JPS60158212A - 腐蝕性薬品に対する特性が良好な対衝撃性ポリスチレンの製造方法 - Google Patents
腐蝕性薬品に対する特性が良好な対衝撃性ポリスチレンの製造方法Info
- Publication number
- JPS60158212A JPS60158212A JP59282028A JP28202884A JPS60158212A JP S60158212 A JPS60158212 A JP S60158212A JP 59282028 A JP59282028 A JP 59282028A JP 28202884 A JP28202884 A JP 28202884A JP S60158212 A JPS60158212 A JP S60158212A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- weight
- rubber
- styrene
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000000126 substance Substances 0.000 title description 9
- 239000004793 Polystyrene Substances 0.000 title description 3
- 229920002223 polystyrene Polymers 0.000 title description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 54
- 229920001971 elastomer Polymers 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 22
- 239000005060 rubber Substances 0.000 claims description 22
- 229920002857 polybutadiene Polymers 0.000 claims description 17
- 239000000654 additive Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- 239000005062 Polybutadiene Substances 0.000 claims description 13
- -1 polyethylene Polymers 0.000 claims description 11
- 125000000129 anionic group Chemical group 0.000 claims description 10
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 9
- 238000005336 cracking Methods 0.000 claims description 6
- 229920002545 silicone oil Polymers 0.000 claims description 6
- 238000012662 bulk polymerization Methods 0.000 claims description 5
- RMPAXPOFLJVREM-UHFFFAOYSA-N (1-phenylcyclobutyl)benzene Chemical compound C1CCC1(C=1C=CC=CC=1)C1=CC=CC=C1 RMPAXPOFLJVREM-UHFFFAOYSA-N 0.000 claims description 4
- YASDJUXENMYIBH-UHFFFAOYSA-N 3-methyl-3-phenyl-1,2-dihydroindene Chemical compound C1CC2=CC=CC=C2C1(C)C1=CC=CC=C1 YASDJUXENMYIBH-UHFFFAOYSA-N 0.000 claims description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 125000003827 glycol group Chemical group 0.000 claims description 3
- 150000003626 triacylglycerols Chemical class 0.000 claims description 3
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- 239000004305 biphenyl Substances 0.000 claims description 2
- 125000006267 biphenyl group Chemical group 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 claims description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 150000003440 styrenes Chemical class 0.000 claims description 2
- GGZMJMQKUXVBCQ-UHFFFAOYSA-N 5-phenylhexa-2,4-dien-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)=CC=C(C)C1=CC=CC=C1 GGZMJMQKUXVBCQ-UHFFFAOYSA-N 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 46
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 28
- FZYCEURIEDTWNS-UHFFFAOYSA-N prop-1-en-2-ylbenzene Chemical compound CC(=C)C1=CC=CC=C1.CC(=C)C1=CC=CC=C1 FZYCEURIEDTWNS-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 239000001993 wax Substances 0.000 description 13
- 239000005662 Paraffin oil Substances 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 9
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- 230000008961 swelling Effects 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 230000003078 antioxidant effect Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 3
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 3
- UHUSDOQQWJGJQS-UHFFFAOYSA-N glycerol 1,2-dioctadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)OC(=O)CCCCCCCCCCCCCCCCC UHUSDOQQWJGJQS-UHFFFAOYSA-N 0.000 description 3
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 3
- 229920005669 high impact polystyrene Polymers 0.000 description 3
- 239000004797 high-impact polystyrene Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- LGLDSEPDYUTBNZ-UHFFFAOYSA-N 3-phenylbuta-1,3-dien-2-ylbenzene Chemical compound C=1C=CC=CC=1C(=C)C(=C)C1=CC=CC=C1 LGLDSEPDYUTBNZ-UHFFFAOYSA-N 0.000 description 2
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- 241000592817 Caddo Species 0.000 description 1
- 229920004511 Dow Corning® 200 Fluid Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical class CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000009778 extrusion testing Methods 0.000 description 1
- 235000021149 fatty food Nutrition 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000005003 food packaging material Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8321059 | 1983-12-30 | ||
| FR8321059A FR2557575B1 (fr) | 1983-12-30 | 1983-12-30 | Procede de preparation de polystyrene-choc presentant un bon comportement aux agents corrosifs |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60158212A true JPS60158212A (ja) | 1985-08-19 |
| JPS6343413B2 JPS6343413B2 (enrdf_load_stackoverflow) | 1988-08-30 |
Family
ID=9295733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59282028A Granted JPS60158212A (ja) | 1983-12-30 | 1984-12-29 | 腐蝕性薬品に対する特性が良好な対衝撃性ポリスチレンの製造方法 |
Country Status (15)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3686681B2 (ja) * | 1992-03-10 | 2005-08-24 | 住友化学株式会社 | ゴム変性スチレン系樹脂組成物 |
| DE69624062T3 (de) | 1995-10-25 | 2006-09-21 | Fina Technology, Inc., Houston | Monovinylaromatische Polymere mit verbesserter Spannungsrissbeständigkeit |
| RU2294941C2 (ru) * | 2005-04-06 | 2007-03-10 | Открытое акционерное общество "Пластполимер" | Способ получения стойкого к растрескиванию ударопрочного полистирола |
| US7638559B2 (en) | 2005-05-10 | 2009-12-29 | Nova Chemicals Inc. | Expandable resins |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2646418A (en) * | 1951-05-25 | 1953-07-21 | Dow Chemical Co | Process for polymerizing monovinyl aromatic compounds with rubber |
| IT647966A (enrdf_load_stackoverflow) * | 1960-01-25 | 1900-01-01 | ||
| DE1495638B2 (de) * | 1960-09-07 | 1973-03-22 | Farbwerke Hoechst AG, vormals Meister Lucius & Brüning, 6000 Frankfurt | Verfahren zur herstellung von schlagfestem polystyrol |
| NL279121A (enrdf_load_stackoverflow) * | 1961-06-01 | |||
| GB1025573A (en) * | 1962-12-24 | 1966-04-14 | Foster Grant Co Inc | Improvements in or relating to polymer processes and compositions |
| FR1351613A (fr) * | 1963-01-07 | 1964-02-07 | Dow Chemical Co | Compositions polymérisées oléfiniques à base de résines et d'élastomères et leur procédé d'obtention |
| CA936297A (en) * | 1963-08-15 | 1973-10-30 | Dart Industries Inc. | Impact resistant graft copolymers |
| DE1495837C3 (de) * | 1964-09-30 | 1974-02-14 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung thermoplastisch-elastischer Formmassen |
| GB1229409A (enrdf_load_stackoverflow) * | 1967-05-11 | 1971-04-21 | ||
| JPS5917126B2 (ja) * | 1979-03-29 | 1984-04-19 | 旭化成株式会社 | 改良された耐衝撃性スチレン系重合体の製法 |
| JPS5919577B2 (ja) * | 1980-08-25 | 1984-05-07 | 日本エラストマ−株式会社 | 耐衝撃性ポリスチレンの製造方法 |
| DE3047303A1 (de) * | 1980-12-16 | 1982-07-29 | Basf Ag, 6700 Ludwigshafen | Verfahren zur kontinuierlichen herstellung von mit kautschuk modifizierten polymerisaten von vinylaromaten, verwendung derselben zum spritzgiessen, sowie formteile aus diesen |
| FR2505342A1 (fr) * | 1981-05-07 | 1982-11-12 | Bp Chemical Ltd | Procede de fabrication d'un polymere vinyl-aromatique tres tenace |
-
1983
- 1983-12-30 FR FR8321059A patent/FR2557575B1/fr not_active Expired
-
1984
- 1984-12-13 GB GB08431498A patent/GB2153370B/en not_active Expired
- 1984-12-20 DE DE3446592A patent/DE3446592A1/de not_active Ceased
- 1984-12-20 IT IT24147/84A patent/IT1177474B/it active
- 1984-12-21 DK DK626184A patent/DK626184A/da not_active Application Discontinuation
- 1984-12-21 CA CA000470934A patent/CA1241484A/fr not_active Expired
- 1984-12-24 NL NL8403940A patent/NL191336C/xx not_active IP Right Cessation
- 1984-12-27 LU LU85713A patent/LU85713A1/fr unknown
- 1984-12-27 CH CH6193/84A patent/CH662815A5/fr not_active IP Right Cessation
- 1984-12-27 NO NO845237A patent/NO845237L/no unknown
- 1984-12-28 BE BE0/214272A patent/BE901418A/fr not_active IP Right Cessation
- 1984-12-28 SE SE8406665A patent/SE465879B/sv unknown
- 1984-12-28 AT AT0412184A patent/AT394369B/de not_active IP Right Cessation
- 1984-12-29 KR KR1019840008533A patent/KR920006762B1/ko not_active Expired
- 1984-12-29 JP JP59282028A patent/JPS60158212A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| SE465879B (sv) | 1991-11-11 |
| SE8406665L (sv) | 1985-07-01 |
| IT1177474B (it) | 1987-08-26 |
| NL191336C (nl) | 1995-06-01 |
| NO845237L (no) | 1985-07-01 |
| GB2153370B (en) | 1987-12-23 |
| ATA412184A (de) | 1991-09-15 |
| KR850004786A (ko) | 1985-07-27 |
| IT8424147A0 (it) | 1984-12-20 |
| NL191336B (nl) | 1995-01-02 |
| GB2153370A (en) | 1985-08-21 |
| BE901418A (fr) | 1985-06-28 |
| FR2557575A1 (fr) | 1985-07-05 |
| DE3446592A1 (de) | 1985-07-11 |
| KR920006762B1 (ko) | 1992-08-17 |
| DK626184D0 (da) | 1984-12-21 |
| LU85713A1 (fr) | 1985-07-24 |
| GB8431498D0 (en) | 1985-01-23 |
| CH662815A5 (fr) | 1987-10-30 |
| DK626184A (da) | 1985-07-01 |
| CA1241484A (fr) | 1988-08-30 |
| SE8406665D0 (sv) | 1984-12-28 |
| JPS6343413B2 (enrdf_load_stackoverflow) | 1988-08-30 |
| AT394369B (de) | 1992-03-25 |
| FR2557575B1 (fr) | 1987-02-06 |
| NL8403940A (nl) | 1985-07-16 |
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