JPH09103632A - 極低温分離装置を含む一酸化炭素生産設備 - Google Patents

極低温分離装置を含む一酸化炭素生産設備

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Publication number
JPH09103632A
JPH09103632A JP8154165A JP15416596A JPH09103632A JP H09103632 A JPH09103632 A JP H09103632A JP 8154165 A JP8154165 A JP 8154165A JP 15416596 A JP15416596 A JP 15416596A JP H09103632 A JPH09103632 A JP H09103632A
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JP
Japan
Prior art keywords
carbon monoxide
adsorbent
tank
saturated
adsorbing devices
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP8154165A
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English (en)
Other versions
JP3844540B2 (ja
Inventor
Jean Billy
ジャン・ビリー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
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Filing date
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Publication of JPH09103632A publication Critical patent/JPH09103632A/ja
Application granted granted Critical
Publication of JP3844540B2 publication Critical patent/JP3844540B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0261Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/40Carbon monoxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0223H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0252Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/60Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2280/00Control of the process or apparatus
    • F25J2280/02Control in general, load changes, different modes ("runs"), measurements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S62/00Refrigeration
    • Y10S62/902Apparatus
    • Y10S62/908Filter or absorber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S62/00Refrigeration
    • Y10S62/92Carbon monoxide

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

(57)【要約】 【課題】本発明は、生産損失を大幅に制限することな
く、容易に、能率的に、かつ安価に一酸化炭素の生産を
調整する設備を提供する。 【解決手段】一酸化炭素に対する親和性を有する吸着剤
を含むタンク(9)を精製装置(3)と極低温分離装置
(1)との間の供給ライン(2)内に備える。

Description

【発明の詳細な説明】
【0001】
【発明の属する技術分野】本発明は、一酸化炭素を含む
混合ガスが、少なくとも二つの吸着装置を備え不純物を
吸着する精製装置を含む供給ラインを介し供給される極
低温(cryogenic)分離装置を備えた一酸化炭素生産設備
に関する。
【0002】
【従来の技術】純粋な一酸化炭素は、化学工業において
数多くの方法に使用されており、たいていの場合はスチ
ームリフォームまたは部分酸化によって炭化水素から作
り出されるので水素およびメタンとの混合物の形態にあ
り、この混合物から極低温分離装置において一酸化炭素
が分離される。極低温分離プロセスではアルミナやシリ
カゲル、もしくはモレキュラーシーブのような一種以上
の固体吸着剤を含む複数の吸着装置を有する吸着精製装
置で精製されるので、分離されるべき混合ガスは、本質
的に水および二酸化炭素である凝固性成分をごくわずか
でも含まないことが要求される。上述の吸着剤は一酸化
炭素を保持する親和性をもいくらか有し、その程度はさ
まざまである。このため、吸着精製装置のサイクル操作
は、極低温分離装置の出口における一酸化炭素の生産送
出率(delivery rate)にサイクル的な変動をもたら
す。下流のユーザーステーション、典型的には化学反応
装置は、一般に、この変動に対する許容性がないので、
生産送出率を均するために、一般的には、生産された一
酸化炭素の一部を分流ないし燃焼することによって一酸
化炭素の回流を調整しており、生産損失および廃棄物の
再処理という欠点を伴う。
【0003】
【発明が解決しようとする課題】本発明の課題は、生産
損失を大幅に制限する一方で、簡単に、効率的に、かつ
安価に一酸化炭素の生産を調整する設備を提供すること
である。
【0004】
【課題を解決するための手段】上記課題を解決するため
に、本発明の特徴によれば、本設備は、一酸化炭素に対
する親和性を有する吸着剤を有するタンクを精製装置と
極低温分離装置の間の供給ライン内に永続的に備える。
【0005】本発明の他の特徴および利点は、以下の実
施の形態の説明から明らかになろう。
【0006】
【発明の実施の形態】図1は、一酸化炭素を含む入力混
合ガスを凝固性不純物の除去により精製するために交互
に操作される少なくとも2つの吸着装置(4A,4B)
を有する精製装置(3)の生産放出口に連結する供給ラ
イン(2)を介して分離されるべき混合ガスが供給され
る極低温分離装置(1)を概略的に示している。極低温
分離装置(1)は、純粋一酸化炭素送出ライン(6)お
よび、典型的には水素および残存混合物の放出ライン
(7)および(8)を備える。
【0007】本発明によれば、タンク(9)は、ライン
(2)内に永続的に設置され、このタンクは吸着装置
(4A,4B)と同様の寸法を有し、吸着剤で、有利に
は、吸着装置(4A,4B)中の主たる吸着剤、典型的
にはモレキュラーシーブで満たされている。
【0008】本発明における上記の設備の操作方法は以
下のように説明することができる。
【0009】連続的操作相において、使用されている吸
着装置(4A,4B)中の吸着剤およびタンク( 9) 中
の吸着剤は一酸化炭素で飽和され、したがって後者に対
して「透明」である。吸着装置(4A,4B)が切り替
えられ、新たに再生された吸着剤の使用が開始される
と、吸着装置は一酸化炭素で飽和され、一方タンク
(9)中の吸着剤は保持していた一酸化炭素のいくぶん
かを放出する。逆に、新たに使用が開始された吸着装置
が一酸化炭素の飽和状態に達すると、タンク(9)中の
吸着剤は一酸化炭素で再飽和され、その結果、先に述べ
たように、一酸化炭素生産送出率のサイクル的変動は実
質的に均される。
【図面の簡単な説明】
【図1】本発明の設備を示す概略図。
【符号の説明】
1…極低温分離装置 2…生産ライン 3…精製装置 4A,4B…吸着装置 5…混合ガス取り込み口 6…純粋一酸化炭素送出ライン 7,8…放出ライン 9…タンク

Claims (3)

    【特許請求の範囲】
  1. 【請求項1】 一酸化炭素を含む混合ガスが、少なくと
    も2つの吸着装置(4A,4B) を有し不純物を吸着す
    る精製装置(3)を含む供給ライン(5,2)を介して
    供給される極低温分離装置(1)を含む一酸化炭素生産
    設備において、精製装置(3)と分離装置(1)との間
    の供給ライン(2)内に一酸化炭素に対する親和性を有
    する吸着剤を含むタンク(9)を永続的に備えることを
    特徴とする一酸化炭素生産設備。
  2. 【請求項2】 タンク(9)中の吸着剤が吸着装置(4
    A,4B)中の吸着剤と同種であることを特徴とする請
    求項1記載の設備。
  3. 【請求項3】 吸着剤がモレキュラーシーブであること
    を特徴とする請求項2記載の設備。
JP15416596A 1995-06-15 1996-06-14 極低温分離装置を含む一酸化炭素生産設備 Expired - Fee Related JP3844540B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9507160 1995-06-15
FR9507160A FR2735382B1 (fr) 1995-06-15 1995-06-15 Installation de production de monoxyde de carbone incorporant une unite de separation cryogenique

Publications (2)

Publication Number Publication Date
JPH09103632A true JPH09103632A (ja) 1997-04-22
JP3844540B2 JP3844540B2 (ja) 2006-11-15

Family

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Application Number Title Priority Date Filing Date
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Country Status (8)

Country Link
US (1) US5632162A (ja)
EP (1) EP0748765B1 (ja)
JP (1) JP3844540B2 (ja)
KR (1) KR100440665B1 (ja)
CN (1) CN1089158C (ja)
CA (1) CA2179118C (ja)
DE (1) DE69603674T2 (ja)
FR (1) FR2735382B1 (ja)

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Also Published As

Publication number Publication date
CA2179118A1 (en) 1996-12-16
KR970000307A (ko) 1997-01-21
CA2179118C (en) 2006-04-18
US5632162A (en) 1997-05-27
DE69603674D1 (de) 1999-09-16
FR2735382B1 (fr) 1997-07-25
DE69603674T2 (de) 2000-04-06
CN1146545A (zh) 1997-04-02
CN1089158C (zh) 2002-08-14
FR2735382A1 (fr) 1996-12-20
EP0748765A1 (fr) 1996-12-18
KR100440665B1 (ko) 2004-09-24
JP3844540B2 (ja) 2006-11-15
EP0748765B1 (fr) 1999-08-11

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