JPH07258460A - Resin composition - Google Patents
Resin compositionInfo
- Publication number
- JPH07258460A JPH07258460A JP5025194A JP5025194A JPH07258460A JP H07258460 A JPH07258460 A JP H07258460A JP 5025194 A JP5025194 A JP 5025194A JP 5025194 A JP5025194 A JP 5025194A JP H07258460 A JPH07258460 A JP H07258460A
- Authority
- JP
- Japan
- Prior art keywords
- metal
- fluorescent
- parts
- pts
- glass flakes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 7
- 239000011521 glass Substances 0.000 claims abstract description 22
- 229910052751 metal Inorganic materials 0.000 claims abstract description 13
- 239000002184 metal Substances 0.000 claims abstract description 13
- 239000007850 fluorescent dye Substances 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 12
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052759 nickel Inorganic materials 0.000 abstract description 6
- 229910052709 silver Inorganic materials 0.000 abstract description 6
- 239000004332 silver Substances 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 5
- 239000004793 Polystyrene Substances 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000004417 polycarbonate Substances 0.000 abstract description 4
- 229920000515 polycarbonate Polymers 0.000 abstract description 4
- 229920002223 polystyrene Polymers 0.000 abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 abstract description 3
- 239000004925 Acrylic resin Substances 0.000 abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 abstract description 3
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052737 gold Inorganic materials 0.000 abstract description 2
- 239000010931 gold Substances 0.000 abstract description 2
- 239000000975 dye Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000002932 luster Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000007772 electroless plating Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 101100288971 Mus musculus Lgals3bp gene Proteins 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- TXVWTOBHDDIASC-UHFFFAOYSA-N 1,2-diphenylethene-1,2-diamine Chemical compound C=1C=CC=CC=1C(N)=C(N)C1=CC=CC=C1 TXVWTOBHDDIASC-UHFFFAOYSA-N 0.000 description 1
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- 239000004419 Panlite Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
PURPOSE:To obtain a resin composition useful for key holders, buttons, pachinko machine outer shells, camera parts, etc., by blending light-transmitting thermoplastic resin containing a fluorescent dye, etc., with a specific amount of glass flakes coated with a metal and having a specific form. CONSTITUTION:This composition is obtained by blending 100 pts.wt. of a light- transmitting thermoplastic resin (preferably polycarbonate, acrylic resin, polystyrene, AS, etc.) blending preferably 0.001-5.0wt.% of a fluorescent dye and/or a fluorescent pigment (preferably perylene-based dye or pigment) therein with 0.01-10 pts.wt., preferably 0.05-5.0 pts.wt. of glass flakes coated with a metal (e.g. gold, silver, nickel, aluminum, etc.) and having 0.01-3mm average particle diameter and 1-30mum average thickness.
Description
【０００１】[0001]
【産業上の利用分野】本発明は装飾部品、例えばキ−ホ
ルダ−、ボタン、ケース類、柄等に使用されるか、また
は外観を重要視する部品、例えばパチンコ外殻、カメラ
部品、ＯＡ機器ハウジング、パイプ類、自動車外装品等
に使用される樹脂組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used for decorative parts such as key holders, buttons, cases, handles, etc., or parts for which appearance is important, such as pachinko shells, camera parts, OA equipment. The present invention relates to a resin composition used for housings, pipes, automobile exterior parts and the like.
【０００２】[0002]
【従来の技術】従来からメタリック調の外観を有する樹
脂成形品が知られている。しかしながら、従来の技術は
樹脂成形品にメタリック調を付与する各種メタリック剤
を添加するだけのものである。メタリック剤としては金
属箔、各種金属蒸着フィルム、各種金属コートガラスフ
レーク、各種金属コート雲母等が知られている。しかし
ながらこのようにして得られる成形品は濁りを生じやす
くメタリック調は充分なものでは無かった。より金属光
沢に近い輝きと奥行きのあるメタリック調が求められて
いる。2. Description of the Related Art Conventionally, resin molded products having a metallic appearance have been known. However, the conventional technique merely adds various metallic agents that give a metallic tone to the resin molded product. As metallic agents, metal foils, various metal vapor deposition films, various metal-coated glass flakes, various metal-coated mica, etc. are known. However, the molded product thus obtained was liable to be turbid, and the metallic tone was not sufficient. There is a demand for a metallic tone with a radiance closer to metallic luster and a depth.
【０００３】[0003]
【発明が解決しようとする課題】本発明は、このような
成形品の濁りを解消し、より金属光沢に近い輝きと奥行
きのあるメタリック調の樹脂成形品を容易に提供するこ
とを目的とする。SUMMARY OF THE INVENTION It is an object of the present invention to eliminate such turbidity of a molded product and easily provide a metallic resin molded product having a shine and depth closer to metallic luster and depth. .
【０００４】本発明者は前記目的を達成すべく鋭意検討
した結果、メタリック剤として金属をコ−ティングした
ガラスフレ−クを使用し、さらに蛍光染料および／また
は蛍光顔料が配合された透光性熱可塑性樹脂を使用する
事により金属光沢に近い輝きと奥行きのあるメタリック
調成形品を得ることができる樹脂組成物を完成した。As a result of earnest studies to achieve the above-mentioned object, the present inventor has used a glass flake coated with a metal as a metallic agent and further has a translucent heat containing a fluorescent dye and / or a fluorescent pigment. By using a plastic resin, we have completed a resin composition that can give a metallic-like molded product with a shine close to metallic luster and depth.
【０００５】[0005]
【課題を解決するための手段】本発明は蛍光染料および
／または蛍光顔料が混合された透光性熱可塑性樹脂１０
０重量部に、金属をコーテイングした、平均粒径が０．
０１〜３mmで平均厚さが１〜３０μm のガラスフレーク
を０．０１重量部〜１０重量部配合してなる樹脂組成物
に係るものである。SUMMARY OF THE INVENTION The present invention is a translucent thermoplastic resin 10 containing a fluorescent dye and / or a fluorescent pigment.
0 parts by weight of a metal coated with an average particle size of 0.
The present invention relates to a resin composition containing 0.01 part by weight to 10 parts by weight of glass flakes having an average thickness of 1 to 30 μm and a thickness of 01 to 30 mm.
【０００６】本発明で使用する樹脂は、溶融成形可能な
透光性熱可塑性樹脂であれば特に制限はない。例えばポ
リエチレン、ポリプロピレン、ポリスチレン、ＡＳ、ア
クリル樹脂、ポリカーボネート等、透光性の樹脂があげ
られる。特にポリカーボネート、アクリル樹脂、ポリス
チレン、ＡＳ等透光性の高い樹脂が好ましい。また、少
しでも透光性を保持する限りこれらの樹脂の混合物であ
っても良い。The resin used in the present invention is not particularly limited as long as it is a translucent thermoplastic resin capable of being melt-molded. Examples thereof include translucent resins such as polyethylene, polypropylene, polystyrene, AS, acrylic resin, and polycarbonate. Particularly, a resin having a high light-transmitting property such as polycarbonate, acrylic resin, polystyrene and AS is preferable. Further, a mixture of these resins may be used as long as it retains translucency as much as possible.
【０００７】本発明で使用する蛍光染料および／または
蛍光顔料は、熱可塑性樹脂に使用できるものであれば特
に制限はない。例えば、キサンテン系、チアゾ−ル系、
チアジン系、ペリレン系、ジアミノスチルベン系等があ
げられる。特にペリレン系が好ましく、例えば、ＢＡＳ
Ｆ製のルモゲンカラ−、有本化学工業（株）製のＦｌｕ
ｏｒｅｓｓｅｎｔが好ましい。The fluorescent dye and / or fluorescent pigment used in the present invention is not particularly limited as long as it can be used in a thermoplastic resin. For example, xanthene-based, thiazole-based,
Examples include thiazine-based, perylene-based, diaminostilbene-based and the like. Perylene type is particularly preferable, for example, BAS
Lumogen color manufactured by F, Flu manufactured by Arimoto Chemical Co., Ltd.
preferred is preferred.
【０００８】かかる蛍光染料および／または蛍光顔料の
使用量は特に制限はない。あまりに少ないと蛍光色が得
られ難くなり、又多過ぎると透光性が低下したり、かえ
って変色が激しくなったりするので、熱可塑性樹脂中に
蛍光染料および／または蛍光顔料を０．００１〜５．０
重量％配合するのが好ましい。The amount of such fluorescent dye and / or fluorescent pigment used is not particularly limited. If the amount is too small, it becomes difficult to obtain a fluorescent color, and if the amount is too large, the translucency is lowered or the discoloration becomes severe, so that a fluorescent dye and / or a fluorescent pigment is added to the thermoplastic resin in an amount of 0.001 to 5 .0
It is preferable to add the composition in a weight percentage.
【０００９】本発明で使用するガラスフレークは、平均
粒径が０．０１〜３mmで平均厚さが１〜３０μm であ
る。平均粒径が０．０１mmに達しないものは、平滑面が
不足するためか、輝きと奥行きのある高級なメタリック
調が得られ難くなり、３mmを越えると溶融混合時に破砕
し易くなり、わざわざ大きくする意味がない。また、平
均厚さが１μm に達しないものは、破砕し易くなるので
適当でなく、３０μm を越えると、混合する量に対して
メタリック調付与効果が小さくなる。なお、ここでいう
粒径とはフレークの最も長いところである。ガラスフレ
ークの材質としては通常熱可塑性樹脂に使用されるもの
であれば差支えなく、含アルカリガラス、低アルカリガ
ラス、無アルカリガラスのいずれも用いることができ
る。The glass flakes used in the present invention have an average particle size of 0.01 to 3 mm and an average thickness of 1 to 30 μm. If the average particle size is less than 0.01 mm, it may be difficult to obtain a high-grade metallic tone with brightness and depth due to lack of smooth surface. There is no point in doing it. Further, if the average thickness is less than 1 μm, it is not suitable because it is easily crushed, and if it exceeds 30 μm, the effect of imparting a metallic tone becomes small with respect to the mixing amount. The particle size referred to here is the longest point of flakes. The glass flake may be made of any material commonly used for thermoplastic resins, and any of alkali-containing glass, low-alkali glass and alkali-free glass may be used.
【００１０】上記ガラスフレークにコーティングする金
属は、金属光沢を有しかつガラスにコーティング可能な
金属であればよく、例えば金、銀、ニッケル、アルミニ
ウム等があげられる。また、コーティングする方法に
は、特に制限はなく、任意の方法が採用される。例えば
無電解メッキによる方法が好ましく、コーティングの膜
厚は通常０．００００１〜１０μm であり、ガラスフレ
ークの平滑面、好ましくは更に端面にも均一にコーテイ
ングする。かかる金属をコーティングしたガラスフレー
クは、そのまま使用できるが、更にその表面に、酸化防
止等のために、処理剤をコーテイングしてもよく、こう
することは好ましいことでもある。The metal coated on the glass flakes may be any metal having metallic luster and capable of coating glass, and examples thereof include gold, silver, nickel and aluminum. The coating method is not particularly limited, and any method can be adopted. For example, a method by electroless plating is preferable, the thickness of the coating is usually 0.00001 to 10 μm, and the smooth surface, preferably the end surface of the glass flake is coated uniformly. The glass flakes coated with such a metal can be used as they are, but a treating agent may be further coated on the surface thereof for the purpose of preventing oxidation, which is also preferable.
【００１１】かかる金属をコーティングしたガラスフレ
ークの使用量は、あまりに少ないと輝きと奥行きのある
高級なメタリック調が得られ難くなり、あまりに多いと
物性が低下するので、蛍光染料および／または蛍光顔料
が混合された透光性熱可塑性樹脂１００重量部に０．０
１〜１０重量部使用するのが好ましい。特に好ましいの
は０．０５〜５．０重量部である。If the amount of the glass flake coated with such a metal is too small, it becomes difficult to obtain a high-grade metallic tone with brilliance and depth, and if it is too large, the physical properties are deteriorated. Therefore, a fluorescent dye and / or a fluorescent pigment is used. 0.0 to 100 parts by weight of the mixed translucent thermoplastic resin
It is preferable to use 1 to 10 parts by weight. Particularly preferred is 0.05 to 5.0 parts by weight.
【００１２】更に本発明組成物には、安定剤の添加が好
ましく、更に目的を損わない範囲で有効発現量の離型
剤、帯電防止剤等を添加してもよい。本発明の樹脂組成
物は、構成成分を例えばタンブラー、ブレンダー、ナウ
ターミキサー、バンバリーミキサー、混練ロール、押出
機等により混合して製造することができる。Further, it is preferable to add a stabilizer to the composition of the present invention, and a release agent, an antistatic agent, etc. may be added in an effective amount in a range that does not impair the purpose. The resin composition of the present invention can be produced by mixing the constituents with a tumbler, a blender, a Nauter mixer, a Banbury mixer, a kneading roll, an extruder or the like.
【００１３】[0013]
【実施例】以下に実施例をあげて本発明を更に説明す
る。なお、実施例中の部は重量部である。評価は５０mm
×５０mm×２mmの見本板を目視により蛍光メタリック調
を判定することおよび日本電色工業（株）社製の光沢計
により光沢度を測定することにより行った。EXAMPLES The present invention will be further described with reference to the following examples. The parts in the examples are parts by weight. Evaluation is 50 mm
It was carried out by visually observing the fluorescent metallic tone of a sample plate of × 50 mm × 2 mm and measuring the gloss level with a gloss meter manufactured by Nippon Denshoku Industries Co., Ltd.
【００１４】［実施例１］ポリカーボネート［帝人化成
（株）製パンライトＬ−１２２５ＷＰ］９９．９８部、
蛍光染料［ＢＡＳＦ ＪＡＰＡＮ（株）製 Ｌｕｍｏｇ
ｅｎ Ｆ Ｒｅｄ３００］０．０２部、ニッケルコート
ガラスフレーク［日本板硝子（株）製メタシャインニッ
ケルＲＣＦＳＸ−５２３０ＮＳ（９０４２）平均粒径
０．２３mmで平均厚さ５μm のガラスフレークに膜厚
０．１５μm のニッケルを無電解メッキにてコートした
もの］０．５部によりシリンダー温度２８０℃で押出し
てペレット化した。このペレットを射出成形機［住友重
機械工業（株）製ネスタール・サイキャップ４８０／１
５０］によりシリンダー温度２８０℃、金型温度８０℃
で見本板を作成した。評価結果を表１に示した。Example 1 Polycarbonate [Panlite L-1225WP manufactured by Teijin Chemicals Ltd.] 99.98 parts,
Fluorescent dye [Lumog manufactured by BASF JAPAN Co., Ltd.
en F Red300] 0.02 part, nickel-coated glass flakes [Nippon Sheet Glass Co., Ltd. Metashine Nickel RCFSX-5230NS (9042)] A glass flake having an average particle diameter of 0.23 mm and an average thickness of 5 μm and having a thickness of 0.15 μm. Nickel coated by electroless plating] 0.5 part was extruded at a cylinder temperature of 280 ° C. and pelletized. Injection molding machine [Nestal Cycap 480/1 manufactured by Sumitomo Heavy Industries, Ltd.]
50], cylinder temperature 280 ° C, mold temperature 80 ° C
I made a sample board in. The evaluation results are shown in Table 1.
【００１５】［比較例１］実施例１で使用したニッケル
コートガラスフレークに代えてアルミニウム粉末（平均
粒径５０μm ）１．０部を使用する以外は実施例１と同
様にしてペレットを得た。次いで実施例１と同様にして
見本板を作成した。評価結果を表１に示した。Comparative Example 1 Pellets were obtained in the same manner as in Example 1 except that 1.0 part of aluminum powder (average particle size 50 μm) was used in place of the nickel-coated glass flakes used in Example 1. Then, a sample plate was prepared in the same manner as in Example 1. The evaluation results are shown in Table 1.
【００１６】［比較例２］実施例１で使用した蛍光染料
Ｌｕｍｏｇｅｎ Ｆ Ｒｅｄ３００に代えて蛍光性を有
しない赤色染料［有本化学工業（株）製プラスト・レッ
ド・８３６０］０．１部を使用する以外は実施例１と同
様にしてペレットを得た。次いで実施例１と同様にして
見本板を作成した。[Comparative Example 2] 0.1 part of a red dye having no fluorescence [Plast Red 8360 manufactured by Arimoto Chemical Industry Co., Ltd.] was used in place of the fluorescent dye Lumogen F Red 300 used in Example 1. Pellets were obtained in the same manner as in Example 1 except for the above. Then, a sample plate was prepared in the same manner as in Example 1.
【００１７】［実施例２］ポリスチレン［電気化学工業
（株）製デンカスチロールＧＰ−１］９９．７部、蛍光
顔料［ＤＡＹ−ＧＬＯ ＣＯＬＯＲ ＣＯＲＰ製 ＤＡ
Ｙ−ＧＬＯ Ｓｉｇｎａｌ Ｇｒｅｅｎ１８］０．３
部、銀コートガラスフレーク［日本板硝子（株）製メタ
シャインシルバーＲＣＦＳＸ−５０９０ＰＳ（９０２
６）平均粒径０．０９mmで平均厚さ５μm のガラスフレ
ークに膜厚０．１５μm の銀を無電解メッキにてコート
したもの］５．０部を押出機［ナカタニ（株）製ＶＳＫ
−３０］によりシリンダー温度２００℃で押出してペレ
ット化した。このペレットを射出成形機［住友重機械工
業（株）製ネスタール・サイキャップ４８０／１５０］
によりシリンダー温度２００℃、金型温度５０℃で見本
板を作成した。評価結果を表１に示した。[Example 2] Polystyrene [DENKA STYLOL GP-1 manufactured by Denki Kagaku Kogyo KK] 99.7 parts, fluorescent pigment [DAY-GLO COLOR CORP DA
Y-GLO Signal Green18] 0.3
Part, silver-coated glass flake [Metalshine Silver RCFSX-5090PS (902 manufactured by Nippon Sheet Glass Co., Ltd.)
6) Glass flakes with an average particle diameter of 0.09 mm and an average thickness of 5 μm coated with silver with a thickness of 0.15 μm by electroless plating] 5.0 parts of an extruder [VSK manufactured by Nakatani Co., Ltd.]
-30] was extruded at a cylinder temperature of 200 ° C. to be pelletized. Injection molding machine [Nestal Cycap 480/150 manufactured by Sumitomo Heavy Industries, Ltd.]
A sample plate was prepared at a cylinder temperature of 200 ° C and a mold temperature of 50 ° C. The evaluation results are shown in Table 1.
【００１８】［比較例３］実施例２で使用した銀コート
ガラスフレークに代えてステンレス粉末（平均粒径３０
μm ）５．０部を使用する以外は実施例２と同様にして
ペレット化した。次いで実施例２と同様にして見本板を
作成した。評価結果を表１に示した。Comparative Example 3 Instead of the silver-coated glass flakes used in Example 2, stainless powder (average particle size 30) was used.
Pellets were pelletized in the same manner as in Example 2 except that 5.0 parts was used. Then, a sample plate was prepared in the same manner as in Example 2. The evaluation results are shown in Table 1.
【００１９】[0019]
【表１】 [Table 1]
【００２０】[0020]
【発明の効果】本発明によれば、表１に示すように輝き
と奥行きのある高級な蛍光メタリック調の成形品を容易
に提供することができる。EFFECTS OF THE INVENTION According to the present invention, as shown in Table 1, it is possible to easily provide a high-quality fluorescent metallic tone molded article having brilliance and depth.
Claims (1)
された透光性熱可塑性樹脂１００重量部に、金属をコー
ティングした平均粒径が０．０１〜３mmで平均厚さが１
〜３０μm のガラスフレークを０．０１〜１０重量部配
合してなる樹脂組成物。1. A metal having 100 parts by weight of a translucent thermoplastic resin containing a fluorescent dye and / or a fluorescent pigment coated with an average particle diameter of 0.01 to 3 mm and an average thickness of 1
A resin composition containing 0.01 to 10 parts by weight of glass flakes having a particle size of 30 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05025194A JP3573481B2 (en) | 1994-03-22 | 1994-03-22 | Resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP05025194A JP3573481B2 (en) | 1994-03-22 | 1994-03-22 | Resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07258460A true JPH07258460A (en) | 1995-10-09 |
| JP3573481B2 JP3573481B2 (en) | 2004-10-06 |
Family
ID=12853770
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP05025194A Expired - Fee Related JP3573481B2 (en) | 1994-03-22 | 1994-03-22 | Resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3573481B2 (en) |
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1994
- 1994-03-22 JP JP05025194A patent/JP3573481B2/en not_active Expired - Fee Related
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| WO2019063716A1 (en) | 2017-09-28 | 2019-04-04 | L'oreal | Aerosol device for pigment dyeing based on a particular acrylic polymer and a silicone compound, dyeing process |
| WO2019121501A1 (en) | 2017-12-21 | 2019-06-27 | L'oreal | Process for treating keratin materials using at least one aqueous dispersion of particles of polyurethane or of acrylic polymer and at least one colorant |
| WO2019120957A1 (en) | 2017-12-21 | 2019-06-27 | L'oreal | Composition comprising an aqueous dispersion of polyurethane particles and a cationic surfactant |
| WO2020002154A1 (en) | 2018-06-28 | 2020-01-02 | L'oreal | Device for applying a composition for dyeing keratin fibres, comprising at least one copolymer derived from the polymerization of at least one monomer of crotonic acid or crotonic acid derivative |
| WO2020002051A1 (en) | 2018-06-28 | 2020-01-02 | L'oreal | Composition for dyeing keratin fibres, comprising at least one copolymer derived from the polymerization of at least one crotonic acid monomer and of at least one vinyl ester monomer and a fatty amine |
| US11980682B2 (en) | 2018-06-28 | 2024-05-14 | L'oreal | Composition for dyeing keratin fibres, comprising at least one copolymer derived from the polymerization of at least one crotonic acid monomer and of at least one vinyl ester monomer and a fatty amine |
| WO2020083787A1 (en) | 2018-10-25 | 2020-04-30 | L'oreal | Method for treating keratin fibers using a composition comprising at least one cationic acrylic copolymer and at least one pigment |
| US11986549B2 (en) | 2018-10-25 | 2024-05-21 | L'oreal | Method for treating keratin fibers using a composition comprising at least one silicone acrylic copolymer and at least one pigment |
| FR3087654A1 (en) | 2018-10-25 | 2020-05-01 | L'oreal | PROCESS FOR THE TREATMENT OF KERATINIC FIBERS USING A COMPOSITION COMPRISING AT LEAST ONE CATIONIC ACRYLIC COPOLYMER AND AT LEAST ONE PIGMENT |
| FR3087653A1 (en) | 2018-10-25 | 2020-05-01 | L'oreal | PROCESS FOR THE TREATMENT OF KERATIN FIBERS USING A COMPOSITION COMPRISING AT LEAST ONE ACRYLIC SILICONE COPOLYMER AND AT LEAST ONE PIGMENT |
| US11534387B2 (en) | 2018-10-25 | 2022-12-27 | L'oreal | Method for treating keratin fibers using a composition comprising at least one cationic acrylic copolymer and at least one pigment |
| WO2020083789A1 (en) | 2018-10-25 | 2020-04-30 | L'oreal | Method for treating keratin fibers using a composition comprising at least one silicone acrylic copolymer and at least one pigment |
| FR3090368A1 (en) | 2018-12-20 | 2020-06-26 | L'oreal | Composition for coloring keratin fibers comprising at least one silicone acrylic copolymer, at least one silicone resin and at least one pigment |
| FR3090327A1 (en) | 2018-12-20 | 2020-06-26 | L'oreal | Gelled composition comprising two hydrophilic gelling agents and solid aggregates |
| WO2020127833A1 (en) | 2018-12-20 | 2020-06-25 | L'oreal | Gelled composition comprising two hydrophilic gelling agents and solid aggregates |
| WO2020126773A1 (en) | 2018-12-20 | 2020-06-25 | L'oreal | Composition for dyeing keratin fibers comprising at least one silicone acrylic copolymer, at least one silicone resin and at least one pigment |
| FR3097438A1 (en) | 2019-06-24 | 2020-12-25 | L'oreal | Anhydrous composition comprising at least one amino silicone, at least one alkoxysilane and at least one coloring agent |
| WO2020260097A1 (en) | 2019-06-24 | 2020-12-30 | L'oreal | Anhydrous composition comprising at least one amino silicone, at least one alkoxysilane and at least one coloring agent |
| WO2020260273A1 (en) | 2019-06-24 | 2020-12-30 | L'oreal | Composition comprising at least one alkoxysilane, at least one non-amino silicone and water, the alkoxysilane/non-amino silicone mass ratio ranging from 95/5 to 5/95 |
| FR3097439A1 (en) | 2019-06-24 | 2020-12-25 | L'oreal | Composition comprising at least one alkoxysilane, at least one non-aminated silicone and water, the alkoxysilane / non-aminated silicone mass ratio varying from 95: 5 to 5: 95 |
| FR3097745A1 (en) | 2019-06-26 | 2021-01-01 | L'oreal | Gelled composition comprising a dispersion of solid aggregates |
| WO2020260659A1 (en) | 2019-06-28 | 2020-12-30 | L'oreal | Oily dispersion comprising a polymeric particle and a stabilizer bearing a c9-c22 alkyl group, and process for treating keratin materials using the oily dispersion |
| FR3097756A1 (en) | 2019-06-28 | 2021-01-01 | L'oreal | OILY DISPERSION INCLUDING A POLYMERIC PARTICLE, A STABILIZING AGENT WITH A C9-C22 ALKYL GROUP, PROCESS FOR TREATMENT OF KERATINIC MATERIALS IMPLEMENTING THE OILY DISPERSION |
| FR3099989A1 (en) | 2019-08-22 | 2021-02-26 | L'oreal | Composition comprising at least one alkoxysilane of formula (I), at least one alkoxysilane of formula (II), at least one non-aminated silicone, and optionally direct pigments and / or dyes |
| FR3099990A1 (en) | 2019-08-22 | 2021-02-26 | L'oreal | Process for treating keratin fibers using a composition comprising at least one alkoxysilane of formula (I), at least one alkoxysilane of formula (II), at least one silicone containing an epoxy function, and optionally pigments and / or direct dyes |
| WO2021032873A1 (en) | 2019-08-22 | 2021-02-25 | L'oreal | Composition comprising at least one alkoxysilane of formula (i), at least one alkoxysilane of formula (ii), at least one nonamino silicone, and optionally pigments and/or direct dyes |
| WO2021099517A1 (en) | 2019-11-21 | 2021-05-27 | L'oreal | Composition comprising a (poly)carbodiimide compound and a coloring agent |
| WO2021099515A1 (en) | 2019-11-21 | 2021-05-27 | L'oreal | Process for treating keratin fibers, comprising a (poly)carbodiimide compound, an aqueous dispersion of particles of polymer(s)and a coloring agent |
| FR3103385A1 (en) | 2019-11-21 | 2021-05-28 | L'oreal | Composition comprising a (poly) carbodiimide compound and a coloring agent |
| FR3103384A1 (en) | 2019-11-21 | 2021-05-28 | L'oreal | Process for treating keratin fibers comprising a (poly) carbodiimide compound, an aqueous dispersion of particles of polymer (s) and a coloring agent |
| WO2021116114A1 (en) | 2019-12-13 | 2021-06-17 | L'oreal | Aerosol hair dyeing device based on a crotonic acid copolymer and a fatty amine |
| FR3104428A1 (en) | 2019-12-13 | 2021-06-18 | L'oreal | AEROSOL COLORING DEVICE BASED ON COPOLYMER RESULTING FROM THE POLYMERIZATION OF AT LEAST ONE MONOMER OF CROTONIC ACID AND AT LEAST ONE MONOMER OF VINYL ESTER AND AN ORGANIC AMINE |
| WO2021121882A1 (en) | 2019-12-16 | 2021-06-24 | L'oreal | Hair dyeing process using at least one silicone comprising at least one carboxylic acid anhydride group, at least one amino silicone and at least one pigment and/or direct dye |
| US11931449B2 (en) | 2019-12-16 | 2024-03-19 | L'oreal | Hair dyeing process using at least one silicone comprising at least one carboxylic acid anhydride group, at least one amino silicone and at least one pigment and/or direct dye |
| FR3104431A1 (en) | 2019-12-16 | 2021-06-18 | L'oreal | Coloring process using at least one silicone comprising at least one carboxylic acid anhydride group, at least one amino silicone and at least one direct pigment and / or dye |
| WO2021130335A1 (en) | 2019-12-23 | 2021-07-01 | L'oreal | Emulsified lip gel |
| FR3104990A1 (en) | 2019-12-23 | 2021-06-25 | L'oreal | Emulsified lip gel |
| FR3105734A1 (en) | 2019-12-30 | 2021-07-02 | L'oreal | Process for treating keratin fibers comprising the application of a composition comprising a particular compound and a step of supplying energy to said keratin fibers |
| WO2021136788A1 (en) | 2019-12-30 | 2021-07-08 | L'oreal | Process for treating keratin fibres, comprising the application of a composition comprising a particular compound comprising at least two tetrazoles groups |
| WO2021214053A1 (en) | 2020-04-21 | 2021-10-28 | L'oreal | Process for densifying keratin fibers, based on silicone, an alkoxysilane and a coloring agent |
| FR3109304A1 (en) | 2020-04-21 | 2021-10-22 | L'oreal | PROCESS FOR DENSIFICATION OF KERATINIC FIBERS BASED ON ACRYLIC SILICONE COPOLYMER AND A COLORING AGENT |
| FR3109305A1 (en) | 2020-04-21 | 2021-10-22 | L'oreal | PROCESS FOR DENSIFICATION OF KERATINIC FIBERS BASED ON SILICONE, AN ALCOXYSILANE AND A COLORING AGENT |
| WO2021214056A1 (en) | 2020-04-24 | 2021-10-28 | L'oreal | Process for the treatment of keratin fibers employing a composition comprising at least one alkoxysilane of formula (i), at least one non amino silicone of formula (ii) having a weight-average molecular weight of less than or equal to 1500 g/mol and at least one coloring agent |
| FR3109529A1 (en) | 2020-04-24 | 2021-10-29 | L'oreal | Composition comprising at least one alkoxysilane of formula (I), at least one non-amino silicone of formula (II) and at least one coloring agent |
| FR3109527A1 (en) | 2020-04-24 | 2021-10-29 | L'oreal | Process for treating keratin fibers using a composition comprising at least one alkoxysilane of formula (I), at least one non-amino silicone of formula (II) having an average molecular mass of less than or equal to 1500 g / mol and at least minus a coloring agent. |
| FR3109528A1 (en) | 2020-04-24 | 2021-10-29 | L'oreal | Composition comprising at least one alkoxysilane of formula (I), at least one non-amino silicone of formula (II) having an average molecular mass of less than or equal to 1500 g / mol and at least one coloring agent |
| WO2021214055A1 (en) | 2020-04-24 | 2021-10-28 | L'oreal | Composition comprising at least one alkoxysilane of formula (i), at least one non amino silicone of formula (ii) and at least one coloring agent |
| US12016946B2 (en) | 2020-04-24 | 2024-06-25 | L'oreal | Process for the treatment of keratin fibers employing a composition comprising at least one alkoxysilane of formula (I), at least one non amino silicone of formula (II) having a weight-average molecular weight of less than or equal to 1500 g/mol and at least one coloring agent |
| WO2021260062A1 (en) | 2020-06-23 | 2021-12-30 | L'oreal | Process for treating keratin fibres, comprising the application of a makeup-removing composition, the keratin fibres having been dyed beforehand |
| FR3111558A1 (en) | 2020-06-23 | 2021-12-24 | L'oreal | Process for treating keratin fibers comprising the application of a makeup removing composition, the keratin fibers having been previously colored |
| FR3111810A1 (en) | 2020-06-30 | 2021-12-31 | L'oreal | Composition comprising a combination of fillers |
| WO2022002978A1 (en) | 2020-06-30 | 2022-01-06 | L'oreal | Composition comprising a combination of polyglycerol esters |
| FR3111799A1 (en) | 2020-06-30 | 2021-12-31 | L'oreal | Composition comprising a combination of polyglycerol esters |
| FR3112951A1 (en) | 2020-07-30 | 2022-02-04 | L'oreal | Composition comprising at least one amino silicone, at least one non-amino silicone and at least one coloring agent |
| WO2022023426A1 (en) | 2020-07-30 | 2022-02-03 | L'oreal | Composition comprising at least one amino silicone, at least one non-amino silicone and at least one colouring agent |
| FR3113240A1 (en) | 2020-08-10 | 2022-02-11 | L'oreal | COMPOSITION COMPRISING AT LEAST ONE PARTICULAR SILICONE, AT LEAST ONE ALCANE AND AT LEAST ONE DIRECT COLOR AND/OR AT LEAST ONE PIGMENT |
| FR3115457A1 (en) | 2020-10-23 | 2022-04-29 | L'oreal | Photoprotective composition |
| WO2022084458A1 (en) | 2020-10-23 | 2022-04-28 | L'oreal | Photoprotective composition |
| FR3117032A1 (en) | 2020-12-08 | 2022-06-10 | L'oreal | Gel composition comprising silica airgel and ethylguar as thickening agents |
| FR3117860A1 (en) | 2020-12-17 | 2022-06-24 | L'oreal | Composition comprising at least one silicone of formula (I), at least one silicone of formula (II), at least one metal compound and at least one coloring agent |
| FR3117861A1 (en) | 2020-12-17 | 2022-06-24 | L'oreal | Composition comprising at least one silicone of formula (I), at least one silicone of formula (II) and at least one coloring agent |
| FR3117843A1 (en) | 2020-12-17 | 2022-06-24 | L'oreal | Process for dyeing keratin fibers using at least one metallic compound |
| WO2022129157A1 (en) | 2020-12-17 | 2022-06-23 | L'oreal | Composition comprising at least one silicone of formula (i), at least one silicone of formula (ii) and at least one coloring agent |
| WO2022129192A1 (en) | 2020-12-18 | 2022-06-23 | L'oreal | Dispersion comprising a polymeric particle, a stabilizer bearing a c9-c22 alkyl group, an oil and water, and process for treating keratin materials using the dispersion |
| FR3117842A1 (en) | 2020-12-18 | 2022-06-24 | L'oreal | Composition comprising at least one alkoxysilane, at least one polyoxyalkylene and at least one coloring agent |
| FR3117786A1 (en) | 2020-12-18 | 2022-06-24 | L'oreal | DISPERSION COMPRISING A POLYMERIC PARTICLE, A STABILIZING AGENT WITH A C3-C12 CYCLOALKYL GROUP, AN OIL AND WATER, PROCESS FOR THE TREATMENT OF KERATIN MATERIALS USING THE DISPERSION |
| FR3117846A1 (en) | 2020-12-18 | 2022-06-24 | L'oreal | DISPERSION COMPRISING A POLYMERIC PARTICLE, A STABILIZING AGENT WITH A C9-C22 ALKYL GROUP, AN OIL AND WATER, PROCESS FOR THE TREATMENT OF KERATIN MATERIALS USING THE DISPERSION |
| WO2022129195A1 (en) | 2020-12-18 | 2022-06-23 | L'oreal | Dispersion comprising a polymeric particle, a stabilizer bearing a c3-c12 cycloalkyl group, an oil and water, and process for treating keratin materials using the dispersion |
| FR3117794A1 (en) | 2020-12-23 | 2022-06-24 | L'oreal | Aqueous dispersion of a specific copolymer and its cosmetic applications |
| FR3117855A1 (en) | 2020-12-23 | 2022-06-24 | L'oreal | : Cosmetic composition comprising a copolymer based on acetoacetate functions |
| FR3117852A1 (en) | 2020-12-23 | 2022-06-24 | L'oréal | Cosmetic composition comprising a copolymer based on acetoacetate functions |
| FR3117788A1 (en) | 2020-12-23 | 2022-06-24 | L'oreal | Aqueous dispersion of a specific copolymer and its cosmetic applications |
| FR3117854A1 (en) | 2020-12-23 | 2022-06-24 | L'oréal | Cosmetic composition comprising polymeric particles based on acetoacetate functions |
| WO2022136110A1 (en) | 2020-12-23 | 2022-06-30 | L'oreal | Cosmetic composition comprising polymer particles based on acetoacetate functions |
| WO2022136114A1 (en) | 2020-12-23 | 2022-06-30 | L'oreal | Aqueous dispersion of a specific copolymer, and cosmetic uses thereof |
| WO2022136104A1 (en) | 2020-12-23 | 2022-06-30 | L'oreal | Cosmetic composition comprising a copolymer based on acetoacetate functions |
| FR3117856A1 (en) | 2020-12-23 | 2022-06-24 | L'oréal | Cosmetic composition comprising a block copolymer based on acetoacetate functions |
| FR3117853A1 (en) | 2020-12-23 | 2022-06-24 | L'oreal | Cosmetic composition comprising polymeric particles based on acetoacetate functions |
| WO2022144367A1 (en) | 2020-12-30 | 2022-07-07 | L'oreal | Fragranced cosmetic composition comprising at least one ferulic acid derivative, a dyestuff and a fragrancing material, and process for treating keratin materials and/or clothing using the composition |
| FR3118418A1 (en) | 2020-12-30 | 2022-07-01 | L'oreal | Perfumed cosmetic composition comprising at least one ferulic acid derivative, a coloring material and a fragrancing material, and process for treating keratin material and/or clothing using the composition |
| FR3118420A1 (en) | 2020-12-30 | 2022-07-01 | L'oreal | Composition comprising at least one anti-hair loss agent, at least one pigment, at least one hydrophobic film-forming polymer, at least one aqueous-phase thickening agent and at least one organic solvent and water |
| FR3118401A1 (en) | 2020-12-30 | 2022-07-01 | L'oreal | Device with removable applicator comprising a composition containing at least one anti-hair loss agent, at least one pigment and at least one solvent |
| FR3120530A1 (en) | 2021-03-10 | 2022-09-16 | L'oreal | Hair coloring process comprising the application of a composition comprising at least one (poly)carbodiimide compound and of a composition comprising at least one associative polymer and a particular compound |
| WO2022189573A1 (en) | 2021-03-10 | 2022-09-15 | L'oreal | Hair colouring composition comprising at least one (poly)carbodiimide compound and at least one compound comprising at least one hydroxyl function |
| FR3120529A1 (en) | 2021-03-10 | 2022-09-16 | L'oreal | Hair coloring composition comprising at least one (poly)carbodiimide compound and at least one compound comprising at least one hydroxy function |
| FR3120532A1 (en) | 2021-03-10 | 2022-09-16 | L'oreal | Hair coloring composition comprising at least one (poly)carbodiimide compound and at least one non-carboxylic anionic thickening agent |
| FR3120528A1 (en) | 2021-03-10 | 2022-09-16 | L'oreal | Method for removing color from previously colored hair keratin fibers |
| WO2022189571A1 (en) | 2021-03-10 | 2022-09-15 | L'oreal | Process for removing the colour from hair keratin fibers which have been coloured beforehand with a specific hair colouring composition |
| WO2022189572A1 (en) | 2021-03-10 | 2022-09-15 | L'oreal | Process for removing the colour from previously coloured hair keratin fibers |
| FR3120527A1 (en) | 2021-03-10 | 2022-09-16 | L'oreal | Process for dyeing hair keratin fibers comprising the application of a composition comprising at least one (poly)carbodiimide compound and of a composition comprising at least one associative polymer and a particular compound |
| WO2022189570A1 (en) | 2021-03-10 | 2022-09-15 | L'oreal | Process for colouring hair keratin fibers, comprising the application of a composition comprising at least one (poly)carbodiimide compound and a composition comprising at least one associative polymer and a particular compound |
| WO2022189575A1 (en) | 2021-03-10 | 2022-09-15 | L'oreal | Process for colouring hair keratin fibers comprising the application of a composition comprising at least one (poly)carbodiimide compound and a composition comprising at least one associative polymer and a particular compound |
| FR3120533A1 (en) | 2021-03-10 | 2022-09-16 | L'oreal | Process for removing the color from hair keratin fibers which have been previously colored with a specific hair coloring composition |
| WO2022189576A1 (en) | 2021-03-10 | 2022-09-15 | L'oreal | Hair colouring composition comprising at least one (poly)carbodiimide compound and at least one non-carboxylic anionic thickener |
| FR3123567A1 (en) | 2021-06-07 | 2022-12-09 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, a polymer containing a carboxylic group and a non-silicone fatty substance |
| WO2022258494A1 (en) | 2021-06-07 | 2022-12-15 | L'oreal | Hair dyeing process comprising the application of a (poly)carbodiimide compound, of a polymer bearing a carboxylic group and of a non-silicone fatty substance |
| FR3125424A1 (en) | 2021-07-23 | 2023-01-27 | L'oreal | Hair coloring composition comprising at least one (poly)carbodiimide compound and at least one protein |
| FR3125423A1 (en) | 2021-07-23 | 2023-01-27 | L'oreal | Cosmetic composition comprising at least one (poly)carbodiimide compound and at least one amino alkoxysilane |
| FR3125422A1 (en) | 2021-07-23 | 2023-01-27 | L'oreal | Hair coloring composition comprising at least one (poly)carbodiimide compound, at least one amino alkoxysilane and at least one coloring agent |
| WO2023001953A1 (en) | 2021-07-23 | 2023-01-26 | L'oreal | Hair colouring composition comprising at least one (poly)carbodiimide compound and at least one protein |
| FR3127403A1 (en) | 2021-09-28 | 2023-03-31 | L'oreal | Composition comprising at least one silicone of formula (I), at least one silicone of formula (II), at least one hydrophobic film-forming polymer chosen from copolymers based on silicone resin and fluid silicone |
| FR3127695A1 (en) | 2021-10-05 | 2023-04-07 | L'oreal | OILY DISPERSION COMPRISING A POLYMERIC PARTICLE, A STABILIZING AGENT WITH A C9-C22 ALKYL GROUP, AND A PLASTICIZER METHOD FOR TREATMENT OF KERATIN MATERIALS USING THE OILY DISPERSION |
| WO2023057446A1 (en) | 2021-10-05 | 2023-04-13 | L'oreal | Oily dispersion comprising a polymeric particle and a stabilizer bearing a c9-c22 alkyl group and a plasticizer, and process for treating keratin materials using the oily dispersion |
| FR3129605A1 (en) | 2021-11-26 | 2023-06-02 | Capsum | Method of forming a dispersion comprising drops, and associated apparatus |
| WO2023094613A1 (en) | 2021-11-26 | 2023-06-01 | Capsum | Method for forming a dispersion comprising drops, and associated apparatus |
| WO2023104730A1 (en) | 2021-12-09 | 2023-06-15 | L'oreal | Dispersion comprising a polymeric particle, a stabilizer bearing a cycloalkyl group, an oil and water, and process for treating keratin materials using the dispersion |
| WO2023104924A1 (en) | 2021-12-09 | 2023-06-15 | L'oreal | Composition comprising a combination of polyglycerol esters and a filler |
| FR3130132A1 (en) | 2021-12-09 | 2023-06-16 | L'oreal | DISPERSION COMPRISING A POLYMERIC PARTICLE, A STABILIZING AGENT WITH A CYCLOALKYL GROUP, AN OIL, AND WATER, PROCESS FOR THE TREATMENT OF KERATIN MATERIALS USING THE DISPERSION |
| FR3130133A1 (en) | 2021-12-09 | 2023-06-16 | L'oreal | Composition comprising a combination of polyglycerol esters and a filler |
| WO2023107199A1 (en) | 2021-12-09 | 2023-06-15 | L'oreal | Skin perfecting cosmetic compositions and methods of use |
| FR3130141A1 (en) | 2021-12-13 | 2023-06-16 | L'oreal | Process for dyeing hair comprising the application of a composition comprising a (poly)carbodiimide compound, and the application of a composition comprising a silicone elastomer with carboxylic acid functions |
| WO2023110752A1 (en) | 2021-12-13 | 2023-06-22 | L'oreal | Process for colouring the hair comprising the application of a composition comprising a (poly)carbodiimide compound, and the application of a composition comprising a silicone elastomer containing carboxylic acid functions |
| FR3130616A1 (en) | 2021-12-16 | 2023-06-23 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, a surfactant and a coloring agent |
| FR3130617A1 (en) | 2021-12-16 | 2023-06-23 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, two compounds having specific Hansen solubility parameters and a coloring agent |
| WO2023111269A1 (en) | 2021-12-16 | 2023-06-22 | L'oreal | Process for colouring the hair, comprising at least the application of a composition comprising a (poly)carbodiimide compound, a silicone acrylic copolymer and at least one colouring agent |
| FR3130614A1 (en) | 2021-12-16 | 2023-06-23 | L'oreal | Hair coloring process comprising at least the application of a composition comprising a (poly)carbodiimide compound, a silicone acrylic copolymer and at least one coloring agent |
| FR3130615A1 (en) | 2021-12-16 | 2023-06-23 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer and a coloring agent |
| WO2023111268A1 (en) | 2021-12-16 | 2023-06-22 | L'oreal | Hair dyeing process, comprising the application of a (poly)carbodiimide compound of specific formula, a silicone acrylic polymer, two compounds with specific hansen solubility parameters and a colouring agent |
| WO2023110754A1 (en) | 2021-12-16 | 2023-06-22 | L'oreal | Process for colouring the hair comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, a surfactant and a colouring agent |
| WO2023110772A1 (en) | 2021-12-17 | 2023-06-22 | L'oreal | Cosmetic or dermatological composition comprising at least a merocyanine and a hydrotrope |
| FR3130596A1 (en) | 2021-12-17 | 2023-06-23 | L'oreal | Cosmetic and/or dermatological composition comprising at least one merocyanine and at least ascorbic acid and/or one of its derivatives |
| FR3130595A1 (en) | 2021-12-17 | 2023-06-23 | L'oreal | Cosmetic or dermatological composition comprising at least one merocyanine and one hydrotrope |
| FR3130560A1 (en) | 2021-12-17 | 2023-06-23 | L'oreal | Composition comprising a combination of polyglycerol esters, a mineral UV filter and a liposoluble or specific hydrophobic particulate coloring matter |
| WO2023110763A1 (en) | 2021-12-17 | 2023-06-22 | L'oreal | Cosmetic and/or dermatological composition comprising at least one merocyanine and at least ascorbic acid and/or a derivative thereof |
| WO2023117794A1 (en) | 2021-12-23 | 2023-06-29 | L'oreal | Composition comprising a photocrosslinkable polymer having a hydrophobic group and a coloring agent |
| WO2023117954A1 (en) | 2021-12-23 | 2023-06-29 | L'oreal | Process for removing makeup from keratin fibres which have been treated beforehand with a composition comprising a photocrosslinkable polymer |
| FR3131201A1 (en) | 2021-12-23 | 2023-06-30 | L'oreal | Method for removing make-up from keratin fibers which have been previously treated with a composition comprising a photo-crosslinkable polymer |
| FR3131200A1 (en) | 2021-12-23 | 2023-06-30 | L'oreal | Composition comprising a photo-crosslinkable polymer and a coloring agent |
| FR3131529A1 (en) | 2021-12-31 | 2023-07-07 | L'oreal | Customization kit for a cosmetic composition |
| WO2023126397A1 (en) | 2021-12-31 | 2023-07-06 | L'oreal | Kit for customizing a cosmetic composition |
| FR3131688A1 (en) | 2022-01-12 | 2023-07-14 | L'oreal | Coatings, methods and systems for optically transformed nails |
| FR3132220A1 (en) | 2022-01-31 | 2023-08-04 | L'oreal | skin-perfecting cosmetic compositions and methods of use |
| WO2023187158A1 (en) | 2022-03-31 | 2023-10-05 | L'oreal | Process for dyeing the hair |
| FR3133999A1 (en) | 2022-03-31 | 2023-10-06 | L'oreal | Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer, composition A and/or composition B comprising a coloring agent and an amino silicone |
| FR3134002A1 (en) | 2022-03-31 | 2023-10-06 | L'oreal | Hair coloring process comprising the application of a composition A comprising an alkoxysilane, and the application of a composition B comprising a film-forming polymer, composition A and/or composition B comprising a coloring agent and a silicone resin |
| FR3134000A1 (en) | 2022-03-31 | 2023-10-06 | L'oreal | Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer, composition A and/or composition B comprising a coloring agent and an amino acid |
| FR3134001A1 (en) | 2022-03-31 | 2023-10-06 | L'oreal | Hair coloring process comprising the application of a composition C comprising a metallic compound |
| FR3134003A1 (en) | 2022-03-31 | 2023-10-06 | L'oreal | Process for removing color from keratin fibers previously colored with two alkoxysilanes, a film-forming polymer, a non-ionic cellulose polymer and a coloring agent |
| WO2023187157A1 (en) | 2022-03-31 | 2023-10-05 | L'oreal | Hair dyeing process comprising the application of a composition c comprising a metal compound |
| FR3137283A1 (en) | 2022-06-30 | 2024-01-05 | L'oreal | Use of a composition comprising an alkyl or alkylene carbonate for removing color from previously colored keratin hair fibers without damaging the keratin hair fibers |
| WO2024003303A1 (en) | 2022-06-30 | 2024-01-04 | L'oreal | Process for removing the colour from previously dyed keratinous hair fibres |
| FR3137287A1 (en) | 2022-06-30 | 2024-01-05 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, of a compound comprising at least one carboxylic function, and of a coloring agent comprising aluminum |
| FR3137291A1 (en) | 2022-06-30 | 2024-01-05 | L'oreal | Aerosol coloring device based on silicone acrylic copolymer, a coloring agent and a propellant gas of the dimethyl ether type |
| FR3137286A1 (en) | 2022-06-30 | 2024-01-05 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, and a coloring agent |
| FR3137293A1 (en) | 2022-06-30 | 2024-01-05 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, a compound having at least one carboxylic acid group and a coloring agent |
| FR3137285A1 (en) | 2022-06-30 | 2024-01-05 | L'oreal | Process for removing color from previously colored keratin hair fibers |
| FR3137295A1 (en) | 2022-06-30 | 2024-01-05 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, a compound having at least one carboxylic acid group and a pigment having a particular particle size |
| WO2024003305A1 (en) | 2022-06-30 | 2024-01-04 | L'oreal | Use of a composition comprising an alkyl or alkylene carbonate for removing the colour from previously dyed keratinous hair fibres without damaging the keratinous hair fibres |
| WO2024003304A1 (en) | 2022-06-30 | 2024-01-04 | L'oreal | Process for dyeing the hair, comprising the application of a (poly)carbodiimide compound, of a compound having at least one carboxylic acid group and of a colouring agent |
| WO2024003307A1 (en) | 2022-06-30 | 2024-01-04 | L'oreal | Process for dyeing the hair comprising the application of a (poly)carbodiimide compound, a compound comprising at least one carboxylic function, and a colouring agent comprising aluminium |
| FR3137294A1 (en) | 2022-06-30 | 2024-01-05 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, a silicone acrylic copolymer, a particular alkaline agent and a coloring agent |
| WO2024003302A1 (en) | 2022-06-30 | 2024-01-04 | L'oreal | Process for dyeing the hair comprising the application of a (poly)carbodiimide compound, a compound having at least one carboxylic acid group and a pigment having a particular particle size |
| WO2024013110A1 (en) | 2022-07-11 | 2024-01-18 | L'oreal | Process for dyeing the hair comprising the application of a composition a comprising two alkoxysilanes, and the application of a composition b comprising a film-forming polymer |
| WO2024013111A1 (en) | 2022-07-11 | 2024-01-18 | L'oreal | Process for dyeing the hair comprising the application of a composition a comprising two alkoxysilanes, and the application of a composition b comprising a film-forming polymer |
| FR3137574A1 (en) | 2022-07-11 | 2024-01-12 | L'oreal | Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer |
| FR3137575A1 (en) | 2022-07-11 | 2024-01-12 | L'oreal | Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer |
| FR3139721A1 (en) | 2022-09-16 | 2024-03-22 | L'oreal | Hair coloring process comprising the application of a composition A comprising two alkoxysilanes, and the application of a composition B comprising a film-forming polymer |
| WO2024068929A1 (en) | 2022-09-30 | 2024-04-04 | L'oreal | Cosmetic hair care composition comprising at least one particular amino silicone and at least one colouring agent and/or an optical brightener, and cosmetic hair treatment process |
| WO2024068931A1 (en) | 2022-09-30 | 2024-04-04 | L'oreal | Cosmetic hair care composition comprising at least one particular amino silicone and at least one non-silicone fatty substance, and cosmetic hair treatment process |
| FR3140279A1 (en) | 2022-09-30 | 2024-04-05 | L'oreal | Cosmetic hair care composition comprising at least one particular amino silicone and at least one non-silicone fatty substance, and method for cosmetic treatment of hair |
| FR3140277A1 (en) | 2022-09-30 | 2024-04-05 | L'oreal | Cosmetic hair care composition comprising at least one particular amino silicone and at least one associative polymer, and cosmetic hair treatment method |
| FR3140273A1 (en) | 2022-09-30 | 2024-04-05 | L'oreal | Cosmetic hair care composition comprising at least one particular amino silicone and at least one coloring agent and/or an optical brightener, and method for cosmetic treatment of hair |
| FR3142887A1 (en) | 2022-12-09 | 2024-06-14 | L'oreal | Perfumed cosmetic composition comprising at least one phloretin derivative, a coloring material and a perfuming substance, and process for treating keratin material and/or clothing using the composition |
| WO2024121308A1 (en) | 2022-12-09 | 2024-06-13 | L'oreal | Fragranced cosmetic composition comprising at least one phloretin derivative, a dyestuff and a fragrancing substance |
| WO2024133718A1 (en) | 2022-12-21 | 2024-06-27 | L'oreal | Process for dyeing keratin hair fibers comprising the application of a composition t comprising an amino acid and the application of a (poly)carbodiimide compound and a colouring agent |
| WO2024133715A1 (en) | 2022-12-21 | 2024-06-27 | L'oreal | Process for dyeing keratin hair fibers comprising the application of a treatment with a reducing agent and of a composition comprising a (poly)carbodiimide compound and a colouring agent process for dyeing keratin hair fibers comprising the application of a treatment with a reducing agent and of a composition comprising a (poly)carbodiimide compound and a colouring agent |
| WO2024133717A1 (en) | 2022-12-21 | 2024-06-27 | L'oreal | Process for dyeing keratin hair fibers comprising the application of a composition comprising a (poly)carbodiimide compound, the application of heat and the application of a composition comprising a (poly)carbodiimide compound |
| WO2024133696A1 (en) | 2022-12-21 | 2024-06-27 | L'oreal | Process for dyeing keratin hair fibers comprising the application of a (poly)carbodiimide compound, a compound containing at least one carboxylic acid group, an amino silicone and a colouring agent. |
| WO2024133719A1 (en) | 2022-12-21 | 2024-06-27 | L'oreal | Process for dyeing keratin hair fibers which involves spraying the keratin hair fibers with a composition comprising a (poly)carbodiimide compound and a colouring agent using an airbrush |
| WO2024133693A1 (en) | 2022-12-21 | 2024-06-27 | L'oreal | Process for dyeing keratin hair fibers comprising the application of a particular composition t and the application of a (poly)carbodiimide compound and a colouring agent |
| WO2024133698A1 (en) | 2022-12-21 | 2024-06-27 | L'oreal | Process for dyeing keratin hair fibers comprising the application of a (poly)carbodiimide compound and a colouring agent, the application of steam and shaping at a particular temperature. |
| WO2024133697A1 (en) | 2022-12-21 | 2024-06-27 | L'oreal | Process for dyeing keratin hair fibers comprising the application of a cold plasma treatment and of a composition comprising a (poly)carbodiimide compound and a colouring agent |
| WO2024133716A1 (en) | 2022-12-21 | 2024-06-27 | L'oreal | Process for dyeing keratin hair fibers comprising the application of a treatment with an alkaline agent and of a composition comprising a (poly)carbodiimide compound and a colouring agent |
| FR3143992A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | Hair coloring process comprising the application of a composition T comprising an amino acid and the application of a (poly)carbodiimide compound and a coloring agent |
| FR3143991A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | A method of coloring hair comprising spraying the hair with a composition comprising a (poly)carbodiimide compound and a coloring agent using an airbrush |
| FR3143993A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | Use of a hair coloring composition comprising a (poly)carbodiimide compound, a compound having at least one carboxylic function and a coloring agent for increasing hair volume |
| FR3143986A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | A process for coloring hair comprising the application of a (poly)carbodiimide compound and a coloring agent, the application of steam and shaping at a particular temperature |
| FR3143988A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | A method of coloring hair comprising applying a composition comprising a (poly)carbodiimide compound, applying heat, and applying a composition comprising a (poly)carbodiimide compound |
| FR3143994A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | A process for coloring hair comprising the application of a treatment with an alkaline agent and a composition comprising a (poly)carbodiimide compound and a coloring agent |
| FR3143983A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | Hair coloring process comprising the application of a particular composition T and the application of a (poly)carbodiimide compound and a coloring agent |
| FR3143996A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | Process for coloring hair comprising the application of a treatment with a reducing agent and a composition comprising a (poly)carbodiimide compound and a coloring agent |
| FR3143981A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | A process for coloring hair comprising the application of a treatment with an alcohol and a composition comprising a specific (poly)carbodiimide compound and a coloring agent |
| FR3143987A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | Hair coloring process comprising the application of a (poly)carbodiimide compound, a compound having at least one carboxylic acid group, an amino silicone and a coloring agent |
| FR3143989A1 (en) | 2022-12-21 | 2024-06-28 | L'oreal | A process for coloring hair comprising the application of a cold plasma treatment and a composition comprising a (poly)carbodiimide compound and a coloring agent |
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|---|---|
| JP3573481B2 (en) | 2004-10-06 |
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