JPH0634928B2 - プロセス内で再生可能な重質原油水素化転化用触媒および水素化転化方法 - Google Patents
プロセス内で再生可能な重質原油水素化転化用触媒および水素化転化方法Info
- Publication number
- JPH0634928B2 JPH0634928B2 JP1231327A JP23132789A JPH0634928B2 JP H0634928 B2 JPH0634928 B2 JP H0634928B2 JP 1231327 A JP1231327 A JP 1231327A JP 23132789 A JP23132789 A JP 23132789A JP H0634928 B2 JPH0634928 B2 JP H0634928B2
- Authority
- JP
- Japan
- Prior art keywords
- hydroconversion
- catalyst
- crude oil
- carrier material
- heavy crude
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims description 109
- 238000000034 method Methods 0.000 title claims description 48
- 239000010779 crude oil Substances 0.000 title claims description 44
- 239000011148 porous material Substances 0.000 claims description 60
- 238000006243 chemical reaction Methods 0.000 claims description 56
- 229910052751 metal Inorganic materials 0.000 claims description 41
- 239000002184 metal Substances 0.000 claims description 41
- 239000001257 hydrogen Substances 0.000 claims description 29
- 229910052739 hydrogen Inorganic materials 0.000 claims description 29
- 239000012071 phase Substances 0.000 claims description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 25
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 25
- 230000008569 process Effects 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 19
- 238000009826 distribution Methods 0.000 claims description 17
- 150000002739 metals Chemical class 0.000 claims description 16
- 239000003921 oil Substances 0.000 claims description 14
- 239000007790 solid phase Substances 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 125000002524 organometallic group Chemical group 0.000 claims description 12
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 239000002243 precursor Substances 0.000 claims description 11
- 239000000047 product Substances 0.000 claims description 10
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 8
- 230000000737 periodic effect Effects 0.000 claims description 7
- 239000012263 liquid product Substances 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 229910052570 clay Inorganic materials 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- -1 hexacarbonyl Chemical compound 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 125000005609 naphthenate group Chemical group 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 claims description 4
- 229940031826 phenolate Drugs 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 3
- 239000012876 carrier material Substances 0.000 claims 14
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 2
- 150000007942 carboxylates Chemical class 0.000 claims 2
- 238000011065 in-situ storage Methods 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 238000002474 experimental method Methods 0.000 description 27
- 230000000694 effects Effects 0.000 description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 229910052750 molybdenum Inorganic materials 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- 239000000571 coke Substances 0.000 description 7
- 239000000295 fuel oil Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 229910052742 iron Inorganic materials 0.000 description 7
- 239000008186 active pharmaceutical agent Substances 0.000 description 5
- 239000012018 catalyst precursor Substances 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 4
- 239000000969 carrier Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 238000004231 fluid catalytic cracking Methods 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 239000004489 contact powder Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003892 tartrate salts Chemical class 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- VWBLQUSTSLXQON-UHFFFAOYSA-N N.[V+5] Chemical class N.[V+5] VWBLQUSTSLXQON-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- DLAPQHBZCAAVPQ-UHFFFAOYSA-N iron;pentane-2,4-dione Chemical compound [Fe].CC(=O)CC(C)=O DLAPQHBZCAAVPQ-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- ARVBXAKTGHWMTM-UHFFFAOYSA-N molybdenum;pentane-2,4-dione Chemical compound [Mo].CC(=O)CC(C)=O ARVBXAKTGHWMTM-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 102200118166 rs16951438 Human genes 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 150000003657 tungsten Chemical class 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/240,638 US4888104A (en) | 1988-09-06 | 1988-09-06 | Catalytic system for the hydroconversion of heavy oils |
| US240,638 | 1988-09-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02111446A JPH02111446A (ja) | 1990-04-24 |
| JPH0634928B2 true JPH0634928B2 (ja) | 1994-05-11 |
Family
ID=22907335
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1231327A Expired - Lifetime JPH0634928B2 (ja) | 1988-09-06 | 1989-09-06 | プロセス内で再生可能な重質原油水素化転化用触媒および水素化転化方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4888104A (no) |
| JP (1) | JPH0634928B2 (no) |
| CA (1) | CA1332166C (no) |
| DE (1) | DE3929437C2 (no) |
| ES (1) | ES2016053A6 (no) |
| FR (1) | FR2636069B1 (no) |
| GB (1) | GB2222532B (no) |
| IT (1) | IT1232919B (no) |
| NL (1) | NL8902088A (no) |
| NO (1) | NO173881C (no) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4937218A (en) * | 1988-09-06 | 1990-06-26 | Intevep, S.A. | Catalytic system for the hydroconversion of heavy oils |
| US5484201A (en) * | 1992-01-31 | 1996-01-16 | Goolsbee; James A. | System for the recovery of oil and catalyst from a catalyst/oil mix |
| FR2704864B1 (fr) | 1993-05-06 | 1995-11-17 | Inst Francais Du Petrole | Procede d'hydroreformage catalytique. |
| FR2704774B1 (fr) * | 1993-05-06 | 1995-07-21 | Inst Francais Du Petrole | Procédé de préparation de catalyseurs applicables à la déshydrogénation. |
| FR2704865B1 (fr) * | 1993-05-06 | 1995-07-21 | Inst Francais Du Petrole | Procédé d'hydrogénation catalytique. |
| ATE296679T1 (de) * | 1998-12-08 | 2005-06-15 | Japan Energy Corp | Katalysator zur hydrodesulforierung und verfahren zu seiner herstellung |
| US20050133405A1 (en) * | 2003-12-19 | 2005-06-23 | Wellington Scott L. | Systems and methods of producing a crude product |
| US7737068B2 (en) | 2007-12-20 | 2010-06-15 | Chevron U.S.A. Inc. | Conversion of fine catalyst into coke-like material |
| US7790646B2 (en) | 2007-12-20 | 2010-09-07 | Chevron U.S.A. Inc. | Conversion of fine catalyst into coke-like material |
| US8722556B2 (en) | 2007-12-20 | 2014-05-13 | Chevron U.S.A. Inc. | Recovery of slurry unsupported catalyst |
| US8765622B2 (en) | 2007-12-20 | 2014-07-01 | Chevron U.S.A. Inc. | Recovery of slurry unsupported catalyst |
| JP2009160498A (ja) * | 2007-12-28 | 2009-07-23 | Jgc Catalysts & Chemicals Ltd | 水素化処理触媒の再生方法 |
| US8128811B2 (en) * | 2008-04-11 | 2012-03-06 | Exxonmobil Research And Engineering Company | Hydroprocessing using rejuvenated supported hydroprocessing catalysts |
| US8679322B2 (en) * | 2009-11-24 | 2014-03-25 | Intevep, S.A. | Hydroconversion process for heavy and extra heavy oils and residuals |
| US9168506B2 (en) * | 2010-01-21 | 2015-10-27 | Intevep, S.A. | Additive for hydroconversion process and method for making and using same |
| US8636967B2 (en) * | 2010-01-21 | 2014-01-28 | Intevep, S.A. | Metal recovery from hydroconverted heavy effluent |
| WO2018083715A1 (en) * | 2016-11-07 | 2018-05-11 | Hindustan Petroleum Corporation Limited | Process for producing lighter distillates |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3131142A (en) * | 1961-10-13 | 1964-04-28 | Phillips Petroleum Co | Catalytic hydro-cracking |
| US3271302A (en) * | 1964-06-17 | 1966-09-06 | Universal Oil Prod Co | Multiple-stage hydrorefining of petroleum crude oil |
| US3331769A (en) * | 1965-03-22 | 1967-07-18 | Universal Oil Prod Co | Hydrorefining petroleum crude oil |
| GB1229749A (no) * | 1968-04-04 | 1971-04-28 | ||
| US3657111A (en) * | 1970-02-24 | 1972-04-18 | Universal Oil Prod Co | Slurry process for hydrocarbonaceous black oil conversion |
| US3640817A (en) * | 1970-05-13 | 1972-02-08 | Universal Oil Prod Co | Hydrocarbonaceous black oil conversion process |
| US4341625A (en) * | 1973-08-09 | 1982-07-27 | Chevron Research Company | Method for preparing a catalyst carrier, a catalyst containing the carrier, and a hydrocarbon hydrodesulfurization process using the catalyst |
| JPS5857221B2 (ja) * | 1974-11-25 | 1983-12-19 | トウアネンリヨウコウギヨウ カブシキガイシヤ | スイソカシヨクバイ |
| CA1069486A (en) * | 1975-11-10 | 1980-01-08 | Nalco Chemical Company | Method of preparing a controlled pore volume alumina with citric acid |
| GB1561629A (en) * | 1975-12-10 | 1980-02-27 | Ici Ltd | Catalyst |
| US4051021A (en) * | 1976-05-12 | 1977-09-27 | Exxon Research & Engineering Co. | Hydrodesulfurization of hydrocarbon feed utilizing a silica stabilized alumina composite catalyst |
| US4066530A (en) * | 1976-07-02 | 1978-01-03 | Exxon Research & Engineering Co. | Hydroconversion of heavy hydrocarbons |
| US4226742A (en) * | 1978-07-14 | 1980-10-07 | Exxon Research & Engineering Co. | Catalyst for the hydroconversion of heavy hydrocarbons |
| US4225421A (en) * | 1979-03-13 | 1980-09-30 | Standard Oil Company (Indiana) | Process for hydrotreating heavy hydrocarbons |
| FR2456774A1 (fr) * | 1979-05-18 | 1980-12-12 | Inst Francais Du Petrole | Procede d'hydrotraitement d'hydrocarbures lourds en phase liquide en presence d'un catalyseur disperse |
| FR2486094B1 (no) * | 1980-07-02 | 1985-03-22 | Catalyse Soc Prod Francais | |
| US4399057A (en) * | 1981-06-17 | 1983-08-16 | Standard Oil Company (Indiana) | Catalyst and support, their methods of preparation, and processes employing same |
| US4376037A (en) * | 1981-10-16 | 1983-03-08 | Chevron Research Company | Hydroprocessing of heavy hydrocarbonaceous oils |
| GB2142930B (en) * | 1983-03-19 | 1987-07-01 | Asahi Chemical Ind | A process for cracking a heavy hydrocarbon |
| US4500424A (en) * | 1983-04-07 | 1985-02-19 | Union Oil Company Of California | Desulfurization catalyst and process |
| US4513098A (en) * | 1983-06-28 | 1985-04-23 | Mobil Oil Corporation | Multimetallic catalysts and their method of preparation from organometallic precursors |
| CA1217756A (en) * | 1983-08-10 | 1987-02-10 | Hri, Inc. | Demetallization catalyst and process for metals- containing hydrocarbon feedstocks |
| US4578180A (en) * | 1984-04-05 | 1986-03-25 | Phillips Petroleum Company | Hydrofining process for hydrocarbon containing feed streams |
| JPS6115739A (ja) * | 1984-04-25 | 1986-01-23 | Toa Nenryo Kogyo Kk | 水素化処理用触媒 |
| US4579646A (en) * | 1984-07-13 | 1986-04-01 | Atlantic Richfield Co. | Bottoms visbreaking hydroconversion process |
| US4659454A (en) * | 1984-12-21 | 1987-04-21 | Mobil Oil Corporation | Hydrocracking of heavy feeds plus light fractions with dispersed dual function catalyst |
| US4604189A (en) * | 1984-12-24 | 1986-08-05 | Mobil Oil Corporation | Hydrocracking of heavy feeds with dispersed dual function catalyst |
| US4604190A (en) * | 1985-04-29 | 1986-08-05 | Exxon Research And Engineering Co. | Hydrocracking with chromic acid and an aliphatic polyhydroxy compound |
| US4746419A (en) * | 1985-12-20 | 1988-05-24 | Amoco Corporation | Process for the hydrodemetallation hydrodesulfuration and hydrocracking of a hydrocarbon feedstock |
| US4657665A (en) * | 1985-12-20 | 1987-04-14 | Amoco Corporation | Process for demetallation and desulfurization of heavy hydrocarbons |
| US4701435A (en) * | 1986-04-07 | 1987-10-20 | Intevep, S.A. | Catalyst and method of preparation from a naturally occurring material |
| FR2598631B1 (fr) * | 1986-05-14 | 1988-11-25 | Total France | Catalyseur d'hydrotraitement d'hydrocarbures et application dudit catalyseur |
| US4729980A (en) * | 1987-04-27 | 1988-03-08 | Intevep, S.A. | Catalyst for the simultaneous hydrodemetallization and hydroconversion of heavy hydrocarbon feedstocks and process for preparing the catalyst |
-
1988
- 1988-09-06 US US07/240,638 patent/US4888104A/en not_active Expired - Lifetime
-
1989
- 1989-07-31 CA CA000607110A patent/CA1332166C/en not_active Expired - Fee Related
- 1989-08-01 NO NO893109A patent/NO173881C/no unknown
- 1989-08-14 ES ES8902861A patent/ES2016053A6/es not_active Expired - Lifetime
- 1989-08-17 NL NL8902088A patent/NL8902088A/nl not_active Application Discontinuation
- 1989-08-21 GB GB8919018A patent/GB2222532B/en not_active Expired - Fee Related
- 1989-09-05 FR FR8911590A patent/FR2636069B1/fr not_active Expired - Fee Related
- 1989-09-05 IT IT8967744A patent/IT1232919B/it active
- 1989-09-05 DE DE3929437A patent/DE3929437C2/de not_active Expired - Fee Related
- 1989-09-06 JP JP1231327A patent/JPH0634928B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| NO893109L (no) | 1990-03-07 |
| GB2222532B (en) | 1992-09-23 |
| US4888104A (en) | 1989-12-19 |
| GB8919018D0 (en) | 1989-10-04 |
| JPH02111446A (ja) | 1990-04-24 |
| DE3929437C2 (de) | 1997-12-04 |
| NL8902088A (nl) | 1990-04-02 |
| CA1332166C (en) | 1994-09-27 |
| ES2016053A6 (es) | 1990-10-01 |
| NO173881C (no) | 1994-02-16 |
| NO173881B (no) | 1993-11-08 |
| FR2636069A1 (fr) | 1990-03-09 |
| DE3929437A1 (de) | 1990-05-03 |
| NO893109D0 (no) | 1989-08-01 |
| GB2222532A (en) | 1990-03-14 |
| IT8967744A0 (it) | 1989-09-05 |
| FR2636069B1 (fr) | 1994-04-29 |
| IT1232919B (it) | 1992-03-05 |
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