KR100806416B1 - 산 관능성 플루오로 중합체 막 및 그의 제조 방법 - Google Patents

산 관능성 플루오로 중합체 막 및 그의 제조 방법 Download PDF

Info

Publication number
KR100806416B1
KR100806416B1 KR1020027007596A KR20027007596A KR100806416B1 KR 100806416 B1 KR100806416 B1 KR 100806416B1 KR 1020027007596 A KR1020027007596 A KR 1020027007596A KR 20027007596 A KR20027007596 A KR 20027007596A KR 100806416 B1 KR100806416 B1 KR 100806416B1
Authority
KR
South Korea
Prior art keywords
fluoropolymer
delete delete
acidizable
polymer
acid functional
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020027007596A
Other languages
English (en)
Korean (ko)
Other versions
KR20020063223A (ko
Inventor
스티븐제이. 햄록
나이용 징
셰인에스. 마오
엘.챨스 하디
Original Assignee
쓰리엠 이노베이티브 프로퍼티즈 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 쓰리엠 이노베이티브 프로퍼티즈 캄파니 filed Critical 쓰리엠 이노베이티브 프로퍼티즈 캄파니
Publication of KR20020063223A publication Critical patent/KR20020063223A/ko
Application granted granted Critical
Publication of KR100806416B1 publication Critical patent/KR100806416B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/22Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F114/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F114/18Monomers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/26Removing halogen atoms or halogen-containing groups from the molecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/34Introducing sulfur atoms or sulfur-containing groups
    • C08F8/38Sulfohalogenation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • C08J5/2231Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2243Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231
    • C08J5/225Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds obtained by introduction of active groups capable of ion-exchange into compounds of the type C08J5/2231 containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16Homopolymers or copolymers or vinylidene fluoride
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1039Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1069Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020027007596A 1999-12-15 2000-12-04 산 관능성 플루오로 중합체 막 및 그의 제조 방법 Expired - Fee Related KR100806416B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/464,337 1999-12-15
US09/464,337 US6423784B1 (en) 1999-12-15 1999-12-15 Acid functional fluoropolymer membranes and method of manufacture

Publications (2)

Publication Number Publication Date
KR20020063223A KR20020063223A (ko) 2002-08-01
KR100806416B1 true KR100806416B1 (ko) 2008-02-21

Family

ID=23843521

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020027007596A Expired - Fee Related KR100806416B1 (ko) 1999-12-15 2000-12-04 산 관능성 플루오로 중합체 막 및 그의 제조 방법

Country Status (7)

Country Link
US (3) US6423784B1 (https=)
EP (1) EP1242473A1 (https=)
JP (1) JP2003517054A (https=)
KR (1) KR100806416B1 (https=)
AU (1) AU1943201A (https=)
CA (1) CA2393383A1 (https=)
WO (1) WO2001044314A1 (https=)

Families Citing this family (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69740003D1 (de) 1996-12-20 2010-11-04 Siemens Water Tech Corp Reinigungsmethode
US6780935B2 (en) * 2000-02-15 2004-08-24 Atofina Chemicals, Inc. Fluoropolymer resins containing ionic or ionizable groups and products containing the same
AUPR143400A0 (en) 2000-11-13 2000-12-07 Usf Filtration And Separations Group Inc. Modified membranes
AUPR421501A0 (en) 2001-04-04 2001-05-03 U.S. Filter Wastewater Group, Inc. Potting method
AUPR584301A0 (en) * 2001-06-20 2001-07-12 U.S. Filter Wastewater Group, Inc. Membrane polymer compositions
AUPR692401A0 (en) 2001-08-09 2001-08-30 U.S. Filter Wastewater Group, Inc. Method of cleaning membrane modules
US7247238B2 (en) 2002-02-12 2007-07-24 Siemens Water Technologies Corp. Poly(ethylene chlorotrifluoroethylene) membranes
EP1518290A4 (en) 2002-05-13 2009-12-02 Polyfuel Inc ION-LEADING BLOCK COPOLYMERS
AUPS300602A0 (en) 2002-06-18 2002-07-11 U.S. Filter Wastewater Group, Inc. Methods of minimising the effect of integrity loss in hollow fibre membrane modules
CA2501628C (en) 2002-10-10 2012-12-04 U.S. Filter Wastewater Group, Inc. A filtration and backwashing arrangement for membrane modules
AU2002953111A0 (en) 2002-12-05 2002-12-19 U. S. Filter Wastewater Group, Inc. Mixing chamber
WO2004072141A2 (en) * 2003-02-13 2004-08-26 The Penn State Research Foundation Synthesis of polyphosphazenes with sulfonimide side groups
US20040175625A1 (en) * 2003-03-06 2004-09-09 Lotfi Hedhli Non-perfluorinated resins containing ionic or ionizable groups and products containing the same
US20040197626A1 (en) * 2003-04-01 2004-10-07 Yoocharn Jeon Composite electrolyte for fuel cell
AU2003903507A0 (en) 2003-07-08 2003-07-24 U. S. Filter Wastewater Group, Inc. Membrane post-treatment
KR101115173B1 (ko) 2003-08-29 2012-02-24 지멘스 워터 테크놀로지스 코포레이션 역류
US7183370B2 (en) 2003-09-11 2007-02-27 Toyota Technical Center Usa, Inc Phosphonic-acid grafted hybrid inorganic-organic proton electrolyte membranes (PEMs)
US7071271B2 (en) * 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7179847B2 (en) * 2003-11-13 2007-02-20 3M Innovative Properties Company Polymer electrolytes crosslinked by e-beam
US7259208B2 (en) * 2003-11-13 2007-08-21 3M Innovative Properties Company Reinforced polymer electrolyte membrane
US7074841B2 (en) * 2003-11-13 2006-07-11 Yandrasits Michael A Polymer electrolyte membranes crosslinked by nitrile trimerization
US7265162B2 (en) * 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
WO2005046849A1 (en) 2003-11-14 2005-05-26 U.S. Filter Wastewater Group, Inc. Improved module cleaning method
US7060756B2 (en) 2003-11-24 2006-06-13 3M Innovative Properties Company Polymer electrolyte with aromatic sulfone crosslinking
US7112614B2 (en) * 2003-12-08 2006-09-26 3M Innovative Properties Company Crosslinked polymer
US7060738B2 (en) * 2003-12-11 2006-06-13 3M Innovative Properties Company Polymer electrolytes crosslinked by ultraviolet radiation
US7173067B2 (en) * 2003-12-17 2007-02-06 3M Innovative Properties Company Polymer electrolyte membranes crosslinked by direct fluorination
US7576165B2 (en) * 2004-01-27 2009-08-18 Georgia Institute Of Technology Heterocycle grafted monomers and related polymers and hybrid inorganic-organic polymer membranes
WO2005092799A1 (en) 2004-03-26 2005-10-06 U.S. Filter Wastewater Group, Inc. Process and apparatus for purifying impure water using microfiltration or ultrafiltration in combination with reverse osmosis
AU2005240524C1 (en) 2004-04-22 2009-12-24 Evoqua Water Technologies Llc Filtration apparatus comprising a membrane bioreactor and a treatment vessel for digesting organic materials
US7253236B2 (en) * 2004-06-10 2007-08-07 Dupont Performance Elastomers L.L.C. Grafted fluoroelastomers
US7819956B2 (en) 2004-07-02 2010-10-26 Siemens Water Technologies Corp. Gas transfer membrane
JP2008505197A (ja) 2004-07-05 2008-02-21 シーメンス・ウォーター・テクノロジーズ・コーポレーション 親水性膜
WO2006019097A1 (ja) * 2004-08-18 2006-02-23 Asahi Glass Company, Limited 燃料電池用電解質ポリマー、その製造方法、電解質膜、及び膜・電極接合体
NZ588094A (en) 2004-08-20 2012-04-27 Siemens Water Tech Corp Potting head for hollow fibre filter module
US8790515B2 (en) 2004-09-07 2014-07-29 Evoqua Water Technologies Llc Reduction of backwash liquid waste
AU2005284677B2 (en) 2004-09-14 2010-12-23 Evoqua Water Technologies Llc Methods and apparatus for removing solids from a membrane module
NZ553771A (en) 2004-09-15 2010-11-26 Siemens Water Tech Corp Continuously variable aeration of membrane filtration system and flow control device when used in such application
US7591950B2 (en) 2004-11-02 2009-09-22 Siemens Water Technologies Corp. Submerged cross-flow filtration
WO2006058384A1 (en) 2004-12-03 2006-06-08 Siemens Water Technologies Corp. Membrane post treatment
NZ583228A (en) 2004-12-24 2012-05-25 Siemens Industry Inc Cleaning in membrane filtration systems
US8758622B2 (en) 2004-12-24 2014-06-24 Evoqua Water Technologies Llc Simple gas scouring method and apparatus
NZ562786A (en) 2005-04-29 2010-10-29 Siemens Water Tech Corp Chemical clean for membrane filter
US7214740B2 (en) * 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
WO2007006104A1 (en) 2005-07-14 2007-01-18 Siemens Water Technologies Corp. Monopersulfate treatment of membranes
SG140229A1 (en) 2005-08-22 2008-03-28 Siemens Water Tech Corp An assembly for water filtration using a tube manifold to minimise backwash
WO2007044415A2 (en) 2005-10-05 2007-04-19 Siemens Water Technologies Corp. Method and apparatus for treating wastewater
WO2007044345A2 (en) 2005-10-05 2007-04-19 Siemens Water Technologies Corp. Method and apparatus for treating wastewater
US7455765B2 (en) 2006-01-25 2008-11-25 Siemens Water Technologies Corp. Wastewater treatment system and method
US8293098B2 (en) 2006-10-24 2012-10-23 Siemens Industry, Inc. Infiltration/inflow control for membrane bioreactor
US8318028B2 (en) 2007-04-02 2012-11-27 Siemens Industry, Inc. Infiltration/inflow control for membrane bioreactor
US9764288B2 (en) 2007-04-04 2017-09-19 Evoqua Water Technologies Llc Membrane module protection
EP2463017A1 (en) 2007-05-29 2012-06-13 Siemens Industry, Inc. Membrane cleaning with pulsed airlift pump
US20090280367A1 (en) * 2008-05-12 2009-11-12 Clearedge Power, Inc. Extraction of Energy From Used Cooking Oil
WO2009151556A1 (en) * 2008-06-09 2009-12-17 Fsi International, Inc. Hydrophilic fluoropolymer materials and methods
CN102112213B (zh) 2008-07-24 2016-08-03 伊沃夸水处理技术有限责任公司 用于膜过滤模块的框架系统
JP2012500117A (ja) 2008-08-20 2012-01-05 シーメンス ウォーター テクノロジース コーポレイション 膜濾過システムの逆洗エネルギ効率の改善
AU2010101488B4 (en) 2009-06-11 2013-05-02 Evoqua Water Technologies Llc Methods for cleaning a porous polymeric membrane and a kit for cleaning a porous polymeric membrane
CN102869432B (zh) 2010-04-30 2016-02-03 伊沃夸水处理技术有限责任公司 流体流分配装置
US9022224B2 (en) 2010-09-24 2015-05-05 Evoqua Water Technologies Llc Fluid control manifold for membrane filtration system
JP2014528354A (ja) 2011-09-30 2014-10-27 エヴォクア ウォーター テクノロジーズ エルエルシーEvoqua Water Technologiesllc 隔離バルブ
CN103958024B (zh) 2011-09-30 2016-07-06 伊沃夸水处理技术有限责任公司 改进的歧管排列
AU2013280452B2 (en) 2012-06-28 2017-07-20 Evoqua Water Technologies Llc A potting method
KR20150054918A (ko) 2012-09-14 2015-05-20 에보쿠아 워터 테크놀로지스 엘엘씨 막을 위한 중합체 블렌드
DE112013004713T5 (de) 2012-09-26 2015-07-23 Evoqua Water Technologies Llc Membransicherungsvorrichtung
AU2013231145B2 (en) 2012-09-26 2017-08-17 Evoqua Water Technologies Llc Membrane potting methods
KR20150059788A (ko) 2012-09-27 2015-06-02 에보쿠아 워터 테크놀로지스 엘엘씨 침지된 막을 위한 가스 스코어링 장치
HUE061765T2 (hu) 2013-10-02 2023-08-28 Rohm & Haas Electronic Mat Singapore Pte Ltd Berendezés membrán filtrációs modul javítására
WO2017004496A1 (en) 2015-07-01 2017-01-05 3M Innovative Properties Company Polymeric ionomer separation membranes and methods of use
WO2017004495A1 (en) 2015-07-01 2017-01-05 3M Innovative Properties Company Composite membranes with improved performance and/or durability and methods of use
US10737220B2 (en) 2015-07-01 2020-08-11 3M Innovative Properties Company PVP- and/or PVL-containing composite membranes and methods of use
WO2017011068A1 (en) 2015-07-14 2017-01-19 Evoqua Water Technologies Llc Aeration device for filtration system
US20190060842A1 (en) 2017-08-22 2019-02-28 Daniel M. Knauss Functionalized poly(diallylpiperidinium) and its copolymers for use in ion conducting applications
US10961336B2 (en) * 2017-08-22 2021-03-30 Colorado School Of Mines Method of functionalizing fluoropolymers with acidic side chains exhibiting improved properties, the fluoropolymers thereof, and methods of using
US10836874B2 (en) 2017-10-02 2020-11-17 Colorado School Of Mines High performance cross-linked triblock cationic functionalized polymer for electrochemical applications, methods of making and methods of using
KR102842971B1 (ko) * 2019-07-25 2025-08-06 현대자동차주식회사 연료전지용 촉매 복합체, 이의 제조방법, 촉매 복합체를 포함하는 전해질막 및 이의 제조방법
EP4133542A1 (en) 2020-04-09 2023-02-15 3M Innovative Properties Company Composite including fluorinated polymer and salt nanoparticles and articles including the same
US20230279192A1 (en) 2020-06-08 2023-09-07 3M Innovative Properties Company Process for recycling a solid article including a fluorinated polymer
US20250239638A1 (en) 2021-10-07 2025-07-24 3M Innovative Properties Company Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same
WO2023111750A1 (en) 2021-12-13 2023-06-22 3M Innovative Properties Company Process for recycling a solid article including a fluorinated polymer

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5395886A (en) * 1991-04-01 1995-03-07 Dow Corning Corporation Modified fluorohydrocarbon polymers

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5025503B1 (https=) * 1970-12-21 1975-08-23
JPS60231703A (ja) 1984-04-28 1985-11-18 Kanegafuchi Chem Ind Co Ltd 表面改質含フツ素高分子材料の製法
US4956419A (en) 1988-03-09 1990-09-11 Minnesota Mining And Manufacturing Company Fluorine-containing polymers with pendent thioorgano groups and method of making said polymers
US4894410A (en) 1988-03-09 1990-01-16 Minnesota Mining And Manufacturing Company Fluorine-containing polymers with pendent thioorgano groups
CH691209A5 (de) 1993-09-06 2001-05-15 Scherrer Inst Paul Herstellungsverfahren für einen Polmerelektrolyten und elektrochemische Zelle mit diesem Polymerelektrolyten.
CN1082975C (zh) 1995-06-22 2002-04-17 戴尼昂有限公司 有改进的防焦性的可固化含氟弹性体组合物
JPH11176456A (ja) * 1997-12-15 1999-07-02 Aisin Seiki Co Ltd 固体高分子電解質型燃料電池
DE69908499T2 (de) 1998-01-30 2004-05-13 Hydro-Québec, Montréal Polymerisierbare bis-sulfonylderivate und ihre verwendung in der herstellung von ionenaustauschermembranen

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5395886A (en) * 1991-04-01 1995-03-07 Dow Corning Corporation Modified fluorohydrocarbon polymers

Also Published As

Publication number Publication date
EP1242473A1 (en) 2002-09-25
JP2003517054A (ja) 2003-05-20
CA2393383A1 (en) 2001-06-21
US7160928B2 (en) 2007-01-09
WO2001044314A1 (en) 2001-06-21
US6833412B2 (en) 2004-12-21
US6423784B1 (en) 2002-07-23
US20050119417A1 (en) 2005-06-02
KR20020063223A (ko) 2002-08-01
AU1943201A (en) 2001-06-25
US20030008191A1 (en) 2003-01-09

Similar Documents

Publication Publication Date Title
KR100806416B1 (ko) 산 관능성 플루오로 중합체 막 및 그의 제조 방법
US7960046B2 (en) Sulfonated-perfluorocyclobutane polyelectrolyte membranes for fuel cells
EP1290041B1 (en) Sulfonated perfluorocyclobutane ion-conducting membranes
US20130245219A1 (en) Ionomers and ionically conductive compositions
EP2452955A1 (en) Stabilized fluoropolymer and method for producing same
EP2656425B1 (en) Ionomers and ionically conductive compositions for use as one or more electrode of a fuel cell
US20130252134A1 (en) High molecular weight ionomers and ionically conductive compositions for use as one or more electrode of a fuel cell
JP4706023B2 (ja) スルホン酸化芳香族ポリエーテル、その製造方法及び電解質膜
KR20140088888A (ko) 레독스 플로우 이차 전지 및 레독스 플로우 이차 전지용 전해질막
JP4102299B2 (ja) 燃料電池に用いるイオノマー及びその製造方法
US20100093878A1 (en) Crosslinkable fluoropolymer, crosslinked fluoropolymers and crosslinked fluoropolymer membranes
WO2008023801A1 (en) Polymer electrolyte membrane composed of aromatic polymer membrane base and method for producing the same
JP5333913B2 (ja) アルキルエーテルグラフト鎖からなる高分子電解質膜、及び、その製造方法
KR100796989B1 (ko) 수소이온 전도성 가교형 불소계 공중합체 전해질막
US20110046247A1 (en) Crosslinkable monomer
KR100796990B1 (ko) 친수성 및 술폰화 그룹이 도입된 가지형 불소계 공중합체전해질막
US8829131B2 (en) Fluorinated copolymers, membranes prepared using the latter and fuel cell device including said membranes
JP2003346815A (ja) 膜電極接合体、及びその製造方法
JP2004083864A (ja) フッ素化プロトン伝導性高分子膜およびその製造方法
JP4595159B2 (ja) 電解質の改質方法及び改質電解質
US20110230575A1 (en) Crosslinkable trifluorostyrene polymers and membranes
KR100408877B1 (ko) 불소화, 술폰화에 의한 스티렌-디엔계 공중합체와 그제조방법 및 이 공중합체를 이용한 연료전지용 고분자전해질막
US8664282B2 (en) Process to prepare crosslinkable trifluorostyrene polymers and membranes
KR20120077861A (ko) 솔젤 반응을 이용한 기능성 물질 포함 하이브리드 막의 제조방법
KR100860790B1 (ko) 수소이온 전도성 가지형 염소계 고분자 전해질막 및 그제조방법

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

FPAY Annual fee payment

Payment date: 20130117

Year of fee payment: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

FPAY Annual fee payment

Payment date: 20140117

Year of fee payment: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

FPAY Annual fee payment

Payment date: 20150119

Year of fee payment: 8

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

FPAY Annual fee payment

Payment date: 20160119

Year of fee payment: 9

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 9

FPAY Annual fee payment

Payment date: 20170119

Year of fee payment: 10

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 10

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20180216

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20180216