CN103025430B - 通过均相催化醇胺化获得的聚亚烷基聚胺 - Google Patents

通过均相催化醇胺化获得的聚亚烷基聚胺 Download PDF

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CN103025430B
CN103025430B CN201180036217.2A CN201180036217A CN103025430B CN 103025430 B CN103025430 B CN 103025430B CN 201180036217 A CN201180036217 A CN 201180036217A CN 103025430 B CN103025430 B CN 103025430B
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reaction
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water
product
catalyst
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CN103025430A (zh
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T·绍布
B·布施豪斯
J-P·梅尔德
R·帕切洛
S·许弗
H·维特勒
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • C08G73/0213—Preparatory process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
CN201180036217.2A 2010-05-31 2011-05-27 通过均相催化醇胺化获得的聚亚烷基聚胺 Expired - Fee Related CN103025430B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10164492 2010-05-31
EP10164492.0 2010-05-31
PCT/EP2011/058758 WO2011151268A1 (de) 2010-05-31 2011-05-27 Polyalkylenpolyamine durch homogen-katalysierte alkohol-aminierung

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CN103025430A CN103025430A (zh) 2013-04-03
CN103025430B true CN103025430B (zh) 2015-11-25

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EP (1) EP2576054B1 (https=)
JP (1) JP5911477B2 (https=)
KR (1) KR101804594B1 (https=)
CN (1) CN103025430B (https=)
BR (1) BR112012030453A2 (https=)
CA (1) CA2801109A1 (https=)
ES (1) ES2477238T3 (https=)
MX (1) MX2012013882A (https=)
WO (1) WO2011151268A1 (https=)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8791297B2 (en) 2010-06-29 2014-07-29 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US8637709B2 (en) 2011-03-08 2014-01-28 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US8912361B2 (en) 2011-03-08 2014-12-16 Basf Se Process for preparing di-, tri- and polyamines by homogeneously catalyzed alcohol amination
US8785693B2 (en) 2011-03-08 2014-07-22 Basf Se Process for the preparation of primary amines by homogeneously catalyzed alcohol amination
US9193666B2 (en) 2011-03-08 2015-11-24 Basf Se Process for preparing alkanolamines by homogeneously catalyzed alcohol amination
BR112014012568A2 (pt) * 2011-11-25 2017-06-06 Basf Se processo para a preparação de polialquileno poliaminas alcoxiladas, polialquileno poliamina alcoxilada, e, uso de polialquileno poliaminas alcoxiladas
JP6124911B2 (ja) * 2011-11-25 2017-05-10 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ アルコールの均一系接触アミノ化による親油性ポリアルキレンポリアミン
WO2013076053A1 (de) * 2011-11-25 2013-05-30 Basf Se Synthese von polyalkylenpolyaminen mit einer geringen farbzahl durch homogen-katalysierte alkohol-aminierung unter anwesenheit von wasserstoff
US8877977B2 (en) 2011-11-25 2014-11-04 Basf Se Synthesis of polyalkylenepolyamines having a low color index by homogeneously catalyzed alcohol amination in the presence of hydrogen
US8981093B2 (en) 2012-06-06 2015-03-17 Basf Se Process for preparing piperazine
EP2875027B1 (de) * 2012-07-23 2018-05-02 Basf Se Verfahren zur homogen-katalysierten aminierung von alkoholen mit ammoniak in gegenwart eines komplexkatalysators ohne anionische liganden
EP2961787A1 (de) 2013-02-28 2016-01-06 Basf Se Polyamine und verfahren zu deren herstellung
US8987518B2 (en) 2013-02-28 2015-03-24 Basf Se Polyamines and process for preparation thereof
KR102224391B1 (ko) * 2013-08-21 2021-03-08 바스프 에스이 열적 노화에 대한 개선된 저항을 갖는 플라스틱 복합 부품
WO2018108890A1 (en) * 2016-12-15 2018-06-21 Akzo Nobel Chemicals International B.V. Process for manufacturing ethylene amines
WO2018108888A1 (en) 2016-12-15 2018-06-21 Akzo Nobel Chemicals International B.V. Process for manufacturing hydroxyethyl ethylene amines

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032480A (en) * 1975-07-11 1977-06-28 David Solomonovich Zhuk Method of producing linear polyethylenimine
CN85109304A (zh) * 1984-11-26 1986-08-06 气体产品与化学公司 通过气相反应制聚(多亚烷基多胺)
US5977293A (en) * 1995-12-08 1999-11-02 Basf Aktiengesellschaft Process for continuous preparation of homopolymers of ethyleneimine
CN1441820A (zh) * 2000-02-18 2003-09-10 甘瑟尔股份有限公司 官能化聚亚烷基亚胺的制备方法,含有它们的组合物及其应用

Family Cites Families (9)

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Publication number Priority date Publication date Assignee Title
US3708539A (en) 1970-02-06 1973-01-02 Union Oil Co Condensation of ammonia or a primary or secondary amine with an alcohol
US4044053A (en) 1975-06-02 1977-08-23 Texaco Development Corporation Preparation of polyalkylene polyamines
DE2530042C3 (de) * 1975-07-04 1982-04-22 Institut neftechimičeskogo sinteza imeni A.V. Topčieva Akademii Nauk SSSR, Moskva Verfahren zur Herstellung von linearem Polyäthylenimin
EP0034480A3 (en) 1980-02-14 1982-01-13 Grigg, Ronald Ernest Alkylation of amines
CA1228449A (en) * 1982-04-30 1987-10-20 William B. Herdle Preparation of polyalkylene polyamines
JPS6115865A (ja) * 1984-06-29 1986-01-23 Kao Corp 第３級アミンの製造方法
EP0169547B1 (en) * 1984-07-25 1988-09-21 Air Products And Chemicals, Inc. Selective syntheses of substituted amines
US4745190A (en) 1984-07-25 1988-05-17 Air Products And Chemicals, Inc. Selective synthesis of substituted amines
JP2895973B2 (ja) * 1991-03-05 1999-05-31 花王株式会社 新規第３級アミノアルコール及びその製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032480A (en) * 1975-07-11 1977-06-28 David Solomonovich Zhuk Method of producing linear polyethylenimine
CN85109304A (zh) * 1984-11-26 1986-08-06 气体产品与化学公司 通过气相反应制聚(多亚烷基多胺)
US5977293A (en) * 1995-12-08 1999-11-02 Basf Aktiengesellschaft Process for continuous preparation of homopolymers of ethyleneimine
CN1441820A (zh) * 2000-02-18 2003-09-10 甘瑟尔股份有限公司 官能化聚亚烷基亚胺的制备方法,含有它们的组合物及其应用

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Publication number Publication date
CN103025430A (zh) 2013-04-03
JP5911477B2 (ja) 2016-04-27
WO2011151268A1 (de) 2011-12-08
KR20130089164A (ko) 2013-08-09
KR101804594B1 (ko) 2017-12-04
ES2477238T3 (es) 2014-07-16
EP2576054B1 (de) 2014-05-14
EP2576054A1 (de) 2013-04-10
BR112012030453A2 (pt) 2016-08-09
MX2012013882A (es) 2013-08-27
JP2013533334A (ja) 2013-08-22
CA2801109A1 (en) 2011-12-08

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Granted publication date: 20151125