KR102018406B1 - 경질 폴리우레탄 폼 및 경질 폴리이소시아누레이트 폼의 제조 방법 - Google Patents

경질 폴리우레탄 폼 및 경질 폴리이소시아누레이트 폼의 제조 방법 Download PDF

Info

Publication number
KR102018406B1
KR102018406B1 KR1020147021750A KR20147021750A KR102018406B1 KR 102018406 B1 KR102018406 B1 KR 102018406B1 KR 1020147021750 A KR1020147021750 A KR 1020147021750A KR 20147021750 A KR20147021750 A KR 20147021750A KR 102018406 B1 KR102018406 B1 KR 102018406B1
Authority
KR
South Korea
Prior art keywords
acid
oil
component
mol
polyol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020147021750A
Other languages
English (en)
Korean (ko)
Other versions
KR20140109475A (ko
Inventor
군나르 캄프
Original Assignee
바스프 에스이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바스프 에스이 filed Critical 바스프 에스이
Publication of KR20140109475A publication Critical patent/KR20140109475A/ko
Application granted granted Critical
Publication of KR102018406B1 publication Critical patent/KR102018406B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4219—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from aromatic dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
    • C08G18/4252—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids derived from polyols containing polyether groups and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4288—Polycondensates having carboxylic or carbonic ester groups in the main chain modified by higher fatty oils or their acids or by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/184—Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C08J2375/08—Polyurethanes from polyethers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Laminated Bodies (AREA)
KR1020147021750A 2012-01-02 2012-12-13 경질 폴리우레탄 폼 및 경질 폴리이소시아누레이트 폼의 제조 방법 Active KR102018406B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP12150016 2012-01-02
EP12150016.9 2012-01-02
EP12160927.5 2012-03-23
EP12160927 2012-03-23
PCT/EP2012/075347 WO2013102540A1 (de) 2012-01-02 2012-12-13 Verfahren zur herstellung von polyurethan-hartschäumen und polyisocyanurat-hartschäumen

Publications (2)

Publication Number Publication Date
KR20140109475A KR20140109475A (ko) 2014-09-15
KR102018406B1 true KR102018406B1 (ko) 2019-10-21

Family

ID=47501145

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020147021750A Active KR102018406B1 (ko) 2012-01-02 2012-12-13 경질 폴리우레탄 폼 및 경질 폴리이소시아누레이트 폼의 제조 방법

Country Status (19)

Country Link
EP (1) EP2800769B1 (enExample)
JP (2) JP2015504113A (enExample)
KR (1) KR102018406B1 (enExample)
CN (1) CN104039856B (enExample)
AU (1) AU2012364369B2 (enExample)
BR (1) BR112014016275B1 (enExample)
CA (1) CA2862774C (enExample)
EA (1) EA027089B1 (enExample)
ES (1) ES2560968T3 (enExample)
HU (1) HUE027908T2 (enExample)
IN (1) IN2014CN04925A (enExample)
MX (1) MX339548B (enExample)
MY (1) MY167781A (enExample)
PH (1) PH12014501409A1 (enExample)
PL (1) PL2800769T3 (enExample)
RS (1) RS54603B1 (enExample)
SG (1) SG11201403796RA (enExample)
WO (1) WO2013102540A1 (enExample)
ZA (1) ZA201405619B (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8895636B2 (en) 2012-01-02 2014-11-25 Basf Se Producing rigid polyurethane foams and rigid polyisocyanurate foams
ES2570353T3 (es) * 2012-01-18 2016-05-18 Basf Se Método para la producción de espumas duras de poliuretano
US9475220B2 (en) 2013-02-13 2016-10-25 Basf Se Process for producing composite elements
PL3036267T3 (pl) * 2013-08-20 2018-03-30 Basf Se Ulepszone poliuretanowe i poliizocyjanuranowe sztywne tworzywa piankowe na bazie polieteropolioli modyfikowanych kwasami tłuszczowymi
RU2676285C1 (ru) * 2013-12-16 2018-12-27 Роквул Интернэшнл А/С Композиты на основе вспененного полиизоцианурата, их получение и применение
KR102338624B1 (ko) * 2014-02-11 2021-12-14 바스프 에스이 폴리우레탄 강성 폼 및 폴리이소시아누레이트 강성 폼의 제조 방법
CN104448186A (zh) * 2014-11-20 2015-03-25 镇江拜因诺生物科技有限公司 一种生物基聚氨酯泡沫保温材料
CA2973777C (en) * 2015-03-12 2023-09-26 Huntsman Advanced Materials Licensing (Switzerland) Gmbh Polyol component for the production of pur foams
US10167358B2 (en) * 2015-08-17 2019-01-01 Covestro Deutschland Ag Process for modifying isocyanates with use of cyclic ammonium salts as catalyst
WO2020231603A1 (en) * 2019-05-16 2020-11-19 Dow Global Technologies Llc Compatibilized blends of terephalate ester polyols and hydrocarbon blowing agents
US12319778B2 (en) * 2019-07-22 2025-06-03 Dow Global Technologies Llc Polyurethane compositions, products prepared with same and preparation methods thereof
PT4419574T (pt) 2021-10-18 2025-10-24 Basf Se Processo para a produção de espumas rígidas de poliisocianurato melhoradas à base de poliois poliéster aromáticos e poliois poliéter à base de óxido de etileno
CN116925317B (zh) * 2023-09-19 2023-11-28 南京赛弗尼电气有限公司 一种地面抬升用聚氨酯树脂组合物及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3138562A (en) 1959-05-23 1964-06-23 Bayer Ag Cellular polyurethane plastics
US6664363B1 (en) 1998-02-23 2003-12-16 Stepan Company Low viscosity polyester polyols and methods for preparing same

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1003714B (de) 1956-01-25 1957-03-07 Glanzstoff Ag Verfahren zum Abbau von Polyaethylenterephthalat zu Terephthalsaeuredimethylester
US3399154A (en) * 1965-10-22 1968-08-27 Witco Chemical Corp Rigid polyurethane foams and polyesters for use therein
US5051528A (en) 1990-04-24 1991-09-24 Eastman Kodak Company Recovery process for ethylene glycol and dimethylterephthalate
DE102005041763A1 (de) * 2005-09-01 2007-03-08 Basf Ag Polyisocyanurat Hartschaum und Verfahren zur Herstellung
SI2340269T1 (sl) * 2008-10-15 2013-01-31 Basf Se Poliesterski polioli na bazi terefthalične kisline
EP2492297A1 (de) * 2011-02-23 2012-08-29 Basf Se Polyesterpolyole auf Basis aromatischer Dicarbonsäuren und daraus hergestellte Polyurethanhartschäume
ES2570353T3 (es) * 2012-01-18 2016-05-18 Basf Se Método para la producción de espumas duras de poliuretano

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3138562A (en) 1959-05-23 1964-06-23 Bayer Ag Cellular polyurethane plastics
US6664363B1 (en) 1998-02-23 2003-12-16 Stepan Company Low viscosity polyester polyols and methods for preparing same

Also Published As

Publication number Publication date
IN2014CN04925A (enExample) 2015-09-18
EP2800769B1 (de) 2015-12-09
BR112014016275A8 (pt) 2017-07-04
MX339548B (es) 2016-05-30
MY167781A (en) 2018-09-25
PH12014501409A1 (en) 2014-09-22
HUE027908T2 (en) 2016-11-28
CA2862774C (en) 2020-08-18
BR112014016275A2 (pt) 2017-06-13
EA027089B1 (ru) 2017-06-30
JP2018111818A (ja) 2018-07-19
CN104039856B (zh) 2017-03-01
SG11201403796RA (en) 2014-11-27
JP6567709B2 (ja) 2019-08-28
AU2012364369B2 (en) 2016-01-14
WO2013102540A1 (de) 2013-07-11
ZA201405619B (en) 2015-12-23
JP2015504113A (ja) 2015-02-05
ES2560968T3 (es) 2016-02-23
EA201491312A1 (ru) 2014-11-28
BR112014016275B1 (pt) 2020-10-27
CN104039856A (zh) 2014-09-10
MX2014007821A (es) 2014-09-01
PL2800769T3 (pl) 2016-06-30
CA2862774A1 (en) 2013-07-11
KR20140109475A (ko) 2014-09-15
AU2012364369A1 (en) 2014-07-24
EP2800769A1 (de) 2014-11-12
RS54603B1 (sr) 2016-08-31

Similar Documents

Publication Publication Date Title
KR102018406B1 (ko) 경질 폴리우레탄 폼 및 경질 폴리이소시아누레이트 폼의 제조 방법
KR102058227B1 (ko) 경질 폴리우레탄 발포체 및 경질 폴리이소시아누레이트 발포체의 제조 방법
AU2012366814B2 (en) Method for producing rigid polyurethane foams
CA2875176C (en) Producing rigid polyurethane foams
CA2938060A1 (en) Method for producing polyurethane rigid foams and polyisocyanurate rigid foams
AU2013269763B2 (en) Polyesterols for producing rigid polyurethane foams
US10472454B2 (en) Preparing rigid polyurethane foams
US8895636B2 (en) Producing rigid polyurethane foams and rigid polyisocyanurate foams
US20130251975A1 (en) Producing rigid polyurethane foams and rigid polyisocyanurate foams
US20130324626A1 (en) Producing rigid polyurethane foams
US20130324632A1 (en) Polyesterols for producing rigid polyurethane foams

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7