KR101022790B1 - 수성 도료용 접착 소재의 제조방법 - Google Patents
수성 도료용 접착 소재의 제조방법 Download PDFInfo
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- KR101022790B1 KR101022790B1 KR1020100062898A KR20100062898A KR101022790B1 KR 101022790 B1 KR101022790 B1 KR 101022790B1 KR 1020100062898 A KR1020100062898 A KR 1020100062898A KR 20100062898 A KR20100062898 A KR 20100062898A KR 101022790 B1 KR101022790 B1 KR 101022790B1
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- Prior art keywords
- monomer
- methacrylate
- acrylate
- starch
- methacrylic
- Prior art date
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- 239000000178 monomer Substances 0.000 claims description 95
- -1 phosphate ester Chemical class 0.000 claims description 42
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 37
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 26
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 22
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 21
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 20
- 239000003995 emulsifying agent Substances 0.000 claims description 17
- 239000003505 polymerization initiator Substances 0.000 claims description 12
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 claims description 11
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- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
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- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 5
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
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- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 4
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims description 4
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
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- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 claims description 4
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 claims description 4
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 4
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 claims description 4
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- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 4
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- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 claims description 4
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- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 4
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- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 claims description 3
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- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 3
- 125000005641 methacryl group Chemical group 0.000 claims description 3
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 claims description 3
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- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 2
- BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 claims description 2
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- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 208000008842 sick building syndrome Diseases 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- NJRXVEJTAYWCQJ-UHFFFAOYSA-N thiomalic acid Chemical compound OC(=O)CC(S)C(O)=O NJRXVEJTAYWCQJ-UHFFFAOYSA-N 0.000 description 1
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09D103/04—Starch derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020100062898A KR101022790B1 (ko) | 2010-06-30 | 2010-06-30 | 수성 도료용 접착 소재의 제조방법 |
| CN201180032782.1A CN102971387B (zh) | 2010-06-30 | 2011-06-28 | 水性涂料用粘接材料的制备方法 |
| JP2013518243A JP5733394B2 (ja) | 2010-06-30 | 2011-06-28 | 水性塗料用接着素材の製造方法 |
| PCT/KR2011/004695 WO2012002696A2 (ko) | 2010-06-30 | 2011-06-28 | 수성 도료용 접착 소재의 제조방법 |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020100062898A KR101022790B1 (ko) | 2010-06-30 | 2010-06-30 | 수성 도료용 접착 소재의 제조방법 |
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| KR101022790B1 true KR101022790B1 (ko) | 2011-03-17 |
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|---|---|---|---|
| KR1020100062898A Active KR101022790B1 (ko) | 2010-06-30 | 2010-06-30 | 수성 도료용 접착 소재의 제조방법 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5733394B2 (enExample) |
| KR (1) | KR101022790B1 (enExample) |
| CN (1) | CN102971387B (enExample) |
| WO (1) | WO2012002696A2 (enExample) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101473916B1 (ko) | 2012-12-28 | 2014-12-17 | 대상 주식회사 | 코어-쉘 구조의 전분계 중합체 입자 및 이를 포함하는 도료용 조성물 |
| KR101524729B1 (ko) * | 2013-06-28 | 2015-06-01 | 부산대학교 산학협력단 | 친수성 폴리머를 포함하는 공중합체 및 이를 포함하는 마찰저항 저감용 조성물 |
| KR101542642B1 (ko) | 2012-01-18 | 2015-08-06 | 주식회사 엘지화학 | 저장안정성과 강도가 우수한 친환경 아크릴계 공중합체 라텍스 및 이를 포함하는 아크릴졸 |
| KR101677427B1 (ko) * | 2014-12-30 | 2016-11-29 | 삼화페인트공업주식회사 | 친환경 고광택성 수성 아크릴 수지, 이의 제조방법 및 이를 포함한 도료 |
| KR101751931B1 (ko) | 2014-12-24 | 2017-06-28 | 대상 주식회사 | 전분계 중합체 입자 에멀젼 및 이의 제조방법 |
| CN109266265A (zh) * | 2018-09-14 | 2019-01-25 | 江南大学 | 一种热固性人造板淀粉胶粘剂及其制备方法 |
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| CN103194903B (zh) * | 2013-04-17 | 2015-06-03 | 山东天鼎丰非织造布有限公司 | 防水卷材胎基布用整理剂及其制备方法 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030187135A1 (en) | 2000-08-11 | 2003-10-02 | Ingolf Kuhn | Polymer dispersons containing starch |
| KR20050048286A (ko) * | 2003-11-19 | 2005-05-24 | 주식회사 케이씨씨 | 수성 건축 도료용 에멀젼 수지, 이의 제조 방법 및 이를함유하는 도료 조성물 |
| JP2009242761A (ja) | 2008-04-01 | 2009-10-22 | Kansai Paint Co Ltd | 水分散体及び該水分散体を含む水性塗料組成物 |
| KR20090112103A (ko) * | 2008-04-23 | 2009-10-28 | 주식회사 삼양제넥스 | 무유화제 유화중합을 이용한 전분-아크릴계 공중합체의제조방법 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3287088B2 (ja) * | 1993-12-08 | 2002-05-27 | ジェイエスアール株式会社 | 共重合体ラテックス |
| JP4674067B2 (ja) * | 2004-08-12 | 2011-04-20 | 関西ペイント株式会社 | 変性澱粉含有樹脂水分散体及び該水分散体の製造方法 |
| JP5563192B2 (ja) * | 2007-12-11 | 2014-07-30 | 関西ペイント株式会社 | 塗料組成物 |
| CN101205696A (zh) * | 2007-12-14 | 2008-06-25 | 华南理工大学 | 一种核壳无皂型表面施胶剂的制备方法 |
| JP4744570B2 (ja) * | 2008-08-22 | 2011-08-10 | サイデン化学株式会社 | 重合体組成物の製造方法 |
| KR101035800B1 (ko) * | 2008-09-08 | 2011-05-20 | 주식회사 삼양제넥스 | 전분 공중합체 및 이의 제조방법 |
| JP2010065136A (ja) * | 2008-09-10 | 2010-03-25 | Kansai Paint Co Ltd | 水性塗料組成物、及びこの組成物を用いた塗装方法 |
| AU2009319065A1 (en) * | 2008-11-25 | 2010-06-03 | Basf Se | Method for preparing aqueous polymer dispersions from a vinyl aromatic compound, a conjugated aliphatic diene and an ethylenically unsaturated carboxylic acid nitrile |
-
2010
- 2010-06-30 KR KR1020100062898A patent/KR101022790B1/ko active Active
-
2011
- 2011-06-28 WO PCT/KR2011/004695 patent/WO2012002696A2/ko not_active Ceased
- 2011-06-28 JP JP2013518243A patent/JP5733394B2/ja active Active
- 2011-06-28 CN CN201180032782.1A patent/CN102971387B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030187135A1 (en) | 2000-08-11 | 2003-10-02 | Ingolf Kuhn | Polymer dispersons containing starch |
| KR20050048286A (ko) * | 2003-11-19 | 2005-05-24 | 주식회사 케이씨씨 | 수성 건축 도료용 에멀젼 수지, 이의 제조 방법 및 이를함유하는 도료 조성물 |
| JP2009242761A (ja) | 2008-04-01 | 2009-10-22 | Kansai Paint Co Ltd | 水分散体及び該水分散体を含む水性塗料組成物 |
| KR20090112103A (ko) * | 2008-04-23 | 2009-10-28 | 주식회사 삼양제넥스 | 무유화제 유화중합을 이용한 전분-아크릴계 공중합체의제조방법 |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101542642B1 (ko) | 2012-01-18 | 2015-08-06 | 주식회사 엘지화학 | 저장안정성과 강도가 우수한 친환경 아크릴계 공중합체 라텍스 및 이를 포함하는 아크릴졸 |
| KR101473916B1 (ko) | 2012-12-28 | 2014-12-17 | 대상 주식회사 | 코어-쉘 구조의 전분계 중합체 입자 및 이를 포함하는 도료용 조성물 |
| KR101524729B1 (ko) * | 2013-06-28 | 2015-06-01 | 부산대학교 산학협력단 | 친수성 폴리머를 포함하는 공중합체 및 이를 포함하는 마찰저항 저감용 조성물 |
| KR101751931B1 (ko) | 2014-12-24 | 2017-06-28 | 대상 주식회사 | 전분계 중합체 입자 에멀젼 및 이의 제조방법 |
| KR101677427B1 (ko) * | 2014-12-30 | 2016-11-29 | 삼화페인트공업주식회사 | 친환경 고광택성 수성 아크릴 수지, 이의 제조방법 및 이를 포함한 도료 |
| CN109266265A (zh) * | 2018-09-14 | 2019-01-25 | 江南大学 | 一种热固性人造板淀粉胶粘剂及其制备方法 |
| KR20220102252A (ko) | 2021-01-13 | 2022-07-20 | 경상국립대학교산학협력단 | 초발수성 도막 적층체 및 이의 시공 방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102971387B (zh) | 2015-11-25 |
| JP2013535518A (ja) | 2013-09-12 |
| CN102971387A (zh) | 2013-03-13 |
| WO2012002696A2 (ko) | 2012-01-05 |
| WO2012002696A3 (ko) | 2012-05-03 |
| JP5733394B2 (ja) | 2015-06-10 |
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