JPS6389593A - 鋼の無切削加工用潤滑剤 - Google Patents
鋼の無切削加工用潤滑剤Info
- Publication number
- JPS6389593A JPS6389593A JP62234678A JP23467887A JPS6389593A JP S6389593 A JPS6389593 A JP S6389593A JP 62234678 A JP62234678 A JP 62234678A JP 23467887 A JP23467887 A JP 23467887A JP S6389593 A JPS6389593 A JP S6389593A
- Authority
- JP
- Japan
- Prior art keywords
- lubricant
- binder
- weight
- steel
- solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000314 lubricant Substances 0.000 title claims description 42
- 229910000831 Steel Inorganic materials 0.000 title claims description 9
- 239000010959 steel Substances 0.000 title claims description 9
- 238000005520 cutting process Methods 0.000 title claims description 5
- 239000007787 solid Substances 0.000 claims description 21
- 239000011230 binding agent Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 239000010439 graphite Substances 0.000 claims description 9
- 229910002804 graphite Inorganic materials 0.000 claims description 9
- 239000004816 latex Substances 0.000 claims description 8
- 229920000126 latex Polymers 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 7
- 239000002174 Styrene-butadiene Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 4
- 239000011115 styrene butadiene Substances 0.000 claims description 4
- 239000008365 aqueous carrier Substances 0.000 claims description 2
- 230000001050 lubricating effect Effects 0.000 claims description 2
- 239000002706 dry binder Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000006185 dispersion Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 6
- 239000010408 film Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229920013820 alkyl cellulose Polymers 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- 102100030393 G-patch domain and KOW motifs-containing protein Human genes 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 239000011306 natural pitch Substances 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
- C10M111/04—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
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- C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
- C10M103/04—Metals; Alloys
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- C10M103/06—Metal compounds
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- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
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- C10M125/18—Compounds containing halogen
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Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
め要約のデータは記録されません。
Description
【発明の詳細な説明】
本発明は、固体潤滑剤、結合剤および粘稠剤を含む、鋼
を高温加工する際に用いる潤滑剤に関する。
を高温加工する際に用いる潤滑剤に関する。
金属の無切削加工、とくに継目鋼無情製造の際の芯金の
潤滑に、たとえば黒鉛、アルキレン系重合体または共重
合体および分散剤または被膜安定剤を含有する潤滑剤を
用いることが知られている（ドイツ連邦特許明細書第２
４５０７１６号。）このような潤滑剤は、いわゆるＭＰ
Ｍ（多段式ロール）工程に用いるときには、多くの要求
を満たさなければならない。 すなわち、潤滑剤は水性
分散剤を使用して経済的に適用であって簡単に塗布する
ことができ、担体ｊ−３よび水の分離後、耐水性の均一
で緻密な被膜が形成され、この被膜は高温高圧下で固体
潤滑剤粒子の均一な分散により、高い殿械的安定性を示
すものでなければならない。
潤滑に、たとえば黒鉛、アルキレン系重合体または共重
合体および分散剤または被膜安定剤を含有する潤滑剤を
用いることが知られている（ドイツ連邦特許明細書第２
４５０７１６号。）このような潤滑剤は、いわゆるＭＰ
Ｍ（多段式ロール）工程に用いるときには、多くの要求
を満たさなければならない。 すなわち、潤滑剤は水性
分散剤を使用して経済的に適用であって簡単に塗布する
ことができ、担体ｊ−３よび水の分離後、耐水性の均一
で緻密な被膜が形成され、この被膜は高温高圧下で固体
潤滑剤粒子の均一な分散により、高い殿械的安定性を示
すものでなければならない。
これらの要求を満足する本質的な部分は、結合剤にある
。 このような結合剤として、ドイツ連邦特許明細書４
５０７１６号などには、ブタジェンおよびスチレンおＪ
：びスチレン共重合体が挙げである。
。 このような結合剤として、ドイツ連邦特許明細書４
５０７１６号などには、ブタジェンおよびスチレンおＪ
：びスチレン共重合体が挙げである。
しかし、これら既知の結合剤は、このような潤滑剤に対
する添加量を増大しても、すべての要求を満足させるこ
とはできない。 結合剤としてのブタジェンは柔かすぎ
、またスチレンは通常の共重合体を用いても、最適の被
膜を形成することができない。 また、ヨーロッパ特許
明細書０１６４６３７号には、高温用潤滑剤の例として
スチレン−ブタジェン−共重合体が記載されている。
しかし、その形成には多量の無機塩混合物を必要とする
ため、たとえばＭＰＭ工程において、耐水性の悪さに起
因する不利な作用を示す。
する添加量を増大しても、すべての要求を満足させるこ
とはできない。 結合剤としてのブタジェンは柔かすぎ
、またスチレンは通常の共重合体を用いても、最適の被
膜を形成することができない。 また、ヨーロッパ特許
明細書０１６４６３７号には、高温用潤滑剤の例として
スチレン−ブタジェン−共重合体が記載されている。
しかし、その形成には多量の無機塩混合物を必要とする
ため、たとえばＭＰＭ工程において、耐水性の悪さに起
因する不利な作用を示す。
本発明の課題は、上記のような欠点のない潤滑剤を提供
するにある。
するにある。
本発明によれば、この課題は、結合剤としてカルボキシ
ル スを含有する潤滑剤によって解決される。
ル スを含有する潤滑剤によって解決される。
結合剤としてのカルボキシル化スチレン−ブタジエンラ
テックスは、スチレン含有口が５０％、好ましくは７０
〜８０％のものが用いられる。
テックスは、スチレン含有口が５０％、好ましくは７０
〜８０％のものが用いられる。
水性分散剤としての結合剤は、潤滑剤の他の成分に対し
固形分で４０〜６０重Ｄ％とするのが好ましい。
固形分で４０〜６０重Ｄ％とするのが好ましい。
分散剤は、この場合、本質的には水中で、既に分散して
いる潤滑剤に加えられて、これに結合できるものでなけ
ればならない。
いる潤滑剤に加えられて、これに結合できるものでなけ
ればならない。
潤滑剤の組成は、固体同滑剤または固体潤滑剤混合物、
好ましくは黒鉛を５０〜８０徂０Ｘ％、結合剤を乾燥品
で２０〜５０徂母％、ｄ３よび粘稠剤を０．２〜５．０
重足％を含有してなる。
好ましくは黒鉛を５０〜８０徂０Ｘ％、結合剤を乾燥品
で２０〜５０徂母％、ｄ３よび粘稠剤を０．２〜５．０
重足％を含有してなる。
また、従来、泥膜、乳化剤、殺菌剤および抗酸化剤のよ
うな添加剤を加えることが右利であることが判明してい
る。 個々の添加量は製品仕様ヤ予ｔｉｉｉｉ実験によ
って定めるが、通常は２市■％以下でおる。
うな添加剤を加えることが右利であることが判明してい
る。 個々の添加量は製品仕様ヤ予ｔｉｉｉｉ実験によ
って定めるが、通常は２市■％以下でおる。
本発明による潤滑剤に用いられる個々の成分は、後述す
る製品のグループから選ぶことができる。
る製品のグループから選ぶことができる。
固体潤滑剤としては、黒鉛、ＭＯＳ２ （二酸化モリブ
デン）またはＢＮを用いることができる。
デン）またはＢＮを用いることができる。
これらの固体潤滑剤の中では、黒鉛がとくに良好な結果
を示す。 黒鉛の中でも、純度が高く、たとえば９６％
以上で、粒径が３００μｍ以下のものがすぐれている。
を示す。 黒鉛の中でも、純度が高く、たとえば９６％
以上で、粒径が３００μｍ以下のものがすぐれている。
最良の結果は、純度９９．５％で粒径１ ００ｔ１ｍ
の場合に得られる。
の場合に得られる。
潤滑剤は、水性分散液の１０〜６０重■％の範囲で使用
すべきである。分散液の粘度は、１０〜３０’Ｃで５０
０〜１５０００Ｃｌ）を示すものが好ましい。
すべきである。分散液の粘度は、１０〜３０’Ｃで５０
０〜１５０００Ｃｌ）を示すものが好ましい。
分散液の粘度調整には、粘稠剤または粘稠剤混合物を用
いる。 粘稠剤の具体例としては、水溶性の多糖類、ヒ
ドロキシアルキルセルロースまたはカルボキシメチルセ
ルロース ルキルセルロース、ポリビニルアルコール、ボリアクリ
ル酸とその誘導体、中和または未中和の天然ゴムまたは
その誘導体（たとえばグアル）、ポリビニルピロリドン
、ポリエチレンオキサイド、必要であれば粘土、モンモ
リロナイト、変性モンモリロナイト、ベントナイトなど
の鉱物、および天然ピッチまたは天然アスファルトなど
の充填材がある。
いる。 粘稠剤の具体例としては、水溶性の多糖類、ヒ
ドロキシアルキルセルロースまたはカルボキシメチルセ
ルロース ルキルセルロース、ポリビニルアルコール、ボリアクリ
ル酸とその誘導体、中和または未中和の天然ゴムまたは
その誘導体（たとえばグアル）、ポリビニルピロリドン
、ポリエチレンオキサイド、必要であれば粘土、モンモ
リロナイト、変性モンモリロナイト、ベントナイトなど
の鉱物、および天然ピッチまたは天然アスファルトなど
の充填材がある。
前述したように、潤滑剤は水性分散液の形態で使用され
る。 特許請求の範囲第１項による潤滑剤の水性分散液
は、８０〜３５０’Ｃの温度で工具に塗布できる作用を
もつ。 すなわち、加熱された表面に塗布すると、分散
液の水性担持液が蒸発し、均一な緻密層をもつ潤滑剤の
被膜が形成される。
る。 特許請求の範囲第１項による潤滑剤の水性分散液
は、８０〜３５０’Ｃの温度で工具に塗布できる作用を
もつ。 すなわち、加熱された表面に塗布すると、分散
液の水性担持液が蒸発し、均一な緻密層をもつ潤滑剤の
被膜が形成される。
この潤滑剤の被膜は均一な耐水性の溝道をもち、かつ、
工具を溢れるような人聞の冷却媒体を用いても、洗い流
されたり膨罰したりすることはない。
工具を溢れるような人聞の冷却媒体を用いても、洗い流
されたり膨罰したりすることはない。
本発明による潤滑剤は、たとえば鋼塊または管などの工
作物を加工するために、芯金の挿入を行なう際、とくに
鋼の熱間加工およびいわゆるＭＰＭ工程により鋼塊を継
目無管に圧延加工する際に、また場合によっては、連続
圧延、衝撃加工装置、条鋼圧延またはハンマー鍛造にお
いて、軸、ピストン棒またはダイスなどの工具を潤滑す
るのに好適である。
作物を加工するために、芯金の挿入を行なう際、とくに
鋼の熱間加工およびいわゆるＭＰＭ工程により鋼塊を継
目無管に圧延加工する際に、また場合によっては、連続
圧延、衝撃加工装置、条鋼圧延またはハンマー鍛造にお
いて、軸、ピストン棒またはダイスなどの工具を潤滑す
るのに好適である。
ＭＰＭ工程における芯金の挿入を行なう際に、従来の潤
滑剤に要求されていた事項は、本発明によりすべて完全
に満足される。 とくに８０〜３５０℃の温度で使用し
、加工すると、厚さ１０〜１００ｍμの被膜が形成され
る。 この被膜は耐水性であって、俊続する水冷操作に
よっても、何ら影響を受けない。 軸温度１５０〜２５
０℃では、被膜は良好な機械的性質（たとえば、ジッケ
ンスの割れ試験で割れ硬度６゜５Ｎ＞を示す。 潤滑剤
の耐熱温度は、３５０°Ｃまで全く問題がない。
滑剤に要求されていた事項は、本発明によりすべて完全
に満足される。 とくに８０〜３５０℃の温度で使用し
、加工すると、厚さ１０〜１００ｍμの被膜が形成され
る。 この被膜は耐水性であって、俊続する水冷操作に
よっても、何ら影響を受けない。 軸温度１５０〜２５
０℃では、被膜は良好な機械的性質（たとえば、ジッケ
ンスの割れ試験で割れ硬度６゜５Ｎ＞を示す。 潤滑剤
の耐熱温度は、３５０°Ｃまで全く問題がない。
このような効果は、次に述べる実例でも明らかなように
、従来の潤滑剤では１７られない。
、従来の潤滑剤では１７られない。
止較■−ユ
（ドイツ特許明細書第２４５０７１６号による）粗 成
：固形分３０％、水７０％ 固形分ニア４．３％ 黒 鉛 ２３．２％ ＳＢＲラテックス （スチレン３４％、ラテックスの 固形分換算） ２．０％ アルキルセルロース ０．５％ ケイ酸ナトリウム 粘度：３１００ｃｐｓ、、 ｐＨ＝９．２比較例 ２ （ヨーロッパ特許明細書第０１６／１６３７号による）
粗 成：固形分３０％、水７０％ 固形分：５４．０％ 黒 鉛 １１．０％ ポリリンＦ２（不溶性） ５．０％ ホウ砂 １０．０％ ケイ酸ナトリウム １８．０％ ポリスチレン ２．０％ アルキルセルロース 粘度： ２０００ＣＩ）Ｓ、、 ｐＨ＝１１ 、０叉雁
■（本発明） 組 成：固形分４５％、水５５％ 固形分ニア４．２％ 黒 鉛 ２４．３％ ＳＢＲラテックス （カルボキシル ラテックスの固形分換算） １、０％粘土 ０、５％ 抗酸化剤 粘度： ２８００ｃｐｓ．、 ｐＨ＝８比較例１．２お
よび実施例のように、固形分と分散媒としての水から分
散液を調製し、これを試験のために金属表面、すなわち
前）ボした軸の表面に噴霧、塗布した。 試験結果は第
１表に示す。
：固形分３０％、水７０％ 固形分ニア４．３％ 黒 鉛 ２３．２％ ＳＢＲラテックス （スチレン３４％、ラテックスの 固形分換算） ２．０％ アルキルセルロース ０．５％ ケイ酸ナトリウム 粘度：３１００ｃｐｓ、、 ｐＨ＝９．２比較例 ２ （ヨーロッパ特許明細書第０１６／１６３７号による）
粗 成：固形分３０％、水７０％ 固形分：５４．０％ 黒 鉛 １１．０％ ポリリンＦ２（不溶性） ５．０％ ホウ砂 １０．０％ ケイ酸ナトリウム １８．０％ ポリスチレン ２．０％ アルキルセルロース 粘度： ２０００ＣＩ）Ｓ、、 ｐＨ＝１１ 、０叉雁
■（本発明） 組 成：固形分４５％、水５５％ 固形分ニア４．２％ 黒 鉛 ２４．３％ ＳＢＲラテックス （カルボキシル ラテックスの固形分換算） １、０％粘土 ０、５％ 抗酸化剤 粘度： ２８００ｃｐｓ．、 ｐＨ＝８比較例１．２お
よび実施例のように、固形分と分散媒としての水から分
散液を調製し、これを試験のために金属表面、すなわち
前）ボした軸の表面に噴霧、塗布した。 試験結果は第
１表に示す。
Claims (6)
- （１）鋼を高温で無切削加工する際に用いる、固体潤滑
剤、結合剤および粘稠剤を含む潤滑剤において、結合剤
としてカルボキシル化スチレン−ブタジエンラテックス
を用いることを特徴とする潤滑剤。 - （２）カルボキシル化スチレン−ブタジエンラテックス
のスチレン含有量が５０％以上、好ましくは７０〜８０
％であることを特徴とする特許請求の範囲第１項の潤滑
剤。 - （３）水性分散剤としての結合剤が、潤滑剤の他の成分
に対して固形分で４０〜６０重量％であることを特徴と
する特許請求の範囲第１項または第２項の潤滑剤。 - （４）潤滑剤が、固体潤滑剤とくに黒鉛を５０〜８０重
量％、特許請求の範囲第１項ないし第３項の結合剤を乾
燥品で２０〜５０重量％、そして粘稠剤を０．２〜５．
０重量％含んでいることを特徴とする特許請求の範囲第
１項ないし第３項のいずれかの潤滑剤。 - （５）潤滑剤が水性分散剤として固形分１０〜６０重量
％を含有し、これを熱い工具に塗布して水性担持液を蒸
発させ、高い機械的強度をもつ均一な耐水性の潤滑剤被
膜を形成し、工具を冷却後、無切削加工を開始するよう
にしたことを特徴とする特許請求の範囲第１項ないし第
４項のいずれかの潤滑剤。 - （６）特許請求の範囲第１項による固体潤滑剤、結合剤
および粘稠剤を含有する潤滑剤を用いて、鋼を高温で無
切削加工する際に工具を潤滑する方法において、結合剤
としてカルボキシル化スチレン−ブタジエンラテックス
を用いることを特徴とする方法。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH3800/86A CH669603A5 (ja) | 1986-09-23 | 1986-09-23 | |
| CH3800/86-6 | 1986-09-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6389593A true JPS6389593A (ja) | 1988-04-20 |
| JPH0830198B2 JPH0830198B2 (ja) | 1996-03-27 |
Family
ID=4263721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62234678A Expired - Lifetime JPH0830198B2 (ja) | 1986-09-23 | 1987-09-18 | 鋼の無切削加工用潤滑剤 |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0261438B1 (ja) |
| JP (1) | JPH0830198B2 (ja) |
| CN (1) | CN1011515B (ja) |
| AR (1) | AR243593A1 (ja) |
| AT (1) | ATE55145T1 (ja) |
| CH (1) | CH669603A5 (ja) |
| DE (1) | DE3764052D1 (ja) |
| ES (1) | ES2016603B3 (ja) |
| SU (1) | SU1632373A3 (ja) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0747756B2 (ja) * | 1989-08-09 | 1995-05-24 | 日本電装株式会社 | 金属の冷間塑性加工用水系潤滑処理液 |
| DE69118601T2 (de) * | 1990-07-12 | 1996-09-19 | Daido Machinery | Schmiedeschmiermittel und Verfahren zur Herstellung einer Beschichtung aus Schmiermittel auf der Oberfläche eines linearen Materials |
| CA2088527A1 (en) * | 1992-02-06 | 1993-08-07 | Timcal Ltd. | Mandrel lubricant for manufacturing seamless tubes |
| WO1997002334A1 (de) * | 1995-07-04 | 1997-01-23 | Timcal Ag | Schmiermittel für profilwalzen |
| US7045489B2 (en) | 2000-09-29 | 2006-05-16 | Kelsan Technologies Corp. | Friction control compositions |
| CA2381678C (en) * | 2002-04-12 | 2005-06-21 | Kelsan Technologies Corp. | Friction control composition with enhanced retentivity |
| CN105695076B (zh) * | 2016-02-26 | 2018-09-18 | 常州高特新材料有限公司 | 一种水性金刚线硅片切割液 |
| RU2716499C1 (ru) * | 2019-10-03 | 2020-03-12 | Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) | Способ получения биоразлагаемой низкотемпературной консистентной смазки на основе целлюлозы |
| CN115679195B (zh) * | 2021-07-30 | 2023-10-17 | 宝山钢铁股份有限公司 | 一种汽车驱动轴用无缝钢管及其制造方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2048537A1 (en) * | 1970-10-02 | 1972-04-06 | Chemische Fabrik Budenheim, Rudolf A Oetker, 6501 Budenheim | Lubricants for hot metal - forming - contg mixed inorganic phosphates in polymer binders |
| DE2318086A1 (de) * | 1973-04-11 | 1974-10-31 | Hoechst Ag | Gefrier-tau-stabile polymerlatices als zusatzstoffe zu waessrigen kuehlschmiermitteln |
| US3873458A (en) * | 1973-05-18 | 1975-03-25 | United States Steel Corp | Resin-containing lubricant coatings |
| GB1438215A (en) * | 1974-05-08 | 1976-06-03 | Lonz Ltd | High temperature lubricant |
| US3925214A (en) * | 1974-05-28 | 1975-12-09 | Chemclean Corp | Hot forming lubricant composition, system and method |
| AU499239B2 (en) * | 1974-12-19 | 1979-04-12 | Borg-Warner Chemicals Inc. | Coating composition |
| US4544690A (en) * | 1983-07-27 | 1985-10-01 | Reichhold Chemicals, Incorporated | Aqueous rubberized coal tar emulsion |
-
1986
- 1986-09-23 CH CH3800/86A patent/CH669603A5/de not_active IP Right Cessation
-
1987
- 1987-08-27 EP EP87112493A patent/EP0261438B1/de not_active Expired - Lifetime
- 1987-08-27 DE DE8787112493T patent/DE3764052D1/de not_active Expired - Fee Related
- 1987-08-27 ES ES87112493T patent/ES2016603B3/es not_active Expired - Lifetime
- 1987-08-27 AT AT87112493T patent/ATE55145T1/de not_active IP Right Cessation
- 1987-09-14 CN CN87106375A patent/CN1011515B/zh not_active Expired
- 1987-09-16 SU SU874203328A patent/SU1632373A3/ru active
- 1987-09-18 JP JP62234678A patent/JPH0830198B2/ja not_active Expired - Lifetime
- 1987-09-23 AR AR87308801A patent/AR243593A1/es active
Also Published As
| Publication number | Publication date |
|---|---|
| EP0261438A3 (en) | 1988-12-07 |
| AR243593A1 (es) | 1993-08-31 |
| JPH0830198B2 (ja) | 1996-03-27 |
| CN87106375A (zh) | 1988-04-06 |
| EP0261438B1 (de) | 1990-08-01 |
| DE3764052D1 (de) | 1990-09-06 |
| CH669603A5 (ja) | 1989-03-31 |
| SU1632373A3 (ru) | 1991-02-28 |
| ATE55145T1 (de) | 1990-08-15 |
| CN1011515B (zh) | 1991-02-06 |
| ES2016603B3 (es) | 1990-11-16 |
| EP0261438A2 (de) | 1988-03-30 |
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