KR101567617B1 - 엘라스토머 혼합물의 보강 충전제로서의 침전 규산 - Google Patents
엘라스토머 혼합물의 보강 충전제로서의 침전 규산 Download PDFInfo
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- KR101567617B1 KR101567617B1 KR1020107024891A KR20107024891A KR101567617B1 KR 101567617 B1 KR101567617 B1 KR 101567617B1 KR 1020107024891 A KR1020107024891 A KR 1020107024891A KR 20107024891 A KR20107024891 A KR 20107024891A KR 101567617 B1 KR101567617 B1 KR 101567617B1
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- South Korea
- Prior art keywords
- silica
- sir
- precipitated silica
- weight
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- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 53
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- 239000000945 filler Substances 0.000 title abstract description 12
- 235000012239 silicon dioxide Nutrition 0.000 title abstract 2
- 230000002787 reinforcement Effects 0.000 title description 8
- 239000000806 elastomer Substances 0.000 title description 6
- 125000005624 silicic acid group Chemical class 0.000 title 1
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- 238000009826 distribution Methods 0.000 claims abstract description 39
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 230000008569 process Effects 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 324
- 239000000377 silicon dioxide Substances 0.000 claims description 158
- 238000007792 addition Methods 0.000 claims description 42
- 239000000725 suspension Substances 0.000 claims description 34
- 238000001035 drying Methods 0.000 claims description 29
- -1 benzoic acid ester Chemical class 0.000 claims description 24
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 23
- 239000008187 granular material Substances 0.000 claims description 22
- 239000012065 filter cake Substances 0.000 claims description 21
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- 239000002535 acidifier Substances 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 11
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- 125000003342 alkenyl group Chemical group 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
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- 238000006243 chemical reaction Methods 0.000 claims description 8
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- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
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- 239000011593 sulfur Substances 0.000 claims description 6
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- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 4
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- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 claims description 4
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- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 claims description 2
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 claims description 2
- 101150065749 Churc1 gene Proteins 0.000 claims description 2
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- 229940095602 acidifiers Drugs 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 2
- 150000007529 inorganic bases Chemical class 0.000 claims description 2
- 150000007530 organic bases Chemical class 0.000 claims description 2
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- 125000001424 substituent group Chemical group 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 125000003396 thiol group Chemical class [H]S* 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
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- 239000005060 rubber Substances 0.000 abstract description 63
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 1
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- 239000000243 solution Substances 0.000 description 42
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 17
- 235000019353 potassium silicate Nutrition 0.000 description 17
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 16
- 238000004458 analytical method Methods 0.000 description 14
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- 238000010521 absorption reaction Methods 0.000 description 12
- 239000008367 deionised water Substances 0.000 description 12
- 229910021641 deionized water Inorganic materials 0.000 description 12
- 150000001335 aliphatic alkanes Chemical class 0.000 description 11
- 230000014759 maintenance of location Effects 0.000 description 11
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 11
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- 239000000047 product Substances 0.000 description 10
- 238000004073 vulcanization Methods 0.000 description 10
- 239000002552 dosage form Substances 0.000 description 9
- FLTJDUOFAQWHDF-UHFFFAOYSA-N 2,2-dimethylhexane Chemical compound CCCCC(C)(C)C FLTJDUOFAQWHDF-UHFFFAOYSA-N 0.000 description 8
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- 238000004519 manufacturing process Methods 0.000 description 8
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
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- FBBATURSCRIBHN-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC FBBATURSCRIBHN-UHFFFAOYSA-N 0.000 description 2
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- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 description 1
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
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| DE102008017747.4 | 2008-04-07 | ||
| DE102008017747A DE102008017747A1 (de) | 2008-04-07 | 2008-04-07 | Gefällte Kieselsäuren als Verstärkerfüllstoff für Elastomermischungen |
Publications (2)
| Publication Number | Publication Date |
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| KR20110009132A KR20110009132A (ko) | 2011-01-27 |
| KR101567617B1 true KR101567617B1 (ko) | 2015-11-09 |
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| KR1020107024891A Active KR101567617B1 (ko) | 2008-04-07 | 2009-03-19 | 엘라스토머 혼합물의 보강 충전제로서의 침전 규산 |
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| EP (1) | EP2262730B1 (https=) |
| JP (1) | JP5502851B2 (https=) |
| KR (1) | KR101567617B1 (https=) |
| CN (2) | CN101990519A (https=) |
| BR (1) | BRPI0911068B1 (https=) |
| DE (1) | DE102008017747A1 (https=) |
| ES (1) | ES2476894T3 (https=) |
| MX (1) | MX2010010931A (https=) |
| PL (1) | PL2262730T3 (https=) |
| PT (1) | PT2262730E (https=) |
| RU (1) | RU2544697C2 (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017109743A1 (en) * | 2015-12-23 | 2017-06-29 | Tata Chemicals Limited | Precipitated silica |
| WO2017109742A1 (en) * | 2015-12-23 | 2017-06-29 | Tata Chemicals Limited | Precipitated silica |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5039346B2 (ja) * | 2006-09-12 | 2012-10-03 | 株式会社フジミインコーポレーテッド | 溶射用粉末及び溶射皮膜 |
| DE102008017731A1 (de) * | 2008-04-07 | 2009-10-08 | Continental Aktiengesellschaft | Kautschukmischung |
| US8114935B2 (en) | 2009-05-04 | 2012-02-14 | Ppg Industries Ohio, Inc. | Microporous precipitated silica |
| WO2011144346A1 (en) * | 2010-05-21 | 2011-11-24 | Grace Gmbh & Co. Kg | Porous inorganic oxide particles and methods of making and using the same |
| KR101452656B1 (ko) * | 2010-07-09 | 2014-10-22 | 가부시키가이샤 브리지스톤 | 고무 조성물 및 이를 이용한 공기 타이어 |
| CN102225948A (zh) * | 2011-05-05 | 2011-10-26 | 厦门大学 | 硅三硫醇及其制备方法 |
| FR2988384B1 (fr) * | 2012-03-22 | 2015-09-11 | Rhodia Operations | Procede de preparation de silice precipitee comprenant une etape de fort compactage |
| CN103073762B (zh) * | 2012-12-31 | 2015-10-28 | 特拓(青岛)轮胎技术有限公司 | 一种用于路航系列乘用车轮胎胎面的橡胶组合物技术 |
| KR101507825B1 (ko) * | 2013-10-31 | 2015-04-07 | 한국타이어 주식회사 | 타이어용 고무 조성물 및 이를 이용하여 제조한 타이어 |
| DE102014200563A1 (de) | 2014-01-15 | 2015-07-16 | Evonik Industries Ag | Oligomere Organosilane, deren Herstellung und Verwendung in Kautschukmischungen |
| CN106029569B (zh) * | 2014-02-28 | 2018-11-20 | 罗地亚经营管理公司 | 制备沉淀二氧化硅的方法、沉淀二氧化硅及其用途,特别是用于增强聚合物 |
| CA2892342C (en) | 2014-05-22 | 2016-11-01 | Sylvain-Paul Morency | Tool and method for layer depalletizing |
| FR3058148A1 (fr) * | 2016-10-31 | 2018-05-04 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc comprenant une charge renforcante specifique |
| WO2018202756A1 (en) | 2017-05-05 | 2018-11-08 | Rhodia Operations | Precipitated silica and process for its manufacture |
| EP3619164B1 (en) | 2017-05-05 | 2024-11-27 | Rhodia Operations | Precipitated silica and process for its manufacture |
| JP6781106B2 (ja) * | 2017-06-09 | 2020-11-04 | 東ソー・シリカ株式会社 | ゴム補強充填用含水ケイ酸及びその製造方法 |
| WO2019241498A1 (en) | 2018-06-15 | 2019-12-19 | W. R. Grace & Co.-Conn | Defoamer active, manufacturing method thereof, and defoaming formuation |
| CN109968554B (zh) * | 2019-03-21 | 2021-01-15 | 青岛科技大学 | 一种GR-SiO2/CI材料制备方法及雾化成胶装置 |
| DE102020208510A1 (de) * | 2020-07-07 | 2022-01-13 | Evonik Operations Gmbh | Modifizierte Kieselsäuren, Verfahren zur deren Herstellung und deren Verwendung |
| EP3954743A1 (de) | 2020-08-12 | 2022-02-16 | Evonik Operations GmbH | Verwendung von siliziumdioxid zur verbesserung der leitfähigkeit von beschichtungen |
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| JP2007077012A (ja) | 2005-09-09 | 2007-03-29 | Degussa Ag | 特定の孔径分布を有する沈降シリカ |
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| US4094771A (en) | 1976-01-13 | 1978-06-13 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process for preparation of a sprayable precipitated silicic acid suspension |
| DE3437473A1 (de) | 1984-10-12 | 1986-04-17 | Degussa Ag, 6000 Frankfurt | An der oberflaeche modifizierte synthetische, silikatische fuellstoffe, ein verfahren zur herstellung und deren verwendung |
| DE4004781A1 (de) | 1990-02-16 | 1991-08-22 | Degussa | Verfahren zur herstellung von mit organosiliciumverbindungen modifizierten fuellstoffen, die so hergestellten fuellstoffe und deren verwendung |
| FR2678259B1 (fr) * | 1991-06-26 | 1993-11-05 | Rhone Poulenc Chimie | Nouvelles silices precipitees sous forme de granules ou de poudres, procedes de synthese et utilisation au renforcement des elastomeres. |
| JP3410522B2 (ja) * | 1993-09-09 | 2003-05-26 | 水澤化学工業株式会社 | 粒状非晶質シリカの製造方法 |
| EP0670813B1 (fr) | 1993-09-29 | 2003-03-12 | Rhodia Chimie | Silice precipitee |
| DE4427137B4 (de) * | 1993-10-07 | 2007-08-23 | Degussa Gmbh | Fällungskieselsäure |
| JP3719687B2 (ja) * | 1995-07-21 | 2005-11-24 | 東ソー・シリカ株式会社 | シリカゲルの製造方法 |
| DE19609619A1 (de) | 1996-03-12 | 1997-09-18 | Degussa | Staubarme, gut dispergierbare Granulate auf der Basis von mit Organosiliciumverbindungen modifizierten silikatischen Füllstoffen |
| FR2763581B1 (fr) * | 1997-05-26 | 1999-07-23 | Rhodia Chimie Sa | Silice precipitee utilisable comme charge renforcante pour elastomeres |
| ATE239737T1 (de) | 1997-08-21 | 2003-05-15 | Crompton Corp | Blockierte merkaptosilane als kupplungsmittel für gefüllte kautschukzusammensetzung |
| DE19740440A1 (de) * | 1997-09-15 | 1999-03-18 | Degussa | Leicht dispergierbare Fällungskieselsäure |
| DE19807700A1 (de) | 1998-02-24 | 1999-08-26 | Degussa | Fällungskieselsäuregranulate |
| US5956175A (en) | 1998-07-31 | 1999-09-21 | Msc Specialty Films Inc | Solar control window film |
| DE10137109A1 (de) | 2001-07-30 | 2003-02-27 | Infineon Technologies Ag | Siliziumhaltiger Resist für die Fotolithografie |
| PT1419106T (pt) * | 2001-08-13 | 2016-12-27 | Rhodia Chimie Sa | Processo de preparação de sílicas, sílicas com distribuição granulométrica e/ou repartição porosa específicas e suas utilizações, em particular no reforço de polímeros |
| DE10146325A1 (de) | 2001-09-20 | 2003-04-10 | Degussa | Fällungskieselsäure mit hohem BET/CTAB-Verhältnis |
| DE10163945C1 (de) | 2001-09-26 | 2003-05-08 | Degussa | Geblockte Mercaptosilane, ein Verfahren zu ihrer Herstellung sowie ihre Verwendung |
| DE10223658A1 (de) | 2002-05-28 | 2003-12-18 | Degussa | Organosiliciumverbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| DE10330118A1 (de) | 2002-08-03 | 2004-02-12 | Degussa Ag | Fällungskieselsäure mit hoher Oberfläche |
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2008
- 2008-04-07 DE DE102008017747A patent/DE102008017747A1/de not_active Withdrawn
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2009
- 2009-03-19 PT PT97311872T patent/PT2262730E/pt unknown
- 2009-03-19 EP EP09731187.2A patent/EP2262730B1/de active Active
- 2009-03-19 MX MX2010010931A patent/MX2010010931A/es active IP Right Grant
- 2009-03-19 KR KR1020107024891A patent/KR101567617B1/ko active Active
- 2009-03-19 US US12/935,205 patent/US8658816B2/en active Active
- 2009-03-19 CN CN2009801122501A patent/CN101990519A/zh active Pending
- 2009-03-19 WO PCT/EP2009/053243 patent/WO2009124829A1/de not_active Ceased
- 2009-03-19 RU RU2010145015/05A patent/RU2544697C2/ru active
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- 2009-03-19 BR BRPI0911068-2A patent/BRPI0911068B1/pt active IP Right Grant
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2007077012A (ja) | 2005-09-09 | 2007-03-29 | Degussa Ag | 特定の孔径分布を有する沈降シリカ |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017109743A1 (en) * | 2015-12-23 | 2017-06-29 | Tata Chemicals Limited | Precipitated silica |
| WO2017109742A1 (en) * | 2015-12-23 | 2017-06-29 | Tata Chemicals Limited | Precipitated silica |
| US10981795B2 (en) | 2015-12-23 | 2021-04-20 | Tata Chemicals Limited | Precipitated silica |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0911068B1 (pt) | 2019-04-30 |
| RU2010145015A (ru) | 2013-06-20 |
| PT2262730E (pt) | 2014-07-11 |
| TW201006763A (en) | 2010-02-16 |
| TWI399339B (zh) | 2013-06-21 |
| US8658816B2 (en) | 2014-02-25 |
| EP2262730B1 (de) | 2014-04-30 |
| JP2011516386A (ja) | 2011-05-26 |
| KR20110009132A (ko) | 2011-01-27 |
| US20110021801A1 (en) | 2011-01-27 |
| BRPI0911068A2 (pt) | 2015-12-29 |
| CN101990519A (zh) | 2011-03-23 |
| RU2544697C2 (ru) | 2015-03-20 |
| DE102008017747A1 (de) | 2009-10-08 |
| JP5502851B2 (ja) | 2014-05-28 |
| PL2262730T3 (pl) | 2014-09-30 |
| EP2262730A1 (de) | 2010-12-22 |
| WO2009124829A1 (de) | 2009-10-15 |
| ES2476894T3 (es) | 2014-07-15 |
| CN105836751A (zh) | 2016-08-10 |
| MX2010010931A (es) | 2010-11-12 |
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