JP5911477B2 - アルコールの均一系接触アミノ化によるポリアルキレンポリアミン - Google Patents

アルコールの均一系接触アミノ化によるポリアルキレンポリアミン Download PDF

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JP5911477B2
JP5911477B2 JP2013512851A JP2013512851A JP5911477B2 JP 5911477 B2 JP5911477 B2 JP 5911477B2 JP 2013512851 A JP2013512851 A JP 2013512851A JP 2013512851 A JP2013512851 A JP 2013512851A JP 5911477 B2 JP5911477 B2 JP 5911477B2
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product
reaction
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JP2013533334A5 (https=
JP2013533334A (ja
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シャウプ トーマス
シャウプ トーマス
ブッシュハウス ボリス
ブッシュハウス ボリス
ヨハン−ペーター　メルダー
メルダー ヨハン−ペーター
パシエロ ロッコ
パシエロ ロッコ
ヒュファー シュテファン
ヒュファー シュテファン
ヴィッテラー ヘルムート
ヴィッテラー ヘルムート
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • C08G73/0213—Preparatory process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
JP2013512851A 2010-05-31 2011-05-27 アルコールの均一系接触アミノ化によるポリアルキレンポリアミン Expired - Fee Related JP5911477B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10164492 2010-05-31
EP10164492.0 2010-05-31
PCT/EP2011/058758 WO2011151268A1 (de) 2010-05-31 2011-05-27 Polyalkylenpolyamine durch homogen-katalysierte alkohol-aminierung

Publications (3)

Publication Number Publication Date
JP2013533334A JP2013533334A (ja) 2013-08-22
JP2013533334A5 JP2013533334A5 (https=) 2014-07-10
JP5911477B2 true JP5911477B2 (ja) 2016-04-27

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JP2013512851A Expired - Fee Related JP5911477B2 (ja) 2010-05-31 2011-05-27 アルコールの均一系接触アミノ化によるポリアルキレンポリアミン

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EP (1) EP2576054B1 (https=)
JP (1) JP5911477B2 (https=)
KR (1) KR101804594B1 (https=)
CN (1) CN103025430B (https=)
BR (1) BR112012030453A2 (https=)
CA (1) CA2801109A1 (https=)
ES (1) ES2477238T3 (https=)
MX (1) MX2012013882A (https=)
WO (1) WO2011151268A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014534249A (ja) * 2011-11-25 2014-12-18 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 水素の存在下でのアルコールの均一系接触アミノ化による低い色数を有するポリアルキレンポリアミンの合成

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8791297B2 (en) 2010-06-29 2014-07-29 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US8637709B2 (en) 2011-03-08 2014-01-28 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US8912361B2 (en) 2011-03-08 2014-12-16 Basf Se Process for preparing di-, tri- and polyamines by homogeneously catalyzed alcohol amination
US8785693B2 (en) 2011-03-08 2014-07-22 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US9193666B2 (en) 2011-03-08 2015-11-24 Basf Se Process for preparing alkanolamines by homogeneously catalyzed alcohol amination
BR112014012568A2 (pt) * 2011-11-25 2017-06-06 Basf Se processo para a preparação de polialquileno poliaminas alcoxiladas, polialquileno poliamina alcoxilada, e, uso de polialquileno poliaminas alcoxiladas
JP6124911B2 (ja) * 2011-11-25 2017-05-10 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ アルコールの均一系接触アミノ化による親油性ポリアルキレンポリアミン
US8877977B2 (en) 2011-11-25 2014-11-04 Basf Se Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
US8981093B2 (en) 2012-06-06 2015-03-17 Basf Se Process for preparing piperazine
EP2875027B1 (de) * 2012-07-23 2018-05-02 Basf Se Verfahren zur homogen-katalysierten aminierung von alkoholen mit ammoniak in gegenwart eines komplexkatalysators ohne anionische liganden
EP2961787A1 (de) 2013-02-28 2016-01-06 Basf Se Polyamine und verfahren zu deren herstellung
US8987518B2 (en) 2013-02-28 2015-03-24 Basf Se Polyamines and process for preparation thereof
KR102224391B1 (ko) * 2013-08-21 2021-03-08 바스프 에스이 열적 노화에 대한 개선된 저항을 갖는 플라스틱 복합 부품
WO2018108890A1 (en) * 2016-12-15 2018-06-21 Akzo Nobel Chemicals International B.V. Process for manufacturing ethylene amines
WO2018108888A1 (en) 2016-12-15 2018-06-21 Akzo Nobel Chemicals International B.V. Process for manufacturing hydroxyethyl ethylene amines

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US3708539A (en) 1970-02-06 1973-01-02 Union Oil Co Condensation of ammonia or a primary or secondary amine with an alcohol
US4044053A (en) 1975-06-02 1977-08-23 Texaco Development Corporation Preparation of polyalkylene polyamines
DE2530042C3 (de) * 1975-07-04 1982-04-22 Institut neftechimičeskogo sinteza imeni A.V. Topčieva Akademii Nauk SSSR, Moskva Verfahren zur Herstellung von linearem Polyäthylenimin
US4032480A (en) * 1975-07-11 1977-06-28 David Solomonovich Zhuk Method of producing linear polyethylenimine
EP0034480A3 (en) 1980-02-14 1982-01-13 Grigg, Ronald Ernest Alkylation of amines
CA1228449A (en) * 1982-04-30 1987-10-20 William B. Herdle Preparation of polyalkylene polyamines
JPS6115865A (ja) * 1984-06-29 1986-01-23 Kao Corp 第３級アミンの製造方法
EP0169547B1 (en) * 1984-07-25 1988-09-21 Air Products And Chemicals, Inc. Selective syntheses of substituted amines
US4745190A (en) 1984-07-25 1988-05-17 Air Products And Chemicals, Inc. Selective synthesis of substituted amines
US4617418A (en) * 1984-11-26 1986-10-14 Air Products And Chemicals, Inc. Polyalkylene polyamines via vapor phase reaction
JP2895973B2 (ja) * 1991-03-05 1999-05-31 花王株式会社 新規第３級アミノアルコール及びその製造方法
DE19545874A1 (de) * 1995-12-08 1997-06-12 Basf Ag Verfahren zur kontinuierlichen Herstellung von Homopolymerisaten des Ethylenimins
ES2263589T3 (es) * 2000-02-18 2006-12-16 Centelion Procedimiento para aplicar polialquileniminas funcionalizadas, composiciones que las contienen y sus aplicaciones.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014534249A (ja) * 2011-11-25 2014-12-18 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 水素の存在下でのアルコールの均一系接触アミノ化による低い色数を有するポリアルキレンポリアミンの合成

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CN103025430A (zh) 2013-04-03
WO2011151268A1 (de) 2011-12-08
KR20130089164A (ko) 2013-08-09
KR101804594B1 (ko) 2017-12-04
ES2477238T3 (es) 2014-07-16
CN103025430B (zh) 2015-11-25
EP2576054B1 (de) 2014-05-14
EP2576054A1 (de) 2013-04-10
BR112012030453A2 (pt) 2016-08-09
MX2012013882A (es) 2013-08-27
JP2013533334A (ja) 2013-08-22
CA2801109A1 (en) 2011-12-08

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