JPS61194009A - Makeup cosmetic - Google Patents
Makeup cosmeticInfo
- Publication number
- JPS61194009A JPS61194009A JP3338185A JP3338185A JPS61194009A JP S61194009 A JPS61194009 A JP S61194009A JP 3338185 A JP3338185 A JP 3338185A JP 3338185 A JP3338185 A JP 3338185A JP S61194009 A JPS61194009 A JP S61194009A
- Authority
- JP
- Japan
- Prior art keywords
- cured
- powder
- organopolysiloxane
- makeup cosmetic
- organopolysiloxane elastomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野1
本発明はメークアップ化粧料に間するものであり、さら
に詳しくはオルガノポリシロキサン粉体を含有してなる
メークアップ化粧料に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application 1] The present invention relates to make-up cosmetics, and more particularly to make-up cosmetics containing organopolysiloxane powder.
[従来の技術1
従来、メークアップ化粧料に使用される粉体としては、
タルク、カオリン、ベントナイト、無水ケイ酸、炭化ケ
イ素、アルミナ、酸化チタン、カーボンブラック、グラ
7フイト、黄酸化鉄、ベンガラ、マイカ、マイカチタン
、酸化ジルコニウム、セリサイト、カラミン、群青等の
無機顔料粉体が多く利用されている。[Conventional technology 1 Conventionally, powders used in makeup cosmetics include:
Inorganic pigment powders such as talc, kaolin, bentonite, silicic anhydride, silicon carbide, alumina, titanium oxide, carbon black, graphite, yellow iron oxide, red iron oxide, mica, mica titanium, zirconium oxide, sericite, calamine, ultramarine, etc. The body is used a lot.
また、ポリエチレン樹脂、ポリプロピレン樹脂 ゼ目7
≧L?j訂脂 マh書111.録l腸 柑lしV−ル樹
脂、エポキシ樹脂、ポリスチロール樹脂のような有機合
成樹脂を化粧料に添加した例も知られている(特開昭5
2−99236号公報参照)。In addition, polyethylene resin, polypropylene resin
≧L? J Revised Fat Mah Book 111. There are also known examples of adding organic synthetic resins such as resins, epoxy resins, and polystyrene resins to cosmetics (Japanese Patent Application Laid-Open No.
2-99236).
[発明が解決しようとする問題点1
しかしながら、上記したメークアップ化粧料用無機顔料
粉体は、色相の鮮明さ、着色力、透明性に欠けるという
欠点があった。また、該無機顔料粉体は一般に天然鉱物
を粉砕することにより製造されるが、粒子形状が不規則
であるために、メークアップ化粧料として塗擦時のなめ
らかさ、伸びに欠けるという欠点があった。[Problem to be Solved by the Invention 1] However, the above-mentioned inorganic pigment powder for make-up cosmetics has the drawbacks of lacking sharpness of hue, coloring power, and transparency. In addition, the inorganic pigment powder is generally manufactured by crushing natural minerals, but because the particle shape is irregular, it has the disadvantage that it lacks smoothness and spreadability when applied as a makeup cosmetic. .
また、有機合成樹脂粉体を化粧料に添加した場合でも自
然な色彩感を付与する効果はなかった。Further, even when organic synthetic resin powder was added to cosmetics, there was no effect of imparting a natural color feeling.
本発明は上記して欠点を解消することを目的とし、なめ
らかな塗擦感で、しっとりとした感触を有しかつ健康的
で自然な色彩感を付与することのできるメークアップ化
粧料を提供するものである。The present invention aims to eliminate the above-mentioned drawbacks, and provides a makeup cosmetic that has a smooth application feeling, a moist feel, and can impart a healthy and natural color feel. It is.
[問題点を解決するための手段および作用の説明]
上記した目的は、オルガノポリシロキサン硬化物粉体を
含有してなることを特徴とするメークアップ化粧料によ
り達成することができる。[Description of Means and Effects for Solving Problems] The above-mentioned object can be achieved by a makeup cosmetic characterized by containing a cured organopolysiloxane powder.
これを説明するに、本発明で使用されるオルガノポリシ
ロキサン硬化物粉体は、本発明メークアップ化粧料の肌
への塗擦感をなめらかにし、しっとり感を与え、かつ顔
料に対し鮮明な色相、着色力、透明性を付与し、健康的
な色彩感を与えるために必要な成分である。To explain this, the cured organopolysiloxane powder used in the present invention makes the makeup cosmetic of the present invention feel smooth when applied to the skin, gives a moist feeling, and has a clear hue and contrast to pigments. It is a necessary component to impart coloring strength and transparency, and to give a healthy color feel.
本成分のオルガノポリシロキサン硬化物粉体の原料とな
る硬化性オルff/ポリシロキサン組成物の種類は特に
限定されるものでなく、白金系触媒存在下に付加反応に
より硬化するオルガノポリシロキサンエラストマー組成
物、縮合反応により硬化するオルガノポリシロキサンエ
ラストマー組成物(ここで縮合反応として脱水、脱水素
、脱アルコール、脱オキシム、脱アミン、脱アミド、脱
カルボン酸、脱ケトンが例示される)、有機過酸化物に
より加熱上硬化するオルガノポリシロキサンエラストマ
ー組成物、γ線、紫外線もしくは電子線照射により硬化
するオルガノポリシロキサンエラストマー組成物あるい
は上記の各反応により硬化するオルガ/ポリシロキサン
レジ2組成物が例示される。The type of curable olff/polysiloxane composition that is the raw material for the cured organopolysiloxane powder of this component is not particularly limited, and is an organopolysiloxane elastomer composition that is cured by an addition reaction in the presence of a platinum catalyst. organopolysiloxane elastomer compositions that are cured by condensation reactions (herein, condensation reactions include dehydration, dehydrogenation, dealcoholization, deoxime, deaminerization, deamidation, decarboxylic acid, and deketoneization); Examples include organopolysiloxane elastomer compositions that are cured by heating with oxides, organopolysiloxane elastomer compositions that are cured by irradiation with gamma rays, ultraviolet rays, or electron beams, and organopolysiloxane resin compositions that are cured by each of the above reactions. Ru.
上述した硬化性オルガ/ポリシロキサ2組成物の主剤と
なるオルガノポリシロキサンのけい素原子に結合する有
機基として、は−価炭化水素基が例示され、これにはメ
チル基、エチル基、プロピル基、ブチル基、オクチル基
のようなアルキル基、ビニル基、アリルL 7’ロペニ
ル基のようなフルケニルL2−7二二ルエチル基、2−
フェニルプロピルL 3・3・3− ) ’) フルオ
ロプロピル基のような置換アルキル基、7エ二ル基、ト
リル基、キシリル基のようなアリール基、フェニルエチ
ル基のような置換アリール基あるいはエポキシ基、アミ
7基、水酸基、カルボキシル基、カルボン酸エステル基
らしくはメルカプト基を有する一価炭化水素基などが例
示される。As the organic group bonded to the silicon atom of the organopolysiloxane which is the main ingredient of the above-mentioned curable ORGA/POLYSILOXA 2 composition, a -valent hydrocarbon group is exemplified, and this includes a methyl group, an ethyl group, a propyl group, Alkyl group such as butyl group, octyl group, vinyl group, allyl L 7'Flukenyl group such as lopenyl group 2-722-ethyl group, 2-
Phenylpropyl L 3.3.3- ) ') Substituted alkyl groups such as fluoropropyl groups, aryl groups such as 7-enyl groups, tolyl groups, xylyl groups, substituted aryl groups such as phenylethyl groups, or epoxy Examples include a monovalent hydrocarbon group having a mercapto group, an amine group, a hydroxyl group, a carboxyl group, and a carboxylic acid ester group.
本成分は、上述したオルがノボリシロキサンを主剤とす
る熱硬化性組成物を熱気流中に噴霧し硬化させて粉体を
得る方法や、上述したオルガノポリシロキサンを主剤と
するエネルギー線硬化性組成物を高エネルギー照射下で
噴霧し硬化させて粉体を得る方法や、上述したオルガノ
ポリシロキサンを主剤とする熱硬化性組成物を加熱下あ
るいは上述したオルガノポリシロキサンを主剤とするエ
ネルギー線硬化性組成物をエネルギー線照射下で硬化さ
せたものをボールミル、アトマイザ−などの公知の粉砕
機により粉砕して粉体を得る方法等により製造すること
ができる。This component can be produced by the above-mentioned method of spraying a thermosetting composition containing novolisiloxane as the main ingredient and curing it into a hot air stream, or by using the energy ray-curable composition containing the above-mentioned organopolysiloxane as the main ingredient. A method of obtaining a powder by spraying and curing a substance under high-energy irradiation, a method of curing a thermosetting composition containing the above-mentioned organopolysiloxane as a main ingredient under heating, or an energy ray-curing method using the above-mentioned organopolysiloxane as a main ingredient. It can be produced by a method of obtaining a powder by curing a composition under energy ray irradiation and pulverizing it with a known pulverizer such as a ball mill or an atomizer.
本成分の粒度はsooミクロン以下であることが、本発
明のメークアップ化粧料になめらかさやしっとり感およ
び健康的で自然な色彩感を付与するに好ましく、より好
ましくは100ミクロン以下である。The particle size of this component is preferably less than 100 microns, more preferably less than 100 microns, in order to provide the makeup cosmetic of the present invention with a smooth, moist feel and a healthy, natural color.
本成分の配合量としては化粧料の使用形態により異なり
、特に限定されないが、プレス状メークアップ化粧料に
おいては1.0〜50重量%が好ましく、また、液状メ
ークアップ化粧料においては0.1〜30重量%が好ま
しい。The blending amount of this component varies depending on the usage form of the cosmetic and is not particularly limited, but it is preferably 1.0 to 50% by weight for pressed makeup cosmetics, and 0.1% for liquid makeup cosmetics. ~30% by weight is preferred.
本発明のメークアップ化粧料を得るにはオルJ#J−ム
−I+ −−シー 、息1、・、路lし& by H
ト・ 文6ψ1 和−& 拳、 トび結合油剤を
均一に分散配合することにより得ることができる。To obtain the make-up cosmetics of the present invention, the following steps are taken:
It can be obtained by uniformly dispersing and blending the binding oil.
顔料粉体としては、タルク、カオリン、炭酸カルシウム
、炭酸マグネシウム、ケイ酸マグネシウム、無水ケイ酸
のような体質顔料、酸化チタン、酸化亜鉛のような白色
顔料、ベン〃う、黄酸化鉄、酸化クロム、水酸化クロム
、カーボンブラック、群青のような無機着色顔料、ター
ル色素、紅花色素、β−カロチン、コチニール、クロロ
フィルのような有機着色顔料、魚鱗箔、オキシ塩化ビス
マス、雲母チタン、マイカのようなパール顔料などが例
示される。Pigment powders include talc, kaolin, calcium carbonate, magnesium carbonate, magnesium silicate, extender pigments such as silicic anhydride, white pigments such as titanium oxide, zinc oxide, benzene, yellow iron oxide, and chromium oxide. , inorganic coloring pigments such as chromium hydroxide, carbon black, ultramarine, organic coloring pigments such as tar pigment, safflower pigment, β-carotene, cochineal, chlorophyll, fish scale foil, bismuth oxychloride, titanium mica, mica. Examples include pearl pigments.
結合油剤としては、流動パラフィン、スクワラン、ワセ
リン、ポリイソブチレン、マイクロワックス、イソプロ
ピルミリステート、ミリスチルオクチルドデカノール、
シー(2−エチルヘキシル)サクシネート、ノイソオク
タン酸ネオペンチルグリコール、モノステアリン酸グリ
セリン、イソステアリン酸トリグリセライド、ヤシ油脂
肪酸トリグリセライド、ヒマシ油、エタノール、オクチ
ルドデカ/−ル、ヘキサデシルアルコール、セチルアル
コール、オレイル7ルコール、ステアリルアルコール、
ポリエチレングリコール、ウラリン酸、バルミチン酸、
オレイン酸、ステアリン酸、イソステアリン酸、ラノリ
ン、ミツロウ、オリーブ油のような炭化水素、エステル
、グリセライド、低級アルコール、高級アルコール、多
価アルコール、高級脂肪酸あるいはオルガ/ポリシロキ
サン流体などが例示される。Binding oil agents include liquid paraffin, squalane, petrolatum, polyisobutylene, micro wax, isopropyl myristate, myristyl octyl dodecanol,
Sea (2-ethylhexyl) succinate, neopentyl glycol noisooctanoate, glycerin monostearate, triglyceride isostearate, coconut oil fatty acid triglyceride, castor oil, ethanol, octyl dodecyl alcohol, hexadecyl alcohol, cetyl alcohol, oleyl 7 alcohol , stearyl alcohol,
Polyethylene glycol, uraric acid, valmitic acid,
Examples include oleic acid, stearic acid, isostearic acid, lanolin, beeswax, hydrocarbons such as olive oil, esters, glycerides, lower alcohols, higher alcohols, polyhydric alcohols, higher fatty acids, orga/polysiloxane fluids.
本発明のメークアップ化粧料には必要に応じて、さらに
水、界面活性剤、増粘剤、防腐剤、香料などを配合して
もよい。The makeup cosmetic of the present invention may further contain water, a surfactant, a thickener, a preservative, a perfume, etc., if necessary.
[実施例1 次に本発明を実施例により説明する。[Example 1 Next, the present invention will be explained by examples.
実施例中、部とあるのは重量部を意味する。In the examples, parts mean parts by weight.
実施例1
式
%式%
で示される両末端ジメチルビニルシリル基封鎖ジメチル
ポリシロキサン1()0部、式%式%)
で示される両末端トリメチルシリル基封鎖メチルハイド
ロジエンポリシロキサン3.5部、3−メチル−1−ブ
チン−3オール0.1部お上びオルガノポリシロキサン
全量に対し白金金属自体として10ppmとなるような
量の塩化白金酸イソプロパ/−ル溶液を均一に混合し、
150℃、2時間で硬化させた。このオルガ/ポリシロ
キサンエラストマー硬化物を7トマイザーで微細粉砕し
た。得られたオルガノポリシロキサン硬化物粉体は、走
査型電子顕微鏡の観察により1〜50ミクロンの粒径で
あることが確認された。Example 1 Dimethylpolysiloxane endblocked with dimethylvinylsilyl groups at both ends represented by the formula % Formula % 1 ( ) 0 parts, methylhydrodiene polysiloxane endblocked at both ends by trimethylsilyl groups represented by the formula % Formula % 3.5 parts, 3 - 0.1 part of methyl-1-butyn-3ol and a solution of isopropyl chloroplatinate in an amount such that the platinum metal itself is 10 ppm based on the total amount of organopolysiloxane,
It was cured at 150°C for 2 hours. This cured Olga/polysiloxane elastomer was finely pulverized using a 7tomizer. The obtained cured organopolysiloxane powder was confirmed to have a particle size of 1 to 50 microns by observation with a scanning electron microscope.
次にこのオルが7ポリシロキサン硬化物粉体を使用して
、第1表に示すような組成で油性アイライナーを製造し
た。また、オルガノポリシロキサン硬化物粉体を添加し
ないものを比較例。Next, using this polysiloxane cured product powder, oil-based eyeliner was manufactured with the composition shown in Table 1. In addition, a comparative example is one in which no organopolysiloxane cured product powder is added.
とした。And so.
これらの油性アイライナーを10人のパネラ−を用いて
塗布試験を行なったところ、本発明の油性アイライナー
は比較例に比べ、色に深みがあって鮮明なアイラインを
形成することができ、またしっとりとした感触を有して
おり塗擦感もなめらかであった。When these oil-based eyeliners were applied to a panel of 10 people, an application test was conducted, and it was found that the oil-based eyeliner of the present invention was able to form a clearer eyeline with deeper color than the comparative example. It also had a moist feel and felt smooth when rubbed.
実施例2
メチルトリメトキシシラン20部、シ゛メチルノメトキ
シシラン50部、トリメチルメトキシシラン20部およ
びテトラエチルシリケート3()部に1〕1目、0に調
整した塩酸水溶液500部を加えて5時間加水分解縮合
し、加熱乾燥させてオルガノポリシロキサンレジン硬化
物を得た。Example 2 To 20 parts of methyltrimethoxysilane, 50 parts of dimethylnomethoxysilane, 20 parts of trimethylmethoxysilane, and 3 ( ) parts of tetraethylsilicate, 500 parts of an aqueous hydrochloric acid solution adjusted to 1/1 and 0 was added and hydrolyzed for 5 hours. The mixture was condensed and dried by heating to obtain a cured organopolysiloxane resin.
次に二のオルガノポリシロキサンレジン硬化物を7Fマ
イザーで微細粉細した。得られたオルガノポリシロキサ
ンレジン硬化物粉体は走査型電子顕微鏡の観察により0
.5〜10ミクロンの粒径であることが確認された。Next, the second organopolysiloxane resin cured product was finely pulverized using a 7F mizer. The obtained organopolysiloxane resin cured powder was found to be 0 when observed with a scanning electron microscope.
.. A particle size of 5-10 microns was confirmed.
二のオルガノポリシロキサン硬化物粉体を第2表に示す
ような組成でファワンデーション(プレス成型物)を製
造した。また、オルガノポリシロキサン硬化物粉体を添
加しな(・ものを比較例とした。A fandation (press molded product) was produced using the second organopolysiloxane cured powder having the composition shown in Table 2. In addition, samples without the addition of organopolysiloxane cured product powder were used as comparative examples.
これらのファウンデーションを10人のパネラ−を用い
て塗布試験を行なったところ、本発明のファウンデーシ
ョンは比較例に比べ、健康的で自然な肌色を彩色するこ
とができ、またなめちかな泳楠感としっとりとしrこ感
触を有していた。When these foundations were applied to a panel of 10 people, an application test was conducted, and it was found that the foundation of the present invention was able to create a healthy and natural skin tone compared to the comparative example, and also had a smooth, silky texture. It had a moist and chewy feel.
第 1 表
第2表
[発明の効果1
本発明によれば、オル〃ノポリシロキサン硬化物粉体を
含有しているので、なめらがな塗擦感でしっとりとした
感触を有し、かつ、健康的で自然な色彩感を付与するこ
とのできるメークアンプ化粧料を提供することかで・き
る。Table 1 Table 2 [Effect of the invention 1 According to the present invention, since it contains the ornopolysiloxane cured product powder, it has a smooth and moist feeling when applied, and It is possible to provide a makeup amplifier cosmetic that can impart a healthy and natural color feeling.
Claims (1)
を特徴とするメークアップ化粧料。A makeup cosmetic characterized by containing organopolysiloxane cured powder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3338185A JPS61194009A (en) | 1985-02-21 | 1985-02-21 | Makeup cosmetic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3338185A JPS61194009A (en) | 1985-02-21 | 1985-02-21 | Makeup cosmetic |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61194009A true JPS61194009A (en) | 1986-08-28 |
JPH0417162B2 JPH0417162B2 (en) | 1992-03-25 |
Family
ID=12385015
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3338185A Granted JPS61194009A (en) | 1985-02-21 | 1985-02-21 | Makeup cosmetic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61194009A (en) |
Cited By (119)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6327410A (en) * | 1986-07-18 | 1988-02-05 | Hosokawa Micron Kk | Cosmetic |
WO1988003792A1 (en) * | 1986-11-18 | 1988-06-02 | Toray Silicone Co., Ltd. | Cosmetic material |
JPS63313710A (en) * | 1987-06-16 | 1988-12-21 | Toray Silicone Co Ltd | Face cleaning cosmetic |
JPH01207354A (en) * | 1987-10-15 | 1989-08-21 | Kobayashi Kose Co Ltd | Silicone gel composition and cosmetic containing said composition |
JPH01265008A (en) * | 1988-04-14 | 1989-10-23 | Nippon Chem Ind Co Ltd | Cosmetic |
US4892726A (en) * | 1987-05-29 | 1990-01-09 | Toshiba Silicon Co., Ltd. | Makeup or cosmetic compositions |
US4980167A (en) * | 1989-01-31 | 1990-12-25 | Dow Corning Toray Silicone Company, Ltd. | Silicone cosmetic composition |
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