JP4221722B2 - Pvc重合の連鎖停止の方法 - Google Patents

Pvc重合の連鎖停止の方法 Download PDF

Info

Publication number
JP4221722B2
JP4221722B2 JP2004501469A JP2004501469A JP4221722B2 JP 4221722 B2 JP4221722 B2 JP 4221722B2 JP 2004501469 A JP2004501469 A JP 2004501469A JP 2004501469 A JP2004501469 A JP 2004501469A JP 4221722 B2 JP4221722 B2 JP 4221722B2
Authority
JP
Japan
Prior art keywords
group
carbon atoms
tert
butyl
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2004501469A
Other languages
English (en)
Japanese (ja)
Other versions
JP2005523978A5 (https=
JP2005523978A (ja
Inventor
プファエンドナー,ルドルフ
ヴェグマン,アレックス
バンネマハー,トーマス
ブラウン,ディートリッヒ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Holding AG filed Critical Ciba Holding AG
Publication of JP2005523978A publication Critical patent/JP2005523978A/ja
Publication of JP2005523978A5 publication Critical patent/JP2005523978A5/ja
Application granted granted Critical
Publication of JP4221722B2 publication Critical patent/JP4221722B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02Monomers containing chlorine
    • C08F14/04Monomers containing two carbon atoms
    • C08F14/06Vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/02Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)
JP2004501469A 2002-05-01 2003-04-24 Pvc重合の連鎖停止の方法 Expired - Fee Related JP4221722B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02405355 2002-05-01
PCT/EP2003/004260 WO2003093330A1 (en) 2002-05-01 2003-04-24 Process for chain stopping of pvc polymerization

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2008233436A Division JP2008291280A (ja) 2002-05-01 2008-09-11 Pvc重合の連鎖停止の方法

Publications (3)

Publication Number Publication Date
JP2005523978A JP2005523978A (ja) 2005-08-11
JP2005523978A5 JP2005523978A5 (https=) 2006-06-15
JP4221722B2 true JP4221722B2 (ja) 2009-02-12

Family

ID=29286253

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2004501469A Expired - Fee Related JP4221722B2 (ja) 2002-05-01 2003-04-24 Pvc重合の連鎖停止の方法
JP2008233436A Withdrawn JP2008291280A (ja) 2002-05-01 2008-09-11 Pvc重合の連鎖停止の方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2008233436A Withdrawn JP2008291280A (ja) 2002-05-01 2008-09-11 Pvc重合の連鎖停止の方法

Country Status (12)

Country Link
US (1) US7683144B2 (https=)
EP (1) EP1501878A1 (https=)
JP (2) JP4221722B2 (https=)
KR (1) KR100985091B1 (https=)
CN (1) CN1310972C (https=)
AU (1) AU2003224124A1 (https=)
BR (1) BR0309629A (https=)
CA (1) CA2484148A1 (https=)
MX (1) MXPA04010751A (https=)
RU (1) RU2300536C2 (https=)
TW (1) TWI332958B (https=)
WO (1) WO2003093330A1 (https=)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007066839A1 (en) * 2005-12-07 2007-06-14 Seoul National University Industry Foundation Plasticizer composition containing cyclodextrin derivatives, flexible pvc composition with suppression of the migration of plasticizer containing the same, and manufacturing method thereof
EP2389396A1 (en) 2009-01-21 2011-11-30 Taminco Process for the polymerization of vinyl chloride
CN102181000B (zh) * 2011-04-02 2012-08-22 西安道尔达化工有限公司 一种聚氯乙烯用水乳型高效终止剂及其制备方法
CN102492064B (zh) * 2011-11-25 2014-06-18 常州大学 一种聚氯乙烯树酯终止剂的制备及使用方法
CN102432715B (zh) * 2011-11-28 2013-08-14 河北盛华化工有限公司 一种聚氯乙烯聚合专用乳液型终止剂的制备方法
CA2982465C (en) * 2015-04-20 2024-05-14 Ecolab Usa Inc. Sterically hindered hydroquinones as antifoulants for unsaturated monomers

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3926910A (en) 1973-02-12 1975-12-16 Goodyear Tire & Rubber Reduction of reactor fouling and improvement in the thermal stability of pvc using nitrites
US4229598A (en) 1978-12-14 1980-10-21 Conoco, Inc. Chemicals for treatment of PVC
US4361683A (en) 1981-05-26 1982-11-30 Conoco Inc. Termination of vinyl halide polymerization
DE3264027D1 (en) * 1981-07-06 1985-07-11 Ciba Geigy Ag Stop chain agent for vinylchloride polymerisation
US4478986A (en) * 1981-07-06 1984-10-23 Ciba-Geigy Corporation Tri-N-substituted-s-triazine-trione chain terminator for polyvinyl chloride polymerization
GB2202226A (en) * 1987-03-19 1988-09-21 Gerald Scott Bound antioxidant masterbatches
KR100193146B1 (ko) * 1990-07-20 1999-06-15 월터 클리웨인, 한스-피터 위트린 안정화된 단량체 조성물
DE19609312A1 (de) * 1996-03-09 1997-09-11 Basf Ag Stabilisierte Monomerenzusammensetzung
DE19638868A1 (de) * 1996-09-23 1998-03-26 Basf Ag Stabilisierte Monomerenzusammensetzung
US5880230A (en) * 1997-12-31 1999-03-09 Nalco/Exxon Energy Chemicals, L.P. Shortstop agents for vinyl polymerizations
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
JP2002533482A (ja) * 1998-12-21 2002-10-08 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 多官能性開始剤/調整剤化合物を使用した制御されたラジカル重合の為の組成物と生成方法
US6447649B1 (en) * 2000-07-24 2002-09-10 Ge Betz, Inc. Polymerization inhibitor for vinyl-containing materials
TWI236482B (en) * 2000-11-13 2005-07-21 Ciba Sc Holding Ag Process for the (co)polymerization of vinyl chloride in the presence of a stable free nitroxyl radical
FR2822832B1 (fr) * 2001-04-02 2005-01-14 Atofina Polymerisation en suspension acqueuse du chlorure de vinyle seul ou en melange avec un autre monomere vinylique avec utilisation d'un radical stable de type nitroxyde comme agent d'arret de polymerisation
JP3640390B2 (ja) * 2002-09-12 2005-04-20 住友大阪セメント株式会社 光変調器

Also Published As

Publication number Publication date
TWI332958B (en) 2010-11-11
KR20040106427A (ko) 2004-12-17
CN1310972C (zh) 2007-04-18
WO2003093330A1 (en) 2003-11-13
RU2004135305A (ru) 2005-08-10
KR100985091B1 (ko) 2010-10-04
EP1501878A1 (en) 2005-02-02
CA2484148A1 (en) 2003-11-13
TW200400976A (en) 2004-01-16
US20050222347A1 (en) 2005-10-06
RU2300536C2 (ru) 2007-06-10
MXPA04010751A (es) 2005-03-07
BR0309629A (pt) 2005-03-08
CN1649913A (zh) 2005-08-03
US7683144B2 (en) 2010-03-23
JP2008291280A (ja) 2008-12-04
JP2005523978A (ja) 2005-08-11
AU2003224124A1 (en) 2003-11-17

Similar Documents

Publication Publication Date Title
JP2008291280A (ja) Pvc重合の連鎖停止の方法
JP6225122B2 (ja) スチレン系フルオロポリマーの調製のための方法
CN103635520B (zh) 树脂组合物和成型体
NO862240L (no) Polymerblanding.
BR112016013042B1 (pt) Polímero a base de etileno, composição e artigo
CN102617761B (zh) 氯乙烯悬浮聚合终止剂及其制备方法和使用方法
CN1225485C (zh) 在稳定的硝酰自由基存在下氯乙烯的聚合或共聚
US5892037A (en) Polymeric adducts of hindered amine-epoxides as stabilizers
EP3284761A1 (en) Vinyl chloride-based polymer, preparation method therefor, and thermoplastic resin composition containing same
MXPA05005303A (es) Uso de polvo polimero que contiene absorbedor uv para la estabilizacion de polimeros contra los efectos de la radiacion uv.
CN107567467B (zh) 具有改进的低温特性和良好的耐油性的乙烯共聚物,以及由其生产的可固化混合物和固化橡胶
US6815481B2 (en) Polybutadiene composition
CN112409526B (zh) 一种氯乙烯-醋酸乙烯酯-丙烯酸丁酯共聚物的制备方法
KR20110131184A (ko) 염화비닐의 중합 방법
KR20080049974A (ko) 장갑용 페이스트 염화비닐계 수지의 제조방법
JPH0543760A (ja) 硬質塩化ビニル系樹脂組成物
US5670563A (en) Stabilised chlorine-containing polymer compositions
TW202239780A (zh) 改性聚乙烯醇系聚合物及其應用
CN108137720B (zh) 氯乙烯基聚合物的制备方法和由其制备的氯乙烯基聚合物
SU340177A1 (https=)
KR102002061B1 (ko) 염화비닐계 수지 조성물, 이의 제조방법 및 이로부터 제조된 염화비닐계 수지 성형품
JPH0423813A (ja) α―オレフィン共重合体およびその製造方法
EP0050411B1 (en) Process for the production of vinyl chloride polymers having improved optical properties
JP2023128378A (ja) 亜リン酸エステル組成物
WO2023048245A1 (ja) 塩素化塩化ビニル系樹脂、成形用樹脂組成物及び成形体

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060420

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060420

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20080521

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080528

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20080828

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20080904

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080911

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20081008

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20081106

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111128

Year of fee payment: 3

LAPS Cancellation because of no payment of annual fees