JPS6214905A - 微孔性膜の製造方法 - Google Patents
微孔性膜の製造方法Info
- Publication number
- JPS6214905A JPS6214905A JP60155722A JP15572285A JPS6214905A JP S6214905 A JPS6214905 A JP S6214905A JP 60155722 A JP60155722 A JP 60155722A JP 15572285 A JP15572285 A JP 15572285A JP S6214905 A JPS6214905 A JP S6214905A
- Authority
- JP
- Japan
- Prior art keywords
- membrane
- alcohol
- treatment
- microporous
- microporous membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 238000000034 method Methods 0.000 title abstract description 6
- 239000012528 membrane Substances 0.000 claims abstract description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000012982 microporous membrane Substances 0.000 claims abstract description 16
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- 229920002492 poly(sulfone) Polymers 0.000 claims abstract description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 10
- 239000011550 stock solution Substances 0.000 claims description 7
- 238000005345 coagulation Methods 0.000 claims description 6
- 230000015271 coagulation Effects 0.000 claims description 6
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003495 polar organic solvent Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- -1 polypropylene Polymers 0.000 abstract description 8
- 239000003960 organic solvent Substances 0.000 abstract description 5
- 239000004743 Polypropylene Substances 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 4
- 229920001155 polypropylene Polymers 0.000 abstract description 4
- 238000005406 washing Methods 0.000 abstract description 4
- 229920002678 cellulose Polymers 0.000 abstract description 3
- 230000001112 coagulating effect Effects 0.000 abstract description 3
- 239000004642 Polyimide Substances 0.000 abstract description 2
- 229920001721 polyimide Polymers 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 239000004952 Polyamide Substances 0.000 abstract 1
- 244000052616 bacterial pathogen Species 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 238000001914 filtration Methods 0.000 description 23
- 239000011148 porous material Substances 0.000 description 11
- 239000002904 solvent Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 210000004907 gland Anatomy 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000004953 Aliphatic polyamide Substances 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229920003231 aliphatic polyamide Polymers 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- CTTJWXVQRJUJQW-UHFFFAOYSA-N 2,2-dioctyl-3-sulfobutanedioic acid Chemical compound CCCCCCCCC(C(O)=O)(C(C(O)=O)S(O)(=O)=O)CCCCCCCC CTTJWXVQRJUJQW-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- FDSGHYHRLSWSLQ-UHFFFAOYSA-N dichloromethane;propan-2-one Chemical compound ClCCl.CC(C)=O FDSGHYHRLSWSLQ-UHFFFAOYSA-N 0.000 description 1
- 229960000878 docusate sodium Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
- B01D71/34—Polyvinylidene fluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
- B01D67/0013—Casting processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/12—Specific ratios of components used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60155722A JPS6214905A (ja) | 1985-07-15 | 1985-07-15 | 微孔性膜の製造方法 |
| GB8701193A GB2199786B (en) | 1985-07-15 | 1987-01-20 | Polymeric micro-porous membranes and their production |
| DE19873701633 DE3701633A1 (de) | 1985-07-15 | 1987-01-21 | Mikroporoese membran |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60155722A JPS6214905A (ja) | 1985-07-15 | 1985-07-15 | 微孔性膜の製造方法 |
| GB8701193A GB2199786B (en) | 1985-07-15 | 1987-01-20 | Polymeric micro-porous membranes and their production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6214905A true JPS6214905A (ja) | 1987-01-23 |
| JPH057047B2 JPH057047B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-01-28 |
Family
ID=39339878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60155722A Granted JPS6214905A (ja) | 1985-07-15 | 1985-07-15 | 微孔性膜の製造方法 |
Country Status (3)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109847585A (zh) * | 2018-12-20 | 2019-06-07 | 时代沃顿科技有限公司 | 复合纳滤膜的制备方法和由其制备的复合纳滤膜 |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR8807283A (pt) * | 1987-11-06 | 1990-02-13 | Dow Chemical Co | Membranas semi-permeaveis com regiao discriminatoria interna |
| DE3829752A1 (de) * | 1988-09-01 | 1990-03-22 | Akzo Gmbh | Integrale asymmetrische polyaethersulfonmembran, verfahren zur herstellung und verwendung zur ultrafiltration und mikrofiltration |
| US4902422A (en) * | 1988-12-06 | 1990-02-20 | Board Regents The University Of Texas System | Defect-free ultrahigh flux asymmetric membranes |
| ATE139713T1 (de) * | 1991-03-12 | 1996-07-15 | Toray Industries | Verfahren zur herstellung einer teildurchlässigen verbundmembran |
| US5188734A (en) * | 1991-03-26 | 1993-02-23 | Memtec America Corporation | Ultraporous and microporous integral membranes |
| US5480554A (en) * | 1992-05-13 | 1996-01-02 | Pall Corporation | Integrity-testable wet-dry-reversible ultrafiltration membranes and method for testing same |
| US6277281B1 (en) * | 1994-03-04 | 2001-08-21 | Usf Filtration And Separations Group Inc. | Large pore synthetic polymer membranes |
| DE69534208T2 (de) * | 1994-03-04 | 2005-11-10 | Pall Corp. | Gross-porige Membranen aus synthetischen Polymeren |
| DE4421871C2 (de) * | 1994-06-23 | 1997-06-19 | Seitz Filter Werke | Mehrschichtige Mikrofiltrationsmembran mit integrierter Vorfilterschicht und Verfahren zu ihrer Herstellung |
| US5834107A (en) * | 1996-01-22 | 1998-11-10 | Usf Filtration And Separations Group Inc. | Highly porous polyvinylidene difluoride membranes |
| JP2001504227A (ja) * | 1996-11-14 | 2001-03-27 | ポール・コーポレーション | 膜とその調製方法及び使用方法 |
| US6045899A (en) | 1996-12-12 | 2000-04-04 | Usf Filtration & Separations Group, Inc. | Highly assymetric, hydrophilic, microfiltration membranes having large pore diameters |
| US6146747A (en) * | 1997-01-22 | 2000-11-14 | Usf Filtration And Separations Group Inc. | Highly porous polyvinylidene difluoride membranes |
| US5958989A (en) | 1997-07-08 | 1999-09-28 | Usf Filtration And Separations Group, Inc. | Highly asymmetric ultrafiltration membranes |
| ES2151815B1 (es) * | 1998-05-18 | 2001-08-16 | Consejo Superior Investigacion | Procedimiento para la preparacion de membranas de carbono para la separacion de gases permanentes. |
| AT408656B (de) * | 1998-06-04 | 2002-02-25 | Chemiefaser Lenzing Ag | Verfahren zur herstellung cellulosischer formkörper |
| WO2001089673A2 (en) * | 2000-05-24 | 2001-11-29 | Millipore Corporation | Process of forming multilayered structures |
| AU2003222676B2 (en) | 2002-05-10 | 2009-04-23 | Anteo Technologies Pty Ltd | Generation of surface coating diversity |
| US7881871B2 (en) | 2003-12-12 | 2011-02-01 | Bio-Layer Pty Limited | Method for designing surfaces |
| EP1773866B1 (en) | 2004-07-02 | 2013-06-19 | Bio-Layer Pty Limited | Use of metal complexes |
| EP1721657A1 (en) * | 2005-05-13 | 2006-11-15 | SONY DEUTSCHLAND GmbH | A method of fabricating a polymeric membrane having at least one pore |
| FR2958190B1 (fr) * | 2010-04-01 | 2012-05-18 | Commissariat Energie Atomique | Procede de formation d'un film en polymere fluore de type polyfluorure de vinylidene utilisable comme separateur pour accumulateur au lithium |
| DE102011114634A1 (de) | 2011-10-04 | 2013-04-04 | Mn-Beteiligungs Gmbh | Abrasionsbeständige Membran und Verfahren zu ihrer Herstellung |
| US10532329B2 (en) | 2013-11-14 | 2020-01-14 | Entegris, Inc. | Microporous polyamide-imide membranes |
| DE102018004521A1 (de) | 2018-06-07 | 2019-12-12 | Sartorius Stedim Biotech Gmbh | Serielle Anordnung mit mehreren Lagen asymmetrischer Filtermedien, Herstellungsverfahren, Filtrationseinheit, Verwendung der Anordnung und Charakterisierungsverfahren |
| KR20210129131A (ko) * | 2019-03-14 | 2021-10-27 | 데이진 가부시키가이샤 | 생물학적 입자의 농축막, 농축 디바이스, 농축 시스템 및 농축 방법, 그리고 생물학적 입자의 검출 방법 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50756A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1973-05-02 | 1975-01-07 | ||
| JPS5382669A (en) * | 1976-12-29 | 1978-07-21 | Kuraray Co Ltd | Preparation of dry separating membrane |
-
1985
- 1985-07-15 JP JP60155722A patent/JPS6214905A/ja active Granted
-
1987
- 1987-01-20 GB GB8701193A patent/GB2199786B/en not_active Expired - Lifetime
- 1987-01-21 DE DE19873701633 patent/DE3701633A1/de not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50756A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1973-05-02 | 1975-01-07 | ||
| JPS5382669A (en) * | 1976-12-29 | 1978-07-21 | Kuraray Co Ltd | Preparation of dry separating membrane |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109847585A (zh) * | 2018-12-20 | 2019-06-07 | 时代沃顿科技有限公司 | 复合纳滤膜的制备方法和由其制备的复合纳滤膜 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2199786A (en) | 1988-07-20 |
| JPH057047B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-01-28 |
| GB8701193D0 (en) | 1987-02-25 |
| DE3701633A1 (de) | 1988-08-04 |
| GB2199786B (en) | 1990-03-28 |
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