JPS6131047B2 - - Google Patents
Info
- Publication number
- JPS6131047B2 JPS6131047B2 JP56094172A JP9417281A JPS6131047B2 JP S6131047 B2 JPS6131047 B2 JP S6131047B2 JP 56094172 A JP56094172 A JP 56094172A JP 9417281 A JP9417281 A JP 9417281A JP S6131047 B2 JPS6131047 B2 JP S6131047B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- discharged
- reaction
- crystals
- organic solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005406 washing Methods 0.000 claims description 40
- 238000006243 chemical reaction Methods 0.000 claims description 39
- 239000007788 liquid Substances 0.000 claims description 38
- 239000013078 crystal Substances 0.000 claims description 34
- 238000004140 cleaning Methods 0.000 claims description 30
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 claims description 26
- 239000012452 mother liquor Substances 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 17
- 239000003960 organic solvent Substances 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 9
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 8
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 239000007810 chemical reaction solvent Substances 0.000 claims description 5
- -1 formic acid compound Chemical class 0.000 claims description 5
- 230000002401 inhibitory effect Effects 0.000 claims description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 claims description 3
- FWFSEYBSWVRWGL-UHFFFAOYSA-N cyclohexene oxide Natural products O=C1CCCC=C1 FWFSEYBSWVRWGL-UHFFFAOYSA-N 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical group 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 125000003107 substituted aryl group Chemical group 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 87
- 239000000243 solution Substances 0.000 description 29
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 18
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000001569 carbon dioxide Substances 0.000 description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 description 9
- 239000007789 gas Substances 0.000 description 9
- 239000011259 mixed solution Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000004280 Sodium formate Substances 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 5
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 5
- 235000019254 sodium formate Nutrition 0.000 description 5
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 3
- 235000019345 sodium thiosulphate Nutrition 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002683 reaction inhibitor Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- GKIPXFAANLTWBM-UHFFFAOYSA-N epibromohydrin Chemical compound BrCC1CO1 GKIPXFAANLTWBM-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N sulfur dioxide Inorganic materials O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 1
- 235000010269 sulphur dioxide Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/64—Thiosulfates; Dithionites; Polythionates
- C01B17/66—Dithionites or hydrosulfites (S2O42-)
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56094172A JPS57209809A (en) | 1981-06-18 | 1981-06-18 | Preparation of dithionite |
| US06/386,059 US4388291A (en) | 1981-06-18 | 1982-06-07 | Process for the production of dithionites |
| IN664/CAL/82A IN155274B (en, 2012) | 1981-06-18 | 1982-06-10 | |
| DE8282105148T DE3261938D1 (en) | 1981-06-18 | 1982-06-12 | Process for the production of dithionites |
| EP82105148A EP0068248B1 (en) | 1981-06-18 | 1982-06-12 | Process for the production of dithionites |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56094172A JPS57209809A (en) | 1981-06-18 | 1981-06-18 | Preparation of dithionite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57209809A JPS57209809A (en) | 1982-12-23 |
| JPS6131047B2 true JPS6131047B2 (en, 2012) | 1986-07-17 |
Family
ID=14102919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56094172A Granted JPS57209809A (en) | 1981-06-18 | 1981-06-18 | Preparation of dithionite |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4388291A (en, 2012) |
| EP (1) | EP0068248B1 (en, 2012) |
| JP (1) | JPS57209809A (en, 2012) |
| DE (1) | DE3261938D1 (en, 2012) |
| IN (1) | IN155274B (en, 2012) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5941925B2 (ja) * | 1980-03-06 | 1984-10-11 | 三菱瓦斯化学株式会社 | 亜二チオン酸塩の製造法 |
| US4590058A (en) * | 1985-02-21 | 1986-05-20 | Olin Corporation | Process for producing high purity solutions of alkali metal hydrosulfites |
| US4622216A (en) * | 1985-08-06 | 1986-11-11 | Virginia Chemicals, Inc. | Treatment of sodium dithionite reaction mixture |
| US7759273B2 (en) * | 2005-04-20 | 2010-07-20 | Cabot Corporation | Methods of forming an alkali metal salt |
| EP3980378A4 (en) | 2019-06-10 | 2023-07-26 | Silox Canada Inc. | METHOD AND SYSTEM FOR PRODUCTION OF SODIUM HYDROSULPHITE CRYSTALS |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1434541A (fr) * | 1964-04-14 | 1966-04-08 | Zoutindustrie | Compositions sèches contenant du dithionite stabilisé |
| US3927190A (en) * | 1966-05-16 | 1975-12-16 | Mitsubishi Gas Chemical Co | Method for producing anhydrous hydrosulfite |
| US3718732A (en) * | 1971-01-13 | 1973-02-27 | Virginia Chemicals Inc | Method of recovering chemical values from a formate-sodium hydrosulfite reaction mixture |
| JPS516113B2 (en, 2012) * | 1972-11-28 | 1976-02-25 | ||
| US3961034A (en) * | 1974-09-25 | 1976-06-01 | Virginia Chemicals Inc. | Method of removing sodium thiosulfate from a hydrosulfite reaction mixture |
| JPS51136597A (en) * | 1975-05-21 | 1976-11-26 | Mitsui Toatsu Chem Inc | Method for processing mother solution of sodium dithionite anhydride production |
| JPS51136596A (en) * | 1975-05-21 | 1976-11-26 | Mitsui Toatsu Chem Inc | Method for processing mot her liquid in the production of sodium dithionite |
| JPS5941925B2 (ja) * | 1980-03-06 | 1984-10-11 | 三菱瓦斯化学株式会社 | 亜二チオン酸塩の製造法 |
-
1981
- 1981-06-18 JP JP56094172A patent/JPS57209809A/ja active Granted
-
1982
- 1982-06-07 US US06/386,059 patent/US4388291A/en not_active Expired - Lifetime
- 1982-06-10 IN IN664/CAL/82A patent/IN155274B/en unknown
- 1982-06-12 EP EP82105148A patent/EP0068248B1/en not_active Expired
- 1982-06-12 DE DE8282105148T patent/DE3261938D1/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0068248A1 (en) | 1983-01-05 |
| EP0068248B1 (en) | 1985-01-16 |
| IN155274B (en, 2012) | 1985-01-12 |
| DE3261938D1 (en) | 1985-02-28 |
| US4388291A (en) | 1983-06-14 |
| JPS57209809A (en) | 1982-12-23 |
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