JPWO2014141694A1 - 光触媒体とそれを用いた光触媒分散液、光触媒塗料、光触媒膜および製品 - Google Patents
光触媒体とそれを用いた光触媒分散液、光触媒塗料、光触媒膜および製品 Download PDFInfo
- Publication number
- JPWO2014141694A1 JPWO2014141694A1 JP2015505294A JP2015505294A JPWO2014141694A1 JP WO2014141694 A1 JPWO2014141694 A1 JP WO2014141694A1 JP 2015505294 A JP2015505294 A JP 2015505294A JP 2015505294 A JP2015505294 A JP 2015505294A JP WO2014141694 A1 JPWO2014141694 A1 JP WO2014141694A1
- Authority
- JP
- Japan
- Prior art keywords
- photocatalyst
- tungsten oxide
- tungsten
- mass
- fine particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 195
- 239000006185 dispersion Substances 0.000 title claims description 91
- 239000007788 liquid Substances 0.000 title claims description 48
- 239000003973 paint Substances 0.000 title description 15
- 229910001930 tungsten oxide Inorganic materials 0.000 claims abstract description 119
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims abstract description 117
- 239000010419 fine particle Substances 0.000 claims abstract description 89
- 238000001069 Raman spectroscopy Methods 0.000 claims abstract description 16
- 238000001237 Raman spectrum Methods 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims description 84
- 239000002184 metal Substances 0.000 claims description 70
- 230000001699 photocatalysis Effects 0.000 claims description 61
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 39
- 239000002612 dispersion medium Substances 0.000 claims description 21
- 229910052721 tungsten Inorganic materials 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 20
- 239000010937 tungsten Substances 0.000 claims description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 16
- 239000011230 binding agent Substances 0.000 claims description 15
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 13
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 13
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910044991 metal oxide Inorganic materials 0.000 claims description 8
- 150000004706 metal oxides Chemical class 0.000 claims description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 7
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 229910001925 ruthenium oxide Inorganic materials 0.000 claims description 6
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- VVRQVWSVLMGPRN-UHFFFAOYSA-N oxotungsten Chemical group [W]=O VVRQVWSVLMGPRN-UHFFFAOYSA-N 0.000 abstract description 36
- 239000007789 gas Substances 0.000 description 78
- 239000000843 powder Substances 0.000 description 64
- 239000010408 film Substances 0.000 description 51
- 239000013078 crystal Substances 0.000 description 37
- 238000000034 method Methods 0.000 description 35
- 239000002994 raw material Substances 0.000 description 34
- 238000000354 decomposition reaction Methods 0.000 description 33
- 150000003658 tungsten compounds Chemical class 0.000 description 29
- 229910052760 oxygen Inorganic materials 0.000 description 27
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 26
- 239000001301 oxygen Substances 0.000 description 26
- 239000000654 additive Substances 0.000 description 25
- 230000000996 additive effect Effects 0.000 description 25
- 150000001875 compounds Chemical class 0.000 description 19
- 238000010438 heat treatment Methods 0.000 description 19
- 239000002131 composite material Substances 0.000 description 18
- 238000005092 sublimation method Methods 0.000 description 17
- 238000011282 treatment Methods 0.000 description 17
- 239000000835 fiber Substances 0.000 description 16
- 239000000047 product Substances 0.000 description 16
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 14
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 14
- 238000000859 sublimation Methods 0.000 description 12
- 230000008022 sublimation Effects 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- 238000002156 mixing Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 230000007423 decrease Effects 0.000 description 8
- 230000007547 defect Effects 0.000 description 8
- 238000010894 electron beam technology Methods 0.000 description 8
- 239000002657 fibrous material Substances 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 239000011164 primary particle Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 230000000844 anti-bacterial effect Effects 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000012159 carrier gas Substances 0.000 description 6
- 238000009616 inductively coupled plasma Methods 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 6
- 238000010891 electric arc Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- -1 lower oxides Chemical compound 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 239000004925 Acrylic resin Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 230000001747 exhibiting effect Effects 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 230000001678 irradiating effect Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 239000004566 building material Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000012495 reaction gas Substances 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000010191 image analysis Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- DZKDPOPGYFUOGI-UHFFFAOYSA-N tungsten(iv) oxide Chemical compound O=[W]=O DZKDPOPGYFUOGI-UHFFFAOYSA-N 0.000 description 2
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000132092 Aster Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000047875 Pica hudsonia Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical class [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229940030980 inova Drugs 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 238000013532 laser treatment Methods 0.000 description 1
- 230000004298 light response Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8678—Removing components of undefined structure
- B01D53/8687—Organic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6527—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1023—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1026—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/104—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
- B01D2255/2065—Cerium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20707—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20715—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/2073—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20753—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20776—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/209—Other metals
- B01D2255/2092—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/80—Type of catalytic reaction
- B01D2255/802—Photocatalytic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/92—Dimensions
- B01D2255/9202—Linear dimensions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/90—Odorous compounds not provided for in groups B01D2257/00 - B01D2257/708
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4508—Gas separation or purification devices adapted for specific applications for cleaning air in buildings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/80—Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
- B01D2259/802—Visible light
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Paints Or Removers (AREA)
Abstract
Description
実施形態の光触媒体は、酸化タングステンを5〜100質量%の範囲で含有する酸化タングステン基微粒子を具備している。光触媒体を構成する酸化タングステン基微粒子としては、酸化タングステンの単独微粒子、または酸化タングステンと他の金属元素との混合体や複合体等の微粒子が挙げられる。実施形態の光触媒体において、酸化タングステンの含有量は5〜100質量%の範囲である。酸化タングステンの含有量が5質量%未満であると、酸化タングステン微粒子に基づく可視光応答型光触媒性能を十分に得ることができない。酸化タングステンの含有量は45質量%以上であることが好ましい。
次に、実施形態の光触媒分散液および光触媒塗料、さらにそれらを用いて形成した光触媒膜および光触媒膜を具備する製品について説明する。実施形態の光触媒分散液は、水系分散媒中に実施形態の光触媒体を粒子濃度が0.001〜50質量%の範囲となるように分散させたものである。粒子濃度が0.001質量%未満であると光触媒体の含有量が不足し、所望の性能を得ることができない。粒子濃度が50質量%を超えると、膜化した際に光触媒体の微粒子が近接しすぎた状態で存在し、光触媒性能を十分に発揮させるための表面積を得ることができない。このため、十分な性能を発揮させることができないだけでなく、必要以上に光触媒体を含有するためにコストの増加を招くことになる。光触媒体の濃度は0.01〜20質量%の範囲であることがより好ましい。
原料粉末として平均粒子径が0.5μmの三酸化タングステン粉末を用意した。この原料粉末をキャリアガス(Ar)と共にRFプラズマに噴霧し、さらに反応ガスとしてアルゴンを40L/min、酸素を40L/minの流量で流した。このようにして、原料粉末を昇華させながら酸化反応させる昇華工程を経て、酸化タングステン粉末を作製した。熱処理していない酸化タングステン粉末を試料A(比較例)とした。上記した酸化タングステン粉末を、大気中にて300℃、500℃、575℃、600℃の各温度で熱処理することによって、試料B〜E(実施例)を調製した。また、同一の酸化タングステン粉末を、大気中にて1000℃の温度で熱処理することによって、試料F(比較例)を調製した。熱処理時間はそれぞれ1時間とした。また、試料B〜Eを作製するにあたって、熱処理時の昇温は所定温度に急熱し、1時間経過後に炉から取り出して室温で降温させた。
実施例1および比較例1と同一の試料A〜Fの酸化タングステン粉末を用いて、以下のように光触媒分散液を作製した。まず、酸化タングステン粉末をその濃度が10質量%となるように水中に分散させた。酸化タングステン粉末を水中に分散させた分散液と、平均一次粒子径(D50)が70nmの酸化ジルコニウム粉末を水中に分散させた水系分散液とを、酸化タングステンと酸化ジルコニウムとの合計量に対する酸化ジルコニウムの割合が33質量%となるように混合した。混合分散液のpHが6.5〜5.5の範囲となるように、混合分散液を塩酸とアンモニアで調整した。分散処理はビーズミルを用いて実施した。このようにして得た光触媒分散液の粒子濃度は10質量%であった。
実施例1および比較例1と同一の試料A〜Fの酸化タングステン粉末を用いて、以下のように光触媒分散液を作製した。酸化タングステン粉末をその濃度が10質量%となるように水中に分散させた。酸化タングステン粉末を水中に分散させた分散液と、塩化ルテニウム溶液とを、酸化タングステンと酸化ルテニウムとの合計量に対する酸化ルテニウムの割合が0.02質量%となるように混合した。混合液にアンモニアを滴下してpHを7に調整した。さらに、混合液に平均粒子径(D50)が70nmの酸化ジルコニウム粉末を水中に分散させた水系分散液を滴下して、pHを6.5〜5.5の範囲に調整した。分散液における酸化タングステンと酸化ルテニウムと酸化ジルコニウムとの混合比は、これらの合計量に対して酸化ルテニウムの割合が約0.017質量%、酸化ジルコニウムの割合が約33質量%である。得られた得た光触媒分散液の粒子濃度は13質量%であった。
実施例1および比較例1と同一の試料A〜Fの酸化タングステン粉末を用いて、以下のように光触媒分散液を作製した。酸化タングステン粉末をその濃度が10質量%となるように水中に分散させた。酸化タングステン粉末を水中に分散させた分散液に、平均粒子径が2nmの白金粒子を、酸化タングステンと白金との合計量に対する白金の割合が0.02質量%となるように混合して光触媒分散液を作製した。
Claims (15)
- 酸化タングステンを5質量%以上100質量%以下の範囲で含有する酸化タングステン基微粒子を具備する光触媒体であって、
前記光触媒体のラマン分光法によるラマンスペクトルにおいて、800cm−1以上810cm−1以下の範囲に観察されるピークの強度Yに対する920cm−1以上950cm−1以下の範囲に観察されるピークの強度Xの比(X/Y)が0を超えて0.04以下である光触媒体。 - 前記酸化タングステン基微粒子は、タングステンを除く金属元素を0.001質量%以上50質量%以下の範囲で含有する、請求項1に記載の光触媒体。
- 前記金属元素は、チタン、ジルコニウム、マンガン、鉄、ルテニウム、ニッケル、パラジウム、白金、銅、銀、セリウム、およびアルミニウムから群より選ばれる少なくとも1つである、請求項2に記載の光触媒体。
- 前記金属元素の含有量が0.005質量%以上10質量%以下の範囲である、請求項3に記載の光触媒体。
- 前記酸化タングステン基微粒子は、酸化タングステンを除く金属酸化物を0.01質量%以上70質量%以下の範囲で含有する、請求項1に記載の光触媒体。
- 前記金属酸化物は、酸化ジルコニウム、酸化チタン、および酸化ルテニウムからなる群より選ばれる少なくとも1つである、請求項5に記載の光触媒体。
- 前記酸化タングステン基微粒子は、1nm以上30μm以下の平均粒子径(D50)を有する、請求項1に記載の光触媒体。
- 分散媒と、前記分散媒中に0.001質量%以上50質量%以下の範囲で分散された、請求項1に記載の光触媒体とを具備する光触媒分散液。
- 前記分散媒は水およびアルコールから選ばれる少なくとも1つである、請求項8に記載の光触媒分散液。
- 前記光触媒分散液のpHが1以上9以下である、請求項9に記載の光触媒分散液。
- 請求項8に記載の光触媒分散液と、無機バインダおよび有機バインダから選ばれる少なくとも1つのバインダ成分とを含有する光触媒塗料。
- 請求項8に記載の光触媒分散液を基材に塗布することにより形成された光触媒膜。
- 請求項11に記載の光触媒塗料を基材に塗布することにより形成された光触媒膜。
- 請求項12に記載の光触媒膜を具備する製品。
- 請求項13に記載の光触媒膜を具備する製品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013049315 | 2013-03-12 | ||
JP2013049315 | 2013-03-12 | ||
PCT/JP2014/001369 WO2014141694A1 (ja) | 2013-03-12 | 2014-03-11 | 光触媒体とそれを用いた光触媒分散液、光触媒塗料、光触媒膜および製品 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018111760A Division JP6503116B2 (ja) | 2013-03-12 | 2018-06-12 | 光触媒部材 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPWO2014141694A1 true JPWO2014141694A1 (ja) | 2017-02-16 |
JP6356661B2 JP6356661B2 (ja) | 2018-07-11 |
Family
ID=51536373
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015505294A Active JP6356661B2 (ja) | 2013-03-12 | 2014-03-11 | 光触媒体とそれを用いた光触媒分散液、光触媒塗料、光触媒膜および製品 |
JP2018111760A Active JP6503116B2 (ja) | 2013-03-12 | 2018-06-12 | 光触媒部材 |
JP2019051827A Active JP6721742B2 (ja) | 2013-03-12 | 2019-03-19 | 内装材の製造方法 |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018111760A Active JP6503116B2 (ja) | 2013-03-12 | 2018-06-12 | 光触媒部材 |
JP2019051827A Active JP6721742B2 (ja) | 2013-03-12 | 2019-03-19 | 内装材の製造方法 |
Country Status (3)
Country | Link |
---|---|
JP (3) | JP6356661B2 (ja) |
CN (2) | CN105451882B (ja) |
WO (1) | WO2014141694A1 (ja) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3513738B1 (en) | 2016-09-16 | 2023-07-12 | FUJIFILM Corporation | Ultrasonic diagnostic device and method for controlling ultrasonic diagnostic device |
CN106902808B (zh) * | 2017-03-31 | 2020-02-11 | 北京宇极科技发展有限公司 | 高活性钨基催化剂、制备方法及用途 |
JP7098607B2 (ja) * | 2017-04-27 | 2022-07-11 | 株式会社東芝 | ナノ金属化合物粒子およびそれを用いた塗料並びに膜、膜の製造方法、ナノ金属化合物粒子の製造方法 |
CN106975352A (zh) * | 2017-05-03 | 2017-07-25 | 宁夏大学 | 一种可见光光催化剂wo3及wo3复合涂料与制备和应用 |
CN107469869B (zh) * | 2017-08-23 | 2020-06-23 | 浙江理工大学 | 一种光催化纤维网的制备方法 |
JP7106268B2 (ja) * | 2017-12-14 | 2022-07-26 | 株式会社東芝 | 光触媒付基材およびその製造方法及び光触媒装置 |
JP6989421B2 (ja) * | 2018-03-13 | 2022-01-05 | 株式会社東芝 | 光触媒分散液、光触媒複合材料および光触媒装置 |
CN110270352A (zh) * | 2018-03-15 | 2019-09-24 | 陈锋 | 一种复合光触媒及其制备方法 |
JP7115900B2 (ja) * | 2018-04-26 | 2022-08-09 | シャープ株式会社 | 光触媒層、光触媒体、及び光触媒体の製造方法 |
JP7096743B2 (ja) * | 2018-09-13 | 2022-07-06 | 株式会社東芝 | 光触媒複合材料、光触媒複合材料の製造方法および光触媒装置 |
KR102021420B1 (ko) | 2019-02-27 | 2019-09-16 | 우태영 | 광촉매 프리코트를 이용한 유리 및 알루미늄 구조체 공기필터 및 이의 제조방법 |
WO2020180533A1 (en) | 2019-03-01 | 2020-09-10 | Corning Incorporated | Method of phase quality control for glass ceramics in manufacturing |
CN111715301B (zh) | 2019-03-19 | 2023-09-08 | 株式会社东芝 | 光催化剂制品 |
JP7328165B2 (ja) * | 2020-03-11 | 2023-08-16 | シャープ株式会社 | 光触媒分散液、光触媒被覆部材、光触媒フィルタ及び光触媒層の形成方法 |
KR102455126B1 (ko) * | 2020-12-10 | 2022-10-17 | 주식회사 에어크린 | 향균성을 갖는 광촉매 복합 입자, 이를 이용한 덕트, 및 이들의 제조 방법 |
JP2022098091A (ja) * | 2020-12-21 | 2022-07-01 | シャープ株式会社 | フィルム |
CN113769549A (zh) * | 2021-08-16 | 2021-12-10 | 创钛中科广至材料(苏州)有限公司 | 一种除醛剂 |
CN113861959A (zh) * | 2021-11-10 | 2021-12-31 | 天津大学 | 一种银-铜-氧化钨的光致变色复合纳米材料及制备方法 |
WO2023210240A1 (ja) * | 2022-04-29 | 2023-11-02 | 国立大学法人東海国立大学機構 | 光触媒支持体の製造方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009131790A (ja) * | 2007-11-30 | 2009-06-18 | Toshiba Lighting & Technology Corp | 可視光応答光触媒 |
WO2009096177A1 (ja) * | 2008-01-28 | 2009-08-06 | Kabushiki Kaisha Toshiba | 可視光応答型光触媒粉末とそれを用いた可視光応答型の光触媒材料、光触媒塗料、光触媒製品 |
JP2012120967A (ja) * | 2010-12-07 | 2012-06-28 | Nissan Motor Co Ltd | 可視光応答型光触媒およびこれを含む親水性部材ならびにこれらの製造方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU8748498A (en) * | 1997-12-10 | 1999-06-28 | Toto Ltd. | Photocatalyst composition, substance containing photocatalyst, and material functioning as photocatalyst and process for producing the same |
JP4393963B2 (ja) * | 2004-03-17 | 2010-01-06 | 住友化学株式会社 | 光触媒体コーティング液 |
JP5374747B2 (ja) * | 2006-02-01 | 2013-12-25 | 東芝マテリアル株式会社 | 光触媒材料およびそれを用いた光触媒組成物並びに光触媒製品 |
CN101011658A (zh) * | 2006-02-01 | 2007-08-08 | 东芝照明技术株式会社 | 光触媒材料以及光触媒材料的制造方法 |
JP5306181B2 (ja) * | 2007-03-23 | 2013-10-02 | 株式会社東芝 | 光触媒用三酸化タングステン粉末の製造方法、光触媒用三酸化タングステン粉末および光触媒製品 |
JP5683812B2 (ja) * | 2007-09-05 | 2015-03-11 | 株式会社東芝 | 可視光応答型光触媒粉末の製造方法 |
WO2009110234A1 (ja) * | 2008-03-04 | 2009-09-11 | 株式会社 東芝 | 水系分散液とそれを用いた塗料、膜および製品 |
JP2011005475A (ja) * | 2009-05-29 | 2011-01-13 | Sumitomo Chemical Co Ltd | 光触媒体分散液およびそれを用いた光触媒機能製品 |
JP2012250134A (ja) * | 2009-09-30 | 2012-12-20 | Toto Ltd | 光触媒塗装体およびそのための光触媒コーティング液 |
CN102947001B (zh) * | 2010-03-12 | 2014-12-03 | 株式会社小原 | 光催化剂、浆液状混合物、成型材料及涂料、涂膜形成材料、烧结体、玻璃陶瓷复合体、玻璃、建材及净化材料 |
CN102268198B (zh) * | 2011-05-26 | 2013-02-27 | 上海梅思泰克生态科技有限公司 | 纳米贵金属改性的氧化钨光触媒涂料及其制备方法 |
-
2014
- 2014-03-11 CN CN201480013558.1A patent/CN105451882B/zh active Active
- 2014-03-11 WO PCT/JP2014/001369 patent/WO2014141694A1/ja active Application Filing
- 2014-03-11 JP JP2015505294A patent/JP6356661B2/ja active Active
- 2014-03-11 CN CN201810153100.6A patent/CN108187662B/zh active Active
-
2018
- 2018-06-12 JP JP2018111760A patent/JP6503116B2/ja active Active
-
2019
- 2019-03-19 JP JP2019051827A patent/JP6721742B2/ja active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009131790A (ja) * | 2007-11-30 | 2009-06-18 | Toshiba Lighting & Technology Corp | 可視光応答光触媒 |
WO2009096177A1 (ja) * | 2008-01-28 | 2009-08-06 | Kabushiki Kaisha Toshiba | 可視光応答型光触媒粉末とそれを用いた可視光応答型の光触媒材料、光触媒塗料、光触媒製品 |
JP2012120967A (ja) * | 2010-12-07 | 2012-06-28 | Nissan Motor Co Ltd | 可視光応答型光触媒およびこれを含む親水性部材ならびにこれらの製造方法 |
Also Published As
Publication number | Publication date |
---|---|
CN105451882B (zh) | 2018-03-20 |
JP2019162621A (ja) | 2019-09-26 |
CN108187662A (zh) | 2018-06-22 |
CN108187662B (zh) | 2020-12-11 |
JP2018171620A (ja) | 2018-11-08 |
JP6503116B2 (ja) | 2019-04-17 |
JP6721742B2 (ja) | 2020-07-15 |
JP6356661B2 (ja) | 2018-07-11 |
WO2014141694A1 (ja) | 2014-09-18 |
CN105451882A (zh) | 2016-03-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6721742B2 (ja) | 内装材の製造方法 | |
US10335771B2 (en) | Aqueous dispersion and coating material using the same, and photocatalytic film and product | |
JP5985556B2 (ja) | 水系分散液を用いた膜の製造方法 | |
JP5959675B2 (ja) | 抗菌性部材 | |
US10327445B2 (en) | Antiviral material, antiviral film, antiviral fiber, and antiviral product | |
JP5818943B2 (ja) | 室内用建材 | |
JP5546768B2 (ja) | 可視光応答型光触媒粉末とそれを用いた可視光応答型の光触媒材料、光触媒塗料、光触媒製品 | |
JP5546767B2 (ja) | 可視光応答型光触媒粉末とそれを用いた可視光応答型の光触媒材料、光触媒塗料、光触媒製品 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20170112 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180116 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180314 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20180515 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20180614 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6356661 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |