CN1310972C - Pvc聚合的链终止方法 - Google Patents

Pvc聚合的链终止方法 Download PDF

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Publication number
CN1310972C
CN1310972C CNB038099179A CN03809917A CN1310972C CN 1310972 C CN1310972 C CN 1310972C CN B038099179 A CNB038099179 A CN B038099179A CN 03809917 A CN03809917 A CN 03809917A CN 1310972 C CN1310972 C CN 1310972C
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CN
China
Prior art keywords
group
carbon atoms
alkyl
acid
aliphatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB038099179A
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English (en)
Chinese (zh)
Other versions
CN1649913A (zh
Inventor
R·普发恩德纳
A·维格曼恩
T·万内马彻尔
D·布劳恩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of CN1649913A publication Critical patent/CN1649913A/zh
Application granted granted Critical
Publication of CN1310972C publication Critical patent/CN1310972C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)
CNB038099179A 2002-05-01 2003-04-24 Pvc聚合的链终止方法 Expired - Fee Related CN1310972C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02405355.5 2002-05-01
EP02405355 2002-05-01

Publications (2)

Publication Number Publication Date
CN1649913A CN1649913A (zh) 2005-08-03
CN1310972C true CN1310972C (zh) 2007-04-18

Family

ID=29286253

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB038099179A Expired - Fee Related CN1310972C (zh) 2002-05-01 2003-04-24 Pvc聚合的链终止方法

Country Status (12)

Country Link
US (1) US7683144B2 (https=)
EP (1) EP1501878A1 (https=)
JP (2) JP4221722B2 (https=)
KR (1) KR100985091B1 (https=)
CN (1) CN1310972C (https=)
AU (1) AU2003224124A1 (https=)
BR (1) BR0309629A (https=)
CA (1) CA2484148A1 (https=)
MX (1) MXPA04010751A (https=)
RU (1) RU2300536C2 (https=)
TW (1) TWI332958B (https=)
WO (1) WO2003093330A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007066839A1 (en) * 2005-12-07 2007-06-14 Seoul National University Industry Foundation Plasticizer composition containing cyclodextrin derivatives, flexible pvc composition with suppression of the migration of plasticizer containing the same, and manufacturing method thereof
EP2389396A1 (en) 2009-01-21 2011-11-30 Taminco Process for the polymerization of vinyl chloride
CN102181000B (zh) * 2011-04-02 2012-08-22 西安道尔达化工有限公司 一种聚氯乙烯用水乳型高效终止剂及其制备方法
CN102492064B (zh) * 2011-11-25 2014-06-18 常州大学 一种聚氯乙烯树酯终止剂的制备及使用方法
CN102432715B (zh) * 2011-11-28 2013-08-14 河北盛华化工有限公司 一种聚氯乙烯聚合专用乳液型终止剂的制备方法
CA2982465C (en) * 2015-04-20 2024-05-14 Ecolab Usa Inc. Sterically hindered hydroquinones as antifoulants for unsaturated monomers

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0467848A1 (en) * 1990-07-20 1992-01-22 Ciba-Geigy Ag Stabilized monomer compositions
US5880230A (en) * 1997-12-31 1999-03-09 Nalco/Exxon Energy Chemicals, L.P. Shortstop agents for vinyl polymerizations
WO2002008161A2 (en) * 2000-07-24 2002-01-31 Hercules Incorporated Polymerization inhibitor for vinyl-containing materials

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3926910A (en) 1973-02-12 1975-12-16 Goodyear Tire & Rubber Reduction of reactor fouling and improvement in the thermal stability of pvc using nitrites
US4229598A (en) 1978-12-14 1980-10-21 Conoco, Inc. Chemicals for treatment of PVC
US4361683A (en) 1981-05-26 1982-11-30 Conoco Inc. Termination of vinyl halide polymerization
DE3264027D1 (en) * 1981-07-06 1985-07-11 Ciba Geigy Ag Stop chain agent for vinylchloride polymerisation
US4478986A (en) * 1981-07-06 1984-10-23 Ciba-Geigy Corporation Tri-N-substituted-s-triazine-trione chain terminator for polyvinyl chloride polymerization
GB2202226A (en) * 1987-03-19 1988-09-21 Gerald Scott Bound antioxidant masterbatches
DE19609312A1 (de) * 1996-03-09 1997-09-11 Basf Ag Stabilisierte Monomerenzusammensetzung
DE19638868A1 (de) * 1996-09-23 1998-03-26 Basf Ag Stabilisierte Monomerenzusammensetzung
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
JP2002533482A (ja) * 1998-12-21 2002-10-08 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 多官能性開始剤／調整剤化合物を使用した制御されたラジカル重合の為の組成物と生成方法
TWI236482B (en) * 2000-11-13 2005-07-21 Ciba Sc Holding Ag Process for the (co)polymerization of vinyl chloride in the presence of a stable free nitroxyl radical
FR2822832B1 (fr) * 2001-04-02 2005-01-14 Atofina Polymerisation en suspension acqueuse du chlorure de vinyle seul ou en melange avec un autre monomere vinylique avec utilisation d'un radical stable de type nitroxyde comme agent d'arret de polymerisation
JP3640390B2 (ja) * 2002-09-12 2005-04-20 住友大阪セメント株式会社 光変調器

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0467848A1 (en) * 1990-07-20 1992-01-22 Ciba-Geigy Ag Stabilized monomer compositions
US5880230A (en) * 1997-12-31 1999-03-09 Nalco/Exxon Energy Chemicals, L.P. Shortstop agents for vinyl polymerizations
WO2002008161A2 (en) * 2000-07-24 2002-01-31 Hercules Incorporated Polymerization inhibitor for vinyl-containing materials

Also Published As

Publication number Publication date
TWI332958B (en) 2010-11-11
KR20040106427A (ko) 2004-12-17
WO2003093330A1 (en) 2003-11-13
RU2004135305A (ru) 2005-08-10
KR100985091B1 (ko) 2010-10-04
EP1501878A1 (en) 2005-02-02
CA2484148A1 (en) 2003-11-13
TW200400976A (en) 2004-01-16
US20050222347A1 (en) 2005-10-06
RU2300536C2 (ru) 2007-06-10
MXPA04010751A (es) 2005-03-07
JP4221722B2 (ja) 2009-02-12
BR0309629A (pt) 2005-03-08
CN1649913A (zh) 2005-08-03
US7683144B2 (en) 2010-03-23
JP2008291280A (ja) 2008-12-04
JP2005523978A (ja) 2005-08-11
AU2003224124A1 (en) 2003-11-17

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Granted publication date: 20070418

Termination date: 20110424