JPH0785860A - リチウム電池 - Google Patents
リチウム電池Info
- Publication number
- JPH0785860A JPH0785860A JP5226040A JP22604093A JPH0785860A JP H0785860 A JPH0785860 A JP H0785860A JP 5226040 A JP5226040 A JP 5226040A JP 22604093 A JP22604093 A JP 22604093A JP H0785860 A JPH0785860 A JP H0785860A
- Authority
- JP
- Japan
- Prior art keywords
- negative electrode
- carbon
- diameter
- lithium
- particle size
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 18
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 27
- 239000002245 particle Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 5
- 229920000049 Carbon (fiber) Polymers 0.000 abstract description 4
- 239000004917 carbon fiber Substances 0.000 abstract description 4
- 210000001787 dendrite Anatomy 0.000 abstract description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 4
- 239000011230 binding agent Substances 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 230000006866 deterioration Effects 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000008151 electrolyte solution Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000006230 acetylene black Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000006713 insertion reaction Methods 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- 229910007857 Li-Al Inorganic materials 0.000 description 1
- 229910008447 Li—Al Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- ZJZXSOKJEJFHCP-UHFFFAOYSA-M lithium;thiocyanate Chemical compound [Li+].[S-]C#N ZJZXSOKJEJFHCP-UHFFFAOYSA-M 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000003115 supporting electrolyte Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Carbon And Carbon Compounds (AREA)
- Inert Electrodes (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5226040A JPH0785860A (ja) | 1993-09-10 | 1993-09-10 | リチウム電池 |
| CA002171478A CA2171478C (en) | 1993-09-10 | 1994-09-09 | Lithium battery with electrodes containing carbon fibrils |
| AU77246/94A AU684310B2 (en) | 1993-09-10 | 1994-09-09 | Lithium battery with electrodes containing carbon fibrils |
| US08/612,930 US5879836A (en) | 1993-09-10 | 1994-09-09 | Lithium battery with electrodes containing carbon fibrils |
| EP94928065A EP0786154B1 (en) | 1993-09-10 | 1994-09-09 | Lithium battery with electrodes containing carbon fibrils |
| DE69432906T DE69432906T2 (de) | 1993-09-10 | 1994-09-09 | Lithiumbatterie mit kohlenstoff-fibrillen enthaltenen elektroden |
| AT94928065T ATE244457T1 (de) | 1993-09-10 | 1994-09-09 | Lithiumbatterie mit kohlenstoff-fibrillen enthaltenen elektroden |
| JP50880795A JP3967373B2 (ja) | 1993-09-10 | 1994-09-09 | 炭素フィブリル含有電極を有するリチウム電池 |
| PCT/US1994/010181 WO1995007551A1 (en) | 1993-09-10 | 1994-09-09 | Lithium battery with electrodes containing carbon fibrils |
| KR1019960701214A KR100353351B1 (ko) | 1993-09-10 | 1994-09-09 | 카본피브릴을함유하는전극을갖는리튬전지 |
| JP2004204723A JP2005038851A (ja) | 1993-09-10 | 2004-07-12 | 炭素フィブリル含有電極を有するリチウム電池 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5226040A JPH0785860A (ja) | 1993-09-10 | 1993-09-10 | リチウム電池 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0785860A true JPH0785860A (ja) | 1995-03-31 |
| JPH0785860A6 JPH0785860A6 (enExample) | 2005-02-17 |
Family
ID=16838841
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5226040A Pending JPH0785860A (ja) | 1993-09-10 | 1993-09-10 | リチウム電池 |
| JP50880795A Expired - Fee Related JP3967373B2 (ja) | 1993-09-10 | 1994-09-09 | 炭素フィブリル含有電極を有するリチウム電池 |
| JP2004204723A Withdrawn JP2005038851A (ja) | 1993-09-10 | 2004-07-12 | 炭素フィブリル含有電極を有するリチウム電池 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50880795A Expired - Fee Related JP3967373B2 (ja) | 1993-09-10 | 1994-09-09 | 炭素フィブリル含有電極を有するリチウム電池 |
| JP2004204723A Withdrawn JP2005038851A (ja) | 1993-09-10 | 2004-07-12 | 炭素フィブリル含有電極を有するリチウム電池 |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0786154B1 (enExample) |
| JP (3) | JPH0785860A (enExample) |
| KR (1) | KR100353351B1 (enExample) |
| AT (1) | ATE244457T1 (enExample) |
| AU (1) | AU684310B2 (enExample) |
| CA (1) | CA2171478C (enExample) |
| DE (1) | DE69432906T2 (enExample) |
| WO (1) | WO1995007551A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004508686A (ja) * | 2000-09-07 | 2004-03-18 | ザ ジレット カンパニー | 電池のカソード |
| KR100444140B1 (ko) * | 2000-11-24 | 2004-08-09 | 주식회사 동운인터내셔널 | 고성능 이차전지용 도전재 및 이를 이용한 이차전지 |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1042875C (zh) * | 1996-01-22 | 1999-04-07 | 中国科学院物理研究所 | 一种用于锂电池的弥散阳极及其制备方法 |
| IL126976A (en) | 1996-05-15 | 2001-11-25 | Hyperion Catalysis Internat | Nano-fibers are made of graphite in electrochemical capacitors |
| US6194099B1 (en) | 1997-12-19 | 2001-02-27 | Moltech Corporation | Electrochemical cells with carbon nanofibers and electroactive sulfur compounds |
| EP1074056A1 (en) * | 1998-03-31 | 2001-02-07 | Axiva GmbH | Lithium battery and electrode |
| JP2002519826A (ja) * | 1998-03-31 | 2002-07-02 | セラニーズ・ヴェンチャーズ・ゲーエムベーハー | リチウム電池および電極 |
| US7029794B2 (en) | 1998-03-31 | 2006-04-18 | Celanese Ventures Gmbh | Lithium battery and electrode |
| US6703163B2 (en) | 1998-03-31 | 2004-03-09 | Celanese Ventures Gmbh | Lithium battery and electrode |
| US6280697B1 (en) * | 1999-03-01 | 2001-08-28 | The University Of North Carolina-Chapel Hill | Nanotube-based high energy material and method |
| US6815121B2 (en) | 2000-07-31 | 2004-11-09 | Electrovaya Inc. | Particulate electrode including electrolyte for a rechargeable lithium battery |
| JP4197859B2 (ja) * | 2001-05-30 | 2008-12-17 | 株式会社Gsiクレオス | リチウム二次電池の電極材およびこれを用いたリチウム二次電池 |
| JP3930335B2 (ja) * | 2001-08-29 | 2007-06-13 | 株式会社Gsiクレオス | 気相成長法による炭素繊維、電池用電極材および炭素繊維の製造方法 |
| JP3930276B2 (ja) * | 2001-08-29 | 2007-06-13 | 株式会社Gsiクレオス | 気相成長法による炭素繊維、リチウム二次電池用電極材およびリチウム二次電池 |
| JP2004220910A (ja) * | 2003-01-15 | 2004-08-05 | Mitsubishi Materials Corp | 負極材料及びこれを用いた負極、並びにこの負極を用いたリチウムイオン電池及びリチウムポリマー電池 |
| JP2004220911A (ja) * | 2003-01-15 | 2004-08-05 | Mitsubishi Materials Corp | リチウムポリマー電池用負極材料及びこれを用いた負極、並びにこの負極を用いたリチウムイオン電池及びリチウムポリマー電池 |
| JP5162817B2 (ja) * | 2005-08-26 | 2013-03-13 | 宇部興産株式会社 | ネットワーク状炭素材料 |
| JP5036564B2 (ja) * | 2006-01-20 | 2012-09-26 | 昭和電工株式会社 | プレートレット型スリット気相法炭素繊維の製造方法 |
| WO2012084764A1 (de) | 2010-12-21 | 2012-06-28 | Bayer Materialscience Ag | Verfahren zur herstellung von pulverförmigen polymer-kohlenstoffnanoröhren-gemischen |
| CA2839614A1 (en) | 2011-06-23 | 2012-12-27 | Molecular Rebar Design, Llc | Lithium ion batteries using discrete carbon nanotubes, methods for production thereof and products obtained therefrom |
| JP6408912B2 (ja) | 2011-12-15 | 2018-10-17 | エイ123・システムズ・リミテッド・ライアビリティ・カンパニーA123 Systems, Llc | ハイブリッドバッテリーシステム |
| JP7096184B2 (ja) * | 2019-03-12 | 2022-07-05 | トヨタ自動車株式会社 | リチウムイオン二次電池及びその製造方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4663230A (en) * | 1984-12-06 | 1987-05-05 | Hyperion Catalysis International, Inc. | Carbon fibrils, method for producing same and compositions containing same |
| CA1296766C (en) * | 1986-05-13 | 1992-03-03 | Yuzuru Takahashi | Secondary battery |
| JPH0817092B2 (ja) * | 1989-11-21 | 1996-02-21 | 株式会社リコー | 電極用基材及びその製造方法 |
| US5246794A (en) * | 1991-03-19 | 1993-09-21 | Eveready Battery Company, Inc. | Cathode collector made from carbon fibrils |
| US5302474A (en) * | 1993-04-02 | 1994-04-12 | Valence Technology, Inc. | Fullerene-containing cathodes for solid electrochemical cells |
-
1993
- 1993-09-10 JP JP5226040A patent/JPH0785860A/ja active Pending
-
1994
- 1994-09-09 WO PCT/US1994/010181 patent/WO1995007551A1/en not_active Ceased
- 1994-09-09 AU AU77246/94A patent/AU684310B2/en not_active Ceased
- 1994-09-09 JP JP50880795A patent/JP3967373B2/ja not_active Expired - Fee Related
- 1994-09-09 DE DE69432906T patent/DE69432906T2/de not_active Expired - Lifetime
- 1994-09-09 AT AT94928065T patent/ATE244457T1/de not_active IP Right Cessation
- 1994-09-09 KR KR1019960701214A patent/KR100353351B1/ko not_active Expired - Fee Related
- 1994-09-09 CA CA002171478A patent/CA2171478C/en not_active Expired - Fee Related
- 1994-09-09 EP EP94928065A patent/EP0786154B1/en not_active Expired - Lifetime
-
2004
- 2004-07-12 JP JP2004204723A patent/JP2005038851A/ja not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004508686A (ja) * | 2000-09-07 | 2004-03-18 | ザ ジレット カンパニー | 電池のカソード |
| KR100444140B1 (ko) * | 2000-11-24 | 2004-08-09 | 주식회사 동운인터내셔널 | 고성능 이차전지용 도전재 및 이를 이용한 이차전지 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0786154B1 (en) | 2003-07-02 |
| DE69432906T2 (de) | 2004-05-27 |
| EP0786154A4 (enExample) | 1997-07-30 |
| DE69432906D1 (de) | 2003-08-07 |
| ATE244457T1 (de) | 2003-07-15 |
| JPH09502566A (ja) | 1997-03-11 |
| WO1995007551A1 (en) | 1995-03-16 |
| EP0786154A1 (en) | 1997-07-30 |
| JP3967373B2 (ja) | 2007-08-29 |
| KR960705375A (ko) | 1996-10-09 |
| JP2005038851A (ja) | 2005-02-10 |
| CA2171478A1 (en) | 1995-03-16 |
| KR100353351B1 (ko) | 2002-12-28 |
| CA2171478C (en) | 2007-06-19 |
| AU684310B2 (en) | 1997-12-11 |
| AU7724694A (en) | 1995-03-27 |
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