JPS61171708A - 耐熱性樹脂、その製造法およびそれからなる光学用素子 - Google Patents
耐熱性樹脂、その製造法およびそれからなる光学用素子Info
- Publication number
- JPS61171708A JPS61171708A JP59262868A JP26286884A JPS61171708A JP S61171708 A JPS61171708 A JP S61171708A JP 59262868 A JP59262868 A JP 59262868A JP 26286884 A JP26286884 A JP 26286884A JP S61171708 A JPS61171708 A JP S61171708A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- acrylic acid
- aromatic vinyl
- methacrylic acid
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920006015 heat resistant resin Polymers 0.000 title claims 5
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 230000003287 optical effect Effects 0.000 title description 6
- 239000000178 monomer Substances 0.000 claims abstract description 14
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 238000010557 suspension polymerization reaction Methods 0.000 claims abstract description 6
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims abstract 8
- -1 aromatic vinyl compound Chemical class 0.000 claims abstract 7
- 229920002554 vinyl polymer Polymers 0.000 claims abstract 7
- 125000000217 alkyl group Chemical group 0.000 claims abstract 4
- 229910052700 potassium Inorganic materials 0.000 claims abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 3
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract 3
- 239000003792 electrolyte Substances 0.000 claims abstract 2
- 229910052736 halogen Inorganic materials 0.000 claims abstract 2
- 150000002367 halogens Chemical class 0.000 claims abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 229910052744 lithium Inorganic materials 0.000 claims 3
- 239000000126 substance Substances 0.000 claims 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 150000003863 ammonium salts Chemical class 0.000 claims 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- 239000011591 potassium Substances 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- USNWAMPROKAEIT-UHFFFAOYSA-N [Na].C(C=C)(=O)O Chemical compound [Na].C(C=C)(=O)O USNWAMPROKAEIT-UHFFFAOYSA-N 0.000 claims 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims 1
- 239000011347 resin Substances 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 229920006026 co-polymeric resin Polymers 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000011324 bead Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- LLLCSBYSPJHDJX-UHFFFAOYSA-M potassium;2-methylprop-2-enoate Chemical compound [K+].CC(=C)C([O-])=O LLLCSBYSPJHDJX-UHFFFAOYSA-M 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- KPQOXMCRYWDRSB-UHFFFAOYSA-N 1-(2-chlorophenyl)pyrrole-2,5-dione Chemical compound ClC1=CC=CC=C1N1C(=O)C=CC1=O KPQOXMCRYWDRSB-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 244000089486 Phragmites australis subsp australis Species 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- DZGUJOWBVDZNNF-UHFFFAOYSA-N azanium;2-methylprop-2-enoate Chemical compound [NH4+].CC(=C)C([O-])=O DZGUJOWBVDZNNF-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59262868A JPS61171708A (ja) | 1984-12-14 | 1984-12-14 | 耐熱性樹脂、その製造法およびそれからなる光学用素子 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59262868A JPS61171708A (ja) | 1984-12-14 | 1984-12-14 | 耐熱性樹脂、その製造法およびそれからなる光学用素子 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6258156A Division JP2778916B2 (ja) | 1994-10-24 | 1994-10-24 | 光学用素子 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61171708A true JPS61171708A (ja) | 1986-08-02 |
| JPH0582405B2 JPH0582405B2 (enrdf_load_stackoverflow) | 1993-11-18 |
Family
ID=17381742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59262868A Granted JPS61171708A (ja) | 1984-12-14 | 1984-12-14 | 耐熱性樹脂、その製造法およびそれからなる光学用素子 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61171708A (enrdf_load_stackoverflow) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6253316A (ja) * | 1985-08-30 | 1987-03-09 | Daihachi Kagaku Kogyosho:Kk | 難燃性樹脂組成物 |
| JPS62138510A (ja) * | 1985-12-11 | 1987-06-22 | Japan Synthetic Rubber Co Ltd | 共重合体の製造方法 |
| JPS63273616A (ja) * | 1987-04-30 | 1988-11-10 | Kyowa Gas Chem Ind Co Ltd | 耐熱性メタクリル系樹脂の製造方法 |
| JPS63304045A (ja) * | 1987-06-03 | 1988-12-12 | Nippon Shokubai Kagaku Kogyo Co Ltd | 耐熱分解性の改良されたメタクリル系樹脂組成物 |
| US5140067A (en) * | 1988-10-31 | 1992-08-18 | Mitsubishi Rayon Company Limited | Heat resistant and impact resistant resin composition |
| JPH09165486A (ja) * | 1996-09-30 | 1997-06-24 | Nippon Shokubai Co Ltd | 耐熱分解性の改良されたメタクリル系樹脂組成物 |
| US6417306B1 (en) | 1999-12-13 | 2002-07-09 | Nippon Shokubai Co., Ltd, | Transparent heat-resistant resin and production process therefor |
| JP2003277567A (ja) * | 2002-03-20 | 2003-10-02 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物 |
| JP2003292715A (ja) * | 2002-04-03 | 2003-10-15 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物 |
| WO2013005634A1 (ja) | 2011-07-01 | 2013-01-10 | 旭化成ケミカルズ株式会社 | アクリル系熱可塑性樹脂組成物及びその成形体 |
| WO2017188031A1 (ja) * | 2016-04-28 | 2017-11-02 | 株式会社日本触媒 | マレイミド系ブロック共重合体の製造方法 |
| US11015011B2 (en) | 2016-04-28 | 2021-05-25 | Nippon Shokubai Co., Ltd. | Method for producing maleimide block copolymer |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52996A (en) * | 1975-06-24 | 1977-01-06 | Hitachi Chem Co Ltd | Resin composition |
| JPS5949210A (ja) * | 1982-09-14 | 1984-03-21 | Asahi Chem Ind Co Ltd | 耐熱性に優れた共重合体 |
| JPS60217216A (ja) * | 1984-04-12 | 1985-10-30 | Asahi Chem Ind Co Ltd | 低ソリ性アクリル系樹脂を基盤とするデイスク盤 |
-
1984
- 1984-12-14 JP JP59262868A patent/JPS61171708A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52996A (en) * | 1975-06-24 | 1977-01-06 | Hitachi Chem Co Ltd | Resin composition |
| JPS5949210A (ja) * | 1982-09-14 | 1984-03-21 | Asahi Chem Ind Co Ltd | 耐熱性に優れた共重合体 |
| JPS60217216A (ja) * | 1984-04-12 | 1985-10-30 | Asahi Chem Ind Co Ltd | 低ソリ性アクリル系樹脂を基盤とするデイスク盤 |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6253316A (ja) * | 1985-08-30 | 1987-03-09 | Daihachi Kagaku Kogyosho:Kk | 難燃性樹脂組成物 |
| JPS62138510A (ja) * | 1985-12-11 | 1987-06-22 | Japan Synthetic Rubber Co Ltd | 共重合体の製造方法 |
| JPS63273616A (ja) * | 1987-04-30 | 1988-11-10 | Kyowa Gas Chem Ind Co Ltd | 耐熱性メタクリル系樹脂の製造方法 |
| JPS63304045A (ja) * | 1987-06-03 | 1988-12-12 | Nippon Shokubai Kagaku Kogyo Co Ltd | 耐熱分解性の改良されたメタクリル系樹脂組成物 |
| US5140067A (en) * | 1988-10-31 | 1992-08-18 | Mitsubishi Rayon Company Limited | Heat resistant and impact resistant resin composition |
| JPH09165486A (ja) * | 1996-09-30 | 1997-06-24 | Nippon Shokubai Co Ltd | 耐熱分解性の改良されたメタクリル系樹脂組成物 |
| US6417306B1 (en) | 1999-12-13 | 2002-07-09 | Nippon Shokubai Co., Ltd, | Transparent heat-resistant resin and production process therefor |
| JP2003277567A (ja) * | 2002-03-20 | 2003-10-02 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物 |
| JP2003292715A (ja) * | 2002-04-03 | 2003-10-15 | Mitsubishi Rayon Co Ltd | 熱可塑性樹脂組成物 |
| WO2013005634A1 (ja) | 2011-07-01 | 2013-01-10 | 旭化成ケミカルズ株式会社 | アクリル系熱可塑性樹脂組成物及びその成形体 |
| US10030134B2 (en) | 2011-07-01 | 2018-07-24 | Asahi Kasei Kabushiki Kaisha | Acrylic thermoplastic resin composition and molded article thereof |
| WO2017188031A1 (ja) * | 2016-04-28 | 2017-11-02 | 株式会社日本触媒 | マレイミド系ブロック共重合体の製造方法 |
| US11015011B2 (en) | 2016-04-28 | 2021-05-25 | Nippon Shokubai Co., Ltd. | Method for producing maleimide block copolymer |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0582405B2 (enrdf_load_stackoverflow) | 1993-11-18 |
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