KR100985091B1 - Pvc 중합의 사슬 중단 방법 - Google Patents

Pvc 중합의 사슬 중단 방법 Download PDF

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Publication number
KR100985091B1
KR100985091B1 KR1020047017507A KR20047017507A KR100985091B1 KR 100985091 B1 KR100985091 B1 KR 100985091B1 KR 1020047017507 A KR1020047017507 A KR 1020047017507A KR 20047017507 A KR20047017507 A KR 20047017507A KR 100985091 B1 KR100985091 B1 KR 100985091B1
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South Korea
Prior art keywords
alkyl
radical
carbon atoms
acid
cycloaliphatic
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Expired - Fee Related
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KR1020047017507A
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English (en)
Korean (ko)
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KR20040106427A (ko
Inventor
파엔드너루돌프
베크만알렉스
반네마허토마스
브라운디트리히
Original Assignee
시바 홀딩 인코포레이티드
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Publication of KR20040106427A publication Critical patent/KR20040106427A/ko
Application granted granted Critical
Publication of KR100985091B1 publication Critical patent/KR100985091B1/ko
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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • C08F14/04Monomers containing two carbon atoms
    • C08F14/06Vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/02Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)
KR1020047017507A 2002-05-01 2003-04-24 Pvc 중합의 사슬 중단 방법 Expired - Fee Related KR100985091B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP02405355.5 2002-05-01
EP02405355 2002-05-01
PCT/EP2003/004260 WO2003093330A1 (en) 2002-05-01 2003-04-24 Process for chain stopping of pvc polymerization

Publications (2)

Publication Number Publication Date
KR20040106427A KR20040106427A (ko) 2004-12-17
KR100985091B1 true KR100985091B1 (ko) 2010-10-04

Family

ID=29286253

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020047017507A Expired - Fee Related KR100985091B1 (ko) 2002-05-01 2003-04-24 Pvc 중합의 사슬 중단 방법

Country Status (12)

Country Link
US (1) US7683144B2 (https=)
EP (1) EP1501878A1 (https=)
JP (2) JP4221722B2 (https=)
KR (1) KR100985091B1 (https=)
CN (1) CN1310972C (https=)
AU (1) AU2003224124A1 (https=)
BR (1) BR0309629A (https=)
CA (1) CA2484148A1 (https=)
MX (1) MXPA04010751A (https=)
RU (1) RU2300536C2 (https=)
TW (1) TWI332958B (https=)
WO (1) WO2003093330A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007066839A1 (en) * 2005-12-07 2007-06-14 Seoul National University Industry Foundation Plasticizer composition containing cyclodextrin derivatives, flexible pvc composition with suppression of the migration of plasticizer containing the same, and manufacturing method thereof
EP2389396A1 (en) 2009-01-21 2011-11-30 Taminco Process for the polymerization of vinyl chloride
CN102181000B (zh) * 2011-04-02 2012-08-22 西安道尔达化工有限公司 一种聚氯乙烯用水乳型高效终止剂及其制备方法
CN102492064B (zh) * 2011-11-25 2014-06-18 常州大学 一种聚氯乙烯树酯终止剂的制备及使用方法
CN102432715B (zh) * 2011-11-28 2013-08-14 河北盛华化工有限公司 一种聚氯乙烯聚合专用乳液型终止剂的制备方法
CA2982465C (en) * 2015-04-20 2024-05-14 Ecolab Usa Inc. Sterically hindered hydroquinones as antifoulants for unsaturated monomers

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060147145A1 (en) * 2002-09-12 2006-07-06 Sumitomo Osaka Cement Co., Ltd. Optical modulator

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3926910A (en) 1973-02-12 1975-12-16 Goodyear Tire & Rubber Reduction of reactor fouling and improvement in the thermal stability of pvc using nitrites
US4229598A (en) 1978-12-14 1980-10-21 Conoco, Inc. Chemicals for treatment of PVC
US4361683A (en) 1981-05-26 1982-11-30 Conoco Inc. Termination of vinyl halide polymerization
DE3264027D1 (en) * 1981-07-06 1985-07-11 Ciba Geigy Ag Stop chain agent for vinylchloride polymerisation
US4478986A (en) * 1981-07-06 1984-10-23 Ciba-Geigy Corporation Tri-N-substituted-s-triazine-trione chain terminator for polyvinyl chloride polymerization
GB2202226A (en) * 1987-03-19 1988-09-21 Gerald Scott Bound antioxidant masterbatches
KR100193146B1 (ko) * 1990-07-20 1999-06-15 월터 클리웨인, 한스-피터 위트린 안정화된 단량체 조성물
DE19609312A1 (de) * 1996-03-09 1997-09-11 Basf Ag Stabilisierte Monomerenzusammensetzung
DE19638868A1 (de) * 1996-09-23 1998-03-26 Basf Ag Stabilisierte Monomerenzusammensetzung
US5880230A (en) * 1997-12-31 1999-03-09 Nalco/Exxon Energy Chemicals, L.P. Shortstop agents for vinyl polymerizations
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
JP2002533482A (ja) * 1998-12-21 2002-10-08 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 多官能性開始剤/調整剤化合物を使用した制御されたラジカル重合の為の組成物と生成方法
US6447649B1 (en) * 2000-07-24 2002-09-10 Ge Betz, Inc. Polymerization inhibitor for vinyl-containing materials
TWI236482B (en) * 2000-11-13 2005-07-21 Ciba Sc Holding Ag Process for the (co)polymerization of vinyl chloride in the presence of a stable free nitroxyl radical
FR2822832B1 (fr) * 2001-04-02 2005-01-14 Atofina Polymerisation en suspension acqueuse du chlorure de vinyle seul ou en melange avec un autre monomere vinylique avec utilisation d'un radical stable de type nitroxyde comme agent d'arret de polymerisation

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060147145A1 (en) * 2002-09-12 2006-07-06 Sumitomo Osaka Cement Co., Ltd. Optical modulator

Also Published As

Publication number Publication date
TWI332958B (en) 2010-11-11
KR20040106427A (ko) 2004-12-17
CN1310972C (zh) 2007-04-18
WO2003093330A1 (en) 2003-11-13
RU2004135305A (ru) 2005-08-10
EP1501878A1 (en) 2005-02-02
CA2484148A1 (en) 2003-11-13
TW200400976A (en) 2004-01-16
US20050222347A1 (en) 2005-10-06
RU2300536C2 (ru) 2007-06-10
MXPA04010751A (es) 2005-03-07
JP4221722B2 (ja) 2009-02-12
BR0309629A (pt) 2005-03-08
CN1649913A (zh) 2005-08-03
US7683144B2 (en) 2010-03-23
JP2008291280A (ja) 2008-12-04
JP2005523978A (ja) 2005-08-11
AU2003224124A1 (en) 2003-11-17

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