KR100570474B1 - 6-메틸-3-헵텐-2-온의 제조방법 - Google Patents

6-메틸-3-헵텐-2-온의 제조방법 Download PDF

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Publication number
KR100570474B1
KR100570474B1 KR1020050088831A KR20050088831A KR100570474B1 KR 100570474 B1 KR100570474 B1 KR 100570474B1 KR 1020050088831 A KR1020050088831 A KR 1020050088831A KR 20050088831 A KR20050088831 A KR 20050088831A KR 100570474 B1 KR100570474 B1 KR 100570474B1
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South Korea
Prior art keywords
methyl
reaction
carbon
dimethyl
isovaleraldehyde
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KR1020050088831A
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English (en)
Korean (ko)
Inventor
요이치 기도
노리아키 구마가이
히데하루 이와사키
다카시 오니시
후유오 우에야마
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가부시키가이샤 구라레
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Priority claimed from JP19548096A external-priority patent/JP3805435B2/ja
Priority claimed from JP35221496A external-priority patent/JP3882245B2/ja
Priority claimed from KR1019970031195A external-priority patent/KR100537371B1/ko
Application filed by 가부시키가이샤 구라레 filed Critical 가부시키가이샤 구라레
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Publication of KR100570474B1 publication Critical patent/KR100570474B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/172—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with the obtention of a fully saturated alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C07C29/40—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing carbon-to-metal bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C07C29/42—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing triple carbon-to-carbon bonds, e.g. with metal-alkynes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C07C45/513—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being an etherified hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
    • C07C45/676—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton by elimination of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/73—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/203—Unsaturated compounds containing keto groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020050088831A 1996-07-05 2005-09-23 6-메틸-3-헵텐-2-온의 제조방법 KR100570474B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JPJP-P-1996-00195480 1996-07-05
JP19548096A JP3805435B2 (ja) 1996-07-05 1996-07-05 ６−メチル−３−ヘプテン−２−オンの製造方法
JPJP-P-1996-00352214 1996-12-11
JP35221496A JP3882245B2 (ja) 1996-12-11 1996-12-11 フィトン及びイソフィトールの製造方法
JPJP-P-1997-00051356 1997-03-06
JP5135697 1997-03-06
KR1019970031195A KR100537371B1 (ko) 1996-07-05 1997-07-05 6-메틸-3-헵텐-2-온및6-메틸-2-헵탄온유사체의제조방법및피톤또는이소피톨의제조방법

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1019970031195A Division KR100537371B1 (ko) 1996-07-05 1997-07-05 6-메틸-3-헵텐-2-온및6-메틸-2-헵탄온유사체의제조방법및피톤또는이소피톨의제조방법

Publications (1)

Publication Number Publication Date
KR100570474B1 true KR100570474B1 (ko) 2006-04-12

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KR1020050088831A KR100570474B1 (ko) 1996-07-05 2005-09-23 6-메틸-3-헵텐-2-온의 제조방법

Country Status (6)

Country Link
US (2) US5955636A (pt-PT)
EP (2) EP0816321B1 (pt-PT)
KR (1) KR100570474B1 (pt-PT)
CN (2) CN1125805C (pt-PT)
AT (1) ATE218527T1 (pt-PT)
DE (2) DE69731007T2 (pt-PT)

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DE19959053A1 (de) * 1999-12-07 2001-06-13 Basf Ag Verfahren zur Herstellung von Ketonen, insbesondere von 6-Methylheptan-2-on
KR20010083487A (ko) * 2000-02-15 2001-09-01 구광시 소팔콘의 제조방법
DE10044390A1 (de) * 2000-09-08 2002-03-21 Degussa Verfahren zur Herstellung von 6-Methylheptanon
DE10106186A1 (de) 2001-02-10 2002-08-14 Oxeno Olefinchemie Gmbh Verfahren zur Kondensation von Aldehyden mit Ketonen mittels Mehrphasenreaktion
DE10111071A1 (de) * 2001-03-08 2002-09-19 Degussa Verfahren zur Herstellung von Methylketonen
DE10112099A1 (de) * 2001-03-14 2002-09-19 Degussa Verbessertes Verfahren zur Herstellung von 6-Methylheptanon
DE10123066A1 (de) * 2001-05-11 2002-11-14 Basf Ag Verfahren zur Herstellung von höheren alpha,beta-ungesättigten Alkoholen
DE10149349A1 (de) * 2001-10-06 2003-04-17 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 6-Methylheptan-2-on und dessen Verwendung
ITMI20012267A1 (it) * 2001-10-29 2003-04-29 Chemi Spa Preparazione ed uso di un catalizzatore eterogeneo per l'idrogenerazione di un doppio legame di un composto carbonilico b-insaturo
EP1327620A1 (en) * 2002-01-14 2003-07-16 Aventis Animal Nutrition S.A. Process for the preparation of phytone
US6979751B2 (en) * 2002-12-23 2005-12-27 Eastman Chemical Company Processes for the preparation of higher molecular weight ketones
US6960694B2 (en) * 2003-07-01 2005-11-01 Eastman Chemical Company Processes for preparing β-hydroxy-ketones and α,β-unsaturated ketones
US7071361B2 (en) 2004-06-25 2006-07-04 Fastman Chemical Company Processes for the preparation of high molecular weight saturated ketones
US7897822B2 (en) 2005-12-20 2011-03-01 Dsm Ip Assets B.V. Process for ubiquinone intermediates
TWI492755B (zh) * 2009-12-30 2015-07-21 Metal Ind Res & Dev Ct 抗糖尿病及抗新陳代謝疾病之香椿超臨界萃取物、製備方法及用途
US8546621B2 (en) * 2010-08-24 2013-10-01 Dsm Ip Assets B.V. Process for the manufacture of 3,7-dimethyl-1-octen-3-ol
ES2678472T3 (es) * 2010-08-24 2018-08-13 Dsm Ip Assets B.V. Procedimiento para la fabricación de 3,7-dimetil-1-octen-3-ol
CN102821771B (zh) * 2010-12-28 2015-01-14 高雄医学大学 抗糖尿病及抗新陈代谢疾病的香椿超临界萃取物、制备方法及用途
US9611200B2 (en) 2012-12-18 2017-04-04 Dsm Ip Assets B.V. (6R,10R)-6,10,14-trimetylpentadecan-2-one prepared from 6,10,14 trimetylpentadeca-5,9,13-trien-2-one or 6,10,14-trimetylpentadeca-5,9-dien-2-one
ES2746749T3 (es) * 2012-12-18 2020-03-06 Dsm Ip Assets Bv (6R,10R)-6,10,14-Trimetilpentadecan-2-ona preparada a partir de 6,10-dimetilundec-5-en-2-ona o 6,10-dimetilundeca-5,9-dien-2-ona
CN104854068A (zh) * 2012-12-18 2015-08-19 帝斯曼知识产权资产管理有限公司 由(r)-6,10-14-三甲基十五碳-5-烯-2-酮制备的(6r,10r)-6,10,14-三甲基十五烷-2-酮
CN105037120B (zh) * 2015-05-25 2016-09-21 吉林北沙制药有限公司 一种甲基庚酮的新型合成方法
WO2017098050A1 (en) * 2015-12-11 2017-06-15 Dsm Ip Assets B.V. Process for the manufacture of 6,10,14-trimethylpentadecan-2-one, isophytol and alpha-tocopherol
CN105399613B (zh) * 2015-12-31 2018-09-25 山东新和成药业有限公司 一种香料6-甲基-3-庚烯-2-酮的制备方法
CN107673959B (zh) * 2017-10-27 2019-10-11 西南化工研究设计院有限公司 一种制备甲基庚烯酮的方法和系统
CN109651118A (zh) * 2018-12-25 2019-04-19 万华化学集团股份有限公司 一种植酮的制备方法
CN111995512B (zh) * 2019-05-27 2023-11-10 四川海思科制药有限公司 一种全消旋植物醇组合物及其制备方法和应用
CN111018672B (zh) * 2019-12-09 2023-01-13 万华化学集团股份有限公司 一种制备芳樟醇的方法

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JPS4925251A (pt-PT) * 1972-06-29 1974-03-06
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IT1085879B (it) * 1976-04-08 1985-05-28 Basf Ag Processo per la preparazione di chetoni superiori
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ATE181909T1 (de) * 1995-04-04 1999-07-15 Kuraray Co Verfahren zur herstellung von 6-methylheptan-2-on

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Publication number Publication date
CN1125805C (zh) 2003-10-29
DE69731007T2 (de) 2006-02-23
CN1178784A (zh) 1998-04-15
EP0816321B1 (en) 2002-06-05
EP0816321A1 (en) 1998-01-07
ATE218527T1 (de) 2002-06-15
EP1122236A3 (en) 2001-08-16
CN1250507C (zh) 2006-04-12
US6232506B1 (en) 2001-05-15
US5955636A (en) 1999-09-21
EP1122236A2 (en) 2001-08-08
DE69712984T2 (de) 2003-01-16
DE69731007D1 (de) 2004-11-04
DE69712984D1 (de) 2002-07-11
CN1393435A (zh) 2003-01-29
EP1122236B1 (en) 2004-09-29

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