JP2000507282A - フッ素化チオエーテル末端キャップを持つマレイン酸コポリマー - Google Patents
フッ素化チオエーテル末端キャップを持つマレイン酸コポリマーInfo
- Publication number
- JP2000507282A JP2000507282A JP9532813A JP53281397A JP2000507282A JP 2000507282 A JP2000507282 A JP 2000507282A JP 9532813 A JP9532813 A JP 9532813A JP 53281397 A JP53281397 A JP 53281397A JP 2000507282 A JP2000507282 A JP 2000507282A
- Authority
- JP
- Japan
- Prior art keywords
- carbon atoms
- formula
- mixture
- group
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3566—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2918—Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
- Y10T428/292—In coating or impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.式IIの単位を持つコポリマーを有する組成物であって、 式中、 Mは、H、アルカリ金属、アンモニウムカチオン、またはそれらの混合物; Nは、OM、またはOM、OR、およびNR1R2の混合物であって、モル比は (OM):(OR):(NR1R2)が[1−(e+f)]:e:fに等しく、ここでeおよび fは各々0ないし0.5であり、(e+f)は0.8未満; R、R1、およびR2は、各々別々にH、または炭素原子の数が1ないし20で ある分岐状あるいは直鎖状アルキル基; Yは2ないし10個の炭素原子を持つアルキル基、6ないし12個の炭素原子 を持つアリール基、あるいは4ないし12個の炭素原子を持つアルコキシ基; Xはフッ化チオールラジカル; ZはH;さらに、 vおよびwは、各々正の数であり、vとwとのモル比は約0.4:1から約1 .3:1、 であるであることを特徴とする組成物。 2.前記Yは炭素数が6個のアルキルであることを特徴とする請求項1に記載の 組成物。 3.前記Xは、 Rf−(A)d−B−S− の式で表されるフッ化チオールラジカルであって、 該式中、 Aは、−SO2N(R3)−、−CON(R3)−、−S−および-SO2−から なる群から選択される二価ラジカルであり、R3はH、または1ないし6個の炭 素原子を持つアルキル基、 dは、0または1、さらに Bは、二価の直鎖状炭化水素ラジカル−CnH2n−であって、nは2ないし約 12、 であることを特徴とする請求項1に記載の組成物。 4.耐汚染性および酸性染料による着色に対する耐性を繊維に付与する方法であ って、 式II: の単位を持つコポリマーを有する組成物を有効量塗布することを含み、 該式中、 Mは、H、アルカリ金属、アンモニウムカチオン、またはそれらの混合物; Nは、OM、またはOM、OR、およびNR1R2の混合物であって、モル比は (OM):(OR):(NR1R2)が[1−(e+f)]:e:fに等しく、ここでeおよび fは各々0ないし0.5であり、(e+f)は0.8未満; R、R1、およびR2は、各々別々にH、または炭素原子の数が1ないし20で ある分岐状あるいは直鎖状アルキル基; Yは2ないし10個の炭素原子を持つアルキル基、6ないし12個の炭素原子 を持つアリール基、あるいは4ないし12個の炭素原子を持つアルコキシ基; Xはフッ化チオールラジカル; ZはH:さらに、 vおよびwは、各々正の数であり、vとwとのモル比は約0.4:1から約1 .3:1、 であるであることを特徴とする方法。 5.式IIの組成物の有効量は、繊維の重量を基準として約0.1%から約5. 0%までであることを特徴とする請求項4に記載の方法。 6.前記式IIの組成物を、少なくとも1種類の他のフェノール樹脂系耐汚染剤 またはポリカルボキシル系耐汚染剤と同時に塗布することを特徴とする請求項4 に記載の方法。 7.防汚性および酸性染料による着色に対する耐性をカーペットに付与する方法 であって、 式II: の単位を持つコポリマーを有する組成物を有効量塗布することを含み、 該式中、 Mは、H、アルカリ金属、アンモニウムカチオン、またはそれらの混合物; Nは、OM、またはOM、OR、およびNR1R2の混合物であって、モル比は (OM):(OR):(NR1R2)が[1−(e+f)]:e:fに等しく、ここでeお よびfは各々0ないし0.5であり、(ef−f)は0.8未満; R、R1、およびR2は、各々別々にH、または炭素原子の数が1ないし20で ある分岐状あるいは直鎖状アルキル基; Yは2ないし10個の炭素原子を持つアルキル基、6ないし12個の炭素原子 を持つアリール基、あるいは4ないし12個の炭素原子を持つアルコキシ基; Xはフッ化チオールラジカル; ZはH;さらに、 vおよびwは、各々正の数であり、vとwとのモル比は約0.4:1から約1 .3:1、 であるであることを特徴とする方法。 8. 式II:の単位を持つコポリマーを有する組成物が塗布されている繊維であって、 該式中、 Mは、H、アルカリ金属、アンモニウムカチオン、またはそれらの混合物; Nは、OM、またはOM、OR、およびNR1R2の混合物であって、モル比は (OM):(OR):(NR1R2)が[1−(e+f)]:e:fに等しく、ここでeお よびfは各々0ないし0.5であり、(e+f)は0.8未満; R、R1、およびR2は、各々別々にH、または炭素原子の数が1ないし20で ある分岐状あるいは直鎖状アルキル基; Yは2ないし10個の炭素原子を持つアルキル基、6ないし12個の炭素原子 を持つアリール基、あるいは4ないし12個の炭素原子を持つアルコキシ基; Xはフッ化チオールラジカル; ZはH;さらに、 vおよびwは、各々正の数であり、vとwとのモル比は約0.4:1から約1 .3:1、 であるであることを特徴とする繊維。 9.ナイロン、絹、またはウールからなる群から選択されることを特徴とする請 求項8に記載の繊維。 10. 式II: の単位を持つコポリマーを有する組成物を合成する方法であって、 該式中、 Mは、H、アルカリ金属、アンモニウムカチオン、またはそれらの混合物; Nは、OM、またはOM、OR、およびNR1R2の混合物であって、モル比は (OM):(OR):(NR1R2)が[1−(e+f)]:e:fに等しく、ここでeおよび fは各々0ないし0.5であり、(e+f)は0.8未満; R、R1、およびR2は、各々別々にH、または炭素原子の数が1ないし20で ある分岐状あるいは直鎖状アルキル基; Yは2ないし10個の炭素原子を持つアルキル基、6ないし12個の炭素原子 を持つアリール基、あるいは4ないし12個の炭素原子を持つアルコキシ基; Xはフッ化チオールラジカル; ZはH;さらに、 vおよびwは、各々正の数であり、vとwとのモル比は約0.4:1から約1 .3:1であり、 (1)式Iのフッ化チオール存在下、マレイン酸無水物と炭素数が4ないし1 2個のアルファオレフィンとを反応させる工程であって、該式Iは、 Rf−(A)d−B−SH I であり、さらに 該式中、 Rfは、少なくとも一つの酸素原子が任意に割り込む完全フッ素化直鎖または 分岐状の炭素数が3ないし14個である脂肪族ラジカル; Aは、−SO2N(R3)−、−CON(R3)−、−S−または−SO2−から 選択される二価ラジカルであって、R3はHまたは1ないし6炭素原子を持つア ルキル基、 dは、0または1、さらに Bは、二価の直鎖状炭化水素ラジカル−CnH2n−であって、nは2ないし約 12、および好ましくは2であるフッ化チオール存在下、マレイン酸無水物を炭 素数が4ないし12個のアルファ・オレフィンと反応させることで、XおよびY が式IIで定義されたものと同様であるXおよびYによって末端キャップ化され たマレイン酸無水物/アルファ・オレフィンコポリマーを生成する工程と、 (2)前記マレイン酸無水物/アルファ・オレフィンコポリマーをR4OH(該 式中、R4は炭素数1ないし18個のアルキル、アルカリ金属イオン、またはア ンモニウムカチオン)と反応させて式IIの組成物を生成する工程と、 を有することを特徴とする方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/617,518 US5712348A (en) | 1996-03-13 | 1996-03-13 | Maleic acid copolymers with fluorinated thioether end-cap |
US08/617,518 | 1996-03-13 | ||
PCT/US1997/003914 WO1997033926A1 (en) | 1996-03-13 | 1997-03-12 | Maleic acid copolymers with fluorinated thioether end cap |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2000507282A true JP2000507282A (ja) | 2000-06-13 |
JP3723222B2 JP3723222B2 (ja) | 2005-12-07 |
Family
ID=24473959
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP53281397A Expired - Fee Related JP3723222B2 (ja) | 1996-03-13 | 1997-03-12 | フッ素化チオエーテル末端キャップを持つマレイン酸コポリマー |
Country Status (10)
Country | Link |
---|---|
US (2) | US5712348A (ja) |
EP (1) | EP0886659B1 (ja) |
JP (1) | JP3723222B2 (ja) |
KR (1) | KR19990087751A (ja) |
CN (1) | CN1105733C (ja) |
AU (1) | AU727201B2 (ja) |
CA (1) | CA2249024A1 (ja) |
DE (1) | DE69702186T2 (ja) |
TW (1) | TW377360B (ja) |
WO (1) | WO1997033926A1 (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69835649T2 (de) * | 1997-10-15 | 2007-09-13 | E.I. Dupont De Nemours And Co., Wilmington | Copolymere aus Maleinsäure oder dessen Anhydrid und fluorierten Olefinen |
DE10125158A1 (de) * | 2001-05-22 | 2002-12-05 | Basf Ag | Nieder-und hochmolekulare Emulgatoren, insbesondere auf Bassis von Polyisobutylen, sowie deren Mischungen |
US7335234B2 (en) * | 2002-10-16 | 2008-02-26 | Columbia Insurance Company | Method of treating fibers, carpet yarns and carpets to enhance repellency |
US20050015886A1 (en) * | 2003-07-24 | 2005-01-27 | Shaw Industries Group, Inc. | Methods of treating and cleaning fibers, carpet yarns and carpets |
JP4726464B2 (ja) * | 2004-11-05 | 2011-07-20 | 富士フイルム株式会社 | 光学部材形成用重合性組成物、光学部材、および、光学部材の製造方法 |
US7785374B2 (en) | 2005-01-24 | 2010-08-31 | Columbia Insurance Co. | Methods and compositions for imparting stain resistance to nylon materials |
US20070050912A1 (en) * | 2005-09-02 | 2007-03-08 | Materniak Joyce M | Reduction of turmeric and iodine staining |
US20070136953A1 (en) * | 2005-12-20 | 2007-06-21 | Materniak Joyce M | Stability for coapplication |
US8357621B2 (en) * | 2009-06-29 | 2013-01-22 | E.I. Du Pont De Nemours And Company | Soil resist method |
US7901589B2 (en) | 2009-06-29 | 2011-03-08 | E.I. Du Pont De Nemours And Company | Propanediol soil resist compositions |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE759823A (fr) * | 1969-12-03 | 1971-05-17 | Bayer Ag | Agents ameliorant la solidite au mouille |
DE1961369C3 (de) * | 1969-12-06 | 1979-03-01 | Bayer Ag, 5090 Leverkusen | Dioxydiphenylsulfon-Formaldehyd-Kondensationsprodukte und ihre Verwendung als Gerbstoffe und Naßechtheitsverbesserungsmittel |
MX154899A (es) * | 1979-05-03 | 1987-12-29 | Ciba Geigy Ag | Procedimiento para la preparacion de oligomeros terminados en sulfuro de perfluordalquilo |
US4574139A (en) * | 1983-06-17 | 1986-03-04 | Kuraray Co., Ltd. | Polymer having a fluorine-containing end group and production of the same |
US4592940A (en) * | 1983-12-16 | 1986-06-03 | Monsanto Company | Stain-resistant nylon carpets impregnated with condensation product of formaldehyde with mixture of diphenolsulfone and phenolsulfonic acid |
US4591591A (en) * | 1984-03-08 | 1986-05-27 | Eli Lilly And Company | Pyridazinone derivatives as inotropic agents |
FR2575165B1 (fr) * | 1984-12-26 | 1987-01-23 | Atochem | Telomeres fluores a groupements hydrophiles, leur procede de preparation et leur utilisation comme agents tensioactifs en milieu aqueux, notamment comme additifs aux emulseurs proteiniques anti-incendie |
ZA889534B (en) * | 1987-12-21 | 1990-08-29 | Du Pont | Stain-resistant aromatic/meleic anhydride polymers |
KR920006476B1 (ko) * | 1987-12-21 | 1992-08-07 | 이 아이 듀우판 디 네모아 앤드 캄파니 | 방오성 폴리아미드 직물 지지체 및 직물 지지체에 방오성을 제공하는 방법 |
US4948650A (en) * | 1987-12-21 | 1990-08-14 | E. I. Du Pont De Nemours And Company | Stain-resistant textile substrates |
US5460887A (en) * | 1990-12-13 | 1995-10-24 | E. I. Du Pont De Nemours And Company | Stain-resistant polyamide substrates |
JPH06504097A (ja) * | 1990-12-27 | 1994-05-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 無水マレイン酸/ビニルまたはアリルエーテルポリマー耐汚染性材料 |
-
1996
- 1996-03-13 US US08/617,518 patent/US5712348A/en not_active Expired - Fee Related
-
1997
- 1997-03-07 TW TW086102777A patent/TW377360B/zh active
- 1997-03-12 DE DE69702186T patent/DE69702186T2/de not_active Expired - Fee Related
- 1997-03-12 EP EP97909022A patent/EP0886659B1/en not_active Expired - Lifetime
- 1997-03-12 JP JP53281397A patent/JP3723222B2/ja not_active Expired - Fee Related
- 1997-03-12 KR KR1019980707223A patent/KR19990087751A/ko not_active Application Discontinuation
- 1997-03-12 AU AU20776/97A patent/AU727201B2/en not_active Ceased
- 1997-03-12 CN CN97192999A patent/CN1105733C/zh not_active Expired - Fee Related
- 1997-03-12 WO PCT/US1997/003914 patent/WO1997033926A1/en not_active Application Discontinuation
- 1997-03-12 CA CA002249024A patent/CA2249024A1/en not_active Abandoned
- 1997-09-25 US US08/937,953 patent/US5824372A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP3723222B2 (ja) | 2005-12-07 |
AU2077697A (en) | 1997-10-01 |
DE69702186D1 (de) | 2000-07-06 |
AU727201B2 (en) | 2000-12-07 |
WO1997033926A1 (en) | 1997-09-18 |
US5712348A (en) | 1998-01-27 |
KR19990087751A (ko) | 1999-12-27 |
US5824372A (en) | 1998-10-20 |
TW377360B (en) | 1999-12-21 |
CN1105733C (zh) | 2003-04-16 |
DE69702186T2 (de) | 2001-03-01 |
CA2249024A1 (en) | 1997-09-18 |
EP0886659A1 (en) | 1998-12-30 |
EP0886659B1 (en) | 2000-05-31 |
CN1213385A (zh) | 1999-04-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5464911A (en) | Superior stain resistant compositions | |
JP3819034B2 (ja) | カルボン酸を含むポリマー/レゾール樹脂耐汚染性剤 | |
US5770656A (en) | Partial fluoroesters or thioesters of maleic acid polymers and their use as soil and stain resists | |
EP0562024B1 (en) | Maleic anhydride/olefin polymer stain-resists | |
US5945493A (en) | Fluorine-containing maleic acid terpolymer soil and stain resists | |
JPS6399285A (ja) | 撥水撥油剤 | |
JP2000507282A (ja) | フッ素化チオエーテル末端キャップを持つマレイン酸コポリマー | |
JP3775435B2 (ja) | マレイン酸ポリマーの部分フルオロエステルまたはフルオロチオエステルおよびスルホン化芳香族縮合物によるポリアミド材料の処理 | |
JPH0713118B2 (ja) | 新規共重合体及び撥水撥油剤 | |
MXPA00012691A (en) | Fluorine-containing maleic acid terpolymer soil and stain resists |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20040303 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20050111 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20041222 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20050411 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20050411 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20050906 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20050915 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
LAPS | Cancellation because of no payment of annual fees |