DE69921229T2 - Verfahren zur Herstellung von Lithium enthaltendes Manganoxid - Google Patents
Verfahren zur Herstellung von Lithium enthaltendes Manganoxid Download PDFInfo
- Publication number
- DE69921229T2 DE69921229T2 DE69921229T DE69921229T DE69921229T2 DE 69921229 T2 DE69921229 T2 DE 69921229T2 DE 69921229 T DE69921229 T DE 69921229T DE 69921229 T DE69921229 T DE 69921229T DE 69921229 T2 DE69921229 T2 DE 69921229T2
- Authority
- DE
- Germany
- Prior art keywords
- lithium
- ion
- alkali metal
- exchanged product
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 title claims description 62
- 238000000034 method Methods 0.000 title claims description 45
- 229910052744 lithium Inorganic materials 0.000 title claims description 19
- 238000002360 preparation method Methods 0.000 title claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title description 18
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 118
- 239000011572 manganese Substances 0.000 claims description 48
- 150000002642 lithium compounds Chemical class 0.000 claims description 46
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 27
- 229910052748 manganese Inorganic materials 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 23
- 229910001415 sodium ion Inorganic materials 0.000 claims description 22
- 229910052596 spinel Inorganic materials 0.000 claims description 22
- 239000011029 spinel Substances 0.000 claims description 22
- 229910001414 potassium ion Inorganic materials 0.000 claims description 21
- 229910001416 lithium ion Inorganic materials 0.000 claims description 18
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 17
- 238000005342 ion exchange Methods 0.000 claims description 17
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 claims description 16
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 15
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 11
- 239000010406 cathode material Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 6
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 6
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims description 6
- 229910008168 Li1+x Mn2-y O4 Inorganic materials 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 3
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 3
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims description 3
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 claims description 3
- 239000011734 sodium Substances 0.000 description 46
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 43
- 239000000047 product Substances 0.000 description 36
- 238000006243 chemical reaction Methods 0.000 description 30
- 229910052708 sodium Inorganic materials 0.000 description 23
- 239000011591 potassium Substances 0.000 description 18
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 17
- 229910052700 potassium Inorganic materials 0.000 description 17
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 16
- 239000002245 particle Substances 0.000 description 14
- 230000003647 oxidation Effects 0.000 description 12
- 238000007254 oxidation reaction Methods 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- 238000006722 reduction reaction Methods 0.000 description 9
- 239000003638 chemical reducing agent Substances 0.000 description 8
- LBSANEJBGMCTBH-UHFFFAOYSA-N manganate Chemical compound [O-][Mn]([O-])(=O)=O LBSANEJBGMCTBH-UHFFFAOYSA-N 0.000 description 8
- 150000002894 organic compounds Chemical class 0.000 description 8
- 239000007788 liquid Substances 0.000 description 7
- 239000000376 reactant Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000001354 calcination Methods 0.000 description 6
- 150000002697 manganese compounds Chemical class 0.000 description 6
- 239000012286 potassium permanganate Substances 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 150000003222 pyridines Chemical class 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- -1 alkali metal cation Chemical class 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- YCMLQMDWSXFTIF-UHFFFAOYSA-N 2-methylbenzenesulfonimidic acid Chemical compound CC1=CC=CC=C1S(N)(=O)=O YCMLQMDWSXFTIF-UHFFFAOYSA-N 0.000 description 2
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229910013553 LiNO Inorganic materials 0.000 description 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical group [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- FBDMJGHBCPNRGF-UHFFFAOYSA-M [OH-].[Li+].[O-2].[Mn+2] Chemical compound [OH-].[Li+].[O-2].[Mn+2] FBDMJGHBCPNRGF-UHFFFAOYSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009831 deintercalation Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 229910001437 manganese ion Chemical group 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 239000012803 melt mixture Substances 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052566 spinel group Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/02—Oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/30—Three-dimensional structures
- C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US82329 | 1998-05-21 | ||
| US09/082,329 US5955052A (en) | 1998-05-21 | 1998-05-21 | Method for making lithiated manganese oxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69921229D1 DE69921229D1 (de) | 2004-11-25 |
| DE69921229T2 true DE69921229T2 (de) | 2006-03-09 |
Family
ID=22170526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69921229T Expired - Fee Related DE69921229T2 (de) | 1998-05-21 | 1999-05-14 | Verfahren zur Herstellung von Lithium enthaltendes Manganoxid |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US5955052A (enExample) |
| EP (1) | EP0959045B1 (enExample) |
| JP (1) | JP2000034127A (enExample) |
| KR (1) | KR100636446B1 (enExample) |
| CA (1) | CA2271516C (enExample) |
| DE (1) | DE69921229T2 (enExample) |
| TW (1) | TW504498B (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6482374B1 (en) * | 1999-06-16 | 2002-11-19 | Nanogram Corporation | Methods for producing lithium metal oxide particles |
| US6083475A (en) * | 1999-04-02 | 2000-07-04 | Rentech, Inc. | Method for making lithiated metal oxide |
| EP1089365B1 (en) * | 1999-10-01 | 2016-07-20 | Tosoh Corporation | Lithium manganese oxide, and process for its production and secondary cell employing it |
| JP2001273898A (ja) * | 2000-01-20 | 2001-10-05 | Japan Storage Battery Co Ltd | 非水電解質二次電池用正極活物質およびその製造方法並びにそれを使用した非水電解質二次電池 |
| US6783893B2 (en) * | 2001-11-19 | 2004-08-31 | The Gillette Company | Alkaline battery |
| US6759167B2 (en) * | 2001-11-19 | 2004-07-06 | The Gillette Company | Primary lithium electrochemical cell |
| US8137842B2 (en) * | 2004-01-22 | 2012-03-20 | The Gillette Company | Battery cathodes |
| KR100912095B1 (ko) | 2006-11-20 | 2009-08-13 | 한국지질자원연구원 | 중공사막 필터를 이용한 이온 교환형 리튬 흡착제 및 그의제조 방법 |
| US20080119350A1 (en) * | 2006-11-20 | 2008-05-22 | Korea Institute Of Geosciences And Mineral Resources | Ion exchange type lithium adsorbent using filter and method for preparing the same |
| JP5014218B2 (ja) * | 2007-03-22 | 2012-08-29 | 三洋電機株式会社 | 非水電解質二次電池 |
| US8137761B2 (en) * | 2008-06-13 | 2012-03-20 | Caterpillar Inc. | Method of coating and induction heating a component |
| JP2010108912A (ja) * | 2008-09-30 | 2010-05-13 | Sanyo Electric Co Ltd | 非水電解質二次電池、その電池に用いられる正極活物質、及び、その正極活物質の製造方法 |
| US8142933B2 (en) * | 2009-09-30 | 2012-03-27 | Conocophillips Company | Anode material for high power lithium ion batteries |
| US8303840B2 (en) * | 2010-03-12 | 2012-11-06 | The Gillette Company | Acid-treated manganese dioxide and methods of making thereof |
| US20110219607A1 (en) | 2010-03-12 | 2011-09-15 | Nanjundaswamy Kirakodu S | Cathode active materials and method of making thereof |
| US8298706B2 (en) * | 2010-03-12 | 2012-10-30 | The Gillette Company | Primary alkaline battery |
| US20110223477A1 (en) * | 2010-03-12 | 2011-09-15 | Nelson Jennifer A | Alkaline battery including lambda-manganese dioxide and method of making thereof |
| CN102070199B (zh) * | 2010-11-18 | 2012-09-05 | 清华大学 | 微米框状锰系锂离子电池阴极电极材料的制备方法 |
| US8703336B2 (en) | 2012-03-21 | 2014-04-22 | The Gillette Company | Metal-doped nickel oxide active materials |
| US9570741B2 (en) | 2012-03-21 | 2017-02-14 | Duracell U.S. Operations, Inc. | Metal-doped nickel oxide active materials |
| US9028564B2 (en) | 2012-03-21 | 2015-05-12 | The Gillette Company | Methods of making metal-doped nickel oxide active materials |
| WO2015049796A1 (ja) * | 2013-10-04 | 2015-04-09 | 日産自動車株式会社 | 非水電解質二次電池用正極活物質およびその製造方法 |
| US9793542B2 (en) | 2014-03-28 | 2017-10-17 | Duracell U.S. Operations, Inc. | Beta-delithiated layered nickel oxide electrochemically active cathode material and a battery including said material |
| JP7105802B2 (ja) | 2017-05-09 | 2022-07-25 | デュラセル、ユーエス、オペレーションズ、インコーポレーテッド | ベータ脱リチウム化層状酸化ニッケルの電気化学的に活性なカソード材料を含む電池 |
| CN107492648B (zh) * | 2017-08-18 | 2019-12-27 | 湖北文理学院 | 棉花基碳纤维/MnO/C材料、制备方法及应用 |
| CN112563564B (zh) * | 2020-11-13 | 2021-11-09 | 上海空间电源研究所 | 一种制备钠离子固体电解质的软化学合成方法 |
| KR102492040B1 (ko) * | 2021-01-08 | 2023-01-27 | 고려대학교 산학협력단 | 양극 활물질 제조 방법 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4312930A (en) * | 1978-09-29 | 1982-01-26 | Union Carbide Corporation | MnO2 Derived from LiMn2 O4 |
| US4246253A (en) * | 1978-09-29 | 1981-01-20 | Union Carbide Corporation | MnO2 derived from LiMn2 O4 |
| US4590059A (en) * | 1983-09-30 | 1986-05-20 | Union Carbide Corporation | Process for the production of manganese dioxide |
| JPH0746607B2 (ja) * | 1987-01-29 | 1995-05-17 | 三洋電機株式会社 | 非水系二次電池 |
| GB2221213B (en) * | 1988-07-12 | 1991-09-04 | Csir | Synthesizing lithium manganese oxide |
| FR2644295A1 (fr) * | 1989-03-09 | 1990-09-14 | Accumulateurs Fixes | Generateur electrochimique rechargeable a anode de lithium |
| US5153081A (en) * | 1989-07-28 | 1992-10-06 | Csir | Lithium manganese oxide compound |
| FR2659075B1 (fr) * | 1990-03-01 | 1992-05-29 | France Etat Armement | Procede de preparation d'oxydes de manganese par voie sol-gel. |
| US5135732A (en) * | 1991-04-23 | 1992-08-04 | Bell Communications Research, Inc. | Method for preparation of LiMn2 O4 intercalation compounds and use thereof in secondary lithium batteries |
| US5211933A (en) * | 1991-04-23 | 1993-05-18 | Bell Communications Research, Inc. | Method for preparation of LiCoO2 intercalation compound for use in secondary lithium batteries |
| CA2096264A1 (en) * | 1993-05-14 | 1994-11-15 | Jeffrey Raymond Dahn | Novel method for preparing solid solution materials for secondary non-aqueous batteries |
| US5506077A (en) * | 1993-06-14 | 1996-04-09 | Koksbang; Rene | Manganese oxide cathode active material |
| FR2707426B1 (fr) * | 1993-07-09 | 1995-08-18 | Accumulateurs Fixes | Générateur électrochimique rechargeable au lithium et son procédé de réalisation. |
| US5478672A (en) * | 1993-12-24 | 1995-12-26 | Sharp Kabushiki Kaisha | Nonaqueous secondary battery, positive-electrode active material |
| US5558961A (en) * | 1994-06-13 | 1996-09-24 | Regents, University Of California | Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material |
| US5766569A (en) * | 1995-09-07 | 1998-06-16 | Kerr-Mcgee Chemical Corporation | Lithium manganese oxide compound and method of preparation |
| US5702679A (en) * | 1995-10-06 | 1997-12-30 | Kerr-Mcgee Chemical Corp. | Method of preparing Li1+X- Mn2-X O4 for use as secondary battery |
| US5604057A (en) * | 1995-11-27 | 1997-02-18 | General Motors Corporation | Secondary cell having a lithium intercolating manganese oxide |
| US5605773A (en) * | 1995-12-06 | 1997-02-25 | Kerr-Mcgee Corporation | Lithium manganese oxide compound and method of preparation |
| GB9600772D0 (en) | 1996-01-15 | 1996-03-20 | Univ St Andrews | Improvements in and relating to electrochemical cells |
| US5753202A (en) * | 1996-04-08 | 1998-05-19 | Duracell Inc. | Method of preparation of lithium manganese oxide spinel |
| US5770018A (en) * | 1996-04-10 | 1998-06-23 | Valence Technology, Inc. | Method for preparing lithium manganese oxide compounds |
| US5976489A (en) * | 1996-04-10 | 1999-11-02 | Valence Technology, Inc. | Method for preparing lithium manganese oxide compounds |
| US5759510A (en) * | 1996-10-03 | 1998-06-02 | Carus Chemical Company | Lithiated manganese oxide |
| US5824285A (en) * | 1996-10-23 | 1998-10-20 | Valence Technology, Inc. | Method of making lithium manganese oxide compounds |
| US6048645A (en) * | 1997-08-21 | 2000-04-11 | Valence Technology, Inc. | Method of preparing lithium ion electrochemical cells |
-
1998
- 1998-05-21 US US09/082,329 patent/US5955052A/en not_active Expired - Fee Related
-
1999
- 1999-05-12 CA CA002271516A patent/CA2271516C/en not_active Expired - Fee Related
- 1999-05-13 KR KR1019990017214A patent/KR100636446B1/ko not_active Expired - Fee Related
- 1999-05-14 US US09/312,033 patent/US6207129B1/en not_active Expired - Fee Related
- 1999-05-14 JP JP11134516A patent/JP2000034127A/ja active Pending
- 1999-05-14 DE DE69921229T patent/DE69921229T2/de not_active Expired - Fee Related
- 1999-05-14 EP EP99108652A patent/EP0959045B1/en not_active Expired - Lifetime
- 1999-05-15 TW TW088107909A patent/TW504498B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2271516C (en) | 2005-08-23 |
| TW504498B (en) | 2002-10-01 |
| KR19990088267A (ko) | 1999-12-27 |
| HK1023979A1 (en) | 2000-09-29 |
| EP0959045B1 (en) | 2004-10-20 |
| JP2000034127A (ja) | 2000-02-02 |
| CA2271516A1 (en) | 1999-11-21 |
| US5955052A (en) | 1999-09-21 |
| KR100636446B1 (ko) | 2006-10-18 |
| US6207129B1 (en) | 2001-03-27 |
| EP0959045A3 (en) | 2000-05-10 |
| EP0959045A2 (en) | 1999-11-24 |
| DE69921229D1 (de) | 2004-11-25 |
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