KR101967933B1 - Sn 합금 도금 장치 및 방법 - Google Patents
Sn 합금 도금 장치 및 방법 Download PDFInfo
- Publication number
- KR101967933B1 KR101967933B1 KR1020130153140A KR20130153140A KR101967933B1 KR 101967933 B1 KR101967933 B1 KR 101967933B1 KR 1020130153140 A KR1020130153140 A KR 1020130153140A KR 20130153140 A KR20130153140 A KR 20130153140A KR 101967933 B1 KR101967933 B1 KR 101967933B1
- Authority
- KR
- South Korea
- Prior art keywords
- anode
- liquid
- chamber
- alloy plating
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000007747 plating Methods 0.000 title claims abstract description 265
- 229910001128 Sn alloy Inorganic materials 0.000 title claims abstract description 91
- 238000000034 method Methods 0.000 title claims description 22
- 239000007788 liquid Substances 0.000 claims abstract description 339
- 150000002500 ions Chemical class 0.000 claims abstract description 178
- 239000000243 solution Substances 0.000 claims abstract description 76
- 239000000758 substrate Substances 0.000 claims abstract description 72
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 61
- 239000002253 acid Substances 0.000 claims abstract description 56
- 239000003792 electrolyte Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 55
- 239000003011 anion exchange membrane Substances 0.000 claims description 44
- 238000005192 partition Methods 0.000 claims description 30
- 229910045601 alloy Inorganic materials 0.000 claims description 25
- 239000000956 alloy Substances 0.000 claims description 25
- 238000000502 dialysis Methods 0.000 claims description 18
- 229910052718 tin Inorganic materials 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 239000007789 gas Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 6
- 230000005587 bubbling Effects 0.000 claims description 5
- 230000000903 blocking effect Effects 0.000 claims description 3
- 238000000151 deposition Methods 0.000 claims 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 165
- 229940098779 methanesulfonic acid Drugs 0.000 description 83
- 229910020836 Sn-Ag Inorganic materials 0.000 description 12
- 229910020988 Sn—Ag Inorganic materials 0.000 description 12
- 238000005868 electrolysis reaction Methods 0.000 description 11
- 101100493705 Caenorhabditis elegans bath-36 gene Proteins 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 9
- 230000007423 decrease Effects 0.000 description 8
- 230000005684 electric field Effects 0.000 description 8
- 238000001704 evaporation Methods 0.000 description 6
- 230000008020 evaporation Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004020 conductor Substances 0.000 description 4
- -1 methanesulfonate ion Chemical class 0.000 description 4
- 239000012466 permeate Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 239000000385 dialysis solution Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- AICMYQIGFPHNCY-UHFFFAOYSA-J methanesulfonate;tin(4+) Chemical compound [Sn+4].CS([O-])(=O)=O.CS([O-])(=O)=O.CS([O-])(=O)=O.CS([O-])(=O)=O AICMYQIGFPHNCY-UHFFFAOYSA-J 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 229910000679 solder Inorganic materials 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 229910020830 Sn-Bi Inorganic materials 0.000 description 1
- 229910020888 Sn-Cu Inorganic materials 0.000 description 1
- 229910018728 Sn—Bi Inorganic materials 0.000 description 1
- 229910019204 Sn—Cu Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000001687 destabilization Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- GTBQRHOYAUGRPV-UHFFFAOYSA-N methanesulfonic acid;silver Chemical compound [Ag].CS(O)(=O)=O GTBQRHOYAUGRPV-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/12—Process control or regulation
- C25D21/14—Controlled addition of electrolyte components
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/002—Cell separation, e.g. membranes, diaphragms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/10—Agitating of electrolytes; Moving of racks
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/16—Regeneration of process solutions
- C25D21/18—Regeneration of process solutions of electrolytes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/30—Electroplating: Baths therefor from solutions of tin
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/003—Electroplating using gases, e.g. pressure influence
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/001—Apparatus specially adapted for electrolytic coating of wafers, e.g. semiconductors or solar cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/008—Current shielding devices
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Automation & Control Theory (AREA)
- Electroplating Methods And Accessories (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012272168A JP6022922B2 (ja) | 2012-12-13 | 2012-12-13 | Sn合金めっき装置及び方法 |
| JPJP-P-2012-272168 | 2012-12-13 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20140077112A KR20140077112A (ko) | 2014-06-23 |
| KR101967933B1 true KR101967933B1 (ko) | 2019-04-10 |
Family
ID=50929683
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020130153140A Active KR101967933B1 (ko) | 2012-12-13 | 2013-12-10 | Sn 합금 도금 장치 및 방법 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20140166492A1 (enExample) |
| JP (1) | JP6022922B2 (enExample) |
| KR (1) | KR101967933B1 (enExample) |
| TW (1) | TWI582271B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9303329B2 (en) * | 2013-11-11 | 2016-04-05 | Tel Nexx, Inc. | Electrochemical deposition apparatus with remote catholyte fluid management |
| JP6335763B2 (ja) | 2014-11-20 | 2018-05-30 | 株式会社荏原製作所 | めっき装置及びめっき方法 |
| US10011919B2 (en) * | 2015-05-29 | 2018-07-03 | Lam Research Corporation | Electrolyte delivery and generation equipment |
| KR101776149B1 (ko) | 2015-07-24 | 2017-09-08 | 덕산하이메탈(주) | 발열 및 비정질 특성을 가진 합금 도금용 도금장치 및 도금방법 |
| JP2017137519A (ja) * | 2016-02-01 | 2017-08-10 | 株式会社荏原製作所 | めっき装置 |
| JP6986921B2 (ja) * | 2017-10-12 | 2021-12-22 | 株式会社荏原製作所 | めっき装置及びめっき方法 |
| JP6942072B2 (ja) * | 2018-02-22 | 2021-09-29 | 株式会社荏原製作所 | めっき装置 |
| CN108827992B (zh) * | 2018-06-21 | 2021-03-23 | 西凡仪器(深圳)有限公司 | K金电铸镀层成分全自动控制装置和系统 |
| KR102343152B1 (ko) | 2019-02-28 | 2021-12-23 | 미쓰비시 마테리알 가부시키가이샤 | 고농도 술폰산주석 수용액 및 그 제조 방법 |
| JP2021025092A (ja) * | 2019-08-06 | 2021-02-22 | 株式会社荏原製作所 | 基板処理装置 |
| JP7227875B2 (ja) * | 2019-08-22 | 2023-02-22 | 株式会社荏原製作所 | 基板ホルダおよびめっき装置 |
| EP3929332B1 (en) * | 2020-06-25 | 2023-08-30 | Semsysco GmbH | Shield body system for a process fluid for chemical and/or electrolytic surface treatment of a substrate |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001316893A (ja) * | 2000-05-01 | 2001-11-16 | Shimonoseki Mekki Kk | 不溶性陽極を使用する表面処理方法及びその装置 |
| JP2003277996A (ja) * | 2002-03-19 | 2003-10-02 | Dainippon Screen Mfg Co Ltd | メッキ装置およびメッキ液組成調整方法 |
| US20060096867A1 (en) * | 2004-11-10 | 2006-05-11 | George Bokisa | Tin alloy electroplating system |
| JP2007138304A (ja) * | 2000-03-17 | 2007-06-07 | Ebara Corp | めっき装置及び方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03145793A (ja) * | 1989-10-31 | 1991-06-20 | Fujitsu Ltd | プリント配線板の電解めっき用気泡撹拌装置 |
| US5227046A (en) * | 1991-10-07 | 1993-07-13 | Unisys Corporation | Low temperature tin-bismuth electroplating system |
| JP2559935B2 (ja) * | 1991-12-20 | 1996-12-04 | 日本リーロナール株式会社 | 不溶性陽極を用いた錫又は錫ー鉛合金電気めっきの方法及び装置 |
| JPH06158397A (ja) * | 1992-11-18 | 1994-06-07 | Asahi Glass Co Ltd | 金属の電気メッキ方法 |
| US5312539A (en) * | 1993-06-15 | 1994-05-17 | Learonal Inc. | Electrolytic tin plating method |
| US6251255B1 (en) * | 1998-12-22 | 2001-06-26 | Precision Process Equipment, Inc. | Apparatus and method for electroplating tin with insoluble anodes |
| JP4441725B2 (ja) * | 2003-11-04 | 2010-03-31 | 石原薬品株式会社 | 電気スズ合金メッキ方法 |
| EP2194165A1 (en) * | 2008-10-21 | 2010-06-09 | Rohm and Haas Electronic Materials LLC | Method for replenishing tin and its alloying metals in electrolyte solutions |
| JP5876767B2 (ja) * | 2012-05-15 | 2016-03-02 | 株式会社荏原製作所 | めっき装置及びめっき液管理方法 |
-
2012
- 2012-12-13 JP JP2012272168A patent/JP6022922B2/ja active Active
-
2013
- 2013-12-10 KR KR1020130153140A patent/KR101967933B1/ko active Active
- 2013-12-11 US US14/103,767 patent/US20140166492A1/en not_active Abandoned
- 2013-12-12 TW TW102145935A patent/TWI582271B/zh active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007138304A (ja) * | 2000-03-17 | 2007-06-07 | Ebara Corp | めっき装置及び方法 |
| JP2001316893A (ja) * | 2000-05-01 | 2001-11-16 | Shimonoseki Mekki Kk | 不溶性陽極を使用する表面処理方法及びその装置 |
| JP2003277996A (ja) * | 2002-03-19 | 2003-10-02 | Dainippon Screen Mfg Co Ltd | メッキ装置およびメッキ液組成調整方法 |
| US20060096867A1 (en) * | 2004-11-10 | 2006-05-11 | George Bokisa | Tin alloy electroplating system |
Also Published As
| Publication number | Publication date |
|---|---|
| US20140166492A1 (en) | 2014-06-19 |
| TW201435147A (zh) | 2014-09-16 |
| JP6022922B2 (ja) | 2016-11-09 |
| JP2014118578A (ja) | 2014-06-30 |
| KR20140077112A (ko) | 2014-06-23 |
| TWI582271B (zh) | 2017-05-11 |
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