FR3090327A1 - Gelled composition comprising two hydrophilic gelling agents and solid aggregates - Google Patents

Abstract

The present invention relates to a composition comprising at least one aqueous phase gelled with at least two distinct hydrophilic gelling agents and at least one oily phase gelled with at least one lipophilic gelling agent chosen from the elastomers of the invention. 'organopolysiloxane; said phases forming therein a macroscopically homogeneous mixture; said composition further comprising a dispersion of solid aggregates, said aggregates being formed from 10% to 80% by weight of wax (es), relative to their total weight.

Description

Description

Title of the invention: Gelled composition comprising two hydrophilic gelling agents and solid aggregates

The present invention relates to a new dosage particularly interesting in terms of its technical performance and sensory feelings it provides the user when applied on them, for the field of care and hygiene keratin materials, in particular of the skin and / or the lips, and in particular of the skin.

Technical area

[0002] Cosmetic compositions are commonly used to camouflage and / or unify imperfections in the relief of the skin such as pores, wrinkles and / or fine lines and / or scars. In this regard, numerous formulations, solid or fluid, anhydrous or not, have to date been developed.

When these compositions are more particularly intended to blur the visibility of the relief of the skin, the formulator implements therein diffusing or blurring charges. However, the corresponding compositions, currently available, are not entirely satisfactory, in particular in terms of blurring performance.

In order to obtain a satisfactory degree of blurring, it is often necessary to introduce a large quantity of blurring charges into the composition. However, this level of blurring charges can lead to destabilization of said composition and lead to cosmetic properties not in accordance with user expectations, in particular the formation of fluff during the application of the product and / or after drying and / or penetration of the product into the skin.

This defect is prohibitive for the user, because the application is not homogeneous or pleasant given this fluffy effect on the application or during the elimination of the product. In addition, it gives an impression of "dirty" on the skin.

Prior art

To overcome this problem and have a comfortable treatment with a blurring effect, alternative oily dosage forms are currently available on the cosmetic market.

However, these formulations have the drawbacks linked to the presence of high levels of fatty phase in the composition, namely the procuring of shiny skin and / or the sensation of oily and / or sticky skin.

The use of crosslinked silicones is another alternative. This type of raw material makes it possible to combine mat effect and soft-focus. However, they have the disadvantage of being characterized by an uncomfortable greasy and warm touch, with a "mask" effect.

Furthermore, cosmetic compositions combining a matt effect and a softfocus effect, comprising an aqueous-alcoholic or aqueous phyllosilicate gel of formula Mg ₃ Si ₄ Oio (OH) ₂ , have already been proposed, for example in WO 2016/083385 . These phyllosilicates are in the form of platelets, consisting of a single material, and are dispersed in the aqueous phase.

However, these mineral compounds tend to induce a linting effect when applied to keratin materials when they are used in cosmetic compositions.

It therefore remains difficult for those skilled in the art to develop homogeneous compositions capable of providing an immediate visual result on the skin with a feeling of lightness and comfort on application, with a smooth deposit, non-sticky, and without linting effect during application, this expected immediate result is preferably good coverage of color imperfections and / or relief imperfections.

Statement of the invention

There therefore remains a need for cosmetic compositions making it possible to mask the imperfections of the skin, while having good cosmetic properties, in particular in terms of optical and sensory effects, and in particular providing a feeling of comfort on application. .

The present invention aims precisely to meet this need.

Summary of the invention

[0014] Thus, according to one of its aspects, the present invention relates to a composition, in particular cosmetic, in particular for making up and / or caring for keratin materials, comprising:

At least one aqueous phase gelled with at least two distinct hydrophilic gelling agents, the first hydrophilic gelling agent being chosen from polymers and copolymers of 2-acrylamido 2-methylpropane sulfonic acid and the second hydrophilic gelling agent being chosen from polymers of 2-acrylamido-2-methylpropane sulfonic acid, copolymers of 2-acrylamido-2-methylpropane sulfonic acid and of vinylpyrrolidone or of vinylformarmide, sodium polyacrylates and crosslinked (meth) acrylic acid homopolymers; and

At least one oily phase gelled with at least one lipophilic gelling agent chosen from elastomers of organopolysiloxane;

Said phases forming therein a macroscopically homogeneous mixture;

Said composition further comprising a dispersion of solid aggregates, said aggregates being formed from 10% to 80% by weight of wax (es), relative to their total weight.

By "keratin materials" is meant in particular the skin, the lips and / or the eyelashes, in particular the skin and / or the lips, and preferably the skin.

Against all expectations, the inventors have found that the use of two specific hydrophilic gelling agents and the incorporation of a dispersion of solid aggregates as defined above makes it possible to improve the optical and sensory performance of a composition having a gel-gel architecture.

As can be seen from the examples given below, the compositions according to the invention have a better soft-focus optical effect while retaining very good sensoriality, in particular in terms of comfort, tights and slipperiness.

In addition, the compositions according to the invention advantageously have a smooth finish with a reduced fluffing effect, or even no fluffing effect during application.

Compositions, called gel-gel, are already offered in the cosmetic field. This type of formulation combines a gelled aqueous phase with a gelled oily phase. Thus, gel / gel formulations are described in Almeida et al., Pharmaceutical Development and Technology, 2008, 13: 487, Tables 1 and 2, page 488; WO 99/65455; PI 0405758-9; WO 99/62497; JP 2005-112834 and WO 2008/081175. However, to the knowledge of the inventors, this type of composition does not at present make it possible to conceal and smooth imperfections in relief without altering the other expected cosmetic performances.

As stated above, the inventors have found that the addition of a dispersion of specific solid aggregates in a composition of gel-gel type using two specific hydrophilic gelling agents makes it possible to obtain a composition combining optical performance and sensory. In particular, a composition according to the invention makes it possible to mask the imperfections and to provide a luminous complexion, while having good sensory properties, in particular in terms of emollience, comfort, stickiness and slippery on the skin.

Another subject of the invention, according to another of its aspects, is a cosmetic process for making up and / or caring for keratin materials, in particular the skin and / or the lips, comprising at least one step of application to said keratin materials of a composition according to the invention.

detailed description

Cosmetic composition

First, it is important to note that a composition according to the invention is different from an emulsion.

An emulsion generally consists of an oily liquid phase and an aqueous liquid phase. It is a dispersion of droplets from one of the two liquid phases in the other. The size of the droplets forming the dispersed phase of the emulsion is typically of the order of a micrometer (0.1 to 100 μm). In addition, an emulsion requires the presence of a surfactant or an emulsifier to ensure its stability over time.

Conversely, a composition according to the invention consists of a macroscopically homogeneous mixture of at least two immiscible gelled phases. Each of these phases has a gel-like texture. This texture is reflected in particular visually by a consistent and / or creamy appearance.

By "macroscopically homogeneous mixture" is meant a mixture in which each of the gelled phases cannot be individualized with the naked eye.

More specifically, in a composition according to the invention, the gelled aqueous phase and the gelled oily phase interpenetrate and thus form a stable and consistent product. This consistency is achieved by mixing the interpenetrating macro-domains. These interpenetrating macro-domains are not measurable objects. Thus, under the microscope, the composition according to the invention is very different from an emulsion. A composition according to the invention can also not be characterized as having a "sense", ie an O / W or W / O sense.

Thus, a composition according to the invention has a gel-like consistency. The stability of the composition is durable without surfactant. Consequently, a composition, in particular a cosmetic composition, according to the invention does not require a surfactant or a silicone emulsifier to ensure its stability over time.

It is known from the state of the art to observe the intrinsic nature of a mixture of aqueous and oily gels in a gel-type composition, for example, by introducing a coloring matter either in the aqueous gelled phase either in the lipophilic gelled phase, before the gel-type composition is formed. During visual inspection, in a gel-type composition, the coloring matter appears to be uniformly dispersed, even if the coloring is present only in the gelled aqueous phase or in the gelled oily phase. Indeed, if two different dyes of distinct colors are introduced respectively in the oily phase and in the aqueous phase, before the formation of the gel-type composition, the two colors can be observed as uniformly dispersed throughout the gel-type composition. This is different from an emulsion in which, if a dye, soluble in water or soluble in oil, is introduced respectively in the aqueous and oily phases, before forming the emulsion, only the color of the dye will be observed. present in the external phase (Remington: The Science and Practice of Pharmacy, 19th Edition (1995), Chapter 21, page 282).

In the case of the present invention, the test which will be favored for distinguishing a gel-type composition from an emulsion is a dilution test. In fact, in a gel-type composition, the aqueous and oily gelled domains interpenetrate and form a consistent and stable composition, in which the behavior in water and in oil is different from the behavior of an emulsion. Consequently, the behavior during dilution of a gel-type composition (bi-continuous system) can be compared to that of an emulsion.

More specifically, the dilution test consists of putting 40 g of product and 160 g of dilution solvent (water or oil) in a 500 ml plastic beaker. The dilution is carried out with controlled stirring to avoid any emulsification phenomenon. In particular, this is done using a planetary motion mixer: Speed Mixer TM DAC400EVZ. The speed of the mixer is set at 1500 rpm for 4 minutes. Finally, the observation of the resulting sample is carried out using an optical microscope at a magnification of x 100 (x10 x10). It can be noted that the oils such as Parleam® and Xiameter PMX-200 Silicone Lluid 5CS® sold by Dow Corning are suitable as dilution solvent in the same way as one of the oils contained in the composition.

In the case of a gel-type composition (bi-continuous system), when it is diluted in oil or in water, a heterogeneous appearance is always observed. When a gel-type composition (bi-continuous system) is diluted in water, pieces of oily gel are observed in suspension and when a gel-type composition (bi-continuous system) is diluted in oil, pieces of aqueous gel in suspension are observed.

On the contrary, during dilution, the emulsions exhibit different behavior. An O / W emulsion, when diluted in an aqueous solvent, gradually reduces without presenting a heterogeneous and lumpy appearance. This same O / W emulsion, when diluted with the oil, has a heterogeneous appearance (pieces of O / W emulsion suspended in the oil). A W / O emulsion, when diluted with an aqueous solvent, has a heterogeneous appearance (pieces of W / O emulsion suspended in water). This same W / O emulsion, when diluted in oil, gradually reduces without presenting a heterogeneous and lumpy appearance.

According to the present invention, the aqueous gelled phase and the oily gelled phase forming a composition according to the invention are present therein in a weight ratio varying from 95/5 to 5/95. More preferably, the aqueous phase and the oily phase are present in a weight ratio varying from 30/70 to 90/10.

The ratio between the two gelled phases is adjusted according to the desired cosmetic properties.

Thus, in the case of a makeup composition, in particular of the face, it will be advantageous to favor a weight ratio of aqueous gelled phase / oily gelled phase greater than 1, in particular varying from 55/45 to 90/10, preferably varying from 60/40 to 85/15.

These preferred ratios are particularly advantageous for obtaining fresh and light compositions.

Advantageously, a composition according to the invention can therefore be in the form of a creamy gel having a minimum stress below which it does not flow unless it has been subjected to an external mechanical stress.

As follows from what follows, a composition according to the invention may have a minimum threshold stress of 1.5 Pa and in particular greater than 10 Pa.

It can also advantageously have a stiffness modulus G * at least equal to 400 Pa, and preferably greater than 1000 Pa.

According to an advantageous alternative embodiment, the gelled phases considered to form a composition according to the invention may respectively have a threshold stress greater than 1.5 Pa, and preferably greater than 10 Pa.

The characterization of the threshold stresses is carried out by rheology measurements in oscillation. A methodology is proposed in the exemplification chapter of this text.

In general, the corresponding measurements are made at 25 ° C using an imposed constraint rheometer, RS600 HAAKE, equipped with a plane-plane measuring body (diameter 60 mm) provided with '' an anti-evaporation device (bell). For each measurement, the sample is gently placed and the measurements begin 5 minutes after the sample is placed in the air gap (2 mm). The composition tested is then subjected to a stress ramp of 10 ² to 10 ³ Pa at a frequency fixed at 1 Hz.

A composition according to the invention can also have a certain elasticity. This elasticity can be characterized by a modulus of rigidity G * which under this threshold of minimum stress can be at least equal to 400 Pa, and preferably greater than 1000 Pa. The G * value of a composition can be obtained by subjecting the composition considered at a stress ramp of 10 ² to 10 ³ Pa at a frequency fixed at 1 Hz.

Dispersion of solid aggregates

As mentioned above, a composition according to the invention comprises at least one dispersion of solid aggregates.

According to a preferred embodiment, a composition according to the invention comprises from 1% to 40% by weight, preferably from 2% to 35% by weight, and more preferably from 5% to 30% by weight, d solid aggregates relative to the total weight of the composition.

According to the invention, the term "aggregates" means an assembly of separate compounds which adhere to one another and form a whole. Such aggregates can have various shapes and sizes.

Preferably, the aggregates present in a composition according to the invention have a size between 0.1 pm and 100 pm, preferably between 0.1 pm and 10 pm.

The term "solid" means aggregates or a composition having, at 25 ° C and at atmospheric pressure (1 atm = 10 ⁵ Pa), a hardness greater than 0.5 N, preferably greater than 2 N, said hardness is preferably measured using a texturometer provided with a hemispherical probe with a diameter of 12.7 mm.

By "dispersion of solid aggregates" is meant that the solid aggregates are dispersed in the composition according to the invention.

Preferably, the solid aggregates are dispersed in the gelled aqueous phase and / or in the gelled oily phase, and in particular mainly in the gelled oily phase.

More preferably, the aggregates are dispersed in the gelled oily phase.

Waxes

As indicated above, the solid aggregates are formed from 10% to 80% by weight of wax (es), relative to their total weight.

Preferably, the solid aggregates are formed from 10% to 50% by weight of wax (es), and preferably from 10% to 40% by weight of wax (es), relative to their total weight.

By “wax” within the meaning of the present invention, is meant a lipophilic compound, solid at room temperature (25 ° C.), with reversible solid / liquid state change, having a melting point greater than or equal to 30 ° C up to 120 ° C.

The melting point of the wax can be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name DSC 30 by the company METLER.

Preferably, the measurement protocol is as follows:

A 5 mg sample of wax placed in a crucible is subjected to a first temperature rise ranging from -20 ° C to 100 ° C, at the heating rate of ° C / minute, then is cooled from 100 ° C to - 20 ° C at a cooling rate of 10 ° C / minute and finally subjected to a second temperature rise ranging from -20 ° C to 100 ° C at a heating rate of 5 ° C / minute. During the second temperature rise, the variation in the difference in power absorbed by the empty crucible and by the crucible containing the wax sample is measured as a function of the temperature. The melting point of the compound is the value of the temperature corresponding to the top of the peak of the curve representing the variation of the difference in power absorbed as a function of the temperature.

The wax may in particular have a hardness ranging from 0.05 MPa to 15 MPa, and preferably ranging from 6 MPa to 15 MPa. The hardness is determined by measuring the compressive force measured at 20 ° C using the texturometer sold under the name TA-TX2Î by the company RHEO, equipped with a stainless steel cylinder with a diameter of 2 mm. moving at the measuring speed of 0.1 mm / s, and penetrating into the wax at a penetration depth of 0.3 mm.

The waxes can be hydrocarbon, silicone or fluorinated and be of vegetable, mineral, animal and / or synthetic origin.

In particular, the waxes have a melting temperature greater than 30 ° C and better still greater than 45 ° C.

Apolar wax

By “apolar wax”, within the meaning of the present invention, is meant a wax whose solubility parameter _{a a} at 25 ° C as defined below is equal to 0 (J / cm ³ ) ' ^{/ 2} .

Apolar waxes are in particular hydrocarbon waxes consisting only of carbon and hydrogen atoms and free of heteroatoms such as N, O, Si and P.

In particular, by apolar wax is meant a wax which consists only of apolar wax and not a mixture which would also include other types of waxes which are not apolar waxes.

By way of illustration of apolar waxes suitable for the invention, mention may in particular be made of hydrocarbon waxes such as microcrystalline waxes, paraffin waxes, ozokerite, polymethylene waxes, polyethylene waxes, especially microcires polyethylene.

As polyethylene wax, mention may be made of Performalene 500-L Polyethylene and Performalene 400 Polyethylene marketed by New Phase Technologies and Asensa SC 211 marketed by Honeywell.

As polymethylene wax, mention may be made of Cirebelle 108 sold by Cirebelle.

As ozokerite, mention may be made of Ozokerite Wax SP 1020 P.

As microcrystalline waxes which can be used, mention may be made of Multiwax W 445® sold by the company Sonnebom and Microwax HW® and Base wax 30540® sold by the company Paramelt.

As microcires which can be used according to the invention as apolar wax, mention may in particular be made of polyethylene microcires such as those marketed under the names of Micropoly 200®, 220®, 220L® and 250S® by the company Micro Powders.

Polar wax

By "polar wax", within the meaning of the present invention, is meant a wax whose solubility parameter _{a a} at 25 ° C is different from 0 (J / cm ³ ) ' ^{/ 2} .

In particular, by "polar wax" means a wax whose chemical structure is formed essentially, even constituted, of carbon and hydrogen atoms, and comprising at least one strongly electronegative heteroatom such as an atom oxygen, nitrogen, silicon or phosphorus.

The definition and calculation of the solubility parameters in the Hansen three-dimensional solubility space are described in the article by C. M. Hansen: "The three dimensionnai solubility parameters", J. Paint Technol. 39, 105 (1967).

According to this Hansen space:

· Ô _D characterizes the London dispersion forces resulting from the formation of dipoles induced during molecular shocks;

• ô _p characterizes the Debye interaction forces between permanent dipoles as well as the Keesom interaction forces between induced dipoles and permanent dipoles;

• ô _h characterizes the specific interaction forces (such as hydrogen bonds, acid / base, donor / acceptor, etc.);

• ô _a is determined by the equation: ô _a = (érop ² + ôh ² ) ' ^{/ 2} .

The parameters ô _p , ô _h , ô _D and ô _a are expressed in (J / cm ³ ) ' ^/! .

The polar waxes can in particular be hydrocarbon-based, fluorinated or silicone-based, and preferably hydrocarbon-based or silicone-based.

By "silicone wax" means an oil comprising at least one silicon atom, and in particular comprising Si-O groups.

By "hydrocarbon wax" means a wax formed essentially, or even constituted, of carbon and hydrogen atoms, and optionally oxygen, nitrogen atoms, and containing no atom silicon or fluorine. It can contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

Hydrocarbon waxes

According to a first preferred embodiment, the polar wax is a hydrocarbon wax.

As a polar hydrocarbon wax, in particular a wax chosen from ester waxes and alcohol waxes is preferred.

By "ester wax" is understood according to the invention a wax comprising at least one ester function. The ester waxes can also be hydroxylated.

By "alcohol wax" is meant according to the invention a wax comprising at least one alcohol function, that is to say comprising at least one free hydroxyl group (-OH).

One can in particular use as ester wax, ester waxes such as those chosen from:

I. waxes of formula RiCOOR ₂ in which Ri and R ₂ represent linear, branched or cyclic aliphatic chains whose number of atoms varies from 10 to 50, which may contain a heteroatom such as O, N or P and whose point temperature melting ranges from 25 ° C to 120 ° C. In particular, it is possible to use as ester wax a (hydroxy stearyloxy) C ₂ oC _4O alkyl stearate (the alkyl group comprising from 20 to 40 carbon atoms), alone or as a mixture or a C ₂ alkyl stearate oC _4O . Such waxes are sold in particular under the names “Kester Wax K 82 P®”, “Hydroxypolyester K 82 P®”, “Kester Wax K 80 P®”, or “Kester Wax K 82 H®” by the company Koster Keunen. It is also possible to use a montanate (octacosanoate) of glycol and butylene glycol such as the Licowax KPS Flakes wax (INCI name: glycol montanate) sold by the company Clariant.

i i. di- (trimethylol-1,1,1 propane) tetrastearate, sold under the name Hest 2T-4S® by the company Heterene.

i ii. diester waxes of a dicarboxylic acid of general formula R ₃ - (- OCO-R ₄ COO-R ₅ ), in which R ₃ and R ₅ are identical or different, preferably identical and represent a C ₄ alkyl group - C ₃₀ (alkyl group comprising from 4 to 30 carbon atoms) and R ₄ represents a C ₄ -C ₃₀ aliphatic group (alkyl group comprising from 4 to 30 carbon atoms) linear or branched and which may or may not contain one or more unsaturations. Preferably, the C ₄ -C ₃₀ aliphatic group is linear and unsaturated.

i v. Mention may also be made of the waxes obtained by catalytic hydrogenation of animal or vegetable oils having fatty chains, linear or branched, of C ₈ C ₃₂ , for example such as hydrogenated jojoba oil, hydrogenated sunflower oil, l hydrogenated castor oil, hydrogenated coconut oil, as well as the waxes obtained by hydrogenation of castor oil esterified with cetyl alcohol, such as those sold under the names of Phyto wax ricin 16L64® and 22L73® by Sophim company. Such waxes are described in application FR2792190. As waxes obtained by hydrogenation of olive oil esterified with stearyl alcohol, mention may be made of those sold under the name "Phytowax Olive 18 L 57".

v. The waxes corresponding to the partial or total, preferably total, esters of a C ₆ -C ₃₀ carboxylic acid, saturated, optionally hydroxylated, with glycerol. By total esters is meant that all of the hydroxyl functions of glycerol are esterified. By way of example, mention may be made of trihydroxystearin (or glyceryl trihydroxystearate), tristearine (or glyceryl tristearate), tribehenine (or glyceryl tribehenate), alone or as a mixture. Among suitable compounds, there may be mentioned the triesters of glycerol and 12-hydroxystearic acid, or of hydrogenated castor oil, such as, for example, Thixcin R, Thixcin E, sold by Elementis Specialties.

v i. Mention may also be made of the ester of behenic acid and of glycerol, and in particular the mixtures of esters of behenic acid and of glycerol, such as for example the mixture glyceryl dibehenate, tribehenin, glyceryl behenate sold by the company Gattefossé under reference Compritol 888 CG ATO.

v ii. Mention may also be made of beeswax, synthetic beeswax, polyglycerolated beeswax, carnauba wax, candellila wax, oxypropylenated lanolin wax, rice bran wax, '' Ouricury, Alfa wax, cork fiber wax, sugar cane wax, Japanese wax, sumac wax, montan wax, Orange wax, Laurel wax, hydrogenated Jojoba wax, and mixtures thereof.

According to another embodiment, the polar wax can be an alcohol wax.

Mention may be made, as alcohol wax, of the alcohols, preferably linear, preferably saturated, comprising from 16 to 60 carbon atoms, the melting point of which is between 25 ° C. and 120 ° C. As alcohol wax, mention may be made, for example, of Performacol 550-L Alcohol from New Phase Technologie, stearic alcohol, cetyl alcohol, myristic alcohol, palmitic alcohol, behenic alcohol, erucic alcohol, arachidyl alcohol, or mixtures thereof.

Silicon waxes

By "silicone wax" means an oil comprising at least one silicon atom, and in particular comprising Si-O groups.

Among the commercial silicone waxes of this type, there may be mentioned in particular those sold under the names Abilwax 9810 (Goldschmidt), KL910 and KL7002 (Shin Etsu), or 176-11481 (General Electric).

The silicone waxes which can be used can also be alkyl or alkoxydimethicones, as well as the (C ₂ oC ₆ o) alkyldimethicones, in particular the (C ₃ oC ₄₅ ) alkyldimethicones such as the silicone wax sold under the name SE-1642 by the company GE-Bayer Silicones or C ₃₀ - ₄ 5 Alkyldimethylsilyl Polypropyl Silsesquioxane under the name SW-8005® C30 Resin Wax marketed by the company Dow Corning.

Mention may also be made of silicone waxes obtained by esterification with a (poly) alkoxylated silicone such as silicone beeswax, silicone candelilla wax, silicone camauba wax.

Preferably, the wax or waxes are chosen from ester waxes.

According to a preferred embodiment, the wax or waxes are chosen from beeswax and a mixture of esters of behenic acid and of glycerol.

According to a preferred embodiment, the wax or waxes are chosen from mixtures of esters of behenic acid and of glycerol.

Non-volatile oils

The solid aggregates can also comprise one or more nonvolatile oils.

By "oil" means a non-aqueous compound, immiscible with water, liquid at room temperature (25 ° C) and atmospheric pressure (760 mm Hg).

By "non-volatile" is meant an oil whose vapor pressure at room temperature and atmospheric pressure is not zero and less than 0.02 mm Hg (2.66 Pa) and better still less than 10 ³ mm of Hg (0.13 Pa).

As non-volatile oil, mention may in particular be made of: [0106] · hydrocarbon oils of animal origin, • hydrocarbon oils of plant origin, synthetic ethers having from to 40 carbon atoms, such as dicapryl ether , • synthetic esters, such as oils of formula RiCOOR ₂ , in which Ri represents a residue of a linear or branched fatty acid containing from 1 to 40 carbon atoms and R ₂ represents a hydrocarbon chain, in particular, branched containing 1 to 40 carbon atoms provided that Ri + R ₂ is greater than or equal to 10. The esters can be, in particular, chosen from alcohol and fatty acid esters, such as, for example, cetostearyl octanoate, esters of isopropyl alcohol, such as isopropyl myristate, isopropyl palmitate, ethyl palmitate, 2-ethylhexyl palmitate, isopropyl stearate, octyl stearate, hydroxylated esters, such as isostearyl lactate, octyl hydroxystearate, ricinoleates of alcohols or polyalcohols, hexyl laurate, esters of neopentanoic acid, such as isodecyl neopentanoate, isotridecyl neopentanoate, esters of isononanoic acid, such as isononyl isononanoate , isotridecyl isononanoate, • polyol esters and pentaerythritol esters, such as dipentaerythritol tetrahydroxystearate / dipeterythritol tetraisostearate, • branched and / or unsaturated fatty chain liquid alcohols having from 12 to 26 atoms of carbon, such as 2-octyldodecanol, isostearyl alcohol, oleic alcohol, • higher C _[2 -C ₂₂ fatty acids, such as oleic acid, linoleic acid, linolenic acid, and their mixtures, • non-phenylated silicone oils, such as, for example, caprylyl methicone, and • phenylated silicone oils, such as, for example, phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenics yl methyldiphenyl trisiloxanes, and 2-phenylethyl trimethylsiloxysilicates, dimethicones or phenyltri methicone with viscosity less than or equal to 100 cSt, trimethylpentaphenyltrisiloxane, and their mixtures;

• as well as mixtures of these different oils.

Preferably, the aggregates further comprise at least one non-volatile oil, in particular chosen from non-volatile nonpolar hydrocarbon oils, non-volatile ester oils and their mixtures.

By “apolar oil” within the meaning of the present invention, is meant an oil whose solubility parameter at 25 ° C, d _a , is equal to 0 (J / cm ³ ) ' ^{/ 2} .

The definition and calculation of the solubility parameters in the Hansen three-dimensional solubility space are described in the article by C. M. Hansen: "The three dimensional solubility parameters", J. Paint Technol. 39, 105 (1967).

According to this Hansen space:

· Ô _D characterizes the London dispersion forces resulting from the formation of dipoles induced during molecular shocks;

• ô _p characterizes the Debye interaction forces between permanent dipoles as well as the Keesom interaction forces between induced dipoles and permanent dipoles;

• ô _h characterizes the specific interaction forces (such as hydrogen bonds, acid / base, donor / acceptor, etc.); and • ô _a is determined by the equation: ô _a = (érop ² + ôh ² ) ' ^{/ 2} .

The parameters ô _p , ô _h , ô _D and ô _a are expressed in (I / cm ³ ) ' ^{/ 2} .

[0112] Preferably, the non-volatile non-polar hydrocarbon-based oil is free of oxygen atom.

Preferably, the non-volatile non-polar hydrocarbon oil can be chosen from linear or branched hydrocarbons, of mineral or synthetic origin. In particular, it can be chosen from:

· Paraffin oil or its derivatives, • petrolatum oil, • naphthalene oil, • polybutylenes, in particular Indopol H-100 (of molar mass or M _w =

965 g / mol), Indopol H-300 (M _w = 1340 g / mol), Indopol H-1500 (M _w = 2160 g / mol) marketed or manufactured by the company Amoco, • polyisobutenes and hydrogenated polyisobutenes, in particular Parléam® marketed by the company Nippon Oil Fats, Panalane H-300 E marketed or manufactured by the company Amoco (M _w = 1340 g / mol), Viseal 20000 marketed or manufactured by the company Synteal (M _w = 6000 g / mol), the Rewopal PIB 1000 sold or manufactured by the company Witco (M _w = 1000 g / mol), • decene / butene copolymers, polybutene / polyisobutene copolymers, in particular Indopol L-14, • polydecenes and hydrogenated polydecenes, in particular Puresyn 10 (M _w = 723 g / mol), Puresyn 150 (M _w = 9200 g / mol) sold or manufactured by the company Mobil Chemicals, • and their mixtures.

Said non-volatile oil can also be an ester oil, in particular having between 18 and 70 carbon atoms.

As examples, mention may be made of mono-, di- or tri-esters.

The ester oils can in particular be hydroxylated.

The non-volatile ester oil can preferably be chosen from:

· The monoesters comprising between 18 and 40 carbon atoms in total, in particular the monoesters of formula RiCOOR ₂ in which Ri represents the remainder of a linear or branched fatty acid containing from 4 to 40 carbon atoms and R ₂ represents a notably branched hydrocarbon chain containing from 4 to 40 carbon atoms provided that Ri + R ₂ is greater than or equal to 18, such as, for example, Purcellin oil (ketostearyl octanoate), isononyl isononanoate, C in alcohol benzoate _[2 to C _5, palmitate 2-ethyl hexyl neopentanoate octyledodécyle stearate, 2-octyldodecyl, erucate 2-octyldodecyl isostearate d isostearyl, 2-octyl dodecyl benzoate, alcohol or polyalcohol octanoates, decanoates or ricinoleates, isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, palmitate 2-ethyl-hexyl, 2-hexyl-decyl laurate, 2-octyl-decyl palmitate, 2-o myristate ctyldodecyl, 2-diethyl-hexyl succinate. Preferably, these are the esters of formula RiCOOR ₂ in which Ri represents the remainder of a linear or branched fatty acid containing from 4 to 40 carbon atoms and R ₂ represents a notably branched hydrocarbon chain containing from 4 to 40 carbon atoms, Ri and R ₂ being such that Ri + R ₂ is greater than or equal to 18. Preferably, the ester comprises between 18 and 40 carbon atoms in total. Mention may be made, as preferred monoesters, of isononyl isononanoate, oleyl erucate and / or octyl-2-docecyl neopentanoate;

• diesters, in particular comprising between 18 and 60 carbon atoms in total, in particular between 18 and 50 carbon atoms in total. The diesters of dicarboxylic acid and of monoalcohols, such as preferably diisostearyl malate or the diesters of glycol and of mono carboxylic acids, such as neopentylglycol diheptanoate or poly-2-glyceryl diisostearate, in particular such as the compound sold, can be used in particular. under the commercial reference Dermol DGDIS by the company Alzo;

triesters, in particular comprising between 35 and 70 carbon atoms in total, in particular such as triesters of triacarboxylic acid, such as triisostearyl citrate, or tridecyl trimellitate, or triesters of glycol and mono-carboxylic acids such as triisostearate polyglycerol-2;

tetraesters, in particular having a total carbon number ranging from 35 to 70, such as tetraesters of pentaerythritol or of polyglycerol and of a mono carboxylic acid, for example such as pentaerythrityl tetrapelargonate, tetraisostearate pentaerythrityl, pentaerythrity teteasononanoate , tri-2-decyl glyceryl tetradecanoate, polyglyceryl-2 tetraisostearate or alternatively tetra-decyl-2 pentaerythrityl tetradecanoate;

polyesters obtained by condensation of dimer and / or trimer of unsaturated fatty acid and of diol such as those described in patent application FR0853634, such as in particular dilinoleic acid and 1,4-butanediol. Mention may in particular be made, as such, of the polymer marketed by Biosynthis under the name Viscoplast 14436H (INCI name: dilinoleic acid / butanediol copolymer), or alternatively the copolymers of polyols and diacid dimers, and their esters, such as Hailuscent ISDA;

the esters and polyesters of dimer diol and of mono- or dicarboxylic acid, such as the esters of dimer diol and of fatty acid and the esters of dimer diols and of dimer dicarboxylic acid, in particular obtainable from a dicarboxylic acid derivative in particular derived from the dimerization of an unsaturated fatty acid in particular in C ₈ to C ₃₄ , in particular in Ci ₂ to C ₂₂ , in particular in Ci6 to C ₂₀ , and more particularly in C _[8 , such as esters of dilinoleic diacids and of dimeroleic diol dimers, for example such as those sold by the company Nippon Fine Chemical under the trade name Lusplan DD-DA5® and DD-DA7®;

vinylpyrrolidone / 1-hexadecene copolymers, such as, for example, that sold under the name Antaron V-216 (also called Ganex V216) by the company ISP (M _w = 7300 g / mol);

vegetable hydrocarbon oils such as triglycerides of fatty acids (liquid at room temperature), in particular of fatty acids having from 7 to 40 carbon atoms, such as triglycerides of heptanoic or octanoic acids or jojoba oil, in particular, mention may be made of saturated triglycerides such as caprylic / capric triglyceride, glyceryl triheptanoate, glycerol trioctanoate, Ci ₈ - ₃₆ acid triglycerides such as those sold under the reference DUB TGI 24 by Stéarineries Dubois; and the unsaturated tri glycerides such as castor oil, olive oil, ximenia oil, pracaxi oil;

• and their mixtures.

Preferably, the solid aggregates are formed from 10% to 80% by weight of oil (s), and preferably del5% to 75% by weight, relative to their total weight.

According to a preferred embodiment, the solid aggregates comprise at least one non-polar non-volatile hydrocarbon-based oil and one non-volatile ester oil.

Preferably, the solid aggregates comprise at least two non-volatile non-volatile hydrocarbon oils and one non-volatile ester oil.

According to a particularly preferred embodiment, the solid aggregates comprise cetearyl ethylhexanoate (and) isopropyl myristate, hydrogenated polyisobutene and a mineral oil.

According to a first preferred variant, the solid aggregates comprise cetearyl ethylhexanoate (and) isopropyl myristate, hydrogenated polyisobutene, a mineral oil, and glyceryl dibehenate (and) tribehenin (and) glyceryl behenate.

According to a second preferred variant, the solid aggregates comprise cetearyl ethylhexanoate (and) isopropyl myristate, hydrogenated polyisobutene, a mineral oil, and a beeswax.

Hydrophilic gelling agents

By "hydrophilic gelling agent" for the purposes of the present invention, a compound capable of gelling the aqueous phase of the compositions according to the invention. The gelling agent is hydrophilic and is therefore present in the aqueous phase of the composition. The gelling agent can be water-soluble or water-dispersible.

As specified above, the aqueous phase of a composition according to the invention is gelled by at least two distinct hydrophilic gelling agents, the first hydrophilic gelling agent being chosen from polymers and copolymers of 2-acrylamido 2 acid -methylpropane sulfonic and the second hydrophilic gelling agent being chosen from polymers of 2-acrylamido-2-methylpropane sulfonic, copolymers of 2-acrylamido-2-methylpropane sulfonic and vinylpyrrolidone or vinylformarmide, sodium polyacrylates and crosslinked (meth) acrylic acid homopolymers.

First hydrophilic gelling agent

The first hydrophilic gelling agent is chosen from polymers and copolymers of 2-acrylamido 2-methylpropane sulfonic acid.

In particular, a composition according to the invention can comprise from 0.1% to 8% by weight, preferably from 0.2% to 5% by weight, and more preferably from 0.3% to 2% by weight. weight of the first hydrophilic gelling agent, relative to the total weight of the composition.

The polymers used which are suitable as the first hydrophilic gelling agent can be homopolymers or copolymers, crosslinked or non-crosslinked comprising at least the 2-acrylamido 2-methyl propane sulfonic acid monomer (AMPS®) neutralized by a mineral base other than ammonia such as soda or potash.

They are preferably neutralized completely or almost completely neutralized, that is to say neutralized at least 90%.

These AMPS® polymers according to the invention can be crosslinked or non-crosslinked.

When the polymers are crosslinked, the crosslinking agents can be chosen from olefinically polyunsaturated compounds commonly used for the crosslinking of the polymers obtained by radical polymerization.

Mention may be made, for example, as crosslinking agents, of divinylbenzene, diallyl ether, dipropylene glycol-diallylether, polyglycol-diallylethers, triethylene glycol-divinyl ether, hydroquinone-diallyl-ether, di (meth) acrylate. ethylene glycol or tetraethylene glycol, trimethylol propane triacrylate, methylene-bis-acrylamide, methylene-bis-methacrylamide, triallylamine, triallylcyanurate, diallylmaleate, tetraallylethylenediamine, tetraethyl-allyl-ethylethanol , ally le (meth) acrylate, allyl ethers of alcohols from the sugar series, or other allyl- or vinyl-ethers of polyfunctional alcohols, as well as allyl esters of derivatives of phosphoric acid and / or vinylphosphonic, or mixtures of these compounds.

According to a preferred embodiment of the invention, the crosslinking agent is chosen from methylene-bis-acrylamide, allyl methacrylate or trimethylol propane triacrylate (TMPTA). The crosslinking rate generally ranges from 0.01% to 10% by mole and more particularly from 0.2% to 2% by mole relative to the polymer.

The AMPS® polymers suitable for the invention are water-soluble or water-dispersible. They are in this case:

· Or "homopolymers" comprising only AMPS® monomers and, if they are crosslinked, one or more crosslinking agents such as those defined above;

• or copolymers obtained from AMPS® and one or more hydrophilic or hydrophobic ethylenically unsaturated monomers and, if they are crosslinked, one or more crosslinking agents such as those defined above. When said copolymers contain hydrophobic ethylenically unsaturated monomers, the latter do not contain a fatty chain and are preferably present in small amounts.

By “fatty chain”, within the meaning of the present invention, any hydrocarbon chain containing at least 7 carbon atoms.

By “water-soluble or water-dispersible” is meant polymers which, introduced into an aqueous phase at 25 ° C., at a mass concentration equal to 1%, allow a macroscopically homogeneous and transparent solution to be obtained, it i.e. having a maximum light transmittance value, at a wavelength equal to 500 nm, through a sample 1 cm thick, at least 60%, preferably at least 70% .

The “homopolymers” according to the invention are preferably crosslinked and neutralized, and they can be obtained according to the preparation process comprising the following steps:

A. dispersing or dissolving the monomer such as AMPS® in free form in a solution of tert-butanol or water and tert-butanol;

b. the solution or dispersion of monomer obtained in a) is neutralized with one or more inorganic or organic bases, preferably ammonia NH ₃ , in an amount making it possible to obtain a rate of neutralization of the sulfonic acid functions of the polymer ranging from 90 % 100 % ;

vs. the crosslinking monomer (s) is added to the solution or dispersion obtained in b);

d. a conventional radical polymerization is carried out in the presence of free radical initiators at a temperature ranging from 10 ° C to 150 ° C; the polymer precipitating in the solution or dispersion based on tert-butanol.

The water-soluble or water-dispersible copolymers of AMPS® according to the invention contain water-soluble ethylenically unsaturated monomers, hydrophobic monomers or their mixtures.

The water-soluble co-monomers can be ionic or non-ionic.

Among the ionic water-soluble co-monomers, mention may be made, for example, of the following compounds and their salts:

[(Meth) acrylic acid, • styrene sulfonic acid, • vinylsulfonic acid and (meth) allylsulfonic acid, • vinyl phonic acid, • maleic acid, • acid itaconic, • crotonic acid, • water-soluble vinyl monomers of formula (A) below:

[0147] Lormule (A):

[0148]

[Chem.l] (A)

In which:

Ri is chosen from H, -CH ₃ , -C ₂ H ₅ or -C ₃ H ₇ ;

• Xi is chosen from alkyl oxides of type -OR ₂ where R ₂ is a hydrocarbon radical, linear or branched, saturated or unsaturated, having from 1 to 6 carbon atoms, substituted by at least one sulfonic group ( -SO ₃ -) and / or sulfate (-SO4-) and / or phosphate (-PO ₄ H ₂ -).

Among the nonionic water-soluble co-monomers, there may be mentioned, for example: [0152] · (meth) acrylamide, • N-vinylacetamide and N-methyl N-vinylacetamide, • N-vinylformamide and N-methyl N-vinylformamide, • maleic anhydride, • vinylamine, • N-vinyllactams comprising a cyclic alkyl group having 4 to 9 carbon atoms, such as N-vinylpyrrolidone, N-butyrolactam and N-vinylcaprolactam, • vinyl alcohol of formula CH ₂ = CHOH, • water-soluble vinyl monomers of formula (B) below:

Formula (B):

[Chem.2]

In which:

· R ₃ is chosen from H, -CH ₃ , -C ₂ H ₅ or -C ₃ H ₇ ;

• X ₂ is chosen from alkyl oxides of type -OR4 where R4 is a hydrocarbon radical, linear or branched, saturated or unsaturated, having from 1 to 6 carbons, optionally substituted by a halogen atom (iodine, bromine, chlorine, fluorine); a hydroxy group (-OH); ether.

Examples include glycidyl (meth) acrylate, hydroxyethyl methacrylate, and (meth) acrylates of ethylene glycol, diethylene glycol or polyalkylene glycol.

Among the hydrophobic comonomers without a fatty chain, there may be mentioned, for example:

· Styrene and its derivatives such as 4-butylstyrene, alpha methylstyrene and vinyltoluene;

• vinyl acetate of formula CH ₂ = CH-OCOCH ₃ ;

• vinyl ethers of formula CH ₂ = CHOR in which R is a hydrocarbon radical, linear or branched, saturated or unsaturated, having from 1 to 6 carbons;

• 1 acrylonitrile;

• caprolactone;

• vinyl chloride and vinylidene chloride;

• silicone derivatives, leading after polymerization to silicone polymers such as methacryloxypropyltris (trimethylsiloxy) silane and silicone methacrylamides;

• the hydrophobic vinyl monomers of formula (C) below:

Formula (C):

[Chem. 3]

HX- “CR.

co ' ^Ci

X

In which:

· R4 is chosen from H, -CH ₃ , -C ₂ H ₅ or -C ₃ H ₇ ;

• X ₃ is chosen from alkyl oxides of -OR ₅ type where R ₅ is a hydrocarbon radical, linear or branched, saturated or unsaturated, having from 1 to 6 carbon atoms.

Examples include methyl methacrylate, ethyl methacrylate, n-butyl (meth) acrylate, tertiary butyl (meth) acrylate, cyclohexyl acrylate and isobornyl acrylate and the like. 2-hexyl ethyl acrylate.

The water-soluble or water-dispersible AMPS® polymers of the invention preferably have a molar mass ranging from 50,000 g / mole to 10,000,000 g / mole, preferably from 80,000 g / mole to 8,000,000 g / mole, and even more preferably from 100,000 g / mole to 7,000,000 g / mole.

As water-soluble or water-dispersible homopolymers of AMPS® suitable for the invention, mention may be made, for example, of crosslinked or non-crosslinked polymers of sodium acrylamide-2-methyl propane sulfonate such as that used in the commercial product Simulgel 800 ( CTFA name: Sodium Polyacryloyldimethyl Taurate), crosslinked polymers of acrylamide-2-methyl propane ammonium sulfonate (INCI name: Ammonium Polyacryldimethyltauramide) such as those described in patent EP0815928B1 and such as the product sold under the trade name Hostacerin AMPS ® by the company Clariant.

As water-soluble or water-dispersible copolymers of AMPS® in accordance with the invention, there may be mentioned, for example:

· Acrylamide / acrylamido-2-methyl propane sulfonate crosslinked copolymers such as that used in the commercial product Sepigel 305 (CTFA name: Polyacrylamide / C13-C14 Isoparaffin / Laureth-7) or that used in the commercial product sold under the name Simulgel 600 (CTFA name: Acrylamide / Sodium acryloyldimethyltaurate / Isohexadecane / Polysorbate-80) by the company Seppic;

• the copolymers of AMPS® and of vinylpyrrolidone or of vinylformamide such as that used in the commercial product sold under the name Aristoflex AVC® by the company Clariant (name CTFA: Ammonium Acryloyldimethyltaurate / VP Copolymer) but neutralized by soda or potash ;

• copolymers of AMPS® and sodium acrylate, such as for example the copolymer AMPS / sodium acrylate such as that used in the commercial product sold under the name Simulgel EG® by the company Seppic or under the trade name Sepinov EM (CTFA name: Hydroxyethyl Acrylate / Sodium Acryloyldimethyl taurate copolymer);

• the copolymers of AMPS® and hydroxyethyl acrylate, such as for example the copolymer AMPS® / hydroxyethyl acrylate such as that used in the commercial product sold under the name Simulgel NS® by the company Seppic (CTFA name: Hydroxyethyl Acrylate / Sodium Acryloyldimethyltaurate copolymer (And) Squalane (And) Polysorbate 60) or as the product marketed under the name Acrylamido-2-Methylpropane Sulfonate / Hydroxyethylacrylate copolymer as the commercial product Sepinov EMT 10 (INCI name: Hydroxyethyl Acrylate / Sodium Acryloyldimethyl taurate ).

Preferably, the first hydrophilic gelling agent is chosen from copolymers of 2-acrylamido-2-methylpropane-sulfomic acid and of hydroxyethyl acrylate.

In particular, a composition according to the invention may comprise from 0.1% to 8% by weight in dry matter, preferably from 0.2% to 5% by weight and more preferably from 0.3% to 2 % by weight of copolymer (s) of 2-acrylamido 2-methylpropane sulfonic acid, crosslinked and / or neutralized, relative to the total weight of the composition.

Second hydrophilic gelling agent

The second hydrophilic gelling agent is chosen from polymers of 2-acrylamido-2-methylpropane sulfonic acid, copolymers of 2-acrylamido-2-methylpropane sulfonic acid and vinylpyrrolidone or vinylformarmide, sodium polyacrylates and crosslinked (meth) acrylic acid homopolymers.

According to a preferred embodiment, the hydrophilic gelling agent is chosen from crosslinked polymers of acrylamide-2-methyl propane ammonium sulfonate, copolymers of 2-acrylamido-2-methylpropane-sulfonic acid and of vinylpyrrolidone, sodium polyacrylates, in particular partially neutralized, and crosslinked acrylic acid homopolymers.

In particular, a composition according to the invention may comprise from 0.1% to 8% by weight, preferably from 0.2% to 5% by weight, and more preferably from 0.3% to 2% by weight. weight of the second hydrophilic gelling agent, relative to the total weight of the composition.

2-acrylamido-2-methylpropane-sulfoma acid polymer (AMPS)

As stated above, the composition according to the invention may comprise at least one polymer of 2-acrylamido-2-methylpropane-sulfonic acid as the second hydrophilic gelling agent.

The polymer of 2-acrylamido-2-methylpropane-sulfonic acid which can be used in the composition according to the invention comprises 2-acrylamido-2-methylpropane-sulfonic acid units of formula (I) below:

[Chem. 4]

In which X ⁺ is a proton, an alkali metal cation, an alkaline earth cation or the ammonium ion.

As polymer of 2-acrylamido-2-methylpropane-sulfonic acid suitable for the invention, mention may be made, for example, of crosslinked or non-crosslinked polymers of sodium acrylamide-2-methyl propane sulfonate such as that used in the commercial product Simulgel 800 (CTFA name: Sodium Polyacryloyldimethyl Taurate), crosslinked polymers of ammonium acrylamide-2-methyl propane sulfonate (INCI name: Ammonium Polyacryldimethyltauramide) such as those described in patent EP0815928B1 and as the product sold under the trade name Hostacerin AMPS® by the company Clariant.

Preferably, as polymer of 2-acrylamido-2-methylpropane-sulfonic acid which can be used in the composition according to the invention, mention may be made in particular of crosslinked polymers of ammonium acrylamide-2-methyl propane sulfonate ( INCI name: Ammonium Polyacryldimethyltauramide), such as the product sold under the trade name Hostacerin AMPS® by the company Clariant.

[0180] Cooolxmers of AMPS®-and vinylpyrrolidone or vinylformamide

A composition according to the invention can comprise at least one copolymer of AMPS® and of vinylpyrrolidone or of vinylformamide as the second hydrophilic gelling agent.

Mention may in particular be made of the copolymers of AMPS® and of vinylpyrrolidone or of vinylformamide such as that used in the commercial product sold under the name Aristoflex AVC® by the company Clariant (name CTFA: Ammonium Acryloyldimethyltaurate / VP Copolymer) but neutralized by soda or potash.

Preferably, the second hydrophilic gelling agent is chosen from copolymers of 2-acrylamido-2-methylpropane-sulfonic acid and vinylpyrrolidone.

[0184] Sodium polyacrylate

A composition according to the invention may comprise at least one sodium polyacrylate as the second hydrophilic gelling agent.

Mention may in particular be made of sodium polyacrylates such as those marketed under the name Cosmedia SP® containing 90% dry matter and 10% water, or Cosmedia SPL® in reverse emulsion containing approximately 60% dry matter, an oil (hydrogenated polydecene) and a surfactant (PPG-5 Laureth-5), both sold by the company Cognis.

Mention may also be made of partially neutralized sodium polyacrylate such as the product sold by the company Sensient under the name Covacryl MV 60®.

Mention may also be made of partially neutralized sodium polyacrylates which are in the form of a reverse emulsion comprising at least one polar oil, for example that sold under the name Luvigel® EM by the company BASF.

Preferably, the second hydrophilic gelling agent is chosen from sodium polyacrylates, in particular partially neutralized.

Homooolymers of acid (crosslinked methkicrylic)

A composition according to the invention can comprise at least one homopolymer of cross-linked (meth) acrylic acid as second hydrophilic gelling agent.

By “(meth) acrylic” within the meaning of the present application, one understands “acrylic or methacrylic”.

By way of example, mention may be made of those sold by Lubrizol under the names Carbopol, 910, 934, 940, 941, 934 P, 980, 981, 2984, 5984, Carbopol Ultrez 10 Polymer, or by 3V-Sigma under the name Synthalen® K, Synthalen® L, or Synthalen® M.

Mention may in particular be made of Carbopol (CTFA name: carbomer) sold by the company Lubrizol.

Preferably, the second hydrophilic gelling agent is chosen from homo24 crosslinked acrylic acid polymers.

Lipophilic gelling agent

By "lipophilic gelling agent" for the purposes of the present invention, a compound capable of gelling the oily phase of the compositions according to the invention. The gelling agent is lipophilic, therefore present in the oily phase of the composition.

According to the present invention, the lipophilic gelling agent is chosen from organopolysiloxane elastomers.

The advantage of the organopolysiloxane elastomer is that it gives the composition according to the invention good application properties. It provides a very soft and mattifying feel after application, particularly advantageous for application to the skin. It can also allow effective filling of the hollows present on keratin materials.

By "organopolysiloxane elastomer" or "silicone elastomer" is meant a flexible, deformable organopolysiloxane having viscoelastic properties and in particular the consistency of a sponge or a flexible sphere. Its modulus of elasticity is such that this material resists deformation and has a limited capacity for extension and contraction. This material is able to return to its original shape after stretching.

It is more particularly a crosslinked organopolysiloxane elastomer.

Thus, the organopolysiloxane elastomer can be obtained by crosslinking addition reaction of diorganopolysiloxane containing at least one hydrogen bonded to silicon and of diorganopolysiloxane having ethylenically unsaturated groups bonded to silicon, in particular in the presence of platinum catalyst; or by dehydrogenation crosslinking condensation reaction between a diorganopolysiloxane with hydroxyl endings and a diorganopolysiloxane containing at least one hydrogen bonded to silicon, in particular in the presence of an organotin; or by crosslinking condensation reaction of a hydroxyl-terminated diorganopolysiloxane and of a hydrolyzable organopolysilane; or by thermal crosslinking of organopolysiloxane, in particular in the presence of an organoperoxide catalyst; or by crosslinking of organopolysiloxane by high energy radiation such as gamma rays, ultraviolet rays, electron beam.

Preferably, the organopolysiloxane elastomer is obtained by crosslinking addition reaction (A) of diorganopolysiloxane containing at least two hydrogens each linked to a silicon, and (B) of diorganopolysiloxane having at least two ethylenically unsaturated groups linked to silicon, in particular in the presence (C) of a platinum catalyst, as for example described in application EP295886.

In particular, the organopolysiloxane elastomer can be obtained by reaction of dimethylpolysiloxane with dimethylvinylsiloxy endings and methylhydrogenopoly25 siloxane with trimethylsiloxy endings, in the presence of a platinum catalyst.

The compound (A) is the basic reagent for the formation of elastomeric organopolysiloxane and the crosslinking is carried out by addition reaction of the compound (A) with the compound (B) in the presence of the catalyst (C).

The compound (A) is in particular an organopolysiloxane having at least two hydrogen atoms linked to distinct silicon atoms in each molecule.

The compound (A) can have any molecular structure, in particular a linear chain or branched chain structure or a cyclic structure.

The compound (A) can have a viscosity at 25 ° C ranging from 1 to 50,000 centistokes, in particular to be well miscible with the compound (B).

The organic groups linked to the silicon atoms of compound (A) can be alkyl groups such as methyl, ethyl, propyl, butyl, octyl; substituted alkyl groups such as 2-phenylethyl, 2-phenylpropyl, 3,3,3-trifluoropropyl; aryl groups such as phenyl, tolyl, xylyl; substituted aryl groups such as phenylethyl; and substituted monovalent hydrocarbon groups such as an epoxy group, a carboxylate ester group, or a mercapto group.

Compound (A) can thus be chosen from methylhydrogenopolysiloxanes with trimethylsiloxy endings, dimethylsiloxane-methylhydrogenosiloxane copolymers with trimethylsiloxy endings, cyclic dimethylsiloxane-methylhydrogenosiloxane copolymers.

Compound (B) is advantageously a diorganopolysiloxane having at least two lower alkenyl groups (for example C ₂ -C ₄ ); the lower alkenyl group can be chosen from vinyl, allyl, and propenyl groups. These lower alkenyl groups can be located in any position of the organopolysiloxane molecule but are preferably located at the ends of the organopolysiloxane molecule.

Organopolysiloxane (B) can have a branched chain, straight chain, cyclic or network structure but the straight chain structure is preferred. Compound (B) can have a viscosity ranging from a liquid state to a gum state. Preferably, the compound (B) has a viscosity of at least 100 centistokes at 25 ° C.

In addition to the abovementioned alkenyl groups, the other organic groups linked to the silicon atoms in the compound (B) can be alkyl groups such as methyl, ethyl, propyl, butyl or octyl; substituted alkyl groups such as 2-phenylethyl, 2-phenylpropyl or 3,3,3-trifluoropropyl; aryl groups such as phenyl, tolyl or xylyl; substituted aryl groups such as phenylethyl; and substituted monovalent hydrocarbon groups such as an epoxy group, a carboxylate ester group, or a mercapto group.

[0212] The organopolysiloxane (B) can be chosen from methylvinylpolysiloxanes, methylvinylsiloxane-dimethylsiloxane copolymers, dimethylvinylsiloxy-terminated siloxanes diméthylpoly, the diméthylsiloxaneméthylphénylsiloxane copolymers dimethylvinylsiloxy endings, dimethylsiloxane-diphenylsiloxane-methylvinylsiloxane copolymers, dimethylvinylsiloxy-terminated, dimethylsiloxane copolymers trimethylsiloxy-terminated methylvinylsiloxane, dimethylsiloxane-methylphenylsiloxane-methylvinylsiloxane-trimethylsiloxy-copolymers, methyl (3,3,3-trifluoropropyl) - polysiloxane with dimethylvinylsiloxy, and dimethylsiloxylethyl-trifluoroxylethylpropylmethylpropylmethylpropylmethylpropylmethylpropylmethylpropylmethylpropylmethylpropylmethylpropylmethyl) .

In particular, the elastomeric organopolysiloxane can be obtained by reaction of dimethylpolysiloxane with dimethylvinylsiloxy endings and of methylhydrogenpolysiloxane with trimethylsiloxy endings, in the presence of a platinum catalyst.

Advantageously, the sum of the number of ethylenic groups per molecule of the compound (B) and the number of hydrogen atoms linked to silicon atoms per molecule of the compound (A) is at least 5.

It is advantageous that the compound (A) is added in an amount such that the molecular ratio between the total amount of hydrogen atoms bonded to silicon atoms in the compound (A) and the total amount of all the ethylenically unsaturated groups in the compound (B) is in the range from 1.5 / 1 to 20/1.

Compound (C) is the catalyst for the crosslinking reaction, and is in particular chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alkenylsiloxane complexes, chloroplatinic acid-diketone complexes, black platinum, and platinum on support.

The catalyst (C) is preferably added from 0.1 to 1000 parts by weight, better still from 1 to 100 parts by weight, as clean platinum metal per 1000 parts by weight of the total amount of the compounds (A ) and B).

The elastomer is advantageously a non-emulsifying elastomer.

The term "non-emulsifying" defines organopolysiloxane elastomers not containing a hydrophilic chain, and in particular not containing polyoxyalkylene units (in particular polyoxyethylene or polyoxypropylene), or of polyglyceryl unit. Thus, according to a particular embodiment of the invention, the composition comprises an organopolysiloxane elastomer devoid of polyoxyalkylene units and of polyglyceryl unit.

In particular, the silicone elastomer used in the present invention is chosen from Dimethicone Crosspolymer (INCI name), Vinyl Dimethicone Crosspolymer (INCI name), Dimethicone / Vinyl Dimethicone Crosspolymer (INCI name), Dimethicone (and) Dimethicone / Vinyl Dimethicone Crosspolymer (INCI name), Dimethicone Crosspolymer-3 (INCI name).

Preferably, the silicone elastomer used in the present invention is chosen from Dimethicone (and) Dimethicone / Vinyl Dimethicone Crosspolymer.

The particles of organopolysiloxane elastomers can be conveyed in the form of a gel consisting of an elastomeric organopolysiloxane included in at least one hydrocarbon-based oil and / or a silicone oil. In these gels, the organopolysiloxane particles are often non-spherical particles.

Non-emulsifying elastomers are especially described in patents EP242219, EP285886, EP765656 and in application JP-A-61-194009.

The silicone elastomer is generally in the form of a gel, a paste or a powder but advantageously in the form of a gel in which the silicone elastomer is dispersed in a silicone oil linear (dimethicone) or cyclic (ex: cyclopentasiloxane), advantageously in a linear silicone oil.

As non-emulsifying elastomers, use may more particularly be made of those sold under the names "KSG-6", "KSG-15", "KSG-16", "KSG-18", "KSG-41", "KSG -42 "," KSG-43 "," KSG-44 ", by the company Shin Etsu," DC9040 "," DC9041 ", by the company Dow Corning," SFE 839 "by the company General Electric.

According to a particular embodiment, a silicone elastomer gel dispersed in a silicone oil is chosen chosen from a non-exhaustive list comprising cyclopentadimethylsiloxane, dimethicones, dimethylsiloxanes, methyl trimethicone, phenylmethicone, phenyldimethicone, phenyltrimethicone, and the cyclomethicone, preferably a linear silicone oil chosen from polydimethylsiloxanes (PDMS) or dimethicones with a viscosity at 25 ° C ranging from 1 to 500 and at 25 ° C, optionally modified by aliphatic groups, optionally fluorinated, or by functional groups such as hydroxyl, thiol and / or amine groups.

Mention may in particular be made of the following compounds of INCI name:

[0228] · Dimethicone / Vinyl Dimethicone Crosspolymer, such as "USG-105" and "USG-107A" from the company Shin Etsu; "DC9506" and "DC9701" from Dow Corning;

• Dimethicone / Vinyl Dimethicone Crosspolymer (and) Dimethicone, such as "KSG-6" and "KSG-16" from the company Shin Etsu;

• Dimethicone / Vinyl Dimethicone Crosspolymer (and) Cyclopentasiloxane, such as "KSG-15";

• Cyclopentasiloxane (and) Dimethicone Crosspolymer, such as "DC9040", "DC9045" and "DC5930" from the company Dow Corning;

• Dimethicone (and) Dimethicone Crosspolymer, such as "DC9041" from the company Dow Corning;

• Dimethicone (and) Dimethicone Crosspolymer, such as "Dow Corning EL-

9240® silicone elastomer blend ”from the company Dow Corning (mixture of crosslinked polydimethylsiloxane with hexadiene / polydimethysiloxane (2 cSt));

• C4-24 Alkyl Dimethicone / DivinylDimethicone Crosspolymer, such as

NuLastic Silk MA by the company Alzo.

As examples of silicone elastomers dispersed in a linear silicone oil which can advantageously be used according to the invention, mention may be made in particular of the following references:

Dimethicone / Vinyl Dimethicone Crosspolymer (and) Dimethicone, such as "KSG-6" and "KSG-16" from the company Shin Etsu;

• Dimethicone (and) Dimethicone Crosspolymer, such as "DC9041" from the company Dow Corning; and • Dimethicone (and) Dimethicone Crosspolymer, such as “Dow Corning EL9240® silicone elastomer blend” from the company Dow Corning (mixture of polydimethylsiloxane crosslinked by Hexadiene / Polydimethysiloxane (2 cSt)). According to a preferred embodiment, the composition according to the invention comprises at least one crosslinked silicone elastomer of INCI name "dimethicone crosspolymer" or "dimethicone (and) dimethicone crosspolymer", preferably with a dimethicone of viscosity ranging from 1 to 100 is, in particular from 1 to 10 is at 25 ° C., such as the mixture of Polydimethylsiloxane crosslinked by Hexadiene / Polydimethylsiloxane (5cst) marketed under the name DC 9041 by the company Dow Corning or the mixture of Polydimethylsiloxane crosslinked by Hexadiene / Polydimethylsiloxane (2cst) sold under the name EL-9240® by the company Dow Corning.

According to a particularly preferred embodiment, the composition according to the invention comprises at least one crosslinked silicone elastomer of INCI name "dimethicone (and) dimethicone crosspolymer", preferably with a dimethicone of viscosity ranging from 1 to 100 is, in particular from 1 to 10 is at 25 ° C., such as the mixture of Polydimethylsiloxane crosslinked with Hexadiene / Polydimethylsiloxane (5 cst) sold under the name DC 9041 by the company Dow Corning.

The particles of organopolysiloxane elastomers can also be used in powder form, mention may in particular be made of the powders sold under the names “Dow Corning 9505 Powder”, “Dow Corning 9506 Powder” by the company Dow Corning, these powders have the INCI name: dimethicone / vinyl dimethicone crosspolymer.

The organopolysiloxane powder can also be coated with silsesquioxane resin, as described for example in US patent 5,538,793. Such elastomer powders are sold under the names "KSP-100", "KSP-101", "KSP-102", "KSP-103", "KSP-104", "KSP-105" by the company Shin Etsu, and have the name INCI: vinyl dimethicone / methicone silsesquioxane Crosspolymer.

As examples of organopolysiloxane powders coated with silsesquioxane resin which can advantageously be used according to the invention, there may be mentioned in particular the reference "KSP-100" from the company Shin Etsu.

[0236] Such compounds can play the role of both a lipophilic gelling agent and a filler.

According to a first alternative embodiment, if the composition according to the invention comprises an organopolysiloxane powder coated with silsesquioxane resin, it only acts as a lipophilic gelling agent. According to such an alternative embodiment, a composition according to the invention comprises an organopolysiloxane powder coated with silsesquioxane resin as a lipophilic gelling agent, and optionally a separate charge from an organopolysiloxane powder coated with silsesquioxane resin.

According to a second alternative embodiment, if the composition according to the invention comprises an organopolysiloxane powder coated with silsesquioxane resin, it only plays a filler role. According to such an alternative embodiment, a composition according to the invention comprises, as lipophilic gelling agent, an organopolysiloxane elastomer distinct from an organopolysiloxane powder coated with silsesquioxane resin.

According to a third alternative embodiment, if the composition according to the invention comprises an organopolysiloxane powder coated with silsesquioxane resin, it plays a role of lipophilic gelling agent and filler.

As the preferred lipophilic gelling agent of the organopolysiloxane elastomer type, mention may be made in particular of the crosslinked organopolysiloxane elastomers chosen from Dimethicone Crosspolymer (INCI name), Dimethicone (and) Dimethicone Crosspolymer (INCI name), Vinyl Dimethicone Crosspolymer (INCI name), Dimethicone / Vinyl Dimethicone Crosspolymer (INCI name), Dimethicone (and) Dimethicone / Vinyl Dimethicone Crosspolymer, (INCI name), Dimethicone Crosspolymer-3 (INCI name), and in particular Dimethicone (and) Dimethicone / Vinyl Dimethicone Crosspolymer (INCI name).

Preferably, a composition according to the invention comprises as lipophilic agent at least one organopolysiloxane elastomer, and preferably organopolysiloxane powder coated with silsesquioxane resin, in particular which has the name INCI: vinyl dimethicone / methicone silsesquioxane Crosspolymer, and in particular that sold under the name "KSP-100" by the company Shin Etsu.

The organopolysiloxane elastomer may be present in a composition of the present invention at a content of between 0.1% and 35% by weight, in particular between 1% and 20% and more particularly between 2% and 10% by weight, relative to the total weight of the composition.

Aqueous phase

The aqueous phase of a composition according to the invention comprises water and optionally a water-soluble solvent.

By "water-soluble solvent" is meant in the present invention a compound liquid at room temperature and miscible with water (miscibility in water greater than 50% by weight at 25 ° C and atmospheric pressure).

The water-soluble solvents which can be used in the composition of the invention may also be volatile.

Among the water-soluble solvents that can be used in the composition according to the invention, there may be mentioned in particular lower monoalcohols having from 1 to 5 carbon atoms such as ethanol and isopropanol, glycols having from 2 to 8 carbon atoms such as ethylene glycol, propylene glycol, 1,3-butylene glycol and dipropylene glycol, C ₃ and C ₄ ketones and C ₂ -C ₄ aldehydes.

The aqueous phase may be present in the composition in a content ranging from 5% to 99%, better still from 30% to 95% by weight, preferably from 40% to 90% by weight, relative to the total weight of said composition.

According to another alternative embodiment, the aqueous phase of a composition according to the invention may comprise at least one C ₂ -C ₃₂ polyol.

By “polyol”, it is necessary to understand, within the meaning of the present invention, any organic molecule comprising at least two free hydroxyl groups.

Preferably, a polyol according to the present invention is present in liquid form at room temperature.

A polyol suitable for the invention may be an alkyl type compound, linear, branched or cyclic, saturated or unsaturated, bearing on the alkyl chain at least two -OH functions, in particular at least three -OH functions, and more particularly at least four -OH functions.

The polyols which are advantageously suitable for the formulation of a composition according to the present invention are those having in particular from 2 to 32 carbon atoms, preferably 3 to 16 carbon atoms.

Advantageously, the polyol can for example be chosen from ethylene glycol, pentaerythritol, trimethylolpropane, propylene glycol, 1,3-propanediol, butylene glycol, isoprene glycol, pentylene glycol, hexylene glycol, glycerol, polyglycerols, such as glycerol oligomers such as diglycerol, polyethylene glycols, and mixtures thereof.

According to a preferred embodiment of the invention, said polyol is chosen from ethylene glycol, pentaerythritol, trimethylolpropane, propylene glycol, dipropylene glycol, glycerol, polyglycerols, polyethylene glycols, and their mixtures .

According to a particular embodiment, the composition of the invention can comprise at least dipropylene glycol.

According to another particular mode, the composition of the invention can comprise at least glycerol.

Oily phase

Within the meaning of the invention, an oily phase comprises at least one oil.

The term "oil" means any fatty substance in liquid form at room temperature at atmospheric pressure.

An oily phase suitable for the preparation of the compositions, in particular cosmetic compositions according to the invention, can comprise hydrocarbon oils, silicone oils, fluorinated or not, or mixtures thereof.

The oils may be volatile or non-volatile.

They can be of animal, vegetable, mineral or synthetic origin. According to an alternative embodiment, oils of silicone origin are preferred.

For the purposes of the present invention, the term "non-volatile oil" means an oil having a vapor pressure of less than 0.13 Pa.

For the purposes of the present invention, the term "silicone oil" means an oil comprising at least one silicon atom, and in particular at least one Si-O group.

The term “fluorinated oil” means an oil comprising at least one fluorine atom. [0265] The term “hydrocarbon-based oil” means an oil mainly containing hydrogen and carbon atoms.

The oils can optionally include oxygen, nitrogen, sulfur and / or phosphorus atoms, for example, in the form of hydroxyl or acid radicals.

By “volatile oil” is meant, within the meaning of the invention, any oil capable of evaporating on contact with the skin in less than an hour, at ambient temperature and atmospheric pressure. Volatile oil is a volatile cosmetic compound, liquid at room temperature, in particular having a non-zero vapor pressure, at room temperature and atmospheric pressure, in particular having a vapor pressure ranging from 0.13 Pa to 40,000 Pa (10 ³ at 300 mm Hg), in particular ranging from 1.3 Pa to 13,000 Pa (0.01 to 100 mm Hg), and more particularly ranging from 1.3 Pa to 1,300 Pa (0.01 to 10 mm of Hg).

Volatile oils

The volatile oils can be hydrocarbon-based, or silicone-based.

Mention may in particular be made, among volatile hydrocarbon oils having from 8 to 16 carbon atoms, of branched C ₈ -C ₆ alkanes such as iso-alkanes (also called isoparaffins) of C ₈ -C ₆ , isododecane, isodecane, isohexadecane and for example the oils sold under the trade names of Isopars or Permyls, branched C ₈ -C ₆ esters such as isohexyl neopentanoate, and their mixtures. Preferably, the volatile hydrocarbon oil is chosen from volatile hydrocarbon oils having from 8 to 16 carbon atoms and their mixtures, in particular from isododecane, isodecane, isohexadecane, and is in particular isohexadecane.

Mention may also be made of volatile linear alkanes comprising from 8 to 16 carbon atoms, in particular from 10 to 15 carbon atoms, and more particularly from 11 to 13 carbon atoms, for example such as n-dodecane ( Ci ₂ ) and n-tetradecane (C _M ) sold by Sasol respectively under the references Parafol 12-97 and Parafol 14-97, as well as their mixtures, the undecane-tridecane mixture, the mixtures of n-undecane (Ch) and of n-tridecane (C _n ) obtained in Examples 1 and 2 of application WO 2008/155059 from the company Cognis, and their mixtures.

As volatile silicone oils, mention may be made of linear volatile silicone oils such as hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, tetradecamethylhexasiloxane, hexadecamethylheptasiloxane and dodecamethylpentasiloxane.

As cyclic silicone volatile oils, mention may be made of hexamethylcyclotrisiloxane, octamethylcylotetrasiloxane, decamethylcyclopentasiloxane, cyclohexasiloxane and dodecamethylcyclohexasiloxane, and in particular cyclohexasiloxane.

[0274] Non-volatile oils

The non-volatile oils can, in particular, be chosen from hydrocarbon-based, fluorinated oils and / or non-volatile silicone oils.

As non-volatile hydrocarbon-based oil, there may be mentioned in particular: [0277] · hydrocarbon-based oils of animal origin, • hydrocarbon-based oils of plant origin, synthetic ethers having from to 40 carbon atoms, such as dicapryl ether, • hydrocarbon oils of mineral or synthetic origin, in particular paraffin oil or its derivatives, petroleum jelly oil, naphthalene oil, polybutylenes, hydrogenated polyisobutylenes, decene / butene copolymers, polybutene / polyisobutene copolymers, hydrogenated polydecenes and polydecenes, and mixtures thereof, and preferably hydrogenated polyisobutene;

• synthetic esters, such as oils of formula RiCOOR ₂ , in which Ri represents a residue of a linear or branched fatty acid containing from 1 to 40 carbon atoms and R ₂ represents a hydrocarbon chain, in particular, branched containing 1 with 40 carbon atoms, provided that Ri + R ₂ is greater than or equal to 10. The esters can be, in particular, chosen from esters of alcohol and of fatty acid, such as, for example, ce tostearyl octanoate, esters of isopropyl alcohol, such as isopropyl myristate, isopropyl palmitate, ethyl palmitate, 2-ethylhexyl palmitate, isopropyl stearate, octyl stearate, hydroxylated esters, such as isostearyl lactate, octyl hydroxystearate, alcohol or polyalcohol ricinoleates, hexyl laurate, esters of neopentanoic acid, such as isodecyl neopentanoate, neopentanoate d 'isotridecyl, esters of isononanoic acid, such as isononyl isononanoate, isotridecyl isononanoate, • polyol esters and pentaerythritol esters, such as dipentaerythritol tetrahydroxystearate / tetraisostearate, • fatty alcohols at room temperature with branched carbon chain and / or unsaturated having from 12 to 26 carbon atoms , such as 2-octyldodecanol, isostearyl alcohol, oleic alcohol, • higher fatty acids in Ci ₂ -C ₂ 2, such as oleic acid, linoleic acid, linolenic acid, and mixtures thereof , • non-phenylated silicone oils, such as, for example, caprylyl methycone, and • phenylated silicone oils, such as, for example, phenyl trimethicones, phenyl dimethicones, phenyl trimethylsiloxy diphenylsiloxanes, diphenyl dimethicones, diphenyl methyldiphenyl and trisilox -phenylethyl trimethylsiloxysilicates, dimethicones or phenyltrimethicone with a viscosity less than or equal to 100 cSt, trimethylpentaphenyltrisiloxane, and their mixtures;

• as well as mixtures of these different oils.

A composition according to the invention may comprise from 5% to 95% by weight, better still from 10% to 70% by weight, preferably from 15% to 55% by weight of oil (s) relative to the weight total of said composition.

As specified above, the gelled oily phase according to the invention may have a threshold stress greater than 1.5 Pa and preferably greater than 10 Pa. This threshold stress value reflects a gel-like texture of this oily phase .

Adjuvants

Expenses

A composition according to the invention may also comprise at least one filler, and in particular a filler with a blurring effect or with a blurring effect.

By “fillers”, within the meaning of the present invention, it is understood to mean colorless or white particles, solid of all shapes, of mineral or organic nature, natural or synthetic, which are in an insoluble form and dispersed in the middle of the composition.

Of course, these fillers are used in the appropriate contents and conditions so as not to be detrimental to the compositions.

The blurring charges which can be used in the composition according to the invention are in particular characterized by a refractive index of between 1.33 and 2.

They will generally comprise or be made up of particles having a number average size less than or equal to 25 μm, in particular less than or equal to 20 μm, in particular less than or equal to 15 μm.

By “number-average size” is meant the dimension given by the statistical particle size distribution to half the population, called D50 measured with the MalvernMastersizer.

These particles can be of any shape and in particular be spherical or non-spherical.

Said filler (s) are present in whole or in part, and preferably only, in the gelled aqueous phase or are present in whole or in part, and preferably only, in the gelled oily phase. Preferably, they are present in the gelled aqueous phase.

In particular, the filler is chosen from powders of crosslinked elastomeric organopolysiloxane coated with silsesquioxane resin, powders of crosslinked elastomeric organopolysiloxane coated with hydrophilic silicone resin, polytetrafluoroethylene powders, polyurethane powders, polyurethane powders Carnauba, synthetic wax microcires, silicone resin powders, hollow hemispherical silicone particles, acrylic copolymer powders, vinylidene / acrylomtrile / methylene methacrylate expanded microspheres, polyethylene powders, in particular comprising at least one ethylene / acrylic acid copolymer, polymethyl methacrylate powders, crosslinked elastomeric organopolysiloxane powders, crosslinked elastomeric organopolysiloxane powders coated with silicone resin, starch powders, polyamide powders, silica powders and silicates, especially alumina, airgel hyd particles rophobic, talc of average size in number less than or equal to 3 microns, silica / TiO ₂ composites, barium sulfate particles, boron nitride particles, silica particles treated on the surface with a mineral wax 1 to 2%, amorphous silica microspheres, silica micro-beads, composite talc / TiO ₂ / alumina / silica powders, silicone elastomers, spherical cellulose beads, and their mixtures.

According to a particularly advantageous embodiment of the invention, the filler is a silicone filler, preferably a crosslinked elastomeric organopolysiloxane powder coated with silesquioxane resin.

[0291] The crosslinked elastomeric organopolysiloxane powder coated with hydrophilic silicone resin is generally called "hydrophilic treated", that is to say treated to make it hydrophilic.

Advantageously, to make the crosslinked elastomeric elastomeric organopolysiloxane powder hydrophilic coated with silicone resin, the latter is subjected to a treatment intended to combine at least one cationic polymer and advantageously at least one nonionic or cationic surfactant. . The cationic polymer with optionally the surfactant (s) and the crosslinked elastomeric organopolysiloxane powder can be combined by chemical bonds or by interactions in particular by Van der Waals bonds.

In particular, the crosslinked elastomeric organopolysiloxane powder coated with hydrophilic treated silicone resin is associated with at least one cationic polymer, preferably a quaternary ammonium polymer, in particular a polymer of INCI name "Polyquatemium" and optionally with at at least one ester of C ₈ C ₂₂ fatty acid and of polyoxyethylenated polyol, preferably from 2 to 20 moles of EO such as the esters of C ₈ -Ci ₈ fatty acid and of polyoxyethylenated glycerol of 3 to 15 moles of EO, preferably a polyoxyethylenated C ₈ -Ci ₈ glycol ester, more preferably a C ₈ -Ci ₈ fatty acid ester and polyoxyethylenated glycerol of 5 to 10 moles of EO.

[0294] According to one embodiment, the crosslinked elastomeric organopolysiloxane powder coated with hydrophilic treated silicone resin according to the invention is combined with at least one quaternary ammonium polymer, preferably chosen from polyquatemium-6 and polyquaternium -7, preferably polyquatemium-7. Polyquatemium-6 is a poly (diallyldimethylammonium chloride). Polyquatemium 7 is a copolymer of acrylamide and diallyldimethylammonium chloride.

Advantageously, the crosslinked elastomeric organopolysiloxane powder coated with silsesquioxane resin used as a filler in the compositions according to the invention corresponds to the INCI name: vinyl dimethicone / methicone silsesquioxane Crosspolymer. It is sold in particular under the reference "KSP-100" by the company Shin Etsu.

Advantageously, the crosslinked elastomeric organopolysiloxane powder coated with hydrophilic treated silicone resin, used as a filler in the compositions according to the invention corresponds to the INCI name vinyl dimethicone / methicone silsesquioxane crosspolymer treated with PEG-7 glyceryl cocoate, Polyquatemium-7 and methylsilanol tri-PEG-8 glyceryl cocoate. It is sold in particular under the reference “MW-SRP-100” by the company Miyoshi Kasei.

According to an alternative embodiment, a composition according to the invention can comprise from 0.2% to 40% by weight, in particular from 0.5% to 37% by weight, in particular from 2% to 15% by weight of filler (s), and in particular of crosslinked elastomeric organopolysiloxane powder coated with silicone resin, in particular vinyl dimethicone / methicone silsesquioxane Crosspolymer, relative to the total weight of said composition.

This type of fillers is particularly advantageous insofar as they allow blurring of imperfections. As indicated previously, the performance of these fillers is advantageously increased thanks to their use in a composition according to the invention.

The blurring effect is characterized by Haze and transparency measurements (TH transmission). The “Haze” corresponds to the percentage of light scattered relative to the total transmittance according to ASTM D 1003 (Standard Test Method for Haze and Luminous Transmittance of Transparent Plastics).

Films of 25 μm in composition are applied to polyethylene (PE) films of 50 μm. The film is then measured after one hour of drying at room temperature. Finally, the film is placed in the device and transparency and Haze measurements are taken.

[0301] According to a particular embodiment, in a composition according to the invention, the filler (s) are separate from the oily gelling agent (s).

According to another particular embodiment, in a composition according to the invention, the filler (s) are identical to the oily gelling agent (s).

Advantageously, a composition according to the invention can comprise, in addition to one or more fillers mentioned above, one or more charge (s) conventionally used in care and / or makeup compositions.

These additional fillers are colorless or white particles, solid of all shapes, which are in an insoluble form and dispersed in the medium of the composition.

Inorganic or organic, natural or synthetic in nature, they make it possible to give the composition containing them smoothness, mattness and uniformity to makeup.

In particular, such additional fillers may be present in a composition according to the invention in a content of between 0.5% and 10% by weight, in particular between 0.5% and 7% by weight, in particular between 0.5% and 5% by weight, relative to the total weight of the composition.

According to one embodiment of the invention, a composition can also comprise at least solid particles such as pigments and / or fillers.

Advantageously, a composition according to the invention can comprise from 0.01% to 45% by weight, in particular from 0.1% to 40% by weight, in particular from 1% to 35% by weight and preferably from 2% to 30% by weight of solid particles, relative to the total weight of the composition.

Dyestuffs

A composition according to the invention may also comprise at least one particular or non-particulate coloring matter, water-soluble or not, and preferably at a rate of at least 0.01% by weight, relative to the total weight of the composition .

For obvious reasons, this amount is likely to vary significantly with regard to the intensity of the desired color effect and the color intensity provided by the dyestuffs considered and its adjustment is clearly within the competence of man. art.

A composition according to the invention can comprise from 0.01% to 25% by weight, in particular from 0.1% to 25% by weight, in particular from 1% to 20% by weight, and preferably from 2 , 5% to 15% by weight of coloring matters, relative to the total weight of said composition.

As stated above, the coloring matters suitable for the invention may be water-soluble but also liposoluble.

[0314] By "water-soluble coloring matter", within the meaning of the invention, is meant any generally organic, natural or synthetic compound, soluble in an aqueous phase or solvents miscible with water and capable of coloring.

As water-soluble dyes suitable for the invention, mention may in particular be made of synthetic or natural water-soluble dyes such as for example FDC Red 4, DC Red 6, DC Red 22, DC Red 28, DC Red 30, DC Red 33, DC Orange 4, DC Yellow 5, DC Yellow 6, DC Yellow 8, FDC Green 3, DC Green 5, FDC Blue 1, betanin (beetroot), carmine , copper chlorophyllin, methylene blue, anthocyanins (enocianine, black carrot, hibiscus, elderberry), caramel, riboflavin.

The water-soluble dyes are, for example, beet juice and caramel.

By "liposoluble coloring matter", within the meaning of the invention, is meant any generally organic, natural or synthetic compound, soluble in an oily phase or solvents miscible with a fatty substance and capable of coloring.

As liposoluble dyes suitable for the invention, mention may in particular be made of liposoluble dyes, synthetic or natural, such as, for example, DC Red 17, DC Red 21, DC Red 27, DC Green 6, DC Yellow 11, DC Violet 2, DC Orange 5, Sudan red, carotenes (β-carotene, lycopene), xanthophylls (capsanthin, capsorubin, lutein), palm oil, Sudan brown, quinoline yellow, annatto, curcumin.

The coloring particulate materials may be present in an amount of 0.01% to 15% by weight, relative to the total weight of the composition containing them.

[0320] It can in particular be pigments, pearlescent agents and / or particles with metallic reflections.

By "pigments" is meant white or colored, mineral or organic particles, insoluble in an aqueous solution, intended to color and / or opacify the composition containing them.

A composition according to the invention can comprise from 0.01% to 25% by weight, in particular from 0.1% to 25% by weight, in particular from 1% to 25% by weight, and preferably from 2 , 5% to 15% by weight of pigments, relative to the total weight of said composition.

Preferably, when the composition according to the invention is a makeup composition, it can comprise at least 2.5%, and preferably at least 10% by weight of pigments, relative to the total weight of said composition.

The pigments can be white or colored, mineral and / or organic.

As mineral pigments which can be used in the invention, mention may be made of titanium, zirconium or cerium oxides or dioxides, as well as oxides of zinc, iron or chromium, ferric blue, manganese violet, ultramarine blue and chromium hydrate, and mixtures thereof.

It may also be a pigment having a structure which may, for example, be of the sericite / brown iron oxide / titanium dioxide / silica type. Such a pigment is sold, for example, under the reference Coverleaf NS or JS by the company Chemicals And Catalysts and has a contrast ratio close to 30.

It can also be pigments having a structure which can be, for example, of the silica microsphere type containing iron oxide. An example of a pigment having this structure is that sold by the company Miyoshi under the reference PC Ball PC-LL-100 P, this pigment being made up of silica microspheres containing yellow iron oxide.

Advantageously, the pigments according to the invention are iron oxides and / or titanium dioxides.

By “pearlescent agents”, it is necessary to understand colored particles of any shape, iridescent or not, in particular produced by certain molluscs in their shell or else synthesized, and which exhibit a color effect by optical interference.

[0330] A composition according to the invention can comprise from 0% to 15% by weight of nacres, and in particular from 0.01% to 15% by weight of nacres, relative to the total weight of said composition.

The nacres can be chosen from pearlescent pigments, such as titanium mica coated with an iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with an organic dye, as well as pearlescent pigments based on bismuth oxychloride. It can also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs.

[0332] One can also cite, by way of example of nacres, natural mica coated with titanium oxide, iron oxide, natural pigment or bismuth oxychloride.

Among the nacres available on the market, there may be mentioned the Timica, Flamenco and Duochrome nacres (based on mica) marketed by the company Engelhard, the Timiron nacres marketed by the company Merck, the nacres based on Prestige mica marketed by the company Eckart and the nacres based on Sunshine synthetic mica sold by the company Sun Chemical.

The pearlescent agents can more particularly have a yellow, pink, red, bronze, orange, brown, gold and / or coppery color or reflection.

Advantageously, the nacres in accordance with the invention are the micas coated with titanium dioxide or iron oxide as well as bismuth oxychloride.

By “metallic reflection particles”, within the meaning of the present invention, is meant any compound whose nature, size, structure and surface condition allows it to reflect the incident light in particular in a non-iridescent manner.

The particles with a metallic reflection which can be used in the invention are in particular chosen from:

The particles of at least one metal and / or at least one metal derivative;

• particles comprising a substrate, organic or inorganic, monomaterial or multimaterial, covered at least partially by at least one layer with metallic reflection comprising at least one metal and / or at least one metallic derivative; and • mixtures of said particles.

Among the metals which may be present in said particles, there may be mentioned for example Ag, Au, Cu, Al, Ni, Sn, Mg, Cr, Mo, Ti, Zr, Pt, Va, Rb, W, Zn, Ge, Te, Se and their mixtures or alloys. Ag, Au, Cu, Al, Zn, Ni, Mo, Cr, and their mixtures or alloys (e.g. bronzes and brasses) are preferred metals.

By “metallic derivatives”, we mean compounds derived from metals, in particular oxides, fluorides, chlorides and sulfides.

By way of illustration of these particles, mention may be made of aluminum particles, such as those sold under the names Starbrite 1200 EAC® by the company Siberline and Metalure® by the company Eckart and glass particles covered with a metallic layer, in particular those described in documents JP-A-09188830, JPA-10158450, JP-A-10158541, JP-A-07258460 and JP-A-05017710.

Hydrophobic treatment of dyestuffs

The pulverulent dyestuffs as described above can be treated on the surface, totally or partially, with a hydrophobic agent, to make them more compatible with the oily phase of the composition of the invention, in particular so that they have a good wettability with oils. Thus, these treated pigments are well dispersed in the oily phase.

Hydrophobic treated pigments are described in particular in document EP1086683.

The hydrophobic treatment agent can be chosen from silicones such as methicones, dimethicones, perfluoroalkylsilanes; fatty acids such as stearic acid; metallic soaps such as aluminum dimyristate, the aluminum salt of hydrogenated tallow glutamate; perfluoroalkyl phosphates; polyoxides of hexafluoropropylene; perfluoropolyethers; amino acids; N-acylated amino acids or their salts; lecithin, isopropyl trisostearyl titanate, isostearyl sebacate, and mixtures thereof.

The term alkyl mentioned in the compounds mentioned above denotes in particular an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 carbon atoms.

[0347] Polar additives

Advantageously, a composition according to the invention can also comprise one or more polar additive (s).

According to the present invention, the use of such a polar additive can in particular facilitate the homogenization of the dispersion in the presence of pigments.

The polar additive can be chosen from the compounds considered to be good donors or acceptors of hydrogen bonds, such as for example fatty alcohols, fatty acids, diols, esters and their mixtures.

[0351] According to one embodiment, the polar additives of the invention can be polar oils.

According to one embodiment, the polar additives of the invention can be amphiphilic compounds, comprising a lipophilic part linked to a polar part, for example chosen from esters, branched fatty alcohols in Ci ₂ to C ₂ 6 such as octyldodecanol, or silicone amphiphilic compounds. The polar additives of the invention can also be UV-B and / or UV-A filtering agents, the total quantity of filters possibly being between 0.01% and 10% by weight relative to the total weight of the composition.

A composition according to the invention can comprise from 0.01% to 10% by weight, in particular from 0.05% to 5% by weight, in particular from 0.05% to 1% by weight of additive ( s) polar (s).

Assets

A composition according to the invention may comprise at least one moisturizing agent (also called a humectant), in particular for a care application.

Preferably, the moisturizing agent is glycerin.

The moisturizing agent (s) may be present in the composition in a content ranging from 0.1% to 15% by weight, in particular from 0.5% to 10% by weight, or even from 1% to 6% by weight , relative to the total weight of said composition.

As other active agents which can be used in the composition of the invention, mention may, for example, be made of vitamins, sunscreens and their mixtures, and in particular vitamins such as tocopherol.

Preferably, a composition according to the invention comprises at least one active, in particular chosen from hydrating agents, preferably glycerin, vitamins, preferably tocopherol, and their mixtures.

[0360] According to a preferred embodiment, a composition according to the invention further comprises at least one active.

Preferably, the active ingredient is chosen from shea butter, sodium hyaluronate and their mixture.

[0362] Even more preferably, a composition according to the invention comprises sodium hyaluronate.

[0363] In addition, a composition according to the invention can comprise at least one dispersing agent.

It falls within the routine operations of a person skilled in the art to adjust the nature and the amount of additives present in the compositions in accordance with the invention, so that the desired cosmetic properties of these n are not affected. Destination of the composition

According to a preferred embodiment, a composition of the invention can advantageously be in the form of a composition for caring for the skin and / or keratin fibers, of the body or of the face, in particular of the face.

Preferably, a composition according to the invention is in the form of a composition for caring for the skin of the body or of the face, in particular of the face.

In particular, a composition of the invention may advantageously be in the form of an anti-aging care composition for the skin of the body or of the face, in particular of the face.

According to another embodiment, a composition of the invention can advantageously be in the form of a composition for making up the skin and / or keratin fibers, of the body or of the face, in particular of the face.

Thus, according to a sub-mode of this embodiment, a composition of the invention can advantageously be in the form of a base makeup composition for makeup. A composition of the invention can advantageously be in the form of a foundation.

According to another sub-mode of this embodiment, a composition of the invention can advantageously be in the form of a composition for making up the skin and in particular the face. It can be an eyeshadow or a blush.

According to yet another sub-mode of this embodiment, a composition of the invention can advantageously be in the form of a lip product, in particular a lipstick.

According to yet another sub-mode of this embodiment, a composition of the invention can be in the form of an eyelash product, in particular a mascara.

According to yet another sub-mode of this embodiment, a composition of the invention can advantageously be in the form of an eyebrow product, in particular an eyebrow pencil.

[0374] Such compositions are in particular prepared according to the general knowledge of those skilled in the art.

[0375] Throughout the description, including the claims, the expression "comprising a" must be understood as being synonymous with "comprising at least one", unless otherwise specified.

The expressions "comprised between ... and ...", "comprises from ... to ...", "formed from ... to ...", and "ranging from ... to. .. ”must be understood including limits, unless otherwise specified.

The invention is illustrated in more detail by the examples and figures presented below. Unless otherwise indicated, the quantities indicated are expressed in percentage by mass.

Methodology for the measurements of dynamic rheology in oscillation

These are rheological measurements in harmonic regime which ensure the measurement of the elastic modulus.

The measurements are carried out using a Haake RS600 type rheometer on a product at rest, at 25 ° C. with a movable plane plane 0 60 mm and an air gap of 2 mm.

The harmonic measurements make it possible to characterize the viscoelastic properties of the products. The technique consists in subjecting a material to a stress which varies sinusoidally over time and in measuring the response of the material to this stress. In a domain where the behavior is linear viscoelastic (zone where the deformation is proportional to the stress), the stress (τ) and the deformation (γ) are two sinusoidal functions of time which are written as follows:

[0382] [Math.l] τ (t) - το sin (ort)

[0383] [Math.2] γ (ΐ) = γο sin (ωΐ 4- δ)

Where:

· Τ ₀ represents the maximum amplitude of the constraint (Pa);

• Yo represents the maximum amplitude of the deformation (-);

• ω = 2ΠΝ represents the pulsation (rad.s') with N representing the frequency (Hz); and • ô represents the phase shift of the stress compared to the strain (rad). Thus, the two functions have the same angular frequency but they are phase shifted by an angle ô. Depending on the phase shift ô between rit) and y (t), the behavior of the system can be understood:

[0387] · If = = 0, the material is purely elastic;

• If δ = Π / 2, the material is purely viscous (Newtonian fluid); and • If 0 <δ <Π / 2, the material is viscoelastic.

[0388] In general, the stress and the deformation are written in complex form: [0389] [Math.3]

T * (t) = το e- ' ¹

[0390] [Math.4]

[0391] A complex stiffness modulus, representing the overall resistance of the material to deformation, whether of elastic or viscous origin, is then defined by:

[0392] [Math.5]

G * = τ * · 'γ * = G ’+ iG”

Where:

· G 'is the conservation module or elastic module which characterizes the energy stored and totally restored during a cycle, G' = (τ _ο / γο) cos ô; and • G ”is the loss module or viscous module which characterizes the energy dissipated by internal friction during a cycle, G” = (Το / γ _ο ) sin δ. The selected parameter is the average stiffness modulus G * taken from the plateau measured at a frequency of 1 Hz.

Examples

Example 1: Preparation of the dispersion of solid aggregates

Prior to the preparation of the compositions, a solid composition A formed from the following ingredients is prepared:

[0398]

[Tables 1]

Compounds Trade name Content (% by weight) Isopropyl lauroyl sarcosinate Eldew SL-205®, Ajinomoto 7.43 Caprylyl glycol Dermosoft® Octiol, Evomk Dr. Straétmans GmbH 1.63 Salicyijque capryloyl acid Mexoryl SAB. Chimex 2.23 Cetearyl ethylhexanoate (and) isopropyl myristate Dub Liquide 85 IP®, Stearinerie Dubois 13.00 Hydrogenated polyisobutene Parleam®, Nof Corporation 26.00 Glyceiyl dibehenale (53%) (and) tribehenin (30%) (and? Glyceryl behenate (17%) Compritoi 888 CG ATO®, Gattefosse 16.72 ' 4'isQeétyle stearate Isocetyl stearate, DUB SIS 16, Stearinerie Dubois 23.70 Shea tipper Lipex 204 TR®, Aarhuskarishamn 9.29

The preparation of composition A is carried out in a continuous twin-screw mixer, such as the "BC-21" model from the company CLEXTRAL, and is carried out under the following conditions:

[0400] · inlet temperature: 80 ° C;

• outlet temperature: 20 ° C;

• flow rate: 3 kg / h; and • screw speed: 600 rpm.

The previously melted waxes are introduced at the top of the mixer, at the same time as the oil, then the mixture is cooled under twin-screw mixing continuously until the outlet temperature.

Example 2: Preparation of compositions 1 to 5 according to the invention

The care compositions 1 to 5 according to the invention are prepared, from the weight proportions as detailed in the table below.

[0404]

[Paintings!]

Phase Compounds Foinmle ï TT Ώ IdlrT Ο-ί ^ £ Ît | TÈWÎT £ & 's ΐΉ? M ÎS JÈ 5 i © Aggregates ..... A. ; Dsapertdra of agents ^? ideas of 13.46 13.46 13.46 13.46 O. Phase B Sau Qsp 1G0 ISO Qsp ISO Qsp Οφ 100 Qsp 100 NïSnKS de Bere fBoiasNitiide Powder Ttes- BNPUHP 3002 „Sair: i: -Gob3.ai Ceramics) £ tS5 0, S5 0.8.5 0J5 0, S5 ^: Pheficxvsthaçol δ _; 6Τ , Μΰ 0, ® 0.60 0.60 Citric acid· 0.04 S, S4 0.04 0.04 0.04 Trâodium EÙiylèKftdiaiiiïsie diÆiK'CitlSæ 0.23 0.25 0.25 0.25 Adenosine & W 0.10 0.10 0.10 0.10 Ccp ^ hmêre Hs'dj'oxaéthylacnls.te. · 'Acn’scyldiœéthylteurate de sodtum ΕλΊΤ Κι reyprA S.72 M2 0.72 M2 0.72: GKcerine IMS 18, §8: 18J8 IMS IMS Hyalurotiate dé soditsm (C-ristsSiy al LÔ. Sclasce 0.11 Miss 0.11 0.11 0.11 Àismictsum Poly'aciydï ^ idsmethyi ijijraY · iHcstacem AMPS ’Clari anti M2. Polvaerylaîe de sodiutsi (Ccsæedsa SPÂBÀSF) 0.72 Polodacrylate de jodàim (Covacryl MV 6Â, Setssieal · 0.72 Carbcmer, Carb pclLTtrezlO Pdvmer \ Lubnacl’i 0:72 Axamomim Act- kt Idimethyl Tauœte T? Ccpohtuet (ArisfeSex AVC Clanantï 0.72 . DimêüiKone • KF-ÿ / L-ZCS '·. Shin Eïsei 1/72 1.72 1.72 1 :. ' ^? 2 1.72 Disnetlikeïse 'aad’i dsmeihtc <'. ne crc; .-pdytaffit (X-25KUH ShmEïsw w 8.00 8.00 8.00 S.00 D Parfùtsi iuO 0.10 0.10 0.10 0.10 Phase £ Cell se i CelhiicXesds USE. Daito Kasei Kost c j S _s 74 0 ^,? 4 0.74 0.74 0.74 Vtml dsmethicc-ræ Methicoue stlæstÿiiGXSHe croüpolynieî {KSP 100 ShmEteti! At 94 - ·> - 5.94 5.94 5.94 Titamum dioxide> and) JE-ca {I.riiîfcil · SilA Red. A & rdT £ 115 0.15 0.15 0.15 0.15 Msca'aad) TsmsusE dtcxide (Timka Terre White 5,1X4531 B ASF- 0.13 0.13 0.13 0.13 0.13 Methyl methacrylate crosspolymer {Ccvabead LH T SeiKientl 1.32 1.32 1.32 1.32 1.32

The hydrophilic phase B is prepared beforehand by adding each compound and homogenizing under Rayneri. The lipophilic phase C is prepared beforehand by adding each compound and homogenizing under Rayneri. Phases B and C and the corn46 position A are mixed and homogenized under Rayneri in order to disperse composition A in the form of solid aggregates. Phases D and E are then added to the mixture until homogenization and a smooth cream is obtained.

Example 3: Preparation of compositions 6 to 8 outside the invention

The care compositions 6 to 8 outside the invention are prepared, from the weight proportions as detailed in the table below, according to the same protocol used for compositions 1 to 5 of Example 2:

[0408] [Tables3]

Phase Compounds Forniul® 6 Formula Formula 8 Aggregates A Dispersion of solid aggregates of composition A. 13.46. 13.46 1.3.46 Phase B Water Q & p ίσα Qsp 100 Qsp 103 Nitnire Bore Island (Boron Nstisde Powder Ties BX PUHP 3002 ^s . Samt-Gobam Ceramics ï 0.85 0.85: 0.85 Phenoxy ethano i o, oo 0.60 '0.68 Citric acid 0.04 0.04 0.04 Trisodium Ethylenediamine disuccinate 0.25 <25 ^K ' 0.25 Adenostüe 0.10 0.10 0.10 Hvdroxy ethvlacrylate 'copolymer Sodium acrylovldmiethyltaurate (Sepinov EMT 10®. Seppic) 0.72 <72 ( 1.44 Glycerine 18.88 .18.88 18.88 Sodium hyaluronate. (Çristalhyal LO®. Schance) 0.11 0.1.1 0.1.1 Aerylate ” ^; This,'. Alkyl Acrylate crasspolymer (Pemulen TR-2®, Lubnzol) 0.72 PolyaciyLite Crcsspoiyrner-6 (Sepimax Zen®, Seppic) 0.72 Plisse C DiméAicone (KF-96L-2CS®, ShinEtsu) 1.72 1.72 1.7? Dimethicooe (and) dimethicone vmyl Jiœethiconé 'crosspôlyœéi · (X-25- “034H®, Shin Etait) 8.00 <00 8.00 Phase D Perfume 0.10 0.10 0.1.0 Phase E Cellulose i Cellidobeads USE, Daito · Kasei kogvo) 0.74 0.74 0.74 Vun 1 dimethicosie'Meihicone silsesquioxssie croçspcdvmer (KSP 100, ShinEtsu) 5.94 5.94 5.94 Titanium dioxide tand) mica. (Timiraii Silk Red. Merck j 0.15 0.15 0.1.5 Mica (imdh Titanium. Dioxide (Tunica Terra White MN4501, BASF) 0.13 0.13 0.13 Methvl methacrylate ercespdlymer (Covabeàd LH Seusientl 1.32 1.32 1.32

EXAMPLE 4 Evaluation of the Cosmetic Properties

The cosmetic properties of the compositions 1 to 5 according to the invention and the corn47 positions 6 to 8 outside the invention were evaluated.

[0410] Soft-focus measurement: Haze principle

The determination of the soft-focus is made by measuring the Haze and the transparency, that is to say the perception of light at wide angles.

[0412] Haze is an in vitro measure used to simulate the blurring effect of a formula after application. The Hazegard quantifies the visual perception of a cosmetic film after drying by objective measurements. It measures the intensity of the light passing through a sample. It separately measures direct transmittance (i.e. in the same direction as the incident ray) or hemispherical transmittance (in all directions in space, which is equivalent to total transmittance):

[0413] · Transmittance (T in%): Transparency per transmission, i.e. the amount of light that passes through the sample. If T = 100%, the sample is as transparent as air; if T = 0% the sample is completely opaque;

• Haze (H or SF in%): H = (T _diffused é / T _tota i) x 100, corresponding to the measurement of the blurring of a sample. If H = 100% all the light beams are deflected while if H = 0% no transmitted light beam is deflected.

The measurements are carried out using a Hazegard (Hazegard plus C®, BYK Gardner) on a 25 μm thick film, deposited on a PET film (PA-2871®, BYK10 Gardner). Three measurements are made at different locations on the film after 1 hour of drying at room temperature. The values are then averaged.

The soft focus results are presented in the table below:

[0416] [Tables4]

Composition Haze (%) Transmittance (%) Formula 1 92.5 +/- 0.5 86.8 +/- 0.3 Formula 2 97.2 +/- 1.5 87.3 +/- 0.3 Formula 3 83.9 +/- 1.1 88.2 +/- 0.4 Formula 4 92.4 +/- 0.3 86.4 +/- 0.3 Formula 5 82.7 +/- 1.9 88.4 +/- 0.5 Formula 6 75.3 +/- 1.2 87.9 +/- 0.1 Formula 7 74.1 +/- 1.01 89.2 +/- 0.1 Formula 8 76.7 +/- 0.4 88.2 +/- 0.7

Surprisingly, the compositions 1 to 5 in accordance with the invention, comprising the combination of two specific hydrophilic gelling agents according to the invention, exhibit better blurring performance (soft-focus) than compositions 6 to 8 except invention comprising a second hydrophilic gelling agent not in accordance with the present invention, or a single hydrophilic gelling agent.

In addition, compositions 1 to 5 in accordance with the invention exhibit very good masking performance with added shine, as well as good performance in terms of slipperiness and tackiness. They are easy to apply, are not very sticky and slippery. They have good playtime and leave a soft finish on the skin.

Compositions 1 to 5 according to the invention have very good emollient properties and comfort. In addition, they do not fluff.

Claims (1)

Claims [Claim 1] Composition, in particular cosmetic, in particular for making up and / or caring for keratin materials, comprising: at least one aqueous phase gelled with at least two distinct hydrophilic gelling agents, the first hydrophilic gelling agent being chosen from polymers and copolymers of 2-acrylamido 2-methylpropane sulfonic acid and the second hydrophilic gelling agent being chosen from polymers of 2-acrylamido-2-methylpropane sulfonic acid, copolymers of 2-acrylamido-2-methylpropane sulfonic acid and vinylpyrrolidone or vinylformarmide, sodium polyacrylates and crosslinked (meth) acrylic acid homopolymers; and at least one oily phase gelled with at least one lipophilic gelling agent chosen from organopolysiloxane elastomers; said phases forming therein a macroscopically homogeneous mixture; said composition further comprising a dispersion of solid aggregates, said aggregates being formed from 10% to 80% by weight of wax (es), relative to their total weight. [Claim 2] Composition according to Claim 1, in which the first hydrophilic gelling agent is chosen from copolymers of 2-acrylamido-2-methylpropane-sulfonic acid and of hydroxyethyl acrylate. [Claim 3] Composition according to any one of the preceding claims, in which the second hydrophilic gelling agent is chosen from crosslinked polymers of ammonium acrylamide-2-methyl propane sulfonate, 2-acrylamido-2-methylpropane-sulfonic acid copolymers and vinylpyrrolidone, poly sodium acrylates, in particular partially neutralized, and crosslinked acrylic acid homopolymers. [Claim 4] Composition according to any one of the preceding claims, comprising from 0.1% to 8% by weight, preferably from 0.2% to 5% by weight, and more preferably from 0.3% to 2% by weight, first hydrophilic gelling agent, relative to the total weight of the composition. [Claim 5] Composition according to any one of the preceding claims, comprising from 0.1% to 8% by weight, preferably from 0.2% to 5% by weight, and more preferably from 0.3% to 2% by weight, second hydrophilic gelling agent, relative to the total weight of the composition. [Claim 6] Composition according to any one of the preceding claims, comprising from 1% to 40% by weight, preferably from 2% to 35% by weight, and more preferably from 5% to 30% by weight, of solid aggregates relative to the total weight of the composition. [Claim 7] Composition according to any one of the preceding claims, in which the solid aggregates are formed from 10% to 50% by weight of wax (es), and preferably from 10% to 40% by weight of wax (es), relative to at their total weight. [Claim 8] Composition according to any one of the preceding claims, in which the wax or waxes are chosen from ester waxes. [Claim 9] Composition according to any one of the preceding claims, in which the wax or waxes are chosen from mixtures of esters of behenic acid and of glycerol. [Claim 10] Composition according to any one of the preceding claims, in which the said aggregates further comprise at least one non-volatile oil, in particular chosen from non-volatile nonpolar hydrocarbon oils, non-volatile ester oils and their mixtures. [Claim 11] Composition according to any one of the preceding claims, in which said aggregates have a size between 0.1 μιη and 100 μιη, preferably between 0.1 μιη and 10 μιη. [Claim 12] Composition according to any one of the preceding claims, in which said aggregates have, at 25 ° C and under atmospheric pressure, a hardness greater than 0.5 N, preferably greater than 2 N [Claim 13] Composition according to any one of the preceding claims, in which the said aggregates are dispersed in the gelled oily phase. [Claim 14] Composition according to any one of the preceding claims, in which the lipophilic gelling agent chosen from organopolysiloxane elastomers is chosen from Dimethicone Crosspolymer, Dimethicone (and) Dimethicone Crosspolymer, Vinyl Dimethicone Crosspolymer, Dimethicone / Vinyl Dimethicone Crosspolymer, Dimethicone ( and) Dimethicone / Vinyl Dimethicone Crosspolymer, Dimethicone Crosspolymer-3. [Claim 15] Composition according to any one of the preceding claims, in which the lipophilic gelling agent chosen from organopolysiloxane elastomers is chosen from Dimethicone (and) Dime thicone / Vinyl Dimethicone Crosspolymer. [Claim 16] Composition according to any one of the preceding claims, further comprising at least one active, and preferably sodium hyaluronate. [Claim 17] Composition according to any one of the preceding claims, for the care of the skin of the body or of the face, in particular of the face. [Claim 18] Cosmetic process for making up and / or caring for keratin materials, in particular the skin and / or lips, comprising at least one step of applying to said keratin materials a composition as defined according to any one of claims 1 to 17. FRENCH REPUBLIC