JPS60103614A - Manufacture of semiconductor device - Google Patents

Manufacture of semiconductor device

Info

Publication number
JPS60103614A
JPS60103614A JP21098583A JP21098583A JPS60103614A JP S60103614 A JPS60103614 A JP S60103614A JP 21098583 A JP21098583 A JP 21098583A JP 21098583 A JP21098583 A JP 21098583A JP S60103614 A JPS60103614 A JP S60103614A
Authority
JP
Japan
Prior art keywords
resist
layer
resist layer
layers
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP21098583A
Other languages
Japanese (ja)
Other versions
JPH0469411B2 (en
Inventor
Hitoshi Tsuji
均 辻
Chiharu Kato
千晴 加藤
Hiroshi Ishitani
浩 石谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP21098583A priority Critical patent/JPS60103614A/en
Publication of JPS60103614A publication Critical patent/JPS60103614A/en
Publication of JPH0469411B2 publication Critical patent/JPH0469411B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
  • Electrodes Of Semiconductors (AREA)
  • Drying Of Semiconductors (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

PURPOSE:To form a resist layer in a short time and at low cost in a process of forming a multilayer resist structure by laminating the resist with forming a resin layer which has no compatibility with both of upper and lower resist layers between these layers. CONSTITUTION:After forming a first resist layer 21 by spreading the resist for far ultraviolet rays consisting of PMIPK over the surface of a semiconductor substrate 1, novolak-group resin whose solvent is ethylcellosolve is spread to form a resin layer 8. Further on that, the resist same as the first resist layer 21 is spread rather thinly to form a second resist layer 31. After that, when a substrate is exposed by a far ultraviolet exposure device of tight-contact exposure type, the upper and lower resist layers 21 and 31 are exposed to the ultraviolet rays at the same time so that an opening 10 penetrating through both resist layers is formed by development. As the resist layer 8 which has no compatibility is already formed when the second resist layer 31 is formed, there is no possibility that non-uniformity of coating is produced and uniform coating becomes possible.

Description

【発明の詳細な説明】 [発明の技術分野] この発明は、半導体装置の製造方法に関し、特に、サブ
ミクロン級の線巾のVLS Iの製造に好適な半導体装
置の製造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a method for manufacturing a semiconductor device, and more particularly to a method for manufacturing a semiconductor device suitable for manufacturing a VLSI with a submicron line width.

[発明の技術的背景] シリコン半導体デバイスの製造技術の進歩により、線巾
が1〜2μmのVLS Iに関する量産技術がほぼ確立
されており、更に線巾がサブミクロン級のVLSIの量
産技術の開発が進められている。
[Technical Background of the Invention] Due to advances in manufacturing technology for silicon semiconductor devices, mass production technology for VLSI with a line width of 1 to 2 μm has almost been established, and further development of mass production technology for VLSI with a line width of submicron class. is in progress.

線幅がサブミクロン級の高密度LSIの量産技術の開発
のためには、リソグラフィ、エツチング、膜形成技術、
金属配線技術、素子間分離技術等の各種の技術分野で解
決し工ゆかねばならない問題点が多い。 リソグラフィ
技術及び配線形成技術に関しては、多層レジスト構造を
利用するマスクトランスファ技術を採用することにより
、パターン転写工程における解像度の向上と同時にリフ
トオフ配線の実現を図る試みが行われている。
In order to develop mass production technology for high-density LSI with submicron line width, lithography, etching, film formation technology,
There are many problems that must be solved in various technical fields such as metal wiring technology and element isolation technology. Regarding lithography technology and wiring formation technology, attempts are being made to improve resolution in the pattern transfer process and at the same time realize lift-off wiring by employing mask transfer technology that utilizes a multilayer resist structure.

従来、前記のごとき、リソグラフィ及び配線技術に採用
されたマスクトランスファ技術には、以下のごとぎ二つ
の方法があった。
Conventionally, there have been two methods of mask transfer technology employed in lithography and wiring technology as described above, as described below.

第一の方法は、半導体基板の表面にポリメタクリル酸メ
チル(PMMA)から成る遠紫外線用ポジ型レジストを
厚く塗布して、これを第一(下部)レジス1へ層とし、
更に該第−レジス]・層の上に薄く近紫外線用ポジ型レ
ジスト(例えばS hipley社A Z 1 ’35
0 J )を塗布してこれを第二(上部)レジスト層と
した後、まず第ニレジスト層を近紫外線で露光し、かつ
現像して該第ニレジス1一層からなるレジストパターン
を作り、更に該レジストパターンをマスクとして第一レ
ジスト層を遠紫外線で露光する、という方法である。
The first method is to apply a thick layer of deep ultraviolet ray positive resist made of polymethyl methacrylate (PMMA) on the surface of a semiconductor substrate, and apply this as a layer to the first (lower) resist 1.
Furthermore, a thin near-ultraviolet positive type resist (for example, Shipley's AZ 1 '35) is applied on top of the third resist layer.
0 J) to form a second (upper) resist layer, first, the second resist layer was exposed to near ultraviolet light and developed to form a resist pattern consisting of one layer of the second resist 1, and then the resist layer was further exposed to near ultraviolet light and developed. This method involves exposing the first resist layer to deep ultraviolet light using the pattern as a mask.

第1図(a )ないし第1図(f )はこの第一の方法
を工程順に示したものであり、同図において、1は半導
体基板、2は第一レジスト層、3は第二レジスト層、4
は密着露光型紫外線露光装置のマスク、5の矢印で表示
されているのは近紫外線、同じく6の矢印で示されてい
るのは遠紫外線である。
Figures 1(a) to 1(f) show the first method in the order of steps. In the figures, 1 is a semiconductor substrate, 2 is a first resist layer, and 3 is a second resist layer. , 4
is a mask of a contact exposure type ultraviolet exposure device, arrow 5 indicates near ultraviolet rays, and arrow 6 indicates far ultraviolet rays.

一方、第二の方法は以下のような工程(第2図(a)な
いし第2図(f))で構成される。 すなわち、第2図
(a )に示されているように、まず、半導体基板1上
に第一レシスト層2(例えばPMMAを主成分とするポ
ジ型レジスト)を形成した後、更に第一レジスト層2の
上に5i02などの無機質もしくは金属などの無機膜7
を第2図(b)のように形成し、更に無機膜7の上に第
ニレジスト層(例えばPMMAを主成分とするポジ型レ
ジスト)3を形成する。 次に第2図(0)に示すよう
に密着露光によって該第ニレジスト層3に遠紫外線を選
択的に露光し、かつ現像することにより第2図(d )
に示すように開口3aを有したレジストパターンを形成
する。 そして、該レジストパターンをマスクとして第
2図(e)及び(f )に示すように、該無機膜7と第
一レジスト層2に、それぞれエツチング及び遠紫外線6
で選択的露光現像を行うことにより第2図(f)に示さ
れるように第一レジスト層2にリフトオフ配線に適した
不払がりの開口(もしくは溝>2aを形成する。
On the other hand, the second method consists of the following steps (FIG. 2(a) to FIG. 2(f)). That is, as shown in FIG. 2(a), first, a first resist layer 2 (for example, a positive resist mainly composed of PMMA) is formed on a semiconductor substrate 1, and then a first resist layer 2 is formed on the semiconductor substrate 1. An inorganic film 7 made of inorganic material such as 5i02 or metal on top of 2
is formed as shown in FIG. 2(b), and then a second resist layer 3 (for example, a positive resist mainly composed of PMMA) 3 is formed on the inorganic film 7. Next, as shown in FIG. 2(0), the second resist layer 3 is selectively exposed to deep ultraviolet rays by contact exposure and developed.
A resist pattern having openings 3a is formed as shown in FIG. Then, using the resist pattern as a mask, as shown in FIGS. 2(e) and 2(f), the inorganic film 7 and the first resist layer 2 are etched and exposed to deep ultraviolet rays, respectively.
By performing selective exposure and development, as shown in FIG. 2(f), an unburned opening (or groove>2a) suitable for a lift-off wiring is formed in the first resist layer 2.

[青用技術の問題点] 前記のごとき公知のマスクトランスファ技術にはそれぞ
れ、以下のごとき問題点があった。
[Problems with blue technology] Each of the known mask transfer technologies described above has the following problems.

第1図に示した第一の方法では、上層のレジメ1〜と下
層のレジストとが直接に接触するのでそれぞれのレジス
トに相溶性があると、該レジスト層の塗布形成時に塗布
むらが生じてレジスト層形成が不良になるという問題が
生じやすかった。 従って、従来は上層レジストと下層
レジストを同一にすることは側底できなかったが、より
微細なパターンの形成を可能とするためには上層レジス
トも遠紫外線用レジストにすることが望ましい。
In the first method shown in FIG. 1, the upper layer Regimes 1 to 1 are in direct contact with the lower resist layer, so if the respective resists are compatible, uneven coating will occur during coating formation of the resist layer. The problem of poor resist layer formation was likely to occur. Therefore, conventionally it has not been possible to make the upper layer resist and the lower layer resist the same, but in order to enable the formation of finer patterns, it is desirable that the upper layer resist also be a deep ultraviolet resist.

第2図に示した第二の方法は第一の方法に存する前記問
題点を解決するために提案された方法であり、前記無機
膜7は上層レジストと下層レジストとの相溶性に基因す
る塗布むらの発生を防止するために設けられたものであ
る。 しかしながら、前記第二の方法においては、該無
機膜7を形成除去する工程が一般に複雑である上、無機
膜形成時間が長くかかり、また、高価な無機膜形成設備
も5− 必要になる等の欠点があった。
The second method shown in FIG. 2 is a method proposed to solve the above-mentioned problems in the first method. This is provided to prevent unevenness from occurring. However, in the second method, the process of forming and removing the inorganic film 7 is generally complicated, takes a long time to form the inorganic film, and requires expensive inorganic film forming equipment. There were drawbacks.

[発明の目的] この発明は、前記従来方法に存する欠点を除き、より微
細なパターニングを従来方法よりも短かい時間と短かい
工程とで行うことのできる、半導体装置の製造方法を提
供することを目的とする。
[Object of the Invention] The present invention provides a method for manufacturing a semiconductor device, which eliminates the drawbacks of the conventional method and allows finer patterning to be performed in a shorter time and in shorter steps than the conventional method. With the goal.

また、この発明は、微細なリフトオフ配線に適する半導
体装置製造方法の提供を別の目的としている。
Another object of the present invention is to provide a method for manufacturing a semiconductor device suitable for fine lift-off wiring.

[発明の概要] この発明による方法は、半導体基板上に多層レジスト構
造を形成する過程において上層レジスト層と下層レジス
ト層との間に該両層に対して相溶性のない樹脂層を形成
させつつレジストの積層を行うことを特徴とするもので
あり、この発明の方法によれば、相溶性の点から、従来
方法よりも上下レジスト種類の選択について自由度を有
するとともに、はるかに短い時間及び低コストでレジス
ト層の形成を行うことができ′る。
[Summary of the Invention] The method according to the present invention forms a resin layer between an upper resist layer and a lower resist layer, which is incompatible with both layers, in the process of forming a multilayer resist structure on a semiconductor substrate. The method of the present invention is characterized by laminating resists, and from the viewpoint of compatibility, it has more freedom in selecting the types of upper and lower resists than the conventional method, and it also takes much less time and costs less. The resist layer can be formed at low cost.

例えば、上下のレジストがPMIPK(ポリメ6− ヂルイソプ[1ピルケ1−ン)を主成分とするものであ
れば、該樹脂層は例えば、エチルセロソルブを溶媒とす
るノボラック系樹脂で構成することができる。 このよ
うな上下レジストの組合せはザブミクロン級の微細リフ
トオフ用配線の高感度レジストの積層どして極めて好適
である。
For example, if the upper and lower resists are mainly composed of PMIPK (polymer 6-dilysop[1-pirkene]), the resin layer can be composed of a novolak-based resin using ethyl cellosolve as a solvent, for example. . Such a combination of upper and lower resists is extremely suitable for laminating high-sensitivity resists for submicron-level fine lift-off wiring.

[発明の実施例] 第3図(a )ないし第3図(C)を参照して本発明方
法の一実施例を説明する。
[Embodiment of the Invention] An embodiment of the method of the present invention will be described with reference to FIGS. 3(a) to 3(C).

本発明の方法においては、まず第3図(a )に示すよ
うに、半導体基板1の表面にPM I PKを主成分と
する遠紫外線用レジスト(東京応化社製0DUR−10
14>を塗布して第一レジスト層21を形成した後、エ
チルセロソルブを溶媒とするノボラック系樹脂を例えば
0.05〜0.07μm程度の厚さに塗布して樹脂層8
を形成する。
In the method of the present invention, first, as shown in FIG. 3(a), a deep ultraviolet resist (0DUR-10 manufactured by Tokyo Ohka Co., Ltd.
14> to form the first resist layer 21, a novolac resin using ethyl cellosolve as a solvent is applied to a thickness of, for example, about 0.05 to 0.07 μm to form the resin layer 8.
form.

更に、該樹脂層8の上に第一レジスト層21と同一のレ
ジストをやや薄く塗布して第11921層31を第3図
(h )のように形成した後、密着露光型の遠紫外線露
光装置で露光すると(9は該露光装置のマスク)、遠紫
外線に対して上下のレジスト1121.31が同時に感
光するので(樹脂層8は遠紫外線を透過さ−せる)、こ
れを現像すると第3図(C)のように上下のレジスト層
を貫通する開口10(もしくは溝)が形成される。
Furthermore, after applying a slightly thinner layer of the same resist as the first resist layer 21 on the resin layer 8 to form the 11921st layer 31 as shown in FIG. When exposed to light (9 is the mask of the exposure device), the upper and lower resists 1121.31 are simultaneously exposed to far ultraviolet rays (resin layer 8 transmits far ultraviolet rays), and when this is developed, the result shown in FIG. As shown in (C), an opening 10 (or groove) penetrating the upper and lower resist layers is formed.

第11921層31の形成時には、該第ニレジスト層と
相溶性のない樹脂層8が既に形成されているので、レジ
ストの塗布むらが起る恐れはなく、均一な塗布が可能と
なる。
At the time of forming the 11921st layer 31, the resin layer 8 which is incompatible with the second resist layer has already been formed, so there is no risk of uneven coating of the resist, and uniform coating is possible.

また、第一レジス(一層と第ニレジスト層とは相溶性の
点で制約がないので、第ニレジスト層に高感度遠紫外線
レジストを採用することができ、その結果0.5μm級
のりソグラフィが可能となる。
In addition, since there are no restrictions in terms of compatibility between the first resist layer and the second resist layer, a highly sensitive deep ultraviolet resist can be used for the second resist layer, and as a result, 0.5 μm class glue lithography is possible. Become.

そしてPMIPKのようなポジ型の積層レジスト層を形
成することによって、リフトオフ法に適するリソグラフ
ィをすることができる。
By forming a positive laminated resist layer such as PMIPK, lithography suitable for the lift-off method can be performed.

さらに、前記実施例では、上下のレジスト層21.31
を共に遠紫外線用の同一レジストを用いて形成したので
露光は一回で済み、従って従来方法よりも工程数が少く
なっている。
Furthermore, in the embodiment, the upper and lower resist layers 21.31
Since both are formed using the same resist for deep ultraviolet rays, only one exposure is required, and therefore the number of steps is fewer than in the conventional method.

樹脂層8の形成はレジスト層形成装置とほぼ同一のもの
を使用することができる上、短時間で終了する。 また
、従来方法のように蒸着装置等を必要としないので設備
コストが非常に低順である。
The resin layer 8 can be formed using almost the same equipment as the resist layer forming apparatus, and can be completed in a short time. In addition, unlike the conventional method, the method does not require a vapor deposition device, so the equipment cost is extremely low.

なお、前記実施例ではレジストの積層数を2とし、上下
のレジスト層を同一レジストで形成したが、レジメ1〜
層数を3以上とし各層を異種レジスi・で構成してもよ
いこては勿論である。 また、上下のレジスト層を電子
ビーム露光用レジストで形成し、かつ電子ビーム露光装
置で露光を作ってもよいことは当然である。
In the above example, the number of laminated resist layers was set to 2, and the upper and lower resist layers were formed with the same resist.
Of course, the iron may have three or more layers and each layer may be composed of different types of resists. It is also possible to form the upper and lower resist layers using resists for electron beam exposure and to perform exposure using an electron beam exposure apparatus.

[発明の効果] 以上に説明したように、この発明によれば、従来の半導
体装置の製造方法よりも簡単な工程で低コストで高精度
の半導体装置を製造することができる。
[Effects of the Invention] As described above, according to the present invention, a high-precision semiconductor device can be manufactured at low cost and through simpler steps than conventional semiconductor device manufacturing methods.

また、従来方法では塗布むらが発生するので不可能とさ
れるレジストの組合せも本発明方法では可能となり、従
って、従来方法よりも多様なかつ精微なパターニングが
可能となる上、露光時間の9− 短縮も可能となった。 ちなみに従来方法では下層の1
921〜層をPMMAのレジストで構成しているが、前
記実施例のように上下両層をPMIPKのレジストで構
成すると、従来方法に比べど露光時間は172〜1/3
に短縮する。
In addition, the method of the present invention enables combinations of resists that are impossible with conventional methods due to uneven coating.Therefore, it is possible to perform more diverse and precise patterning than with conventional methods, and the exposure time is 9-9 times shorter. is now also possible. By the way, in the conventional method, the lower layer 1
The 921~ layer is made of PMMA resist, but if both the upper and lower layers are made of PMIPK resist as in the above example, the exposure time is 172~1/3 compared to the conventional method.
shorten to

【図面の簡単な説明】[Brief explanation of drawings]

第1図及び第2図は従来のバターニング方法を工程順に
示した図、第3図は本発明方法の一実施例を示した図、
である。 1・・・半導体基板、 2・・・第一レジスト層、 3
・・・第ニレジスト、 4・・・(露光装置の)マスク
、5・・・近紫外線、 6・・・遠紫外線、 7・・・
無機膜、8・・・樹脂層、 9・・・(露光装置の)マ
スク、21・・・第一レジスト層、 31・・・第ニレ
ジスト層。 特許出願人 東京芝浦電気株式会社 10− 第15!I 第2図 第3図
1 and 2 are diagrams showing a conventional buttering method in the order of steps, and FIG. 3 is a diagram showing an embodiment of the method of the present invention.
It is. 1... Semiconductor substrate, 2... First resist layer, 3
...Second resist, 4...Mask (of exposure equipment), 5...Near ultraviolet rays, 6...Far ultraviolet rays, 7...
Inorganic film, 8... Resin layer, 9... Mask (of exposure device), 21... First resist layer, 31... Second resist layer. Patent applicant Tokyo Shibaura Electric Co., Ltd. 10-15! I Figure 2 Figure 3

Claims (1)

【特許請求の範囲】 1 半導体基板上に少なくとも二層以上から成る積層レ
ジスト層を形成する工程と、該積層レジスト層の最上部
レジスト層を選択開口してレジストパターンを形成した
後に該レジストパターンをマスクとしてそれより下層の
レジスト層を順次開口する工程とを含む半導体装置の製
造方法において、 該積層レジスト層の形成工程で各レジスト層間に上下の
各レジスト層に対して相溶性のない樹脂層を形成させて
おくことを特徴とする半導体装置の製造方法。 2 積層レジスト層がリフトオフ配線用レジスト層であ
る特許請求の範囲第1項記載の製造方法。
[Claims] 1. A step of forming a laminated resist layer consisting of at least two or more layers on a semiconductor substrate, forming a resist pattern by selectively opening the uppermost resist layer of the laminated resist layer, and then opening the resist pattern. A method for manufacturing a semiconductor device including a step of sequentially opening resist layers below the resist layer as a mask, in which a resin layer incompatible with the upper and lower resist layers is formed between each resist layer in the step of forming the laminated resist layer. 1. A method for manufacturing a semiconductor device, characterized by forming the semiconductor device in advance. 2. The manufacturing method according to claim 1, wherein the laminated resist layer is a resist layer for lift-off wiring.
JP21098583A 1983-11-11 1983-11-11 Manufacture of semiconductor device Granted JPS60103614A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21098583A JPS60103614A (en) 1983-11-11 1983-11-11 Manufacture of semiconductor device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21098583A JPS60103614A (en) 1983-11-11 1983-11-11 Manufacture of semiconductor device

Publications (2)

Publication Number Publication Date
JPS60103614A true JPS60103614A (en) 1985-06-07
JPH0469411B2 JPH0469411B2 (en) 1992-11-06

Family

ID=16598398

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21098583A Granted JPS60103614A (en) 1983-11-11 1983-11-11 Manufacture of semiconductor device

Country Status (1)

Country Link
JP (1) JPS60103614A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006108500A (en) * 2004-10-07 2006-04-20 Shin Etsu Polymer Co Ltd Method for forming conductive pattern

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58204532A (en) * 1982-05-24 1983-11-29 Hitachi Ltd Formation of pattern

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58204532A (en) * 1982-05-24 1983-11-29 Hitachi Ltd Formation of pattern

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006108500A (en) * 2004-10-07 2006-04-20 Shin Etsu Polymer Co Ltd Method for forming conductive pattern

Also Published As

Publication number Publication date
JPH0469411B2 (en) 1992-11-06

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