JPS60176917A - 結晶ｚｓｍ―５とｚｓｍ―１１ゼオライトの製造方法 - Google Patents
結晶ｚｓｍ―５とｚｓｍ―１１ゼオライトの製造方法Info
- Publication number
- JPS60176917A JPS60176917A JP60011807A JP1180785A JPS60176917A JP S60176917 A JPS60176917 A JP S60176917A JP 60011807 A JP60011807 A JP 60011807A JP 1180785 A JP1180785 A JP 1180785A JP S60176917 A JPS60176917 A JP S60176917A
- Authority
- JP
- Japan
- Prior art keywords
- aged
- reaction mixture
- gel
- nucleating
- crystallization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000323 aluminium silicate Inorganic materials 0.000 title claims description 18
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 229910021536 Zeolite Inorganic materials 0.000 title claims description 3
- 239000010457 zeolite Substances 0.000 title claims description 3
- 239000013078 crystal Substances 0.000 title description 24
- 239000000203 mixture Substances 0.000 claims description 43
- 238000002425 crystallisation Methods 0.000 claims description 37
- 230000008025 crystallization Effects 0.000 claims description 34
- 239000011541 reaction mixture Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 238000010899 nucleation Methods 0.000 claims description 20
- 230000006911 nucleation Effects 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 12
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 3
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000005263 alkylenediamine group Chemical group 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 150000001339 alkali metal compounds Chemical class 0.000 claims 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 claims 1
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 claims 1
- 239000000499 gel Substances 0.000 description 49
- 239000000243 solution Substances 0.000 description 19
- 235000012239 silicon dioxide Nutrition 0.000 description 10
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 150000004645 aluminates Chemical class 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005216 hydrothermal crystallization Methods 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- -1 alkaline earth metal cation Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-O butylazanium Chemical compound CCCC[NH3+] HQABUPZFAYXKJW-UHFFFAOYSA-O 0.000 description 1
- 238000002109 crystal growth method Methods 0.000 description 1
- 229910002026 crystalline silica Inorganic materials 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000035922 thirst Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2876—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures from a reacting mixture containing an amine or an organic cation, e.g. a quaternary onium cation-ammonium, phosphonium, stibonium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
- C01B33/18—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof
- C01B33/181—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by a dry process
- C01B33/185—Preparation of finely divided silica neither in sol nor in gel form; After-treatment thereof by a dry process of crystalline silica-polymorphs having molecular sieve properties, e.g. silicalites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/02—Amorphous compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/22—MFI, e.g. ZSM-5. silicalite, LZ-241
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843402842 DE3402842A1 (de) | 1984-01-27 | 1984-01-27 | Verfahren zur herstellung von kristallinen zeolithischen alumosilicaten |
| DE3402842.0 | 1984-01-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60176917A true JPS60176917A (ja) | 1985-09-11 |
| JPH0583483B2 JPH0583483B2 (https=) | 1993-11-26 |
Family
ID=6226094
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60011807A Granted JPS60176917A (ja) | 1984-01-27 | 1985-01-26 | 結晶ｚｓｍ―５とｚｓｍ―１１ゼオライトの製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4606900A (https=) |
| EP (1) | EP0150256B1 (https=) |
| JP (1) | JPS60176917A (https=) |
| DE (2) | DE3402842A1 (https=) |
| DK (1) | DK34285A (https=) |
| ZA (1) | ZA85618B (https=) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005519014A (ja) * | 2002-03-01 | 2005-06-30 | アクゾ ノーベル ナムローゼ フェンノートシャップ | Ｍｆｉ型の結晶性アルミノシリケートゼオライトを調製する方法 |
| JP2006265019A (ja) * | 2005-03-23 | 2006-10-05 | Shiga Pref Gov | ゼオライト壁材を有する中空シリカマイクロカプセル及びその製造方法 |
| JP2013177312A (ja) * | 2005-10-12 | 2013-09-09 | Basf Se | ケイ酸塩の製造方法 |
| JP2020033242A (ja) * | 2018-08-31 | 2020-03-05 | 水澤化学工業株式会社 | ｏ−キシレン吸着性に優れたＭＦＩ型ゼオライト及びその製造方法 |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0206871B1 (fr) * | 1985-06-19 | 1989-02-01 | Institut Français du Pétrole | Zéolithe oméga stabilisée et désaluminée |
| DE3919098A1 (de) * | 1989-06-10 | 1990-12-13 | Vaw Ver Aluminium Werke Ag | Verfahren zur herstellung von kristallinen und zeolithischen alumosilikaten |
| DE3919400A1 (de) * | 1989-06-14 | 1991-01-10 | Vaw Ver Aluminium Werke Ag | Verfahren zur herstellung von hochkieselsaeurehaltigen alumosilikaten |
| WO1991011256A1 (en) * | 1990-01-31 | 1991-08-08 | Industrial Progress, Inc. | Functional complex microgels with rapid formation kinetics |
| DE4021118A1 (de) * | 1990-07-03 | 1992-01-09 | Vaw Ver Aluminium Werke Ag | Verfahren zur herstellung von kristallinen zeotithanalogen gallosilikaten und ihre verwendung zur herstellung von katalysatoren und adsorbentien |
| UA27705C2 (uk) * | 1990-07-11 | 2000-10-16 | Еколіт-Цеоліте Гмбх | СПОСІБ КАТАЛІТИЧНОЇ ІЗОМЕРИЗАЦІЇ С<sub>8 </sub>- АРОМАТИЧНИХ ВУГЛЕВОДНІВ |
| DE4120847A1 (de) * | 1991-06-25 | 1993-01-14 | Vaw Ver Aluminium Werke Ag | Kristallines, zeolithanaloges gallosilicat und verfahren zu dessen herstellung |
| US5330736A (en) * | 1992-12-07 | 1994-07-19 | W. R. Grace & Co.-Conn. | Zeolite L synthesis and resulting product |
| US5599520A (en) * | 1994-11-03 | 1997-02-04 | Garces; Juan M. | Synthesis of crystalline porous solids in ammonia |
| GB9600082D0 (en) * | 1996-01-04 | 1996-03-06 | Exxon Chemical Patents Inc | Molecular sieves and processes for their manufacture |
| DE19707994A1 (de) * | 1997-02-27 | 1998-09-03 | Sued Chemie Ag | Verfahren zur Herstellung von Zeolithen mit einem hohen Si/Al-Atomverhältnis |
| US6277355B1 (en) * | 1999-07-13 | 2001-08-21 | Exxonmobil Chemical Patents Inc. | Synthesis of ZSM-5 and ZSM-11 |
| US6800272B2 (en) * | 2002-03-13 | 2004-10-05 | Council Of Scientific And Industrial Research | Process for the preparation of ZSM-5 catalyst |
| EP1532076B1 (en) * | 2002-08-28 | 2019-05-15 | Albemarle Netherlands B.V. | Process for the preparation of doped pentasil-type zeolites using doped seeds |
| US6936239B2 (en) * | 2002-08-28 | 2005-08-30 | Akzo Novel Nv | Process for the preparation of doped pentasil-type zeolites using doped faujasite seeds |
| US6964934B2 (en) | 2002-08-28 | 2005-11-15 | Albemarle Netherlands B.V. | Process for the preparation of doped pentasil-type zeolite using doped seeds |
| WO2006087337A1 (en) * | 2005-02-15 | 2006-08-24 | Albemarle Netherlands Bv | Nucleating gel, process for its preparation, and its use in the synthesis of mfi-type zeolite |
| EP1707533A1 (en) * | 2005-04-01 | 2006-10-04 | Petroleo Brasileiro S.A. - Petrobras | Nucleating gel, process for its preparation, and its use in the synthesis of MFI-type zeolite |
| CZ299372B6 (cs) * | 2005-09-23 | 2008-07-09 | Výzkumný ústav anorganické chemie, a. s. | Zpusob výroby zeolitu ZSM-5 s rízenou velikostí krystalu |
| KR101614544B1 (ko) * | 2009-10-20 | 2016-04-22 | 에스케이이노베이션 주식회사 | 나노 크기의 결정성 ｚｓｍ－５ 핵을 사용한 ｚｓｍ－５의 제조 방법 |
| CN101898767B (zh) * | 2010-07-20 | 2011-12-28 | 华东师范大学 | 一种高硅zsm-5沸石的合成方法 |
| KR101662912B1 (ko) * | 2014-12-30 | 2016-10-06 | 주식회사 효성 | 노보넨계 광학 필름, 및 이의 제조방법 |
| CZ2015604A3 (cs) * | 2015-09-03 | 2017-01-11 | Unipetrol Výzkumně Vzdělávací Centrum, A. S. | Způsob výroby dutých kulových částic zeolitu ZSM-5 |
| CZ2016150A3 (cs) * | 2016-03-15 | 2017-08-09 | Unipetrol výzkumně vzdělávací centrum, a.s. | Způsob výroby zeolitu ZSM-5 s vysokým podílem párů atomů hliníku |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2017807A1 (de) * | 1969-05-01 | 1970-11-12 | W.R. Grace & Co., New York, N.Y. (V.St.A.) | Synthetischer Alumosilikatzeolith und Verfahren zu dessen Herstellung |
| US3709979A (en) * | 1970-04-23 | 1973-01-09 | Mobil Oil Corp | Crystalline zeolite zsm-11 |
| CA990708A (en) * | 1970-09-24 | 1976-06-08 | W.R. Grace And Co. | Process for preparing a zeolite containing petroleum cracking catalyst |
| US3886094A (en) * | 1972-12-22 | 1975-05-27 | Grace W R & Co | Preparation of hydrocarbon conversion catalysts |
| US4175114A (en) * | 1973-12-13 | 1979-11-20 | Mobil Oil Corporation | Method for producing zeolites |
| US3947482A (en) * | 1974-03-20 | 1976-03-30 | W. R. Grace & Co. | Method for producing open framework zeolites |
| US4073865A (en) * | 1976-09-27 | 1978-02-14 | Union Carbide Corporation | Silica polymorph and process for preparing same |
| US4146584A (en) * | 1977-04-22 | 1979-03-27 | Mobil Oil Corporation | Catalytic conversion with zsm-35 |
| US4526879A (en) * | 1978-11-13 | 1985-07-02 | Mobil Oil Corporation | Synthesis of zeolite ZSM-5 |
| DE3004060A1 (de) * | 1979-02-07 | 1980-08-21 | Toyo Soda Mfg Co Ltd | Verfahren zum herstellen von y-zeolith |
| DE2935123A1 (de) * | 1979-08-30 | 1981-04-09 | Mobil Oil Corp., 10017 New York, N.Y. | Verfahren zur herstellung von zeolithen |
| US4309313A (en) * | 1980-05-23 | 1982-01-05 | W. R. Grace & Co. | Synthesis of cesium-containing zeolite, CSZ-1 |
| US4333859A (en) * | 1980-10-27 | 1982-06-08 | W. R. Grace & Co. | High silica faujasite polymorph - CSZ-3 and method of synthesizing |
| JPS593932B2 (ja) * | 1980-12-03 | 1984-01-26 | 三菱瓦斯化学株式会社 | 結晶性アルミノシリケ−トの製造方法 |
| JPS6035284B2 (ja) * | 1981-01-27 | 1985-08-14 | 東レ株式会社 | ペンタシル型ゼオライトの製造法 |
| SU1066940A1 (ru) * | 1982-05-13 | 1984-01-15 | Грозненский Ордена Трудового Красного Знамени Нефтяной Институт Им.Акад.М.Д.Миллионщикова | Способ получени цезита |
| CA1225387A (en) * | 1983-11-10 | 1987-08-11 | David E.W. Vaughan | Process for preparing type l zeolites by nucleation technique |
-
1984
- 1984-01-27 DE DE19843402842 patent/DE3402842A1/de not_active Withdrawn
- 1984-07-28 EP EP84108958A patent/EP0150256B1/de not_active Expired - Lifetime
- 1984-07-28 DE DE8484108958T patent/DE3485597D1/de not_active Expired - Lifetime
-
1985
- 1985-01-24 US US06/694,536 patent/US4606900A/en not_active Expired - Lifetime
- 1985-01-25 ZA ZA85618A patent/ZA85618B/xx unknown
- 1985-01-25 DK DK34285A patent/DK34285A/da not_active Application Discontinuation
- 1985-01-26 JP JP60011807A patent/JPS60176917A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005519014A (ja) * | 2002-03-01 | 2005-06-30 | アクゾ ノーベル ナムローゼ フェンノートシャップ | Ｍｆｉ型の結晶性アルミノシリケートゼオライトを調製する方法 |
| JP2006265019A (ja) * | 2005-03-23 | 2006-10-05 | Shiga Pref Gov | ゼオライト壁材を有する中空シリカマイクロカプセル及びその製造方法 |
| JP2013177312A (ja) * | 2005-10-12 | 2013-09-09 | Basf Se | ケイ酸塩の製造方法 |
| JP2020033242A (ja) * | 2018-08-31 | 2020-03-05 | 水澤化学工業株式会社 | ｏ−キシレン吸着性に優れたＭＦＩ型ゼオライト及びその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0583483B2 (https=) | 1993-11-26 |
| EP0150256B1 (de) | 1992-03-18 |
| DK34285D0 (da) | 1985-01-25 |
| DE3485597D1 (de) | 1992-04-23 |
| US4606900A (en) | 1986-08-19 |
| EP0150256A3 (en) | 1988-08-03 |
| DE3402842A1 (de) | 1985-08-08 |
| EP0150256A2 (de) | 1985-08-07 |
| DK34285A (da) | 1985-07-28 |
| ZA85618B (en) | 1985-08-28 |
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