JPS6255524B2 - - Google Patents
Info
- Publication number
- JPS6255524B2 JPS6255524B2 JP55123194A JP12319480A JPS6255524B2 JP S6255524 B2 JPS6255524 B2 JP S6255524B2 JP 55123194 A JP55123194 A JP 55123194A JP 12319480 A JP12319480 A JP 12319480A JP S6255524 B2 JPS6255524 B2 JP S6255524B2
- Authority
- JP
- Japan
- Prior art keywords
- polypropylene
- decomposition
- weight
- boiling heptane
- melt index
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 polypropylene Polymers 0.000 claims description 66
- 229920001155 polypropylene Polymers 0.000 claims description 65
- 239000004743 Polypropylene Substances 0.000 claims description 64
- 238000000354 decomposition reaction Methods 0.000 claims description 30
- 238000009835 boiling Methods 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 25
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 47
- 239000000155 melt Substances 0.000 description 15
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 239000008096 xylene Substances 0.000 description 12
- 150000003254 radicals Chemical class 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 6
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 5
- 238000004898 kneading Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000010292 electrical insulation Methods 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- ODBCKCWTWALFKM-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhex-3-yne Chemical compound CC(C)(C)OOC(C)(C)C#CC(C)(C)OOC(C)(C)C ODBCKCWTWALFKM-UHFFFAOYSA-N 0.000 description 1
- IOHPVZBSOKLVMN-UHFFFAOYSA-N 2-(2-phenylethyl)benzoic acid Chemical compound OC(=O)C1=CC=CC=C1CCC1=CC=CC=C1 IOHPVZBSOKLVMN-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- KRDXTHSSNCTAGY-UHFFFAOYSA-N 2-cyclohexylpyrrolidine Chemical compound C1CCNC1C1CCCCC1 KRDXTHSSNCTAGY-UHFFFAOYSA-N 0.000 description 1
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000003608 radiolysis reaction Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010421 standard material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
Landscapes
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12319480A JPS5747305A (en) | 1980-09-04 | 1980-09-04 | Modifying method of polypropylene |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12319480A JPS5747305A (en) | 1980-09-04 | 1980-09-04 | Modifying method of polypropylene |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5747305A JPS5747305A (en) | 1982-03-18 |
JPS6255524B2 true JPS6255524B2 (hr) | 1987-11-20 |
Family
ID=14854512
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12319480A Granted JPS5747305A (en) | 1980-09-04 | 1980-09-04 | Modifying method of polypropylene |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5747305A (hr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0359326U (hr) * | 1989-10-06 | 1991-06-11 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6082335A (ja) * | 1983-10-13 | 1985-05-10 | Ube Ind Ltd | ポリプロピレンバンドの製造法 |
JPS60147403A (ja) * | 1984-01-10 | 1985-08-03 | Mitsui Toatsu Chem Inc | 高流動性耐衝撃性ポリプロピレン樹脂組成物 |
JPS6164426A (ja) * | 1984-09-07 | 1986-04-02 | Ube Ind Ltd | ポリプロピレンシ−トの製造法 |
JPS61211306A (ja) * | 1985-03-15 | 1986-09-19 | Idemitsu Petrochem Co Ltd | 改質ポリプロピレン樹脂の製造方法 |
JP2006016597A (ja) * | 2004-06-01 | 2006-01-19 | Mitsui Chemicals Inc | プロピレン系樹脂組成物およびフィルムへの応用 |
EP2410539B1 (en) | 2009-03-17 | 2019-02-20 | Prime Polymer Co., Ltd. | Polypropylene for film capacitor, polypropylene sheet for film capacitor, methods for producing same, and uses of same |
JP5617655B2 (ja) * | 2011-01-19 | 2014-11-05 | 王子ホールディングス株式会社 | コンデンサー用ポリプロピレンフィルム |
JP2014195110A (ja) * | 2014-05-26 | 2014-10-09 | Prime Polymer Co Ltd | フィルムコンデンサ用ポリプロピレンフィルムの製造方法 |
TW202110646A (zh) * | 2019-07-10 | 2021-03-16 | 日商東洋紡股份有限公司 | 雙軸配向聚丙烯系樹脂膜及使用該雙軸配向聚丙烯系樹脂膜之包裝體 |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4856749A (hr) * | 1971-11-20 | 1973-08-09 | ||
JPS4879851A (hr) * | 1972-01-28 | 1973-10-26 | ||
JPS4892456A (hr) * | 1972-03-11 | 1973-11-30 | ||
JPS506019A (hr) * | 1973-05-21 | 1975-01-22 | ||
JPS5021053A (hr) * | 1973-05-21 | 1975-03-06 | ||
JPS5148196A (ja) * | 1974-10-23 | 1976-04-24 | Hitachi Cable | Keeburutanmatsubu |
JPS51133393A (en) * | 1975-05-15 | 1976-11-19 | Showa Denko Kk | A process for manufacturing a propylene copolymer |
JPS5219595A (en) * | 1975-08-06 | 1977-02-14 | Sumitomo Chem Co Ltd | Method and apparatus for automatic arresting of ions in water |
JPS5415592A (en) * | 1977-07-04 | 1979-02-05 | Seiko Seiki Kk | Cylindrical grinding machine |
JPS5470388A (en) * | 1977-11-16 | 1979-06-06 | Mitsubishi Chem Ind Ltd | Production of olefin polymer |
JPS5581125A (en) * | 1978-12-13 | 1980-06-18 | Sumitomo Chem Co Ltd | Drawn polypropylene film |
JPS5592712A (en) * | 1978-12-29 | 1980-07-14 | Sumitomo Chem Co Ltd | Insulating polypropylene |
-
1980
- 1980-09-04 JP JP12319480A patent/JPS5747305A/ja active Granted
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4856749A (hr) * | 1971-11-20 | 1973-08-09 | ||
JPS4879851A (hr) * | 1972-01-28 | 1973-10-26 | ||
JPS4892456A (hr) * | 1972-03-11 | 1973-11-30 | ||
JPS506019A (hr) * | 1973-05-21 | 1975-01-22 | ||
JPS5021053A (hr) * | 1973-05-21 | 1975-03-06 | ||
JPS5148196A (ja) * | 1974-10-23 | 1976-04-24 | Hitachi Cable | Keeburutanmatsubu |
JPS51133393A (en) * | 1975-05-15 | 1976-11-19 | Showa Denko Kk | A process for manufacturing a propylene copolymer |
JPS5219595A (en) * | 1975-08-06 | 1977-02-14 | Sumitomo Chem Co Ltd | Method and apparatus for automatic arresting of ions in water |
JPS5415592A (en) * | 1977-07-04 | 1979-02-05 | Seiko Seiki Kk | Cylindrical grinding machine |
JPS5470388A (en) * | 1977-11-16 | 1979-06-06 | Mitsubishi Chem Ind Ltd | Production of olefin polymer |
JPS5581125A (en) * | 1978-12-13 | 1980-06-18 | Sumitomo Chem Co Ltd | Drawn polypropylene film |
JPS5592712A (en) * | 1978-12-29 | 1980-07-14 | Sumitomo Chem Co Ltd | Insulating polypropylene |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0359326U (hr) * | 1989-10-06 | 1991-06-11 |
Also Published As
Publication number | Publication date |
---|---|
JPS5747305A (en) | 1982-03-18 |
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