JPH1197065A - 超薄層固体リチウム電池及びその製造方法 - Google Patents
超薄層固体リチウム電池及びその製造方法Info
- Publication number
- JPH1197065A JPH1197065A JP10151857A JP15185798A JPH1197065A JP H1197065 A JPH1197065 A JP H1197065A JP 10151857 A JP10151857 A JP 10151857A JP 15185798 A JP15185798 A JP 15185798A JP H1197065 A JPH1197065 A JP H1197065A
- Authority
- JP
- Japan
- Prior art keywords
- battery
- thin
- polymer electrolyte
- manufacturing
- electrolyte battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0436—Small-sized flat cells or batteries for portable equipment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
- H01M6/188—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/40—Printed batteries, e.g. thin film batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49112—Electric battery cell making including laminating of indefinite length material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Dispersion Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002203490A CA2203490A1 (fr) | 1997-04-23 | 1997-04-23 | Piles au lithium ultra-minces et a l'etat solide et procede de fabrication |
| CA2203490 | 1997-04-23 | ||
| CA002203869A CA2203869A1 (fr) | 1997-04-28 | 1997-04-28 | Piles au lithium ultra-minces et a l'etat solide et procede de fabrication |
| CA2203869 | 1997-04-28 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011016787A Division JP2011151029A (ja) | 1997-04-23 | 2011-01-28 | 超薄層固体リチウム電池及びその製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH1197065A true JPH1197065A (ja) | 1999-04-09 |
Family
ID=25679267
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10151857A Withdrawn JPH1197065A (ja) | 1997-04-23 | 1998-04-23 | 超薄層固体リチウム電池及びその製造方法 |
| JP2011016787A Pending JP2011151029A (ja) | 1997-04-23 | 2011-01-28 | 超薄層固体リチウム電池及びその製造方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011016787A Pending JP2011151029A (ja) | 1997-04-23 | 2011-01-28 | 超薄層固体リチウム電池及びその製造方法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US6030421A (cg-RX-API-DMAC10.html) |
| EP (1) | EP0875952B1 (cg-RX-API-DMAC10.html) |
| JP (2) | JPH1197065A (cg-RX-API-DMAC10.html) |
| DE (1) | DE69802134T2 (cg-RX-API-DMAC10.html) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11307086A (ja) * | 1998-04-21 | 1999-11-05 | Japan Energy Corp | ポリマー電池製造におけるカソード及びアノードフィルム作製方法 |
| JP2001167751A (ja) * | 1999-12-09 | 2001-06-22 | Matsushita Electric Ind Co Ltd | 電池のリード線接続方法及び装置 |
| JP2002319391A (ja) * | 2001-04-20 | 2002-10-31 | Sumitomo Electric Ind Ltd | リチウム電池負極およびその製造方法 |
| JP2006511908A (ja) * | 2002-12-23 | 2006-04-06 | バッツキャップ | 電気エネルギー貯蔵アッセンブリの巻回装置の構造 |
| JP2006519470A (ja) * | 2003-03-05 | 2006-08-24 | アベスター、リミテッド、パートナーシップ | 電気化学セル積層体の層を電気的に絶縁するための製造プロセスおよび装置 |
| JP2007506224A (ja) * | 2003-09-18 | 2007-03-15 | アベスター、リミテッド、パートナーシップ | 高分子バッテリーの組合せ体の積み重ね装置および方法 |
| JP2011151029A (ja) * | 1997-04-23 | 2011-08-04 | Bathium Canada Inc | 超薄層固体リチウム電池及びその製造方法 |
| JP2012252962A (ja) * | 2011-06-06 | 2012-12-20 | Tokyo Univ Of Science | ナトリウム二次電池 |
| WO2013161926A1 (ja) * | 2012-04-27 | 2013-10-31 | 株式会社日本マイクロニクス | 二次電池 |
| WO2019221010A1 (ja) * | 2018-05-14 | 2019-11-21 | 日立化成株式会社 | 二次電池用電池部材の製造方法、及び、二次電池 |
| JP2020061258A (ja) * | 2018-10-09 | 2020-04-16 | 本田技研工業株式会社 | 固体電池の製造方法 |
| JPWO2021250803A1 (cg-RX-API-DMAC10.html) * | 2020-06-10 | 2021-12-16 |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69942866D1 (de) * | 1998-06-25 | 2010-11-25 | Hydro Quebec | Polymere aus Blockcopolymerisierbaren Monomeren und ihre Verwendung in der Herstellung von Ionenleitern |
| US6616714B1 (en) * | 1998-09-14 | 2003-09-09 | Hydro-Quebec | Process for cutting polymer electrolyte multi-layer batteries and batteries obtained thereby |
| US6761744B1 (en) | 1999-07-16 | 2004-07-13 | Quallion Llc | Lithium thin film lamination technology on electrode to increase battery capacity |
| US6645675B1 (en) | 1999-09-02 | 2003-11-11 | Lithium Power Technologies, Inc. | Solid polymer electrolytes |
| US6664006B1 (en) | 1999-09-02 | 2003-12-16 | Lithium Power Technologies, Inc. | All-solid-state electrochemical device and method of manufacturing |
| US6823571B1 (en) * | 2000-01-24 | 2004-11-30 | Atd Corporation | Apparatus and method for manufacture of multilayer metal products |
| JP2001266952A (ja) * | 2000-03-23 | 2001-09-28 | Sony Corp | リチウムイオン電池およびその製造方法 |
| FR2831331B1 (fr) * | 2001-10-22 | 2004-11-19 | Commissariat Energie Atomique | Procede de fabrication d'une micro-batterie |
| US20030104282A1 (en) * | 2001-11-15 | 2003-06-05 | Weibing Xing | In situ thermal polymerization method for making gel polymer lithium ion rechargeable electrochemical cells |
| US6916679B2 (en) * | 2002-08-09 | 2005-07-12 | Infinite Power Solutions, Inc. | Methods of and device for encapsulation and termination of electronic devices |
| US8394522B2 (en) * | 2002-08-09 | 2013-03-12 | Infinite Power Solutions, Inc. | Robust metal film encapsulation |
| US8431264B2 (en) * | 2002-08-09 | 2013-04-30 | Infinite Power Solutions, Inc. | Hybrid thin-film battery |
| US8236443B2 (en) * | 2002-08-09 | 2012-08-07 | Infinite Power Solutions, Inc. | Metal film encapsulation |
| US8404376B2 (en) | 2002-08-09 | 2013-03-26 | Infinite Power Solutions, Inc. | Metal film encapsulation |
| US8445130B2 (en) * | 2002-08-09 | 2013-05-21 | Infinite Power Solutions, Inc. | Hybrid thin-film battery |
| US8021778B2 (en) | 2002-08-09 | 2011-09-20 | Infinite Power Solutions, Inc. | Electrochemical apparatus with barrier layer protected substrate |
| US7993773B2 (en) | 2002-08-09 | 2011-08-09 | Infinite Power Solutions, Inc. | Electrochemical apparatus with barrier layer protected substrate |
| US20070264564A1 (en) | 2006-03-16 | 2007-11-15 | Infinite Power Solutions, Inc. | Thin film battery on an integrated circuit or circuit board and method thereof |
| KR101056603B1 (ko) * | 2002-08-16 | 2011-08-11 | 프라운호퍼-게젤샤프트 츄어 푀르더룽 데어 안게반텐 포르슝에.파우. | 전기 화학적 성분을 생산하기 위한, 펀칭 패턴을 갖는 컴파운드 필름 |
| US8445137B1 (en) | 2002-11-27 | 2013-05-21 | Quallion Llc | Primary battery having sloped voltage decay |
| US8728285B2 (en) * | 2003-05-23 | 2014-05-20 | Demaray, Llc | Transparent conductive oxides |
| US20050287441A1 (en) * | 2004-06-23 | 2005-12-29 | Stefano Passerini | Lithium polymer electrolyte batteries and methods of making |
| KR101127370B1 (ko) | 2004-12-08 | 2012-03-29 | 인피니트 파워 솔루션스, 인크. | LiCoO2의 증착 |
| US7959769B2 (en) * | 2004-12-08 | 2011-06-14 | Infinite Power Solutions, Inc. | Deposition of LiCoO2 |
| KR100803189B1 (ko) * | 2005-04-14 | 2008-02-14 | 삼성에스디아이 주식회사 | 전극, 그 제조 방법, 바인더 조성물 및 이들을 채용한 리튬전지 |
| TWI467840B (zh) * | 2005-09-02 | 2015-01-01 | A123 Systems Inc | 奈米組成電極以及其相關裝置 |
| US7780745B2 (en) * | 2005-10-10 | 2010-08-24 | Silverman Martin S | Conformal lithium polymer battery |
| US7968231B2 (en) * | 2005-12-23 | 2011-06-28 | U Chicago Argonne, Llc | Electrode materials and lithium battery systems |
| KR100790849B1 (ko) * | 2006-01-27 | 2008-01-02 | 삼성에스디아이 주식회사 | 폴리우레탄 바인더, 이를 포함하는 전극 및 상기 전극을채용한 리튬 전지 |
| CA2552282A1 (fr) | 2006-07-18 | 2008-01-18 | Hydro Quebec | Materiau multi-couches a base de lithium vif, procedes de preparation et applications dans les generateurs electrochimiques |
| US7718319B2 (en) | 2006-09-25 | 2010-05-18 | Board Of Regents, The University Of Texas System | Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries |
| US8062708B2 (en) * | 2006-09-29 | 2011-11-22 | Infinite Power Solutions, Inc. | Masking of and material constraint for depositing battery layers on flexible substrates |
| US8197781B2 (en) * | 2006-11-07 | 2012-06-12 | Infinite Power Solutions, Inc. | Sputtering target of Li3PO4 and method for producing same |
| KR101430615B1 (ko) * | 2007-09-19 | 2014-08-14 | 삼성에스디아이 주식회사 | 캐소드 및 이를 채용한 리튬 전지 |
| TWI441937B (zh) * | 2007-12-21 | 2014-06-21 | Infinite Power Solutions Inc | 形成用於電解質薄膜之濺鍍靶材的方法 |
| US8268488B2 (en) | 2007-12-21 | 2012-09-18 | Infinite Power Solutions, Inc. | Thin film electrolyte for thin film batteries |
| KR101606183B1 (ko) | 2008-01-11 | 2016-03-25 | 사푸라스트 리써치 엘엘씨 | 박막 배터리 및 기타 소자를 위한 박막 캡슐화 |
| US8017227B2 (en) * | 2008-03-03 | 2011-09-13 | Parviz Soroushian | Adaptive composite materials |
| CN101983469B (zh) * | 2008-04-02 | 2014-06-04 | 无穷动力解决方案股份有限公司 | 与能量采集关联的储能装置的无源过电压/欠电压控制和保护 |
| KR20110058793A (ko) | 2008-08-11 | 2011-06-01 | 인피니트 파워 솔루션스, 인크. | 전자기 에너지를 수확하기 위한 일체형 컬렉터 표면을 갖는 에너지 디바이스 및 전자기 에너지를 수확하는 방법 |
| WO2010030743A1 (en) * | 2008-09-12 | 2010-03-18 | Infinite Power Solutions, Inc. | Energy device with integral conductive surface for data communication via electromagnetic energy and method thereof |
| WO2010042594A1 (en) * | 2008-10-08 | 2010-04-15 | Infinite Power Solutions, Inc. | Environmentally-powered wireless sensor module |
| US20100294428A1 (en) * | 2009-05-20 | 2010-11-25 | Snyder Shawn W | Method of Integrating Electrochemical Devices Into and Onto Fixtures |
| KR101792287B1 (ko) * | 2009-09-01 | 2017-10-31 | 사푸라스트 리써치 엘엘씨 | 집적된 박막 배터리를 갖는 인쇄 회로 보드 |
| US20110300432A1 (en) | 2010-06-07 | 2011-12-08 | Snyder Shawn W | Rechargeable, High-Density Electrochemical Device |
| JP6137747B2 (ja) * | 2012-03-28 | 2017-05-31 | 住友化学株式会社 | ナトリウム二次電池用活物質、ナトリウム二次電池用電極、ナトリウム二次電池 |
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| DE102018221609A1 (de) | 2018-12-13 | 2020-06-18 | Robert Bosch Gmbh | Verfahren zur Herstellung eines Elektrodenfilms für einen Energiespeicher |
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| JPH01276567A (ja) * | 1988-04-28 | 1989-11-07 | Brother Ind Ltd | 積層型ペーパバッテリの製造法 |
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| DE69802134T2 (de) * | 1997-04-23 | 2002-03-07 | Hydro-Quebec, Montreal | Dünnschicht Feststoff Lithiumzellen und Verfahren zur Herstellung |
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- 1998-04-23 EP EP98201306A patent/EP0875952B1/fr not_active Expired - Lifetime
- 1998-04-23 US US09/064,821 patent/US6030421A/en not_active Expired - Lifetime
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2011
- 2011-01-28 JP JP2011016787A patent/JP2011151029A/ja active Pending
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| JPS6059655A (ja) * | 1983-09-12 | 1985-04-06 | Hitachi Maxell Ltd | リチウム電極の製造法 |
| JPH01276567A (ja) * | 1988-04-28 | 1989-11-07 | Brother Ind Ltd | 積層型ペーパバッテリの製造法 |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011151029A (ja) * | 1997-04-23 | 2011-08-04 | Bathium Canada Inc | 超薄層固体リチウム電池及びその製造方法 |
| JPH11307086A (ja) * | 1998-04-21 | 1999-11-05 | Japan Energy Corp | ポリマー電池製造におけるカソード及びアノードフィルム作製方法 |
| JP2001167751A (ja) * | 1999-12-09 | 2001-06-22 | Matsushita Electric Ind Co Ltd | 電池のリード線接続方法及び装置 |
| JP2002319391A (ja) * | 2001-04-20 | 2002-10-31 | Sumitomo Electric Ind Ltd | リチウム電池負極およびその製造方法 |
| JP2006511908A (ja) * | 2002-12-23 | 2006-04-06 | バッツキャップ | 電気エネルギー貯蔵アッセンブリの巻回装置の構造 |
| JP2006519470A (ja) * | 2003-03-05 | 2006-08-24 | アベスター、リミテッド、パートナーシップ | 電気化学セル積層体の層を電気的に絶縁するための製造プロセスおよび装置 |
| JP2011198774A (ja) * | 2003-03-05 | 2011-10-06 | Bathium Canada Inc | 電気化学セル積層体の層を電気的に絶縁するための製造プロセスおよび装置 |
| JP4869918B2 (ja) * | 2003-03-05 | 2012-02-08 | バシウム・カナダ・インコーポレーテッド | 電気化学セル積層体の層を電気的に絶縁するための製造プロセスおよび装置 |
| JP2007506224A (ja) * | 2003-09-18 | 2007-03-15 | アベスター、リミテッド、パートナーシップ | 高分子バッテリーの組合せ体の積み重ね装置および方法 |
| JP4786342B2 (ja) * | 2003-09-18 | 2011-10-05 | バシウム・カナダ・インコーポレーテッド | 高分子バッテリーの組合せ体の積み重ね装置および方法 |
| JP2012252962A (ja) * | 2011-06-06 | 2012-12-20 | Tokyo Univ Of Science | ナトリウム二次電池 |
| WO2013161926A1 (ja) * | 2012-04-27 | 2013-10-31 | 株式会社日本マイクロニクス | 二次電池 |
| WO2013161051A1 (ja) * | 2012-04-27 | 2013-10-31 | 株式会社日本マイクロニクス | 二次電池 |
| CN104247124A (zh) * | 2012-04-27 | 2014-12-24 | 日本麦可罗尼克斯股份有限公司 | 二次电池 |
| TWI504035B (zh) * | 2012-04-27 | 2015-10-11 | Nihon Micronics Kk | Secondary battery |
| JPWO2013161926A1 (ja) * | 2012-04-27 | 2015-12-24 | 株式会社日本マイクロニクス | 二次電池 |
| US9972862B2 (en) | 2012-04-27 | 2018-05-15 | Kabushiki Kaisha Nihon Micronics | Secondary battery |
| WO2019221010A1 (ja) * | 2018-05-14 | 2019-11-21 | 日立化成株式会社 | 二次電池用電池部材の製造方法、及び、二次電池 |
| JP2020061258A (ja) * | 2018-10-09 | 2020-04-16 | 本田技研工業株式会社 | 固体電池の製造方法 |
| CN111029634A (zh) * | 2018-10-09 | 2020-04-17 | 本田技研工业株式会社 | 固体电池的制造方法 |
| JPWO2021250803A1 (cg-RX-API-DMAC10.html) * | 2020-06-10 | 2021-12-16 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69802134T2 (de) | 2002-03-07 |
| JP2011151029A (ja) | 2011-08-04 |
| DE69802134D1 (de) | 2001-11-29 |
| EP0875952A1 (fr) | 1998-11-04 |
| EP0875952B1 (fr) | 2001-10-24 |
| US6030421A (en) | 2000-02-29 |
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