JPWO2010001972A1 - 難燃性原着ポリエステル繊維、これを用いた難燃材および難燃性原着ポリエステル繊維の製造方法 - Google Patents
難燃性原着ポリエステル繊維、これを用いた難燃材および難燃性原着ポリエステル繊維の製造方法 Download PDFInfo
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- JPWO2010001972A1 JPWO2010001972A1 JP2010519114A JP2010519114A JPWO2010001972A1 JP WO2010001972 A1 JPWO2010001972 A1 JP WO2010001972A1 JP 2010519114 A JP2010519114 A JP 2010519114A JP 2010519114 A JP2010519114 A JP 2010519114A JP WO2010001972 A1 JPWO2010001972 A1 JP WO2010001972A1
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Classifications
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- D—TEXTILES; PAPER
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- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/06—Dyes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
Description
これらのホスファゼン類の中でも、フェノキシホスファゼン(式(3)中、X1およびX2=フェノキシ基)、プロポキシホスファゼン(式(3)中、X1およびX2=プロポキシ基)、ジアミノホスファゼン(式(3)中、X1およびX2=アミノ基)を基本骨格とした直鎖状化合物で、リン原子濃度10質量%以上のものが好ましい。特に、ホスファゼン類は、一般に融点が低く、熱可塑性ポリエステル樹脂との相溶性および/または分散性が悪く、紡糸時に均一に混合するのが困難であり、かつブリードの問題が生じる場合がある。このため、マスターバッチ化して使用するあるいは他の難燃剤と併用して使用するなどの細心の注意が必要である。
表1に示す質量%のポリリン酸アンモニウム(APP)1(クラリアント社製、製品名PekoflamTC204、白色粉末、平均粒径8μm、リン含有量32質量%、窒素含有量15質量%、重合度1000、分解温度285℃)、無機赤リンおよび着色剤を含むそれぞれのマスターバッチと、表1に示す質量%のポリエチレンテレフタレート(PET)樹脂1(三菱化学株式会社製、商品名「NOVAPEX」)とをエクストルーダーで溶融混合して、表1に示す割合の難燃性ポリエステル樹脂組成物をそれぞれ得た。次いでこれらを乾式法で引き取り速度520m/min、温度230〜285℃で溶融紡糸し、単糸6.6デシテックスの難燃性ステープル(難燃性繊維1〜7)を得た。
ポリリン酸アンモニウム(APP)1の代わりに、表2に示す質量%のポリリン酸アンモニウム(APP)2(ブーデンハイム社製、製品名テラージュC−30、白色粉末、平均粒径10μm、リン含有量32質量%、メラミン被覆品、分解温度305℃)、ポリリン酸アンモニウム(APP)3(鈴祐化学製、製品名ファイアカット760、白色粉末、平均粒径8μm、リン含有量32質量%、分解温度250℃)、ポリリン酸メラミン(三和化学製、製品名MPP−A、白色粉末、平均粒径4μm、リン含有量15質量%、分解温度320℃)、ピロリン酸メラミン(鈴祐化学製、製品名ファイアカットCLMP、白色粉末、リン含有量15質量%、窒素含有量38質量%、平均粒径10μm、分解温度310℃)、ポリフェノキシホスファゼン(大塚化学製、製品名ホスファゼン、リン含有量13質量%、分解温度350℃以上)を用いる以外は、実施例1に準じて紡糸を行ない、難燃性ステープル(難燃性繊維9〜14)を得た。これらの難燃性繊維9〜14について、実施例1と同様に紡糸性、難燃性、着色度、耐光性および機械的物性(強度および伸度)を調べ、その結果を実施例9〜14として表2に示した。
表3に示す質量%のポリリン酸アンモニウム(APP)1、ポリリン酸アンモニウム(APP)3、無機赤リンを用いる以外は、実施例1に準じて紡糸を行ない、難燃性ステープル(比較難燃性繊維1〜6)を得た。これらの比較難燃性繊維1〜6について、実施例1と同様に紡糸性、難燃性、着色度、耐光性および機械的物性(強度および伸度)を調べ、その結果を比較例1ないし7として表3に示した。
(実施例15)
実施例2、6、8、10、11および13で得た難燃性繊維2、6、8、10、11および13に、難燃加工未処理繊維(表中、未処理繊維と表記する)を表4に示す割合で配合して難燃綿を調製し、難燃材1〜6とした。これらの難燃性を調べた。なお、難燃加工未処理繊維は、ポリエステル樹脂組成物としてポリリン酸アンモニウムを含ませないこと以外は実施例1と同様にして調製したポリエステル樹脂組成物を紡糸した未処理繊維である。難燃材1〜6(難燃綿)の難燃性の評価は、実施例1と同様の方法を採用した。結果を表4に示す。
Claims (11)
- ポリリン酸アンモニウム、ポリリン酸メラミンおよびホスファゼン類からなる群より選択される少なくとも1つの無機リン−窒素系化合物を含む難燃剤と、着色剤と、熱可塑性ポリエステル樹脂と、を含む難燃性ポリエステル樹脂組成物を溶融紡糸して得られる繊維であって、
前記ポリエステル樹脂組成物の総重量を基準として、前記無機リン−窒素系化合物の含有量は0.1〜12質量%であり、前記着色剤の含有量は0.01〜5質量%でありおよび前記熱可塑性ポリエステル樹脂の含有量は83〜99.89質量%であることを特徴とする難燃性原着ポリエステル繊維。 - ポリリン酸アンモニウム、ポリリン酸メラミンおよびホスファゼン類からなる群より選択される少なくとも1つの無機リン−窒素系化合物ならびに無機赤リンを含む難燃剤と、着色剤と、熱可塑性ポリエステル樹脂と、を含む難燃性ポリエステル樹脂組成物を溶融紡糸して得られる繊維であって、
前記ポリエステル樹脂組成物の総重量を基準として、前記無機リン−窒素系化合物の含有量は0.1〜8質量%であり、前記無機赤リンの含有量は0.1〜8質量%であり、前記着色剤の含有量は0.01〜5質量%でありおよび前記熱可塑性ポリエステル樹脂の含有量は83〜99.79質量%であり、
かつ前記無機リン−窒素系化合物および前記無機赤リンの含有量の合計が0.2〜12質量%であることを特徴とする、請求項1に記載の難燃性原着ポリエステル繊維。 - 前記無機リン−窒素系化合物が、ポリリン酸アンモニウムおよびポリリン酸メラミンからなる群より選択される少なくとも1つのポリリン酸塩と、ホスファゼン類と、を含むことを特徴とする、請求項1に記載の難燃性原着ポリエステル繊維。
- 前記無機リン−窒素系化合物が、ポリリン酸アンモニウムおよびポリリン酸メラミンからなる群より選択される少なくとも1つのポリリン酸塩を含み、
難燃剤におけるポリリン酸塩由来のリン原子に対するポリリン酸塩由来でないリン原子の割合がリン原子比率で0.1〜20であることを特徴とする、請求項1〜3のいずれか1項に記載の難燃性原着ポリエステル繊維。 - 前記無機リン−窒素系化合物の分解温度が270℃以上である、請求項1〜4のいずれか1項に記載の難燃性原着ポリエステル繊維。
- 前記熱可塑性ポリエステル樹脂が再生ポリエステル樹脂を含む、請求項1〜5のいずれか1項に記載の難燃性原着ポリエステル繊維。
- 前記着色剤が、アゾ系、アンスラキノン系、キナクリドン系、シアニングリーンおよびシアニンブルーからなるシアニン系、ジオキサジン系、α型フタロシアニンおよびβ型フタロシアニンからなるフタロシアニン系、ペリノン系、ベリレン系、ポリアゾ系、チタンイエロー、群青、酸化鉄、弁柄、亜鉛華、アナターゼ酸化チタンおよびルチル酸化チタンからなる酸化チタン系ならびにカーボンブラック、グラファイト、スピリットブラック、チャンネルブラックおよびファーネスブラックからなるカーボン系からなる群より選択される少なくとも1つである、請求項1〜6のいずれか1項に記載の難燃性原着ポリエステル繊維。
- 乾式法で引き取り速度300〜1000m/min、紡糸温度200〜300℃で溶融紡糸して得られる繊維である、請求項1〜7のいずれか1項に記載の難燃性原着ポリエステル繊維。
- 無機リン−窒素系化合物または前記無機リン−窒素系化合物を含有するマスターバッチ、無機赤リンまたは前記無機赤リンを含有するマスターバッチ、着色剤を含有するマスターバッチおよび熱可塑性ポリエステル樹脂を溶融混合し、次いで溶融紡糸することを特徴とする、請求項1〜8のいずれか1項に記載の難燃性原着ポリエステル繊維の製造方法。
- 請求項1〜8のいずれか1項に記載の難燃性原着ポリエステル繊維または請求項9の製造方法により得られる難燃性原着ポリエステル繊維を5〜100質量%含有する難燃材。
- 請求項10に記載の難燃材を用いた自動車用内装材。
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US9023922B2 (en) | 2012-05-24 | 2015-05-05 | Sabic Global Technologies B.V. | Flame retardant compositions, articles comprising the same and methods of manufacture thereof |
US20130313493A1 (en) | 2012-05-24 | 2013-11-28 | Sabic Innovative Plastics Ip B.V. | Flame retardant polycarbonate compositions, methods of manufacture thereof and articles comprising the same |
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JP4787183B2 (ja) * | 2007-02-16 | 2011-10-05 | 株式会社高木化学研究所 | 難燃性ポリエステル繊維、これを用いた難燃材および難燃性ポリエステル繊維の製造方法 |
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- 2009-07-02 US US12/918,485 patent/US20110086225A1/en not_active Abandoned
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WO2010001972A1 (ja) | 2010-01-07 |
US20110086225A1 (en) | 2011-04-14 |
JP5470532B2 (ja) | 2014-04-16 |
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