KR101632529B1 - 파라크실렌 회수 공정에서의 페놀 제거 - Google Patents

파라크실렌 회수 공정에서의 페놀 제거 Download PDF

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KR101632529B1
KR101632529B1 KR1020147033162A KR20147033162A KR101632529B1 KR 101632529 B1 KR101632529 B1 KR 101632529B1 KR 1020147033162 A KR1020147033162 A KR 1020147033162A KR 20147033162 A KR20147033162 A KR 20147033162A KR 101632529 B1 KR101632529 B1 KR 101632529B1
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phenol
xylene
stream
para
aromatic hydrocarbon
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KR20150013615A (ko
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존 디 이 오우
글렌 에이 히터
쉬팡 엘 루오
인둘리스 제이 에이랜즈
지반 에스 아비찬다니
알렌 스콧 고릭
마크 더블유 나쉬
테렌스 씨 오스비
로버트 지 팅거
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엑손모빌 케미칼 패턴츠 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/245—Stationary reactors without moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
    • C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
    • C07C37/82—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by solid-liquid treatment; by chemisorption
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/06—Alkylated phenols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/005—Processes comprising at least two steps in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/14—Purification; Separation; Use of additives by crystallisation; Purification or separation of the crystals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020147033162A 2012-05-31 2013-05-02 파라크실렌 회수 공정에서의 페놀 제거 Expired - Fee Related KR101632529B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261653698P 2012-05-31 2012-05-31
US61/653,698 2012-05-31
US201261681501P 2012-08-09 2012-08-09
US61/681,501 2012-08-09
PCT/US2013/039193 WO2013180888A1 (en) 2012-05-31 2013-05-02 Phenol removal in paraxylene recovery process

Publications (2)

Publication Number Publication Date
KR20150013615A KR20150013615A (ko) 2015-02-05
KR101632529B1 true KR101632529B1 (ko) 2016-06-21

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Country Status (7)

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US (3) US9012711B2 (enExample)
JP (2) JP6317736B2 (enExample)
KR (1) KR101632529B1 (enExample)
CN (2) CN107285975A (enExample)
BR (1) BR112014029716A2 (enExample)
TW (3) TWI537249B (enExample)
WO (1) WO2013180888A1 (enExample)

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BR112014029716A2 (pt) 2012-05-31 2017-06-27 Exxonmobil Chemical Patents Inc remoção de fenol em processo de recuperação de paraxileno
US9156749B2 (en) * 2012-05-31 2015-10-13 Exxonmobil Chemical Patents Inc. Styrene removal in paraxylene recovery process
US9193645B2 (en) * 2012-08-31 2015-11-24 Exxonmobil Chemical Patents Inc. Xylene isomerization process and catalyst therefor
US9422208B2 (en) 2013-05-07 2016-08-23 Exxonmobil Chemical Patents Inc. Treatment of aromatic hydrocarbon stream
FR3010911B1 (fr) * 2013-09-20 2017-06-09 Ifp Energies Now Procede de separation des xylenes par contre courant simule traitant une charge contenant des impuretes oxygenees aromatiques de type phenols
US9598332B2 (en) 2013-12-20 2017-03-21 Exxonmobil Chemical Patents Inc. Production of para-xylene
WO2015094500A2 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Production of para-xylene
WO2016003612A1 (en) 2014-06-30 2016-01-07 Exxonmobil Chemical Patents Inc. Processes for the production of para-xylene
JP6389284B2 (ja) 2014-06-30 2018-09-12 エクソンモービル・ケミカル・パテンツ・インク パラキシレンの製造方法
US9469579B2 (en) 2014-06-30 2016-10-18 Exxonmobil Chemical Patents Inc. Process for the production of xylenes
CN104292083A (zh) * 2014-10-11 2015-01-21 江苏常州酞青新材料科技有限公司 一种丙二醇苯醚精制过程中苯酚的去除方法
US9963403B2 (en) 2014-10-27 2018-05-08 Exxonmobil Chemical Patents Inc. Process and apparatus for the conversion of hydrocarbons
KR101974770B1 (ko) 2015-04-30 2019-05-02 엑손모빌 케미칼 패턴츠 인코포레이티드 파라-자일렌의 제조를 위한 방법 및 장치
CN110914229B (zh) 2017-11-21 2023-01-31 中国石油化工股份有限公司 从煤衍生的液体制备二甲苯和苯酚的方法
US20190241485A1 (en) 2017-12-22 2019-08-08 Exxonmobil Chemical Patents Inc. Catalysts for Producing Paraxylene by Methylation of Benzene and/or Toluene
US11053176B2 (en) 2018-03-30 2021-07-06 Exxonmobil Chemical Patents Inc. Process for co-production of mixed xylenes and high octane C9+ aromatics
TWI773974B (zh) 2019-03-29 2022-08-11 美商艾克頌美孚化學專利股份有限公司 新穎沸石，其製法，及其於轉化芳族烴之用途
KR20210126101A (ko) 2019-03-29 2021-10-19 엑손모빌 케미칼 패턴츠 인코포레이티드 방향족 탄화수소 전환용 mel형 제올라이트, 상기 제올라이트의 제조 방법, 및 상기 제올라이트를 포함하는 촉매 조성물
CN110746255A (zh) * 2019-09-24 2020-02-04 陕西煤化工技术工程中心有限公司 一种粗苯制对二甲苯的方法
CN113443992B (zh) * 2020-03-25 2022-09-27 天津大加化工有限公司 一种低苯酚含量的水杨酸甲酯的制备方法
FR3112289B1 (fr) * 2020-07-10 2022-07-22 Arkema France Purification de liquides aromatiques

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US9156749B2 (en) 2012-05-31 2015-10-13 Exxonmobil Chemical Patents Inc. Styrene removal in paraxylene recovery process
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JP2017066151A (ja) 2017-04-06
WO2013180888A1 (en) 2013-12-05
WO2013180888A8 (en) 2014-07-24
US9434661B2 (en) 2016-09-06
CN104395272A (zh) 2015-03-04
BR112014029716A2 (pt) 2017-06-27
JP2015521199A (ja) 2015-07-27
TW201813948A (zh) 2018-04-16
TWI640506B (zh) 2018-11-11
US9012711B2 (en) 2015-04-21
TW201613844A (en) 2016-04-16
CN107285975A (zh) 2017-10-24
TW201406721A (zh) 2014-02-16
US20130324780A1 (en) 2013-12-05
US9205401B2 (en) 2015-12-08
TWI537249B (zh) 2016-06-11
US20150314261A1 (en) 2015-11-05
KR20150013615A (ko) 2015-02-05
JP6317736B2 (ja) 2018-04-25
TWI624455B (zh) 2018-05-21
US20150299070A1 (en) 2015-10-22

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