KR101250703B1 - 차단된 이소시아네이트 및 코팅 조성물에서의 이들의 용도 - Google Patents
차단된 이소시아네이트 및 코팅 조성물에서의 이들의 용도 Download PDFInfo
- Publication number
- KR101250703B1 KR101250703B1 KR1020077007528A KR20077007528A KR101250703B1 KR 101250703 B1 KR101250703 B1 KR 101250703B1 KR 1020077007528 A KR1020077007528 A KR 1020077007528A KR 20077007528 A KR20077007528 A KR 20077007528A KR 101250703 B1 KR101250703 B1 KR 101250703B1
- Authority
- KR
- South Korea
- Prior art keywords
- bis
- cyclohexane
- isocyanatomethyl
- composition
- isocyanurate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/757—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing at least two isocyanate or isothiocyanate groups linked to the cycloaliphatic ring by means of an aliphatic group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/8074—Lactams
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US60710704P | 2004-09-03 | 2004-09-03 | |
| US60/607,107 | 2004-09-03 | ||
| PCT/US2005/031685 WO2006029141A1 (en) | 2004-09-03 | 2005-09-02 | Blocked isocyanates and their use in coating compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20070049684A KR20070049684A (ko) | 2007-05-11 |
| KR101250703B1 true KR101250703B1 (ko) | 2013-04-03 |
Family
ID=35355819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020077007528A Expired - Lifetime KR101250703B1 (ko) | 2004-09-03 | 2005-09-02 | 차단된 이소시아네이트 및 코팅 조성물에서의 이들의 용도 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20080033086A1 (https=) |
| EP (1) | EP1789466B1 (https=) |
| JP (2) | JP5191733B2 (https=) |
| KR (1) | KR101250703B1 (https=) |
| CN (1) | CN101072806B (https=) |
| AT (1) | ATE532808T1 (https=) |
| AU (1) | AU2005282549A1 (https=) |
| BR (1) | BRPI0515235B1 (https=) |
| CA (1) | CA2577785C (https=) |
| MX (1) | MX2007002611A (https=) |
| WO (1) | WO2006029141A1 (https=) |
| ZA (1) | ZA200701641B (https=) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2375508T3 (es) * | 2007-05-21 | 2012-03-01 | Dow Global Technologies Llc | Objetos recubiertos. |
| EP2036937A1 (en) * | 2007-09-13 | 2009-03-18 | Stichting Dutch Polymer Institute | Polycarbonate and process for producing the same |
| CN101469259B (zh) * | 2007-12-27 | 2012-09-19 | 上海轻工业研究所有限公司 | 聚氨酯反应性热熔结构胶 |
| FR2927631B1 (fr) * | 2008-02-15 | 2010-03-05 | Arkema France | Utilisation d'un promoteur d'adherence dans une solution de nettoyage de la surface d'un substrat a base de tpe et/ou de pa, pour augmenter l'adherence dudit substrat avec les joints de colle aqueux. |
| JP5566360B2 (ja) | 2010-11-22 | 2014-08-06 | ローム アンド ハース カンパニー | ビス(イソシアナトメチル)シクロヘキサンからのイソシアヌラート組成物および第三級アミン触媒を含むポリウレタンコーティング組成物 |
| CN102477251B (zh) * | 2010-11-22 | 2015-05-13 | 罗门哈斯公司 | 包含源自二(异氰酸根合甲基)环己烷和源自脂族二异氰酸酯的异氰尿酸酯组合物的双组分聚氨酯涂料组合物 |
| JP6247492B2 (ja) | 2012-11-06 | 2017-12-13 | ダウ グローバル テクノロジーズ エルエルシー | 水性皮革コーティング組成物および皮革をコーティングするための方法 |
| WO2015119696A1 (en) * | 2013-11-18 | 2015-08-13 | E. I. Du Pont De Nemours And Company | Composites and ballistic resistant armor articles containing the composites |
| JP6622399B2 (ja) | 2016-05-20 | 2019-12-18 | 三井化学株式会社 | 硬化性組成物、塗料、太陽電池用塗料、太陽電池バックシート用塗料、接着剤、太陽電池用接着剤、太陽電池バックシート用接着剤、シートの製造方法、および、硬化剤 |
| JP2019536849A (ja) * | 2016-10-18 | 2019-12-19 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag | ブロックトポリイソシアネートの触媒架橋によるプラスチックの製造 |
| US10918764B2 (en) * | 2018-08-21 | 2021-02-16 | The Secant Group, Llc | Tunable, controlled-release, urethane-containing elastomers and processes of forming the same |
| EP3800213A1 (en) | 2019-10-01 | 2021-04-07 | Cromogenia Units, S.A. | Blocked isocyanate polyurethane compositions using a new blocking agent, method of manufacture and uses thereof |
| CN110804146B (zh) * | 2019-12-06 | 2021-09-07 | 万华化学集团股份有限公司 | 一种存储稳定的封闭型异氰酸酯组合物及其制备方法和应用 |
| CN111647382B (zh) * | 2020-06-30 | 2022-03-25 | 浙江华峰热塑性聚氨酯有限公司 | 一种tpu粘合剂的制备方法及其用途 |
| CN112266464B (zh) * | 2020-11-06 | 2022-05-03 | 广东也乐新材料制造有限公司 | 一种高耐性封闭型水性聚异氰酸酯的制备方法及其应用 |
| CN112557582B (zh) * | 2020-12-17 | 2022-11-01 | 南通恒华粘合材料科技有限公司 | 一种聚酯多元醇羟值测定的方法 |
| CN115925581B (zh) * | 2021-08-09 | 2024-12-03 | 万华化学集团股份有限公司 | 一种制备异氰酸酯的方法 |
| EP4163314B1 (de) * | 2021-10-05 | 2023-12-06 | Evonik Operations GmbH | Verfahren zur herstellung fester polyurethanhärter |
| CN114276520B (zh) * | 2021-12-08 | 2023-09-19 | 万华化学集团股份有限公司 | 一种封闭多异氰酸酯组合物及其制备方法与应用 |
| CN114736350B (zh) * | 2022-05-25 | 2023-12-19 | 安徽科瑞达新材料有限公司 | 一种脂肪族二异氰酸酯的二聚体加成产物的制备方法 |
| IT202300016509A1 (it) * | 2023-08-03 | 2025-02-03 | Maflon S P A | Composizione di poliisocianati bloccati, uso di detta composizione, e metodo di preparazione |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR940008986B1 (ko) * | 1990-05-24 | 1994-09-28 | 미쓰이도오아쓰가가꾸가부시끼가이샤 | 폴리이소시아네이트-이소시아누레이트 및 그의 제조방법, 이들의 용도 |
| KR100201799B1 (ko) | 1996-04-12 | 1999-06-15 | 야마모토 카즈모토 | 블록트 폴리이소시아네이트 조성물 및 그를 포함하는 일액형 열 경화성 수지 조성물 |
| KR100252607B1 (ko) | 1992-04-23 | 2000-04-15 | 빌프리더 하이더 | 이소시아네이트프레폴리머,그의제조방법및일액형코팅조성물에서의그의용도 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2105777C3 (de) * | 1971-02-08 | 1976-02-05 | Veba Chemie Ag | Pulverförmige Überzugsmasse |
| DE2215080C3 (de) * | 1972-03-28 | 1978-10-12 | Bayer Ag, 5090 Leverkusen | Pulverförmige Überzugsmittel |
| DE2707656C2 (de) * | 1977-02-23 | 1986-04-17 | Bayer Ag, 5090 Leverkusen | Pulverförmige Überzugsmittel |
| DE2916201A1 (de) * | 1979-04-21 | 1980-10-30 | Huels Chemische Werke Ag | Verfahren zur trimerisierung von diisocyanaten |
| JPS5698136A (en) * | 1980-01-08 | 1981-08-07 | Kanegafuchi Chem Ind Co Ltd | Continuous manufacture of laminated substance |
| JPS579773A (en) * | 1980-06-23 | 1982-01-19 | Takeda Chem Ind Ltd | Production of polyisocyanate |
| DE3046409A1 (de) * | 1980-12-10 | 1982-07-15 | Bayer Ag, 5090 Leverkusen | Beschichtungsmittel und ein verfahren zur herstellung von ueberzuegen |
| US4395529A (en) * | 1981-07-20 | 1983-07-26 | Cargill, Incorporated | Coating powders for protective films based on epsilon-caprolactam blocked isocyanates |
| US4491663A (en) * | 1982-04-14 | 1985-01-01 | Ford Motor Company | Trifunctional blocked isocyanate containing an isocyanurate ring |
| US5246557A (en) * | 1984-02-29 | 1993-09-21 | The Baxenden Chemical Co. | Blocked isocyanates |
| CA1334848C (en) * | 1988-08-05 | 1995-03-21 | William E. Slack | Process for the production of polyisocyanates which contain isocyanurate groups |
| US4973646A (en) * | 1990-04-09 | 1990-11-27 | Eastman Kodak Company | Powder coating compositions |
| JP3056280B2 (ja) * | 1990-05-24 | 2000-06-26 | 三井化学株式会社 | ポリイソシアナト−イソシアヌレート及びその製造方法、ならびにこれらの用途 |
| US5232988A (en) * | 1992-02-25 | 1993-08-03 | Miles Inc. | Blocked polyisocyanates prepared from partially trimerized cyclic organic diisocyanates having (cyclo)aliphatically bound isocyanate groups and their use for the production of coatings |
| US5817732A (en) * | 1993-02-12 | 1998-10-06 | Asahi Kasei Kogyo Kabushiki Kaisha | Blocked polyisocyanate and coating composition |
| CA2116167C (en) * | 1993-03-15 | 2007-05-15 | Myron W. Shaffer | One-component coating compositions containing oxime- or lactam-blocked polyisocyanates which have improved resistance to yellowing |
| US5510443A (en) * | 1993-03-15 | 1996-04-23 | Bayer Corporation | Process for preparing a coating with improved resistance to yellowing and the resulting coating |
| US5939547A (en) * | 1997-12-22 | 1999-08-17 | Bayer Corporation | Formation of blocked isocyanurate group-containing polyisocyanates from partially blocked isocyanates |
| JPH11240936A (ja) * | 1998-02-26 | 1999-09-07 | Mitsubishi Gas Chem Co Inc | ポリイソシアネートオリゴマーおよび該ポリイソシアネートオリゴマーを用いたポリウレタン塗料 |
| US6355761B1 (en) * | 1999-05-12 | 2002-03-12 | Basf Coatings Ag | Coating composition |
| DE19860049A1 (de) * | 1998-12-23 | 2000-06-29 | Basf Ag | Härtbare Zubereitungen |
| JP2000290493A (ja) * | 1999-04-09 | 2000-10-17 | Asahi Chem Ind Co Ltd | ブロックポリイソシアネート組成物 |
| US6252121B1 (en) * | 1999-07-27 | 2001-06-26 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-ligand complex catalyzed processes |
| US6660385B2 (en) * | 2000-10-11 | 2003-12-09 | Kansai Paint Co., Ltd. | Cationic paint composition |
| DE10123419A1 (de) * | 2001-05-14 | 2002-11-21 | Bayer Ag | Verfahren zur Herstellung von aliphatischen Polyisocyanaten mit Uretdion-Isocyanurat- sowie Iminooxadiazindionstruktur |
| CA2504147C (en) * | 2002-10-31 | 2012-08-14 | Dow Global Technologies Inc. | Polyurethane dispersion and articles prepared therefrom |
| US20040087754A1 (en) * | 2002-10-31 | 2004-05-06 | Paul Foley | Polyurethane compounds and articles prepared therefrom |
| BRPI0408042B1 (pt) * | 2003-02-28 | 2014-12-02 | Dow Global Technology Inc | "composição de poliisocianato isocianurato e processo para a preparação de uma mistura de poliisocianato isocianurato". |
-
2005
- 2005-09-02 CA CA2577785A patent/CA2577785C/en not_active Expired - Lifetime
- 2005-09-02 US US11/660,774 patent/US20080033086A1/en not_active Abandoned
- 2005-09-02 AT AT05795032T patent/ATE532808T1/de active
- 2005-09-02 BR BRPI0515235A patent/BRPI0515235B1/pt active IP Right Grant
- 2005-09-02 MX MX2007002611A patent/MX2007002611A/es unknown
- 2005-09-02 EP EP05795032A patent/EP1789466B1/en not_active Expired - Lifetime
- 2005-09-02 KR KR1020077007528A patent/KR101250703B1/ko not_active Expired - Lifetime
- 2005-09-02 AU AU2005282549A patent/AU2005282549A1/en not_active Abandoned
- 2005-09-02 WO PCT/US2005/031685 patent/WO2006029141A1/en not_active Ceased
- 2005-09-02 JP JP2007530472A patent/JP5191733B2/ja not_active Expired - Lifetime
- 2005-09-02 CN CN2005800372164A patent/CN101072806B/zh not_active Expired - Lifetime
-
2007
- 2007-02-23 ZA ZA200701641A patent/ZA200701641B/xx unknown
-
2012
- 2012-10-01 JP JP2012219599A patent/JP5778647B2/ja not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR940008986B1 (ko) * | 1990-05-24 | 1994-09-28 | 미쓰이도오아쓰가가꾸가부시끼가이샤 | 폴리이소시아네이트-이소시아누레이트 및 그의 제조방법, 이들의 용도 |
| KR100252607B1 (ko) | 1992-04-23 | 2000-04-15 | 빌프리더 하이더 | 이소시아네이트프레폴리머,그의제조방법및일액형코팅조성물에서의그의용도 |
| KR100201799B1 (ko) | 1996-04-12 | 1999-06-15 | 야마모토 카즈모토 | 블록트 폴리이소시아네이트 조성물 및 그를 포함하는 일액형 열 경화성 수지 조성물 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5778647B2 (ja) | 2015-09-16 |
| US20080033086A1 (en) | 2008-02-07 |
| EP1789466B1 (en) | 2011-11-09 |
| ATE532808T1 (de) | 2011-11-15 |
| CA2577785C (en) | 2014-10-28 |
| KR20070049684A (ko) | 2007-05-11 |
| WO2006029141A1 (en) | 2006-03-16 |
| ZA200701641B (en) | 2008-08-27 |
| CA2577785A1 (en) | 2006-03-16 |
| JP2008512520A (ja) | 2008-04-24 |
| CN101072806A (zh) | 2007-11-14 |
| AU2005282549A1 (en) | 2006-03-16 |
| BRPI0515235A (pt) | 2008-07-15 |
| BRPI0515235B1 (pt) | 2016-09-27 |
| CN101072806B (zh) | 2012-09-05 |
| JP2013067800A (ja) | 2013-04-18 |
| JP5191733B2 (ja) | 2013-05-08 |
| MX2007002611A (es) | 2007-04-27 |
| EP1789466A1 (en) | 2007-05-30 |
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