JPS6114214A - 加硫ゴム用ゴム状重合体組成物 - Google Patents
加硫ゴム用ゴム状重合体組成物Info
- Publication number
- JPS6114214A JPS6114214A JP13296084A JP13296084A JPS6114214A JP S6114214 A JPS6114214 A JP S6114214A JP 13296084 A JP13296084 A JP 13296084A JP 13296084 A JP13296084 A JP 13296084A JP S6114214 A JPS6114214 A JP S6114214A
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- compound
- rubber
- weight
- rubbery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 82
- -1 diene compound Chemical class 0.000 claims abstract description 28
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 26
- 239000006085 branching agent Substances 0.000 claims abstract description 18
- 229920001971 elastomer Polymers 0.000 claims description 59
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 20
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 15
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- 150000003606 tin compounds Chemical class 0.000 abstract description 27
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052744 lithium Inorganic materials 0.000 abstract description 8
- 239000003054 catalyst Substances 0.000 abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 239000005060 rubber Substances 0.000 description 34
- 239000004636 vulcanized rubber Substances 0.000 description 29
- 150000001875 compounds Chemical class 0.000 description 28
- 238000000034 method Methods 0.000 description 28
- 238000006116 polymerization reaction Methods 0.000 description 20
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 14
- 230000020169 heat generation Effects 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 230000000704 physical effect Effects 0.000 description 10
- 238000005096 rolling process Methods 0.000 description 10
- 238000004073 vulcanization Methods 0.000 description 10
- 239000006229 carbon black Substances 0.000 description 9
- 235000019241 carbon black Nutrition 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- 238000005859 coupling reaction Methods 0.000 description 7
- 230000006872 improvement Effects 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- 230000008878 coupling Effects 0.000 description 6
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- 238000010168 coupling process Methods 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 4
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 4
- GCTFWCDSFPMHHS-UHFFFAOYSA-M Tributyltin chloride Chemical compound CCCC[Sn](Cl)(CCCC)CCCC GCTFWCDSFPMHHS-UHFFFAOYSA-M 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- 238000004898 kneading Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000005049 silicon tetrachloride Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 235000014692 zinc oxide Nutrition 0.000 description 3
- KNENSDLFTGIERH-UHFFFAOYSA-N 2,2,4,4-tetramethyl-3-phenylpentan-3-ol Chemical compound CC(C)(C)C(O)(C(C)(C)C)C1=CC=CC=C1 KNENSDLFTGIERH-UHFFFAOYSA-N 0.000 description 2
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 210000000078 claw Anatomy 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229940125904 compound 1 Drugs 0.000 description 2
- 229920003244 diene elastomer Polymers 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000010734 process oil Substances 0.000 description 2
- 239000006235 reinforcing carbon black Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- RIECPYZYOLVSJK-UHFFFAOYSA-N tert-butyl 2-dimethylsilyl-5-methylindole-1-carboxylate Chemical compound C[SiH](C)c1cc2cc(C)ccc2n1C(=O)OC(C)(C)C RIECPYZYOLVSJK-UHFFFAOYSA-N 0.000 description 2
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- DOTHBUNQSVFCPF-UHFFFAOYSA-N Cl[SiH](Cl)Cl.Cl[SiH](Cl)Cl.C=C Chemical compound Cl[SiH](Cl)Cl.Cl[SiH](Cl)Cl.C=C DOTHBUNQSVFCPF-UHFFFAOYSA-N 0.000 description 1
- VIZORQUEIQEFRT-UHFFFAOYSA-N Diethyl adipate Chemical compound CCOC(=O)CCCCC(=O)OCC VIZORQUEIQEFRT-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000005063 High cis polybutadiene Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005064 Low cis polybutadiene Substances 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- GKLHPGUBVQWIJK-UHFFFAOYSA-L [O-][Cl]=O.[O-][Cl]=O.CCCCCCCC[Sn++]CCCCCCCC Chemical compound [O-][Cl]=O.[O-][Cl]=O.CCCCCCCC[Sn++]CCCCCCCC GKLHPGUBVQWIJK-UHFFFAOYSA-L 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- KIBOQZPTKOGILP-UHFFFAOYSA-G butyl(trichloro)stannane tetrachlorostannane Chemical compound C(CCC)[Sn](Cl)(Cl)Cl.[Sn](Cl)(Cl)(Cl)Cl KIBOQZPTKOGILP-UHFFFAOYSA-G 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- KWTSZCJMWHGPOS-UHFFFAOYSA-M chloro(trimethyl)stannane Chemical compound C[Sn](C)(C)Cl KWTSZCJMWHGPOS-UHFFFAOYSA-M 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- XBEREOHJDYAKDA-UHFFFAOYSA-N lithium;propane Chemical compound [Li+].CC[CH2-] XBEREOHJDYAKDA-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- KJGLZJQPMKQFIK-UHFFFAOYSA-N methanolate;tributylstannanylium Chemical compound CCCC[Sn](CCCC)(CCCC)OC KJGLZJQPMKQFIK-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- SYXYWTXQFUUWLP-UHFFFAOYSA-N sodium;butan-1-olate Chemical compound [Na+].CCCC[O-] SYXYWTXQFUUWLP-UHFFFAOYSA-N 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- SYUVAXDZVWPKSI-UHFFFAOYSA-N tributyl(phenyl)stannane Chemical compound CCCC[Sn](CCCC)(CCCC)C1=CC=CC=C1 SYUVAXDZVWPKSI-UHFFFAOYSA-N 0.000 description 1
- FVRKTAOFDKFAMI-UHFFFAOYSA-M tributylstannanylium;bromide Chemical compound [Br-].CCCC[Sn+](CCCC)CCCC FVRKTAOFDKFAMI-UHFFFAOYSA-M 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13296084A JPS6114214A (ja) | 1984-06-29 | 1984-06-29 | 加硫ゴム用ゴム状重合体組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13296084A JPS6114214A (ja) | 1984-06-29 | 1984-06-29 | 加硫ゴム用ゴム状重合体組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6114214A true JPS6114214A (ja) | 1986-01-22 |
| JPH0550535B2 JPH0550535B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-07-29 |
Family
ID=15093520
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13296084A Granted JPS6114214A (ja) | 1984-06-29 | 1984-06-29 | 加硫ゴム用ゴム状重合体組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6114214A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62283105A (ja) * | 1986-05-30 | 1987-12-09 | Japan Synthetic Rubber Co Ltd | ゴム組成物 |
| JPS6335607A (ja) * | 1986-07-30 | 1988-02-16 | Sumitomo Chem Co Ltd | ジエン系重合体およびその製造法 |
| JPS6341547A (ja) * | 1986-08-08 | 1988-02-22 | Japan Synthetic Rubber Co Ltd | 水添ジエン系重合体ゴム組成物 |
| FR2603592A1 (fr) * | 1986-09-08 | 1988-03-11 | Bridgestone Corp | Composition de caoutchouc de polybutadiene |
| JPS63191844A (ja) * | 1987-02-04 | 1988-08-09 | Yokohama Rubber Co Ltd:The | タイヤトレツド用ゴム組成物 |
| US5500482A (en) * | 1993-09-20 | 1996-03-19 | The Yokohama Rubber Co., Ltd. | Rubber composition for tire tread |
| JP2006045403A (ja) * | 2004-08-06 | 2006-02-16 | Jsr Corp | 共役ジエン系共重合ゴムの製造方法 |
| JP2009235408A (ja) * | 1997-07-11 | 2009-10-15 | Bridgestone Corp | 重合体とシリカ表面の相互作用によって低下したヒステリシスを示すエラストマー類 |
| JP2014502302A (ja) * | 2010-11-23 | 2014-01-30 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 低ｐｉ及び改善された低温流れを有する官能性ジエンエラストマー、及びそれを含有するゴム組成物 |
| JP2014503617A (ja) * | 2010-11-23 | 2014-02-13 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 特定のジエンエラストマーと特定の比表面積を有するカーボンブラックとを含む組成物 |
| JP2014105238A (ja) * | 2012-11-26 | 2014-06-09 | Sumitomo Rubber Ind Ltd | タイヤ用ゴム組成物及び空気入りタイヤ |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3956232A (en) * | 1972-11-20 | 1976-05-11 | Phillips Petroleum Company | Preparation of organometal terminated polymers |
| JPS5787407A (en) * | 1980-11-21 | 1982-05-31 | Japan Synthetic Rubber Co Ltd | Preparation of styrene-butadiene copolymer |
| JPS5893709A (ja) * | 1981-11-30 | 1983-06-03 | Japan Synthetic Rubber Co Ltd | ウェットスキッド特性及び摩耗特性が改良されたゴム組成物 |
| JPS5945338A (ja) * | 1982-09-07 | 1984-03-14 | Japan Synthetic Rubber Co Ltd | ブタジエン系重合体ゴム組成物 |
-
1984
- 1984-06-29 JP JP13296084A patent/JPS6114214A/ja active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3956232A (en) * | 1972-11-20 | 1976-05-11 | Phillips Petroleum Company | Preparation of organometal terminated polymers |
| JPS5787407A (en) * | 1980-11-21 | 1982-05-31 | Japan Synthetic Rubber Co Ltd | Preparation of styrene-butadiene copolymer |
| JPS5893709A (ja) * | 1981-11-30 | 1983-06-03 | Japan Synthetic Rubber Co Ltd | ウェットスキッド特性及び摩耗特性が改良されたゴム組成物 |
| JPS5945338A (ja) * | 1982-09-07 | 1984-03-14 | Japan Synthetic Rubber Co Ltd | ブタジエン系重合体ゴム組成物 |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62283105A (ja) * | 1986-05-30 | 1987-12-09 | Japan Synthetic Rubber Co Ltd | ゴム組成物 |
| JPS6335607A (ja) * | 1986-07-30 | 1988-02-16 | Sumitomo Chem Co Ltd | ジエン系重合体およびその製造法 |
| JPS6341547A (ja) * | 1986-08-08 | 1988-02-22 | Japan Synthetic Rubber Co Ltd | 水添ジエン系重合体ゴム組成物 |
| FR2603592A1 (fr) * | 1986-09-08 | 1988-03-11 | Bridgestone Corp | Composition de caoutchouc de polybutadiene |
| JPS63191844A (ja) * | 1987-02-04 | 1988-08-09 | Yokohama Rubber Co Ltd:The | タイヤトレツド用ゴム組成物 |
| US5500482A (en) * | 1993-09-20 | 1996-03-19 | The Yokohama Rubber Co., Ltd. | Rubber composition for tire tread |
| JP2009235408A (ja) * | 1997-07-11 | 2009-10-15 | Bridgestone Corp | 重合体とシリカ表面の相互作用によって低下したヒステリシスを示すエラストマー類 |
| JP2006045403A (ja) * | 2004-08-06 | 2006-02-16 | Jsr Corp | 共役ジエン系共重合ゴムの製造方法 |
| JP2014502302A (ja) * | 2010-11-23 | 2014-01-30 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 低ｐｉ及び改善された低温流れを有する官能性ジエンエラストマー、及びそれを含有するゴム組成物 |
| JP2014503617A (ja) * | 2010-11-23 | 2014-02-13 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | 特定のジエンエラストマーと特定の比表面積を有するカーボンブラックとを含む組成物 |
| JP2014105238A (ja) * | 2012-11-26 | 2014-06-09 | Sumitomo Rubber Ind Ltd | タイヤ用ゴム組成物及び空気入りタイヤ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0550535B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-07-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3438317B2 (ja) | タイヤトレッド用ゴム組成物 | |
| EP3280745B1 (en) | Initiators for the copolymerisation of diene monomers and vinyl aromatic monomers | |
| US20090036567A1 (en) | Process for producing modified diene polymer rubber | |
| JPS6245895B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| WO1997039055A1 (fr) | Composition de caoutchouc | |
| EP0581618A1 (en) | Rubber composition and production thereof | |
| JPH09136993A (ja) | ジエン系重合体ゴム組成物 | |
| JPH0129802B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| US7005469B2 (en) | Modified rubber, process for producing the same, and composition | |
| EP3049447B1 (en) | Low vinyl bond modified elastomeric copolymers | |
| JP2595919B2 (ja) | 改良されたゴム状重合体組成物 | |
| JP2003155380A (ja) | ゴム組成物 | |
| JPH09110904A (ja) | 変性ジエン系重合体ゴムの製造方法 | |
| US5001196A (en) | Process for preparation of diene type polymer rubber | |
| JPH0637578B2 (ja) | ゴム組成物 | |
| JPS6114214A (ja) | 加硫ゴム用ゴム状重合体組成物 | |
| JPS63101440A (ja) | ゴム組成物 | |
| JP2012102248A (ja) | 変性共役ジエン系共重合体、その製造方法、及び変性共役ジエン系共重合体組成物 | |
| JPH0580505B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JPS6250349A (ja) | 改善されたタイヤ用共役ジエン系ゴム組成物 | |
| JPH0776635A (ja) | 選択部分水添重合体組成物 | |
| JPS6227442A (ja) | 改善されたタイヤ用ゴム組成物 | |
| US20030114612A1 (en) | Coupled diene polymers modified with electrophilic groups | |
| JPS62156146A (ja) | タイヤ用のゴム組成物 | |
| JPH0755963B2 (ja) | 改良されたゴム状重合体の製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |