KR100636446B1 - 리튬화 망간 옥사이드의 제조방법 - Google Patents

리튬화 망간 옥사이드의 제조방법 Download PDF

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Publication number
KR100636446B1
KR100636446B1 KR1019990017214A KR19990017214A KR100636446B1 KR 100636446 B1 KR100636446 B1 KR 100636446B1 KR 1019990017214 A KR1019990017214 A KR 1019990017214A KR 19990017214 A KR19990017214 A KR 19990017214A KR 100636446 B1 KR100636446 B1 KR 100636446B1
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Prior art keywords
lithium
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alkali metal
ions
ion exchange
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KR1019990017214A
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Korean (ko)
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KR19990088267A (ko
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파디아크샤야쿠마르
필라이지.치탐바라타누
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카루스 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/02—Oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
KR1019990017214A 1998-05-21 1999-05-13 리튬화 망간 옥사이드의 제조방법 Expired - Fee Related KR100636446B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US9/082,329 1998-05-21
US09/082,329 US5955052A (en) 1998-05-21 1998-05-21 Method for making lithiated manganese oxide
US09/082,329 1998-05-21

Publications (2)

Publication Number Publication Date
KR19990088267A KR19990088267A (ko) 1999-12-27
KR100636446B1 true KR100636446B1 (ko) 2006-10-18

Family

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Country Status (7)

Country Link
US (2) US5955052A (enExample)
EP (1) EP0959045B1 (enExample)
JP (1) JP2000034127A (enExample)
KR (1) KR100636446B1 (enExample)
CA (1) CA2271516C (enExample)
DE (1) DE69921229T2 (enExample)
TW (1) TW504498B (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6482374B1 (en) * 1999-06-16 2002-11-19 Nanogram Corporation Methods for producing lithium metal oxide particles
US6083475A (en) * 1999-04-02 2000-07-04 Rentech, Inc. Method for making lithiated metal oxide
EP1089365B1 (en) * 1999-10-01 2016-07-20 Tosoh Corporation Lithium manganese oxide, and process for its production and secondary cell employing it
JP2001273898A (ja) * 2000-01-20 2001-10-05 Japan Storage Battery Co Ltd 非水電解質二次電池用正極活物質およびその製造方法並びにそれを使用した非水電解質二次電池
US6783893B2 (en) * 2001-11-19 2004-08-31 The Gillette Company Alkaline battery
US6759167B2 (en) * 2001-11-19 2004-07-06 The Gillette Company Primary lithium electrochemical cell
US8137842B2 (en) * 2004-01-22 2012-03-20 The Gillette Company Battery cathodes
KR100912095B1 (ko) 2006-11-20 2009-08-13 한국지질자원연구원 중공사막 필터를 이용한 이온 교환형 리튬 흡착제 및 그의제조 방법
US20080119350A1 (en) * 2006-11-20 2008-05-22 Korea Institute Of Geosciences And Mineral Resources Ion exchange type lithium adsorbent using filter and method for preparing the same
JP5014218B2 (ja) * 2007-03-22 2012-08-29 三洋電機株式会社 非水電解質二次電池
US8137761B2 (en) * 2008-06-13 2012-03-20 Caterpillar Inc. Method of coating and induction heating a component
JP2010108912A (ja) * 2008-09-30 2010-05-13 Sanyo Electric Co Ltd 非水電解質二次電池、その電池に用いられる正極活物質、及び、その正極活物質の製造方法
US8142933B2 (en) * 2009-09-30 2012-03-27 Conocophillips Company Anode material for high power lithium ion batteries
US20110223477A1 (en) * 2010-03-12 2011-09-15 Nelson Jennifer A Alkaline battery including lambda-manganese dioxide and method of making thereof
US8298706B2 (en) 2010-03-12 2012-10-30 The Gillette Company Primary alkaline battery
US8303840B2 (en) * 2010-03-12 2012-11-06 The Gillette Company Acid-treated manganese dioxide and methods of making thereof
US20110219607A1 (en) * 2010-03-12 2011-09-15 Nanjundaswamy Kirakodu S Cathode active materials and method of making thereof
CN102070199B (zh) * 2010-11-18 2012-09-05 清华大学 微米框状锰系锂离子电池阴极电极材料的制备方法
US8703336B2 (en) 2012-03-21 2014-04-22 The Gillette Company Metal-doped nickel oxide active materials
US9570741B2 (en) 2012-03-21 2017-02-14 Duracell U.S. Operations, Inc. Metal-doped nickel oxide active materials
US9028564B2 (en) 2012-03-21 2015-05-12 The Gillette Company Methods of making metal-doped nickel oxide active materials
KR101728645B1 (ko) 2013-10-04 2017-04-19 닛산 지도우샤 가부시키가이샤 비수 전해질 2차 전지용 정극 활물질 및 그 제조 방법
US9793542B2 (en) 2014-03-28 2017-10-17 Duracell U.S. Operations, Inc. Beta-delithiated layered nickel oxide electrochemically active cathode material and a battery including said material
JP7105802B2 (ja) 2017-05-09 2022-07-25 デュラセル、ユーエス、オペレーションズ、インコーポレーテッド ベータ脱リチウム化層状酸化ニッケルの電気化学的に活性なカソード材料を含む電池
CN107492648B (zh) * 2017-08-18 2019-12-27 湖北文理学院 棉花基碳纤维/MnO/C材料、制备方法及应用
CN112563564B (zh) * 2020-11-13 2021-11-09 上海空间电源研究所 一种制备钠离子固体电解质的软化学合成方法
KR102492040B1 (ko) 2021-01-08 2023-01-27 고려대학교 산학협력단 양극 활물질 제조 방법

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4312930A (en) * 1978-09-29 1982-01-26 Union Carbide Corporation MnO2 Derived from LiMn2 O4
US4246253A (en) * 1978-09-29 1981-01-20 Union Carbide Corporation MnO2 derived from LiMn2 O4
US4590059A (en) * 1983-09-30 1986-05-20 Union Carbide Corporation Process for the production of manganese dioxide
JPH0746607B2 (ja) * 1987-01-29 1995-05-17 三洋電機株式会社 非水系二次電池
CA1331506C (en) * 1988-07-12 1994-08-23 Michael Makepeace Thackeray Method of synthesizing a lithium manganese oxide
FR2644295A1 (fr) * 1989-03-09 1990-09-14 Accumulateurs Fixes Generateur electrochimique rechargeable a anode de lithium
US5153081A (en) * 1989-07-28 1992-10-06 Csir Lithium manganese oxide compound
FR2659075B1 (fr) * 1990-03-01 1992-05-29 France Etat Armement Procede de preparation d'oxydes de manganese par voie sol-gel.
US5135732A (en) * 1991-04-23 1992-08-04 Bell Communications Research, Inc. Method for preparation of LiMn2 O4 intercalation compounds and use thereof in secondary lithium batteries
US5211933A (en) * 1991-04-23 1993-05-18 Bell Communications Research, Inc. Method for preparation of LiCoO2 intercalation compound for use in secondary lithium batteries
CA2096264A1 (en) * 1993-05-14 1994-11-15 Jeffrey Raymond Dahn Novel method for preparing solid solution materials for secondary non-aqueous batteries
US5506077A (en) * 1993-06-14 1996-04-09 Koksbang; Rene Manganese oxide cathode active material
FR2707426B1 (fr) * 1993-07-09 1995-08-18 Accumulateurs Fixes Générateur électrochimique rechargeable au lithium et son procédé de réalisation.
DE69409352T2 (de) * 1993-12-24 1998-07-23 Sharp Kk Nichtwässrige Sekundärbatterie, aktives Material für positive Elektrode und Verfahren zu dessen Herstellung
US5558961A (en) * 1994-06-13 1996-09-24 Regents, University Of California Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material
US5766569A (en) * 1995-09-07 1998-06-16 Kerr-Mcgee Chemical Corporation Lithium manganese oxide compound and method of preparation
US5702679A (en) * 1995-10-06 1997-12-30 Kerr-Mcgee Chemical Corp. Method of preparing Li1+X- Mn2-X O4 for use as secondary battery
US5604057A (en) * 1995-11-27 1997-02-18 General Motors Corporation Secondary cell having a lithium intercolating manganese oxide
US5605773A (en) * 1995-12-06 1997-02-25 Kerr-Mcgee Corporation Lithium manganese oxide compound and method of preparation
GB9600772D0 (en) * 1996-01-15 1996-03-20 Univ St Andrews Improvements in and relating to electrochemical cells
US5753202A (en) * 1996-04-08 1998-05-19 Duracell Inc. Method of preparation of lithium manganese oxide spinel
US5770018A (en) * 1996-04-10 1998-06-23 Valence Technology, Inc. Method for preparing lithium manganese oxide compounds
US5976489A (en) * 1996-04-10 1999-11-02 Valence Technology, Inc. Method for preparing lithium manganese oxide compounds
US5759510A (en) * 1996-10-03 1998-06-02 Carus Chemical Company Lithiated manganese oxide
US5824285A (en) * 1996-10-23 1998-10-20 Valence Technology, Inc. Method of making lithium manganese oxide compounds
US6048645A (en) * 1997-08-21 2000-04-11 Valence Technology, Inc. Method of preparing lithium ion electrochemical cells

Also Published As

Publication number Publication date
US6207129B1 (en) 2001-03-27
EP0959045A3 (en) 2000-05-10
CA2271516C (en) 2005-08-23
EP0959045B1 (en) 2004-10-20
JP2000034127A (ja) 2000-02-02
EP0959045A2 (en) 1999-11-24
US5955052A (en) 1999-09-21
TW504498B (en) 2002-10-01
KR19990088267A (ko) 1999-12-27
CA2271516A1 (en) 1999-11-21
DE69921229D1 (de) 2004-11-25
HK1023979A1 (en) 2000-09-29
DE69921229T2 (de) 2006-03-09

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