KR101120901B1 - 유체 촉매적 분해 공정용 가솔린 황 감소 촉매 - Google Patents

유체 촉매적 분해 공정용 가솔린 황 감소 촉매 Download PDF

Info

Publication number
KR101120901B1
KR101120901B1 KR1020067018891A KR20067018891A KR101120901B1 KR 101120901 B1 KR101120901 B1 KR 101120901B1 KR 1020067018891 A KR1020067018891 A KR 1020067018891A KR 20067018891 A KR20067018891 A KR 20067018891A KR 101120901 B1 KR101120901 B1 KR 101120901B1
Authority
KR
South Korea
Prior art keywords
zeolite
lewis acid
composition
catalyst
containing component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020067018891A
Other languages
English (en)
Korean (ko)
Other versions
KR20070004721A (ko
Inventor
루이종 후
신진 자오
리차드 웜스베처
마이클 지바스
Original Assignee
더블유.알. 그레이스 앤드 캄파니-콘.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 더블유.알. 그레이스 앤드 캄파니-콘. filed Critical 더블유.알. 그레이스 앤드 캄파니-콘.
Publication of KR20070004721A publication Critical patent/KR20070004721A/ko
Application granted granted Critical
Publication of KR101120901B1 publication Critical patent/KR101120901B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/088—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B01J29/146—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J29/166—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
KR1020067018891A 2004-03-16 2005-03-16 유체 촉매적 분해 공정용 가솔린 황 감소 촉매 Expired - Fee Related KR101120901B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/801,424 US8084383B2 (en) 2004-03-16 2004-03-16 Gasoline sulfur reduction catalyst for fluid catalytic cracking process
US10/801,424 2004-03-16
PCT/US2005/008890 WO2005090523A1 (en) 2004-03-16 2005-03-16 Gasoline sulfur reduction catalyst for fluid catalytic cracking process

Publications (2)

Publication Number Publication Date
KR20070004721A KR20070004721A (ko) 2007-01-09
KR101120901B1 true KR101120901B1 (ko) 2012-02-27

Family

ID=34963529

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020067018891A Expired - Fee Related KR101120901B1 (ko) 2004-03-16 2005-03-16 유체 촉매적 분해 공정용 가솔린 황 감소 촉매

Country Status (16)

Country Link
US (1) US8084383B2 (enExample)
EP (1) EP1733006B1 (enExample)
JP (1) JP2007529311A (enExample)
KR (1) KR101120901B1 (enExample)
CN (1) CN1930270B (enExample)
AR (1) AR050485A1 (enExample)
AU (1) AU2005224255B2 (enExample)
BR (1) BRPI0508332B1 (enExample)
CA (1) CA2559763C (enExample)
IL (1) IL177295A (enExample)
IN (1) IN2012DN00751A (enExample)
NO (1) NO20064651L (enExample)
RU (1) RU2396304C2 (enExample)
TW (1) TWI390029B (enExample)
WO (1) WO2005090523A1 (enExample)
ZA (1) ZA200607572B (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI428180B (zh) 2005-02-25 2014-03-01 Grace W R & Co 適用於流體化觸媒裂解程序之汽油硫減量觸媒
CN101855013B (zh) * 2006-03-15 2013-05-01 巴斯福催化剂公司 用于在催化裂化过程中降低汽油硫含量的催化剂组合物
US8409428B2 (en) * 2006-06-28 2013-04-02 Saudi Arabian Oil Company Catalyst additive for reduction of sulfur in catalytically cracked gasoline
AU2008219190B2 (en) * 2007-02-21 2013-05-09 W. R. Grace & Co.-Conn. Gasoline sulfur reduction catalyst for fluid catalytic cracking process
JP4906535B2 (ja) * 2007-02-23 2012-03-28 一般財団法人石油エネルギー技術センター 流動接触分解触媒及びその製造方法並びに低硫黄接触分解ガソリンの製造方法
WO2010014256A1 (en) * 2008-07-30 2010-02-04 Saudi Arabian Oil Company Metallic clay based fcc gasoline sulfur reduction additive compositions
CA2770524A1 (en) 2008-08-21 2010-02-25 Sbi Fine Chemicals Inc. Solid, heterogeneous catalysts and methods of use
TW201029929A (en) * 2008-12-18 2010-08-16 Grace W R & Co Novel ultra stable zeolite Y and method for manufacturing the same
US8905478B2 (en) * 2010-03-17 2014-12-09 Britax Child Safety, Inc. Child safety seat with structural support
TWI611014B (zh) * 2012-07-23 2018-01-11 Ｗ Ｒ 康格雷氏公司 經鎂穩定之極低蘇打催化裂解觸媒及其形成方法
CN104981290A (zh) * 2012-12-21 2015-10-14 阿尔比马尔欧洲有限公司 增加丙烯产量的改良y型沸石/zsm-5催化剂
CN104399512B (zh) * 2014-12-10 2017-01-11 郭帅 一种废轮胎油再生高效环保催化剂
RU2599720C1 (ru) * 2015-07-08 2016-10-10 Акционерное общество "Газпромнефть - Омский НПЗ" Катализатор для осуществления реакций межмолекулярного переноса водорода и способ его приготовления
RU2711568C1 (ru) * 2019-07-31 2020-01-17 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) Способ переработки тяжелого углеводородного сырья с использованием серопонижающих добавок к катализаторам крекинга
JP7576429B2 (ja) * 2019-11-15 2024-10-31 日揮触媒化成株式会社 流動接触分解触媒の製造方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040004585A (ko) * 2001-04-13 2004-01-13 더블유.알. 그레이스 앤드 캄파니-콘. 유체 촉매에 의한 분해 방법용 가솔린 황 감소 촉매

Family Cites Families (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3293192A (en) * 1965-08-23 1966-12-20 Grace W R & Co Zeolite z-14us and method of preparation thereof
US3402996A (en) * 1966-12-19 1968-09-24 Grace W R & Co Ion exchange of crystalline zeolites
CA967136A (en) 1969-07-28 1975-05-06 Apparao T. Lengade Hydrocarbon conversion catalyst
US3607043A (en) * 1969-11-19 1971-09-21 Grace W R & Co Cation and thermal stabilization of a faujasite-type zeolite
GB1285435A (en) * 1970-01-19 1972-08-16 Carr Fastener Co Ltd Electrical switch
US3676368A (en) 1970-08-26 1972-07-11 Grace W R & Co Rare earth-hydrogen exchanged zeolites
US3957689A (en) * 1974-08-02 1976-05-18 W. R. Grace & Co. Process for preparing an attrition resistant zeolite hydrocarbon conversion catalyst
US4218344A (en) * 1975-12-19 1980-08-19 Standard Oil Company (Indiana) Catalytic cracking with reduced emission of noxious gases
US4126579A (en) * 1977-03-22 1978-11-21 W. R. Grace & Co. Hydrocarbon conversion catalyst manufacture
US4188285A (en) * 1978-12-20 1980-02-12 Chevron Research Company Selective process for removal of thiophenes from gasoline using a silver-exchanged faujasite-type zeolite
US4226743A (en) * 1979-03-12 1980-10-07 W. R. Grace & Co. Silica-alumina hydrogel catalyst
US4267072A (en) * 1979-03-15 1981-05-12 Standard Oil Company (Indiana) Catalytic cracking catalyst with reduced emission of noxious gases
US4359378A (en) * 1979-04-16 1982-11-16 Chevron Research Company Catalytic cracking process for improved octane
US4280898A (en) * 1979-11-05 1981-07-28 Standard Oil Company (Indiana) Fluid catalytic cracking of heavy petroleum fractions
US4957892A (en) * 1980-07-29 1990-09-18 Uop Process for combusting solid sulfur containing material
JPS57207546A (en) * 1981-06-13 1982-12-20 Shokubai Kasei Kogyo Kk Hydrocracking catalyst composition and its production
JPS5927768Y2 (ja) * 1981-07-25 1984-08-11 典和 藤橋 濡損を防止した折畳み洋傘
US4458023A (en) 1981-08-10 1984-07-03 W. R. Grace & Co. Catalyst manufacture
US4877514A (en) * 1981-12-07 1989-10-31 Ashland Oil, Inc. Carbo-metallic oil conversion process and catalysts
US4542116A (en) * 1982-03-29 1985-09-17 The Standard Oil Company Catalyst for removing sulfur oxides from a gas
JPS59150539A (ja) * 1983-02-16 1984-08-28 Res Assoc Residual Oil Process<Rarop> 炭化水素転化触媒
US4606813A (en) * 1983-02-25 1986-08-19 Engelhard Corporation Fluid catalytic cracking catalyst for cracking sulfur containing petroleum feedstocks and a process for using it
US4493902A (en) * 1983-02-25 1985-01-15 Engelhard Corporation Fluid catalytic cracking catalyst comprising microspheres containing more than about 40 percent by weight Y-faujasite and methods for making
US4781815A (en) * 1983-05-02 1988-11-01 Union Carbide Corporation Catalytic cracking process
FR2563445B1 (fr) * 1984-04-26 1986-08-14 Pro Catalyse Ste Fse Prod Cata Nouveau catalyseur d'hydrocraquage destine a la production de distillats moyens
US4855036A (en) * 1984-10-03 1989-08-08 Uop Catalytic cracking process
US4588701A (en) * 1984-10-03 1986-05-13 Union Carbide Corp. Catalytic cracking catalysts
EP0188841B2 (en) 1984-12-21 1992-01-15 Catalysts & Chemicals Industries Co., Ltd. Hydrocarbon catalytic cracking catalyst compositions and method therefor
US4764269A (en) * 1985-07-15 1988-08-16 W. R. Grace & Co. Cracking catalyst
US4627911A (en) * 1985-08-21 1986-12-09 Mobil Oil Corporation Dispersed catalyst cracking with methanol as a coreactant
US4889617A (en) * 1986-03-24 1989-12-26 Chevron Research Company Method of suppressing sodium poisoning of cracking catalysts during fluid catalytic cracking
US4790982A (en) * 1986-04-07 1988-12-13 Katalistiks International, Inc. Metal-containing spinel composition and process of using same
US4957718A (en) * 1987-11-24 1990-09-18 Uop Process for reducing emissions of sulfur oxides and composition useful in same
DE3825169A1 (de) * 1988-07-23 1990-02-01 Huels Chemische Werke Ag Verfahren zur feinentschwefelung von kohlenwasserstoffen
US4965233A (en) * 1988-10-20 1990-10-23 Engelhard Corporation Novel zeolite fluid cracking catalysts and preparation thereof from mixtures of calcined clay
JPH03157339A (ja) * 1989-11-16 1991-07-05 Kureha Chem Ind Co Ltd ジアリールメタンの製造方法
US5002654A (en) * 1989-12-28 1991-03-26 Mobil Oil Corporation Reducing NOx emissions with zinc catalyst
GB2245001A (en) * 1990-06-11 1991-12-18 Unilever Plc Catalyst compositions containing metal ion-exchanged zeolites
US5070052A (en) * 1990-09-21 1991-12-03 Shell Oil Company Basic zinc-containing zeolite compositions
SG50465A1 (en) 1992-02-05 1998-07-20 Grace W R & Co Metal passivation/sox control compositions for fcc
US5243121A (en) 1992-03-19 1993-09-07 Engelhard Corporation Fluid catalytic cracking process for increased formation of isobutylene and isoamylenes
BR9203110A (pt) 1992-08-12 1994-03-01 Petroleo Brasileiro Sa Composicao catalitica passivadora para o craqueamento de hidrocarbonetos,alumina e processo de craqueamento catalitico fluido
US5376608A (en) * 1993-01-27 1994-12-27 W. R. Grace & Co.-Conn. Sulfur reduction in FCC gasoline
US5601798A (en) * 1993-09-07 1997-02-11 Pq Corporation Process for preparing zeolite Y with increased mesopore volume
CN1034586C (zh) * 1993-11-05 1997-04-16 中国石油化工总公司 多产低碳烯烃的催化转化方法
JP2992971B2 (ja) * 1994-09-01 1999-12-20 株式会社ジャパンエナジー 水素化処理用触媒
US6036847A (en) * 1996-03-26 2000-03-14 W. R. Grace & Co.-Conn. Compositions for use in catalytic cracking to make reduced sulfur content gasoline
US5788834A (en) * 1996-07-19 1998-08-04 Exxon Research And Engineering Company Catalytic cracking process with Y zeolite catalyst comprising silica binder containing silica gel
FR2753717B1 (fr) * 1996-09-24 1998-10-30 Procede et installation pour la production d'essences de craquage catalytique a faible teneur en soufre
US5990030A (en) * 1997-06-13 1999-11-23 Tricat Industries, Inc. Sox reducing additive for FCC systems
US6852214B1 (en) * 1998-08-31 2005-02-08 Mobil Oil Corporation Gasoline sulfur reduction in fluid catalytic cracking
US20020153283A1 (en) * 1998-12-28 2002-10-24 Arthur W Chester Gasoline sulfur reduction in fluid catalytic cracking
US6974787B2 (en) * 1998-08-31 2005-12-13 Exxonmobil Corporation Gasoline sulfur reduction in fluid catalytic cracking
US6846403B2 (en) * 1998-12-28 2005-01-25 Mobil Oil Corporation Gasoline sulfur reduction in fluid catalytic cracking
DE19962669B4 (de) * 1998-12-28 2004-07-01 Mobil Oil Corp. Verringerung des Schwefelgehaltes in Benzin beim katalytischen Wirbelschichtcracken
US7803267B2 (en) * 1998-12-28 2010-09-28 W. R. Grace & Co.-Conn. Gasoline sulfur reduction in fluid catalytic cracking
RU2166529C1 (ru) * 1999-09-01 2001-05-10 Левинбук Михаил Исаакович Способ получения моторных топлив
US6635169B1 (en) * 1999-09-20 2003-10-21 Mobil Oil Corporation Method for reducing gasoline sulfur in fluid catalytic cracking
CN100335596C (zh) * 1999-09-20 2007-09-05 格雷斯公司 流化床催化裂化中汽油硫的减少
DE10036055A1 (de) 2000-07-25 2002-02-07 Bayer Ag Verfahren zur Herstellung von di- oder trifunktionellen Initiatorsystemen auf Lithiumbasis sowie deren Verwendung
DE10045742A1 (de) * 2000-09-15 2002-04-18 Bosch Gmbh Robert Umlenkeinrichtung für ein Fördermittel an einer Transportstrecke
US6638892B1 (en) * 2002-04-18 2003-10-28 Conocophillips Company Syngas conversion and catalyst system employed therefor
KR100903898B1 (ko) 2002-08-29 2009-06-19 알베마를 네덜란드 비.브이. 저급 올레핀 제조용 촉매

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20040004585A (ko) * 2001-04-13 2004-01-13 더블유.알. 그레이스 앤드 캄파니-콘. 유체 촉매에 의한 분해 방법용 가솔린 황 감소 촉매

Also Published As

Publication number Publication date
CN1930270A (zh) 2007-03-14
US8084383B2 (en) 2011-12-27
AU2005224255A1 (en) 2005-09-29
BRPI0508332B1 (pt) 2014-12-09
EP1733006A1 (en) 2006-12-20
AU2005224255B2 (en) 2011-05-12
EP1733006B1 (en) 2020-05-13
RU2396304C2 (ru) 2010-08-10
CN1930270B (zh) 2011-06-08
BRPI0508332A (pt) 2007-07-24
TW200602480A (en) 2006-01-16
NO20064651L (no) 2006-12-15
IN2012DN00751A (enExample) 2015-06-19
ZA200607572B (en) 2008-08-27
KR20070004721A (ko) 2007-01-09
JP2007529311A (ja) 2007-10-25
IL177295A (en) 2011-09-27
RU2006136369A (ru) 2008-04-27
IL177295A0 (en) 2006-12-10
CA2559763C (en) 2013-08-27
US20050205464A1 (en) 2005-09-22
WO2005090523A1 (en) 2005-09-29
TWI390029B (zh) 2013-03-21
CA2559763A1 (en) 2005-09-29
AR050485A1 (es) 2006-11-01

Similar Documents

Publication Publication Date Title
JP3545652B2 (ja) 流動接触分解におけるガソリン中の硫黄の低減
US6846403B2 (en) Gasoline sulfur reduction in fluid catalytic cracking
US8221615B2 (en) Gasoline sulfur reduction catalyst for fluid catalytic cracking process
JP3550065B2 (ja) 流動床式接触分解におけるガソリンの硫黄低減
KR100863822B1 (ko) 유체 촉매에 의한 분해 방법용 가솔린 황 감소 촉매
KR101120901B1 (ko) 유체 촉매적 분해 공정용 가솔린 황 감소 촉매
JP5335697B2 (ja) 流動接触分解プロセスのためのガソリンイオウ分減少触媒
MXPA06009287A (en) Gasoline sulfur reduction catalyst for fluid catalytic cracking process

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20150109

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20160113

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20170131

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20170131