JPH0578026B2 - - Google Patents
Info
- Publication number
- JPH0578026B2 JPH0578026B2 JP166784A JP166784A JPH0578026B2 JP H0578026 B2 JPH0578026 B2 JP H0578026B2 JP 166784 A JP166784 A JP 166784A JP 166784 A JP166784 A JP 166784A JP H0578026 B2 JPH0578026 B2 JP H0578026B2
- Authority
- JP
- Japan
- Prior art keywords
- color
- silver
- compound
- mol
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001875 compounds Chemical class 0.000 claims description 45
- 229910052709 silver Inorganic materials 0.000 claims description 44
- 239000004332 silver Substances 0.000 claims description 44
- 238000000034 method Methods 0.000 claims description 37
- -1 silver halide Chemical class 0.000 claims description 35
- 239000000463 material Substances 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 25
- 238000012545 processing Methods 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical group 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 46
- 239000000975 dye Substances 0.000 description 43
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 33
- 239000000839 emulsion Substances 0.000 description 26
- 238000011161 development Methods 0.000 description 23
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 19
- 239000000243 solution Substances 0.000 description 18
- 238000000354 decomposition reaction Methods 0.000 description 17
- 230000001235 sensitizing effect Effects 0.000 description 16
- 239000011575 calcium Substances 0.000 description 14
- 238000005406 washing Methods 0.000 description 14
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 239000002244 precipitate Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000002253 acid Substances 0.000 description 11
- 150000002443 hydroxylamines Chemical class 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 108010010803 Gelatin Proteins 0.000 description 10
- 229910052791 calcium Inorganic materials 0.000 description 10
- 229910001424 calcium ion Inorganic materials 0.000 description 10
- 239000008273 gelatin Substances 0.000 description 10
- 229920000159 gelatin Polymers 0.000 description 10
- 235000019322 gelatine Nutrition 0.000 description 10
- 235000011852 gelatine desserts Nutrition 0.000 description 10
- 238000004061 bleaching Methods 0.000 description 9
- 239000002738 chelating agent Substances 0.000 description 9
- 229910052742 iron Inorganic materials 0.000 description 9
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 8
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 7
- 229910021612 Silver iodide Inorganic materials 0.000 description 7
- 238000003672 processing method Methods 0.000 description 7
- 229940045105 silver iodide Drugs 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 6
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 6
- 239000007844 bleaching agent Substances 0.000 description 6
- 230000001680 brushing effect Effects 0.000 description 6
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 6
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 6
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 6
- 230000006641 stabilisation Effects 0.000 description 6
- 238000011105 stabilization Methods 0.000 description 6
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 5
- 239000000084 colloidal system Substances 0.000 description 5
- 229940125904 compound 1 Drugs 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- 229910001425 magnesium ion Inorganic materials 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- 150000001412 amines Chemical group 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 235000010265 sodium sulphite Nutrition 0.000 description 4
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 3
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 150000002505 iron Chemical class 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000019445 benzyl alcohol Nutrition 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- 150000001661 cadmium Chemical class 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 description 2
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 2
- 159000000014 iron salts Chemical class 0.000 description 2
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 2
- NPKFETRYYSUTEC-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide Chemical compound CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 NPKFETRYYSUTEC-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 150000004989 p-phenylenediamines Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229960003330 pentetic acid Drugs 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 235000011181 potassium carbonates Nutrition 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical group [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- ZRHUHDUEXWHZMA-UHFFFAOYSA-N 1,4-dihydropyrazol-5-one Chemical compound O=C1CC=NN1 ZRHUHDUEXWHZMA-UHFFFAOYSA-N 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- YGDWUQFZMXWDKE-UHFFFAOYSA-N 1-oxido-1,3-thiazole Chemical class [O-]S1=CN=C=C1 YGDWUQFZMXWDKE-UHFFFAOYSA-N 0.000 description 1
- WNOVBLHBCHOXKD-UHFFFAOYSA-N 2,3-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=C(O)C=CC(O)=C1C(C)(C)CC(C)(C)C WNOVBLHBCHOXKD-UHFFFAOYSA-N 0.000 description 1
- CLDZVCMRASJQFO-UHFFFAOYSA-N 2,5-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=C(C(C)(C)CC(C)(C)C)C=C1O CLDZVCMRASJQFO-UHFFFAOYSA-N 0.000 description 1
- JBAITADHMBPOQQ-UHFFFAOYSA-N 2-(1h-benzimidazol-2-yl)-1,3-thiazole Chemical compound C1=CSC(C=2NC3=CC=CC=C3N=2)=N1 JBAITADHMBPOQQ-UHFFFAOYSA-N 0.000 description 1
- QADPIHSGFPJNFS-UHFFFAOYSA-N 2-(1h-benzimidazol-2-ylmethyl)-1,3-thiazole Chemical compound N=1C2=CC=CC=C2NC=1CC1=NC=CS1 QADPIHSGFPJNFS-UHFFFAOYSA-N 0.000 description 1
- BIEFDNUEROKZRA-UHFFFAOYSA-N 2-(2-phenylethenyl)aniline Chemical group NC1=CC=CC=C1C=CC1=CC=CC=C1 BIEFDNUEROKZRA-UHFFFAOYSA-N 0.000 description 1
- QTLHLXYADXCVCF-UHFFFAOYSA-N 2-(4-amino-n-ethyl-3-methylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C(C)=C1 QTLHLXYADXCVCF-UHFFFAOYSA-N 0.000 description 1
- WFXLRLQSHRNHCE-UHFFFAOYSA-N 2-(4-amino-n-ethylanilino)ethanol Chemical compound OCCN(CC)C1=CC=C(N)C=C1 WFXLRLQSHRNHCE-UHFFFAOYSA-N 0.000 description 1
- JVXHQHGWBAHSSF-UHFFFAOYSA-L 2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;hydron;iron(2+) Chemical compound [H+].[H+].[Fe+2].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O JVXHQHGWBAHSSF-UHFFFAOYSA-L 0.000 description 1
- WYMDDFRYORANCC-UHFFFAOYSA-N 2-[[3-[bis(carboxymethyl)amino]-2-hydroxypropyl]-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)CN(CC(O)=O)CC(O)=O WYMDDFRYORANCC-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- MWGATWIBSKHFMR-UHFFFAOYSA-N 2-anilinoethanol Chemical compound OCCNC1=CC=CC=C1 MWGATWIBSKHFMR-UHFFFAOYSA-N 0.000 description 1
- NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical compound C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 description 1
- GCABLKFGYPIVFC-UHFFFAOYSA-N 3-(1-benzofuran-2-yl)-3-oxopropanenitrile Chemical compound C1=CC=C2OC(C(CC#N)=O)=CC2=C1 GCABLKFGYPIVFC-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical class C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- RMKRCLBDIMSFQB-UHFFFAOYSA-N 4-amino-2-benzylphenol Chemical compound NC1=CC=C(O)C(CC=2C=CC=CC=2)=C1 RMKRCLBDIMSFQB-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- PUOLMZVLZLRQBX-UHFFFAOYSA-N 4-n-(2-butan-2-yloxyethyl)-4-n-ethyl-2-methylbenzene-1,4-diamine Chemical compound CCC(C)OCCN(CC)C1=CC=C(N)C(C)=C1 PUOLMZVLZLRQBX-UHFFFAOYSA-N 0.000 description 1
- MTGIPEYNFPXFCM-UHFFFAOYSA-N 4-n-(2-ethoxyethyl)-4-n-ethyl-2-methylbenzene-1,4-diamine Chemical compound CCOCCN(CC)C1=CC=C(N)C(C)=C1 MTGIPEYNFPXFCM-UHFFFAOYSA-N 0.000 description 1
- MTOCKMVNXPZCJW-UHFFFAOYSA-N 4-n-dodecyl-4-n-ethyl-2-methylbenzene-1,4-diamine Chemical compound CCCCCCCCCCCCN(CC)C1=CC=C(N)C(C)=C1 MTOCKMVNXPZCJW-UHFFFAOYSA-N 0.000 description 1
- FFAJEKUNEVVYCW-UHFFFAOYSA-N 4-n-ethyl-4-n-(2-methoxyethyl)-2-methylbenzene-1,4-diamine Chemical compound COCCN(CC)C1=CC=C(N)C(C)=C1 FFAJEKUNEVVYCW-UHFFFAOYSA-N 0.000 description 1
- PZBQVZFITSVHAW-UHFFFAOYSA-N 5-chloro-2h-benzotriazole Chemical compound C1=C(Cl)C=CC2=NNN=C21 PZBQVZFITSVHAW-UHFFFAOYSA-N 0.000 description 1
- LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 1
- AOCDQWRMYHJTMY-UHFFFAOYSA-N 5-nitro-2h-benzotriazole Chemical compound C1=C([N+](=O)[O-])C=CC2=NNN=C21 AOCDQWRMYHJTMY-UHFFFAOYSA-N 0.000 description 1
- XPAZGLFMMUODDK-UHFFFAOYSA-N 6-nitro-1h-benzimidazole Chemical compound [O-][N+](=O)C1=CC=C2N=CNC2=C1 XPAZGLFMMUODDK-UHFFFAOYSA-N 0.000 description 1
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- FCKYPQBAHLOOJQ-UHFFFAOYSA-N Cyclohexane-1,2-diaminetetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)C1CCCCC1N(CC(O)=O)CC(O)=O FCKYPQBAHLOOJQ-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 101000618467 Hypocrea jecorina (strain ATCC 56765 / BCRC 32924 / NRRL 11460 / Rut C-30) Endo-1,4-beta-xylanase 2 Proteins 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- BZORFPDSXLZWJF-UHFFFAOYSA-N N,N-dimethyl-1,4-phenylenediamine Chemical compound CN(C)C1=CC=C(N)C=C1 BZORFPDSXLZWJF-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical class CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229940114081 cinnamate Drugs 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229940120503 dihydroxyacetone Drugs 0.000 description 1
- XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- VEPSWGHMGZQCIN-UHFFFAOYSA-H ferric oxalate Chemical compound [Fe+3].[Fe+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O VEPSWGHMGZQCIN-UHFFFAOYSA-H 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- WTNULKDCIHSVKN-UHFFFAOYSA-N imidazo[1,2-a]pyridin-2-ol Chemical compound C1=CC=CC2=NC(O)=CN21 WTNULKDCIHSVKN-UHFFFAOYSA-N 0.000 description 1
- PTFYQSWHBLOXRZ-UHFFFAOYSA-N imidazo[4,5-e]indazole Chemical compound C1=CC2=NC=NC2=C2C=NN=C21 PTFYQSWHBLOXRZ-UHFFFAOYSA-N 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002641 lithium Chemical group 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- XONPDZSGENTBNJ-UHFFFAOYSA-N molecular hydrogen;sodium Chemical compound [Na].[H][H] XONPDZSGENTBNJ-UHFFFAOYSA-N 0.000 description 1
- RGQFFQXJSCXIJX-UHFFFAOYSA-N n-[2-[2-amino-5-(diethylamino)phenyl]ethyl]methanesulfonamide Chemical compound CCN(CC)C1=CC=C(N)C(CCNS(C)(=O)=O)=C1 RGQFFQXJSCXIJX-UHFFFAOYSA-N 0.000 description 1
- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical class C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- FYWSTUCDSVYLPV-UHFFFAOYSA-N nitrooxythallium Chemical compound [Tl+].[O-][N+]([O-])=O FYWSTUCDSVYLPV-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 238000005691 oxidative coupling reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229930195143 oxyphenol Natural products 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical class N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
- 229940099427 potassium bisulfite Drugs 0.000 description 1
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- JVUYWILPYBCNNG-UHFFFAOYSA-N potassium;oxido(oxo)borane Chemical group [K+].[O-]B=O JVUYWILPYBCNNG-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- OENLEHTYJXMVBG-UHFFFAOYSA-N pyridine;hydrate Chemical compound [OH-].C1=CC=[NH+]C=C1 OENLEHTYJXMVBG-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- SOUHUMACVWVDME-UHFFFAOYSA-N safranin O Chemical compound [Cl-].C12=CC(N)=CC=C2N=C2C=CC(N)=CC2=[N+]1C1=CC=CC=C1 SOUHUMACVWVDME-UHFFFAOYSA-N 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 125000004436 sodium atom Chemical group 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000004328 sodium tetraborate Chemical group 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- NBOMNTLFRHMDEZ-UHFFFAOYSA-N thiosalicylic acid Chemical compound OC(=O)C1=CC=CC=C1S NBOMNTLFRHMDEZ-UHFFFAOYSA-N 0.000 description 1
- 229940103494 thiosalicylic acid Drugs 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/407—Development processes or agents therefor
- G03C7/413—Developers
Description
ïŒç£æ¥äžã®å©çšåéïŒ
æ¬çºæã¯ããã²ã³åéã«ã©ãŒæå
ææã®åŠçæ¹
æ³ã«é¢ãããæŽã«è©³ããè¿°ã¹ããšèããå®å®æ§ã
åäžããããã²ã³åéã«ã©ãŒæå ææã®åŠçæ¹æ³
ã«é¢ããã ïŒåŸæ¥æè¡ïŒ ããã²ã³åéã«ã©ãŒæå ææã®åŠçã«ãããŠã
ã«ã©ãŒçŸå液ã¯æå ææã®åçæ§ãå·Šå³ããéèŠ
ãªåœ¹å²ããæãããŠããã 該液äžã«ã¯äžè¬ã«ã«ãã©ãŒãšã«ãããªã³ã°ããŠ
è²çŽ ã圢æããè³éŠæ第äžçŽã¢ãã³çŸåäž»è¬ãå«
ãŸããŠãããã該ååç©ã¯ç©ºæ°äžã®é žçŽ ãããã¯
çŸå液äžã®éå±ã€ãªã³ã«ããçµæé žåãåçç¹æ§
ã«åœ±é¿ãåãŒããããæ ã«ã©ãŒçŸåäž»è¬ã®é žåé²
æ¢å€ãšããŠäºç¡«é žå¡©ãçšããŠããããšã¯åšç¥ã
ããäºç¡«é žå¡©ã¯è©²çŸåäž»è¬ãšã«ãã©ãŒãšã®ã«ãã
ãªã³ã°ãèããé»å®³ããããããã®äœ¿çšéã¯éå®
ãããé»çœçŸå液ã®ããã«å€éã«äœ¿çšããããšã¯
ã§ããªãã ãŸããç±³åœç¹èš±3141771å·ã«èšèŒã®ããã«ãäº
ç¡«é žå¡©ãšãšãã«ããããã·ã«ã¢ãã³é¡ãé žåé²æ¢
å€ãšããŠçšããããšãã§ããããããããããã
ã·ã«ã¢ãã³é¡ã¯ééå±ã€ãªã³ãäŸãã°éã€ãªã³ã
é ã€ãªã³ã®ååšã«ããèããå解ãä¿é²ããã¢ã³
ã¢ãã¢ãçæããåŸåãããããã®ããã«ããŠçº
çããã¢ã³ã¢ãã¢ã¯åšç¥ã®ããã«ã«ã©ãŒåçã®ç¹
æ§ã«æªåœ±é¿ãåãŒããããããããã·ã«ã¢ãã³é¡
ãçšããŠãã«ã©ãŒçŸå液ã®å®å®æ§ã¯äžå åã§ãã
ããšãå€ãã åãéã€ãªã³ã¯ã«ã©ãŒçŸå液ã®åŸæµŽã«ããæŒçœ
液ãæŒçœå®ç液ã®äž»æåãšããŠäœ¿çšãããŠããå Ž
åãå€ããã調液æãããã¯åŠçæãçŸå液ãžæ¯
èŒçå€éã«æ··å ¥ããæãã¬ã«ããªã®åå ã«ãªãã
ãšãããã ä»æ¹ã«ã©ãŒçŸå液ã¯PHïŒãPH12ã®ã¢ã«ã«ãªæ§ã
å¿ èŠãªããçé žãããã¢ãŒããªã³é žãããã¢ãŒã
䜿çšããŠããããšã¯åšç¥ã ããæ°Žäžã«ç±æ¥ããã«
ã«ã·ãŠã ã€ãªã³ããã°ãã·ãŠã ã€ãªã³ãããã¯æ
å ææãã溶åºããã«ã«ã·ãŠã ã€ãªã³ã¯è©²ããã
ã¢ãŒäžã§ã®æº¶è§£åºŠãèããäœãããã«ã«ã©ãŒçŸå
液äžã§çœè²æ²æŸ±ãçããæå ææã«ä»çãããèª
åçŸåæ©ã®ãã€ã«ã¿ãŒã®ç®ã¥ãŸããèµ·ãããšãã
åé¡ãçããããã該éå±ã€ãªã³ã®é°ãã€å€ãäž
å¯æ¬ ãšãªãã 以äžã®ããã«ã«ã©ãŒçŸå液ã«ãããŠã¯ãã«ã©ãŒ
çŸåäž»è¬ãããããã·ã«ã¢ãã³é¡çã®ææ©æåã®
å解ãé²æ¢ãããã€ãã«ã«ã·ãŠã ã€ãªã³ããã°ã
ã·ãŠã ã€ãªã³ã®é èœèœãå åã§ããæ§èœãå¿ èŠãš
ãªãã åŸæ¥ãã«ã©ãŒçŸåäž»è¬ãããããã·ã«ã¢ãã³é¡
ã®å解ãé²æ¢ããæ¹æ³ãšããŠã¯ãæ°å€ãæ瀺ãã
ãŠããã äŸãã°ãç¹éæ52â27638å·æ现æžèšèŒã®ãã
ãããµã é žãçšããæ¹æ³ãå52â49828å·æ现æž
èšèŒã®ãžããããã·ããã¿ã¬ã³ååç©ãçšããæ¹
æ³ãå52â102727å·æ现æžèšèŒã®ç³é¡ãçšããæ¹
æ³ãå54â3532å·æ现æžèšèŒã®ã¢ã«ã«ããŒã«ã¢ã
ã³ãçšããæ¹æ³ãå56â94349å·æ现æžèšèŒã®ã
ãªã¢ã«ãã¬ã³ã€ãã³ãçšããæ¹æ³ãå52â143020
å·åã³å53â89425å·æ现æžèšèŒã®Î±âã¢ããã«
ã«ããã«ååç©ãçšããæ¹æ³ãå56â75647å·å
ã³å55â41448å·æ现æžèšèŒã®ã°ã«ã³ã³é žã«ä»£è¡š
ããããªãã·ã«ã«ãã³é žãçšããæ¹æ³ãç±³åœç¹èš±
第3615503å·åã³è±åœç¹èš±ç¬¬1306176å·æ现æžèšèŒ
ã®ããããã·ã¢ã»ãã³ããžããããã·ã¢ã»ãã³ã
çšããæ¹æ³ãç±³åœç¹èš±ç¬¬3823017å·æ现æžèšèŒã®
ïŒâã¢ããªããšã¿ããŒã«ãçšããæ¹æ³ãç¹éæ56
â47038å·åã³å56â32140å·åã³ç±³åœç¹èš±ç¬¬
3746544å·æ现æžèšèŒã®è³éŠæããªããããã·å
åç©ãçšããæ¹æ³çå€ãã®æ¹æ³ãæ瀺ãããŠãã
ããããããã«ã©ãŒçŸå液ã®å®å®åãäžå åã§ã
ã€ãããååç©ãé«äŸ¡ã§ãã€ããã䜿çšéãå€ã
ã€ãããååç©èªèº«ãåçæ§ã«åœ±é¿ãäžãããã
å®çšäžæºè¶³ã§ããçµæã¯åŸãããŠããªãã ä»æ¹ãçŸå液ã«çšããããéå±ã€ãªã³é ãã€å€
ïŒãã¬ãŒãå€ïŒãšããŠã¯ãå€ãã®ååç©ãç¥ãã
ãŠããã ç¡æ©ãã¬ãŒãå€ãšããŠã¯ãããªããªãªã³é žãã
ãªãŠã ããããµã¡ã¿ãªã³é žãããªãŠã ãããã©ã
ãªãªã³é žãããªãŠã çãåšç¥ã§ããããã«ã«ã·ãŠ
ã ã®é ãã€èœãäœããã«ã©ãŒçŸå液ãçµæãããš
ã«ã«ã·ãŠã ã®æ²æŸ±ãçãããšããæ¬ ç¹ãæããŠã
ãã ã¢ããããªã«ã«ãã³é žç³»ãã¬ãŒãå€ãšããŠã¯ã
ãããªãäžé ¢é žããšãã¬ã³ãžã¢ãã³åé ¢é žããã
ããããããããã¯ã«ã«ã·ãŠã ã®é ãã€èœãäœ
ããåãã®éé¯äœèªèº«ããã«ã©ãŒçŸåäž»è¬ããã
ããã·ã«ã¢ãã³ã®å解èœãä¿é²ãããšããæ¬ ç¹ã
æããŠãããç±³åœç¹èš±2875049å·èšèŒã®ïŒïŒïŒâ
ãžã¢ãããããããŒã«åé ¢é žã¯æ°Žæº¶æ§ãäœããå
ã«ã«ã·ãŠã ã®é ãã€èœãäœãæºè¶³ã§ãããã®ã§ã¯
ãªããç¹éæ52â25632å·èšèŒã®ïŒïŒïŒâã·ã¯ã
ãããµã³ãžã¢ãã³âïŒïŒ®ïŒNâ²ïŒNâ²âåé ¢é žã
åã³å57â102624å·èšèŒã®ãã¹ããããã·ãšãã¬
ã³ãžã¢ãã³äºé ¢é žã¯ã«ã©ãŒçŸåäž»è¬ãããããã·
ã«ã¢ãã³ã®å解ãæ¯èŒçå°ãªãããã©ãã«ã«ã·ãŠ
ã ã®é ãã€èœã¯äœããåéåžžã«é«äŸ¡ãªååç©ã§ã
ããã«ã©ãŒçŸå液ã«äœ¿çšããã«ã¯å®çšçã§ãªãã
åãåŸè¿°ã®æ¬çºæã®äžè¬åŒïŒïŒã§ç€ºããããžãš
ãã¬ã³ããªã¢ãã³äºé ¢é žããããªãšãã¬ã³ããã©
ãã³å é ¢é žã¯ãç±³åœç¹èš±3462269å·çã«èšèŒãã
ãŠããããã«ã©ãŒçŸè±¡äž»è¬ãããããã·ã«ã¢ãã³
é¡ãå解é²æ¢å¹æã«ã€ããŠäžå åã§ããã ææ©ãã¹ãã³é žç³»ãã¬ãŒãå€ãšããŠã¯ã
Research Disclosure18170å·ãç¹éæ52â
102726å·ãå53â42730å·ãå56â97347å·ãå54
â121127å·ãå55â4024å·ãå55â4025å·ãå55
â29883å·ãå55â126241å·ãå55â65955å·ãå
55â659560å·ãå57â179843å·ãå54â61125å·ã
åã³è¥¿ç¬ç¹èš±1045373å·ã«èšèŒãããŠããããã
ãããã«ã«ã·ãŠã ã®é ãã€èœãäœãã€ããã«ã©ãŒ
çŸåäž»è¬ãããããã·ã«ã¢ãã³ã®å解é²æ¢ãäžå
åã§ãã€ãããé«äŸ¡ã§ãã€ããçã®çç±ã§å®çšã§
ãããã®ã§ã¯ãªãã åãåŸè¿°ã®äžè¬åŒïŒïŒã§ç€ºãããããããã·
ã¢ã«ããªãã³ãžãã¹ãã³é žã¯ãç±³åœç¹èš±3214454
å·çã«äŸç€ºãããŠãããã該ååç©ã¯ã«ã©ãŒçŸå
äž»è¬ãããããã·ã«ã¢ãã³ã®å解ãèããæå¶ã
ãããç±³åœç¹èš±3794591å·æ现æžèšèŒã®ããã«ã
ã«ã«ã·ãŠã ã€ãªã³åã³ãããªãŠã ã€ãªã³ãããã¯
ã«ãªãŠã ã€ãªã³ãšé£æº¶æ§ã®å¡©ãäœããšããæ¬ ç¹ã
ãããããæ²æŸ±çæã®é²æ¢æ段ãåæ¢ãããŠã
ããäŸãã°ç±³åœç¹èš±3794591å·æ现æžèšèŒã®ãã
ã«ãªããŠã ã€ãªã³ã䜵çšããæ¹æ³ããããããã
ãªããããªããŠã ã€ãªã³ã¯éåžžã«é«äŸ¡ã§ãããã
ã®äœ¿çšéã¯éå®ããããšåæã«ã該ãã¬ãŒãå€ã
ã«ã©ãŒçŸå液äžã®ã«ã«ã·ãŠã ã€ãªã³ããã°ãã·ãŠ
ã ã€ãªã³ãé ãã€ããã®ã«å åãªéã䜿çšãã
ã°ããã¯ãåèšæ²æŸ±ã¯çæããªããŠã ã€ãªã³ã®å¹
æãäžå åãªããšãå€ããæŽã«ãåèšæ²æŸ±é²æ¢ã®
å¥æ段ãšããŠã¯ãç±³åœç¹èš±3994730å·ã«è©²ãã¬ãŒ
ãå€ãä»ã®ã¢ããããªã«ã«ãã³é žåã¯ã¢ããããª
ãã¹ãã³é žãšäœµçšããæ¹æ³ãæ瀺ãããŠãããã
ãããªãã䜵çšãããã¬ãŒãå€çš®ã«ãã€ãŠã¯å å
ãªããããã·ã«ã¢ãã³å解é²æ¢èœãåŸãããããŸ
ãéã€ãªã³ã®æ··å ¥ã«ããã«ããªãé²æ¢ããããšã¯
ã§ããªããæŽã«ã䜵çšãããã¬ãŒãå€æ¿åºŠã«å¯Ÿã
ãŠäžè¬åŒïŒïŒã®ååç©ã®æ¿åºŠãéåžžã«é«ããšã
ããããã·ã«ã¢ãã³å解é²æ¢ãæŒçœæ¶²ãæŒçœå®ç
液ã®æ··å ¥ã«ããã«ããªé²æ¢ã®ç¹ã§åªããããå®é
äžçŸå液äžã«ååšããã«ã«ã·ãŠã ã€ãªã³ã®é ãã€
ã«ã¯äžå åã§ãããçµæãããšã«ã«ã·ãŠã ã€ãªã³
ã®æ²æŸ±ãçæãããåãäžè¬åŒïŒïŒã®ååç©ã®
æ¿åºŠãäœããšã«ã«ã·ãŠã ã€ãªã³ã®é ãã€ã®ç¹ã§ã¯
åªããããç¹ã«éã€ãªã³ã®æ··å ¥ã«ããã«ããªã倧
ããå®çšäžåé¡ãšãªãã 以äžã®ããã«ãã«ã©ãŒçŸå液ã®å®å®åãäŸã
ã°ãã«ã©ãŒçŸåäž»è¬ãããããã·ã«ã¢ãã³é¡ã®å
解ãé²æ¢ãããã€ãã«ã«ã·ãŠã ã€ãªã³ããã°ãã·
ãŠã ã€ãªã³ã®æ²æŸ±ãé²æ¢ãããã€ãéã€ãªã³ã®æ··
å ¥ã«ããã«ããªãé²æ¢ããæ¹æ³ã«é¢ããŠã¯ãããŸ
ã ã«å åã«æºè¶³ãã§ãããã€å®çšçãªæ段ã¯èŠã
åºãããŠããªãã ïŒçºæã®ç®çïŒ åŸã€ãŠæ¬çºæã®ç®çã¯ã第äžã«ã«ã©ãŒçŸåäž»è¬
ãããããã·ã«ã¢ãã³çã®ã«ã©ãŒçŸå液äžã®ææ©
æåããéãé ãªã©ã®ééå±ã€ãªã³ã®ååšã«ã
ããå解ãä¿é²ãããããšããå åã«ä¿è·ããã
ã«ã©ãŒçŸå液ãçšããŠã«ã©ãŒåçåãåŸãåçåŠ
çæ¹æ³ã®æäŸã«ããã æ¬çºæã®ç®çã¯ç¬¬äºã«ãã«ã«ã·ãŠã ã€ãªã³ãã
ã°ãã·ãŠã ã€ãªã³ã®ååšäžã«ãããŠããããéå±
ã€ãªã³ã®é ãã€èœãå åã«ãããã€æ²æŸ±ç©ãçœæ¿
ãçããããšã®ãªãã«ã©ãŒçŸå液ãšããããçšã
ãŠã«ã©ãŒåçåãåŸãåçåŠçæ¹æ³ã®æäŸã«ã
ãã æ¬çºæã®ç®çã¯ç¬¬äžã«ãéã€ãªã³ãå«æããæŒ
çœæ¶²ãæŒçœå®ç液ãæ··å ¥ããŠãã«ããªãçæãã
ããšã®ãªãã«ã©ãŒçŸå液ãçšããŠãã«ã©ãŒåçå
ãåŸãåçåŠçæ¹æ³ã®æäŸã«ããã ïŒçºæã®æ§æïŒ äžèšç®çã¯ãããã²ã³åéã«ã©ãŒæå ææã (1) è³éŠæ第äžçŽã¢ãã³ã«ã©ãŒçŸåäž»è¬åã³ã (2) äžèšäžè¬åŒïŒïŒã§è¡šããããå°ããšãäžçš®
ã®ååç©ãåã³ (3) äžèšäžè¬åŒïŒïŒã§è¡šããããå°ããšãäžçš®
ã®ååç© ãå«æãããã€ãïŒïŒã®ååç©ã«å¯ŸããŠïŒïŒ
ã®ååç©ã®æ¿åºŠãã¢ã«æ¯ã§3.0ã20åã«ãªããã
ã«å«æããã«ã©ãŒçŸå液ã«ãŠåŠçããããšã«ãã€
ãŠéæãããããšãèŠãåºããã æ¬çºæã®åŠããäžè¬åŒïŒïŒã®ååç©ã«å¯ŸããŠ
äžè¬åŒïŒïŒã®ååç©ã®å²åãèãã倧ãããã
ãšãçŸå液äžã®ããããã·ã«ã¢ãã³ã®å解ãé²æ¢
ã§ãããããŸãæŒçœæ¶²ãæŒçœå®ç液ã®çŸå液ãžã®
æ··å ¥ã«ããã«ããªã®é²æ¢ãå¯èœãšãªã€ãããšã¯ã
åŸæ¥ã®ç¥èŠããã¯ãŸã€ããäºæ³ãããªãã€ãããš
ã§ããã
æ³ã«é¢ãããæŽã«è©³ããè¿°ã¹ããšèããå®å®æ§ã
åäžããããã²ã³åéã«ã©ãŒæå ææã®åŠçæ¹æ³
ã«é¢ããã ïŒåŸæ¥æè¡ïŒ ããã²ã³åéã«ã©ãŒæå ææã®åŠçã«ãããŠã
ã«ã©ãŒçŸå液ã¯æå ææã®åçæ§ãå·Šå³ããéèŠ
ãªåœ¹å²ããæãããŠããã 該液äžã«ã¯äžè¬ã«ã«ãã©ãŒãšã«ãããªã³ã°ããŠ
è²çŽ ã圢æããè³éŠæ第äžçŽã¢ãã³çŸåäž»è¬ãå«
ãŸããŠãããã該ååç©ã¯ç©ºæ°äžã®é žçŽ ãããã¯
çŸå液äžã®éå±ã€ãªã³ã«ããçµæé žåãåçç¹æ§
ã«åœ±é¿ãåãŒããããæ ã«ã©ãŒçŸåäž»è¬ã®é žåé²
æ¢å€ãšããŠäºç¡«é žå¡©ãçšããŠããããšã¯åšç¥ã
ããäºç¡«é žå¡©ã¯è©²çŸåäž»è¬ãšã«ãã©ãŒãšã®ã«ãã
ãªã³ã°ãèããé»å®³ããããããã®äœ¿çšéã¯éå®
ãããé»çœçŸå液ã®ããã«å€éã«äœ¿çšããããšã¯
ã§ããªãã ãŸããç±³åœç¹èš±3141771å·ã«èšèŒã®ããã«ãäº
ç¡«é žå¡©ãšãšãã«ããããã·ã«ã¢ãã³é¡ãé žåé²æ¢
å€ãšããŠçšããããšãã§ããããããããããã
ã·ã«ã¢ãã³é¡ã¯ééå±ã€ãªã³ãäŸãã°éã€ãªã³ã
é ã€ãªã³ã®ååšã«ããèããå解ãä¿é²ããã¢ã³
ã¢ãã¢ãçæããåŸåãããããã®ããã«ããŠçº
çããã¢ã³ã¢ãã¢ã¯åšç¥ã®ããã«ã«ã©ãŒåçã®ç¹
æ§ã«æªåœ±é¿ãåãŒããããããããã·ã«ã¢ãã³é¡
ãçšããŠãã«ã©ãŒçŸå液ã®å®å®æ§ã¯äžå åã§ãã
ããšãå€ãã åãéã€ãªã³ã¯ã«ã©ãŒçŸå液ã®åŸæµŽã«ããæŒçœ
液ãæŒçœå®ç液ã®äž»æåãšããŠäœ¿çšãããŠããå Ž
åãå€ããã調液æãããã¯åŠçæãçŸå液ãžæ¯
èŒçå€éã«æ··å ¥ããæãã¬ã«ããªã®åå ã«ãªãã
ãšãããã ä»æ¹ã«ã©ãŒçŸå液ã¯PHïŒãPH12ã®ã¢ã«ã«ãªæ§ã
å¿ èŠãªããçé žãããã¢ãŒããªã³é žãããã¢ãŒã
䜿çšããŠããããšã¯åšç¥ã ããæ°Žäžã«ç±æ¥ããã«
ã«ã·ãŠã ã€ãªã³ããã°ãã·ãŠã ã€ãªã³ãããã¯æ
å ææãã溶åºããã«ã«ã·ãŠã ã€ãªã³ã¯è©²ããã
ã¢ãŒäžã§ã®æº¶è§£åºŠãèããäœãããã«ã«ã©ãŒçŸå
液äžã§çœè²æ²æŸ±ãçããæå ææã«ä»çãããèª
åçŸåæ©ã®ãã€ã«ã¿ãŒã®ç®ã¥ãŸããèµ·ãããšãã
åé¡ãçããããã該éå±ã€ãªã³ã®é°ãã€å€ãäž
å¯æ¬ ãšãªãã 以äžã®ããã«ã«ã©ãŒçŸå液ã«ãããŠã¯ãã«ã©ãŒ
çŸåäž»è¬ãããããã·ã«ã¢ãã³é¡çã®ææ©æåã®
å解ãé²æ¢ãããã€ãã«ã«ã·ãŠã ã€ãªã³ããã°ã
ã·ãŠã ã€ãªã³ã®é èœèœãå åã§ããæ§èœãå¿ èŠãš
ãªãã åŸæ¥ãã«ã©ãŒçŸåäž»è¬ãããããã·ã«ã¢ãã³é¡
ã®å解ãé²æ¢ããæ¹æ³ãšããŠã¯ãæ°å€ãæ瀺ãã
ãŠããã äŸãã°ãç¹éæ52â27638å·æ现æžèšèŒã®ãã
ãããµã é žãçšããæ¹æ³ãå52â49828å·æ现æž
èšèŒã®ãžããããã·ããã¿ã¬ã³ååç©ãçšããæ¹
æ³ãå52â102727å·æ现æžèšèŒã®ç³é¡ãçšããæ¹
æ³ãå54â3532å·æ现æžèšèŒã®ã¢ã«ã«ããŒã«ã¢ã
ã³ãçšããæ¹æ³ãå56â94349å·æ现æžèšèŒã®ã
ãªã¢ã«ãã¬ã³ã€ãã³ãçšããæ¹æ³ãå52â143020
å·åã³å53â89425å·æ现æžèšèŒã®Î±âã¢ããã«
ã«ããã«ååç©ãçšããæ¹æ³ãå56â75647å·å
ã³å55â41448å·æ现æžèšèŒã®ã°ã«ã³ã³é žã«ä»£è¡š
ããããªãã·ã«ã«ãã³é žãçšããæ¹æ³ãç±³åœç¹èš±
第3615503å·åã³è±åœç¹èš±ç¬¬1306176å·æ现æžèšèŒ
ã®ããããã·ã¢ã»ãã³ããžããããã·ã¢ã»ãã³ã
çšããæ¹æ³ãç±³åœç¹èš±ç¬¬3823017å·æ现æžèšèŒã®
ïŒâã¢ããªããšã¿ããŒã«ãçšããæ¹æ³ãç¹éæ56
â47038å·åã³å56â32140å·åã³ç±³åœç¹èš±ç¬¬
3746544å·æ现æžèšèŒã®è³éŠæããªããããã·å
åç©ãçšããæ¹æ³çå€ãã®æ¹æ³ãæ瀺ãããŠãã
ããããããã«ã©ãŒçŸå液ã®å®å®åãäžå åã§ã
ã€ãããååç©ãé«äŸ¡ã§ãã€ããã䜿çšéãå€ã
ã€ãããååç©èªèº«ãåçæ§ã«åœ±é¿ãäžãããã
å®çšäžæºè¶³ã§ããçµæã¯åŸãããŠããªãã ä»æ¹ãçŸå液ã«çšããããéå±ã€ãªã³é ãã€å€
ïŒãã¬ãŒãå€ïŒãšããŠã¯ãå€ãã®ååç©ãç¥ãã
ãŠããã ç¡æ©ãã¬ãŒãå€ãšããŠã¯ãããªããªãªã³é žãã
ãªãŠã ããããµã¡ã¿ãªã³é žãããªãŠã ãããã©ã
ãªãªã³é žãããªãŠã çãåšç¥ã§ããããã«ã«ã·ãŠ
ã ã®é ãã€èœãäœããã«ã©ãŒçŸå液ãçµæãããš
ã«ã«ã·ãŠã ã®æ²æŸ±ãçãããšããæ¬ ç¹ãæããŠã
ãã ã¢ããããªã«ã«ãã³é žç³»ãã¬ãŒãå€ãšããŠã¯ã
ãããªãäžé ¢é žããšãã¬ã³ãžã¢ãã³åé ¢é žããã
ããããããããã¯ã«ã«ã·ãŠã ã®é ãã€èœãäœ
ããåãã®éé¯äœèªèº«ããã«ã©ãŒçŸåäž»è¬ããã
ããã·ã«ã¢ãã³ã®å解èœãä¿é²ãããšããæ¬ ç¹ã
æããŠãããç±³åœç¹èš±2875049å·èšèŒã®ïŒïŒïŒâ
ãžã¢ãããããããŒã«åé ¢é žã¯æ°Žæº¶æ§ãäœããå
ã«ã«ã·ãŠã ã®é ãã€èœãäœãæºè¶³ã§ãããã®ã§ã¯
ãªããç¹éæ52â25632å·èšèŒã®ïŒïŒïŒâã·ã¯ã
ãããµã³ãžã¢ãã³âïŒïŒ®ïŒNâ²ïŒNâ²âåé ¢é žã
åã³å57â102624å·èšèŒã®ãã¹ããããã·ãšãã¬
ã³ãžã¢ãã³äºé ¢é žã¯ã«ã©ãŒçŸåäž»è¬ãããããã·
ã«ã¢ãã³ã®å解ãæ¯èŒçå°ãªãããã©ãã«ã«ã·ãŠ
ã ã®é ãã€èœã¯äœããåéåžžã«é«äŸ¡ãªååç©ã§ã
ããã«ã©ãŒçŸå液ã«äœ¿çšããã«ã¯å®çšçã§ãªãã
åãåŸè¿°ã®æ¬çºæã®äžè¬åŒïŒïŒã§ç€ºããããžãš
ãã¬ã³ããªã¢ãã³äºé ¢é žããããªãšãã¬ã³ããã©
ãã³å é ¢é žã¯ãç±³åœç¹èš±3462269å·çã«èšèŒãã
ãŠããããã«ã©ãŒçŸè±¡äž»è¬ãããããã·ã«ã¢ãã³
é¡ãå解é²æ¢å¹æã«ã€ããŠäžå åã§ããã ææ©ãã¹ãã³é žç³»ãã¬ãŒãå€ãšããŠã¯ã
Research Disclosure18170å·ãç¹éæ52â
102726å·ãå53â42730å·ãå56â97347å·ãå54
â121127å·ãå55â4024å·ãå55â4025å·ãå55
â29883å·ãå55â126241å·ãå55â65955å·ãå
55â659560å·ãå57â179843å·ãå54â61125å·ã
åã³è¥¿ç¬ç¹èš±1045373å·ã«èšèŒãããŠããããã
ãããã«ã«ã·ãŠã ã®é ãã€èœãäœãã€ããã«ã©ãŒ
çŸåäž»è¬ãããããã·ã«ã¢ãã³ã®å解é²æ¢ãäžå
åã§ãã€ãããé«äŸ¡ã§ãã€ããçã®çç±ã§å®çšã§
ãããã®ã§ã¯ãªãã åãåŸè¿°ã®äžè¬åŒïŒïŒã§ç€ºãããããããã·
ã¢ã«ããªãã³ãžãã¹ãã³é žã¯ãç±³åœç¹èš±3214454
å·çã«äŸç€ºãããŠãããã該ååç©ã¯ã«ã©ãŒçŸå
äž»è¬ãããããã·ã«ã¢ãã³ã®å解ãèããæå¶ã
ãããç±³åœç¹èš±3794591å·æ现æžèšèŒã®ããã«ã
ã«ã«ã·ãŠã ã€ãªã³åã³ãããªãŠã ã€ãªã³ãããã¯
ã«ãªãŠã ã€ãªã³ãšé£æº¶æ§ã®å¡©ãäœããšããæ¬ ç¹ã
ãããããæ²æŸ±çæã®é²æ¢æ段ãåæ¢ãããŠã
ããäŸãã°ç±³åœç¹èš±3794591å·æ现æžèšèŒã®ãã
ã«ãªããŠã ã€ãªã³ã䜵çšããæ¹æ³ããããããã
ãªããããªããŠã ã€ãªã³ã¯éåžžã«é«äŸ¡ã§ãããã
ã®äœ¿çšéã¯éå®ããããšåæã«ã該ãã¬ãŒãå€ã
ã«ã©ãŒçŸå液äžã®ã«ã«ã·ãŠã ã€ãªã³ããã°ãã·ãŠ
ã ã€ãªã³ãé ãã€ããã®ã«å åãªéã䜿çšãã
ã°ããã¯ãåèšæ²æŸ±ã¯çæããªããŠã ã€ãªã³ã®å¹
æãäžå åãªããšãå€ããæŽã«ãåèšæ²æŸ±é²æ¢ã®
å¥æ段ãšããŠã¯ãç±³åœç¹èš±3994730å·ã«è©²ãã¬ãŒ
ãå€ãä»ã®ã¢ããããªã«ã«ãã³é žåã¯ã¢ããããª
ãã¹ãã³é žãšäœµçšããæ¹æ³ãæ瀺ãããŠãããã
ãããªãã䜵çšãããã¬ãŒãå€çš®ã«ãã€ãŠã¯å å
ãªããããã·ã«ã¢ãã³å解é²æ¢èœãåŸãããããŸ
ãéã€ãªã³ã®æ··å ¥ã«ããã«ããªãé²æ¢ããããšã¯
ã§ããªããæŽã«ã䜵çšãããã¬ãŒãå€æ¿åºŠã«å¯Ÿã
ãŠäžè¬åŒïŒïŒã®ååç©ã®æ¿åºŠãéåžžã«é«ããšã
ããããã·ã«ã¢ãã³å解é²æ¢ãæŒçœæ¶²ãæŒçœå®ç
液ã®æ··å ¥ã«ããã«ããªé²æ¢ã®ç¹ã§åªããããå®é
äžçŸå液äžã«ååšããã«ã«ã·ãŠã ã€ãªã³ã®é ãã€
ã«ã¯äžå åã§ãããçµæãããšã«ã«ã·ãŠã ã€ãªã³
ã®æ²æŸ±ãçæãããåãäžè¬åŒïŒïŒã®ååç©ã®
æ¿åºŠãäœããšã«ã«ã·ãŠã ã€ãªã³ã®é ãã€ã®ç¹ã§ã¯
åªããããç¹ã«éã€ãªã³ã®æ··å ¥ã«ããã«ããªã倧
ããå®çšäžåé¡ãšãªãã 以äžã®ããã«ãã«ã©ãŒçŸå液ã®å®å®åãäŸã
ã°ãã«ã©ãŒçŸåäž»è¬ãããããã·ã«ã¢ãã³é¡ã®å
解ãé²æ¢ãããã€ãã«ã«ã·ãŠã ã€ãªã³ããã°ãã·
ãŠã ã€ãªã³ã®æ²æŸ±ãé²æ¢ãããã€ãéã€ãªã³ã®æ··
å ¥ã«ããã«ããªãé²æ¢ããæ¹æ³ã«é¢ããŠã¯ãããŸ
ã ã«å åã«æºè¶³ãã§ãããã€å®çšçãªæ段ã¯èŠã
åºãããŠããªãã ïŒçºæã®ç®çïŒ åŸã€ãŠæ¬çºæã®ç®çã¯ã第äžã«ã«ã©ãŒçŸåäž»è¬
ãããããã·ã«ã¢ãã³çã®ã«ã©ãŒçŸå液äžã®ææ©
æåããéãé ãªã©ã®ééå±ã€ãªã³ã®ååšã«ã
ããå解ãä¿é²ãããããšããå åã«ä¿è·ããã
ã«ã©ãŒçŸå液ãçšããŠã«ã©ãŒåçåãåŸãåçåŠ
çæ¹æ³ã®æäŸã«ããã æ¬çºæã®ç®çã¯ç¬¬äºã«ãã«ã«ã·ãŠã ã€ãªã³ãã
ã°ãã·ãŠã ã€ãªã³ã®ååšäžã«ãããŠããããéå±
ã€ãªã³ã®é ãã€èœãå åã«ãããã€æ²æŸ±ç©ãçœæ¿
ãçããããšã®ãªãã«ã©ãŒçŸå液ãšããããçšã
ãŠã«ã©ãŒåçåãåŸãåçåŠçæ¹æ³ã®æäŸã«ã
ãã æ¬çºæã®ç®çã¯ç¬¬äžã«ãéã€ãªã³ãå«æããæŒ
çœæ¶²ãæŒçœå®ç液ãæ··å ¥ããŠãã«ããªãçæãã
ããšã®ãªãã«ã©ãŒçŸå液ãçšããŠãã«ã©ãŒåçå
ãåŸãåçåŠçæ¹æ³ã®æäŸã«ããã ïŒçºæã®æ§æïŒ äžèšç®çã¯ãããã²ã³åéã«ã©ãŒæå ææã (1) è³éŠæ第äžçŽã¢ãã³ã«ã©ãŒçŸåäž»è¬åã³ã (2) äžèšäžè¬åŒïŒïŒã§è¡šããããå°ããšãäžçš®
ã®ååç©ãåã³ (3) äžèšäžè¬åŒïŒïŒã§è¡šããããå°ããšãäžçš®
ã®ååç© ãå«æãããã€ãïŒïŒã®ååç©ã«å¯ŸããŠïŒïŒ
ã®ååç©ã®æ¿åºŠãã¢ã«æ¯ã§3.0ã20åã«ãªããã
ã«å«æããã«ã©ãŒçŸå液ã«ãŠåŠçããããšã«ãã€
ãŠéæãããããšãèŠãåºããã æ¬çºæã®åŠããäžè¬åŒïŒïŒã®ååç©ã«å¯ŸããŠ
äžè¬åŒïŒïŒã®ååç©ã®å²åãèãã倧ãããã
ãšãçŸå液äžã®ããããã·ã«ã¢ãã³ã®å解ãé²æ¢
ã§ãããããŸãæŒçœæ¶²ãæŒçœå®ç液ã®çŸå液ãžã®
æ··å ¥ã«ããã«ããªã®é²æ¢ãå¯èœãšãªã€ãããšã¯ã
åŸæ¥ã®ç¥èŠããã¯ãŸã€ããäºæ³ãããªãã€ãããš
ã§ããã
ãåã
ãåã
åŒäžãïœã¯ïŒåã¯ïŒãè¡šãããã¯äœçŽã¢ã«ã
ã«åºïŒå¥œãŸããã¯ççŽ æ°ïŒãïŒã®ãã®ãäŸãã°ã¡
ãã«åºããšãã«åºãªã©ïŒãè¡šãããïŒã¯åäžã§ã
ç°ãªã€ãŠãè¯ããæ°ŽçŽ ååãã¢ã«ã«ãªéå±åå
ïŒãããªãŠã ååãã«ãªãŠã ååããªããŠã åå
ãªã©ïŒãŸãã¯ãã¢ã³ã¢ããŠã ãè¡šããã äžè¬åŒïŒïŒã§è¡šããããååç©ã®å ·äœäŸãšã
ãŠã¯ã次ã®ãã®ãæããããšãã§ããã
ã«åºïŒå¥œãŸããã¯ççŽ æ°ïŒãïŒã®ãã®ãäŸãã°ã¡
ãã«åºããšãã«åºãªã©ïŒãè¡šãããïŒã¯åäžã§ã
ç°ãªã€ãŠãè¯ããæ°ŽçŽ ååãã¢ã«ã«ãªéå±åå
ïŒãããªãŠã ååãã«ãªãŠã ååããªããŠã åå
ãªã©ïŒãŸãã¯ãã¢ã³ã¢ããŠã ãè¡šããã äžè¬åŒïŒïŒã§è¡šããããååç©ã®å ·äœäŸãšã
ãŠã¯ã次ã®ãã®ãæããããšãã§ããã
ãåã
ãåã
äžè¬åŒïŒïŒã§è¡šããããååç©ã®å
·äœäŸãšã
ãŠã¯ã次ã®ãã®ãæããããšãã§ããã
ãŠã¯ã次ã®ãã®ãæããããšãã§ããã
ãåã
ãåã
äžè¬åŒïŒïŒã®ååç©ã¯ãžãšãã¬ã³ããªã¢ãã³
âäºé ¢é žãããªãšãã¬ã³ããã©ãã³âå é ¢é žãªã©
ãšããŠç¥ãããŠãããååç©ã®æ·»å éã¯ã«ã©ãŒçŸ
å液ïŒåœã0.0001ã0.05ã¢ã«ã奜ãŸããã¯0.001
ã0.01ã¢ã«ã§ããã äžè¬åŒïŒïŒã®ååç©ã¯ïŒâããããã·ãšããª
ãã³âïŒïŒïŒâãžãã¹ãã³é žãªã©ãšããŠç¥ãããŠ
ãããååç©ã®æ·»å éã¯ã«ã©ãŒçŸå液ïŒåœãã
ååç©ïŒïŒã«å¯ŸããŠã¢ã«æ¯ã§ïŒã20åã§ããã
奜ãŸããã¯ïŒã15åããã奜ãŸããã¯ïŒã10åã§
ããã äžè¬åŒïŒïŒã®ååç©äžâïŒã奜ãŸãããäž
è¬åŒïŒïŒã®ååç©äžâïŒã奜ãŸããã æ¬çºæã«äœ¿çšãããè³éŠæ第äžçŽã¢ãã³ã«ã©ãŒ
çŸåäž»è¬ã¯å ¬ç¥ã§ãããæ°ã ã®ã«ã©ãŒçŸåããã»
ã¹ã«ãããŠãåºç¯ã«äœ¿çšãããŠããã奜ãŸããäŸ
ã¯ïœâããšãã¬ã³ãžã¢ãã³èªå°äœã§ãã代衚äŸã
以äžã«ç€ºããããããã«éå®ããããã®ã§ã¯ãª
ãã âïŒ ïŒ®ïŒïŒ®âãžãšãã«âïœâããšãã¬ã³ãžã¢
ã㳠âïŒ ïŒâã¢ããâïŒâãžãšãã«ã¢ãããã«ãš
㳠âïŒ ïŒâã¢ããâïŒâïŒïŒ®âãšãã«ââã©
ãŠãªã«ã¢ããïŒãã«ãšã³ âïŒ ïŒâãâãšãã«ââïŒÎ²âããããã·
ãšãã«ïŒã¢ãããã¢ããªã³ âïŒ ïŒâã¡ãã«âïŒâãâãšãã«ââïŒÎ²
âããããã·ãšãã«ïŒã¢ãããã¢ããªã³ âïŒ ïŒ®âãšãã«ââïŒÎ²âã¡ã¿ã³ã¹ã«ãã³
ã¢ãããšãã«ïŒâïŒâã¡ãã«âïŒâã¢ããã¢ã
ãªã³ âïŒ ïŒ®âïŒïŒâã¢ããâïŒâãžãšãã«ã¢ãã
ããšãã«ãšãã«ïŒã¡ã¿ã³ã¹ã«ãã³ã¢ãã âïŒ ïŒ®ïŒïŒ®âãžã¡ãã«âïœâããšãã¬ã³ãžã¢
ã㳠âïŒ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«â
âã¡ããã·ãšãã«ã¢ããªã³ â10 ïŒâã¢ããâïŒâã¡ãã«ââãšãã«â
âβâãšããã·ãšãã«ã¢ããªã³ â11 ïŒâã¢ããâïŒâã¡ãã«ââãšãã«â
âβâãããã·ãšãã«ã¢ããªã³ ãŸãããããã®ïœâããšãã¬ã³ãžã¢ãã³èªå°äœ
ã¯ç¡«é žå¡©ãå¡©é žå¡©ãäºç¡«é žå¡©ãïœâãã«ãšã³ã¹ã«
ãã³é žå¡©ãªã©ã®å¡©ã§ãã€ãŠããããäžèšååç©
ã¯ãç±³åœç¹èš±2193015å·ãå2552241å·ãå
2566271å·ãå2592364å·ãå3656950å·ãå
3698525å·çã«èšèŒãããŠããã該è³éŠæäžçŽã¢
ãã³çŸåäž»è¬ã®äœ¿çšéã¯çŸå溶液ïŒåœãçŽ0.1
ïœãçŽ20ïœãæŽã«å¥œãŸããã¯çŽ0.5ïœãçŽ10ïœã®
æ¿åºŠã§ããã æ¬çºæã§äœ¿çšãããã«ã©ãŒçŸå液äžã«ã¯ãåšç¥
ã®ããã«ããããã·ã«ã¢ãã³é¡ãå«ãããšã奜ãŸ
ããã ããããã·ã«ã¢ãã³é¡ã¯ãã«ã©ãŒçŸå液äžã«ã
ããŠéé¢ã¢ãã³ã®åœ¢ã§äœ¿çšããããšãã§ãããšã
ããã®ã®æ°Žæº¶æ§ã®é žå¡©ã®åœ¢ã§ããã䜿çšããã®ã
ããäžè¬çã§ããããã®ãããªå¡©é¡ã®äžè¬çãªäŸ
ã¯ãç¡«é žå¡©ãèé žå¡©ãå¡©åç©ãçé žå¡©ãçé žå¡©ã
é ¢é žå¡©ãã®ä»ã§ãããããããã·ã«ã¢ãã³é¡ã¯çœ®
æåã¯ç¡çœ®æã®ãããã§ãã€ãŠãããããããã
ã·ã«ã¢ãã³é¡ã®çªçŽ ååãã¢ã«ãã«åºã«ãã€ãŠçœ®
æãããŠããŠãããã奜ãŸããããããã·ã«ã¢ã
ã³é¡ã¯æ¬¡åŒã®ãããªååç©ã§ããã
âäºé ¢é žãããªãšãã¬ã³ããã©ãã³âå é ¢é žãªã©
ãšããŠç¥ãããŠãããååç©ã®æ·»å éã¯ã«ã©ãŒçŸ
å液ïŒåœã0.0001ã0.05ã¢ã«ã奜ãŸããã¯0.001
ã0.01ã¢ã«ã§ããã äžè¬åŒïŒïŒã®ååç©ã¯ïŒâããããã·ãšããª
ãã³âïŒïŒïŒâãžãã¹ãã³é žãªã©ãšããŠç¥ãããŠ
ãããååç©ã®æ·»å éã¯ã«ã©ãŒçŸå液ïŒåœãã
ååç©ïŒïŒã«å¯ŸããŠã¢ã«æ¯ã§ïŒã20åã§ããã
奜ãŸããã¯ïŒã15åããã奜ãŸããã¯ïŒã10åã§
ããã äžè¬åŒïŒïŒã®ååç©äžâïŒã奜ãŸãããäž
è¬åŒïŒïŒã®ååç©äžâïŒã奜ãŸããã æ¬çºæã«äœ¿çšãããè³éŠæ第äžçŽã¢ãã³ã«ã©ãŒ
çŸåäž»è¬ã¯å ¬ç¥ã§ãããæ°ã ã®ã«ã©ãŒçŸåããã»
ã¹ã«ãããŠãåºç¯ã«äœ¿çšãããŠããã奜ãŸããäŸ
ã¯ïœâããšãã¬ã³ãžã¢ãã³èªå°äœã§ãã代衚äŸã
以äžã«ç€ºããããããã«éå®ããããã®ã§ã¯ãª
ãã âïŒ ïŒ®ïŒïŒ®âãžãšãã«âïœâããšãã¬ã³ãžã¢
ã㳠âïŒ ïŒâã¢ããâïŒâãžãšãã«ã¢ãããã«ãš
㳠âïŒ ïŒâã¢ããâïŒâïŒïŒ®âãšãã«ââã©
ãŠãªã«ã¢ããïŒãã«ãšã³ âïŒ ïŒâãâãšãã«ââïŒÎ²âããããã·
ãšãã«ïŒã¢ãããã¢ããªã³ âïŒ ïŒâã¡ãã«âïŒâãâãšãã«ââïŒÎ²
âããããã·ãšãã«ïŒã¢ãããã¢ããªã³ âïŒ ïŒ®âãšãã«ââïŒÎ²âã¡ã¿ã³ã¹ã«ãã³
ã¢ãããšãã«ïŒâïŒâã¡ãã«âïŒâã¢ããã¢ã
ãªã³ âïŒ ïŒ®âïŒïŒâã¢ããâïŒâãžãšãã«ã¢ãã
ããšãã«ãšãã«ïŒã¡ã¿ã³ã¹ã«ãã³ã¢ãã âïŒ ïŒ®ïŒïŒ®âãžã¡ãã«âïœâããšãã¬ã³ãžã¢
ã㳠âïŒ ïŒâã¢ããâïŒâã¡ãã«ââãšãã«â
âã¡ããã·ãšãã«ã¢ããªã³ â10 ïŒâã¢ããâïŒâã¡ãã«ââãšãã«â
âβâãšããã·ãšãã«ã¢ããªã³ â11 ïŒâã¢ããâïŒâã¡ãã«ââãšãã«â
âβâãããã·ãšãã«ã¢ããªã³ ãŸãããããã®ïœâããšãã¬ã³ãžã¢ãã³èªå°äœ
ã¯ç¡«é žå¡©ãå¡©é žå¡©ãäºç¡«é žå¡©ãïœâãã«ãšã³ã¹ã«
ãã³é žå¡©ãªã©ã®å¡©ã§ãã€ãŠããããäžèšååç©
ã¯ãç±³åœç¹èš±2193015å·ãå2552241å·ãå
2566271å·ãå2592364å·ãå3656950å·ãå
3698525å·çã«èšèŒãããŠããã該è³éŠæäžçŽã¢
ãã³çŸåäž»è¬ã®äœ¿çšéã¯çŸå溶液ïŒåœãçŽ0.1
ïœãçŽ20ïœãæŽã«å¥œãŸããã¯çŽ0.5ïœãçŽ10ïœã®
æ¿åºŠã§ããã æ¬çºæã§äœ¿çšãããã«ã©ãŒçŸå液äžã«ã¯ãåšç¥
ã®ããã«ããããã·ã«ã¢ãã³é¡ãå«ãããšã奜ãŸ
ããã ããããã·ã«ã¢ãã³é¡ã¯ãã«ã©ãŒçŸå液äžã«ã
ããŠéé¢ã¢ãã³ã®åœ¢ã§äœ¿çšããããšãã§ãããšã
ããã®ã®æ°Žæº¶æ§ã®é žå¡©ã®åœ¢ã§ããã䜿çšããã®ã
ããäžè¬çã§ããããã®ãããªå¡©é¡ã®äžè¬çãªäŸ
ã¯ãç¡«é žå¡©ãèé žå¡©ãå¡©åç©ãçé žå¡©ãçé žå¡©ã
é ¢é žå¡©ãã®ä»ã§ãããããããã·ã«ã¢ãã³é¡ã¯çœ®
æåã¯ç¡çœ®æã®ãããã§ãã€ãŠãããããããã
ã·ã«ã¢ãã³é¡ã®çªçŽ ååãã¢ã«ãã«åºã«ãã€ãŠçœ®
æãããŠããŠãããã奜ãŸããããããã·ã«ã¢ã
ã³é¡ã¯æ¬¡åŒã®ãããªååç©ã§ããã
ãåã
äžåŒã«ãããŠïŒ²ã¯æ°ŽçŽ åååã¯ïŒãïŒåã®ççŽ
ååãæããã¢ã«ãã«åºïŒå¥œãŸããã¯çœ®æããŠã
ããççŽ ïŒãïŒã®ã¢ã«ãã«åºïŒãè¡šããã äžèšååç©ã¯æ°Žæº¶æ§é žå¡©ã§ãã€ãŠããããã
æ°ŽçŽ ååã®å Žåãç¹ã«å¥œãŸããã該ååç©ã®æ·»å
éã¯ã«ã©ãŒçŸå液ïŒåœã奜ãŸããã¯0.1ïœã20
ïœãæŽã«å¥œãŸããã¯ïŒïœã10ïœã§ããã æ¬çºæã«çšããããããããã·ã«ã¢ãã³ãšããŠ
ã¯å ·äœçã«ã¯äžèšã®ååç©ãæããããšãã§ã
ãã
ååãæããã¢ã«ãã«åºïŒå¥œãŸããã¯çœ®æããŠã
ããççŽ ïŒãïŒã®ã¢ã«ãã«åºïŒãè¡šããã äžèšååç©ã¯æ°Žæº¶æ§é žå¡©ã§ãã€ãŠããããã
æ°ŽçŽ ååã®å Žåãç¹ã«å¥œãŸããã該ååç©ã®æ·»å
éã¯ã«ã©ãŒçŸå液ïŒåœã奜ãŸããã¯0.1ïœã20
ïœãæŽã«å¥œãŸããã¯ïŒïœã10ïœã§ããã æ¬çºæã«çšããããããããã·ã«ã¢ãã³ãšããŠ
ã¯å ·äœçã«ã¯äžèšã®ååç©ãæããããšãã§ã
ãã
ãåã
ãåã
ãåã
ãåã
ãåã
æ¬çºæã«äœ¿çšãããã«ã©ãŒçŸå液ã¯ã奜ãŸãã
ã¯PHïŒã12ããã奜ãŸããã¯ïŒã11.0ã§ãããã
ã®ã«ã©ãŒçŸå液ã«ã¯ããã®ä»ã®æ¢ç¥ã®çŸå液æå
ã®ååç©ãå«ãŸããããšãã§ãããã äŸãã°ã¢ã«ã«ãªå€ãPHç·©è¡å€ãšããŠã¯èæ§ãœãŒ
ããèæ§ã«ãªãçé žãœãŒããçé žã«ãªã第ïŒãªã³
é žãœãŒãã第ïŒãªã³é žã«ãªãã¡ã¿ããŠé žã«ãªãã
ãŠç ãªã©ãåç¬åã¯çµã¿åããã§çšããããããŸ
ããç·©è¡èœãäžãããã調åäžã®éœåã®ãããã
ããã¯ã€ãªã³åŒ·åºŠãé«ãããããçã®ç®çã§ãã
ãã«ãªã³é žæ°ŽçŽ ïŒãããªãŠã åã¯ã«ãªããªã³é žïŒ
æ°ŽçŽ ã«ãªåã¯ãããªãŠã ãéçé žãœãŒãåã¯ã«
ãªãããŠé žãç¡é žã¢ã«ã«ãªãç¡«é žã¢ã«ã«ãªãªã©ã
çš®ã ã®å¡©é¡ã䜿çšãããã ã«ã©ãŒçŸå液ã«ã¯ãå¿ èŠã«ããä»»æã®çŸåä¿é²
å€ãæ·»å ã§ãããäŸãã°ç±³åœç¹èš±2648604å·ãç¹
å ¬æ44â9503å·ãç±³åœç¹èš±3171247å·ã§ä»£è¡šãã
ãåçš®ã®ããªããžãŠã ååç©ããã®ä»ã®ã«ããªã
ãã¯ååç©ãããšããµãã©ãã³ã®ãããªã«ããªã³
æ§è²çŽ ãç¡é žã¿ãªãŠã ãç¡é žã«ãªãŠã ã®åŠãäžæ§
å¡©ãç¹å ¬æ44â9304å·ãç±³åœç¹èš±2533990å·ãå
2531832å·ãå2950970å·ãå2577127å·èšèŒã®ã
ãªãšãã¬ã³ã°ãªã³ãŒã«ããã®èªå°äœãããªããªãš
ãŒãã«é¡ãªã©ã®ãããªã³æ§ååç©ãç¹å ¬æ44â
9509å·ããã«ã®ãŒç¹èš±682862å·èšèŒã®ææ©æº¶å€ã
ææ©ã¢ãã³ããšã¿ããŒã«ã¢ãã³ããšãã¬ã³ãžã¢ã
ã³ããžãšã¿ããŒã«ã¢ãã³ãªã©ããã®ã»ãL.F.A.
MasonèãPhotographic Processing
ChemistryãP40ã43ïŒFocal PressâLondonâ
1966ïŒã«èšè¿°ãããŠããä¿é²å€ãçšããããšãã§
ããããã®ã»ãç±³åœç¹èš±2515147å·ã«èšèŒã®ãã³
ãžã«ã¢ã«ã³ãŒã«ãããšãã«ãšãã«ã¢ã«ã³ãŒã«ãæ¥
æ¬åçåŠäŒèª14å·»ã74ããŒãžïŒ1952幎ïŒèšèŒã®ã
ãªãžã³ãããã©ãžã³ãã¢ãã³é¡ãªã©ãæçšãªçŸå
ä¿é²å€ã§ãããåç±³åœç¹èš±3201242å·èšèŒã®ããª
ãšãŒãã«ç³»ååç©ã䜿çšããŠãããããªãã§ãã
ç¹ã«ãšãã¬ã³ãžã¢ãã³ããã³ãžã«ã¢ã«ã³ãŒã«ãã
ãªãšãŒãã«ç³»ååç©ã奜ãŸããã ãŸããéåžžä¿æå€ãšããŠçšããããäºç¡«é žãœãŒ
ããäºç¡«é žã«ãªãéäºç¡«é žã«ãªåã¯éäºç¡«é žãœãŒ
ããå ããããšãã§ããã æ¬çºæã«ãããŠã«ã©ãŒçŸå液ã«ã¯å¿ èŠã«ããã
ä»»æã®ã«ããªé²æ¢å€ãæ·»å ã§ãããã«ããªé²æ¢å€
ãšããŠã¯èåã«ãªãŠã ãèåãããªãŠã ãæ²åã«
ãªãŠã ã®åŠãã¢ã«ã«ãªéå±ããã²ã³åç©åã³ææ©
ã«ããªé²æ¢å€ã䜿çšã§ãããææ©ã«ããªé²æ¢å€ãš
ããŠã¯ãäŸãã°ãã³ãŸããªã¢ãŸãŒã«ãïŒâããã
ãã³ãºã€ãããŸãŒã«ãïŒâãããã€ãœã€ã³ããŸãŒ
ã«ãïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã«ãïŒâããã
ãã³ãŸããªã¢ãŸãŒã«ãïŒâã¯ããâãã³ãŸããªã¢
ãŸãŒã«ãïŒâãã¢ãŸãªã«âãã³ãºã€ãããŸãŒã«ã
ïŒâãã¢ãŸãªã«ã¡ãã«âãã³ãºã€ãããŸãŒã«ãã
ãããã·ã¢ã¶ã€ã³ããªãžã³ã®åŠãå«çªçŽ ãããç°
ååç©åã³ïŒâããšãã«âïŒâã¡ã«ã«ããããã©
ãŸãŒã«ãïŒâã¡ã«ã«ãããã³ãºã€ãããŸãŒã«ãïŒ
âã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«ã®åŠãã¡ã«ã«ãã
眮æãããç°ååç©ãæŽã«ããªãµãªãã«é žã®åŠã
ã¡ã«ã«ãã眮æã®è³éŠæååç©ã䜿çšããããšã
ã§ãããç¹ã«å¥œãŸããã¯å«çªçŽ ãããç°ååç©ã§
ããããããã®ã«ããªé²æ¢å€ã¯ãåŠçäžã«ã«ã©ãŒ
æå ææäžãã溶åºããã«ã©ãŒçŸå液äžã«èç©ã
ãŠãããã å転ã«ã©ãŒåŠçã®å Žåã«ã¯ãã«ã©ãŒçŸå液äžã«
競äºã«ãã©ãŒãã«ãã©ã·å€ããã³è£åçŸåè¬ãå
ããããšãã§ããã 競äºã«ãã©ãŒãšããŠã¯ãã·ãã©ãžã³é žãïŒªé žã
ïŒšé žãªã©ãæçšã§ãããããšãã°ãç±³åœç¹èš±
2742832å·ãç¹å ¬æ44â9504å·ãå44â9506å·ã
å44â9507å·ãç±³åœç¹èš±3520690å·ãå3560212
å·ãå3645737å·çã«èšèŒãããååç©ãçšãåŸ
ãã ã«ãã©ã·å€ãšããŠã¢ã«ã«ãªéå±ãããã€ãã©ã€
ããã¢ãã³ãã©ã³ããšãã¬ã³ãžã¢ãã³ãªã©ãçšã
ãããšãã§ããããã®ä»ç¹å ¬æ47â38816å·ã«èš
èŒãããååç©ãçšããããšãã§ããã è£åçŸåè¬ãšããŠïœâã¢ããããšããŒã«ãâ
ãã³ãžã«âïœâã¢ããããšããŒã«ãïŒâããšãã«
âïŒâãã©ãŸãªãã³é¡ãªã©ãçšããããšãã§ã
ããããšãã°ç¹å ¬æ452â41475å·ãå46â19037
å·ã«èšèŒã®ååç©ã¯æçšã§ããã æ¬çºæã«äœ¿çšãããæŒçœæ¶²äžåã¯æŒçœå®ç液äž
ã«ã¯æŒçœå€ãšããŠéã€ãªã³ãå«æãããéã€ãªã³
ãšããŠã¯ãå¡©åéãèµ€è¡å¡©ã®ãããªç¡æ©éå¡©ãã¯
ãšã³é žéãã·ãŠãŠé žéã®ãããªææ©éå¡©ããšãã¬
ã³ãžã¢ãã³åé ¢é žéå¡©ã«ä»£è¡šããããããªã¢ãã
ããªã«ã«ãã³é žéé¯äœçããããããšãã§ãã
ãããããã«éå®ããããã®ã§ã¯ãªãã æ¬çºæã®ã«ã©ãŒåçåŠçæ¹æ³ã¯ãç±³åœç¹èš±
3227551å·ãå3227552å·ã«èšèŒã®åŠãæ¹æ³ãçšã
ãæ¡æ£è»¢åã«ã©ãŒåçæ³ã«çšããããšãã§ããã
ãã®å Žåã«ã¯ãã«ãã©ãŒã¯åŠçå·¥çšäžã«ä»ã®å±€ãž
æ¡æ£ããŠãããããåã¯æ¡æ£ããå¿ èŠãããã æ¬çºæã®åŠçæ¹æ³ã¯çºè²å€ãæå ææäžã«å«ãŸ
ããŠããå åçŸåæ¹åŒïŒç±³åœç¹èš±2376679å·ãå
2322027åã³å2801171å·ïŒã®ã»ããçºè²å€ãçŸå
液äžã«ååšããããããå€åçŸåæ¹åŒïŒç±³åœç¹èš±
2252718å·ãå2592243å·åã³å2590970å·ïŒã«ã
é©çšã§ããã åŸã€ãŠæ¬çºæã®åŠçæ¹æ³ã¯ã«ã©ãŒãã¬ãã€ã«
ã ãã«ã©ãŒããŒããŒãã«ã©ãŒããžãã€ã«ã ãã«ã©
ãŒå転ãã€ã«ã ãªã©ã®äžè¬çãªããã²ã³åéã«ã©
ãŒåçææã®ãããã®åŠçã«ãé©çšã§ããã æ¬çºæã®æ¹æ³ã«ãããŠãç»åé²å ãããã«ã©ãŒ
ãã¬ãã€ã«ã ãã«ã©ãŒããžãã€ã«ã ãã«ã©ãŒããŒ
ããŒãªã©ã®åŠçå·¥çšã¯ãéåžž (1) ã«ã©ãŒçŸåâæŒçœâæ°ŽæŽâå®çâæ°ŽæŽâå®å®
âä¹Ÿç¥ (2) ã«ã©ãŒçŸåâæŒçœå®çâæ°ŽæŽâå®å®âä¹Ÿç¥ (3) ã«ã©ãŒçŸåâåæ¢å®çâæŒçœå®çâæ°ŽæŽâå®
å®âä¹Ÿç¥ ãåºæ¬ãšããŠããããŸãã«ã©ãŒçŸååã«ãå
济ã硬è济ãªã©ãèšããŠãè¯ããæŒçœã®åŸã®æ°Ž
æŽãããã¯å®å®æµŽçã¯çç¥ããããšãã§ããã ä»æ¹ãã«ã©ãŒå転ãã€ã«ã ã®åŠçå·¥çšã¯ãé
åžž (4) é»çœçŸåâåæ¢âæ°ŽæŽâã«ãã©ã·âã«ã©ãŒçŸ
åâåæ¢âæ°ŽæŽâæŒçœâæ°ŽæŽâå®çâæ°ŽæŽâå®
å®âä¹Ÿç¥ (5) é»çœçŸåâæ°ŽæŽâã«ãã©ã·âã«ã©ãŒçŸåâæ°Ž
æŽâä¿é²âæŒçœâå®çâæ°ŽæŽâå®å®âä¹Ÿç¥ ãåºæ¬ãšããŠããã(4)ãš(5)ã®å·¥çšã¯æŽã«å济ãå
硬è济ãäžå济ãªã©ãèšããããšãã§ãããåã
æŒçœå®ç济ãçšããŠããããååæ¢æµŽãå®å®æµŽã
ã«ã©ãŒçŸå济åŸã®æ°ŽæŽãæŒçœæµŽåŸã®æ°ŽæŽæµŽãä¿é²
济çã¯çç¥ããããšãã§ãããã«ãã©ã·æµŽã«ã¯ã«
ãã©ã·å€äŸãã°ïœâããã«ã¢ãã³ãã©ã³ãããªãŠ
ã ãããã€ãã©ã€ããã¹ãºâã¢ããããªã«ã«ãã³
é ¢é žå¡©ãæ°ŽçŽ åããŠçŽ ãããªãŠã çãçšããããš
ãã§ãããããããã«ãã©ã·å€ãã«ã©ãŒçŸå济ã«
æ·»å ããããšã«ãããã«ãã©ã·æµŽãçç¥ããããš
ãã§ãããåãã«ãã©ã·æµŽã¯åé²å ã«å€ããããš
ãã§ããã æ¬çºæã®åçåŠçæ¹æ³ã«ãããŠãäžèš(1)ã(5)ã«
瀺ãå·¥çšã¯æçšã§ããããæ¬çºæã¯ãããã®å·¥çš
ã«éå®ãããªãã ãŸãã«ã©ãŒçŸåå·¥çšã¯ãéåžž20ã60âã30ç§ã
10åã®æ¡ä»¶äžã«ãŠè¡ãªãããã æ¬çºæã«äœ¿çšãããããã²ã³åéã«ã©ãŒåçæ
å ææãšã¯ãã«ã©ãŒãã¬ãã€ã«ã ãã«ã©ãŒããŒã
ãŒãã«ã©ãŒããžãã€ã«ã ãã«ã©ãŒå転ãã€ã«ã ãª
ã©ã«ã©ãŒçŸåå·¥çšã䌎ãã«ã©ãŒåçæå ææãªã
å šãŠã«é©ããã æ¬çºæã«çšããããåçä¹³å€ã¯P.Glafkidesè
Chimie et Physique PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et alè
Making and Coating Photographic Emulsion
ïŒThe Focal Pressåã1964幎ïŒãªã©ã«èšèŒãã
ãæ¹æ³ãçšããŠèª¿è£œããããšãã§ãããããªã
ã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³ã¢ãã¢æ³çã®ãããã§
ãããããŸãå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãå
å¿ããã圢åŒãšããŠã¯çåŽæ··åæ³ãåææ··åæ³ã
ãããã®çµåããªã©ã®ããããçšããŠãããã ç²åãéã€ãªã³éå°ã®äžã«ãããŠåœ¢æãããæ¹
æ³ïŒããããéæ··åæ³ïŒãçšããããšãã§ããã
åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®ç
æããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããªã
ã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³ã
çšããããšãã§ããã æ¬çºæã«çšããããåçæå ææã®åçä¹³å€å±€
ã«ã¯ããã²ã³åéãšããŠèåéãæ²èåéãæ²å¡©
èåéãå¡©èåéããã³å¡©åéã®ããããçšããŠ
ãããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã æ¬çºæã«çšããããæå ææã®åçä¹³å€ã¯ãã¡
ãã³è²çŽ é¡ãã®ä»ã«ãã€ãŠåå å¢æãããŠããã
çšããããè²çŽ ã«ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ãè€åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²
çŽ ãããããŒã©ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²
çŽ ãã¹ããªã«è²çŽ ãããã³ãããªããœããŒã«è²çŽ
ãå å«ããããç¹ã«æçšãªè²çŽ ã¯ã·ã¢ãã³è²çŽ ã
ã¡ãã·ã¢ãã³è²çŽ ããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«
å±ããè²çŽ ã§ããããããã®è²çŽ é¡ã«ã¯å¡©åºæ§ç°
ç¯ç°æ žãšããŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ ž
ã®ãããããé©çšã§ããã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšããããã å¢æè²çŽ ãšãšãã«ãããèªèº«åå å¢æäœçšãã
ããªãè²çŽ ãããã¯å¯èŠå ãå®è³ªçã«åžåããªã
ç©è³ªã§ãã€ãŠã匷è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«
ãã§ããããããšãã°å«ããçŽ ç°ç¯ç°åºã§çœ®æã
ããã¢ããã¹ãã«ãã³ååç©ïŒããšãã°ç±³åœç¹èš±
2933390å·ãå3635721å·ã«èšèŒã®ãã®ïŒãè³éŠæ
ææ©é žãã«ã ã¢ã«ãããçž®åç©ïŒããšãã°ç±³åœç¹
èš±3743510å·ã«èšèŒã®ãã®ïŒãã«ãããŠã å¡©ãã¢ã¶
ã€ã³ãã³ååç©ãªã©ãå«ãã§ãããã åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³ãã€ããšããŠ
ã¯ããŒã©ãã³ãçšããã®ãæå©ã§ãããããã以
å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒãºç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã«èªå°äœãã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«å
åç©è³ªãçšããããšãã§ããã æ¬çºæã«ã¯æ¯æäœäžã«å°ãªããšãïŒã€ã®ç°ãªã
åå æ床ãæããå€å±€å€è²åçææãé©çšã§ã
ããå€å±€å€©ç¶è²åçææã¯ãéåžžæ¯æäœäžã«èµ€æ
æ§ä¹³å€å±€ãç·ææ§ä¹³å€å±€ãããã³éææ§ä¹³å€å±€ã
åã å°ãªããšãäžã€æããããããã®å±€ã®é åºã¯
å¿ èŠã«å¿ããŠä»»æã«ããã¹ããèµ€ææ§ä¹³å€å±€ã«ã·
ã¢ã³åœ¢æã«ãã©ãŒããç·ææ§ä¹³å€å±€ã«ããŒã³ã¿åœ¢
æã«ãã©ãŒããéææ§ä¹³å€å±€ã«ã€ãšããŒåœ¢æã«ã
ã©ãŒãããããå«ãã®ãéåžžã§ããããå Žåã«ã
ãç°ãªãçµåãããšãããšãã§ããã æ¬çºæã«çšããããæå ææã«ã¯èŠªæ°Žæ§ã³ãã€
ãå±€ã«ãã€ã«ã¿ãŒææãšããŠããããã¯ã€ã©ãžãš
ãŒã·ãšã³é²æ¢ãã®ä»çš®ã ã®ç®çã§ã氎溶æ§ææã
å«æããŠããããã®ãããªææã«ã¯ãªããœããŒã«
ææããããªããœããŒã«ææãã¹ãã«ãªææãã¡
ãã·ã¢ãã³ææãã·ã¢ãã³ææãåã³ã¢ãŸææã
å å«ããããäžã§ããªããœããŒã«ææïŒãããªã
ãœããŒã«ææåã³ã¡ãã·ã¢ãã³ææãæçšã§ã
ãã æ¬çºæã«çšããããæå ææã«ã¯äžèšã®å ¬ç¥ã®
éè²é²æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«
çšããè²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšãã
ããšãã§ãããäŸãã°ããã€ããããã³èªå°äœã
没é£åèªå°äœãïœâã¢ã«ã³ãã·ããšããŒã«é¡ãïœ
âãªãã·ããšããŒã«èªå°äœããã¹ããšããŒã«é¡ã
ããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«ã¯çŽ«å€ç·åžåå€ãå«ãã§ãããããšã
ã°ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«å
åç©ïŒããšãã°ç±³åœç¹èš±3533794å·ã«èšèŒã®ã
ã®ïŒãïŒâãã¢ãŸãªãã³ååç©ïŒããšãã°ç±³åœç¹
èš±3314794å·ãå3352681å·ã«èšèŒã®ãã®ïŒããã³
ãŸããšãã³ååç©ïŒããšãã°ç¹éæ46â2784å·ã«
èšèŒã®ãã®ïŒãã±ã€ãé žãšã¹ãã«ååç©ïŒããšã
ã°ç±³åœç¹èš±3705805å·ãå3707375å·ã«èšèŒã®ã
ã®ïŒããã¿ãžãšã³ååç©ïŒããšãã°ç±³åœç¹èš±
4045229å·ã«èšèŒã®ãã®ïŒãããã¯ãã³ãŸãªãã·
ãŸãŒã«ååç©ïŒããšãã°ç±³åœç¹èš±3700455å·ã«èš
èŒã®ãã®ïŒãçšããããšãã§ãããããã«ç±³åœç¹
èš±3499762å·ãç¹éæ54â48535å·ã«èšèŒã®ãã®ã
çšããããšãã§ããã玫å€ç·åžåæ§ã®ã«ãã©ãŒ
ïŒããšãã°Î±âããããŒã«ç³»ã«ã·ã¢ã³è²çŽ 圢æã«
ãã©ãŒïŒã玫å€ç·åžåæ§ã®ããªããŒãªã©ãçšããŠ
ãããããããã®çŽ«å€ç·åžåå€ã¯ç¹å®ã®å±€ã«åªæ
ãããŠãããã æ¬çºæã«çšããããæå ææã«ãããŠãåçä¹³
å€å±€ãã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ã¯ã¹ãã«ãã³
ç³»ãããªã¢ãžã³ç³»ããªããµãŸãŒã«ç³»ããããã¯ã¯
ããªã³ç³»ãªã©ã®å¢çœå€ãå«ãã§ãããããããã¯
氎溶æ§ã®ãã®ã§ãããããŸãæ°Žäžæº¶æ§ã®å¢çœå€ã
åæ£ç©ã®åœ¢ã§çšããŠãããã æ¬çºæã«çšããããåçæå ææã®åçä¹³å€å±€
ã«ã¯è²çŽ 圢æã«ãã©ãŒãå³ã¡ãçºè²çŸååŠçã«ã
ããŠè³éŠæïŒçŽã¢ãã³çŸåè¬ïŒäŸãã°ãããšãã¬
ã³ãžã¢ãã³èªå°äœããã¢ããããšããŒã«èªå°äœãª
ã©ïŒãšã®é žåã«ãããªã³ã°ã«ãã€ãŠçºè²ãããå
åç©ã䜵ããŠçšããŠããããäŸãã°ããŒã³ã¿ã«ã
ã©ãŒãšããŠãïŒâãã©ãŸãã³ã«ãã©ãŒããã©ãŸã
ãã³ãã€ãããŸãŒã«ã«ãã©ãŒãã·ã¢ãã¢ã»ãã«ã¯
ããã³ã«ãã©ãŒãééã¢ã·ã«ã¢ã»ããããªã«ã«ã
ã©ãŒçããããã€ãšããŒã«ãã©ãŒãšããŠãã¢ã·ã«
ã¢ã»ãã¢ããã«ãã©ãŒïŒäŸãã°ãã³ãŸã€ã«ã¢ã»ã
ã¢ããªãé¡ããããã€ã«ã¢ã»ãã¢ããªãé¡ïŒãç
ããããã·ã¢ã³ã«ãã©ãŒãšããŠãããããŒã«ã«ã
ã©ãŒãåã³ããšããŒã«ã«ãã©ãŒçããããããã
ã®ã«ãã©ãŒã¯ååäžã«ãã©ã¹ãåºãšãã°ããçæ°Ž
åºãæããéæ¡æ£æ§ã®ãã®ããŸãã¯ããªããŒåã
ãããã®ãæãŸãããã«ãã©ãŒã¯ãéã€ãªã³ã«å¯Ÿ
ãïŒåœéæ§ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããã
åãè²è£æ£ã®å¹æããã€ã«ã©ãŒãã«ãã©ãŒããã
ãã¯çŸåã«ãšããªã€ãŠçŸåæå¶å€ãŸãã¯çŸåä¿é²
å€ãæŸåºããã«ãã©ãŒïŒããããDIRã«ãã©ãŒãŸ
ãã¯DARã«ãã©ãŒïŒã§ãã€ãŠãããã åãDIRã«ãã©ãŒä»¥å€ã«ããã«ãããªã³ã°åå¿
ã®çæç©ãç¡è²ã§ãã€ãŠãçŸåæå¶å€ãæŸåºãã
ç¡åè²DIRã«ãããªã³ã°ååç©ãå«ãã§ãããã DIRã«ãã©ãŒä»¥å€ã«çŸåã«ãšããªã€ãŠçŸåæå¶
å€ãæŸåºããååç©ãæå ææäžã«å«ãã§ãã
ãã äžèšã«ãã©ãŒçã¯ãæå ææã«æ±ããããç¹æ§
ãæºè¶³ããããã«åäžå±€ã«äºçš®é¡ä»¥äžã䜵çšãã
ããšãã§ããããåäžã®ååç©ãç°ãªã€ãïŒå±€ä»¥
äžã«æ·»å ããããšãããã¡ããå·®æ¯ããªãã å®æœäŸ ïŒ ããªã¢ã»ãã«ã»ã«ããŒã¹æ¯æäœäžã«ãäžèšã«ç€º
ããããªçµæã®åå±€ãããªãå€å±€ã«ã©ãŒæå ææ
ãäœè£œããã 第ïŒå±€ïŒãã¬ãŒã·ãšã³é²æ¢å±€ é»è²ã³ãã€ãéãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒäžéå±€ ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ããããã³ã®
ä¹³ååæ£ç©ãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒäœæ床赀æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠâŠéå¡åž
é1.6ïœïŒm2 å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠ1.5Ã10-5ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.04ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.003ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.0006
ã¢ã« 第ïŒå±€ïŒé«æ床赀æä¹³å€å±€ 溶èåéä¹³å€ïŒæ²åéïŒ10ã¢ã«ïŒ ïŒâŠâŠéå¡åž
é1.4ïœïŒm2 å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠ1.2Ã10-5ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.2ã¢ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.0016
ã¢ã« 第ïŒå±€ïŒäžéå±€ 第ïŒå±€ãšåã 第ïŒå±€ïŒäœæ床ç·æä¹³å€å±€ ååæ£æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠâŠ
å¡åžéé1.29ïŒm2 å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.05ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.08ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.0015
ã¢ã« 第ïŒå±€ïŒé«æ床ç·æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒ10ã¢ã«ïŒ ïŒâŠâŠå¡åžé
é1.3ïŒm2 å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠ2.5Ã10-5ã¢
ã« å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.8Ã10-5ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.017ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.03ã¢
ã« ã«ãã©ãŒEXâ10âŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.003ã¢
㫠第ïŒå±€ïŒã€ãšããŒãã€ã«ã¿ãŒå±€ ãŒã©ãã³æ°Žæº¶æ¶²äžã«é»è²ã³ãã€ãéãšïŒïŒïŒ
âãžâïœãªã¯ãã«ãã€ããããã³ã®ä¹³ååæ£ç©
ãšãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒäœæ床éæä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠâŠå¡åžé
é0.7ïŒm2 ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.25ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.015ã¢
㫠第10å±€ïŒé«æ床éæä¹³å€å±€ æ²èåéïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠâŠå¡åžéé
0.6ïŒm2 ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.06ã¢
㫠第11å±€ïŒç¬¬ïŒä¿è·å±€ æ²èåéïŒæ²åéïŒã¢ã«ïŒ ïŒå¹³åç²åŸ0.07ÎŒïŒ
âŠâŠå¡åžéé0.5ïœ çŽ«å€ç·åžåå€UVâïŒã®ä¹³ååæ£ç©ãå«ã
ãŒã©ãã³å±€ 第12å±€ïŒç¬¬ïŒä¿è·å±€ ããªã¡ãã«ã¡ã¿ãã¢ã¯ãªã¬ãŒãç²åïŒçŽåŸçŽ
1.5ÎŒïŒãå«ããŒã©ãã³å±€ãå¡åžã åå±€ã«ã¯äžèšçµæç©ã®ä»ã«ããŒã©ãã³ç¡¬åå€
âïŒãçé¢æŽ»æ§å€æ·»å ããã 以äžã®åŠãããŠè©Šæãäœè£œããã è©Šæäœãã®ã«çšããååç© å¢æè²çŽ ïŒã¢ã³ãããâïŒã»5â²âãžã¯ããâ
ïŒã»3â²âãžâïŒÎ³âã¹ã«ããããã«ïŒâïŒâãšã
ã«âãã¢ã«ã«ãã·ã¢ãã³ãããããµã€ãã»ããª
ãžããŠã å¡© å¢æè²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»3â²â
ãžâïŒÎ³âã¹ã«ããããã«ïŒâïŒã»ïŒã»4â²ã»5â²â
ãžãã³ãŸãã¢ã«ã«ãã·ã¢ãã³ããããã·ãµã€
ãã»ããªãšãã«ã¢ãã³å¡© å¢æè²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»5â²â
ãžã¯ããâïŒã»3â²âãžâïŒÎ³âã¹ã«ããããã«ïŒ
ãªããµã«ã«ãã·ã¢ãã³ã»ãããªãŠã å¡© å¢æè²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»ïŒã»
5â²ã»6â²âããã©ã¯ããâïŒïŒ1â²âãžãšãã«â
ïŒã»3â²âãžâïœÎ²âãβâïŒÎ³âã¹ã«ããããã«ïŒ
ãšããã·ããšãã«ïœãã³ãŸã€ãããŸãã«ã«ãã·
ã¢ãã³ãããããµã€ããããªãŠã å¡©
ã¯PHïŒã12ããã奜ãŸããã¯ïŒã11.0ã§ãããã
ã®ã«ã©ãŒçŸå液ã«ã¯ããã®ä»ã®æ¢ç¥ã®çŸå液æå
ã®ååç©ãå«ãŸããããšãã§ãããã äŸãã°ã¢ã«ã«ãªå€ãPHç·©è¡å€ãšããŠã¯èæ§ãœãŒ
ããèæ§ã«ãªãçé žãœãŒããçé žã«ãªã第ïŒãªã³
é žãœãŒãã第ïŒãªã³é žã«ãªãã¡ã¿ããŠé žã«ãªãã
ãŠç ãªã©ãåç¬åã¯çµã¿åããã§çšããããããŸ
ããç·©è¡èœãäžãããã調åäžã®éœåã®ãããã
ããã¯ã€ãªã³åŒ·åºŠãé«ãããããçã®ç®çã§ãã
ãã«ãªã³é žæ°ŽçŽ ïŒãããªãŠã åã¯ã«ãªããªã³é žïŒ
æ°ŽçŽ ã«ãªåã¯ãããªãŠã ãéçé žãœãŒãåã¯ã«
ãªãããŠé žãç¡é žã¢ã«ã«ãªãç¡«é žã¢ã«ã«ãªãªã©ã
çš®ã ã®å¡©é¡ã䜿çšãããã ã«ã©ãŒçŸå液ã«ã¯ãå¿ èŠã«ããä»»æã®çŸåä¿é²
å€ãæ·»å ã§ãããäŸãã°ç±³åœç¹èš±2648604å·ãç¹
å ¬æ44â9503å·ãç±³åœç¹èš±3171247å·ã§ä»£è¡šãã
ãåçš®ã®ããªããžãŠã ååç©ããã®ä»ã®ã«ããªã
ãã¯ååç©ãããšããµãã©ãã³ã®ãããªã«ããªã³
æ§è²çŽ ãç¡é žã¿ãªãŠã ãç¡é žã«ãªãŠã ã®åŠãäžæ§
å¡©ãç¹å ¬æ44â9304å·ãç±³åœç¹èš±2533990å·ãå
2531832å·ãå2950970å·ãå2577127å·èšèŒã®ã
ãªãšãã¬ã³ã°ãªã³ãŒã«ããã®èªå°äœãããªããªãš
ãŒãã«é¡ãªã©ã®ãããªã³æ§ååç©ãç¹å ¬æ44â
9509å·ããã«ã®ãŒç¹èš±682862å·èšèŒã®ææ©æº¶å€ã
ææ©ã¢ãã³ããšã¿ããŒã«ã¢ãã³ããšãã¬ã³ãžã¢ã
ã³ããžãšã¿ããŒã«ã¢ãã³ãªã©ããã®ã»ãL.F.A.
MasonèãPhotographic Processing
ChemistryãP40ã43ïŒFocal PressâLondonâ
1966ïŒã«èšè¿°ãããŠããä¿é²å€ãçšããããšãã§
ããããã®ã»ãç±³åœç¹èš±2515147å·ã«èšèŒã®ãã³
ãžã«ã¢ã«ã³ãŒã«ãããšãã«ãšãã«ã¢ã«ã³ãŒã«ãæ¥
æ¬åçåŠäŒèª14å·»ã74ããŒãžïŒ1952幎ïŒèšèŒã®ã
ãªãžã³ãããã©ãžã³ãã¢ãã³é¡ãªã©ãæçšãªçŸå
ä¿é²å€ã§ãããåç±³åœç¹èš±3201242å·èšèŒã®ããª
ãšãŒãã«ç³»ååç©ã䜿çšããŠãããããªãã§ãã
ç¹ã«ãšãã¬ã³ãžã¢ãã³ããã³ãžã«ã¢ã«ã³ãŒã«ãã
ãªãšãŒãã«ç³»ååç©ã奜ãŸããã ãŸããéåžžä¿æå€ãšããŠçšããããäºç¡«é žãœãŒ
ããäºç¡«é žã«ãªãéäºç¡«é žã«ãªåã¯éäºç¡«é žãœãŒ
ããå ããããšãã§ããã æ¬çºæã«ãããŠã«ã©ãŒçŸå液ã«ã¯å¿ èŠã«ããã
ä»»æã®ã«ããªé²æ¢å€ãæ·»å ã§ãããã«ããªé²æ¢å€
ãšããŠã¯èåã«ãªãŠã ãèåãããªãŠã ãæ²åã«
ãªãŠã ã®åŠãã¢ã«ã«ãªéå±ããã²ã³åç©åã³ææ©
ã«ããªé²æ¢å€ã䜿çšã§ãããææ©ã«ããªé²æ¢å€ãš
ããŠã¯ãäŸãã°ãã³ãŸããªã¢ãŸãŒã«ãïŒâããã
ãã³ãºã€ãããŸãŒã«ãïŒâãããã€ãœã€ã³ããŸãŒ
ã«ãïŒâã¡ãã«ãã³ãŸããªã¢ãŸãŒã«ãïŒâããã
ãã³ãŸããªã¢ãŸãŒã«ãïŒâã¯ããâãã³ãŸããªã¢
ãŸãŒã«ãïŒâãã¢ãŸãªã«âãã³ãºã€ãããŸãŒã«ã
ïŒâãã¢ãŸãªã«ã¡ãã«âãã³ãºã€ãããŸãŒã«ãã
ãããã·ã¢ã¶ã€ã³ããªãžã³ã®åŠãå«çªçŽ ãããç°
ååç©åã³ïŒâããšãã«âïŒâã¡ã«ã«ããããã©
ãŸãŒã«ãïŒâã¡ã«ã«ãããã³ãºã€ãããŸãŒã«ãïŒ
âã¡ã«ã«ãããã³ãŸãã¢ãŸãŒã«ã®åŠãã¡ã«ã«ãã
眮æãããç°ååç©ãæŽã«ããªãµãªãã«é žã®åŠã
ã¡ã«ã«ãã眮æã®è³éŠæååç©ã䜿çšããããšã
ã§ãããç¹ã«å¥œãŸããã¯å«çªçŽ ãããç°ååç©ã§
ããããããã®ã«ããªé²æ¢å€ã¯ãåŠçäžã«ã«ã©ãŒ
æå ææäžãã溶åºããã«ã©ãŒçŸå液äžã«èç©ã
ãŠãããã å転ã«ã©ãŒåŠçã®å Žåã«ã¯ãã«ã©ãŒçŸå液äžã«
競äºã«ãã©ãŒãã«ãã©ã·å€ããã³è£åçŸåè¬ãå
ããããšãã§ããã 競äºã«ãã©ãŒãšããŠã¯ãã·ãã©ãžã³é žãïŒªé žã
ïŒšé žãªã©ãæçšã§ãããããšãã°ãç±³åœç¹èš±
2742832å·ãç¹å ¬æ44â9504å·ãå44â9506å·ã
å44â9507å·ãç±³åœç¹èš±3520690å·ãå3560212
å·ãå3645737å·çã«èšèŒãããååç©ãçšãåŸ
ãã ã«ãã©ã·å€ãšããŠã¢ã«ã«ãªéå±ãããã€ãã©ã€
ããã¢ãã³ãã©ã³ããšãã¬ã³ãžã¢ãã³ãªã©ãçšã
ãããšãã§ããããã®ä»ç¹å ¬æ47â38816å·ã«èš
èŒãããååç©ãçšããããšãã§ããã è£åçŸåè¬ãšããŠïœâã¢ããããšããŒã«ãâ
ãã³ãžã«âïœâã¢ããããšããŒã«ãïŒâããšãã«
âïŒâãã©ãŸãªãã³é¡ãªã©ãçšããããšãã§ã
ããããšãã°ç¹å ¬æ452â41475å·ãå46â19037
å·ã«èšèŒã®ååç©ã¯æçšã§ããã æ¬çºæã«äœ¿çšãããæŒçœæ¶²äžåã¯æŒçœå®ç液äž
ã«ã¯æŒçœå€ãšããŠéã€ãªã³ãå«æãããéã€ãªã³
ãšããŠã¯ãå¡©åéãèµ€è¡å¡©ã®ãããªç¡æ©éå¡©ãã¯
ãšã³é žéãã·ãŠãŠé žéã®ãããªææ©éå¡©ããšãã¬
ã³ãžã¢ãã³åé ¢é žéå¡©ã«ä»£è¡šããããããªã¢ãã
ããªã«ã«ãã³é žéé¯äœçããããããšãã§ãã
ãããããã«éå®ããããã®ã§ã¯ãªãã æ¬çºæã®ã«ã©ãŒåçåŠçæ¹æ³ã¯ãç±³åœç¹èš±
3227551å·ãå3227552å·ã«èšèŒã®åŠãæ¹æ³ãçšã
ãæ¡æ£è»¢åã«ã©ãŒåçæ³ã«çšããããšãã§ããã
ãã®å Žåã«ã¯ãã«ãã©ãŒã¯åŠçå·¥çšäžã«ä»ã®å±€ãž
æ¡æ£ããŠãããããåã¯æ¡æ£ããå¿ èŠãããã æ¬çºæã®åŠçæ¹æ³ã¯çºè²å€ãæå ææäžã«å«ãŸ
ããŠããå åçŸåæ¹åŒïŒç±³åœç¹èš±2376679å·ãå
2322027åã³å2801171å·ïŒã®ã»ããçºè²å€ãçŸå
液äžã«ååšããããããå€åçŸåæ¹åŒïŒç±³åœç¹èš±
2252718å·ãå2592243å·åã³å2590970å·ïŒã«ã
é©çšã§ããã åŸã€ãŠæ¬çºæã®åŠçæ¹æ³ã¯ã«ã©ãŒãã¬ãã€ã«
ã ãã«ã©ãŒããŒããŒãã«ã©ãŒããžãã€ã«ã ãã«ã©
ãŒå転ãã€ã«ã ãªã©ã®äžè¬çãªããã²ã³åéã«ã©
ãŒåçææã®ãããã®åŠçã«ãé©çšã§ããã æ¬çºæã®æ¹æ³ã«ãããŠãç»åé²å ãããã«ã©ãŒ
ãã¬ãã€ã«ã ãã«ã©ãŒããžãã€ã«ã ãã«ã©ãŒããŒ
ããŒãªã©ã®åŠçå·¥çšã¯ãéåžž (1) ã«ã©ãŒçŸåâæŒçœâæ°ŽæŽâå®çâæ°ŽæŽâå®å®
âä¹Ÿç¥ (2) ã«ã©ãŒçŸåâæŒçœå®çâæ°ŽæŽâå®å®âä¹Ÿç¥ (3) ã«ã©ãŒçŸåâåæ¢å®çâæŒçœå®çâæ°ŽæŽâå®
å®âä¹Ÿç¥ ãåºæ¬ãšããŠããããŸãã«ã©ãŒçŸååã«ãå
济ã硬è济ãªã©ãèšããŠãè¯ããæŒçœã®åŸã®æ°Ž
æŽãããã¯å®å®æµŽçã¯çç¥ããããšãã§ããã ä»æ¹ãã«ã©ãŒå転ãã€ã«ã ã®åŠçå·¥çšã¯ãé
åžž (4) é»çœçŸåâåæ¢âæ°ŽæŽâã«ãã©ã·âã«ã©ãŒçŸ
åâåæ¢âæ°ŽæŽâæŒçœâæ°ŽæŽâå®çâæ°ŽæŽâå®
å®âä¹Ÿç¥ (5) é»çœçŸåâæ°ŽæŽâã«ãã©ã·âã«ã©ãŒçŸåâæ°Ž
æŽâä¿é²âæŒçœâå®çâæ°ŽæŽâå®å®âä¹Ÿç¥ ãåºæ¬ãšããŠããã(4)ãš(5)ã®å·¥çšã¯æŽã«å济ãå
硬è济ãäžå济ãªã©ãèšããããšãã§ãããåã
æŒçœå®ç济ãçšããŠããããååæ¢æµŽãå®å®æµŽã
ã«ã©ãŒçŸå济åŸã®æ°ŽæŽãæŒçœæµŽåŸã®æ°ŽæŽæµŽãä¿é²
济çã¯çç¥ããããšãã§ãããã«ãã©ã·æµŽã«ã¯ã«
ãã©ã·å€äŸãã°ïœâããã«ã¢ãã³ãã©ã³ãããªãŠ
ã ãããã€ãã©ã€ããã¹ãºâã¢ããããªã«ã«ãã³
é ¢é žå¡©ãæ°ŽçŽ åããŠçŽ ãããªãŠã çãçšããããš
ãã§ãããããããã«ãã©ã·å€ãã«ã©ãŒçŸå济ã«
æ·»å ããããšã«ãããã«ãã©ã·æµŽãçç¥ããããš
ãã§ãããåãã«ãã©ã·æµŽã¯åé²å ã«å€ããããš
ãã§ããã æ¬çºæã®åçåŠçæ¹æ³ã«ãããŠãäžèš(1)ã(5)ã«
瀺ãå·¥çšã¯æçšã§ããããæ¬çºæã¯ãããã®å·¥çš
ã«éå®ãããªãã ãŸãã«ã©ãŒçŸåå·¥çšã¯ãéåžž20ã60âã30ç§ã
10åã®æ¡ä»¶äžã«ãŠè¡ãªãããã æ¬çºæã«äœ¿çšãããããã²ã³åéã«ã©ãŒåçæ
å ææãšã¯ãã«ã©ãŒãã¬ãã€ã«ã ãã«ã©ãŒããŒã
ãŒãã«ã©ãŒããžãã€ã«ã ãã«ã©ãŒå転ãã€ã«ã ãª
ã©ã«ã©ãŒçŸåå·¥çšã䌎ãã«ã©ãŒåçæå ææãªã
å šãŠã«é©ããã æ¬çºæã«çšããããåçä¹³å€ã¯P.Glafkidesè
Chimie et Physique PhotographiqueïŒPaul
Montel瀟åã1967幎ïŒãG.F.Duffinè
Photographic Emulsion ChemistryïŒThe Focal
Pressåã1966幎ïŒãV.L.Zelikman et alè
Making and Coating Photographic Emulsion
ïŒThe Focal Pressåã1964幎ïŒãªã©ã«èšèŒãã
ãæ¹æ³ãçšããŠèª¿è£œããããšãã§ãããããªã
ã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³ã¢ãã¢æ³çã®ãããã§
ãããããŸãå¯æº¶æ§éå¡©ãšå¯æº¶æ§ããã²ã³å¡©ãå
å¿ããã圢åŒãšããŠã¯çåŽæ··åæ³ãåææ··åæ³ã
ãããã®çµåããªã©ã®ããããçšããŠãããã ç²åãéã€ãªã³éå°ã®äžã«ãããŠåœ¢æãããæ¹
æ³ïŒããããéæ··åæ³ïŒãçšããããšãã§ããã
åææ··åæ³ã®äžã€ã®åœ¢åŒãšããŠããã²ã³åéã®ç
æããã液çžäžã®pAgãäžå®ã«ä¿ã€æ¹æ³ãããªã
ã¡ããããã³ã³ãããŒã«ãã»ããã«ãžãšããæ³ã
çšããããšãã§ããã æ¬çºæã«çšããããåçæå ææã®åçä¹³å€å±€
ã«ã¯ããã²ã³åéãšããŠèåéãæ²èåéãæ²å¡©
èåéãå¡©èåéããã³å¡©åéã®ããããçšããŠ
ãããã ããã²ã³åéç²å圢æãŸãã¯ç©ççæã®éçšã«
ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ãã¿ãªãŠã
å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããžãŠã å¡©ãŸ
ãã¯ãã®é¯å¡©ãéå¡©ãŸãã¯éé¯å¡©ãªã©ãå ±åãã
ãŠãããã æ¬çºæã«çšããããæå ææã®åçä¹³å€ã¯ãã¡
ãã³è²çŽ é¡ãã®ä»ã«ãã€ãŠåå å¢æãããŠããã
çšããããè²çŽ ã«ã¯ãã·ã¢ãã³è²çŽ ãã¡ãã·ã¢ã
ã³è²çŽ ãè€åã·ã¢ãã³è²çŽ ãè€åã¡ãã·ã¢ãã³è²
çŽ ãããããŒã©ãŒã·ã¢ãã³è²çŽ ãããã·ã¢ãã³è²
çŽ ãã¹ããªã«è²çŽ ãããã³ãããªããœããŒã«è²çŽ
ãå å«ããããç¹ã«æçšãªè²çŽ ã¯ã·ã¢ãã³è²çŽ ã
ã¡ãã·ã¢ãã³è²çŽ ããã³è€åã¡ãã·ã¢ãã³è²çŽ ã«
å±ããè²çŽ ã§ããããããã®è²çŽ é¡ã«ã¯å¡©åºæ§ç°
ç¯ç°æ žãšããŠã·ã¢ãã³è²çŽ é¡ã«éåžžå©çšãããæ ž
ã®ãããããé©çšã§ããã ãããã®å¢æè²çŽ ã¯åç¬ã«çšããŠãããããã
ããã®çµåããçšããŠããããå¢æè²çŽ ã®çµåã
ã¯ç¹ã«åŒ·è²å¢æã®ç®çã§ãã°ãã°çšããããã å¢æè²çŽ ãšãšãã«ãããèªèº«åå å¢æäœçšãã
ããªãè²çŽ ãããã¯å¯èŠå ãå®è³ªçã«åžåããªã
ç©è³ªã§ãã€ãŠã匷è²å¢æã瀺ãç©è³ªãä¹³å€äžã«å«
ãã§ããããããšãã°å«ããçŽ ç°ç¯ç°åºã§çœ®æã
ããã¢ããã¹ãã«ãã³ååç©ïŒããšãã°ç±³åœç¹èš±
2933390å·ãå3635721å·ã«èšèŒã®ãã®ïŒãè³éŠæ
ææ©é žãã«ã ã¢ã«ãããçž®åç©ïŒããšãã°ç±³åœç¹
èš±3743510å·ã«èšèŒã®ãã®ïŒãã«ãããŠã å¡©ãã¢ã¶
ã€ã³ãã³ååç©ãªã©ãå«ãã§ãããã åçä¹³å€ã®çµåå€ãŸãã¯ä¿è·ã³ãã€ããšããŠ
ã¯ããŒã©ãã³ãçšããã®ãæå©ã§ãããããã以
å€ã®èŠªæ°Žæ§ã³ãã€ããçšããããšãã§ããã ããšãã°ãŒã©ãã³èªå°äœããŒã©ãã³ãšä»ã®é«å
åãšã®ã°ã©ããããªããŒãã¢ã«ããã³ãã«ãŒã€ã³
çã®èçœè³ªïŒããããã·ãšãã«ã»ã«ããŒã¹ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒã¹ãã»ã«ããŒãºç¡«é žãšã¹ã
ã«é¡çã®åŠãã»ã«ããŒã«èªå°äœãã¢ã«ã®ã³é žãœãŒ
ãã柱ç²èªå°äœãªã©ã®ç³èªå°äœïŒããªããã«ã¢ã«
ã³ãŒã«ãããªããã«ã¢ã«ã³ãŒã«éšåã¢ã»ã¿ãŒã«ã
ããªââããã«ãããªãã³ãããªã¢ã¯ãªã«é žã
ããªã¡ã¿ã¯ãªã«é žãããªã¢ã¯ãªã«ã¢ãããããªã
ãã«ã€ãããŸãŒã«ãããªããã«ãã©ãŸãŒã«çã®å
äžãããã¯å ±éåäœã®åŠãå€çš®ã®åæ芪氎æ§é«å
åç©è³ªãçšããããšãã§ããã æ¬çºæã«ã¯æ¯æäœäžã«å°ãªããšãïŒã€ã®ç°ãªã
åå æ床ãæããå€å±€å€è²åçææãé©çšã§ã
ããå€å±€å€©ç¶è²åçææã¯ãéåžžæ¯æäœäžã«èµ€æ
æ§ä¹³å€å±€ãç·ææ§ä¹³å€å±€ãããã³éææ§ä¹³å€å±€ã
åã å°ãªããšãäžã€æããããããã®å±€ã®é åºã¯
å¿ èŠã«å¿ããŠä»»æã«ããã¹ããèµ€ææ§ä¹³å€å±€ã«ã·
ã¢ã³åœ¢æã«ãã©ãŒããç·ææ§ä¹³å€å±€ã«ããŒã³ã¿åœ¢
æã«ãã©ãŒããéææ§ä¹³å€å±€ã«ã€ãšããŒåœ¢æã«ã
ã©ãŒãããããå«ãã®ãéåžžã§ããããå Žåã«ã
ãç°ãªãçµåãããšãããšãã§ããã æ¬çºæã«çšããããæå ææã«ã¯èŠªæ°Žæ§ã³ãã€
ãå±€ã«ãã€ã«ã¿ãŒææãšããŠããããã¯ã€ã©ãžãš
ãŒã·ãšã³é²æ¢ãã®ä»çš®ã ã®ç®çã§ã氎溶æ§ææã
å«æããŠããããã®ãããªææã«ã¯ãªããœããŒã«
ææããããªããœããŒã«ææãã¹ãã«ãªææãã¡
ãã·ã¢ãã³ææãã·ã¢ãã³ææãåã³ã¢ãŸææã
å å«ããããäžã§ããªããœããŒã«ææïŒãããªã
ãœããŒã«ææåã³ã¡ãã·ã¢ãã³ææãæçšã§ã
ãã æ¬çºæã«çšããããæå ææã«ã¯äžèšã®å ¬ç¥ã®
éè²é²æ¢å€ã䜵çšããããšãã§ãããŸãæ¬çºæã«
çšããè²åå®å®å€ã¯åç¬ãŸãã¯ïŒçš®ä»¥äžäœµçšãã
ããšãã§ãããäŸãã°ããã€ããããã³èªå°äœã
没é£åèªå°äœãïœâã¢ã«ã³ãã·ããšããŒã«é¡ãïœ
âãªãã·ããšããŒã«èªå°äœããã¹ããšããŒã«é¡ã
ããã æ¬çºæãçšããŠäœãããæå ææã«ã¯èŠªæ°Žæ§ã³
ãã€ãå±€ã«ã¯çŽ«å€ç·åžåå€ãå«ãã§ãããããšã
ã°ã¢ãªãŒã«åºã§çœ®æããããã³ãŸããªã¢ãŸãŒã«å
åç©ïŒããšãã°ç±³åœç¹èš±3533794å·ã«èšèŒã®ã
ã®ïŒãïŒâãã¢ãŸãªãã³ååç©ïŒããšãã°ç±³åœç¹
èš±3314794å·ãå3352681å·ã«èšèŒã®ãã®ïŒããã³
ãŸããšãã³ååç©ïŒããšãã°ç¹éæ46â2784å·ã«
èšèŒã®ãã®ïŒãã±ã€ãé žãšã¹ãã«ååç©ïŒããšã
ã°ç±³åœç¹èš±3705805å·ãå3707375å·ã«èšèŒã®ã
ã®ïŒããã¿ãžãšã³ååç©ïŒããšãã°ç±³åœç¹èš±
4045229å·ã«èšèŒã®ãã®ïŒãããã¯ãã³ãŸãªãã·
ãŸãŒã«ååç©ïŒããšãã°ç±³åœç¹èš±3700455å·ã«èš
èŒã®ãã®ïŒãçšããããšãã§ãããããã«ç±³åœç¹
èš±3499762å·ãç¹éæ54â48535å·ã«èšèŒã®ãã®ã
çšããããšãã§ããã玫å€ç·åžåæ§ã®ã«ãã©ãŒ
ïŒããšãã°Î±âããããŒã«ç³»ã«ã·ã¢ã³è²çŽ 圢æã«
ãã©ãŒïŒã玫å€ç·åžåæ§ã®ããªããŒãªã©ãçšããŠ
ãããããããã®çŽ«å€ç·åžåå€ã¯ç¹å®ã®å±€ã«åªæ
ãããŠãããã æ¬çºæã«çšããããæå ææã«ãããŠãåçä¹³
å€å±€ãã®ä»ã®èŠªæ°Žæ§ã³ãã€ãå±€ã«ã¯ã¹ãã«ãã³
ç³»ãããªã¢ãžã³ç³»ããªããµãŸãŒã«ç³»ããããã¯ã¯
ããªã³ç³»ãªã©ã®å¢çœå€ãå«ãã§ãããããããã¯
氎溶æ§ã®ãã®ã§ãããããŸãæ°Žäžæº¶æ§ã®å¢çœå€ã
åæ£ç©ã®åœ¢ã§çšããŠãããã æ¬çºæã«çšããããåçæå ææã®åçä¹³å€å±€
ã«ã¯è²çŽ 圢æã«ãã©ãŒãå³ã¡ãçºè²çŸååŠçã«ã
ããŠè³éŠæïŒçŽã¢ãã³çŸåè¬ïŒäŸãã°ãããšãã¬
ã³ãžã¢ãã³èªå°äœããã¢ããããšããŒã«èªå°äœãª
ã©ïŒãšã®é žåã«ãããªã³ã°ã«ãã€ãŠçºè²ãããå
åç©ã䜵ããŠçšããŠããããäŸãã°ããŒã³ã¿ã«ã
ã©ãŒãšããŠãïŒâãã©ãŸãã³ã«ãã©ãŒããã©ãŸã
ãã³ãã€ãããŸãŒã«ã«ãã©ãŒãã·ã¢ãã¢ã»ãã«ã¯
ããã³ã«ãã©ãŒãééã¢ã·ã«ã¢ã»ããããªã«ã«ã
ã©ãŒçããããã€ãšããŒã«ãã©ãŒãšããŠãã¢ã·ã«
ã¢ã»ãã¢ããã«ãã©ãŒïŒäŸãã°ãã³ãŸã€ã«ã¢ã»ã
ã¢ããªãé¡ããããã€ã«ã¢ã»ãã¢ããªãé¡ïŒãç
ããããã·ã¢ã³ã«ãã©ãŒãšããŠãããããŒã«ã«ã
ã©ãŒãåã³ããšããŒã«ã«ãã©ãŒçããããããã
ã®ã«ãã©ãŒã¯ååäžã«ãã©ã¹ãåºãšãã°ããçæ°Ž
åºãæããéæ¡æ£æ§ã®ãã®ããŸãã¯ããªããŒåã
ãããã®ãæãŸãããã«ãã©ãŒã¯ãéã€ãªã³ã«å¯Ÿ
ãïŒåœéæ§ãããã¯ïŒåœéæ§ã®ã©ã¡ãã§ãããã
åãè²è£æ£ã®å¹æããã€ã«ã©ãŒãã«ãã©ãŒããã
ãã¯çŸåã«ãšããªã€ãŠçŸåæå¶å€ãŸãã¯çŸåä¿é²
å€ãæŸåºããã«ãã©ãŒïŒããããDIRã«ãã©ãŒãŸ
ãã¯DARã«ãã©ãŒïŒã§ãã€ãŠãããã åãDIRã«ãã©ãŒä»¥å€ã«ããã«ãããªã³ã°åå¿
ã®çæç©ãç¡è²ã§ãã€ãŠãçŸåæå¶å€ãæŸåºãã
ç¡åè²DIRã«ãããªã³ã°ååç©ãå«ãã§ãããã DIRã«ãã©ãŒä»¥å€ã«çŸåã«ãšããªã€ãŠçŸåæå¶
å€ãæŸåºããååç©ãæå ææäžã«å«ãã§ãã
ãã äžèšã«ãã©ãŒçã¯ãæå ææã«æ±ããããç¹æ§
ãæºè¶³ããããã«åäžå±€ã«äºçš®é¡ä»¥äžã䜵çšãã
ããšãã§ããããåäžã®ååç©ãç°ãªã€ãïŒå±€ä»¥
äžã«æ·»å ããããšãããã¡ããå·®æ¯ããªãã å®æœäŸ ïŒ ããªã¢ã»ãã«ã»ã«ããŒã¹æ¯æäœäžã«ãäžèšã«ç€º
ããããªçµæã®åå±€ãããªãå€å±€ã«ã©ãŒæå ææ
ãäœè£œããã 第ïŒå±€ïŒãã¬ãŒã·ãšã³é²æ¢å±€ é»è²ã³ãã€ãéãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒäžéå±€ ïŒïŒïŒâãžâïœâãªã¯ãã«ãã€ããããã³ã®
ä¹³ååæ£ç©ãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒäœæ床赀æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠâŠéå¡åž
é1.6ïœïŒm2 å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠ1.5Ã10-5ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.04ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.003ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.0006
ã¢ã« 第ïŒå±€ïŒé«æ床赀æä¹³å€å±€ 溶èåéä¹³å€ïŒæ²åéïŒ10ã¢ã«ïŒ ïŒâŠâŠéå¡åž
é1.4ïœïŒm2 å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠ1.2Ã10-5ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.2ã¢ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.0016
ã¢ã« 第ïŒå±€ïŒäžéå±€ 第ïŒå±€ãšåã 第ïŒå±€ïŒäœæ床ç·æä¹³å€å±€ ååæ£æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠâŠ
å¡åžéé1.29ïŒm2 å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠïŒÃ10-5ã¢ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.05ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.08ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.0015
ã¢ã« 第ïŒå±€ïŒé«æ床ç·æä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒ10ã¢ã«ïŒ ïŒâŠâŠå¡åžé
é1.3ïŒm2 å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠ2.5Ã10-5ã¢
ã« å¢æè²çŽ âŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.8Ã10-5ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.017ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.03ã¢
ã« ã«ãã©ãŒEXâ10âŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.003ã¢
㫠第ïŒå±€ïŒã€ãšããŒãã€ã«ã¿ãŒå±€ ãŒã©ãã³æ°Žæº¶æ¶²äžã«é»è²ã³ãã€ãéãšïŒïŒïŒ
âãžâïœãªã¯ãã«ãã€ããããã³ã®ä¹³ååæ£ç©
ãšãå«ããŒã©ãã³å±€ 第ïŒå±€ïŒäœæ床éæä¹³å€å±€ æ²èåéä¹³å€ïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠâŠå¡åžé
é0.7ïŒm2 ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.25ã¢
ã« ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.015ã¢
㫠第10å±€ïŒé«æ床éæä¹³å€å±€ æ²èåéïŒæ²åéïŒïŒã¢ã«ïŒ ïŒâŠâŠå¡åžéé
0.6ïŒm2 ã«ãã©ãŒEXâïŒâŠâŠéïŒã¢ã«ã«å¯ŸããŠ0.06ã¢
㫠第11å±€ïŒç¬¬ïŒä¿è·å±€ æ²èåéïŒæ²åéïŒã¢ã«ïŒ ïŒå¹³åç²åŸ0.07ÎŒïŒ
âŠâŠå¡åžéé0.5ïœ çŽ«å€ç·åžåå€UVâïŒã®ä¹³ååæ£ç©ãå«ã
ãŒã©ãã³å±€ 第12å±€ïŒç¬¬ïŒä¿è·å±€ ããªã¡ãã«ã¡ã¿ãã¢ã¯ãªã¬ãŒãç²åïŒçŽåŸçŽ
1.5ÎŒïŒãå«ããŒã©ãã³å±€ãå¡åžã åå±€ã«ã¯äžèšçµæç©ã®ä»ã«ããŒã©ãã³ç¡¬åå€
âïŒãçé¢æŽ»æ§å€æ·»å ããã 以äžã®åŠãããŠè©Šæãäœè£œããã è©Šæäœãã®ã«çšããååç© å¢æè²çŽ ïŒã¢ã³ãããâïŒã»5â²âãžã¯ããâ
ïŒã»3â²âãžâïŒÎ³âã¹ã«ããããã«ïŒâïŒâãšã
ã«âãã¢ã«ã«ãã·ã¢ãã³ãããããµã€ãã»ããª
ãžããŠã å¡© å¢æè²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»3â²â
ãžâïŒÎ³âã¹ã«ããããã«ïŒâïŒã»ïŒã»4â²ã»5â²â
ãžãã³ãŸãã¢ã«ã«ãã·ã¢ãã³ããããã·ãµã€
ãã»ããªãšãã«ã¢ãã³å¡© å¢æè²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»5â²â
ãžã¯ããâïŒã»3â²âãžâïŒÎ³âã¹ã«ããããã«ïŒ
ãªããµã«ã«ãã·ã¢ãã³ã»ãããªãŠã å¡© å¢æè²çŽ ïŒã¢ã³ãããâïŒâãšãã«âïŒã»ïŒã»
5â²ã»6â²âããã©ã¯ããâïŒïŒ1â²âãžãšãã«â
ïŒã»3â²âãžâïœÎ²âãβâïŒÎ³âã¹ã«ããããã«ïŒ
ãšããã·ããšãã«ïœãã³ãŸã€ãããŸãã«ã«ãã·
ã¢ãã³ãããããµã€ããããªãŠã å¡©
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
âïŒ
H2CHCSO2CH2CONH
ïŒCH2ïŒ2NHCOCH2SO2CHïŒCH2
ïŒCH2ïŒ2NHCOCH2SO2CHïŒCH2
ãåã
ãã®åçèŠçŽ ã«ãã¿ã³ã°ã¹ãã³å
æºãçšããã
ã€ã«ã¿ãŒã§è²æž©åºŠã4800°Kã«èª¿æŽãã25CMSã®
ã¯ãµãåé²å ãäžããåŸãäžèšã®åŠçå·¥çšã«åŸã€
ãŠ38âã§çŸååŠçãè¡ãªã€ãã ã«ã©ãŒçŸå ïŒå15ç§ æŒ çœ ïŒå20ç§ å® ç ïŒå20ç§ æ°Ž æŽ ïŒå15ç§ å® å® 30ç§ åå·¥çšã«çšããåŠç液çµæã¯äžèšã®éãã§ãã€
ãã ã«ã©ãŒçŸå液 ãã¬ãŒãå€ïŒç¬¬ïŒè¡šåç §ïŒ äºç¡«é žãããªãŠã 4.0ïœ çé žã«ãªãŠã 30.0ïœ èåã«ãªãŠã 1.4ïœ æ²åã«ãªãŠã 1.3mg ããããã·ã«ã¢ãã³ç¡«é žå¡© 2.4ïœ ïŒâïŒïŒ®âãšãã«ââβâããããã·ãšãã«ã¢
ããïŒâïŒâã¡ãã«ã¢ããªã³ç¡«é žå¡© 4.5ïœ æ°Žãå ã㊠1.0 PH10.0 æŒçœæ¶² ãšãã¬ã³ãžã¢ãã³åé ¢é žç¬¬äºéã¢ã³ã¢ããŠã å¡©
80.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žäºãããªãŠã å¡© 8.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°Žãå ã㊠1.0 PH6.0 å®ç液 ããã©ããªãªã³é žãããªãŠã 2.0ïœ äºç¡«é žãããªãŠã 4.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 氎溶液ïŒ70ïŒ ïŒ 175.0ml éäºç¡«é žãããªãŠã 4.6ïœ æ°Žãå ã㊠1.0 PH6.6 å®å®æ¶² ãã«ããªã³ïŒ40ïŒ ïŒ 8.0ml æ°Žãå ã㊠1.0 æŽã«äžèšã«ã©ãŒçŸå液ã«ãäžèšæŒçœæ¶²ã0.05ïŒ
åã³ã«ã«ã·ãŠã ã200ppmæ·»å ããæ·»å çŽåŸãšæŽ
ã«40âã§ïŒé±éçµéåŸã«ãããŠåæ§ã«åŠçããã
ãŸããïŒé±éçµéåŸã®ããããã·ã«ã¢ãã³æ®åé
åã³æ²æŸ±ã®æç¡ã確èªããã æå°æ¿åºŠéšã®å€åãšããããã·ã«ã¢ãã³æ®åé
ã第ïŒè¡šã«ç€ºããã
ã€ã«ã¿ãŒã§è²æž©åºŠã4800°Kã«èª¿æŽãã25CMSã®
ã¯ãµãåé²å ãäžããåŸãäžèšã®åŠçå·¥çšã«åŸã€
ãŠ38âã§çŸååŠçãè¡ãªã€ãã ã«ã©ãŒçŸå ïŒå15ç§ æŒ çœ ïŒå20ç§ å® ç ïŒå20ç§ æ°Ž æŽ ïŒå15ç§ å® å® 30ç§ åå·¥çšã«çšããåŠç液çµæã¯äžèšã®éãã§ãã€
ãã ã«ã©ãŒçŸå液 ãã¬ãŒãå€ïŒç¬¬ïŒè¡šåç §ïŒ äºç¡«é žãããªãŠã 4.0ïœ çé žã«ãªãŠã 30.0ïœ èåã«ãªãŠã 1.4ïœ æ²åã«ãªãŠã 1.3mg ããããã·ã«ã¢ãã³ç¡«é žå¡© 2.4ïœ ïŒâïŒïŒ®âãšãã«ââβâããããã·ãšãã«ã¢
ããïŒâïŒâã¡ãã«ã¢ããªã³ç¡«é žå¡© 4.5ïœ æ°Žãå ã㊠1.0 PH10.0 æŒçœæ¶² ãšãã¬ã³ãžã¢ãã³åé ¢é žç¬¬äºéã¢ã³ã¢ããŠã å¡©
80.0ïœ ãšãã¬ã³ãžã¢ãã³åé ¢é žäºãããªãŠã å¡© 8.0ïœ èåã¢ã³ã¢ããŠã 150.0ïœ æ°Žãå ã㊠1.0 PH6.0 å®ç液 ããã©ããªãªã³é žãããªãŠã 2.0ïœ äºç¡«é žãããªãŠã 4.0ïœ ããªç¡«é žã¢ã³ã¢ããŠã 氎溶液ïŒ70ïŒ ïŒ 175.0ml éäºç¡«é žãããªãŠã 4.6ïœ æ°Žãå ã㊠1.0 PH6.6 å®å®æ¶² ãã«ããªã³ïŒ40ïŒ ïŒ 8.0ml æ°Žãå ã㊠1.0 æŽã«äžèšã«ã©ãŒçŸå液ã«ãäžèšæŒçœæ¶²ã0.05ïŒ
åã³ã«ã«ã·ãŠã ã200ppmæ·»å ããæ·»å çŽåŸãšæŽ
ã«40âã§ïŒé±éçµéåŸã«ãããŠåæ§ã«åŠçããã
ãŸããïŒé±éçµéåŸã®ããããã·ã«ã¢ãã³æ®åé
åã³æ²æŸ±ã®æç¡ã確èªããã æå°æ¿åºŠéšã®å€åãšããããã·ã«ã¢ãã³æ®åé
ã第ïŒè¡šã«ç€ºããã
ãè¡šã
æ¬çºæïŒNo.ïŒã11ã12ã13ã16ïŒã«ããã°ãæŒ
çœæ¶²ã®æ·»å ã«ããã«ããªã¯ã»ãšãã©ãªããåãã
ãããã·ã«ã¢ãã³ã®å解ãé²æ¢ããããã€ãã«ã«
ã·ãŠã ã«åž°å ããæ²æŸ±ãçæããªãã ååç©âïŒã®æ·»å éãçžå¯Ÿçã«å€ãå ŽåïŒNo.
ïŒã10ïŒã¯ã«ããªã¯ãªããåãããããã·ã«ã¢ã
ã³ã®å解ãé²æ¢ãããŠããããã«ã«ã·ãŠã ã®æ²æŸ±
ãçæããã ãŸããNo.ïŒåã³No.ïŒã¯æ²æŸ±ã®çæã¯é²æ¢ãããŠ
ããããã«ããªåã³ïŒåã¯ããããã·ã«ã¢ãã³ã®
å解é²æ¢ã®ç¹ã§äžå åã§ããã 以äžã®ããã«ååç©âïŒã®æ·»å éãååç©
âïŒã«æ¯ã¹ãŠæ¯èŒçå€ããšïŒNo.ïŒã14ã15ïŒãæ²
柱ã¯çæããªãããã«ããªåã³ïŒåã¯ããããã·
ã«ã¢ãã³ã®å解é²æ¢ã®ç¹ã§äžå åã§ãããåãå
åç©âïŒã®æ·»å éãååç©âïŒã«æ¯ã¹ãŠéåžž
ã«å°ãªããšïŒNo.ïŒã10ïŒãæ²æŸ±ãçæããã å®æœäŸ ïŒ ä»¥äžã®ã«ã©ãŒçŸå液ã調液ããã èžçæ°Ž 800ml ãã³ãžã«ã¢ã«ã³ãŒã« 14ml ãžãšãã¬ã³ã°ãªã³ãŒã« 10ml äºç¡«é žãããªãŠã ïŒïœ èåã«ãªãŠã 0.5ïœ çé žãããªãŠã 30ïœ ïŒ®âãšãã«ââïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããš
ãã«ïŒâïŒâã¡ãã«âïŒâã¢ããã¢ããªã³ã¹ã«ã
ããŒã 5.0ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 4.0ïœ æ·»å å€ïŒç¬¬ïŒè¡šåç §ïŒ èžçæ°Žãå ã㊠1000ml PHïŒ10.00ã«åãããã ãã®ã«ã©ãŒçŸå液ã«Feã€ãªã³ãšããŠ1ppm
ïŒFeCl3溶液ïŒãåã³Caã€ãªã³ãšããŠ200ppm
ïŒCaïŒNO3ïŒ2溶液ïŒæ·»å ãã40âã§20æ¥éä¿åã
ãã ãã®åŸããããã·ã«ã¢ãã³åã³ã«ã©ãŒçŸåäž»è¬
ã®æ¿åºŠãåæããåæ²æŸ±ã®æç¡ã確èªããã çµæã第ïŒè¡šã«ç€ºãã
çœæ¶²ã®æ·»å ã«ããã«ããªã¯ã»ãšãã©ãªããåãã
ãããã·ã«ã¢ãã³ã®å解ãé²æ¢ããããã€ãã«ã«
ã·ãŠã ã«åž°å ããæ²æŸ±ãçæããªãã ååç©âïŒã®æ·»å éãçžå¯Ÿçã«å€ãå ŽåïŒNo.
ïŒã10ïŒã¯ã«ããªã¯ãªããåãããããã·ã«ã¢ã
ã³ã®å解ãé²æ¢ãããŠããããã«ã«ã·ãŠã ã®æ²æŸ±
ãçæããã ãŸããNo.ïŒåã³No.ïŒã¯æ²æŸ±ã®çæã¯é²æ¢ãããŠ
ããããã«ããªåã³ïŒåã¯ããããã·ã«ã¢ãã³ã®
å解é²æ¢ã®ç¹ã§äžå åã§ããã 以äžã®ããã«ååç©âïŒã®æ·»å éãååç©
âïŒã«æ¯ã¹ãŠæ¯èŒçå€ããšïŒNo.ïŒã14ã15ïŒãæ²
柱ã¯çæããªãããã«ããªåã³ïŒåã¯ããããã·
ã«ã¢ãã³ã®å解é²æ¢ã®ç¹ã§äžå åã§ãããåãå
åç©âïŒã®æ·»å éãååç©âïŒã«æ¯ã¹ãŠéåžž
ã«å°ãªããšïŒNo.ïŒã10ïŒãæ²æŸ±ãçæããã å®æœäŸ ïŒ ä»¥äžã®ã«ã©ãŒçŸå液ã調液ããã èžçæ°Ž 800ml ãã³ãžã«ã¢ã«ã³ãŒã« 14ml ãžãšãã¬ã³ã°ãªã³ãŒã« 10ml äºç¡«é žãããªãŠã ïŒïœ èåã«ãªãŠã 0.5ïœ çé žãããªãŠã 30ïœ ïŒ®âãšãã«ââïŒÎ²âã¡ã¿ã³ã¹ã«ãã³ã¢ãããš
ãã«ïŒâïŒâã¡ãã«âïŒâã¢ããã¢ããªã³ã¹ã«ã
ããŒã 5.0ïœ ããããã·ã«ã¢ãã³ç¡«é žå¡© 4.0ïœ æ·»å å€ïŒç¬¬ïŒè¡šåç §ïŒ èžçæ°Žãå ã㊠1000ml PHïŒ10.00ã«åãããã ãã®ã«ã©ãŒçŸå液ã«Feã€ãªã³ãšããŠ1ppm
ïŒFeCl3溶液ïŒãåã³Caã€ãªã³ãšããŠ200ppm
ïŒCaïŒNO3ïŒ2溶液ïŒæ·»å ãã40âã§20æ¥éä¿åã
ãã ãã®åŸããããã·ã«ã¢ãã³åã³ã«ã©ãŒçŸåäž»è¬
ã®æ¿åºŠãåæããåæ²æŸ±ã®æç¡ã確èªããã çµæã第ïŒè¡šã«ç€ºãã
ãè¡šã
æ¬çºæã«ããã°ãããããã·ã«ã¢ãã³åã³ã«ã©
ãŒçŸåäž»è¬ã®å£åãèããé²æ¢ããããã€ã«ã«ã·
ãŠã ã«åž°å ããæ²æŸ±ãçæããªãã æ¯èŒäŸNo.ïŒã¯ããããã·ã«ã¢ãã³åã³ã«ã©ãŒçŸ
åäž»è¬ã®å£åãé²æ¢ãããŠããããæ²æŸ±ãçæã
ãã æ¯èŒäŸNo.ïŒåã³No.ïŒã¯æ²æŸ±ãçæããªããä¿æ
æ§ã«å£ãã
ãŒçŸåäž»è¬ã®å£åãèããé²æ¢ããããã€ã«ã«ã·
ãŠã ã«åž°å ããæ²æŸ±ãçæããªãã æ¯èŒäŸNo.ïŒã¯ããããã·ã«ã¢ãã³åã³ã«ã©ãŒçŸ
åäž»è¬ã®å£åãé²æ¢ãããŠããããæ²æŸ±ãçæã
ãã æ¯èŒäŸNo.ïŒåã³No.ïŒã¯æ²æŸ±ãçæããªããä¿æ
æ§ã«å£ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ããã²ã³åéã«ã©ãŒæå ææã (1) è³éŠæ第äžçŽã¢ãã³ã«ã©ãŒçŸåäž»è¬ã (2) äžèšäžè¬åŒïŒïŒã§è¡šããããå°ããšãäžçš®
ã®ååç©ãåã³ (3) äžèšäžè¬åŒïŒïŒã§è¡šããããå°ããšãäžçš®
ã®ååç© ãå«æãããã€ãïŒïŒã®ååç©ã«å¯ŸããŠïŒïŒ
ã®ååç©ã®æ¿åºŠãã¢ã«æ¯ã§3.0ã20åã«ãªããã
ã«å«æããã«ã©ãŒçŸå液ã«ãŠåŠçããããšãç¹åŸŽ
ãšããããã²ã³åéã«ã©ãŒæå ææã®åŠçæ¹æ³ã ãåã ãåã ïŒåŒäžãïœã¯ïŒåã¯ïŒãè¡šãããã¯äœçŽã¢ã«ã
ã«åºãè¡šãããïŒã¯åäžã§ãç°ãªã€ãŠããŠãè¯
ããæ°ŽçŽ ååãã¢ã«ã«ãªéå±ååãŸãã¯ã¢ã³ã¢ã
ãŠã ãè¡šãããïŒ
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP166784A JPS60144739A (ja) | 1984-01-09 | 1984-01-09 | ããã²ã³åéã«ã©âæå ææã®åŠçæ¹æ³ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP166784A JPS60144739A (ja) | 1984-01-09 | 1984-01-09 | ããã²ã³åéã«ã©âæå ææã®åŠçæ¹æ³ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60144739A JPS60144739A (ja) | 1985-07-31 |
JPH0578026B2 true JPH0578026B2 (ja) | 1993-10-27 |
Family
ID=11507866
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP166784A Granted JPS60144739A (ja) | 1984-01-09 | 1984-01-09 | ããã²ã³åéã«ã©âæå ææã®åŠçæ¹æ³ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60144739A (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0711696B2 (ja) * | 1987-02-20 | 1995-02-08 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ |
JPH07111567B2 (ja) * | 1987-03-25 | 1995-11-29 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéã«ã©ãŒåçæå ææã®åŠçæ¹æ³ |
-
1984
- 1984-01-09 JP JP166784A patent/JPS60144739A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS60144739A (ja) | 1985-07-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPH0246932B2 (ja) | ||
US4596764A (en) | Method of processing image-wise exposed silver halide color photographic material | |
JPH0246933B2 (ja) | ||
EP0675406B1 (en) | A method of processing using a low volume thin tank processing system | |
JPS6116066B2 (ja) | ||
JPH068956B2 (ja) | ããã²ã³åéã«ã©âæå ææã®åŠçæ¹æ³ | |
JPS6320335B2 (ja) | ||
JPS6024464B2 (ja) | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ | |
JPH0419538B2 (ja) | ||
JPS606506B2 (ja) | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ | |
JPH0251493B2 (ja) | ||
DE60203036T2 (de) | Verfahren zur Entwicklung eines photographischen Elementes, das einen ein ElektronenÌbertragungsmittel Freisetzenden Kuppler enthÀlt | |
US4554242A (en) | Method for processing color photographic light-sensitive material | |
JPH0257297B2 (ja) | ||
JPH0578026B2 (ja) | ||
JPS6144304B2 (ja) | ||
JPH0789211B2 (ja) | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ | |
JPS6320339B2 (ja) | ||
JPS6141145A (ja) | ããã²ã³åéã«ã©âåçæå ææã®åŠçæ¹æ³ | |
JP3371046B2 (ja) | æŒçœæ¶²ã®èª¿è£œæ¹æ³ | |
US6489089B1 (en) | Bleach/fix solution for single-use silver removal in color negative films | |
JPS6144305B2 (ja) | ||
JPH07122740B2 (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPS62108252A (ja) | ã«ã©âç»å圢ææ¹æ³ | |
JP2942889B2 (ja) | ããã²ã³åéã«ã©ãŒåçç»å圢ææ¹æ³ |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |