JPS62156172A - 水中防汚被覆剤 - Google Patents
水中防汚被覆剤Info
- Publication number
- JPS62156172A JPS62156172A JP29891885A JP29891885A JPS62156172A JP S62156172 A JPS62156172 A JP S62156172A JP 29891885 A JP29891885 A JP 29891885A JP 29891885 A JP29891885 A JP 29891885A JP S62156172 A JPS62156172 A JP S62156172A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- coating
- monomer
- copolymer
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 58
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 48
- 239000000178 monomer Substances 0.000 claims abstract description 47
- 229920001577 copolymer Polymers 0.000 claims abstract description 32
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 30
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 10
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 53
- 229920000642 polymer Polymers 0.000 abstract description 51
- -1 polydimethylsiloxane group Polymers 0.000 abstract description 23
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 7
- 239000000306 component Substances 0.000 abstract 3
- 239000000243 solution Substances 0.000 description 38
- 239000010408 film Substances 0.000 description 34
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 20
- 238000003756 stirring Methods 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 17
- 229920002379 silicone rubber Polymers 0.000 description 15
- 239000004945 silicone rubber Substances 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 238000001035 drying Methods 0.000 description 12
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 12
- 239000011259 mixed solution Substances 0.000 description 12
- 239000013535 sea water Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 239000002904 solvent Substances 0.000 description 11
- 238000003860 storage Methods 0.000 description 11
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 10
- 239000008096 xylene Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 239000004342 Benzoyl peroxide Substances 0.000 description 8
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 8
- 235000019400 benzoyl peroxide Nutrition 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- DCERHCFNWRGHLK-UHFFFAOYSA-N C[Si](C)C Chemical group C[Si](C)C DCERHCFNWRGHLK-UHFFFAOYSA-N 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000010422 painting Methods 0.000 description 5
- 239000002966 varnish Substances 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000004264 Petrolatum Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000006482 condensation reaction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229940066842 petrolatum Drugs 0.000 description 3
- 235000019271 petrolatum Nutrition 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 239000002519 antifouling agent Substances 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 230000036314 physical performance Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000011345 viscous material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000007227 biological adhesion Effects 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-AATRIKPKSA-N diethyl fumarate Chemical compound CCOC(=O)\C=C\C(=O)OCC IEPRKVQEAMIZSS-AATRIKPKSA-N 0.000 description 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 description 1
- 229960004419 dimethyl fumarate Drugs 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- YFMFSCRSAWIWOP-UHFFFAOYSA-N phenyl(trityl)diazene Chemical compound C1=CC=CC=C1N=NC(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 YFMFSCRSAWIWOP-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000003902 seawater pollution Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- LPUCKLOWOWADAC-UHFFFAOYSA-M tributylstannyl 2-methylprop-2-enoate Chemical compound CCCC[Sn](CCCC)(CCCC)OC(=O)C(C)=C LPUCKLOWOWADAC-UHFFFAOYSA-M 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29891885A JPS62156172A (ja) | 1985-12-27 | 1985-12-27 | 水中防汚被覆剤 |
| CA000526215A CA1274649A (en) | 1985-12-27 | 1986-12-23 | Antifouling coating |
| GB8630822A GB2188938B (en) | 1985-12-27 | 1986-12-23 | Antifouling coating composition comprising a polymer having siloxane and/or alkylsilyl groups |
| NO865269A NO177464C (no) | 1985-12-27 | 1986-12-23 | Anvendelse av en Si-holdig polymer som et bindemiddel i en antigromaling |
| US07/209,813 US4883852A (en) | 1985-12-27 | 1988-06-22 | Antifouling coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29891885A JPS62156172A (ja) | 1985-12-27 | 1985-12-27 | 水中防汚被覆剤 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62156172A true JPS62156172A (ja) | 1987-07-11 |
| JPH0560503B2 JPH0560503B2 (enrdf_load_stackoverflow) | 1993-09-02 |
Family
ID=17865861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29891885A Granted JPS62156172A (ja) | 1985-12-27 | 1985-12-27 | 水中防汚被覆剤 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62156172A (enrdf_load_stackoverflow) |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62290768A (ja) * | 1986-06-10 | 1987-12-17 | Kansai Paint Co Ltd | 防汚塗料組成物 |
| JPS636067A (ja) * | 1986-06-26 | 1988-01-12 | Nippon Paint Co Ltd | 撥水型防汚塗料組成物 |
| JPS63168469A (ja) * | 1986-12-29 | 1988-07-12 | Shin Etsu Chem Co Ltd | 室温硬化性塗料組成物 |
| JPS6429475A (en) * | 1987-07-24 | 1989-01-31 | Shinetsu Chemical Co | Antifouling paint composition |
| JPH01284513A (ja) * | 1988-05-11 | 1989-11-15 | Chuo Rika Kogyo Kk | アクリル系エマルジョン組成物 |
| JPH01319518A (ja) * | 1988-06-20 | 1989-12-25 | Nisshin Kagaku Kogyo Kk | シリコーン／アクリル共重合体組成物 |
| WO1991016383A1 (en) * | 1990-04-25 | 1991-10-31 | Kansai Paint Company, Limited | Automotive topcoating composition |
| JPH05230161A (ja) * | 1992-02-18 | 1993-09-07 | Shin Etsu Chem Co Ltd | グラフト共重合体及びそれを用いた被覆組成物 |
| US5409994A (en) * | 1990-04-25 | 1995-04-25 | Kansai Paint Company, Limited | Automotive top coating composition |
| WO1996014214A1 (fr) * | 1994-11-07 | 1996-05-17 | Sony Chemicals Corporation | Materiau d'impression par transfert thermique |
| CN1040990C (zh) * | 1993-07-15 | 1998-12-02 | 中国科学院兰州化学物理研究所 | 单组份防污涂料 |
| JPH11263937A (ja) * | 1998-03-19 | 1999-09-28 | Nof Corp | 複層塗膜および防汚方法 |
| JP2003268300A (ja) * | 2002-03-14 | 2003-09-25 | Nippon Yushi Basf Coatings Kk | 自動車外板用上塗り塗料、塗装方法、及び塗膜 |
| JP2006503159A (ja) * | 2002-10-15 | 2006-01-26 | ナルコ エナジー サーヴィシーズ，エル．ピー． | （メタ）アクリル酸の工程において汚れの付着を防止するための組成物及び方法 |
| EP1974951A1 (en) | 2007-03-30 | 2008-10-01 | FUJIFILM Corporation | Coating composition for thermal transfer image-receiving sheet, and thermal transfer image-receiving sheet |
| US7670743B2 (en) | 2005-03-04 | 2010-03-02 | Ricoh Company, Ltd. | Image forming method |
| US7785762B2 (en) | 2005-12-15 | 2010-08-31 | Ricoh Company, Ltd. | Image forming apparatus and image forming method |
| US7928175B2 (en) | 2003-03-14 | 2011-04-19 | Mitsubishi Rayon Co., Ltd. | Antifouling paint composition |
| US10409129B2 (en) | 2016-05-11 | 2019-09-10 | Ricoh Company, Ltd. | Electrochromic element |
| US10429710B2 (en) | 2016-05-13 | 2019-10-01 | Ricoh Company, Ltd. | Electrochromic device |
| US10975296B2 (en) | 2017-01-26 | 2021-04-13 | Ricoh Company, Ltd. | Electrochromic compound, electrochromic composition, and electrochromic element |
| US11106106B2 (en) | 2018-03-19 | 2021-08-31 | Ricoh Company, Ltd. | Electrochromic device, electronic dimming eyeglasses, augmented reality eyeglasses, and camera |
| US11370963B2 (en) | 2018-07-25 | 2022-06-28 | Ricoh Company, Ltd. | Electrochromic compound, electrochromic composition, and electrochromic element |
| US11859131B2 (en) | 2018-07-25 | 2024-01-02 | Ricoh Company, Ltd. | Electrochromic compound, electrochromic composition, and electrochromic element |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4118356B2 (ja) * | 1996-12-12 | 2008-07-16 | 日本ペイント株式会社 | 防汚塗料組成物 |
| US8335456B2 (en) | 2006-04-17 | 2012-12-18 | Ricoh Company, Ltd. | Image forming apparatus, image forming method, and process cartridge |
| EP2078988B1 (en) | 2008-01-10 | 2013-06-26 | Ricoh Company, Ltd. | Image forming apparatus and image forming method |
| JP5402279B2 (ja) | 2008-06-27 | 2014-01-29 | 株式会社リコー | 電子写真感光体、その製造方法、及びそれを使用した画像形成装置 |
| JP6786858B2 (ja) | 2015-06-19 | 2020-11-18 | 株式会社リコー | エレクトロクロミック化合物及びエレクトロクロミック組成物 |
| JP2018136468A (ja) | 2017-02-23 | 2018-08-30 | 株式会社リコー | エレクトロクロミック表示装置及びその製造方法 |
| EP3712695B1 (en) | 2019-03-20 | 2022-02-23 | Ricoh Company, Ltd. | Electrochromic device, wearable device, and method for driving electrochromic device |
| EP3771736B1 (en) | 2019-07-31 | 2023-11-15 | Ricoh Company, Ltd. | Electrochromic element |
| US12091612B2 (en) | 2020-03-30 | 2024-09-17 | Ricoh Company, Ltd. | Electrochromic element |
| JP7472705B2 (ja) | 2020-07-29 | 2024-04-23 | 株式会社リコー | エレクトロクロミック素子、エレクトロクロミック調光素子、及びエレクトロクロミック装置 |
| WO2022113702A1 (en) | 2020-11-30 | 2022-06-02 | Ricoh Company, Ltd. | Electrochromic compound, electrochromic composition, and electrochromic element |
-
1985
- 1985-12-27 JP JP29891885A patent/JPS62156172A/ja active Granted
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62290768A (ja) * | 1986-06-10 | 1987-12-17 | Kansai Paint Co Ltd | 防汚塗料組成物 |
| JPS636067A (ja) * | 1986-06-26 | 1988-01-12 | Nippon Paint Co Ltd | 撥水型防汚塗料組成物 |
| JPS63168469A (ja) * | 1986-12-29 | 1988-07-12 | Shin Etsu Chem Co Ltd | 室温硬化性塗料組成物 |
| JPS6429475A (en) * | 1987-07-24 | 1989-01-31 | Shinetsu Chemical Co | Antifouling paint composition |
| JPH01284513A (ja) * | 1988-05-11 | 1989-11-15 | Chuo Rika Kogyo Kk | アクリル系エマルジョン組成物 |
| JPH01319518A (ja) * | 1988-06-20 | 1989-12-25 | Nisshin Kagaku Kogyo Kk | シリコーン／アクリル共重合体組成物 |
| WO1991016383A1 (en) * | 1990-04-25 | 1991-10-31 | Kansai Paint Company, Limited | Automotive topcoating composition |
| US5409994A (en) * | 1990-04-25 | 1995-04-25 | Kansai Paint Company, Limited | Automotive top coating composition |
| JPH05230161A (ja) * | 1992-02-18 | 1993-09-07 | Shin Etsu Chem Co Ltd | グラフト共重合体及びそれを用いた被覆組成物 |
| CN1040990C (zh) * | 1993-07-15 | 1998-12-02 | 中国科学院兰州化学物理研究所 | 单组份防污涂料 |
| WO1996014214A1 (fr) * | 1994-11-07 | 1996-05-17 | Sony Chemicals Corporation | Materiau d'impression par transfert thermique |
| JPH11263937A (ja) * | 1998-03-19 | 1999-09-28 | Nof Corp | 複層塗膜および防汚方法 |
| JP2003268300A (ja) * | 2002-03-14 | 2003-09-25 | Nippon Yushi Basf Coatings Kk | 自動車外板用上塗り塗料、塗装方法、及び塗膜 |
| JP2006503159A (ja) * | 2002-10-15 | 2006-01-26 | ナルコ エナジー サーヴィシーズ，エル．ピー． | （メタ）アクリル酸の工程において汚れの付着を防止するための組成物及び方法 |
| US7928175B2 (en) | 2003-03-14 | 2011-04-19 | Mitsubishi Rayon Co., Ltd. | Antifouling paint composition |
| US7670743B2 (en) | 2005-03-04 | 2010-03-02 | Ricoh Company, Ltd. | Image forming method |
| US7785762B2 (en) | 2005-12-15 | 2010-08-31 | Ricoh Company, Ltd. | Image forming apparatus and image forming method |
| EP1974951A1 (en) | 2007-03-30 | 2008-10-01 | FUJIFILM Corporation | Coating composition for thermal transfer image-receiving sheet, and thermal transfer image-receiving sheet |
| US10409129B2 (en) | 2016-05-11 | 2019-09-10 | Ricoh Company, Ltd. | Electrochromic element |
| US10429710B2 (en) | 2016-05-13 | 2019-10-01 | Ricoh Company, Ltd. | Electrochromic device |
| US10975296B2 (en) | 2017-01-26 | 2021-04-13 | Ricoh Company, Ltd. | Electrochromic compound, electrochromic composition, and electrochromic element |
| US11106106B2 (en) | 2018-03-19 | 2021-08-31 | Ricoh Company, Ltd. | Electrochromic device, electronic dimming eyeglasses, augmented reality eyeglasses, and camera |
| US11370963B2 (en) | 2018-07-25 | 2022-06-28 | Ricoh Company, Ltd. | Electrochromic compound, electrochromic composition, and electrochromic element |
| US11859131B2 (en) | 2018-07-25 | 2024-01-02 | Ricoh Company, Ltd. | Electrochromic compound, electrochromic composition, and electrochromic element |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0560503B2 (enrdf_load_stackoverflow) | 1993-09-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS62156172A (ja) | 水中防汚被覆剤 | |
| US5116611A (en) | Antifouling paint | |
| TWI343404B (en) | Silyl ester copolymer compositions | |
| KR960005430B1 (ko) | 방오 페인트 | |
| JP6979791B2 (ja) | 両親媒性ブロック共重合体を利用した塗料用レベリング剤 | |
| US4883852A (en) | Antifouling coating | |
| JP2017507203A (ja) | 改善されたオープンタイムを有する水溶型コーティング組成物 | |
| GB2559454B (en) | A silyl ester copolymer and use thereof in an antifouling composition | |
| CN110467860B (zh) | 防污涂料组合物 | |
| JPS62283167A (ja) | 水中防汚被覆剤 | |
| JP2775862B2 (ja) | 生物付着防止塗料組成物 | |
| JP2600813B2 (ja) | 水中防汚被覆剤 | |
| JPH0446306B2 (enrdf_load_stackoverflow) | ||
| JP2002348536A (ja) | 防汚塗料組成物及びその塗膜 | |
| JPH011773A (ja) | 水中防汚被覆剤 | |
| JP3510975B2 (ja) | 硬化性樹脂組成物 | |
| JPS63110268A (ja) | 水中防汚被覆剤 | |
| JPH02674A (ja) | 水中防汚被覆剤 | |
| JP2775861B2 (ja) | 生物付着防止塗料組成物 | |
| JPH01121374A (ja) | 水中防汚被覆剤 | |
| JP3957790B2 (ja) | 塗料用組成物 | |
| JPS63168476A (ja) | 水中防汚被覆剤 | |
| JPH0335065A (ja) | 水中防汚被覆剤 | |
| JPH01252677A (ja) | 水中防汚被覆剤 | |
| JPH01121372A (ja) | 水中防汚被覆剤 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |