JPH10505371A - 低着色のマレイン化高酸価高分子量ポリプロピレン - Google Patents
低着色のマレイン化高酸価高分子量ポリプロピレンInfo
- Publication number
- JPH10505371A JPH10505371A JP8508214A JP50821496A JPH10505371A JP H10505371 A JPH10505371 A JP H10505371A JP 8508214 A JP8508214 A JP 8508214A JP 50821496 A JP50821496 A JP 50821496A JP H10505371 A JPH10505371 A JP H10505371A
- Authority
- JP
- Japan
- Prior art keywords
- polypropylene
- maleic anhydride
- maleated
- weight
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 polypropylene Polymers 0.000 title claims abstract description 148
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 139
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 139
- 239000002253 acid Substances 0.000 title claims abstract description 40
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 76
- 238000000034 method Methods 0.000 claims abstract description 51
- 239000003999 initiator Substances 0.000 claims abstract description 26
- 150000003254 radicals Chemical class 0.000 claims abstract description 23
- 239000008240 homogeneous mixture Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 22
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 8
- 150000002978 peroxides Chemical group 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000004677 Nylon Substances 0.000 claims description 5
- 229920001778 nylon Polymers 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 claims description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 229930004008 p-menthane Natural products 0.000 claims description 2
- CFJYNSNXFXLKNS-UHFFFAOYSA-N trans-p-menthane Natural products CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 claims description 2
- 238000010348 incorporation Methods 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 238000010924 continuous production Methods 0.000 abstract description 7
- 239000000047 product Substances 0.000 description 22
- 239000002904 solvent Substances 0.000 description 14
- 238000013467 fragmentation Methods 0.000 description 8
- 238000006062 fragmentation reaction Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 229920000098 polyolefin Polymers 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 238000010923 batch production Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 238000010309 melting process Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920001074 Tenite Polymers 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000013466 adhesive and sealant Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 230000001808 coupling effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000002478 γ-tocopherol Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.4.5より大きい酸価、76以下の黄色度カラー指数及び少なくとも20,000の 数平均分子量を有するマレイン化ポリプロピレンを含んでなる組成物。 2.酸価が9〜60であり、黄色度カラー指数が60より小さい請求の範囲第1項 に記載の組成物。 3.黄色度カラー指数が40より小さく、数平均分子量が20,000〜100,000であ り、マレイン化ポリプロピレンに2重量%より少ないコモノマーが含有されてい る請求の範囲第1項に記載の組成物。 4.ナイロン10〜90重量%、ポリプロピレン10〜90重量%及び請求の範囲第1 項に記載の組成物0.1〜10重量%のブレンドからなる組成物。 5.(a)ポリプロピレンの無水マレイン酸に対する重量比が10〜200である 溶融ポリプロピレンと溶融無水マレイン酸との均質混合物を反応器の一端部で連 続的に形成すること、 (b)ポリプロピレンの遊離基開始剤に対するモル比が200〜4,000であり、そ して無水マレイン酸の遊離基開始剤に対するモル比が1〜70となる量のこの溶融 ポリプロピレンと溶融無水マレイン酸との均質混合物中に、遊離基開始剤を連続 的に導入して、マレイン化ポリプロピレンを製造すること、及び (c)反応器の反対側端部からマレイン化ポリプロピレン生成物を連続的に取 り出すこと を含んでなる低着色の高酸価高分子量マレイン化ポリプロピレンの製造方法。 6.ポリプロピレンの無水マレイン酸に対する重量比が25〜60であり、ポリプ ロピレンの遊離基開始剤に対するモル比が270〜2,10 0であり、そして無水マレイン酸の遊離基開始剤に対するモル比が3.5〜15である 請求の範囲第5項に記載の方法。 7.(a)におけるポリプロピレンのメルトフローレートが230℃で0.1〜50で ある請求の範囲第5項に記載の方法。 8.反応器がスクリュー押出機であり、反応が、ポリプロピレン中への無水マ レイン酸の組み入れ効率が35%より大きい割合で進行する請求の範囲第5項に記 載の方法。 9.遊離基開始剤が、180℃での半減期が3秒より大きい過酸化物であり、ジ −tert−ブチルペルオキシド、tert−ブチルヒドロペルオキシド、クメンヒドロ ペルオキシド、p−メンタンペルオキシド、p−メンタンヒドロペルオキシド及 び2,5−ジメチル−2,5−ビス(t−ブチルペルオキシ)ヘキサンからなる 群から選ばれる請求の範囲第5項に記載の方法。 10.工程(b)を190〜205℃の温度で行う請求の範囲第5項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US29620894A | 1994-08-25 | 1994-08-25 | |
US08/296,208 | 1994-08-25 | ||
PCT/US1995/010528 WO1996006120A1 (en) | 1994-08-25 | 1995-08-18 | Maleated high acid number high molecular weight polypropylene of low color |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006285356A Division JP2007046061A (ja) | 1994-08-25 | 2006-10-19 | 低着色のマレイン化高酸価高分子量ポリプロピレン |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH10505371A true JPH10505371A (ja) | 1998-05-26 |
JP4382158B2 JP4382158B2 (ja) | 2009-12-09 |
Family
ID=23141056
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP50821496A Expired - Lifetime JP4382158B2 (ja) | 1994-08-25 | 1995-08-18 | 低着色のマレイン化高酸価高分子量ポリプロピレンの製造方法 |
JP2006285356A Pending JP2007046061A (ja) | 1994-08-25 | 2006-10-19 | 低着色のマレイン化高酸価高分子量ポリプロピレン |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006285356A Pending JP2007046061A (ja) | 1994-08-25 | 2006-10-19 | 低着色のマレイン化高酸価高分子量ポリプロピレン |
Country Status (12)
Country | Link |
---|---|
US (3) | US5955547A (ja) |
EP (1) | EP0777693B1 (ja) |
JP (2) | JP4382158B2 (ja) |
KR (1) | KR970705587A (ja) |
CN (2) | CN1054864C (ja) |
AT (1) | ATE203250T1 (ja) |
AU (1) | AU3408395A (ja) |
CA (1) | CA2197791C (ja) |
DE (1) | DE69521808T2 (ja) |
MX (1) | MX9701375A (ja) |
WO (1) | WO1996006120A1 (ja) |
ZA (1) | ZA957165B (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002538238A (ja) * | 1999-03-03 | 2002-11-12 | イーストマン ケミカル カンパニー | 機能化ポリプロピレン及びその製造方法 |
JP2009280821A (ja) * | 2001-05-06 | 2009-12-03 | Honeywell Internatl Inc | マレエート化ポリプロピレンおよびその調製方法 |
JP2015108128A (ja) * | 2013-10-25 | 2015-06-11 | 三洋化成工業株式会社 | 変性ポリオレフィンの製造法 |
Families Citing this family (58)
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US7408007B2 (en) * | 1994-08-25 | 2008-08-05 | Eastman Chemical Company | Maleated high acid number high molecular weight polypropylene of low color |
DE19648895A1 (de) * | 1996-11-26 | 1998-05-28 | Clariant Gmbh | Polar modifizierte Polypropylen-Wachse |
DE19653042A1 (de) * | 1996-12-19 | 1998-06-25 | Basf Ag | Flammgeschützte Formmassen |
GB2326164B (en) * | 1997-06-13 | 2001-02-21 | Eastman Chem Co | Emulsification process for functionalized polyolefins and emulsions made therefrom |
US6228948B1 (en) * | 1998-01-16 | 2001-05-08 | E. I. Du Pont De Nemours And Company | High melt flow, highly-grafted polypropylene |
US6362280B1 (en) * | 1998-04-27 | 2002-03-26 | Honeywell International Inc. | Emulsible polyolefin wax |
WO2002018463A1 (en) * | 2000-08-29 | 2002-03-07 | Dupont Canada Inc. | High melt flow, highly-grafted polypropylene |
US7282541B2 (en) | 2000-10-30 | 2007-10-16 | Exxonmobil Chemical Patents Inc. | Functionalized polypropylene-based polymers |
AU2002215367A1 (en) | 2000-10-30 | 2002-05-15 | Exxonmobil Chemical Patents Inc. | Graft-modified polymers based on novel propylene ethylene copolymers |
US6312783B1 (en) | 2000-11-13 | 2001-11-06 | Oriental Weavers Of America | Polypropylene-based carpet yarn |
US8058354B2 (en) * | 2001-02-09 | 2011-11-15 | Eastman Chemical Company | Modified carboxylated polyolefins and their use as adhesion promoters |
US6774185B2 (en) | 2001-04-04 | 2004-08-10 | Bridgestone Corporation | Metal hydroxide filled rubber compositions and tire components |
US7585563B2 (en) * | 2001-05-01 | 2009-09-08 | Ocv Intellectual Capital, Llc | Fiber size, sized reinforcements, and articles reinforced with such reinforcements |
US7732047B2 (en) * | 2001-05-01 | 2010-06-08 | Ocv Intellectual Capital, Llc | Fiber size, sized reinforcements, and articles reinforced with sized reinforcements |
US7256236B1 (en) * | 2001-05-06 | 2007-08-14 | Honeywell International Inc. | Maleated polypropylenes and processes for the preparation thereof |
US6845797B2 (en) * | 2001-10-12 | 2005-01-25 | Bridgestone Corporation | Tire compositions comprising epoxidized natural rubber and a functionalized polyolefin |
JP4010141B2 (ja) * | 2001-12-06 | 2007-11-21 | 住友化学株式会社 | 改質ポリプロピレン樹脂とその製造方法 |
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US6818698B1 (en) | 2002-10-07 | 2004-11-16 | Owens Corning Composites Sprl | Aqueous emulsification of high molecular weight functionlized polyolefins |
AU2003275601A1 (en) * | 2002-10-25 | 2004-05-13 | Nof Corporation | Graft copolymer, composition containing the same and molded object thereof, and process for producing the same |
US6855771B2 (en) * | 2002-10-31 | 2005-02-15 | Grant Doney | Process for making block polymers or copolymers from isotactic polypropylene |
US20050218551A1 (en) * | 2004-04-01 | 2005-10-06 | Izhar Halahmi | Process for producing polar polyolefines and modified polyolefines thereof |
IL161473A0 (en) * | 2004-04-18 | 2004-09-27 | Polyram Ram On Ind Lp | Star-like polyolefin having high propylene content and polar derivatives thereof and method for its production |
WO2005113667A1 (ja) * | 2004-05-24 | 2005-12-01 | Prime Polymer Co., Ltd. | 繊維強化樹脂組成物及びその成形品 |
US20060069187A1 (en) * | 2004-09-29 | 2006-03-30 | Klosiewicz Daniel W | Functionalized polyolefin emulsions |
US20060069209A1 (en) * | 2004-09-29 | 2006-03-30 | Klosiewicz Daniel W | Heat stable functionalized polyolefin emulsions |
US8058355B2 (en) * | 2004-10-06 | 2011-11-15 | Eastman Chemical Company | Modified chlorinated carboxylated polyolefins and their use as adhesion promoters |
CN100584870C (zh) * | 2005-06-03 | 2010-01-27 | 中国科学院长春应用化学研究所 | 稀土化合物参与的功能化聚烯烃树脂的制备方法 |
US20070082209A1 (en) * | 2005-10-11 | 2007-04-12 | Williams Kevin A | Adhesion-promoting primer composition for non-olefin substrates |
US7750078B2 (en) | 2005-12-07 | 2010-07-06 | Exxonmobil Chemical Patents Inc. | Systems and methods used for functionalization of polymeric material and polymeric materials prepared therefrom |
US20070166490A1 (en) * | 2006-01-13 | 2007-07-19 | Sonoco Development, Inc. | Transparent and colored container |
US20070208110A1 (en) * | 2006-03-03 | 2007-09-06 | Sigworth William D | Coupling agents for natural fiber-filled polyolefins |
US8071220B2 (en) * | 2006-07-21 | 2011-12-06 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates having improved adhesion to polar substrates |
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- 1995-08-18 DE DE69521808T patent/DE69521808T2/de not_active Expired - Lifetime
- 1995-08-18 KR KR1019970701173A patent/KR970705587A/ko not_active Application Discontinuation
- 1995-08-18 WO PCT/US1995/010528 patent/WO1996006120A1/en active IP Right Grant
- 1995-08-18 JP JP50821496A patent/JP4382158B2/ja not_active Expired - Lifetime
- 1995-08-18 CA CA002197791A patent/CA2197791C/en not_active Expired - Lifetime
- 1995-08-18 EP EP95930856A patent/EP0777693B1/en not_active Expired - Lifetime
- 1995-08-18 AT AT95930856T patent/ATE203250T1/de not_active IP Right Cessation
- 1995-08-18 CN CN95195808A patent/CN1054864C/zh not_active Expired - Fee Related
- 1995-08-18 AU AU34083/95A patent/AU3408395A/en not_active Abandoned
- 1995-08-18 MX MX9701375A patent/MX9701375A/es unknown
- 1995-08-25 ZA ZA957165A patent/ZA957165B/xx unknown
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1997
- 1997-05-20 US US08/859,628 patent/US5955547A/en not_active Expired - Lifetime
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1999
- 1999-02-24 US US09/256,830 patent/US6046279A/en not_active Expired - Lifetime
- 1999-11-08 CN CN99123575A patent/CN1262287A/zh active Pending
-
2001
- 2001-09-11 US US09/951,985 patent/US20020026010A1/en not_active Abandoned
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2002538238A (ja) * | 1999-03-03 | 2002-11-12 | イーストマン ケミカル カンパニー | 機能化ポリプロピレン及びその製造方法 |
JP2009280821A (ja) * | 2001-05-06 | 2009-12-03 | Honeywell Internatl Inc | マレエート化ポリプロピレンおよびその調製方法 |
JP2015028180A (ja) * | 2001-05-06 | 2015-02-12 | ハネウェル・インターナショナル・インコーポレーテッド | マレエート化ポリプロピレンおよびその調製方法 |
JP2015108128A (ja) * | 2013-10-25 | 2015-06-11 | 三洋化成工業株式会社 | 変性ポリオレフィンの製造法 |
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CN1054864C (zh) | 2000-07-26 |
AU3408395A (en) | 1996-03-14 |
US20020026010A1 (en) | 2002-02-28 |
EP0777693B1 (en) | 2001-07-18 |
MX9701375A (es) | 1997-05-31 |
JP4382158B2 (ja) | 2009-12-09 |
DE69521808D1 (de) | 2001-08-23 |
ZA957165B (en) | 1996-04-17 |
KR970705587A (ko) | 1997-10-09 |
US5955547A (en) | 1999-09-21 |
CN1161702A (zh) | 1997-10-08 |
CA2197791A1 (en) | 1996-02-29 |
JP2007046061A (ja) | 2007-02-22 |
CA2197791C (en) | 2001-06-19 |
CN1262287A (zh) | 2000-08-09 |
DE69521808T2 (de) | 2001-11-08 |
ATE203250T1 (de) | 2001-08-15 |
US6046279A (en) | 2000-04-04 |
WO1996006120A1 (en) | 1996-02-29 |
EP0777693A1 (en) | 1997-06-11 |
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