KR101804594B1 - 균일하게 촉매화된 알콜 아미노화에 의한 폴리알킬렌 폴리아민 - Google Patents

균일하게 촉매화된 알콜 아미노화에 의한 폴리알킬렌 폴리아민 Download PDF

Info

Publication number
KR101804594B1
KR101804594B1 KR1020127033440A KR20127033440A KR101804594B1 KR 101804594 B1 KR101804594 B1 KR 101804594B1 KR 1020127033440 A KR1020127033440 A KR 1020127033440A KR 20127033440 A KR20127033440 A KR 20127033440A KR 101804594 B1 KR101804594 B1 KR 101804594B1
Authority
KR
South Korea
Prior art keywords
mmol
catalyst
product
group
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020127033440A
Other languages
English (en)
Korean (ko)
Other versions
KR20130089164A (ko
Inventor
토마스 샤웁
보리스 부슈하우스
요한-페터 멀더
로코 파시엘로
슈테판 후퍼
헬무트 비텔러
Original Assignee
바스프 에스이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바스프 에스이 filed Critical 바스프 에스이
Publication of KR20130089164A publication Critical patent/KR20130089164A/ko
Application granted granted Critical
Publication of KR101804594B1 publication Critical patent/KR101804594B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • C08G73/0213—Preparatory process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
KR1020127033440A 2010-05-31 2011-05-27 균일하게 촉매화된 알콜 아미노화에 의한 폴리알킬렌 폴리아민 Expired - Fee Related KR101804594B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10164492 2010-05-31
EP10164492.0 2010-05-31
PCT/EP2011/058758 WO2011151268A1 (de) 2010-05-31 2011-05-27 Polyalkylenpolyamine durch homogen-katalysierte alkohol-aminierung

Publications (2)

Publication Number Publication Date
KR20130089164A KR20130089164A (ko) 2013-08-09
KR101804594B1 true KR101804594B1 (ko) 2017-12-04

Family

ID=44352284

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020127033440A Expired - Fee Related KR101804594B1 (ko) 2010-05-31 2011-05-27 균일하게 촉매화된 알콜 아미노화에 의한 폴리알킬렌 폴리아민

Country Status (9)

Country Link
EP (1) EP2576054B1 (https=)
JP (1) JP5911477B2 (https=)
KR (1) KR101804594B1 (https=)
CN (1) CN103025430B (https=)
BR (1) BR112012030453A2 (https=)
CA (1) CA2801109A1 (https=)
ES (1) ES2477238T3 (https=)
MX (1) MX2012013882A (https=)
WO (1) WO2011151268A1 (https=)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8791297B2 (en) 2010-06-29 2014-07-29 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US8637709B2 (en) 2011-03-08 2014-01-28 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US8912361B2 (en) 2011-03-08 2014-12-16 Basf Se Process for preparing di-, tri- and polyamines by homogeneously catalyzed alcohol amination
US8785693B2 (en) 2011-03-08 2014-07-22 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US9193666B2 (en) 2011-03-08 2015-11-24 Basf Se Process for preparing alkanolamines by homogeneously catalyzed alcohol amination
BR112014012568A2 (pt) * 2011-11-25 2017-06-06 Basf Se processo para a preparação de polialquileno poliaminas alcoxiladas, polialquileno poliamina alcoxilada, e, uso de polialquileno poliaminas alcoxiladas
JP6124911B2 (ja) * 2011-11-25 2017-05-10 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ アルコールの均一系接触アミノ化による親油性ポリアルキレンポリアミン
WO2013076053A1 (de) * 2011-11-25 2013-05-30 Basf Se Synthese von polyalkylenpolyaminen mit einer geringen farbzahl durch homogen-katalysierte alkohol-aminierung unter anwesenheit von wasserstoff
US8877977B2 (en) 2011-11-25 2014-11-04 Basf Se Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
US8981093B2 (en) 2012-06-06 2015-03-17 Basf Se Process for preparing piperazine
EP2875027B1 (de) * 2012-07-23 2018-05-02 Basf Se Verfahren zur homogen-katalysierten aminierung von alkoholen mit ammoniak in gegenwart eines komplexkatalysators ohne anionische liganden
EP2961787A1 (de) 2013-02-28 2016-01-06 Basf Se Polyamine und verfahren zu deren herstellung
US8987518B2 (en) 2013-02-28 2015-03-24 Basf Se Polyamines and process for preparation thereof
KR102224391B1 (ko) * 2013-08-21 2021-03-08 바스프 에스이 열적 노화에 대한 개선된 저항을 갖는 플라스틱 복합 부품
WO2018108890A1 (en) * 2016-12-15 2018-06-21 Akzo Nobel Chemicals International B.V. Process for manufacturing ethylene amines
WO2018108888A1 (en) 2016-12-15 2018-06-21 Akzo Nobel Chemicals International B.V. Process for manufacturing hydroxyethyl ethylene amines

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2895973B2 (ja) * 1991-03-05 1999-05-31 花王株式会社 新規第３級アミノアルコール及びその製造方法
JP2000501757A (ja) * 1995-12-08 2000-02-15 ビーエーエスエフ アクチェンゲゼルシャフト エチレンイミンのホモポリマーの連続的製造方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3708539A (en) 1970-02-06 1973-01-02 Union Oil Co Condensation of ammonia or a primary or secondary amine with an alcohol
US4044053A (en) 1975-06-02 1977-08-23 Texaco Development Corporation Preparation of polyalkylene polyamines
DE2530042C3 (de) * 1975-07-04 1982-04-22 Institut neftechimičeskogo sinteza imeni A.V. Topčieva Akademii Nauk SSSR, Moskva Verfahren zur Herstellung von linearem Polyäthylenimin
US4032480A (en) * 1975-07-11 1977-06-28 David Solomonovich Zhuk Method of producing linear polyethylenimine
EP0034480A3 (en) 1980-02-14 1982-01-13 Grigg, Ronald Ernest Alkylation of amines
CA1228449A (en) * 1982-04-30 1987-10-20 William B. Herdle Preparation of polyalkylene polyamines
JPS6115865A (ja) * 1984-06-29 1986-01-23 Kao Corp 第３級アミンの製造方法
EP0169547B1 (en) * 1984-07-25 1988-09-21 Air Products And Chemicals, Inc. Selective syntheses of substituted amines
US4745190A (en) 1984-07-25 1988-05-17 Air Products And Chemicals, Inc. Selective synthesis of substituted amines
US4617418A (en) * 1984-11-26 1986-10-14 Air Products And Chemicals, Inc. Polyalkylene polyamines via vapor phase reaction
ES2263589T3 (es) * 2000-02-18 2006-12-16 Centelion Procedimiento para aplicar polialquileniminas funcionalizadas, composiciones que las contienen y sus aplicaciones.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2895973B2 (ja) * 1991-03-05 1999-05-31 花王株式会社 新規第３級アミノアルコール及びその製造方法
JP2000501757A (ja) * 1995-12-08 2000-02-15 ビーエーエスエフ アクチェンゲゼルシャフト エチレンイミンのホモポリマーの連続的製造方法

Also Published As

Publication number Publication date
CN103025430A (zh) 2013-04-03
JP5911477B2 (ja) 2016-04-27
WO2011151268A1 (de) 2011-12-08
KR20130089164A (ko) 2013-08-09
ES2477238T3 (es) 2014-07-16
CN103025430B (zh) 2015-11-25
EP2576054B1 (de) 2014-05-14
EP2576054A1 (de) 2013-04-10
BR112012030453A2 (pt) 2016-08-09
MX2012013882A (es) 2013-08-27
JP2013533334A (ja) 2013-08-22
CA2801109A1 (en) 2011-12-08

Similar Documents

Publication Publication Date Title
KR101804594B1 (ko) 균일하게 촉매화된 알콜 아미노화에 의한 폴리알킬렌 폴리아민
US8697834B2 (en) Polyalkylenepolyamines by homogeneously catalyzed alcohol amination
US9550725B2 (en) Lipophilic polyalkylenepolyamines by homogeneously catalyzed alcohol amination
CN103958567B (zh) 烷氧基化聚亚烷基多胺
US20130137901A1 (en) Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
CN100489010C (zh) 高度支化的高官能度聚脲
CN103958566B (zh) 通过均相催化醇胺化提高聚亚烷基多胺的摩尔质量
CN105008431A (zh) 聚胺及其制备方法
US12522689B2 (en) Mannich base epoxy curative, cured epoxy resins thereof and methods of preparing the same
US8987518B2 (en) Polyamines and process for preparation thereof
KR102596991B1 (ko) 고급 에틸렌 아민의 제조 방법
Brouwer et al. The promoting role of polycations in the cobalt (II) phthalocyanine tetrasodium sulfonate catalysed oxidation of thiols
KR20140098204A (ko) 수소 존재 하의 균일 촉매화 알코올 아민화에 의한 낮은 색 지수를 갖는 폴리알킬렌 폴리아민의 합성
JP4984449B2 (ja) アルキル化ポリアルキレンポリアミン組成物、及びその製造方法
US7645855B2 (en) Highly functional, highly branched polyureas
Cheng et al. Synthesis of poly (aminoamides) via enzymatic means
JPS6172009A (ja) 環状アミン側鎖を有する重合体およびその製造法

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20201129

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20201129