JPS6399285A - 撥水撥油剤 - Google Patents
撥水撥油剤Info
- Publication number
- JPS6399285A JPS6399285A JP61216854A JP21685486A JPS6399285A JP S6399285 A JPS6399285 A JP S6399285A JP 61216854 A JP61216854 A JP 61216854A JP 21685486 A JP21685486 A JP 21685486A JP S6399285 A JPS6399285 A JP S6399285A
- Authority
- JP
- Japan
- Prior art keywords
- fluorine
- group
- water
- polymerization
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 239000005871 repellent Substances 0.000 title claims abstract description 10
- 230000002940 repellent Effects 0.000 title claims abstract description 8
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 35
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 13
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 8
- 125000003709 fluoroalkyl group Chemical group 0.000 claims abstract description 7
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 27
- 239000011737 fluorine Substances 0.000 claims description 27
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 125000001153 fluoro group Chemical group F* 0.000 claims description 8
- 229920002313 fluoropolymer Polymers 0.000 claims description 6
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 239000004811 fluoropolymer Substances 0.000 claims description 4
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 4
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- 229920000642 polymer Polymers 0.000 abstract description 33
- 238000010539 anionic addition polymerization reaction Methods 0.000 abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 3
- 238000010526 radical polymerization reaction Methods 0.000 abstract description 2
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 22
- 239000003921 oil Substances 0.000 description 13
- 239000000178 monomer Substances 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 8
- -1 fluoroalkyl methacrylate Chemical compound 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000010408 film Substances 0.000 description 5
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- 238000012662 bulk polymerization Methods 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 3
- SJBBXFLOLUTGCW-UHFFFAOYSA-N 1,3-bis(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=CC(C(F)(F)F)=C1 SJBBXFLOLUTGCW-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 239000003708 ampul Substances 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- 230000001007 puffing effect Effects 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- MKTOIPPVFPJEQO-UHFFFAOYSA-N 4-(3-carboxypropanoylperoxy)-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OOC(=O)CCC(O)=O MKTOIPPVFPJEQO-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000134884 Ericales Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
- 241000519996 Teucrium chamaedrys Species 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- KSCFJBIXMNOVSH-UHFFFAOYSA-N dyphylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1N(CC(O)CO)C=N2 KSCFJBIXMNOVSH-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- 239000010720 hydraulic oil Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 150000004681 metal hydrides Chemical class 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- ODZPKZBBUMBTMG-UHFFFAOYSA-N sodium amide Chemical compound [NH2-].[Na+] ODZPKZBBUMBTMG-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000005369 trialkoxysilyl group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12292086 | 1986-05-28 | ||
| JP61-122920 | 1986-05-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6399285A true JPS6399285A (ja) | 1988-04-30 |
| JPH0464634B2 JPH0464634B2 (de) | 1992-10-15 |
Family
ID=14847871
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61216854A Granted JPS6399285A (ja) | 1986-05-28 | 1986-09-12 | 撥水撥油剤 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6399285A (de) |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01197570A (ja) * | 1988-02-01 | 1989-08-09 | Daikin Ind Ltd | 低屈折率ハードコート剤 |
| JPH01259072A (ja) * | 1988-04-08 | 1989-10-16 | Daikin Ind Ltd | 防湿コーティング剤 |
| WO1994013137A1 (fr) * | 1992-12-16 | 1994-06-23 | Shiseido Company, Ltd. | Fleur sechee et procede de production |
| JPH06104754B2 (ja) * | 1989-07-24 | 1994-12-21 | ジェルマン サイエンシズ テクノロジー インコーポレイテッド | 改良された撥水性及び撥油性を得るための多孔質基材の処理方法 |
| JPH10237389A (ja) * | 1997-02-26 | 1998-09-08 | Moon Star Co | 革靴用艶出し剤 |
| US6716944B2 (en) | 2001-04-13 | 2004-04-06 | Asahi Glass Company, Limited | Water and oil repellent composition |
| JP2004352976A (ja) * | 2003-05-02 | 2004-12-16 | Daikin Ind Ltd | 含フッ素重合体を含んでなる表面処理剤 |
| WO2004108779A1 (ja) | 2003-06-09 | 2004-12-16 | Daikin Industries, Ltd. | メーソンリー処理剤 |
| WO2005092937A1 (ja) * | 2004-03-26 | 2005-10-06 | Daikin Industries, Ltd. | 含フッ素単量体、含フッ素重合体および表面処理剤 |
| WO2006046643A1 (ja) * | 2004-10-29 | 2006-05-04 | Daikin Industries, Ltd. | 含フッ素処理剤組成物 |
| JPWO2004108855A1 (ja) * | 2003-06-09 | 2006-07-20 | ダイキン工業株式会社 | ケイ素を含有する含フッ素表面処理剤 |
| JP2007211376A (ja) * | 2006-02-10 | 2007-08-23 | Daikin Ind Ltd | 含フッ素重合体を鞘に含む芯鞘構造複合繊維および該複合繊維を有する物品 |
| JP2007269642A (ja) * | 2006-03-30 | 2007-10-18 | Daikin Ind Ltd | フルオロアクリレート重合体を含有する化粧料 |
| JP2009191272A (ja) * | 2003-05-02 | 2009-08-27 | Daikin Ind Ltd | 含フッ素重合体を含んでなる表面処理剤 |
| US7638575B2 (en) | 2004-03-26 | 2009-12-29 | Daikin Industries, Ltd. | Surface treating agent, fluorine-containing monomer and fluorine-containing polymer |
| WO2011122442A1 (ja) * | 2010-03-30 | 2011-10-06 | ダイキン工業株式会社 | α－クロロアクリレートを使用した撥水撥油剤 |
| US8461254B2 (en) | 2005-05-09 | 2013-06-11 | Dow Corning Corporation | Fluorosilicones and fluorine- and silicon-containing surface treatment agent |
| WO2013099611A1 (ja) * | 2011-12-28 | 2013-07-04 | ダイキン工業株式会社 | 含フッ素組成物および含フッ素重合体 |
| US8552106B2 (en) | 2008-03-31 | 2013-10-08 | Daikin Industries, Ltd. | Dispersion of fluorosilicones and fluorine- and silicon-containing surface treatment agent |
| US8927667B2 (en) | 2008-02-06 | 2015-01-06 | Daikin Industries, Ltd. | Fluorosilicones and fluorine- and silicon-containing surface treatment agent |
| WO2018084132A1 (ja) * | 2016-11-01 | 2018-05-11 | ダイキン工業株式会社 | 含フッ素重合体および表面処理剤組成物 |
-
1986
- 1986-09-12 JP JP61216854A patent/JPS6399285A/ja active Granted
Cited By (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01197570A (ja) * | 1988-02-01 | 1989-08-09 | Daikin Ind Ltd | 低屈折率ハードコート剤 |
| JPH01259072A (ja) * | 1988-04-08 | 1989-10-16 | Daikin Ind Ltd | 防湿コーティング剤 |
| JPH06104754B2 (ja) * | 1989-07-24 | 1994-12-21 | ジェルマン サイエンシズ テクノロジー インコーポレイテッド | 改良された撥水性及び撥油性を得るための多孔質基材の処理方法 |
| US5560965A (en) * | 1992-12-16 | 1996-10-01 | Shiseido Company, Ltd. | Dry flower and process for production of same |
| WO1994013137A1 (fr) * | 1992-12-16 | 1994-06-23 | Shiseido Company, Ltd. | Fleur sechee et procede de production |
| JPH10237389A (ja) * | 1997-02-26 | 1998-09-08 | Moon Star Co | 革靴用艶出し剤 |
| US6716944B2 (en) | 2001-04-13 | 2004-04-06 | Asahi Glass Company, Limited | Water and oil repellent composition |
| JP2009191272A (ja) * | 2003-05-02 | 2009-08-27 | Daikin Ind Ltd | 含フッ素重合体を含んでなる表面処理剤 |
| JP2004352976A (ja) * | 2003-05-02 | 2004-12-16 | Daikin Ind Ltd | 含フッ素重合体を含んでなる表面処理剤 |
| US9328455B2 (en) | 2003-05-02 | 2016-05-03 | Daikin Industries, Ltd. | Surface-treating agent comprising fluoropolymer |
| US7915337B2 (en) | 2003-05-02 | 2011-03-29 | Daikin Industries, Ltd. | Surface-treating agent comprising fluoropolymer |
| WO2004108779A1 (ja) | 2003-06-09 | 2004-12-16 | Daikin Industries, Ltd. | メーソンリー処理剤 |
| US9382363B2 (en) | 2003-06-09 | 2016-07-05 | Daikin Industries, Ltd. | Masonry-treating agent |
| JPWO2004108855A1 (ja) * | 2003-06-09 | 2006-07-20 | ダイキン工業株式会社 | ケイ素を含有する含フッ素表面処理剤 |
| US7776982B2 (en) | 2003-06-09 | 2010-08-17 | Daikin Industries, Ltd. | Silicon-containing fluorochemical surface-treating agent |
| WO2005092937A1 (ja) * | 2004-03-26 | 2005-10-06 | Daikin Industries, Ltd. | 含フッ素単量体、含フッ素重合体および表面処理剤 |
| US8153756B2 (en) | 2004-03-26 | 2012-04-10 | Daikin Industries, Ltd. | Fluorine-containing monomer, fluorine-containing polymer and surface treating agent |
| US7638575B2 (en) | 2004-03-26 | 2009-12-29 | Daikin Industries, Ltd. | Surface treating agent, fluorine-containing monomer and fluorine-containing polymer |
| KR100840819B1 (ko) * | 2004-03-26 | 2008-06-23 | 다이킨 고교 가부시키가이샤 | 불소 함유 단량체, 불소 함유 중합체 및 표면 처리제 |
| US7442829B2 (en) | 2004-03-26 | 2008-10-28 | Daikin Industries, Ltd. | Fluorine-containing monomer, fluorine-containing polymer and surface treating agent |
| WO2006046643A1 (ja) * | 2004-10-29 | 2006-05-04 | Daikin Industries, Ltd. | 含フッ素処理剤組成物 |
| US8197590B2 (en) | 2004-10-29 | 2012-06-12 | Daikin Industries, Ltd. | Fluorine-containing treatment composition |
| US8461254B2 (en) | 2005-05-09 | 2013-06-11 | Dow Corning Corporation | Fluorosilicones and fluorine- and silicon-containing surface treatment agent |
| JP2007211376A (ja) * | 2006-02-10 | 2007-08-23 | Daikin Ind Ltd | 含フッ素重合体を鞘に含む芯鞘構造複合繊維および該複合繊維を有する物品 |
| JP2007269642A (ja) * | 2006-03-30 | 2007-10-18 | Daikin Ind Ltd | フルオロアクリレート重合体を含有する化粧料 |
| US8927667B2 (en) | 2008-02-06 | 2015-01-06 | Daikin Industries, Ltd. | Fluorosilicones and fluorine- and silicon-containing surface treatment agent |
| US8552106B2 (en) | 2008-03-31 | 2013-10-08 | Daikin Industries, Ltd. | Dispersion of fluorosilicones and fluorine- and silicon-containing surface treatment agent |
| CN102822309A (zh) * | 2010-03-30 | 2012-12-12 | 大金工业株式会社 | 使用α-氯丙烯酸酯的拨水拨油剂 |
| WO2011122442A1 (ja) * | 2010-03-30 | 2011-10-06 | ダイキン工業株式会社 | α－クロロアクリレートを使用した撥水撥油剤 |
| CN102822309B (zh) * | 2010-03-30 | 2015-12-09 | 大金工业株式会社 | 使用α-氯丙烯酸酯的拨水拨油剂 |
| WO2013099611A1 (ja) * | 2011-12-28 | 2013-07-04 | ダイキン工業株式会社 | 含フッ素組成物および含フッ素重合体 |
| JP2013151651A (ja) * | 2011-12-28 | 2013-08-08 | Daikin Industries Ltd | 含フッ素組成物および含フッ素重合体 |
| US10640594B2 (en) | 2011-12-28 | 2020-05-05 | Daikin Industries, Ltd. | Fluorine-containing composition and fluorine-containing polymer |
| WO2018084132A1 (ja) * | 2016-11-01 | 2018-05-11 | ダイキン工業株式会社 | 含フッ素重合体および表面処理剤組成物 |
| KR20190053897A (ko) * | 2016-11-01 | 2019-05-20 | 다이킨 고교 가부시키가이샤 | 불소 함유 중합체 및 표면 처리제 조성물 |
| JPWO2018084132A1 (ja) * | 2016-11-01 | 2019-09-26 | ダイキン工業株式会社 | 含フッ素重合体および表面処理剤組成物 |
| EP3536718A4 (de) * | 2016-11-01 | 2020-07-22 | Daikin Industries, Ltd. | Fluoriertes polymer und oberflächenbehandlungszusammensetzung |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0464634B2 (de) | 1992-10-15 |
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