KR101740746B1 - 낮은 표면장력, 낮은 액체 점도 및 높은 고형물 함량을 갖는 플루오로아이오노머 분산액 - Google Patents

낮은 표면장력, 낮은 액체 점도 및 높은 고형물 함량을 갖는 플루오로아이오노머 분산액 Download PDF

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KR101740746B1
KR101740746B1 KR1020117030673A KR20117030673A KR101740746B1 KR 101740746 B1 KR101740746 B1 KR 101740746B1 KR 1020117030673 A KR1020117030673 A KR 1020117030673A KR 20117030673 A KR20117030673 A KR 20117030673A KR 101740746 B1 KR101740746 B1 KR 101740746B1
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fluoroionomer
formula
liquid composition
solvent
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KR20120046117A (ko
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루카 메를로
알레산드로 지엘미
빈센초 아르첼라
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솔베이 스페셜티 폴리머스 이태리 에스.피.에이.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/20—Halogenation
    • C08F8/22—Halogenation by reaction with free halogens
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16—Organic material
    • B01J39/18—Macromolecular compounds
    • B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C08F14/26—Tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275—Heterogeneous membranes
    • C08J5/2281—Heterogeneous membranes fluorine containing heterogeneous membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1058—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/1062—Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the physical properties of the porous support, e.g. its porosity or thickness
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24752—Laterally noncoextensive components

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
KR1020117030673A 2009-06-12 2010-06-10 낮은 표면장력, 낮은 액체 점도 및 높은 고형물 함량을 갖는 플루오로아이오노머 분산액 Active KR101740746B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09162625.9 2009-06-12
EP09162625 2009-06-12
PCT/EP2010/058182 WO2010142772A1 (en) 2009-06-12 2010-06-10 Fluoroionomers dispersions having low surface tension, low liquid viscosity and high solid content

Publications (2)

Publication Number Publication Date
KR20120046117A KR20120046117A (ko) 2012-05-09
KR101740746B1 true KR101740746B1 (ko) 2017-05-26

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KR1020117030673A Active KR101740746B1 (ko) 2009-06-12 2010-06-10 낮은 표면장력, 낮은 액체 점도 및 높은 고형물 함량을 갖는 플루오로아이오노머 분산액

Country Status (6)

Country Link
US (2) US9450262B2 (enExample)
EP (1) EP2440586B1 (enExample)
JP (1) JP5575885B2 (enExample)
KR (1) KR101740746B1 (enExample)
CN (2) CN102459361B (enExample)
WO (1) WO2010142772A1 (enExample)

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JP5409803B2 (ja) * 2008-12-11 2014-02-05 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア フルオロイオノマー組成物の精製
US8709199B2 (en) * 2011-09-13 2014-04-29 GM Global Technology Operations LLC Method of preparing a water vapor transfer membrane
WO2013064640A1 (en) 2011-11-04 2013-05-10 Solvicore Gmbh & Co. Kg Method for the preparation of catalyst-coated membranes
US10020526B2 (en) 2012-09-12 2018-07-10 GM Global Technology Operations LLC Reverse osmosis membranes made with PFSA ionomer and ePTFE
FR3001732B1 (fr) 2013-02-04 2016-02-26 Rhodia Operations Utilisation d'agents dispersants pour la preparation d'encres pour piles a combustible
JP2016519398A (ja) * 2013-04-29 2016-06-30 エルジー・ケム・リミテッド 高分子電解質膜、高分子電解質膜を含む膜電極接合体および膜電極接合体を含む燃料電池
JP6151111B2 (ja) * 2013-07-02 2017-06-21 旭化成株式会社 電解質溶液の製造方法、電解質溶液、電解質膜、電極触媒層、膜電極接合体、及び固体高分子電解質型燃料電池
EP2842620A1 (en) 2013-08-26 2015-03-04 Agfa-Gevaert A method for preparing a composite membrane
WO2020183306A1 (en) * 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
US20220320558A1 (en) * 2019-06-06 2022-10-06 W. L. Gore & Associates, Inc. Method of wetting low surface energy substrate and a system therefor
KR102507911B1 (ko) * 2021-03-31 2023-03-07 도레이첨단소재 주식회사 양이온 교환막 및 이의 제조방법

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JP2005327714A (ja) 2004-04-22 2005-11-24 Solvay Solexis Spa フッ素化膜
EP1798793A1 (en) * 2004-08-18 2007-06-20 Asahi Glass Company, Limited Electrolyte polymer for fuel cell, method for producing same, electrolyte membrane, and membrane electrode assembly
WO2008077894A1 (en) * 2006-12-22 2008-07-03 Solvay Solexis S.P.A. Process for operating a fuel cell in dry conditions

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JP2005206684A (ja) 2004-01-22 2005-08-04 Asahi Kasei Corp フッ素化スルホン酸ポリマーの製造方法
JP2005327714A (ja) 2004-04-22 2005-11-24 Solvay Solexis Spa フッ素化膜
EP1798793A1 (en) * 2004-08-18 2007-06-20 Asahi Glass Company, Limited Electrolyte polymer for fuel cell, method for producing same, electrolyte membrane, and membrane electrode assembly
WO2008077894A1 (en) * 2006-12-22 2008-07-03 Solvay Solexis S.P.A. Process for operating a fuel cell in dry conditions

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US20170194661A1 (en) 2017-07-06
JP5575885B2 (ja) 2014-08-20
EP2440586B1 (en) 2020-02-05
KR20120046117A (ko) 2012-05-09
WO2010142772A1 (en) 2010-12-16
CN102459361A (zh) 2012-05-16
US9450262B2 (en) 2016-09-20
CN110272512A (zh) 2019-09-24
US20120076990A1 (en) 2012-03-29
US9947952B2 (en) 2018-04-17
JP2012529549A (ja) 2012-11-22
CN102459361B (zh) 2019-07-05
EP2440586A1 (en) 2012-04-18

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