KR101190758B1 - 올레핀 중합을 위한 촉매 조성물 - Google Patents
올레핀 중합을 위한 촉매 조성물 Download PDFInfo
- Publication number
- KR101190758B1 KR101190758B1 KR1020077029523A KR20077029523A KR101190758B1 KR 101190758 B1 KR101190758 B1 KR 101190758B1 KR 1020077029523 A KR1020077029523 A KR 1020077029523A KR 20077029523 A KR20077029523 A KR 20077029523A KR 101190758 B1 KR101190758 B1 KR 101190758B1
- Authority
- KR
- South Korea
- Prior art keywords
- carbon atoms
- group
- groups
- alkyl
- phenyl
- Prior art date
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- 0 CC*(C)C1=C(*)C2C(C)=C(C)C(*)=C(C(C*)C(C)*)C2C(*)=C1* Chemical compound CC*(C)C1=C(*)C2C(C)=C(C)C(*)=C(C(C*)C(C)*)C2C(*)=C1* 0.000 description 2
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/20—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of antimony, bismuth, vanadium, niobium or tantalum
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/130,925 | 2005-05-17 | ||
US11/130,925 US7232869B2 (en) | 2005-05-17 | 2005-05-17 | Catalyst composition for olefin polymerization |
PCT/US2006/016114 WO2006124231A1 (en) | 2005-05-17 | 2006-04-27 | Catalyst composition for olefin polymerization |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20080033906A KR20080033906A (ko) | 2008-04-17 |
KR101190758B1 true KR101190758B1 (ko) | 2012-10-12 |
Family
ID=36829739
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020077029523A KR101190758B1 (ko) | 2005-05-17 | 2006-04-27 | 올레핀 중합을 위한 촉매 조성물 |
Country Status (11)
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005052654A1 (de) * | 2005-11-04 | 2007-05-16 | Ticona Gmbh | Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren |
CA2670826C (en) | 2006-12-14 | 2015-06-23 | Albemarle Corporation | Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins |
KR101278336B1 (ko) * | 2007-10-25 | 2013-06-25 | 루머스 노보렌 테크놀로지 게엠베하 | 안사-메탈로센 화합물의 라세모선택적 합성, 안사-메탈로센 화합물, 이를 포함하는 촉매, 그 촉매를 이용한 올레핀 폴리머 제조 공정, 그리고 올레핀 호모- 및 코폴리머 |
JP5598856B2 (ja) * | 2007-10-25 | 2014-10-01 | ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー |
EP2172493A1 (en) | 2008-10-02 | 2010-04-07 | Total Petrochemicals Research Feluy | Activating supports based on perfluorinated boronic acids |
SG172454A1 (en) * | 2008-12-31 | 2011-08-29 | Lummus Novolen Technology Gmbh | New metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers |
EP2633104A1 (en) | 2010-10-28 | 2013-09-04 | Lummus Novolen Technology Gmbh | Nonwoven and yarn polypropylene with additivation |
US8895465B2 (en) * | 2010-11-22 | 2014-11-25 | Albemarle Corporation | Activator compositions, their preparation, and their use in catalysis |
EP2573091A1 (en) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Process for recycling of free ligand from their corresponding metallocene complexes |
CN104334590B (zh) * | 2012-02-08 | 2016-08-31 | 信实工业公司 | 用于制备uhmwpe的单中心催化剂在无机氧化物载体上的固定化 |
KR101549206B1 (ko) | 2012-05-08 | 2015-09-02 | 주식회사 엘지화학 | 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법 |
KR101584350B1 (ko) * | 2013-04-08 | 2016-01-13 | 한화케미칼 주식회사 | 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법 |
FR3039431B1 (fr) * | 2015-07-29 | 2019-05-31 | IFP Energies Nouvelles | Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines |
FR3042989A1 (fr) * | 2015-10-30 | 2017-05-05 | Ifp Energies Now | Nouvelle composition catalytique a base de nickel en presence d'un activateur specifique et son utilisation dans un procede d'oligomerisation des olefines |
FR3045414B1 (fr) * | 2015-12-18 | 2019-12-27 | IFP Energies Nouvelles | Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines |
CN108786919B (zh) * | 2017-05-05 | 2020-07-21 | 中国石油化工股份有限公司 | 负载型茂金属催化剂及其制备方法和应用和丙烯酸甲酯的制备方法 |
CN108786918B (zh) * | 2017-05-05 | 2020-07-24 | 中国石油化工股份有限公司 | 负载型茂金属催化剂及其制备方法和应用和丙烯酸甲酯的制备方法 |
US11161922B2 (en) | 2017-10-31 | 2021-11-02 | Exxonmobil Chemical Patents Inc. | Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents |
WO2019089145A1 (en) | 2017-10-31 | 2019-05-09 | Exxonmobil Chemical Patents Inc. | Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents |
KR102301666B1 (ko) * | 2017-12-22 | 2021-09-14 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매의 제조 방법, 상기 제조 방법으로 제조된 혼성 담지 메탈로센 촉매, 및 이를 이용하는 폴리올레핀의 제조 방법 |
KR102431269B1 (ko) | 2018-11-02 | 2022-08-10 | 주식회사 엘지화학 | 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법 |
US11352375B2 (en) | 2018-12-28 | 2022-06-07 | Braskem S.A. | Auxiliaries for olefin polymerization process |
US11866522B2 (en) | 2018-12-28 | 2024-01-09 | Braskem S.A. | Process for introducing catalyst in a polymerization process |
CN115368490B (zh) * | 2021-05-20 | 2023-11-28 | 中国科学技术大学 | 硼烷助催化剂、合成方法及其应用 |
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-
2005
- 2005-05-17 US US11/130,925 patent/US7232869B2/en not_active Expired - Fee Related
-
2006
- 2006-04-27 BR BRPI0610163-1A patent/BRPI0610163A2/pt not_active IP Right Cessation
- 2006-04-27 DE DE602006013300T patent/DE602006013300D1/de active Active
- 2006-04-27 KR KR1020077029523A patent/KR101190758B1/ko not_active IP Right Cessation
- 2006-04-27 AT AT06758705T patent/ATE462731T1/de active
- 2006-04-27 WO PCT/US2006/016114 patent/WO2006124231A1/en active Application Filing
- 2006-04-27 JP JP2008512305A patent/JP2008545821A/ja not_active Ceased
- 2006-04-27 ES ES06758705T patent/ES2342106T3/es active Active
- 2006-04-27 CN CN2006800169691A patent/CN101384624B/zh not_active Expired - Fee Related
- 2006-04-27 EP EP06758705A patent/EP1882000B1/en not_active Not-in-force
- 2006-05-04 TW TW095115912A patent/TW200710110A/zh unknown
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2007
- 2007-05-16 US US11/803,801 patent/US7468416B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR20080033906A (ko) | 2008-04-17 |
EP1882000A1 (en) | 2008-01-30 |
JP2008545821A (ja) | 2008-12-18 |
WO2006124231A1 (en) | 2006-11-23 |
US7232869B2 (en) | 2007-06-19 |
DE602006013300D1 (de) | 2010-05-12 |
BRPI0610163A2 (pt) | 2010-06-01 |
US20060264587A1 (en) | 2006-11-23 |
US20070249799A1 (en) | 2007-10-25 |
CN101384624B (zh) | 2012-07-04 |
CN101384624A (zh) | 2009-03-11 |
TW200710110A (en) | 2007-03-16 |
US7468416B2 (en) | 2008-12-23 |
ATE462731T1 (de) | 2010-04-15 |
EP1882000B1 (en) | 2010-03-31 |
ES2342106T3 (es) | 2010-07-01 |
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