic acid
US8318989B2 (en) 2008-12-22 2012-11-27 E I Du Pont De Nemours And Company Process for producing guerbet alcohols using water tolerant basic catalysts
EP2679304A1 (en) 2012-06-29 2014-01-01 Abengoa Bioenergía Nuevas Tecnologías, S. A. Process for obtaining higher alcohols in the presence of a gallium containing mixed oxide
US20140179958A1 (en) * 2012-12-20 2014-06-26 Celanese International Corporation Catalysts and processes for producing butanol

Also Published As

Publication number Publication date
IN2014MN02648A (cg-RX-API-DMAC7.html) 2015-08-21
MX2015000224A (es) 2015-10-09
RU2014152879A (ru) 2016-08-20
EP2679304A1 (en) 2014-01-01
KR20150088235A (ko) 2015-07-31
BR112014032466A2 (pt) 2017-08-01
US9475741B2 (en) 2016-10-25
ZA201409539B (en) 2015-11-25
EP2767336A1 (en) 2014-08-20
CN104736239A (zh) 2015-06-24
US20150166443A1 (en) 2015-06-18
CA2877974A1 (en) 2014-01-03
CA2877974C (en) 2021-06-22
MX346356B (es) 2017-03-15
CN104736239B (zh) 2018-06-08
ES2545132T3 (es) 2015-09-08
KR102100714B1 (ko) 2020-04-16
WO2014001597A1 (es) 2014-01-03
HUE025461T2 (en) 2016-02-29
EP2767336B1 (en) 2015-07-01

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 01/07/2013, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved

Owner name: CATALYXX INC. (US)

B25K Entry of change of name and/or headquarter and transfer of application, patent and certificate of addition of invention: republication

Owner name: CATALYXX INC. (US)

Free format text: RETIFICACAO DO DESPACHO ?(25.1) ? TRANSFERENCIA DE TITULAR? PUBLICADO NA RPI NO 2827, DE 11/03/2025, QUANTO AO ITEM ?(54) - TITULO?.ONDE SE LE: ?PROCESSO DE OBTENCAO DE ALCOOIS SUPERIORES?LEIA-SE: ?CATALISADOR PARA A OBTENCAO DE ALCOOIS SUPERIORES?