JPS6027700A - 気相法炭素繊維の製造法 - Google Patents
気相法炭素繊維の製造法Info
- Publication number
- JPS6027700A JPS6027700A JP58134355A JP13435583A JPS6027700A JP S6027700 A JPS6027700 A JP S6027700A JP 58134355 A JP58134355 A JP 58134355A JP 13435583 A JP13435583 A JP 13435583A JP S6027700 A JPS6027700 A JP S6027700A
- Authority
- JP
- Japan
- Prior art keywords
- substrate
- carbon fiber
- transition metal
- reactor
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 26
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 26
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 239000012808 vapor phase Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 title description 21
- 239000000758 substrate Substances 0.000 claims abstract description 25
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 21
- 150000003624 transition metals Chemical class 0.000 claims abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 5
- 239000002134 carbon nanofiber Substances 0.000 claims description 4
- 239000010419 fine particle Substances 0.000 claims description 3
- 238000000151 deposition Methods 0.000 claims description 2
- 238000000197 pyrolysis Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 16
- 239000012159 carrier gas Substances 0.000 abstract description 12
- 229930195733 hydrocarbon Natural products 0.000 abstract description 12
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 12
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 239000004215 Carbon black (E152) Substances 0.000 abstract description 8
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 150000002894 organic compounds Chemical class 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 229910001120 nichrome Inorganic materials 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 8
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052863 mullite Inorganic materials 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 3
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229910000953 kanthal Inorganic materials 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229910052706 scandium Inorganic materials 0.000 description 2
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- 239000006200 vaporizer Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- 229910052767 actinium Inorganic materials 0.000 description 1
- QQINRWTZWGJFDB-UHFFFAOYSA-N actinium atom Chemical compound [Ac] QQINRWTZWGJFDB-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Crystals, And After-Treatments Of Crystals (AREA)
- Carbon And Carbon Compounds (AREA)
- Inorganic Fibers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58134355A JPS6027700A (ja) | 1983-07-25 | 1983-07-25 | 気相法炭素繊維の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58134355A JPS6027700A (ja) | 1983-07-25 | 1983-07-25 | 気相法炭素繊維の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6027700A true JPS6027700A (ja) | 1985-02-12 |
| JPH0424320B2 JPH0424320B2 (forum.php) | 1992-04-24 |
Family
ID=15126426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58134355A Granted JPS6027700A (ja) | 1983-07-25 | 1983-07-25 | 気相法炭素繊維の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6027700A (forum.php) |
Cited By (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6278217A (ja) * | 1985-09-26 | 1987-04-10 | Showa Denko Kk | 気相法炭素繊維の製造法 |
| US5210116A (en) * | 1988-01-19 | 1993-05-11 | Yazaki Corporation | Resin composite material containing graphite fiber |
| US5273817A (en) * | 1990-10-12 | 1993-12-28 | Kitagawa Industries Co., Ltd. | Plastic material for wrapping over and carrying food |
| US6150446A (en) * | 1997-08-29 | 2000-11-21 | Teijin Limited | Destaticizing thermoplastic resin composition |
| US6221489B1 (en) | 1998-11-19 | 2001-04-24 | Showa Denko Kabushiki Kaisha | Carbonaceous fiber acute-angled at both ends and production process therefor |
| WO2002049412A1 (en) | 2000-12-20 | 2002-06-27 | Showa Denko K.K. | Branched vapor-grown carbon fiber, electrically conductive transparent composition and use thereof |
| US6489025B2 (en) | 2000-04-12 | 2002-12-03 | Showa Denko K.K. | Fine carbon fiber, method for producing the same and electrically conducting material comprising the fine carbon fiber |
| US6565971B2 (en) | 2000-11-10 | 2003-05-20 | Showa Denko Kabushiki Kaisha | Fine carbon fiber and method for producing the same |
| US6730398B2 (en) | 2001-08-31 | 2004-05-04 | Showa Denko K.K. | Fine carbon and method for producing the same |
| US6780388B2 (en) | 2000-05-31 | 2004-08-24 | Showa Denko K.K. | Electrically conducting fine carbon composite powder, catalyst for polymer electrolyte fuel battery and fuel battery |
| JP2004360160A (ja) * | 2003-05-09 | 2004-12-24 | Showa Denko Kk | 直線性微細炭素繊維及びそれを用いた樹脂複合体 |
| US6844061B2 (en) | 2001-08-03 | 2005-01-18 | Showa Denko K.K. | Fine carbon fiber and composition thereof |
| US6974627B2 (en) | 2001-09-20 | 2005-12-13 | Showa Denko K.K. | Fine carbon fiber mixture and composition thereof |
| US7131886B2 (en) * | 2001-09-10 | 2006-11-07 | Canon Kabushiki Kaisha | Method of producing fiber, and methods of producing electron-emitting device, electron source, and image display device each using the fiber |
| US7150911B2 (en) | 2001-02-08 | 2006-12-19 | Showa Denko Kabushiki Kaisha | Electrical insulating vapor grown carbon fiber and method for producing the same, and use thereof |
| US7150840B2 (en) | 2002-08-29 | 2006-12-19 | Showa Denko K.K. | Graphite fine carbon fiber, and production method and use thereof |
| US7390593B2 (en) | 2001-11-07 | 2008-06-24 | Showa Denko K.K. | Fine carbon fiber, method for producing the same and use thereof |
| US7585434B2 (en) | 2002-12-26 | 2009-09-08 | Showa Denko K.K. | Carbonaceous material for forming electrically conductive material and use thereof |
| WO2009125857A1 (ja) | 2008-04-08 | 2009-10-15 | 帝人株式会社 | 炭素繊維及びその製造方法 |
| US7700064B2 (en) | 2004-03-11 | 2010-04-20 | Teijin Limited | Carbon fiber |
| US7771694B2 (en) | 2003-08-26 | 2010-08-10 | Showa Denko K.K. | Crimped carbon fiber and production method thereof |
| US7879442B2 (en) | 2003-09-16 | 2011-02-01 | Showa Denko K.K. | Composite of vapor grown carbon fiber and inorganic fine particle and use thereof |
| JP2013509349A (ja) * | 2009-11-02 | 2013-03-14 | アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニー | Ｃｎｔ浸出セラミック繊維材料及びそのプロセス |
| US8716167B2 (en) | 2009-06-03 | 2014-05-06 | Showa Denko K.K. | Catalyst for fuel cell and polymer electrolyte fuel cell using the same |
| WO2014080629A1 (ja) | 2012-11-20 | 2014-05-30 | 昭和電工株式会社 | リチウムイオン電池用負極材の製造方法 |
| WO2014080632A1 (ja) | 2012-11-21 | 2014-05-30 | 昭和電工株式会社 | リチウムイオン電池用負極材の製造方法 |
| WO2015019993A1 (ja) | 2013-08-05 | 2015-02-12 | 昭和電工株式会社 | 複合体の製造方法及びリチウムイオン電池用負極材 |
| US10029442B2 (en) | 2005-07-28 | 2018-07-24 | Nanocomp Technologies, Inc. | Systems and methods for formation and harvesting of nanofibrous materials |
| US10138128B2 (en) | 2009-03-03 | 2018-11-27 | Applied Nanostructured Solutions, Llc | System and method for surface treatment and barrier coating of fibers for in situ CNT growth |
| US11231042B2 (en) | 2017-02-09 | 2022-01-25 | Eagleburgmann Germany Gmbh & Co. Kg | Mechanical seal assembly with safety seal |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5477725A (en) * | 1977-12-05 | 1979-06-21 | Asahi Chem Ind Co Ltd | Production of carbon whisker |
| JPS55162412A (en) * | 1979-06-04 | 1980-12-17 | Asahi Chem Ind Co Ltd | Manufacture of carbonaceous whisker |
-
1983
- 1983-07-25 JP JP58134355A patent/JPS6027700A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5477725A (en) * | 1977-12-05 | 1979-06-21 | Asahi Chem Ind Co Ltd | Production of carbon whisker |
| JPS55162412A (en) * | 1979-06-04 | 1980-12-17 | Asahi Chem Ind Co Ltd | Manufacture of carbonaceous whisker |
Cited By (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6278217A (ja) * | 1985-09-26 | 1987-04-10 | Showa Denko Kk | 気相法炭素繊維の製造法 |
| US5210116A (en) * | 1988-01-19 | 1993-05-11 | Yazaki Corporation | Resin composite material containing graphite fiber |
| US5273817A (en) * | 1990-10-12 | 1993-12-28 | Kitagawa Industries Co., Ltd. | Plastic material for wrapping over and carrying food |
| US6150446A (en) * | 1997-08-29 | 2000-11-21 | Teijin Limited | Destaticizing thermoplastic resin composition |
| US6221489B1 (en) | 1998-11-19 | 2001-04-24 | Showa Denko Kabushiki Kaisha | Carbonaceous fiber acute-angled at both ends and production process therefor |
| US6527988B1 (en) | 1998-11-20 | 2003-03-04 | Showa Denko Kabushiki Kaisha | Process of making carbon fiber with sharp ends |
| US6489025B2 (en) | 2000-04-12 | 2002-12-03 | Showa Denko K.K. | Fine carbon fiber, method for producing the same and electrically conducting material comprising the fine carbon fiber |
| US6699582B2 (en) | 2000-04-12 | 2004-03-02 | Showa Denko Kabushiki Kaisha | Fine carbon fiber, method for producing the same and electrically conducting material comprising the fine carbon fiber |
| US6998176B2 (en) | 2000-04-12 | 2006-02-14 | Showa Denko K.K. | Fine carbon fiber, method for producing the same and electrically conducting material comprising the fine carbon fiber |
| US6780388B2 (en) | 2000-05-31 | 2004-08-24 | Showa Denko K.K. | Electrically conducting fine carbon composite powder, catalyst for polymer electrolyte fuel battery and fuel battery |
| US6998171B2 (en) | 2000-11-10 | 2006-02-14 | Showa Denko Kabushiki Kaisha | Fine carbon fiber and method for producing the same |
| US6565971B2 (en) | 2000-11-10 | 2003-05-20 | Showa Denko Kabushiki Kaisha | Fine carbon fiber and method for producing the same |
| WO2002049412A1 (en) | 2000-12-20 | 2002-06-27 | Showa Denko K.K. | Branched vapor-grown carbon fiber, electrically conductive transparent composition and use thereof |
| EP2277435A1 (en) | 2000-12-20 | 2011-01-26 | Showa Denko K.K. | Branched vapor grown carbon fiber, electrically conductive transparent composition and use thereof |
| US7122132B2 (en) | 2000-12-20 | 2006-10-17 | Showa Denko K.K. | Branched vapor-grown carbon fiber, electrically conductive transparent composition and use thereof |
| US7150911B2 (en) | 2001-02-08 | 2006-12-19 | Showa Denko Kabushiki Kaisha | Electrical insulating vapor grown carbon fiber and method for producing the same, and use thereof |
| US6844061B2 (en) | 2001-08-03 | 2005-01-18 | Showa Denko K.K. | Fine carbon fiber and composition thereof |
| US6730398B2 (en) | 2001-08-31 | 2004-05-04 | Showa Denko K.K. | Fine carbon and method for producing the same |
| US7131886B2 (en) * | 2001-09-10 | 2006-11-07 | Canon Kabushiki Kaisha | Method of producing fiber, and methods of producing electron-emitting device, electron source, and image display device each using the fiber |
| US6974627B2 (en) | 2001-09-20 | 2005-12-13 | Showa Denko K.K. | Fine carbon fiber mixture and composition thereof |
| CN1321232C (zh) * | 2001-09-20 | 2007-06-13 | 昭和电工株式会社 | 细碳纤维混合物及其组合物 |
| US7390593B2 (en) | 2001-11-07 | 2008-06-24 | Showa Denko K.K. | Fine carbon fiber, method for producing the same and use thereof |
| US7150840B2 (en) | 2002-08-29 | 2006-12-19 | Showa Denko K.K. | Graphite fine carbon fiber, and production method and use thereof |
| US7585434B2 (en) | 2002-12-26 | 2009-09-08 | Showa Denko K.K. | Carbonaceous material for forming electrically conductive material and use thereof |
| JP2004360160A (ja) * | 2003-05-09 | 2004-12-24 | Showa Denko Kk | 直線性微細炭素繊維及びそれを用いた樹脂複合体 |
| US8084121B2 (en) | 2003-05-09 | 2011-12-27 | Showa Denko K.K. | Fine carbon fiber with linearity and resin composite material using the same |
| US8372511B2 (en) | 2003-05-09 | 2013-02-12 | Showa Denko K.K. | Fine carbon fiber with linearity and resin composite material using the same |
| US7771694B2 (en) | 2003-08-26 | 2010-08-10 | Showa Denko K.K. | Crimped carbon fiber and production method thereof |
| US7879442B2 (en) | 2003-09-16 | 2011-02-01 | Showa Denko K.K. | Composite of vapor grown carbon fiber and inorganic fine particle and use thereof |
| US7700064B2 (en) | 2004-03-11 | 2010-04-20 | Teijin Limited | Carbon fiber |
| US10029442B2 (en) | 2005-07-28 | 2018-07-24 | Nanocomp Technologies, Inc. | Systems and methods for formation and harvesting of nanofibrous materials |
| US9376765B2 (en) | 2008-04-08 | 2016-06-28 | Teijin Limited | Carbon fiber and method for producing the same |
| WO2009125857A1 (ja) | 2008-04-08 | 2009-10-15 | 帝人株式会社 | 炭素繊維及びその製造方法 |
| US10138128B2 (en) | 2009-03-03 | 2018-11-27 | Applied Nanostructured Solutions, Llc | System and method for surface treatment and barrier coating of fibers for in situ CNT growth |
| US8716167B2 (en) | 2009-06-03 | 2014-05-06 | Showa Denko K.K. | Catalyst for fuel cell and polymer electrolyte fuel cell using the same |
| JP2013509349A (ja) * | 2009-11-02 | 2013-03-14 | アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニー | Ｃｎｔ浸出セラミック繊維材料及びそのプロセス |
| WO2014080629A1 (ja) | 2012-11-20 | 2014-05-30 | 昭和電工株式会社 | リチウムイオン電池用負極材の製造方法 |
| WO2014080632A1 (ja) | 2012-11-21 | 2014-05-30 | 昭和電工株式会社 | リチウムイオン電池用負極材の製造方法 |
| WO2015019993A1 (ja) | 2013-08-05 | 2015-02-12 | 昭和電工株式会社 | 複合体の製造方法及びリチウムイオン電池用負極材 |
| US11231042B2 (en) | 2017-02-09 | 2022-01-25 | Eagleburgmann Germany Gmbh & Co. Kg | Mechanical seal assembly with safety seal |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0424320B2 (forum.php) | 1992-04-24 |
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