JPH03104113A - Formation of resist pattern - Google Patents

Formation of resist pattern

Info

Publication number
JPH03104113A
JPH03104113A JP1241313A JP24131389A JPH03104113A JP H03104113 A JPH03104113 A JP H03104113A JP 1241313 A JP1241313 A JP 1241313A JP 24131389 A JP24131389 A JP 24131389A JP H03104113 A JPH03104113 A JP H03104113A
Authority
JP
Japan
Prior art keywords
resist
resist film
intermediate layer
film
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1241313A
Other languages
Japanese (ja)
Inventor
Jukichi Tsunako
津波古 充吉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yokogawa Electric Corp
Original Assignee
Yokogawa Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yokogawa Electric Corp filed Critical Yokogawa Electric Corp
Priority to JP1241313A priority Critical patent/JPH03104113A/en
Publication of JPH03104113A publication Critical patent/JPH03104113A/en
Pending legal-status Critical Current

Links

Landscapes

  • Preparing Plates And Mask In Photomechanical Process (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)

Abstract

PURPOSE:To form a pattern with high precision without fail by a method wherein a photo reflecting or absorbing intermediate layer is provided between the first and second resist films and then the first resist film is removed by exposure and development processes. CONSTITUTION:The surface of a silicon substrate 1 having stepped parts is coated with the first resist 2 to smooth the surface. Next, an Al thin film as a photo reflecting intermediate layer 3a is formed on the first resist film 2. Next, the second resist film 4 is formed on the intermediate layer 3a. Next, the second resist film 4 is exposed and developed using the conventional photolithographic process to form a resist pattern region 5 so that the Al thin film 3a as the intermediate layer may be exposed. Next, the Al thin film 3a is etched away using the second resist film 4 as a mask. Finally, the first resist film 2 is removed by exposure and development processes using the Al thin film 3a as a mask.

Description

【発明の詳細な説明】 く産業上の利用分野〉 本発明は段差を有する基板(例えばSi)へのパターン
形成方法に関し,安定,確実なパターニングにより精度
向上をはかったレジストパターンの形成方法に関する. 〈従来の技術〉 段差のある基板へのレジストパターンの形成は多層レジ
スト法を用いて行われる.この多層レジスト法には3層
レジスト法,2層レジスト法,PC M ( Port
able Confornable Hasking)
法等が知られている。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for forming a pattern on a substrate (for example, Si) having steps, and more particularly, to a method for forming a resist pattern that improves accuracy through stable and reliable patterning. <Conventional technology> A multilayer resist method is used to form a resist pattern on a substrate with steps. This multi-layer resist method includes three-layer resist method, two-layer resist method, PCM (Port
Conformable Hasking)
The law is known.

第2図(a)〜(f)は3層レジスト法を示す概略工程
図である.工程に従って説明する.(a)段差を有する
基板1上に第1のレジスト膜2を形成する工程. (b)前記第1のレジスト膜2上にSi02などの中間
層3を形成する工程. (c)前記中間層3の上に第2のレジスト膜4を形成す
る工程. (d)前記第2のレジスト膜4を露光・現像によりパタ
ーニングし前記中間層3を露出させる工程.(e)前記
第2のレジスト膜4をマスクとして前記中間層3をフロ
ロカーボン(CF4)系RIE(反応性イオンエッチン
グ)により除去し前記第1のレジスト膜2を露出させる
工程. (f)前記第2のレジスト11!4および中間層3をマ
スクとして02系RIEにより前記第1のレジスト膜2
を除去し前記基板1を露出させる工程.第3図(a)〜
(d)は2層レジスト法を示す概略工程図である.工程
に従って説明する.(a)段差を有する基板1上に第1
のレジスト膜2を形成する工程. (b)前記第1のレジスト膜2上に第2のレジストM4
を形成する工程。
FIGS. 2(a) to 2(f) are schematic process diagrams showing the three-layer resist method. I will explain the process step by step. (a) Step of forming a first resist film 2 on a substrate 1 having a step. (b) Step of forming an intermediate layer 3 such as Si02 on the first resist film 2. (c) Step of forming a second resist film 4 on the intermediate layer 3. (d) A step of patterning the second resist film 4 by exposure and development to expose the intermediate layer 3. (e) Using the second resist film 4 as a mask, the intermediate layer 3 is removed by fluorocarbon (CF4)-based RIE (reactive ion etching) to expose the first resist film 2. (f) The first resist film 2 is formed by 02-based RIE using the second resist 11!4 and the intermediate layer 3 as a mask.
a step of removing and exposing the substrate 1. Figure 3(a)~
(d) is a schematic process diagram showing the two-layer resist method. I will explain the process step by step. (a) A first plate is placed on a substrate 1 having steps.
Step of forming resist film 2. (b) A second resist M4 is formed on the first resist film 2.
The process of forming.

(c)前記第2のレジスト膜4を露光・現像によりバタ
ーニングし前記第1のレジスト膜2を露出させる工程。
(c) A step of patterning the second resist film 4 by exposure and development to expose the first resist film 2.

(d)前記第2のレジスト膜4をマスクとして02系R
IEにより前記第1のレジスト膜2を除去し前記基板1
を露出させる工程. 第4図(a)〜(d)はPCM法を示す概略工程図であ
る.この工程は2層レジスト法と同様であるが,第1の
レジストftlA2としてDUV(DeepUltra
  Violet)系レジストを用いる点が異なってお
り,工程(C)で第2のレジスト膜4を露光・現像によ
りバターニングした後,工程(d)ではDUV光を全面
照射した後現像によって第1のレジスト膜を除去する, く発明が解決しようとする課題〉 しかしながら.上記従来のパターン形成方法においては
次のような問題があった. ■3層.2層レジスト法においては第1のレジストを除
去する際に02RIEを用いるが.このとき02イオン
により叩き出されたレジストのボリマーがマスクとして
残る第1のレジスト3の測面や露出した基板に付着する
。これは次の工程で基板にスバッタや蒸着などを行うよ
うな場合の障害となる. ■また,PCM法においては第1,第2のレジスト層が
混合する恐れがあり,精密なパターン形成には問題があ
る. 本発明は上記従来技術の問題点にに鑑みて成されたもの
で,安定,確実なパターニングにより精度向上をはかっ
たレジストパターンの形或方法を実現する事を目的とす
る. 〈課題を解決するための手段〉 上記課題を解決するための本発明の構成は,レジストパ
ターンの形成方法において, 段差を有する基板上に表面が平らな第1のレジスト膜を
形成する工程と.前記第1のレジスト膜上に露光光を反
射または吸収する中間層を形成する工程と,前記中間層
上に第2のレジスト膜を形成する工程と,前記第2のレ
ジスト膜をパターニングして前記中間層を露出させる工
程と,前記第2のレジストパターンをマスクとして前記
中間層を除去する工程と,前記中間層をマスクとして前
記第1のレジスト膜を全面露光・現像を行うことにより
除去する工程を含んで形成された事を特徴とするもので
ある. く作用〉 第1のレジストと第2のレジストの間に光を反射または
吸収する中間層を設けたので.第1のレジストを除去す
る際も露光・現像を用いる事が出来る. 〈実施例〉 以下.本発明のレジストパターンの形成方法について図
面を参照して説明する.第1図(a)〜(f)は本発明
の一実施例の構成を示す概略製作工程図である.工程に
従って説明する。
(d) 02 series R using the second resist film 4 as a mask
The first resist film 2 is removed by IE and the substrate 1 is removed.
The process of exposing Figures 4(a) to 4(d) are schematic process diagrams showing the PCM method. This process is similar to the two-layer resist method, but DUV (Deep Ultra) is used as the first resist ftlA2.
The difference is that a Violet-based resist is used, and after the second resist film 4 is patterned by exposure and development in step (C), the first resist film 4 is patterned by irradiating the entire surface with DUV light and then developed in step (d). Problems that the invention attempts to solve by removing the resist film However,. The conventional pattern forming method described above had the following problems. ■3 layers. In the two-layer resist method, 02RIE is used to remove the first resist. At this time, the polymer of the resist ejected by the 02 ions adheres to the surface of the first resist 3 remaining as a mask and to the exposed substrate. This becomes an obstacle when sputtering or vapor deposition is performed on the substrate in the next process. ■Also, in the PCM method, there is a risk that the first and second resist layers may mix, which poses a problem in forming precise patterns. The present invention was made in view of the problems of the prior art described above, and aims to realize a resist pattern shape or method that improves accuracy through stable and reliable patterning. <Means for Solving the Problems> The structure of the present invention for solving the above problems is as follows: A method for forming a resist pattern includes a step of forming a first resist film with a flat surface on a substrate having a step. forming an intermediate layer that reflects or absorbs exposure light on the first resist film; forming a second resist film on the intermediate layer; patterning the second resist film to a step of exposing the intermediate layer; a step of removing the intermediate layer using the second resist pattern as a mask; and a step of removing the first resist film by exposing and developing the entire surface using the intermediate layer as a mask. It is characterized by being formed by including. Effect> An intermediate layer that reflects or absorbs light is provided between the first resist and the second resist. Exposure and development can also be used to remove the first resist. <Example> Below. A method for forming a resist pattern according to the present invention will be explained with reference to the drawings. FIGS. 1(a) to 1(f) are schematic manufacturing process diagrams showing the configuration of an embodiment of the present invention. The process will be explained step by step.

工程(a) 段差を有するシリコン基板1の表面にスビナを用いて3
μm程度の厚さに第1のレジスト2を塗布して表面を平
滑にする. 工程(b) 第1のレジスト膜2上にスパッタや蒸着等より光を反射
する中間層3aとしてAl薄膜を0.1μm程度の厚さ
に形成する. ■程(c) そのA/薄膜3aの上に厚さ1μm程度の第2のレジス
ト膜4を形成する. 工程(d) 第2のレジスト膜4を通常のフォトリソ工程を用いて露
光・現像し,レジストパターン領域5を形成してA1薄
膜3aを露出させる. 工程(e) 第2のレジスト膜4をマスクとしてA l 薄11a 
3aをエッチングにより除去する。
Step (a) Using a subina on the surface of the silicon substrate 1 having steps, 3
The first resist 2 is applied to a thickness of about μm to make the surface smooth. Step (b) A thin Al film with a thickness of about 0.1 μm is formed as a light-reflecting intermediate layer 3a on the first resist film 2 by sputtering, vapor deposition, or the like. (c) A second resist film 4 with a thickness of about 1 μm is formed on the A/thin film 3a. Step (d) The second resist film 4 is exposed and developed using a normal photolithography process to form a resist pattern region 5 and expose the A1 thin film 3a. Step (e) Al thin layer 11a using the second resist film 4 as a mask
3a is removed by etching.

工程(f) Al薄膜3aをマスクとして露光・現iIAte行い第
1のレジスト12を除去する。
Step (f) Using the Al thin film 3a as a mask, exposure and development are performed to remove the first resist 12.

なお,本実施例においては中間層としてAI薄膜を用い
たが,Al薄膜に限ることなく光を反射または吸収する
部材であれば良い. 〈発明の効果〉 以上,実施例とともに具体的に説明したように本発明の
レジストのパターニング方法によれば,第1のレジスト
と第2のレジストの間に光を反射または吸収する中間層
を設けたので,第1のレジストを除去する際も露光・現
像を用いる事が出来安定.i実に精度の良いパターンを
形成する事が出来る。
Although an AI thin film was used as the intermediate layer in this example, it is not limited to an Al thin film, and any material that reflects or absorbs light may be used. <Effects of the Invention> As specifically explained above in conjunction with the examples, according to the resist patterning method of the present invention, an intermediate layer that reflects or absorbs light is provided between the first resist and the second resist. Therefore, exposure and development can be used to remove the first resist and it is stable. It is possible to form patterns with very high precision.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明のレジストパターンの形成方法の一実施
例を示す概略工程図,第2図〜第4図は従来のバターニ
ング方法の概略工程を示す図である. 1・・・シリコン基板,2・・・第1のレジスト膜,3
・・・中間層,4・・・第2のレジスト膜,5・・・パ
ターン第 1 図 泰2図 第3図
FIG. 1 is a schematic process diagram showing an embodiment of the resist pattern forming method of the present invention, and FIGS. 2 to 4 are diagrams showing schematic steps of a conventional patterning method. 1... Silicon substrate, 2... First resist film, 3
...Intermediate layer, 4...Second resist film, 5...Pattern Fig. 1 Fig. 2 Fig. 3

Claims (1)

【特許請求の範囲】 以下の工程を含むレジストパターンの形成方法。 1)段差を有する基板上に表面が平らな第1のレジスト
膜を形成する工程と、 2)前記第1のレジスト膜上に露光光を反射または吸収
する中間層を形成する工程と、 3)前記中間層上に第2のレジスト膜を形成する工程と
、 4)前記第2のレジスト膜をパターニングして前記中間
層を露出させる工程と、 5)前記第2のレジストパターンをマスクとして前記中
間層を除去する工程と、 6)前記中間層をマスクとして前記第1のレジスト膜を
全面露光・現像を行うことにより除去する工程。
[Claims] A method for forming a resist pattern including the following steps. 1) forming a first resist film with a flat surface on a substrate having steps; 2) forming an intermediate layer that reflects or absorbs exposure light on the first resist film; 3) forming a second resist film on the intermediate layer; 4) patterning the second resist film to expose the intermediate layer; 5) using the second resist pattern as a mask to expose the intermediate layer; 6) removing the first resist film by exposing and developing the entire surface of the first resist film using the intermediate layer as a mask.
JP1241313A 1989-09-18 1989-09-18 Formation of resist pattern Pending JPH03104113A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1241313A JPH03104113A (en) 1989-09-18 1989-09-18 Formation of resist pattern

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1241313A JPH03104113A (en) 1989-09-18 1989-09-18 Formation of resist pattern

Publications (1)

Publication Number Publication Date
JPH03104113A true JPH03104113A (en) 1991-05-01

Family

ID=17072436

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1241313A Pending JPH03104113A (en) 1989-09-18 1989-09-18 Formation of resist pattern

Country Status (1)

Country Link
JP (1) JPH03104113A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0792688A (en) * 1990-02-26 1995-04-07 Applied Materials Inc Method of multilayer photoresist etching
US7354699B2 (en) 2001-11-06 2008-04-08 Hitachi Metals, Ltd. Method for producing alignment mark

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0792688A (en) * 1990-02-26 1995-04-07 Applied Materials Inc Method of multilayer photoresist etching
US7354699B2 (en) 2001-11-06 2008-04-08 Hitachi Metals, Ltd. Method for producing alignment mark

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