KR100594559B1 - 활성화된 할로겐화알킬알루미늄을 사용한 부틸 고무의 개선된 제조 방법 - Google Patents
활성화된 할로겐화알킬알루미늄을 사용한 부틸 고무의 개선된 제조 방법 Download PDFInfo
- Publication number
- KR100594559B1 KR100594559B1 KR1019990047352A KR19990047352A KR100594559B1 KR 100594559 B1 KR100594559 B1 KR 100594559B1 KR 1019990047352 A KR1019990047352 A KR 1019990047352A KR 19990047352 A KR19990047352 A KR 19990047352A KR 100594559 B1 KR100594559 B1 KR 100594559B1
- Authority
- KR
- South Korea
- Prior art keywords
- solution
- catalyst
- reaction
- mol
- aluminoxane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
- C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002252295A CA2252295C (en) | 1998-10-30 | 1998-10-30 | Improved process for preparation of butyl rubber utilizing activated alkylaluminum halides |
| CA2,252,295 | 1998-10-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20000029399A KR20000029399A (ko) | 2000-05-25 |
| KR100594559B1 true KR100594559B1 (ko) | 2006-06-28 |
Family
ID=4162974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019990047352A Expired - Fee Related KR100594559B1 (ko) | 1998-10-30 | 1999-10-29 | 활성화된 할로겐화알킬알루미늄을 사용한 부틸 고무의 개선된 제조 방법 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6403747B2 (enExample) |
| EP (1) | EP0997481B1 (enExample) |
| JP (2) | JP2000136207A (enExample) |
| KR (1) | KR100594559B1 (enExample) |
| CN (1) | CN1117774C (enExample) |
| CA (1) | CA2252295C (enExample) |
| DE (1) | DE69936831T2 (enExample) |
| RU (1) | RU2242482C2 (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2252295C (en) * | 1998-10-30 | 2007-07-17 | Bayer Inc. | Improved process for preparation of butyl rubber utilizing activated alkylaluminum halides |
| CA2308257A1 (en) * | 2000-05-05 | 2001-11-05 | Adam A. Gronowski | Process for preparation of butyl rubber having broad molecular weight distribution |
| CA2329552C (en) | 2000-12-22 | 2010-04-13 | Bayer Inc. | An improved process for the preparation of butyl rubber utilizing alkylaluminum dihalides and aluminoxanes |
| CA2360611C (en) * | 2001-10-30 | 2010-08-17 | Bayer Inc. | Transition metal-free initiator for the preparation of isobutylene-based polymers |
| CA2390046A1 (en) * | 2002-06-28 | 2003-12-28 | Bayer Inc. | Method for improving the processability of butyl polymers |
| CA2406432C (en) * | 2002-10-03 | 2011-11-29 | Bayer Inc. | Adhesive compounds of butyl-type rubber |
| JP5227490B2 (ja) * | 2004-08-25 | 2013-07-03 | Jx日鉱日石エネルギー株式会社 | オレフィン重合体の製造方法 |
| CN101602823B (zh) * | 2008-06-13 | 2011-04-20 | 中国石油化工股份有限公司 | 一种阳离子聚合引发体系及其应用 |
| MY160791A (en) * | 2008-07-15 | 2017-03-15 | Arlanxeo Deutschland Gmbh | Common solvent process for producing high molecular weight halobutly rubber |
| RU2394844C1 (ru) * | 2009-01-11 | 2010-07-20 | Открытое акционерное общество "Нижнекамскнефтехим" | Способ получения бутилкаучука |
| EP2525987B1 (en) * | 2010-01-20 | 2016-08-24 | LANXESS International S.A. | Common solvent process for producing high molecular weight halogenated rubber |
| MY159846A (en) | 2010-01-20 | 2017-02-15 | Lanxess Int Sa | Common solvent process for producing high molecular weight brominated rubber |
| PL2526128T3 (pl) * | 2010-01-20 | 2017-08-31 | Arlanxeo Deutschland Gmbh | Sposób produkcji jonomerów halobutylowych |
| CN102140147B (zh) * | 2010-02-03 | 2012-10-17 | 中国石油天然气股份有限公司 | 一种催化聚合制备丁基橡胶的方法 |
| CN102875716B (zh) * | 2011-07-15 | 2014-04-02 | 中国石油天然气股份有限公司 | 一种溶液法合成丁基橡胶的方法 |
| RU2690942C2 (ru) | 2014-04-30 | 2019-06-07 | Арланксео Сингапур Пте. Лтд. | Высоконепредельная мультимодальная полиизоолефиновая композиция и способ ее получения |
| US10626201B2 (en) * | 2014-04-30 | 2020-04-21 | Arlanxeo Singapore Pte. Ltd. | Butyl rubber with new sequence distribution |
| CN106146710B (zh) * | 2015-04-22 | 2018-12-28 | 中国石油化工股份有限公司 | 一种阳离子聚合方法 |
| KR102732181B1 (ko) * | 2016-02-16 | 2024-11-19 | 바스프 에스이 | 고반응성 이소부텐 단독- 또는 공중합체의 제조 방법 |
| RU2614457C1 (ru) * | 2016-05-13 | 2017-03-28 | Публичное Акционерное Общество "Нижнекамскнефтехим" | Способ получения бутилкаучука |
| EP3301133A1 (en) | 2016-09-29 | 2018-04-04 | ARLANXEO Canada Inc. | Multi-modal polyisoolefin compositions and processes for their production |
| CN116670180A (zh) * | 2020-12-18 | 2023-08-29 | 阿朗新科新加坡私人有限公司 | 在生产不饱和异烯烃共聚物中催化剂的超声处理 |
| RU2753679C1 (ru) * | 2020-12-23 | 2021-08-19 | Публичное Акционерное Общество "Нижнекамскнефтехим" | Способ получения бутилкаучука |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3361725A (en) * | 1965-06-02 | 1968-01-02 | Exxon Research Engineering Co | Process for preparation of solution butyl rubbers using a major amount of air2x and a minor amount of airx2 as catalyst |
| US4103079A (en) * | 1975-11-26 | 1978-07-25 | Exxon Research & Engineering Co. | Halogenated organoaluminum compounds and method of preparation |
| US4171414A (en) * | 1977-08-25 | 1979-10-16 | Exxon Research & Engineering Co. | Catalyst composition for an improved polymerization process of isoolefins and multiolefins |
| KR920000187B1 (ko) * | 1987-02-11 | 1992-01-10 | 스태미카본 베. 뷔. | 에틸렌 (공)중합을 위한 촉매조성물, 그 제조방법 및 (공)중합방법 |
| KR920000187A (ko) * | 1990-02-28 | 1992-01-10 | 아오이 죠이찌 | 다중 통신 시스템 |
| US5668232A (en) * | 1995-07-10 | 1997-09-16 | Bayer Ag | Process for the production of polyisoolefins |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2772255A (en) * | 1952-12-22 | 1956-11-27 | Exxon Research Engineering Co | Polymerization process |
| US2844569A (en) | 1954-11-05 | 1958-07-22 | Exxon Research Engineering Co | Solution process for making isobutylene-diolefin synthetic rubber |
| DE2328541C2 (de) * | 1973-06-05 | 1983-09-08 | Natalja Vasiljevna Ščerbakova | Verfahren zur Herstellung von hochmolekularem Butylkautschuk |
| CA1019095A (en) * | 1973-06-25 | 1977-10-11 | Lev N. Vladykin | Method for preparing butyl rubber |
| JPS5336874B2 (enExample) * | 1973-06-29 | 1978-10-05 | ||
| SU494391A1 (ru) * | 1974-01-18 | 1975-12-05 | Институт Химии Башкирского Филиала Ан Ссср | Способ получени полиизобутилена |
| SU792901A1 (ru) * | 1978-06-05 | 1997-03-10 | В.Д. Петрова | Способ получения бутилкаучука |
| CA1238145A (en) * | 1982-09-30 | 1988-06-14 | Kenneth W. Powers | Modified lewis acid catalyzed polymerization |
| US4564647A (en) * | 1983-11-14 | 1986-01-14 | Idemitsu Kosan Company Limited | Process for the production of polyethylene compositions |
| SU1807699A1 (ru) * | 1990-04-16 | 1996-04-27 | Научно-производственное объединение "Ярсинтез" | Способ получения высокомолекулярного бутилкаучука |
| BE1008739A3 (fr) | 1994-01-12 | 1996-07-02 | Kanegafuchi Chemical Ind | Procede de preparation d'un polymere d'isobutylene. |
| CA2252295C (en) * | 1998-10-30 | 2007-07-17 | Bayer Inc. | Improved process for preparation of butyl rubber utilizing activated alkylaluminum halides |
-
1998
- 1998-10-30 CA CA002252295A patent/CA2252295C/en not_active Expired - Fee Related
-
1999
- 1999-10-19 DE DE69936831T patent/DE69936831T2/de not_active Expired - Lifetime
- 1999-10-19 EP EP99120061A patent/EP0997481B1/en not_active Expired - Lifetime
- 1999-10-21 US US09/422,524 patent/US6403747B2/en not_active Expired - Lifetime
- 1999-10-25 JP JP11302323A patent/JP2000136207A/ja active Pending
- 1999-10-29 KR KR1019990047352A patent/KR100594559B1/ko not_active Expired - Fee Related
- 1999-10-29 RU RU99122681/04A patent/RU2242482C2/ru not_active IP Right Cessation
- 1999-10-29 CN CN99123627A patent/CN1117774C/zh not_active Expired - Fee Related
-
2011
- 2011-08-22 JP JP2011180803A patent/JP5490760B2/ja not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3361725A (en) * | 1965-06-02 | 1968-01-02 | Exxon Research Engineering Co | Process for preparation of solution butyl rubbers using a major amount of air2x and a minor amount of airx2 as catalyst |
| US4103079A (en) * | 1975-11-26 | 1978-07-25 | Exxon Research & Engineering Co. | Halogenated organoaluminum compounds and method of preparation |
| US4171414A (en) * | 1977-08-25 | 1979-10-16 | Exxon Research & Engineering Co. | Catalyst composition for an improved polymerization process of isoolefins and multiolefins |
| KR920000187B1 (ko) * | 1987-02-11 | 1992-01-10 | 스태미카본 베. 뷔. | 에틸렌 (공)중합을 위한 촉매조성물, 그 제조방법 및 (공)중합방법 |
| KR920000187A (ko) * | 1990-02-28 | 1992-01-10 | 아오이 죠이찌 | 다중 통신 시스템 |
| US5668232A (en) * | 1995-07-10 | 1997-09-16 | Bayer Ag | Process for the production of polyisoolefins |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69936831T2 (de) | 2008-05-15 |
| EP0997481A1 (en) | 2000-05-03 |
| EP0997481B1 (en) | 2007-08-15 |
| US6403747B2 (en) | 2002-06-11 |
| DE69936831D1 (de) | 2007-09-27 |
| JP2000136207A (ja) | 2000-05-16 |
| JP5490760B2 (ja) | 2014-05-14 |
| CN1117774C (zh) | 2003-08-13 |
| JP2011231337A (ja) | 2011-11-17 |
| US20010041780A1 (en) | 2001-11-15 |
| CN1253141A (zh) | 2000-05-17 |
| RU2242482C2 (ru) | 2004-12-20 |
| CA2252295A1 (en) | 2000-04-30 |
| CA2252295C (en) | 2007-07-17 |
| KR20000029399A (ko) | 2000-05-25 |
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