JPH0577057B2 - - Google Patents
Info
- Publication number
- JPH0577057B2 JPH0577057B2 JP60254960A JP25496085A JPH0577057B2 JP H0577057 B2 JPH0577057 B2 JP H0577057B2 JP 60254960 A JP60254960 A JP 60254960A JP 25496085 A JP25496085 A JP 25496085A JP H0577057 B2 JPH0577057 B2 JP H0577057B2
- Authority
- JP
- Japan
- Prior art keywords
- silver halide
- group
- emulsion
- sensitive
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 silver halide Chemical class 0.000 claims description 97
- 239000000839 emulsion Substances 0.000 claims description 86
- 229910052709 silver Inorganic materials 0.000 claims description 71
- 239000004332 silver Substances 0.000 claims description 71
- 239000000463 material Substances 0.000 claims description 23
- 230000035945 sensitivity Effects 0.000 claims description 18
- 230000003287 optical effect Effects 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 63
- 238000000034 method Methods 0.000 description 42
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 28
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 26
- 239000002245 particle Substances 0.000 description 25
- 239000000243 solution Substances 0.000 description 21
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 18
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 18
- 108010010803 Gelatin Proteins 0.000 description 17
- 229920000159 gelatin Polymers 0.000 description 17
- 239000008273 gelatin Substances 0.000 description 17
- 235000019322 gelatine Nutrition 0.000 description 17
- 235000011852 gelatine desserts Nutrition 0.000 description 17
- 239000011780 sodium chloride Substances 0.000 description 13
- 238000003860 storage Methods 0.000 description 12
- 238000011161 development Methods 0.000 description 11
- 230000018109 developmental process Effects 0.000 description 11
- 206010070834 Sensitisation Diseases 0.000 description 10
- 230000008313 sensitization Effects 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 229910001961 silver nitrate Inorganic materials 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 239000011630 iodine Substances 0.000 description 6
- 239000011259 mixed solution Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 6
- 229910021607 Silver chloride Inorganic materials 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000001235 sensitizing effect Effects 0.000 description 5
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 125000004421 aryl sulphonamide group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000000586 desensitisation Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- PMWJOLLLHRDHNP-UHFFFAOYSA-N 2,3-dioctylbenzene-1,4-diol Chemical compound CCCCCCCCC1=C(O)C=CC(O)=C1CCCCCCCC PMWJOLLLHRDHNP-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical group NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 2
- 125000005153 alkyl sulfamoyl group Chemical group 0.000 description 2
- 125000004422 alkyl sulphonamide group Chemical group 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000005129 aryl carbonyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000005070 ripening Effects 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical group C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 101150006989 NDEL1 gene Proteins 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- LHLMOSXCXGLMMN-CLTUNHJMSA-M [(1s,5r)-8-methyl-8-propan-2-yl-8-azoniabicyclo[3.2.1]octan-3-yl] 3-hydroxy-2-phenylpropanoate;bromide Chemical compound [Br-].C([C@H]1CC[C@@H](C2)[N+]1(C)C(C)C)C2OC(=O)C(CO)C1=CC=CC=C1 LHLMOSXCXGLMMN-CLTUNHJMSA-M 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 1
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 description 1
- 125000004391 aryl sulfonyl group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- XNSQZBOCSSMHSZ-UHFFFAOYSA-K azane;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxymethyl)amino]acetate;iron(3+) Chemical compound [NH4+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O XNSQZBOCSSMHSZ-UHFFFAOYSA-K 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 229910001864 baryta Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 150000001661 cadmium Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- KYQODXQIAJFKPH-UHFFFAOYSA-N diazanium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [NH4+].[NH4+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O KYQODXQIAJFKPH-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- UETZVSHORCDDTH-UHFFFAOYSA-N iron(2+);hexacyanide Chemical compound [Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UETZVSHORCDDTH-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- HNQIVZYLYMDVSB-UHFFFAOYSA-N methanesulfonimidic acid Chemical group CS(N)(=O)=O HNQIVZYLYMDVSB-UHFFFAOYSA-N 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- QWOKKHXWFDAJCZ-UHFFFAOYSA-N octane-1-sulfonamide Chemical group CCCCCCCCS(N)(=O)=O QWOKKHXWFDAJCZ-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000003921 particle size analysis Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- JVUYWILPYBCNNG-UHFFFAOYSA-N potassium;oxido(oxo)borane Chemical compound [K+].[O-]B=O JVUYWILPYBCNNG-UHFFFAOYSA-N 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- SOUHUMACVWVDME-UHFFFAOYSA-N safranin O Chemical compound [Cl-].C12=CC(N)=CC=C2N=C2C=CC(N)=CC2=[N+]1C1=CC=CC=C1 SOUHUMACVWVDME-UHFFFAOYSA-N 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical group NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03535—Core-shell grains
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Description
ãç£æ¥äžã®å©çšåéã
æ¬çºæã¯ãããã²ã³åéã«ã©ãŒåçæå
ææã«
é¢ãããæŽã«è©³ããã¯ãæ¯æäœäžã«å°ãªããšãçº
è²æ§ã®ç°ãªãïŒçš®ä»¥äžã®æè²æ§å±€ãæããæå æ
æã§ãã€ãŠãçè©Šæå³ã¡é²å åè©Šæã®ä¿åæ§ã«åª
ããäžã€é²å åã®å§åã«ããå¢æã«ããªãæå¶ã§
ããããã²ã³åéå€å±€ã«ã©ãŒåçæå ææã«é¢ã
ããæ¬çºæã®æå ææã¯ãç¹ã«ã«ã©ãŒããªã³ãçš
æå ææïŒä»¥äžã«ã©ãŒããŒããŒãšç§°ããïŒã«å¥œé©
ã«é©çšããããšãã§ããã ãåŸæ¥ã®æè¡ã æ¯æäœäžã«è€æ°ã®æè²æ§å±€ãæããããã²ã³å
éã«ã©ãŒåçæå ææã«ãããŠã¯ãæ¯æäœããæ
ãé ãæå å±€ã¯ãæãå€åŽã«è¿ãé¢ä¿äžãå€éšã
ãã®å€åèŠå ãããªãã¡ç±ã湿床ãå§åã«å¯ŸããŠ
ä»ã®å±€ãããææã§ããã äŸãã°ã«ã©ãŒããŒããŒã®å Žåã¯ãæ¯æäœããæ
ãé ãæå å±€ã¯éåžžèµ€æå æ§å±€ã§ãããåŸã€ãŠã
ã®èµ€æå æ§å±€ãä»ã®ïŒå±€ã€ãŸãéæå æ§å±€ã»ç·æ
å æ§å±€ãããå€éšå€åèŠå ã«å¯ŸããŠææã§ããã æ¬çºæè ãã®ç 究ã«ããã°ãèµ€æå æ§ããã²ã³
åéä¹³å€ã¯ããããã€ãç¶æ³ãã次ã®ïŒç¹ã®æ¬ ç¹
ãåºæãã 第ïŒç¹ã¯ãçè©Šæã€ãŸãé²å åè©Šæã®ä¿åæ§ã®
åé¡ã§ãããæ¯æäœããæãé ãå±€ïŒã«ã©ãŒããŒ
ããŒã§ã¯éåžžèµ€æå æ§å±€ïŒã¯ãå€éšããã®ç±ã湿
床ãé žçŽ çã®åœ±é¿ã«ãããé²å åã®æ床å€åç¹ã«
æžæãçãæããä»ã®ïŒå±€ãšã®æ床ãã©ã³ã¹ã厩
ããã ã©ãïŒçŸåæïŒã«ãããŠã¯ãäžåºŠèšå®ããæ¡ä»¶
ãåããŒããŒæ¯ã«å€æŽããããšã¯äºå®äžäžå¯èœã§
ããã®ã§ãåžžã«åäžãªæ§èœãæã€ãæå ææãèŠ
æ±ãããäžèšã®ããã«æ床ãã©ã³ã¹ã厩ããããš
ã¯ãã©ãã§ã®æ©çããäœäžãããããšã«ã€ãªã
ããåŸã€ãŠçè©Šæä¿åäžã§ã®æ床ãé調ãã«ããª
ã®ãã©ã³ã¹ã®åŽ©ããªã補åã®éçºãå¿ èŠã§ããã 第ïŒç¹ã¯ãå§åã«ããã«ããªç¹ã«å¢æã«ããªã®
åé¡ã§ãããè¿å¹Žãçç£å·¥çšã®é«éåãé«éããª
ã³ã¿ãŒã®éçºçã«ãããå€éšããã®å§åã¯çš®ã ã®
圢ã§å ããããã«ãªã€ããç¹ã«å§åã«ãããèµ€æ
å æ§ä¹³å€ã¯å¢æãæžæãçãæããç¹ã«å¢æã«ã
ãã«ããªã¯ãããªã³ãã®å質ãèããå£åããã
ã®ã§æ¹è¯ãæãŸããã äžèšç¬¬ïŒç¹ã®ãçè©Šæã®ä¿åæ§æ¹è¯ã®æè¡ã«ã€
ããŠã¯ãåŸæ¥ããã2Ræ³ãå¢æè²çŽ ãå®å®å€ãª
ã©ã®çš®é¡ã»éã»çµåãçã§ãæ°å€ãã®ææ¡ããªã
ããŠããããããããããæªã äžå åã§ãããäž
å±€ä¿åæ§ãæ¹åãããæå ææãæãŸããŠããã 第ïŒç¹ã®ãå§åå¹æã«ã€ããŠã¯ãå€ãããã±
ã€ã»ããŒã»ã¡ã€ã¶ããžã€ãŒãã«ã»ãªãã»ãªããã€
ã«ã«ã»ãœãµãšãã€ã»ãªãã»ã¢ã¡ãªã«ãïŒK.B.
MatherïŒJ.Opt.Soc.Am.ïŒ38ïŒ1054ïŒ1948ïŒãã
ããŒã»ãã¢ãŒã¬ã³ã¹ïŒããŒã»ãã»ã¹ã¡ããããœãŒ
ã·ã€ã«ã»ãšã»ã€ã³ãã¹ããªã¢ã«ã»ããªãã°ã©ã
ã€ãïŒP.FaelenceïŒand P.de SmetïŒScl.et Ind.
Phot.ïŒ25ïŒNo.ïŒïŒ178ïŒ1954ïŒããããŒã»ãã¢ãŒ
ã¬ã³ã¹ããžã€ãŒãã«ã»ãªãã»ããªãã°ã©ãã€ã
ã¯ã»ãµã€ãšã³ã¹ãïŒP.FaelenceïŒJ.Phot.Sci.ïŒïŒïŒ
105ïŒ1954ïŒçã«è©³çŽ°ã«èšèŒãããŠããããå ·äœç
ãªå¯Ÿçã«ã€ããŠã¯èšèŒããªãã å§åç¹æ§ãæ¹è¯ããæ段ãšããŠãããªããŒãä¹³
åç©ãªã©ã®å¯å¡å€ãå«æãããæ¹æ³ãããã²ã³å
éä¹³å€ã®ããã²ã³åéïŒãŒã©ãã³æ¯ãå°ãããã
çã®æ¹æ³ã§ãå§åãç²åã«å°éãããªãæ¹æ³ãã
ãã äŸãã°ç°ç¯ç°ç¶ååç©ãçšãããã®ïŒè±åœç¹èš±
第738618å·ïŒãã¢ã«ãã«ãã¿ã¬ãŒããçšãããã®
ïŒå738637å·ïŒãã¢ã«ãã«ãšã¹ãã«ãçšãããã®
ïŒå738639å·ïŒãå€äŸ¡ã¢ã«ã³ãŒã«ãçšãããã®ïŒç±³
åœç¹èš±ç¬¬2960404å·ïŒãã«ã«ããã·ã¢ã«ãã«ã»ã«ã
ãŒã¹ãçšãããã®ïŒå3121060å·ïŒããã©ãã€ã³ãš
ã«ã«ãã³é žå¡©ãçšãããã®ïŒç¹éæ49â5017å·ïŒã
ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããšææ©é žãçšãããã®ïŒç¹
å ¬æ53â28086å·ïŒçãææ¡ãããŠããã ããããå¯å¡å€ãæ·»å ãããšãä¹³å€å±€ã®æ©æ¢°ç
匷床ãäœããªãã䜿çšéã«ã¯éçãããããŸããŒ
ã©ãã³ãå¢ãããšçŸååŠçé床ãé ããªãããã€
ãŠãããã®åŸæ¥æè¡ããååãªå¹æã¯éæãé£
ãããã®ãããªããšãããç²åèªäœå¿åã«ããªã
çºçãã«ãããã®ãæãŸãããã®éçºãèŠæãã
ãŠããã ãããäžè¿°ã®æç®ã«ã¯ãå§åã«ããªãæ¹åãã
æè¡ã¯äœã瀺ãããŠããªãã ç¹éæ58â9137å·æ现æžçã«ã¯ãç²åå éšã«ãš
ãŒãååžããããããšå§åæžæãçããããšãèš
èŒãããŠããããå¿åã«ããªã®æ¹åã«é¢ããèšèŒ
ã¯å šããªãã å€å±€æ§é ãæããããã²ã³åéç²åèªäœã«ã€ã
ãŠã¯ããžã€ãŒãã«ã»ãªãã»ããªãã°ã©ãã€ãã¯ã»
ãµã€ãšã³ã¹ïŒJ.Photo.Sci.ïŒïŒ24ïŒ198ïŒ1976ïŒã«
AgBrïŒAgBrIïŒæ²çŽ å«æç18ãŸãã¯32ã¢ã«
ïŒ ïŒïŒAgBrãããªãäžå±€æ§é ã®ããã²ã³åéç²
åã«ã€ããèšåããªãããŠããããããããã«ã
å§åã«ããªã«ã€ããŠã®ç€ºåã¯ãªãã ç±³åœç¹èš±ç¬¬2592250å·ãããã€ãç¹èš±ç¬¬1169290
å·ãã€ã®ãªã¹ç¹èš±ç¬¬1027146å·ãç±³åœç¹èš±ç¬¬
3206313å·ãç±³åœç¹èš±ç¬¬2756148å·çã«ã¯ãå éšæœ
ååããã²ã³åéä¹³å€ããããã«è¡šé¢ååŠå¢æã
æœãããã®ãèšèŒãããŠããããå§åã«ããªã®æ¹
è¯ã¯äžå åã§ããã ãã®ä»ã³ã¢ïŒã·ãšã«ä¹³å€ã«é¢é£ããŠæ°ã ã®ææ¡
ããªãããŠããããåŸæ¥ã®æè¡ã¯ããããäžèšïŒ
ç¹ã«ã€ããŠæ¹è¯ãäžå åããä¹è³ã¯ãã®åé¡ç¹ã®
解決ã«èæ ®ãæã€ãŠããªãããŸããã«ã©ãŒããŒã
ãŒã«é©çšããããšãããšããšãŒãå«æçã®åé¡ãª
ã©ã§é£ç¹ã倧ãããã®ã§ãã€ããããïŒç¹éæ49
â140444å·ãã®ä»ïŒã ãçºæã®ç®çã æ¬çºæã¯äžèšåŸæ¥æè¡ã®åé¡ç¹ã解決ããŠãç
è©Šæã®ä¿åæ§ãè¯ãããã€å§åã«ããªãªã©ãçã
ãªãããã²ã³åéã«ã©ãŒåçæå ææãæäŸãã
ããšãç®çãšããã ãçºæã®æ§æåã³äœçšã æ¬çºæè ãã¯çš®ã ç 究ã®çµæãæ¯æäœäžã«å°ãª
ããšãæè²æ§ã®ç°ãªãïŒçš®ä»¥äžã®æè²æ§å±€ãæã
ãããã²ã³åéã«ã©ãŒåçæå ææã§ãã€ãŠãæ¯
æäœããæãé ãæå æ§ããã²ã³åéä¹³å€å±€ãã
ã¬åãšãªãããã«ãå³ã¡å åŠæ¿åºŠã«ãããŠãã«ã
ãªïŒ0.1ãã®æ床ç¹ããšã€ãå Žåã®æé©æ床ã®60
ïŒ ä»¥äžã«ãªãããã«ååŠå¢æãæœãããã³ã¢ïŒã·
ãšã«æ§é ãæããå éšæœååããã²ã³åéç²åã
å«æãããã®ã«ãããäžèšç®çãéæãããããš
ãèŠãåºããã æ¬çºæã®æå ææã¯ãäžèšã®ããã«æ¯æäœãã
æãé ãããã²ã³åéä¹³å€å±€ãã³ã¢ïŒã·ãšã«æ§é
ã®å éšæœååããã²ã³åéç²åãå«æãããã®ç²
åã¯ãã¬åãšãªãããã«ååŠå¢æãæœããããã®
ã§ããã®ã§ãããã«ãã該乳å€å±€ãå€éšå€åèŠå
ã«åœ±é¿ãããŠä¿åæ§ã®å£åãå§åã«ããªã®åé¡ã
çããããšãæå¶ã§ããã ãã®çµæãå€éšå€åèŠå ã®åœ±é¿ãæãåãæã
æ¯æäœããæãé ãåŽã®ä¹³å€å±€ã¯ãåŸæ¥ä¿åæ§ã
å£åãããªã©ã®ããšã«ããä»å±€ãšã®ãã©ã³ã¹ãã
ãããç¹ã«æ床ãã©ã³ã¹ãããããå Žåããã€ã
ã®ããæ¬çºæã§ã¯è©²ä¹³å€å±€ã®ä¿åæ§ãæ¹è¯ããã
ã®ã§ãæ床ãã©ã³ã¹ãªã©ãããããªããšããäœçš
ãããããããã ãã€ãæ¬çºæã®æå ææã¯å§åã«ããªãæ¹è¯ã
ãããããããå§åã«ããªã®é²æ¢å¹æã¯ãããã²
ã³åéãå éšæœååã«ããããšã«ããååŠå¢æã®
ãããæ¹ãå€åããããšã«ãããã«ããªã®çºçã
å°ãªããªããã®ãšæšå®ãããã æ¬çºæã®ã«ã©ãŒåçæå ææã¯ãæ¯æäœäžã«å°
ãªããšãæè²æ§ã®ç°ãªãïŒçš®ä»¥äžã®æè²æ§å±€ãæ
ããããäŸãã°äžè¬ã®ã«ã©ãŒããŒããŒã®åŠãæ¯æ
äœäžã«é ã«éææ§ããã²ã³åéä¹³å€å±€ãäžéå±€ã
ç·ææ§ããã²ã³åéä¹³å€å±€ã第1UVå±€ãèµ€ææ§
ããã²ã³åéä¹³å€å±€ã第2UVå±€ããããã¯ãå±€
ãå¡èšããŠãèšïŒå±€æ§æãšããããšãã§ãããã
ã®æ§æã«ãããŠã¯æ¯æäœããæãé ãæå æ§å±€
ã¯ãèµ€ææ§ããã²ã³åéä¹³å€å±€ã§ããã æ¬çºæã«ãããŠãããã¬åãšãªãããã«ååŠå¢
æãæœãããšã¯ãå åŠæ¿åºŠã«ãããŠãã«ããªïŒ
0.1ãã®æ床ç¹ããšã€ãå Žåã®æé©æ床ã®60ïŒ ä»¥
äžã«ãªãããã«ååŠå¢æãããšããããšãæå³ã
ããããã®ãšããç¹éæ59â140444å·ã®æ¹æ³ã«åŸ
ã€ãŠãååŠå¢æã®çšåºŠã決å®ããããšãå¯èœã§ã
ãã ååŠå¢æã¯ãåŸèšããåçš®ã®ååŠå¢ææè¡ãçš
ããŠè¡ãããšãã§ããã æ¬çºæã«ãããŠã³ã¢ïŒã·ãšã«æ§é ãšã¯ãã³ã¢ã€
ãŸãç²åå éšãšã·ãšã«ã€ãŸããã以å€ã®è¡šå±€éšãš
ã§ååŠçµæãã®ä»ååŠçæ§è³ªããç©ççæ§è³ªã®ç°
ãªããã®ããããäŸãã°ã³ã¢ãšã·ãšã«ãšã§ããã²
ã³åéçµæã®ç°ãªããã®ã®ã»ããåäžããã²ã³å
éçµæã§ã¯ããããããããç©å±€åä¹³å€ã§ããã
ã®ãå«ãããã®å Žåã¯ãã³ã¢ãååŠå¢æãªã©ã
ãŠãå éšæœååã«ããæ¬çºæã®ä¹³å€ã«å¥œé©ã«é©çš
ã§ããã ã³ã¢ïŒã·ãšã«æ§é ã®å±€æ°ã¯ãã³ã¢ãšã·ãšã«ã
åã ïŒã€ãã€ã®ïŒå±€æ§é ã§ããïŒå±€ä»¥äžã®æ§é ã§
ãããã ã³ã¢ïŒã·ãšã«æ§é ã¯ãå±€ã圢æããã«å åãªè¢«
èŠå±€ã®ããã²ã³åéã«ããæ§æãããã®ã§ãªããš
ãè¯ããããªãã¡ç¬¬ïŒå³ã«æš¡åŒçã«ç¥ç€ºãããã
ã«å®å šã«è¢«èŠå±€ïœãæ§æãããŠããã®ã§ãã第ïŒ
å³ã«åããç¥ç€ºããããã«å±åšå±€ïœãšãªã€ãŠãã
ã®ã§ããå¹æãåŸãããã°è¯ãã æ¬çºæã«ãããŠã¯ãåèšã®åŠãå¿ ãããããã²
ã³åéçµæãç°ãªããªããŠãããã®ã§ãããã²ã³
åéãšããŠèåéãæ²èåéãæ²å¡©åéãå¡©èå
éãåã³å¡©åéçã®éåžžã®ããã²ã³åéä¹³å€ã«äœ¿
çšãããä»»æã®ãã®ãé©å®æ段ã§ã³ã¢ïŒã·ãšã«æ§
é ãšããŠçšããããšãã§ããã 奜ãŸããã¯ãããã²ã³åéãšããŠå¡©èåéãçš
ããã®ã奜ãŸãããã«ã©ãŒããŒããŒçšããã²ã³å
éãšããŠã¯ãè±éæ§ã®èŠ³ç¹ãããšãŒãããŸã€ãã
å«ãŸãªããããããã¯å«ãã§ãæ°ã¢ã«ïŒ 以äžã奜
ãŸãããæ ã«ãšãŒãã®å«æçã¯å¥œãŸããã¯ïŒãïŒ
ã¢ã«ïŒ ãæŽã«å¥œãŸããã¯ãŸã€ããå«ãŸãªããã®ã
è¯ãã ãŸãã³ã¢ãšã·ãšã«ã®å¡©èåéã«ãããèçŽ ã®æ··
åæ¯çã¯ãç¹ã«å¶éã¯ãªããã奜ãŸããã¯ãã³ã¢
ãšã·ãšã«ã§ã®èçŽ å«æçã¯25ã¢ã«ïŒ å·®ãããããš
ãæ¬çºæã«é©ããŠãããæŽã«ããã²ã³åéç²åã®
ç·èçŽ å«æçã¯40ã70ã¢ã«ïŒ ã§ããããšã奜ãŸã
ãã ã³ã¢ãšã·ãšã«ãšã®å¢çã®ç¶æ ãäŸãã°å¢çã«ã
ããèåéå«æçã®å€åã¯ãé£ç¶çã段éççä»»
æã§ãããã³ã¢ã¯ãã®äžéšïŒäŸãã°è£œé ã«ããã
çš®ç²åã«çžåœããéšåçïŒã«èåéå«æçãïŒã®
éšåããã€ãŠãå·®æ¯ããªããã·ãšã«ã®åãã¯ã³ã¢
ã®å¥œãŸããçŽ è³ªãé èœãã¬åãã§ããããã€éã«
ã³ã¢ã®å¥œãŸãããããçŽ è³ªãé èœããã«è¶³ãåã¿
ã§ããããšããããå ·äœçã«ã¯ãäžèšã·ãšã«ã®å
ãã0.01ã0.3ÎŒmã®ç¯å²ã§ããããã²ã³åéç²å
ã§ããããšã奜ãŸããã æ¬çºæã«çšããããããã²ã³åéç²åã¯ãäžèš
ã®ã³ã¢ïŒã·ãšã«åã®ããã²ã³åéç²åãåäžãã
ã²ã³åéä¹³å€å±€ã«ãããå šç²åã®70ïŒ ä»¥äžãå«ã
ã§ããããšã奜ãŸãããç¹ã«å šç²åãã³ã¢ïŒã·ãš
ã«åããã²ã³åéç²åã§ããããšã奜ãŸããã ãããã³ã¢ïŒã·ãšã«åããã²ã³åéç²åã¯åç¬
ã§äœ¿çšããŠããããå¹³åç²ååŸã®ç°ãªãïŒçš®ä»¥äž
ã®ããã²ã³åéç²åãä»»æã«æ··åããŠäœ¿çšããã®
ã奜ãŸããã ãŸããèåéå«æçã®ç°ãªãã³ã¢ïŒã·ãšã«åã®
ããã²ã³åéç²åãïŒçš®ä»¥äžæ··åããŠå¥œãŸãã䜿
çšããããšãã§ããã æ¬çºæã®ä¹³å€äžã®ããã²ã³åéç²åã®ç²åŸååž
ã¯å€åæ£ã§ãã€ãŠããååæ£ã§ãã€ãŠããããã
ååæ£ä¹³å€ã§ããããšããã奜ãŸãããããã§å
åæ£ä¹³å€ãšã¯ãä¹³å€äžã«å«æãããããã²ã³åé
ç²åã®ç²åŸååžã«ãããŠããã®å€åä¿æ°ã22ïŒ ä»¥
äžã奜ãŸããã¯20ïŒ ä»¥äžãæŽã«å¥œãŸããã¯15ïŒ ä»¥
äžã§ãããããªä¹³å€ããããå€åä¿æ°ã¯ç²åŸååž
ã®åºãã瀺ãä¿æ°ã§æ¬¡åŒã«ãã€ãŠå®çŸ©ãããã å€åä¿æ°ïŒç²åŸååžã®æšæºåå·®ïŒå¹³åç²åŸÃ100ïŒ
é¢ãããæŽã«è©³ããã¯ãæ¯æäœäžã«å°ãªããšãçº
è²æ§ã®ç°ãªãïŒçš®ä»¥äžã®æè²æ§å±€ãæããæå æ
æã§ãã€ãŠãçè©Šæå³ã¡é²å åè©Šæã®ä¿åæ§ã«åª
ããäžã€é²å åã®å§åã«ããå¢æã«ããªãæå¶ã§
ããããã²ã³åéå€å±€ã«ã©ãŒåçæå ææã«é¢ã
ããæ¬çºæã®æå ææã¯ãç¹ã«ã«ã©ãŒããªã³ãçš
æå ææïŒä»¥äžã«ã©ãŒããŒããŒãšç§°ããïŒã«å¥œé©
ã«é©çšããããšãã§ããã ãåŸæ¥ã®æè¡ã æ¯æäœäžã«è€æ°ã®æè²æ§å±€ãæããããã²ã³å
éã«ã©ãŒåçæå ææã«ãããŠã¯ãæ¯æäœããæ
ãé ãæå å±€ã¯ãæãå€åŽã«è¿ãé¢ä¿äžãå€éšã
ãã®å€åèŠå ãããªãã¡ç±ã湿床ãå§åã«å¯ŸããŠ
ä»ã®å±€ãããææã§ããã äŸãã°ã«ã©ãŒããŒããŒã®å Žåã¯ãæ¯æäœããæ
ãé ãæå å±€ã¯éåžžèµ€æå æ§å±€ã§ãããåŸã€ãŠã
ã®èµ€æå æ§å±€ãä»ã®ïŒå±€ã€ãŸãéæå æ§å±€ã»ç·æ
å æ§å±€ãããå€éšå€åèŠå ã«å¯ŸããŠææã§ããã æ¬çºæè ãã®ç 究ã«ããã°ãèµ€æå æ§ããã²ã³
åéä¹³å€ã¯ããããã€ãç¶æ³ãã次ã®ïŒç¹ã®æ¬ ç¹
ãåºæãã 第ïŒç¹ã¯ãçè©Šæã€ãŸãé²å åè©Šæã®ä¿åæ§ã®
åé¡ã§ãããæ¯æäœããæãé ãå±€ïŒã«ã©ãŒããŒ
ããŒã§ã¯éåžžèµ€æå æ§å±€ïŒã¯ãå€éšããã®ç±ã湿
床ãé žçŽ çã®åœ±é¿ã«ãããé²å åã®æ床å€åç¹ã«
æžæãçãæããä»ã®ïŒå±€ãšã®æ床ãã©ã³ã¹ã厩
ããã ã©ãïŒçŸåæïŒã«ãããŠã¯ãäžåºŠèšå®ããæ¡ä»¶
ãåããŒããŒæ¯ã«å€æŽããããšã¯äºå®äžäžå¯èœã§
ããã®ã§ãåžžã«åäžãªæ§èœãæã€ãæå ææãèŠ
æ±ãããäžèšã®ããã«æ床ãã©ã³ã¹ã厩ããããš
ã¯ãã©ãã§ã®æ©çããäœäžãããããšã«ã€ãªã
ããåŸã€ãŠçè©Šæä¿åäžã§ã®æ床ãé調ãã«ããª
ã®ãã©ã³ã¹ã®åŽ©ããªã補åã®éçºãå¿ èŠã§ããã 第ïŒç¹ã¯ãå§åã«ããã«ããªç¹ã«å¢æã«ããªã®
åé¡ã§ãããè¿å¹Žãçç£å·¥çšã®é«éåãé«éããª
ã³ã¿ãŒã®éçºçã«ãããå€éšããã®å§åã¯çš®ã ã®
圢ã§å ããããã«ãªã€ããç¹ã«å§åã«ãããèµ€æ
å æ§ä¹³å€ã¯å¢æãæžæãçãæããç¹ã«å¢æã«ã
ãã«ããªã¯ãããªã³ãã®å質ãèããå£åããã
ã®ã§æ¹è¯ãæãŸããã äžèšç¬¬ïŒç¹ã®ãçè©Šæã®ä¿åæ§æ¹è¯ã®æè¡ã«ã€
ããŠã¯ãåŸæ¥ããã2Ræ³ãå¢æè²çŽ ãå®å®å€ãª
ã©ã®çš®é¡ã»éã»çµåãçã§ãæ°å€ãã®ææ¡ããªã
ããŠããããããããããæªã äžå åã§ãããäž
å±€ä¿åæ§ãæ¹åãããæå ææãæãŸããŠããã 第ïŒç¹ã®ãå§åå¹æã«ã€ããŠã¯ãå€ãããã±
ã€ã»ããŒã»ã¡ã€ã¶ããžã€ãŒãã«ã»ãªãã»ãªããã€
ã«ã«ã»ãœãµãšãã€ã»ãªãã»ã¢ã¡ãªã«ãïŒK.B.
MatherïŒJ.Opt.Soc.Am.ïŒ38ïŒ1054ïŒ1948ïŒãã
ããŒã»ãã¢ãŒã¬ã³ã¹ïŒããŒã»ãã»ã¹ã¡ããããœãŒ
ã·ã€ã«ã»ãšã»ã€ã³ãã¹ããªã¢ã«ã»ããªãã°ã©ã
ã€ãïŒP.FaelenceïŒand P.de SmetïŒScl.et Ind.
Phot.ïŒ25ïŒNo.ïŒïŒ178ïŒ1954ïŒããããŒã»ãã¢ãŒ
ã¬ã³ã¹ããžã€ãŒãã«ã»ãªãã»ããªãã°ã©ãã€ã
ã¯ã»ãµã€ãšã³ã¹ãïŒP.FaelenceïŒJ.Phot.Sci.ïŒïŒïŒ
105ïŒ1954ïŒçã«è©³çŽ°ã«èšèŒãããŠããããå ·äœç
ãªå¯Ÿçã«ã€ããŠã¯èšèŒããªãã å§åç¹æ§ãæ¹è¯ããæ段ãšããŠãããªããŒãä¹³
åç©ãªã©ã®å¯å¡å€ãå«æãããæ¹æ³ãããã²ã³å
éä¹³å€ã®ããã²ã³åéïŒãŒã©ãã³æ¯ãå°ãããã
çã®æ¹æ³ã§ãå§åãç²åã«å°éãããªãæ¹æ³ãã
ãã äŸãã°ç°ç¯ç°ç¶ååç©ãçšãããã®ïŒè±åœç¹èš±
第738618å·ïŒãã¢ã«ãã«ãã¿ã¬ãŒããçšãããã®
ïŒå738637å·ïŒãã¢ã«ãã«ãšã¹ãã«ãçšãããã®
ïŒå738639å·ïŒãå€äŸ¡ã¢ã«ã³ãŒã«ãçšãããã®ïŒç±³
åœç¹èš±ç¬¬2960404å·ïŒãã«ã«ããã·ã¢ã«ãã«ã»ã«ã
ãŒã¹ãçšãããã®ïŒå3121060å·ïŒããã©ãã€ã³ãš
ã«ã«ãã³é žå¡©ãçšãããã®ïŒç¹éæ49â5017å·ïŒã
ã¢ã«ãã«ã¢ã¯ãªã¬ãŒããšææ©é žãçšãããã®ïŒç¹
å ¬æ53â28086å·ïŒçãææ¡ãããŠããã ããããå¯å¡å€ãæ·»å ãããšãä¹³å€å±€ã®æ©æ¢°ç
匷床ãäœããªãã䜿çšéã«ã¯éçãããããŸããŒ
ã©ãã³ãå¢ãããšçŸååŠçé床ãé ããªãããã€
ãŠãããã®åŸæ¥æè¡ããååãªå¹æã¯éæãé£
ãããã®ãããªããšãããç²åèªäœå¿åã«ããªã
çºçãã«ãããã®ãæãŸãããã®éçºãèŠæãã
ãŠããã ãããäžè¿°ã®æç®ã«ã¯ãå§åã«ããªãæ¹åãã
æè¡ã¯äœã瀺ãããŠããªãã ç¹éæ58â9137å·æ现æžçã«ã¯ãç²åå éšã«ãš
ãŒãååžããããããšå§åæžæãçããããšãèš
èŒãããŠããããå¿åã«ããªã®æ¹åã«é¢ããèšèŒ
ã¯å šããªãã å€å±€æ§é ãæããããã²ã³åéç²åèªäœã«ã€ã
ãŠã¯ããžã€ãŒãã«ã»ãªãã»ããªãã°ã©ãã€ãã¯ã»
ãµã€ãšã³ã¹ïŒJ.Photo.Sci.ïŒïŒ24ïŒ198ïŒ1976ïŒã«
AgBrïŒAgBrIïŒæ²çŽ å«æç18ãŸãã¯32ã¢ã«
ïŒ ïŒïŒAgBrãããªãäžå±€æ§é ã®ããã²ã³åéç²
åã«ã€ããèšåããªãããŠããããããããã«ã
å§åã«ããªã«ã€ããŠã®ç€ºåã¯ãªãã ç±³åœç¹èš±ç¬¬2592250å·ãããã€ãç¹èš±ç¬¬1169290
å·ãã€ã®ãªã¹ç¹èš±ç¬¬1027146å·ãç±³åœç¹èš±ç¬¬
3206313å·ãç±³åœç¹èš±ç¬¬2756148å·çã«ã¯ãå éšæœ
ååããã²ã³åéä¹³å€ããããã«è¡šé¢ååŠå¢æã
æœãããã®ãèšèŒãããŠããããå§åã«ããªã®æ¹
è¯ã¯äžå åã§ããã ãã®ä»ã³ã¢ïŒã·ãšã«ä¹³å€ã«é¢é£ããŠæ°ã ã®ææ¡
ããªãããŠããããåŸæ¥ã®æè¡ã¯ããããäžèšïŒ
ç¹ã«ã€ããŠæ¹è¯ãäžå åããä¹è³ã¯ãã®åé¡ç¹ã®
解決ã«èæ ®ãæã€ãŠããªãããŸããã«ã©ãŒããŒã
ãŒã«é©çšããããšãããšããšãŒãå«æçã®åé¡ãª
ã©ã§é£ç¹ã倧ãããã®ã§ãã€ããããïŒç¹éæ49
â140444å·ãã®ä»ïŒã ãçºæã®ç®çã æ¬çºæã¯äžèšåŸæ¥æè¡ã®åé¡ç¹ã解決ããŠãç
è©Šæã®ä¿åæ§ãè¯ãããã€å§åã«ããªãªã©ãçã
ãªãããã²ã³åéã«ã©ãŒåçæå ææãæäŸãã
ããšãç®çãšããã ãçºæã®æ§æåã³äœçšã æ¬çºæè ãã¯çš®ã ç 究ã®çµæãæ¯æäœäžã«å°ãª
ããšãæè²æ§ã®ç°ãªãïŒçš®ä»¥äžã®æè²æ§å±€ãæã
ãããã²ã³åéã«ã©ãŒåçæå ææã§ãã€ãŠãæ¯
æäœããæãé ãæå æ§ããã²ã³åéä¹³å€å±€ãã
ã¬åãšãªãããã«ãå³ã¡å åŠæ¿åºŠã«ãããŠãã«ã
ãªïŒ0.1ãã®æ床ç¹ããšã€ãå Žåã®æé©æ床ã®60
ïŒ ä»¥äžã«ãªãããã«ååŠå¢æãæœãããã³ã¢ïŒã·
ãšã«æ§é ãæããå éšæœååããã²ã³åéç²åã
å«æãããã®ã«ãããäžèšç®çãéæãããããš
ãèŠãåºããã æ¬çºæã®æå ææã¯ãäžèšã®ããã«æ¯æäœãã
æãé ãããã²ã³åéä¹³å€å±€ãã³ã¢ïŒã·ãšã«æ§é
ã®å éšæœååããã²ã³åéç²åãå«æãããã®ç²
åã¯ãã¬åãšãªãããã«ååŠå¢æãæœããããã®
ã§ããã®ã§ãããã«ãã該乳å€å±€ãå€éšå€åèŠå
ã«åœ±é¿ãããŠä¿åæ§ã®å£åãå§åã«ããªã®åé¡ã
çããããšãæå¶ã§ããã ãã®çµæãå€éšå€åèŠå ã®åœ±é¿ãæãåãæã
æ¯æäœããæãé ãåŽã®ä¹³å€å±€ã¯ãåŸæ¥ä¿åæ§ã
å£åãããªã©ã®ããšã«ããä»å±€ãšã®ãã©ã³ã¹ãã
ãããç¹ã«æ床ãã©ã³ã¹ãããããå Žåããã€ã
ã®ããæ¬çºæã§ã¯è©²ä¹³å€å±€ã®ä¿åæ§ãæ¹è¯ããã
ã®ã§ãæ床ãã©ã³ã¹ãªã©ãããããªããšããäœçš
ãããããããã ãã€ãæ¬çºæã®æå ææã¯å§åã«ããªãæ¹è¯ã
ãããããããå§åã«ããªã®é²æ¢å¹æã¯ãããã²
ã³åéãå éšæœååã«ããããšã«ããååŠå¢æã®
ãããæ¹ãå€åããããšã«ãããã«ããªã®çºçã
å°ãªããªããã®ãšæšå®ãããã æ¬çºæã®ã«ã©ãŒåçæå ææã¯ãæ¯æäœäžã«å°
ãªããšãæè²æ§ã®ç°ãªãïŒçš®ä»¥äžã®æè²æ§å±€ãæ
ããããäŸãã°äžè¬ã®ã«ã©ãŒããŒããŒã®åŠãæ¯æ
äœäžã«é ã«éææ§ããã²ã³åéä¹³å€å±€ãäžéå±€ã
ç·ææ§ããã²ã³åéä¹³å€å±€ã第1UVå±€ãèµ€ææ§
ããã²ã³åéä¹³å€å±€ã第2UVå±€ããããã¯ãå±€
ãå¡èšããŠãèšïŒå±€æ§æãšããããšãã§ãããã
ã®æ§æã«ãããŠã¯æ¯æäœããæãé ãæå æ§å±€
ã¯ãèµ€ææ§ããã²ã³åéä¹³å€å±€ã§ããã æ¬çºæã«ãããŠãããã¬åãšãªãããã«ååŠå¢
æãæœãããšã¯ãå åŠæ¿åºŠã«ãããŠãã«ããªïŒ
0.1ãã®æ床ç¹ããšã€ãå Žåã®æé©æ床ã®60ïŒ ä»¥
äžã«ãªãããã«ååŠå¢æãããšããããšãæå³ã
ããããã®ãšããç¹éæ59â140444å·ã®æ¹æ³ã«åŸ
ã€ãŠãååŠå¢æã®çšåºŠã決å®ããããšãå¯èœã§ã
ãã ååŠå¢æã¯ãåŸèšããåçš®ã®ååŠå¢ææè¡ãçš
ããŠè¡ãããšãã§ããã æ¬çºæã«ãããŠã³ã¢ïŒã·ãšã«æ§é ãšã¯ãã³ã¢ã€
ãŸãç²åå éšãšã·ãšã«ã€ãŸããã以å€ã®è¡šå±€éšãš
ã§ååŠçµæãã®ä»ååŠçæ§è³ªããç©ççæ§è³ªã®ç°
ãªããã®ããããäŸãã°ã³ã¢ãšã·ãšã«ãšã§ããã²
ã³åéçµæã®ç°ãªããã®ã®ã»ããåäžããã²ã³å
éçµæã§ã¯ããããããããç©å±€åä¹³å€ã§ããã
ã®ãå«ãããã®å Žåã¯ãã³ã¢ãååŠå¢æãªã©ã
ãŠãå éšæœååã«ããæ¬çºæã®ä¹³å€ã«å¥œé©ã«é©çš
ã§ããã ã³ã¢ïŒã·ãšã«æ§é ã®å±€æ°ã¯ãã³ã¢ãšã·ãšã«ã
åã ïŒã€ãã€ã®ïŒå±€æ§é ã§ããïŒå±€ä»¥äžã®æ§é ã§
ãããã ã³ã¢ïŒã·ãšã«æ§é ã¯ãå±€ã圢æããã«å åãªè¢«
èŠå±€ã®ããã²ã³åéã«ããæ§æãããã®ã§ãªããš
ãè¯ããããªãã¡ç¬¬ïŒå³ã«æš¡åŒçã«ç¥ç€ºãããã
ã«å®å šã«è¢«èŠå±€ïœãæ§æãããŠããã®ã§ãã第ïŒ
å³ã«åããç¥ç€ºããããã«å±åšå±€ïœãšãªã€ãŠãã
ã®ã§ããå¹æãåŸãããã°è¯ãã æ¬çºæã«ãããŠã¯ãåèšã®åŠãå¿ ãããããã²
ã³åéçµæãç°ãªããªããŠãããã®ã§ãããã²ã³
åéãšããŠèåéãæ²èåéãæ²å¡©åéãå¡©èå
éãåã³å¡©åéçã®éåžžã®ããã²ã³åéä¹³å€ã«äœ¿
çšãããä»»æã®ãã®ãé©å®æ段ã§ã³ã¢ïŒã·ãšã«æ§
é ãšããŠçšããããšãã§ããã 奜ãŸããã¯ãããã²ã³åéãšããŠå¡©èåéãçš
ããã®ã奜ãŸãããã«ã©ãŒããŒããŒçšããã²ã³å
éãšããŠã¯ãè±éæ§ã®èŠ³ç¹ãããšãŒãããŸã€ãã
å«ãŸãªããããããã¯å«ãã§ãæ°ã¢ã«ïŒ 以äžã奜
ãŸãããæ ã«ãšãŒãã®å«æçã¯å¥œãŸããã¯ïŒãïŒ
ã¢ã«ïŒ ãæŽã«å¥œãŸããã¯ãŸã€ããå«ãŸãªããã®ã
è¯ãã ãŸãã³ã¢ãšã·ãšã«ã®å¡©èåéã«ãããèçŽ ã®æ··
åæ¯çã¯ãç¹ã«å¶éã¯ãªããã奜ãŸããã¯ãã³ã¢
ãšã·ãšã«ã§ã®èçŽ å«æçã¯25ã¢ã«ïŒ å·®ãããããš
ãæ¬çºæã«é©ããŠãããæŽã«ããã²ã³åéç²åã®
ç·èçŽ å«æçã¯40ã70ã¢ã«ïŒ ã§ããããšã奜ãŸã
ãã ã³ã¢ãšã·ãšã«ãšã®å¢çã®ç¶æ ãäŸãã°å¢çã«ã
ããèåéå«æçã®å€åã¯ãé£ç¶çã段éççä»»
æã§ãããã³ã¢ã¯ãã®äžéšïŒäŸãã°è£œé ã«ããã
çš®ç²åã«çžåœããéšåçïŒã«èåéå«æçãïŒã®
éšåããã€ãŠãå·®æ¯ããªããã·ãšã«ã®åãã¯ã³ã¢
ã®å¥œãŸããçŽ è³ªãé èœãã¬åãã§ããããã€éã«
ã³ã¢ã®å¥œãŸãããããçŽ è³ªãé èœããã«è¶³ãåã¿
ã§ããããšããããå ·äœçã«ã¯ãäžèšã·ãšã«ã®å
ãã0.01ã0.3ÎŒmã®ç¯å²ã§ããããã²ã³åéç²å
ã§ããããšã奜ãŸããã æ¬çºæã«çšããããããã²ã³åéç²åã¯ãäžèš
ã®ã³ã¢ïŒã·ãšã«åã®ããã²ã³åéç²åãåäžãã
ã²ã³åéä¹³å€å±€ã«ãããå šç²åã®70ïŒ ä»¥äžãå«ã
ã§ããããšã奜ãŸãããç¹ã«å šç²åãã³ã¢ïŒã·ãš
ã«åããã²ã³åéç²åã§ããããšã奜ãŸããã ãããã³ã¢ïŒã·ãšã«åããã²ã³åéç²åã¯åç¬
ã§äœ¿çšããŠããããå¹³åç²ååŸã®ç°ãªãïŒçš®ä»¥äž
ã®ããã²ã³åéç²åãä»»æã«æ··åããŠäœ¿çšããã®
ã奜ãŸããã ãŸããèåéå«æçã®ç°ãªãã³ã¢ïŒã·ãšã«åã®
ããã²ã³åéç²åãïŒçš®ä»¥äžæ··åããŠå¥œãŸãã䜿
çšããããšãã§ããã æ¬çºæã®ä¹³å€äžã®ããã²ã³åéç²åã®ç²åŸååž
ã¯å€åæ£ã§ãã€ãŠããååæ£ã§ãã€ãŠããããã
ååæ£ä¹³å€ã§ããããšããã奜ãŸãããããã§å
åæ£ä¹³å€ãšã¯ãä¹³å€äžã«å«æãããããã²ã³åé
ç²åã®ç²åŸååžã«ãããŠããã®å€åä¿æ°ã22ïŒ ä»¥
äžã奜ãŸããã¯20ïŒ ä»¥äžãæŽã«å¥œãŸããã¯15ïŒ ä»¥
äžã§ãããããªä¹³å€ããããå€åä¿æ°ã¯ç²åŸååž
ã®åºãã瀺ãä¿æ°ã§æ¬¡åŒã«ãã€ãŠå®çŸ©ãããã å€åä¿æ°ïŒç²åŸååžã®æšæºåå·®ïŒå¹³åç²åŸÃ100ïŒ
ãåã
å¹³åç²åŸïŒÎ£niriïŒÎ£niïŒ
ããã§riã¯ç²ååã
ã®ç²åŸãniã¯ãã®æ°ãè¡š
ãããŸãå¹³åç²åŸãšã¯ãç«æ¹äœç¶ã®ããã²ã³å
éç²åã®å Žåã¯ãã®äžèŸºã®é·ããçç¶ãªã©ã®ç«æ¹
äœä»¥å€ã®åœ¢ç¶ã®ç²åã®å Žåã¯ãåäžäœç©ãæãã
ç«æ¹äœã«æç®ããæã®äžèŸºã®é·ãã®å¹³åå€ã§ãã€
ãŠãåã ã®ãã®ç²åŸãriã§ããããã®æ°ãniã§ã
ãæã«äžèšã®åŒã§è¡šãããã ãªãäžèšã®ç²ååŸã¯ãäžèšã®ç®çã®ããã«åœè©²
æè¡åéã«ãããŠäžè¬ã«çšããããåçš®ã®æ¹æ³ã«
ãã€ãŠããã枬å®ããããšãã§ããã代衚çãªæ¹
æ³ãšããŠã¯ãã©ãã©ã³ãã®ãç²ååŸåææ³ãA.S.
T.T.ã·ã³ããžãŠã ã»ãªã³ã»ã©ã€ãã»ãã€ã¯ãã¹
ã³ããŒã1955幎ã94ã122é ããŸãã¯ãåçãã
ã»ã¹ã®çè«ãããŒã¹åã³ãžãšãŒã ã¹å ±èã第ïŒ
çããã¯ãã©ã³ç€Ÿçºè¡ïŒ1966幎ïŒã®ç¬¬ïŒç« ã«èšèŒ
ãããŠããã æ¬çºæãå®æœããå Žåãä¹³å€äžã®ããã²ã³åé
ç²åã®å¹³åç²åŸãã0.1ÎŒã2ÎŒã§ããããšã奜ãŸã
ããæŽã«å¥œãŸããã¯ã0.2ÎŒã0.5ÎŒã§ããã ç²åã®æ¶çã¯ç«æ¹äœãååé¢äœãå «é¢äœããã
ãããåãåæ¶ãå¹³æ¿æ¶ãªã©ä»»æã§ãããæãã¯
ãããã®æ··åç©ã§ãè¯ãã ç²åã®çµæ¶åœ¢æ ã«ãããŠãäŸãã°ïœ100ïœé¢ãš
ïœ111ïœé¢ã®æ¯çã¯ä»»æã®ãã®ã䜿çšã§ãããŸãçµ
æ¶åœ¢ã®è€å圢ãæã€ãã®ã§ããããç²åã¯æ§ã ãª
çµæ¶åœ¢ã®ç²åãæ··åãããŠãããã æ¬çºæã®ä¹³å€ã®ããã²ã³åéç²åã®å éšæ žã¯ã
ããŒã»ã°ã©ããããïŒP.GlafkidesïŒèã·ãšãã»
ãšã»ãã€ãžãŒã¯ã»ããªãŒãã°ã©ãã€ãŒã¯
ïŒChimieet Physigue PhotographigueïŒïŒPaul
Montel瀟åã1967幎ïŒããžãŒã»ãšãã»ããã€ã³
ïŒG.F.DuffinïŒèããªãã°ã©ãã€ãã¯ã»ãšãã«ãž
ãšã³ã»ã±ãã¹ããªãŒïŒPhotographic Emulsion
ChemistryïŒïŒThe Focal Preesåã1966幎ïŒããŽ
ã€ã»ãšã«ã»ãŒãªã¯ãã³ä»ïŒV.L.Zelikman et alïŒ
èã¡ã€ãã³ã°ã»ã³ãŠãã€ã³ã°ã»ããªãã°ã©ãã€ã
ã¯ã»ãšãã«ãžãšã³ïŒMaking and Coating
photographic EmulsionïŒïŒThe Focal Prsesåã
1964幎ïŒãªã©ã«èšèŒãããæ¹æ³ãçšããŠèª¿è£œãã
ããšãã§ãããããªãã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³
ã¢ãã¢æ³çã®ãããã§ãåŸãããã ãŸããé æ··åæ³ãéæ··åæ³ãåææ··åæ³ã®ãã
ããçšããŠãè¯ãã奜ãŸããã¯ãé žæ§ãäžæ§é å
ã«ãããŠãpAgã³ã³ãããŒã«ãããã«ãžãšããæ³
ã§èª¿è£œããããšãè¯ãããã®æ¹æ³ã«ãããšãçµæ¶
圢ãèŠåçã§ç²åãµã€ãºãåäžã«è¿ãããã²ã³å
éä¹³å€ãããããããŸãåèšããããã«ãã³ã¢ãš
ã·ãšã«ãé£ç¶ã§ãåã¯äžé£ç¶ã§èª¿è£œããŠãè¯ãã å¥ã ã«åœ¢æããïŒçš®ä»¥äžã®ããã²ã³åéä¹³å€ã
æ··åããŠçšããŠãããã ããã²ã³åéç²åã®ã³ã¢ã調補ããã«éããŠ
ã¯ãåäžãªããã²ã³çµæãšãªã€ãŠããããšã奜ãŸ
ããã ã³ã¢ã調補ãããšãã®pAgãšããŠã¯ãåå¿æž©
床ãããã²ã³åé溶å€ã®çš®é¡ã«ãã€ãŠå€åãã
ãã奜ãŸããã¯ïŒãïŒã§ããããŸãããã²ã³åé
溶å€ãçšãããšç²å圢ææéãçæéã«è¡ããã
ã®ã§å¥œãŸãããäŸãã°ã¢ã³ã¢ãã¢ãããªãšãŒãã«
ãªã©äžè¬ã«ããç¥ãããããã²ã³åé溶å€ãçšã
ãããšãã§ããã ã³ã¢ã®åœ¢ç¶ãšããŠã¯æ¿ç¶ãçç¶ãåæ¶ç³»ã§ãã€
ãŠããŸããå «é¢äœãç«æ¹äœãååé¢äœãããã¯æ··
åç³»ãªã©ãçšããããšãã§ããã ãŸããã³ã¢ã¯ãå€åæ£ã§ãååæ£ã§ããããã
ååæ£ã§ããæ¹ãäžå±€å¥œãŸãããããã§ããåå
æ£ããšã¯åè¿°ããã®ãšå矩ã§ããã ãŸããç²åãµã€ãºãåäžã«ããã«ã¯ãè±åœç¹èš±
第1535016å·ãç¹å ¬æ48â36890å·ãå52â16364
å·çã«èšèŒãããŠããããã«ãç¡é žéãããã²ã³
åã¢ã«ã«ãªæ°Žæº¶æ¶²ã®æ·»å é床ãç²åæé·é床ã«å¿
ããŠå€åãããæ¹æ³ããç±³åœç¹èš±ç¬¬4242445å·ã
ç¹éæ55â158124å·çã«èšèŒãããŠããããã«æ°Ž
溶液æ¿åºŠãå€åãããæ¹æ³ãçšããŠèšçé飜å床
ãè¶ããªãç¯å²ã«ãããŠæ©ãæé·ãããããšã奜
ãŸããããããã®æ¹æ³ã¯ãåæ žçºçãèµ·ãããã
åããã²ã³åéç²åãåäžã«è¢«èŠãããŠããã
ãã奜ãŸããçšããããã ã³ã¢ã«ãååŠå¢æïŒç¡«é»ã貎éå±ãéå å¢æãª
ã©ïŒãæœããŠãè¯ãã ããã²ã³åéç²åã®ã³ã¢ã®åœ¢æãŸãã¯ç©ççæ
ã®éçšã«ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ã
ã¿ãªãŠã å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããž
ãŠã å¡©ãŸãã¯ãã®é¯å¡©ãéå¡©ãŸãéé¯å¡©ãªã©ãå ±
åãããŠãããã ãŸãã³ã¢äžã«ããã²ã³åéãæ°ãã«è¢«èŠããæ¹
æ³ãšããŠã¯ãäŸãã°ãããã²ã³åç©æ°Žæº¶æ¶²ãšç¡é ž
é氎溶液ãšãåæã«æ·»å ããããšãã€ãŸããåæ
æ··åæ³ããŸã奜ãŸããã¯ã³ã³ãããŒã«ãããã«ãž
ãšããæ³ã«ãã€ãŠè¡ãããšãã§ããã詳ããã¯ã
ç¹éæ53â22408å·å ¬å ±ãç¹å ¬æ43â13162å·å ¬
å ±ããžã€ãŒãã«ã»ãªãã»ããªãã°ã©ãã€ãã¯ã»ãµ
ã€ãšã³ã¹ïŒJ.Photo.Sci.ïŒïŒ24ïŒ198ïŒ1976ïŒãªã©ã«
èšèŒãããæ¹æ³ã«ãã€ãŠè¡ãããšãã§ããã ã·ãšã«ã圢æãããšãã®pAgãšããŠã¯ãåå¿æž©
床ãããã²ã³åé溶å€ã®çš®é¡ã»éã«ãã€ãŠå€åã
ããã奜ãŸããã¯ãåèšã³ã¢ã«ã€ããŠè¿°ã¹ããã®
ãåæ§ã«çšããããã ã·ãšã«ã圢æããæ¹æ³ãšããŠã¯ãåææ··åæ³ãŸ
ãã¯ãã³ã³ãããŒã«ãããã«ãžãšããæ³ããã奜
ãŸããã ããã²ã³åéç²åã®ã·ãšã«ã®ãšãŒãå«éã«ã€ã
ãŠã¯ãäŸãã°ãJ.I.ãŽãŒã«ãã·ãŠã¿ã€ã³
ïŒGoldsteinïŒïŒD.B.ãŠã€ãªã¢ã ãºïŒWilliamsïŒ
ãTEMïŒATEMã«ãããç·åæãã¹ãã€ã³ã
ã³ã°ã»ãšã¬ã¯ããã³ã»ãã€ã¯ãã¹ã³ãã€ïŒ1977ïŒã
第ïŒå·»ïŒIITãªãµãŒãã»ã€ã³ã¹ãã€ããŠãŒãïŒã
651é ïŒ1977幎ïŒæïŒã«èšèŒãããæ¹æ³ã«ãã€ãŠ
æ±ããããšãã§ããã ããã²ã³åéç²åã®èª¿è£œã«ãããŠãã·ãšã«ã®æ²
柱圢æåŸãããã¯ç©ççæåŸã®ä¹³å€ããããŸãã¯
å¿ èŠã«å¿ããŠãå éšæ žåœ¢æåŸãããã¯ã·ãšã«åœ¢æ
åŸã®ä¹³å€ããå¯æº¶æ§å¡©é¡ãé€å»ããããã«ã¯ãŒã©
ãã³ãã²ã«åãããŠè¡ãããŒãã«æ°ŽæŽæ³ãçšããŠ
ãããããŸãç¡æ©å¡©é¡ãã¢ããªã³æ§çé¢æŽ»æ§å€ã
ã¢ããªã³æ§ããªããŒïŒäŸãã°ããªã¹ãã¬ã³ã¹ã«ã
ã³é žïŒããããã¯ãŒã©ãã³èªå°äœïŒäŸãã°ã¢ã·ã«
åãŒã©ãã³ãã«ã«ãã¢ã€ã«åãŒã©ãã³ãªã©ïŒãå©
çšããæ²éæ³ïŒããããŠã¬ãŒã·ãšã³ïŒãçšããŠã
ããã æ¬çºæã«çšããããããã²ã³åéä¹³å€ã®è£œé è£
眮ãšããŠã¯ãåçæ¥çã«ãããŠç¥ãããŠãããã®
ãã©ããçšããããšãã§ããããç¹ã«é塩氎溶液
ãšããã²ã³åç©å¡©æ°Žæº¶æ¶²ãæ··åéå ã®èŠªæ°Žæ§ã³ã
ã€ã溶液äžã«æµžæŒ¬ãããããºã«ããå°å ¥ããæ¹
æ³ãæ·»å 液ã®æ¿åºŠãé£ç¶çã«å€åãããæ¹æ³ãé
å€ãéãªã©ã®æ¹æ³ã«ããæ··åéå ã®èŠªæ°Žæ§ã³ãã€
ã溶液äžã®éå°ã®å¯æº¶æ§å¡©åã³æ°Žãé€å»ããç²å
éè·é¢ã®æ¡å€§ãé²æ¢ããæ¹æ³çãå¿çšããè£ çœ®ã
奜ãŸããçšããããšãã§ããã æ¬çºæã«ãããŠãå éšæœååä¹³å€ãšã¯ãäžèšæ¡
件ã»äžèšçŸå液ã«ããè¡šé¢ãå éšçŸåããè¡šé¢
åãå éšåã®æé«æ¿åºŠDmaxãçœå ãçšããŠæ¿åºŠ
枬å®ãããšãã«ã該æé«æ¿åºŠDmaxãè¡šé¢åâŠå
éšåã§ãããããªä¹³å€ãããã奜ãŸããã¯ããã®
æ¿åºŠæ¯ããè¡šé¢ïŒå éšã§ïŒïŒïŒä»¥äžã®æ¯çã«ãªã
ããšãæãŸããã å¡åžè©ŠæïŒæªå¢æä¹³å€ã1dm2åœãã40mgã®é被
èŠéããã€ãŠããªãšãã¬ã³ã³ãŒãæ¯æäœäžã«
被èŠãæœããè©Šæ è¡šé¢çŸå液ïŒïŒ®âã¡ãã«âïœâã¢ããããšããŒã«
ãµã«ããšãŒã 2.5ïœ ã¢ã¹ã³ã«ãã³é ž 10.0ïœ ã¡ã¿ç¡Œé žã«ãªãŠã 35.0ïœ èåã«ãªãŠã 1.0ïœ æ°Žãå ããŠ ïŒ ïŒPHïŒ9.6ïŒ 20âïŒïŒåçŸå å éšçŸå液ïŒäžèšè¡šé¢çŸå液ã«æ²åã«ãªãŠã
ïŒKIïŒã0.5ïœïŒå ããçŸå液ã äœããè©Šæé²å åŸãäžèšåŠç液ã§æŒçœïŒ20âïŒ
åïŒãã次ãã§å éšçŸåïŒ20âïŒåïŒããã ãããµã·ã¢ãéïŒïŒé žå¡© 30ïœ ããšããµãã©ãã³ 30mg æ°Žãå ããŠ ïŒ ãŸãæ¬çºæã«ããããäžèšèŠå®ã«ããå éšã«ã
ãªå€ã®é¶ç¹ã¯ãäœãå¡åžããªãäžèšå¡åžè©Šæãšå
äžã®æ¯æäœïŒRCåçŽïŒã§èª¿ç¯ããã æ¬çºæã§ã¯ãæ¯æäœããæãé ãå±€ã«çšããã
ãä¹³å€ã®çš®é¡ãç¹å®ããŠãããããã®ä»ã®å±€ã«çš
ããããä¹³å€ã«ã€ããŠã¯ãæªå¢æä¹³å€ãšããŠè¡šé¢
æœååã§ããå éšæœååã§ãã©ã¡ãã§ã䜿çšã§ã
ããã©ã¡ããéžæãããã®åºæºãšããŠã¯ãæ±ãã
ããåçç¹æ§ãã決å®ããã°è¯ãã æ¬çºæã®ããã²ã³åéã«ã©ãŒåçæå ææã«ã¯
ä»»æã®æ¯æäœãçšããããšãã§ããç¹ã«å¶éã¯ãª
ããçšããããæ¯æäœãšããŠå¥œãŸããã¯ãäŸãã°
ãã©ã€ã¿çŽãããªãšãã¬ã³è¢«èŠçŽãããªãããã¬
ã³åæçŽãã¬ã©ã¹çŽãã»ã«ããŒã¹ã¢ã»ããŒããã»
ã«ããŒã¹ãã€ãã¬ãŒããããªããã«ã¢ã»ã¿ãŒã«ã
ããªãããã¬ã³ãäŸãã°ããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒãçã®ããªãšã¹ãã«ãã€ã«ã ãããªã¹ãã¬ã³ç
ããããç¹ã«å¥œãŸããã¯ããªãšãã¬ã³è¢«èŠçŽãã
ãªãããã¬ã³åæçŽãçšããããããããã®æ¯æ
äœã¯ãããããã®æå ææã®äœ¿çšç®çã«å¿ããŠé©
å®éžæãããã ãããã®æ¯æäœã¯å¿ èŠã«å¿ããŠäžåŒå å·¥ãæœã
ããã æ¬çºæã®æå ææã«ã¯ãéæ¡æ£æ§ã®ã«ãã©ãŒã
çšããããšãã§ããããããéæ¡æ£æ§ã®ã«ãã©ãŒ
ãšããŠã¯ãã®åéã§éåžžçšãããããã®ãçšãã
ããšãã§ãããæ¯æäœããæãé ãæå æ§ããã²
ã³åéä¹³å€å±€ã«çµåããéæ¡æ£æ§ã®ã«ãã©ãŒãšã
ãŠã¯ãå±€æ§æã«ããç°ãªããã該乳å€å±€ãèµ€ææ§
ã®å Žåã«ã¯ã·ã¢ã³ã«ãã©ãŒãç·ææ§ã®å Žåã«ã¯ã
ãŒã³ã¿ã«ãã©ãŒãéææ§ã®å Žåã«ã¯ã€ãšããŒã«ã
ã©ãŒãçµåããã®ãäžè¬çã§ãããã€ãšããŒã«ã
ã©ãŒãšããŠã¯åçš®ã®ééã±ãã¡ãã¬ã³ç³»ã«ãã©ãŒ
ãçšããããšãã§ããããããã®ãã¡ãã³ãŸã€ã«
ã¢ã»ãã¢ããªãç³»åã³ãããã€ã«ã¢ã»ãã¢ããªã
ç³»ååç©ãæçšã§ããã ããŒã³ã¿ã«ãã©ãŒãšããŠã¯ããã©ãŸãã³ç³»åå
ç©ãã€ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«åå
ç©ãã·ã¢ã³ã«ãã©ãŒãšããŠã¯ãããšããŒã«ç³»åå
ç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ã
ãã ã«ã©ãŒããŒããŒã«æ¬çºæãé©çšããå Žåãæ¯æ
äœããæãé ãæå æ§ããã²ã³åéä¹³å€å±€ãèµ€æ
æ§ã§ããã該局ãå«æããéæ¡æ£æ§ã«ãã©ãŒãã·
ã¢ã³ã«ãã©ãŒã§ããããšã奜ãŸããã æ¬çºæã®æå æ§ææã«çšããããéæ¡æ£æ§ã®ã·
ã¢ã³ã«ãã©ãŒã¯ã奜ãŸããã¯ããšããŒã«ç³»ã·ã¢ã³
ã«ãã©ãŒã§ãããæã奜ãŸããã®ã¯äžèšäžè¬åŒ
ããã§è¡šãããã·ã¢ã³ã«ãã©ãŒã§ããã äžè¬åŒãã
ãããŸãå¹³åç²åŸãšã¯ãç«æ¹äœç¶ã®ããã²ã³å
éç²åã®å Žåã¯ãã®äžèŸºã®é·ããçç¶ãªã©ã®ç«æ¹
äœä»¥å€ã®åœ¢ç¶ã®ç²åã®å Žåã¯ãåäžäœç©ãæãã
ç«æ¹äœã«æç®ããæã®äžèŸºã®é·ãã®å¹³åå€ã§ãã€
ãŠãåã ã®ãã®ç²åŸãriã§ããããã®æ°ãniã§ã
ãæã«äžèšã®åŒã§è¡šãããã ãªãäžèšã®ç²ååŸã¯ãäžèšã®ç®çã®ããã«åœè©²
æè¡åéã«ãããŠäžè¬ã«çšããããåçš®ã®æ¹æ³ã«
ãã€ãŠããã枬å®ããããšãã§ããã代衚çãªæ¹
æ³ãšããŠã¯ãã©ãã©ã³ãã®ãç²ååŸåææ³ãA.S.
T.T.ã·ã³ããžãŠã ã»ãªã³ã»ã©ã€ãã»ãã€ã¯ãã¹
ã³ããŒã1955幎ã94ã122é ããŸãã¯ãåçãã
ã»ã¹ã®çè«ãããŒã¹åã³ãžãšãŒã ã¹å ±èã第ïŒ
çããã¯ãã©ã³ç€Ÿçºè¡ïŒ1966幎ïŒã®ç¬¬ïŒç« ã«èšèŒ
ãããŠããã æ¬çºæãå®æœããå Žåãä¹³å€äžã®ããã²ã³åé
ç²åã®å¹³åç²åŸãã0.1ÎŒã2ÎŒã§ããããšã奜ãŸã
ããæŽã«å¥œãŸããã¯ã0.2ÎŒã0.5ÎŒã§ããã ç²åã®æ¶çã¯ç«æ¹äœãååé¢äœãå «é¢äœããã
ãããåãåæ¶ãå¹³æ¿æ¶ãªã©ä»»æã§ãããæãã¯
ãããã®æ··åç©ã§ãè¯ãã ç²åã®çµæ¶åœ¢æ ã«ãããŠãäŸãã°ïœ100ïœé¢ãš
ïœ111ïœé¢ã®æ¯çã¯ä»»æã®ãã®ã䜿çšã§ãããŸãçµ
æ¶åœ¢ã®è€å圢ãæã€ãã®ã§ããããç²åã¯æ§ã ãª
çµæ¶åœ¢ã®ç²åãæ··åãããŠãããã æ¬çºæã®ä¹³å€ã®ããã²ã³åéç²åã®å éšæ žã¯ã
ããŒã»ã°ã©ããããïŒP.GlafkidesïŒèã·ãšãã»
ãšã»ãã€ãžãŒã¯ã»ããªãŒãã°ã©ãã€ãŒã¯
ïŒChimieet Physigue PhotographigueïŒïŒPaul
Montel瀟åã1967幎ïŒããžãŒã»ãšãã»ããã€ã³
ïŒG.F.DuffinïŒèããªãã°ã©ãã€ãã¯ã»ãšãã«ãž
ãšã³ã»ã±ãã¹ããªãŒïŒPhotographic Emulsion
ChemistryïŒïŒThe Focal Preesåã1966幎ïŒããŽ
ã€ã»ãšã«ã»ãŒãªã¯ãã³ä»ïŒV.L.Zelikman et alïŒ
èã¡ã€ãã³ã°ã»ã³ãŠãã€ã³ã°ã»ããªãã°ã©ãã€ã
ã¯ã»ãšãã«ãžãšã³ïŒMaking and Coating
photographic EmulsionïŒïŒThe Focal Prsesåã
1964幎ïŒãªã©ã«èšèŒãããæ¹æ³ãçšããŠèª¿è£œãã
ããšãã§ãããããªãã¡ãé žæ§æ³ãäžæ§æ³ãã¢ã³
ã¢ãã¢æ³çã®ãããã§ãåŸãããã ãŸããé æ··åæ³ãéæ··åæ³ãåææ··åæ³ã®ãã
ããçšããŠãè¯ãã奜ãŸããã¯ãé žæ§ãäžæ§é å
ã«ãããŠãpAgã³ã³ãããŒã«ãããã«ãžãšããæ³
ã§èª¿è£œããããšãè¯ãããã®æ¹æ³ã«ãããšãçµæ¶
圢ãèŠåçã§ç²åãµã€ãºãåäžã«è¿ãããã²ã³å
éä¹³å€ãããããããŸãåèšããããã«ãã³ã¢ãš
ã·ãšã«ãé£ç¶ã§ãåã¯äžé£ç¶ã§èª¿è£œããŠãè¯ãã å¥ã ã«åœ¢æããïŒçš®ä»¥äžã®ããã²ã³åéä¹³å€ã
æ··åããŠçšããŠãããã ããã²ã³åéç²åã®ã³ã¢ã調補ããã«éããŠ
ã¯ãåäžãªããã²ã³çµæãšãªã€ãŠããããšã奜ãŸ
ããã ã³ã¢ã調補ãããšãã®pAgãšããŠã¯ãåå¿æž©
床ãããã²ã³åé溶å€ã®çš®é¡ã«ãã€ãŠå€åãã
ãã奜ãŸããã¯ïŒãïŒã§ããããŸãããã²ã³åé
溶å€ãçšãããšç²å圢ææéãçæéã«è¡ããã
ã®ã§å¥œãŸãããäŸãã°ã¢ã³ã¢ãã¢ãããªãšãŒãã«
ãªã©äžè¬ã«ããç¥ãããããã²ã³åé溶å€ãçšã
ãããšãã§ããã ã³ã¢ã®åœ¢ç¶ãšããŠã¯æ¿ç¶ãçç¶ãåæ¶ç³»ã§ãã€
ãŠããŸããå «é¢äœãç«æ¹äœãååé¢äœãããã¯æ··
åç³»ãªã©ãçšããããšãã§ããã ãŸããã³ã¢ã¯ãå€åæ£ã§ãååæ£ã§ããããã
ååæ£ã§ããæ¹ãäžå±€å¥œãŸãããããã§ããåå
æ£ããšã¯åè¿°ããã®ãšå矩ã§ããã ãŸããç²åãµã€ãºãåäžã«ããã«ã¯ãè±åœç¹èš±
第1535016å·ãç¹å ¬æ48â36890å·ãå52â16364
å·çã«èšèŒãããŠããããã«ãç¡é žéãããã²ã³
åã¢ã«ã«ãªæ°Žæº¶æ¶²ã®æ·»å é床ãç²åæé·é床ã«å¿
ããŠå€åãããæ¹æ³ããç±³åœç¹èš±ç¬¬4242445å·ã
ç¹éæ55â158124å·çã«èšèŒãããŠããããã«æ°Ž
溶液æ¿åºŠãå€åãããæ¹æ³ãçšããŠèšçé飜å床
ãè¶ããªãç¯å²ã«ãããŠæ©ãæé·ãããããšã奜
ãŸããããããã®æ¹æ³ã¯ãåæ žçºçãèµ·ãããã
åããã²ã³åéç²åãåäžã«è¢«èŠãããŠããã
ãã奜ãŸããçšããããã ã³ã¢ã«ãååŠå¢æïŒç¡«é»ã貎éå±ãéå å¢æãª
ã©ïŒãæœããŠãè¯ãã ããã²ã³åéç²åã®ã³ã¢ã®åœ¢æãŸãã¯ç©ççæ
ã®éçšã«ãããŠãã«ãããŠã å¡©ãäºéå¡©ãéå¡©ã
ã¿ãªãŠã å¡©ãã€ãªãžãŠã å¡©ãŸãã¯ãã®é¯å¡©ãããž
ãŠã å¡©ãŸãã¯ãã®é¯å¡©ãéå¡©ãŸãéé¯å¡©ãªã©ãå ±
åãããŠãããã ãŸãã³ã¢äžã«ããã²ã³åéãæ°ãã«è¢«èŠããæ¹
æ³ãšããŠã¯ãäŸãã°ãããã²ã³åç©æ°Žæº¶æ¶²ãšç¡é ž
é氎溶液ãšãåæã«æ·»å ããããšãã€ãŸããåæ
æ··åæ³ããŸã奜ãŸããã¯ã³ã³ãããŒã«ãããã«ãž
ãšããæ³ã«ãã€ãŠè¡ãããšãã§ããã詳ããã¯ã
ç¹éæ53â22408å·å ¬å ±ãç¹å ¬æ43â13162å·å ¬
å ±ããžã€ãŒãã«ã»ãªãã»ããªãã°ã©ãã€ãã¯ã»ãµ
ã€ãšã³ã¹ïŒJ.Photo.Sci.ïŒïŒ24ïŒ198ïŒ1976ïŒãªã©ã«
èšèŒãããæ¹æ³ã«ãã€ãŠè¡ãããšãã§ããã ã·ãšã«ã圢æãããšãã®pAgãšããŠã¯ãåå¿æž©
床ãããã²ã³åé溶å€ã®çš®é¡ã»éã«ãã€ãŠå€åã
ããã奜ãŸããã¯ãåèšã³ã¢ã«ã€ããŠè¿°ã¹ããã®
ãåæ§ã«çšããããã ã·ãšã«ã圢æããæ¹æ³ãšããŠã¯ãåææ··åæ³ãŸ
ãã¯ãã³ã³ãããŒã«ãããã«ãžãšããæ³ããã奜
ãŸããã ããã²ã³åéç²åã®ã·ãšã«ã®ãšãŒãå«éã«ã€ã
ãŠã¯ãäŸãã°ãJ.I.ãŽãŒã«ãã·ãŠã¿ã€ã³
ïŒGoldsteinïŒïŒD.B.ãŠã€ãªã¢ã ãºïŒWilliamsïŒ
ãTEMïŒATEMã«ãããç·åæãã¹ãã€ã³ã
ã³ã°ã»ãšã¬ã¯ããã³ã»ãã€ã¯ãã¹ã³ãã€ïŒ1977ïŒã
第ïŒå·»ïŒIITãªãµãŒãã»ã€ã³ã¹ãã€ããŠãŒãïŒã
651é ïŒ1977幎ïŒæïŒã«èšèŒãããæ¹æ³ã«ãã€ãŠ
æ±ããããšãã§ããã ããã²ã³åéç²åã®èª¿è£œã«ãããŠãã·ãšã«ã®æ²
柱圢æåŸãããã¯ç©ççæåŸã®ä¹³å€ããããŸãã¯
å¿ èŠã«å¿ããŠãå éšæ žåœ¢æåŸãããã¯ã·ãšã«åœ¢æ
åŸã®ä¹³å€ããå¯æº¶æ§å¡©é¡ãé€å»ããããã«ã¯ãŒã©
ãã³ãã²ã«åãããŠè¡ãããŒãã«æ°ŽæŽæ³ãçšããŠ
ãããããŸãç¡æ©å¡©é¡ãã¢ããªã³æ§çé¢æŽ»æ§å€ã
ã¢ããªã³æ§ããªããŒïŒäŸãã°ããªã¹ãã¬ã³ã¹ã«ã
ã³é žïŒããããã¯ãŒã©ãã³èªå°äœïŒäŸãã°ã¢ã·ã«
åãŒã©ãã³ãã«ã«ãã¢ã€ã«åãŒã©ãã³ãªã©ïŒãå©
çšããæ²éæ³ïŒããããŠã¬ãŒã·ãšã³ïŒãçšããŠã
ããã æ¬çºæã«çšããããããã²ã³åéä¹³å€ã®è£œé è£
眮ãšããŠã¯ãåçæ¥çã«ãããŠç¥ãããŠãããã®
ãã©ããçšããããšãã§ããããç¹ã«é塩氎溶液
ãšããã²ã³åç©å¡©æ°Žæº¶æ¶²ãæ··åéå ã®èŠªæ°Žæ§ã³ã
ã€ã溶液äžã«æµžæŒ¬ãããããºã«ããå°å ¥ããæ¹
æ³ãæ·»å 液ã®æ¿åºŠãé£ç¶çã«å€åãããæ¹æ³ãé
å€ãéãªã©ã®æ¹æ³ã«ããæ··åéå ã®èŠªæ°Žæ§ã³ãã€
ã溶液äžã®éå°ã®å¯æº¶æ§å¡©åã³æ°Žãé€å»ããç²å
éè·é¢ã®æ¡å€§ãé²æ¢ããæ¹æ³çãå¿çšããè£ çœ®ã
奜ãŸããçšããããšãã§ããã æ¬çºæã«ãããŠãå éšæœååä¹³å€ãšã¯ãäžèšæ¡
件ã»äžèšçŸå液ã«ããè¡šé¢ãå éšçŸåããè¡šé¢
åãå éšåã®æé«æ¿åºŠDmaxãçœå ãçšããŠæ¿åºŠ
枬å®ãããšãã«ã該æé«æ¿åºŠDmaxãè¡šé¢åâŠå
éšåã§ãããããªä¹³å€ãããã奜ãŸããã¯ããã®
æ¿åºŠæ¯ããè¡šé¢ïŒå éšã§ïŒïŒïŒä»¥äžã®æ¯çã«ãªã
ããšãæãŸããã å¡åžè©ŠæïŒæªå¢æä¹³å€ã1dm2åœãã40mgã®é被
èŠéããã€ãŠããªãšãã¬ã³ã³ãŒãæ¯æäœäžã«
被èŠãæœããè©Šæ è¡šé¢çŸå液ïŒïŒ®âã¡ãã«âïœâã¢ããããšããŒã«
ãµã«ããšãŒã 2.5ïœ ã¢ã¹ã³ã«ãã³é ž 10.0ïœ ã¡ã¿ç¡Œé žã«ãªãŠã 35.0ïœ èåã«ãªãŠã 1.0ïœ æ°Žãå ããŠ ïŒ ïŒPHïŒ9.6ïŒ 20âïŒïŒåçŸå å éšçŸå液ïŒäžèšè¡šé¢çŸå液ã«æ²åã«ãªãŠã
ïŒKIïŒã0.5ïœïŒå ããçŸå液ã äœããè©Šæé²å åŸãäžèšåŠç液ã§æŒçœïŒ20âïŒ
åïŒãã次ãã§å éšçŸåïŒ20âïŒåïŒããã ãããµã·ã¢ãéïŒïŒé žå¡© 30ïœ ããšããµãã©ãã³ 30mg æ°Žãå ããŠ ïŒ ãŸãæ¬çºæã«ããããäžèšèŠå®ã«ããå éšã«ã
ãªå€ã®é¶ç¹ã¯ãäœãå¡åžããªãäžèšå¡åžè©Šæãšå
äžã®æ¯æäœïŒRCåçŽïŒã§èª¿ç¯ããã æ¬çºæã§ã¯ãæ¯æäœããæãé ãå±€ã«çšããã
ãä¹³å€ã®çš®é¡ãç¹å®ããŠãããããã®ä»ã®å±€ã«çš
ããããä¹³å€ã«ã€ããŠã¯ãæªå¢æä¹³å€ãšããŠè¡šé¢
æœååã§ããå éšæœååã§ãã©ã¡ãã§ã䜿çšã§ã
ããã©ã¡ããéžæãããã®åºæºãšããŠã¯ãæ±ãã
ããåçç¹æ§ãã決å®ããã°è¯ãã æ¬çºæã®ããã²ã³åéã«ã©ãŒåçæå ææã«ã¯
ä»»æã®æ¯æäœãçšããããšãã§ããç¹ã«å¶éã¯ãª
ããçšããããæ¯æäœãšããŠå¥œãŸããã¯ãäŸãã°
ãã©ã€ã¿çŽãããªãšãã¬ã³è¢«èŠçŽãããªãããã¬
ã³åæçŽãã¬ã©ã¹çŽãã»ã«ããŒã¹ã¢ã»ããŒããã»
ã«ããŒã¹ãã€ãã¬ãŒããããªããã«ã¢ã»ã¿ãŒã«ã
ããªãããã¬ã³ãäŸãã°ããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒãçã®ããªãšã¹ãã«ãã€ã«ã ãããªã¹ãã¬ã³ç
ããããç¹ã«å¥œãŸããã¯ããªãšãã¬ã³è¢«èŠçŽãã
ãªãããã¬ã³åæçŽãçšããããããããã®æ¯æ
äœã¯ãããããã®æå ææã®äœ¿çšç®çã«å¿ããŠé©
å®éžæãããã ãããã®æ¯æäœã¯å¿ èŠã«å¿ããŠäžåŒå å·¥ãæœã
ããã æ¬çºæã®æå ææã«ã¯ãéæ¡æ£æ§ã®ã«ãã©ãŒã
çšããããšãã§ããããããéæ¡æ£æ§ã®ã«ãã©ãŒ
ãšããŠã¯ãã®åéã§éåžžçšãããããã®ãçšãã
ããšãã§ãããæ¯æäœããæãé ãæå æ§ããã²
ã³åéä¹³å€å±€ã«çµåããéæ¡æ£æ§ã®ã«ãã©ãŒãšã
ãŠã¯ãå±€æ§æã«ããç°ãªããã該乳å€å±€ãèµ€ææ§
ã®å Žåã«ã¯ã·ã¢ã³ã«ãã©ãŒãç·ææ§ã®å Žåã«ã¯ã
ãŒã³ã¿ã«ãã©ãŒãéææ§ã®å Žåã«ã¯ã€ãšããŒã«ã
ã©ãŒãçµåããã®ãäžè¬çã§ãããã€ãšããŒã«ã
ã©ãŒãšããŠã¯åçš®ã®ééã±ãã¡ãã¬ã³ç³»ã«ãã©ãŒ
ãçšããããšãã§ããããããã®ãã¡ãã³ãŸã€ã«
ã¢ã»ãã¢ããªãç³»åã³ãããã€ã«ã¢ã»ãã¢ããªã
ç³»ååç©ãæçšã§ããã ããŒã³ã¿ã«ãã©ãŒãšããŠã¯ããã©ãŸãã³ç³»åå
ç©ãã€ã³ããŸãã³ç³»ååç©ãã·ã¢ãã¢ã»ãã«åå
ç©ãã·ã¢ã³ã«ãã©ãŒãšããŠã¯ãããšããŒã«ç³»åå
ç©ãããããŒã«ç³»ååç©ãªã©ãçšããããšãã§ã
ãã ã«ã©ãŒããŒããŒã«æ¬çºæãé©çšããå Žåãæ¯æ
äœããæãé ãæå æ§ããã²ã³åéä¹³å€å±€ãèµ€æ
æ§ã§ããã該局ãå«æããéæ¡æ£æ§ã«ãã©ãŒãã·
ã¢ã³ã«ãã©ãŒã§ããããšã奜ãŸããã æ¬çºæã®æå æ§ææã«çšããããéæ¡æ£æ§ã®ã·
ã¢ã³ã«ãã©ãŒã¯ã奜ãŸããã¯ããšããŒã«ç³»ã·ã¢ã³
ã«ãã©ãŒã§ãããæã奜ãŸããã®ã¯äžèšäžè¬åŒ
ããã§è¡šãããã·ã¢ã³ã«ãã©ãŒã§ããã äžè¬åŒãã
ãåŒã
åŒäžãR1ã¯ã¢ãªãŒã«åºãã·ã¯ãã¢ã«ãã«åºãŸ
ãã¯è€çŽ ç°åºãè¡šããR2ã¯ã¢ã«ãã«åºãŸãã¯ã
ãšãã«åºãè¡šããR3ã¯æ°ŽçŽ ååãããã²ã³ååã
ã¢ã«ãã«åºãŸãã¯ã¢ã«ã³ãã·åºãè¡šããZ1ã¯æ°ŽçŽ
ååãããã²ã³ååããŸãã¯è³éŠæ第ïŒçŽã¢ãã³
ç³»çºè²çŸåäž»è¬ã®é žåäœãšã®åå¿ã«ããé¢è±ãåŸ
ãåºãè¡šããR1ã§è¡šãããã¢ãªãŒã«åºã¯ãäŸã
ã°ããšãã«åºããããã«åºã§ããã奜ãŸããã¯ã
ãšãã«åºã§ãããR1ã§è¡šãããè€çŽ ç°åºã¯ãäŸ
ãã°ããªãžã«åºããã©ã³åºçã§ãããR1ã§è¡šã
ããã·ã¯ãã¢ã«ãã«åºã¯äŸãã°ã·ã¯ããããã«
åºãã·ã¯ãããã·ã«åºçã§ããããããã®R1ã§
è¡šãããåºã¯åäžãããã¯è€æ°ã®çœ®æåºãæããŠ
ããŠãè¯ããäŸãã°ããšãã«åºã«å°å ¥ããã眮æ
åºãšããŠã¯ä»£è¡šçãªãã®ã«ããã²ã³ååïŒäŸãã°
ããçŽ ãå¡©çŽ ãèçŽ çïŒãã¢ã«ãã«åºïŒäŸãã°ã¡
ãã«åºããšãã«åºããããã«åºãããã«åºããã
ã·ã«åºçïŒãããããã·ã«åºãã·ã¢ãåºãããã
åºãã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·åºããšããã·
åºçïŒãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºïŒäŸãã°ã¡ã
ã«ã¹ã«ãã³ã¢ããåºããªã¯ãã«ã¹ã«ãã³ã¢ããåº
çïŒãã¢ãªãŒã«ã¹ã«ãã³ã¢ããåºïŒäŸãã°ããšã
ã«ã¹ã«ãã³ã¢ããåºããããã«ã¹ã«ãã³ã¢ããåº
çïŒãã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ããã«
ã¹ã«ãã¢ã¢ã€ã«åºçïŒãã¢ãªãŒã«ã¹ã«ãã¢ã¢ã€ã«
åºïŒäŸãã°ããšãã«ã¹ã«ãã¢ã¢ã€ã«åºçïŒãã¢ã«
ãã«ãªãã·ã«ã«ããã«åºïŒäŸãã°ã¡ãã«ãªãã·ã«
ã«ããã«åºçïŒãã¢ãªãŒã«ãªãã·ã«ã«ããã«åº
ïŒäŸãã°ããšãã«ãªãã·ã«ã«ããã«åºçïŒãã¢ãã
ã¹ã«ãã³ã¢ããåºãã¢ã·ã«ã¢ããåºãã«ã«ãã¢ã€
ã«åºãã¹ã«ããã«åºãã¹ã«ãã€ãã«åºãã¹ã«ããª
ãã·åºãã¹ã«ãåºãã¢ãªãŒã«ãªãã·åºãã¢ã«ã³ã
ã·åºãã«ã«ããã·ã«åºãã¢ã«ãã«ã«ã«ããã«åºã
ã¢ãªãŒã«ã«ã«ããã«åºãã¢ããã«ã«ããã«åºçã
æããããšãã§ããããããã®çœ®æåºã¯ïŒçš®ä»¥äž
ãããšãã«åºã«çœ®æãããŠããŠãè¯ããR1ã§è¡š
ããã奜ãŸããåºãšããŠã¯ãããšãã«åºãŸãã¯ã
ãã²ã³ååãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºãã¢ãªãŒ
ã«ã¹ã«ãã³ã¢ããåºãã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«
åºãã¢ãªãŒã«ã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã¹ã«ã
ãã«åºãã¢ãªãŒã«ã¹ã«ããã«åºãã¢ã«ãã«ã«ã«ã
ãã«åºãã¢ãªãŒã«ã«ã«ããã«åºããããã¯ã·ã¢ã
åºã眮æåºãšããŠïŒã€ãŸãã¯ïŒã€ä»¥äžæããããš
ãã«åºã§ããã R2ã§è¡šãããã¢ã«ãã«åºãçŽéãããã¯åå²
ã®ãã®ã§ããäŸãã°ã¡ãã«åºããšãã«åºãããã
ã«åºãããã«åºããªã¯ãã«åºçã§ããã 次ã«ãåèšäžè¬åŒããã§è¡šãããã·ã¢ã³ã«ã
ã©ãŒã®ä»£è¡šçå ·äœäŸã瀺ãã
ãã¯è€çŽ ç°åºãè¡šããR2ã¯ã¢ã«ãã«åºãŸãã¯ã
ãšãã«åºãè¡šããR3ã¯æ°ŽçŽ ååãããã²ã³ååã
ã¢ã«ãã«åºãŸãã¯ã¢ã«ã³ãã·åºãè¡šããZ1ã¯æ°ŽçŽ
ååãããã²ã³ååããŸãã¯è³éŠæ第ïŒçŽã¢ãã³
ç³»çºè²çŸåäž»è¬ã®é žåäœãšã®åå¿ã«ããé¢è±ãåŸ
ãåºãè¡šããR1ã§è¡šãããã¢ãªãŒã«åºã¯ãäŸã
ã°ããšãã«åºããããã«åºã§ããã奜ãŸããã¯ã
ãšãã«åºã§ãããR1ã§è¡šãããè€çŽ ç°åºã¯ãäŸ
ãã°ããªãžã«åºããã©ã³åºçã§ãããR1ã§è¡šã
ããã·ã¯ãã¢ã«ãã«åºã¯äŸãã°ã·ã¯ããããã«
åºãã·ã¯ãããã·ã«åºçã§ããããããã®R1ã§
è¡šãããåºã¯åäžãããã¯è€æ°ã®çœ®æåºãæããŠ
ããŠãè¯ããäŸãã°ããšãã«åºã«å°å ¥ããã眮æ
åºãšããŠã¯ä»£è¡šçãªãã®ã«ããã²ã³ååïŒäŸãã°
ããçŽ ãå¡©çŽ ãèçŽ çïŒãã¢ã«ãã«åºïŒäŸãã°ã¡
ãã«åºããšãã«åºããããã«åºãããã«åºããã
ã·ã«åºçïŒãããããã·ã«åºãã·ã¢ãåºãããã
åºãã¢ã«ã³ãã·åºïŒäŸãã°ã¡ããã·åºããšããã·
åºçïŒãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºïŒäŸãã°ã¡ã
ã«ã¹ã«ãã³ã¢ããåºããªã¯ãã«ã¹ã«ãã³ã¢ããåº
çïŒãã¢ãªãŒã«ã¹ã«ãã³ã¢ããåºïŒäŸãã°ããšã
ã«ã¹ã«ãã³ã¢ããåºããããã«ã¹ã«ãã³ã¢ããåº
çïŒãã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«åºïŒäŸãã°ããã«
ã¹ã«ãã¢ã¢ã€ã«åºçïŒãã¢ãªãŒã«ã¹ã«ãã¢ã¢ã€ã«
åºïŒäŸãã°ããšãã«ã¹ã«ãã¢ã¢ã€ã«åºçïŒãã¢ã«
ãã«ãªãã·ã«ã«ããã«åºïŒäŸãã°ã¡ãã«ãªãã·ã«
ã«ããã«åºçïŒãã¢ãªãŒã«ãªãã·ã«ã«ããã«åº
ïŒäŸãã°ããšãã«ãªãã·ã«ã«ããã«åºçïŒãã¢ãã
ã¹ã«ãã³ã¢ããåºãã¢ã·ã«ã¢ããåºãã«ã«ãã¢ã€
ã«åºãã¹ã«ããã«åºãã¹ã«ãã€ãã«åºãã¹ã«ããª
ãã·åºãã¹ã«ãåºãã¢ãªãŒã«ãªãã·åºãã¢ã«ã³ã
ã·åºãã«ã«ããã·ã«åºãã¢ã«ãã«ã«ã«ããã«åºã
ã¢ãªãŒã«ã«ã«ããã«åºãã¢ããã«ã«ããã«åºçã
æããããšãã§ããããããã®çœ®æåºã¯ïŒçš®ä»¥äž
ãããšãã«åºã«çœ®æãããŠããŠãè¯ããR1ã§è¡š
ããã奜ãŸããåºãšããŠã¯ãããšãã«åºãŸãã¯ã
ãã²ã³ååãã¢ã«ãã«ã¹ã«ãã³ã¢ããåºãã¢ãªãŒ
ã«ã¹ã«ãã³ã¢ããåºãã¢ã«ãã«ã¹ã«ãã¢ã¢ã€ã«
åºãã¢ãªãŒã«ã¹ã«ãã¢ã¢ã€ã«åºãã¢ã«ãã«ã¹ã«ã
ãã«åºãã¢ãªãŒã«ã¹ã«ããã«åºãã¢ã«ãã«ã«ã«ã
ãã«åºãã¢ãªãŒã«ã«ã«ããã«åºããããã¯ã·ã¢ã
åºã眮æåºãšããŠïŒã€ãŸãã¯ïŒã€ä»¥äžæããããš
ãã«åºã§ããã R2ã§è¡šãããã¢ã«ãã«åºãçŽéãããã¯åå²
ã®ãã®ã§ããäŸãã°ã¡ãã«åºããšãã«åºãããã
ã«åºãããã«åºããªã¯ãã«åºçã§ããã 次ã«ãåèšäžè¬åŒããã§è¡šãããã·ã¢ã³ã«ã
ã©ãŒã®ä»£è¡šçå ·äœäŸã瀺ãã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
ãåã
以äžæ¹æ³ã®å®æœäŸããæ¯èŒäŸãšãšãã«è¿°ã¹ãã
ãªãåœç¶ã®ããšã§ã¯ããããæ¬çºæã¯ä»¥äžã®å®æœ
äŸã«éå®ããããã®ã§ã¯ãªãã å®æœäŸâïŒ ãŸããåä¹³å€ã®èª¿è£œã«ã€ããŠè¿°ã¹ã次ãã§ãã
ããçšããè©Šæã®ç¹æ§ãè¿°ã¹ãã æ¯èŒä¹³å€ïŒ¡ 55âã«å ç±ããïŒïŒ ã®ãŒã©ãã³æº¶æ¶²äžã«PH6.0
ã§èåã«ãªãšå¡©åãããªãŠã ã®æ··å溶液
ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšããããšåœã¢ã«ã®ç¡é ž
é溶液ãšãpAg7.2ã«ã³ã³ãããŒã«ããŠããã«ãž
ãšããæ³ã«ãã€ãŠ20åéã«ããã€ãŠå ããããšã«
ãã€ãŠãå¹³åç²åŸ0.13ÎŒmã®ç«æ¹æ¶å¡©èåéã³ã¢
ä¹³å€ã調補ããã次ãã§èåã«ãªãšå¡©åãããªãŠ
ã ã®æ··å溶液ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšåœã¢ã«
ã®ç¡é žé溶液ãšãpAg7.0ã«ã³ã³ãããŒã«ããŠ60
åéã«ããã€ãŠæ·»å ããããšã«ããå¡©èåéã·ãš
ã«ãæœãããåŸãããä¹³å€ã¯0.35ÎŒmã®ç·å¡©åé
å«æç50ã¢ã«ïŒ ã®ç«æ¹æ¶ååæ£å¡©èåéä¹³å€ã§ã
ã€ãã æ¯èŒä¹³å€ïŒ¢ 45âã§å ç±ããïŒïŒ ã®ãŒã©ãã³æº¶æ¶²äžã«PHïŒã§
å¡©åãããªãŠã ãšããããšåœã¢ã«ã®ç¡é žé溶液ãš
ãpAg6.0ã«ã³ã³ãããŒã«ããŠããã«ãžãšããæ³
ã«ãã€ãŠ50åéã«ããã€ãŠå ããããšã«ãã€ãŠå¹³
åç²åŸ0.36ÎŒmã®å¡©åéç²åãã€ããã次ãã§ç¡
é žéã®50ã¢ã«ïŒ åã®èåã«ãªæº¶æ¶²ãã©ãã·ãŠæ·»å
ããŠããã®åŸ15åéå ç±ããããšã«ãããå¹³åç²
åŸ0.36ÎŒmã®ãããããåã®å€æä¹³å€ãåŸãã æ¬çºæä¹³å€ïŒ£ 60âã«å ç±ããïŒïŒ ã®ãŒã©ãã³æº¶æ¶²äžã«PH5.5
ã§èåã«ãªãšå¡©åãããªãŠã ã®æ··å溶液
ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšåœã¢ã«ã®ç¡é žé溶液ãš
ãpAg6.5ã«ã³ã³ãããŒã«ããŠããã«ãžãšããæ³
ã«ãã€ãŠ15åéã«ããã€ãŠå ããããšã«ãã€ãŠå¹³
åç²åŸ0.15ÎŒmã®ç«æ¹æ¶å¡©èåéã³ã¢ä¹³å€ã調補
ããã次ãã§èåã«ãªãšå¡©åãããªãŠã ã®æ··å溶
液ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšåœã¢ã«ã®ç¡é žé溶
液ãšãpAg7.0ã«ã³ã³ãããŒã«ããŠã45åéã«ã
ãã€ãŠæ·»å ããããšã«ããå¡©èåéã·ãšã«ãæœã
ããåŸãããä¹³å€ã¯å¹³åç²åŸ0.35ÎŒmã®ç·å¡©åé
å«æç50ã¢ã«ïŒ ã®ç«æ¹æ¶ååæ£å¡©èåéä¹³å€ã§ã
ã€ãã æ¬çºæä¹³å€ïŒ€ 50âã«å ç±ããïŒïŒ ã®ãŒã©ãã³æº¶æ¶²äžã«PH6.0
ã«ãŠãèåã«ãªãšå¡©åãããªãŠã ã®æ··å溶液
ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšããããšåœã¢ã«ã®ç¡é ž
é溶液ãšãpAg7.7ã«ã³ã³ãããŒã«ããŠããã«ãž
ãšããæ³ã«ãã€ãŠ20åéã«ããã€ãŠå ããããšã«
ãã€ãŠãå¹³åç²åŸ0.17ÎŒmã®ååé¢äœå¡©èåéã³
ã¢ä¹³å€ã調補ããã次ãã§èåã«ãªãšå¡©åãããª
ãŠã ã®æ··å溶液ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšãåœ
ã¢ã«ã®ç¡é žé溶液ãšãpAg7.7ã«ã³ã³ãããŒã«ã
ãŠ50åéã«ããã€ãŠæ·»å ããããšã«ãããå¡©èå
éã·ãšã«ãæœãããåŸãããä¹³å€ã¯ãå¹³åç²åŸ
0.36ÎŒmã®ç·å¡©åéå«æç50ã¢ã«ïŒ ã®ååé¢äœå
åæ£å¡©èåéä¹³å€ã§ãã€ãã 次ã«ãã®ïŒçš®ã®ä¹³å€ã«ã€ããåèšèšèŒãããšã
ãã®è¡šé¢ãå éšçŸåãè¡ããããããå éšçŸåã®
æé«æ¿åºŠDmaxïŒDIãšããïŒã«å¯Ÿããè¡šé¢çŸåã®
æé«æ¿åºŠDmaxïŒDSãšããïŒã枬å®ããããã®çµ
æã次ã®è¡šâïŒã«ç€ºãã
ãªãåœç¶ã®ããšã§ã¯ããããæ¬çºæã¯ä»¥äžã®å®æœ
äŸã«éå®ããããã®ã§ã¯ãªãã å®æœäŸâïŒ ãŸããåä¹³å€ã®èª¿è£œã«ã€ããŠè¿°ã¹ã次ãã§ãã
ããçšããè©Šæã®ç¹æ§ãè¿°ã¹ãã æ¯èŒä¹³å€ïŒ¡ 55âã«å ç±ããïŒïŒ ã®ãŒã©ãã³æº¶æ¶²äžã«PH6.0
ã§èåã«ãªãšå¡©åãããªãŠã ã®æ··å溶液
ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšããããšåœã¢ã«ã®ç¡é ž
é溶液ãšãpAg7.2ã«ã³ã³ãããŒã«ããŠããã«ãž
ãšããæ³ã«ãã€ãŠ20åéã«ããã€ãŠå ããããšã«
ãã€ãŠãå¹³åç²åŸ0.13ÎŒmã®ç«æ¹æ¶å¡©èåéã³ã¢
ä¹³å€ã調補ããã次ãã§èåã«ãªãšå¡©åãããªãŠ
ã ã®æ··å溶液ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšåœã¢ã«
ã®ç¡é žé溶液ãšãpAg7.0ã«ã³ã³ãããŒã«ããŠ60
åéã«ããã€ãŠæ·»å ããããšã«ããå¡©èåéã·ãš
ã«ãæœãããåŸãããä¹³å€ã¯0.35ÎŒmã®ç·å¡©åé
å«æç50ã¢ã«ïŒ ã®ç«æ¹æ¶ååæ£å¡©èåéä¹³å€ã§ã
ã€ãã æ¯èŒä¹³å€ïŒ¢ 45âã§å ç±ããïŒïŒ ã®ãŒã©ãã³æº¶æ¶²äžã«PHïŒã§
å¡©åãããªãŠã ãšããããšåœã¢ã«ã®ç¡é žé溶液ãš
ãpAg6.0ã«ã³ã³ãããŒã«ããŠããã«ãžãšããæ³
ã«ãã€ãŠ50åéã«ããã€ãŠå ããããšã«ãã€ãŠå¹³
åç²åŸ0.36ÎŒmã®å¡©åéç²åãã€ããã次ãã§ç¡
é žéã®50ã¢ã«ïŒ åã®èåã«ãªæº¶æ¶²ãã©ãã·ãŠæ·»å
ããŠããã®åŸ15åéå ç±ããããšã«ãããå¹³åç²
åŸ0.36ÎŒmã®ãããããåã®å€æä¹³å€ãåŸãã æ¬çºæä¹³å€ïŒ£ 60âã«å ç±ããïŒïŒ ã®ãŒã©ãã³æº¶æ¶²äžã«PH5.5
ã§èåã«ãªãšå¡©åãããªãŠã ã®æ··å溶液
ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšåœã¢ã«ã®ç¡é žé溶液ãš
ãpAg6.5ã«ã³ã³ãããŒã«ããŠããã«ãžãšããæ³
ã«ãã€ãŠ15åéã«ããã€ãŠå ããããšã«ãã€ãŠå¹³
åç²åŸ0.15ÎŒmã®ç«æ¹æ¶å¡©èåéã³ã¢ä¹³å€ã調補
ããã次ãã§èåã«ãªãšå¡©åãããªãŠã ã®æ··å溶
液ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšåœã¢ã«ã®ç¡é žé溶
液ãšãpAg7.0ã«ã³ã³ãããŒã«ããŠã45åéã«ã
ãã€ãŠæ·»å ããããšã«ããå¡©èåéã·ãšã«ãæœã
ããåŸãããä¹³å€ã¯å¹³åç²åŸ0.35ÎŒmã®ç·å¡©åé
å«æç50ã¢ã«ïŒ ã®ç«æ¹æ¶ååæ£å¡©èåéä¹³å€ã§ã
ã€ãã æ¬çºæä¹³å€ïŒ€ 50âã«å ç±ããïŒïŒ ã®ãŒã©ãã³æº¶æ¶²äžã«PH6.0
ã«ãŠãèåã«ãªãšå¡©åãããªãŠã ã®æ··å溶液
ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšããããšåœã¢ã«ã®ç¡é ž
é溶液ãšãpAg7.7ã«ã³ã³ãããŒã«ããŠããã«ãž
ãšããæ³ã«ãã€ãŠ20åéã«ããã€ãŠå ããããšã«
ãã€ãŠãå¹³åç²åŸ0.17ÎŒmã®ååé¢äœå¡©èåéã³
ã¢ä¹³å€ã調補ããã次ãã§èåã«ãªãšå¡©åãããª
ãŠã ã®æ··å溶液ïŒKBrïŒNaClïŒïŒïŒïŒïŒãšãåœ
ã¢ã«ã®ç¡é žé溶液ãšãpAg7.7ã«ã³ã³ãããŒã«ã
ãŠ50åéã«ããã€ãŠæ·»å ããããšã«ãããå¡©èå
éã·ãšã«ãæœãããåŸãããä¹³å€ã¯ãå¹³åç²åŸ
0.36ÎŒmã®ç·å¡©åéå«æç50ã¢ã«ïŒ ã®ååé¢äœå
åæ£å¡©èåéä¹³å€ã§ãã€ãã 次ã«ãã®ïŒçš®ã®ä¹³å€ã«ã€ããåèšèšèŒãããšã
ãã®è¡šé¢ãå éšçŸåãè¡ããããããå éšçŸåã®
æé«æ¿åºŠDmaxïŒDIãšããïŒã«å¯Ÿããè¡šé¢çŸåã®
æé«æ¿åºŠDmaxïŒDSãšããïŒã枬å®ããããã®çµ
æã次ã®è¡šâïŒã«ç€ºãã
ãè¡šã
è¡šâïŒããæãããªæ§ã«ãä¹³å€ïŒ¢ïŒïŒ£ïŒïŒ€ã¯å
éšæœååä¹³å€ã§ãããä¹³å€ïŒ¡ã¯è¡šé¢æœååä¹³å€ã§
ããã ïŒçš®ã®ä¹³å€ã«ã€ããŠã¯ã次ã«ç¡«é»å¢æå€ãèµ€æ
å æ§å¢æè²çŽ åã³å®å®å€ãå ããèµ€ææ§å¡©èåé
ä¹³å€ãåŸãã 次ãã§ã次ã®å±€ãã¬ãžã³ã³ãŒãã€ã³ã°ããããŒ
ããŒæ¯æäœäžã«é 次å¡èšããããšã«ãããããã²
ã³åéå€å±€ã«ã©ãŒåçæå ææãäœæããã 第ïŒå±€ ã€ãšããŒã«ãã©ãŒïŒ¡ïŒ7.8mgïŒãšåžžæ³ã«ãã€ãŠåŸ
ãããéæå æ§å¡©èåéïŒå¹³åç²åŸ0.8ÎŒmãéã«
æç®ããŠ4.0mgïŒåã³ãŒã©ãã³20mgãæããéæ
å æ§ããã²ã³åéä¹³å€å±€ã 第ïŒå±€ ãžãªã¯ãã«ãã€ããããã³0.2mgåã³ãŒã©ãã³
10mgãæããäžéå±€ã 第ïŒå±€ ããŒã³ã¿ã«ãã©ãŒïŒ¢ïŒ4.2mgïŒãšåžžæ³ã«ãã€ãŠåŸ
ãããç·æå æ§å¡©èåéä¹³å€ïŒå¹³åç²åŸ0.5ÎŒmã
éã«æç®ããŠ3.7mgïŒåã³ãŒã©ãã³20mgãæãã
ç·æå æ§ããã²ã³åéä¹³å€å±€ã 第ïŒå±€ ãžãªã¯ãã«ãã€ããããã³0.3mgãšãŒã©ãã³15
mgãæããäžéå±€ã 第ïŒå±€ ã·ã¢ã³ã«ãã©ãŒïŒ£ïŒ3.2mgïŒãšäžèšæ¹æ³ã§èª¿è£œã
ãïŒïŒ¢ïŒïŒ£ïŒïŒ€ã®èµ€æå æ§å¡©èåéä¹³å€ïŒéã«
æç®ããŠ3.0mgïŒåã³ãŒã©ãã³15mgãæããèµ€æ
å æ§ããã²ã³åéä¹³å€å±€ã 第ïŒå±€ ãŒã©ãã³10mgãå«ããŒã©ãã³ä¿è·å±€ã
éšæœååä¹³å€ã§ãããä¹³å€ïŒ¡ã¯è¡šé¢æœååä¹³å€ã§
ããã ïŒçš®ã®ä¹³å€ã«ã€ããŠã¯ã次ã«ç¡«é»å¢æå€ãèµ€æ
å æ§å¢æè²çŽ åã³å®å®å€ãå ããèµ€ææ§å¡©èåé
ä¹³å€ãåŸãã 次ãã§ã次ã®å±€ãã¬ãžã³ã³ãŒãã€ã³ã°ããããŒ
ããŒæ¯æäœäžã«é 次å¡èšããããšã«ãããããã²
ã³åéå€å±€ã«ã©ãŒåçæå ææãäœæããã 第ïŒå±€ ã€ãšããŒã«ãã©ãŒïŒ¡ïŒ7.8mgïŒãšåžžæ³ã«ãã€ãŠåŸ
ãããéæå æ§å¡©èåéïŒå¹³åç²åŸ0.8ÎŒmãéã«
æç®ããŠ4.0mgïŒåã³ãŒã©ãã³20mgãæããéæ
å æ§ããã²ã³åéä¹³å€å±€ã 第ïŒå±€ ãžãªã¯ãã«ãã€ããããã³0.2mgåã³ãŒã©ãã³
10mgãæããäžéå±€ã 第ïŒå±€ ããŒã³ã¿ã«ãã©ãŒïŒ¢ïŒ4.2mgïŒãšåžžæ³ã«ãã€ãŠåŸ
ãããç·æå æ§å¡©èåéä¹³å€ïŒå¹³åç²åŸ0.5ÎŒmã
éã«æç®ããŠ3.7mgïŒåã³ãŒã©ãã³20mgãæãã
ç·æå æ§ããã²ã³åéä¹³å€å±€ã 第ïŒå±€ ãžãªã¯ãã«ãã€ããããã³0.3mgãšãŒã©ãã³15
mgãæããäžéå±€ã 第ïŒå±€ ã·ã¢ã³ã«ãã©ãŒïŒ£ïŒ3.2mgïŒãšäžèšæ¹æ³ã§èª¿è£œã
ãïŒïŒ¢ïŒïŒ£ïŒïŒ€ã®èµ€æå æ§å¡©èåéä¹³å€ïŒéã«
æç®ããŠ3.0mgïŒåã³ãŒã©ãã³15mgãæããèµ€æ
å æ§ããã²ã³åéä¹³å€å±€ã 第ïŒå±€ ãŒã©ãã³10mgãå«ããŒã©ãã³ä¿è·å±€ã
ãåã
ãåã
ãšãã¬ã³ãžã¢ãã³ããã©é
¢é
žéã¢ã³ã¢ããŠã
61ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã
ïŒïœ ããªç¡«é žã¢ã³ã¢ããŠã 125ïœ ã¡ã¿éäºç¡«é žãããªãŠã 13ïœ äºç¡«é žãããªãŠã 2.7ïœ çŽæ°Žãå ããŠïŒãšããïŒPHïŒ7.2ïŒ
61ïœ ãšãã¬ã³ãžã¢ãã³ããã©é ¢é žïŒã¢ã³ã¢ããŠã
ïŒïœ ããªç¡«é žã¢ã³ã¢ããŠã 125ïœ ã¡ã¿éäºç¡«é žãããªãŠã 13ïœ äºç¡«é žãããªãŠã 2.7ïœ çŽæ°Žãå ããŠïŒãšããïŒPHïŒ7.2ïŒ
ãè¡šã
è¡šâïŒãããæ¬çºæã®èµ€æå
æ§ä¹³å€ïŒ£ïŒïŒ€ã¯ã
æ¯èŒã®èµ€æå æ§ä¹³å€ïŒ¡ïŒïŒ¢ã«å¯ŸããŠåŒ·å¶å£åãã¹
ãã§ã®æ床å€åãå°ãããäžã€ä»ã®éæå æ§å±€å
ã³ç·æå æ§å±€ã®æ床å€åã«å¯ŸããŠãã©ã³ã¹ããšã
ãŠãããåŸã€ãŠæ¬çºæã«ä¿ãè©Šæã¯ãã«ã©ãŒåç
æå ææãšããŠåªããçè©Šæä¿åæ§ãäžããããš
ãæããã§ããã å®æœäŸ ïŒ å®æœäŸâïŒã®è©ŠæãçšããŠã也ç¥æã§ã®å§åã«
ããªè©Šéšãè¡ã€ããè©Šéšã¯æ°æ±ç§åŠïŒæ ªïŒè£œåŒæ»
匷床詊éšæ©ãã€ãã³18åã«0.2mmÏãã€ã€éãè£
çãã也ç¥ç¶æ ã®è©Šæã«ãå éã10ïœãã100ïœ
ã®ç¯å²ã§åŒæ»åŒ·åºŠãå€ããŠåŒãæ»ãè©Šéšãè¡ã€ã
åŸãå®æœäŸâïŒã®ã«ã©ãŒçŸååŠçãè¡ããã«ããª
ïŒãã®å Žåã¯ãã·ã¢ã³åïŒã®çºçãæ€å®ãããã
ã®çµæãè¡šâïŒã«ç€ºãã
æ¯èŒã®èµ€æå æ§ä¹³å€ïŒ¡ïŒïŒ¢ã«å¯ŸããŠåŒ·å¶å£åãã¹
ãã§ã®æ床å€åãå°ãããäžã€ä»ã®éæå æ§å±€å
ã³ç·æå æ§å±€ã®æ床å€åã«å¯ŸããŠãã©ã³ã¹ããšã
ãŠãããåŸã€ãŠæ¬çºæã«ä¿ãè©Šæã¯ãã«ã©ãŒåç
æå ææãšããŠåªããçè©Šæä¿åæ§ãäžããããš
ãæããã§ããã å®æœäŸ ïŒ å®æœäŸâïŒã®è©ŠæãçšããŠã也ç¥æã§ã®å§åã«
ããªè©Šéšãè¡ã€ããè©Šéšã¯æ°æ±ç§åŠïŒæ ªïŒè£œåŒæ»
匷床詊éšæ©ãã€ãã³18åã«0.2mmÏãã€ã€éãè£
çãã也ç¥ç¶æ ã®è©Šæã«ãå éã10ïœãã100ïœ
ã®ç¯å²ã§åŒæ»åŒ·åºŠãå€ããŠåŒãæ»ãè©Šéšãè¡ã€ã
åŸãå®æœäŸâïŒã®ã«ã©ãŒçŸååŠçãè¡ããã«ããª
ïŒãã®å Žåã¯ãã·ã¢ã³åïŒã®çºçãæ€å®ãããã
ã®çµæãè¡šâïŒã«ç€ºãã
ãè¡šã
æ¬çºæã®ä¹³å€ïŒ£ïŒïŒ€ã¯ãæ¯èŒä¹³å€ïŒ¡ïŒïŒ¢ã«æ¯ã¹
ãŠãèãã也ç¥æã§ã®å§åã«ããªãåºã«ãããå§
åèæ§ãæ Œæ®µã«åäžããŠããããšãè¡šâïŒããæ
ããã§ããã å®æœäŸâïŒ å®æœäŸâïŒãšåæ§ãªæäœã«ãããè¡šâïŒã«ç€ºã
ãããªå皮塩èåéä¹³å€ã調補ããã
ãŠãèãã也ç¥æã§ã®å§åã«ããªãåºã«ãããå§
åèæ§ãæ Œæ®µã«åäžããŠããããšãè¡šâïŒããæ
ããã§ããã å®æœäŸâïŒ å®æœäŸâïŒãšåæ§ãªæäœã«ãããè¡šâïŒã«ç€ºã
ãããªå皮塩èåéä¹³å€ã調補ããã
ãè¡šã
ãè¡šã
ãããã®ä¹³å€ãè¡šé¢ãå
éšçŸåããæé«æ¿åºŠã®
æ¯DIïŒDSã枬å®ããã
æ¯DIïŒDSã枬å®ããã
ãè¡šã
è¡šâïŒãããæ¬çºæã®ä¹³å€ïŒ©ïŒïŒªïŒïŒ«ïŒïŒ¬ã¯å
éšæœååä¹³å€ã§ããããšãå€ãã ãããïŒçš®ã®ä¹³å€ã«ã€ããŠã次ã«ç¡«é»å¢æå€ã
èµ€æå æ§å¢æè²çŽ åã³å®å®å€ãå ããèµ€ææ§å¡©è
åéä¹³å€ãåŸãã次ãã§å®æœäŸâïŒãšåæ§ã«ããŠ
å€å±€ã«ã©ãŒåçæå ææãäœæããã ãããïŒçš®ã®å¡åžè©Šæã§ãå³æ¥è©ŠæãšãµãŒã¢è©Š
æïŒ50âïŒ20ïŒ RH3æ¥ãåã³50âïŒ80ïŒ RH3æ¥ïŒ
ãäœãã«ã©ãŒçŸååŠçã«ãããçè©Šæä¿åæã§ã®
æ§èœå€åãã¿ããïŒã»ã³ã·ãã¡ããªãŒã®æž¬å®ã¯èµ€
ææ§å±€ã®ã¿ïŒ
éšæœååä¹³å€ã§ããããšãå€ãã ãããïŒçš®ã®ä¹³å€ã«ã€ããŠã次ã«ç¡«é»å¢æå€ã
èµ€æå æ§å¢æè²çŽ åã³å®å®å€ãå ããèµ€ææ§å¡©è
åéä¹³å€ãåŸãã次ãã§å®æœäŸâïŒãšåæ§ã«ããŠ
å€å±€ã«ã©ãŒåçæå ææãäœæããã ãããïŒçš®ã®å¡åžè©Šæã§ãå³æ¥è©ŠæãšãµãŒã¢è©Š
æïŒ50âïŒ20ïŒ RH3æ¥ãåã³50âïŒ80ïŒ RH3æ¥ïŒ
ãäœãã«ã©ãŒçŸååŠçã«ãããçè©Šæä¿åæã§ã®
æ§èœå€åãã¿ããïŒã»ã³ã·ãã¡ããªãŒã®æž¬å®ã¯èµ€
ææ§å±€ã®ã¿ïŒ
ãè¡šã
床ã§ç€ºããã
è¡šâïŒãããæ¬çºæã®ä¹³å€ïŒïŒ©ïŒïŒªïŒïŒ«ïŒïŒ¬ïŒ
ã¯ã匷å¶å£åãã¹ãã«ããæ床å€åãèããæ¹è¯
ãããŠããããšãæããã§ããã å®æœäŸâïŒ å®æœäŸâïŒã®ïŒçš®ã®è©ŠæãçšããŠãå®æœäŸâïŒ
ãšåæ§ã®è©Šéšæ³ã§ä¹Ÿç¥æã§ã®å§åã«ããªè©Šéšãè¡
ã€ãããã®çµæãè¡šâïŒã«ç€ºãã
è¡šâïŒãããæ¬çºæã®ä¹³å€ïŒïŒ©ïŒïŒªïŒïŒ«ïŒïŒ¬ïŒ
ã¯ã匷å¶å£åãã¹ãã«ããæ床å€åãèããæ¹è¯
ãããŠããããšãæããã§ããã å®æœäŸâïŒ å®æœäŸâïŒã®ïŒçš®ã®è©ŠæãçšããŠãå®æœäŸâïŒ
ãšåæ§ã®è©Šéšæ³ã§ä¹Ÿç¥æã§ã®å§åã«ããªè©Šéšãè¡
ã€ãããã®çµæãè¡šâïŒã«ç€ºãã
ãè¡šã
äžè¿°ã®åŠãæ¬çºæã®ããã²ã³åéã«ã©ãŒåçæ
å ææã¯ãçè©Šæã®ä¿åæ§ãè¯ãããã€å§åã«ã
ãªèæ§ã«åªãããšããå¹æãæããã
å ææã¯ãçè©Šæã®ä¿åæ§ãè¯ãããã€å§åã«ã
ãªèæ§ã«åªãããšããå¹æãæããã
第ïŒå³åã³ç¬¬ïŒå³ã¯ãæ¬çºæã«çšããããšãã§
ããç²åæ§é ãæš¡åŒçã«ç¥ç€ºãããã®ã§ããã ïŒâŠâŠè¢«èŠå±€ãïŒâŠâŠå±åšå±€ã
ããç²åæ§é ãæš¡åŒçã«ç¥ç€ºãããã®ã§ããã ïŒâŠâŠè¢«èŠå±€ãïŒâŠâŠå±åšå±€ã
Claims (1)
- ïŒ æ¯æäœäžã«å°ãªããšãæè²æ§ã®ç°ãªãïŒçš®ä»¥
äžã®æè²æ§å±€ãæããããã²ã³åéã«ã©ãŒåçæ
å ææã«ãããŠãæ¯æäœããæãé ãæå æ§ãã
ã²ã³åéä¹³å€å±€ããã¬åãšãªãããã«ãå³ã¡å åŠ
æ¿åºŠã«ãããŠãã«ããªïŒ0.1ãã®æ床ç¹ããšã€ã
å Žåã®æé©æ床ã®60ïŒ ä»¥äžã«ãªãããã«ååŠå¢æ
ãæœãããã³ã¢ïŒã·ãšã«æ§é ãæããå éšæœåå
ããã²ã³åéç²åãå«æããããšãç¹åŸŽãšããã
ãã²ã³åéã«ã©ãŒåçæå ææã
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25496085A JPS62115434A (ja) | 1985-11-15 | 1985-11-15 | ããã²ã³åéã«ã©âåçæå ææ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25496085A JPS62115434A (ja) | 1985-11-15 | 1985-11-15 | ããã²ã³åéã«ã©âåçæå ææ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62115434A JPS62115434A (ja) | 1987-05-27 |
JPH0577057B2 true JPH0577057B2 (ja) | 1993-10-25 |
Family
ID=17272256
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP25496085A Granted JPS62115434A (ja) | 1985-11-15 | 1985-11-15 | ããã²ã³åéã«ã©âåçæå ææ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62115434A (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01224752A (ja) * | 1988-03-04 | 1989-09-07 | Fuji Photo Film Co Ltd | ããã²ã³åéã«ã©ãŒåçæå ææ |
JPH0833602B2 (ja) * | 1988-07-19 | 1996-03-29 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéåçæå ææ |
JPH03100542A (ja) * | 1989-09-13 | 1991-04-25 | Fuji Photo Film Co Ltd | ããã²ã³åéåçä¹³å€ã®è£œé æ¹æ³ |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59140444A (ja) * | 1982-08-12 | 1984-08-11 | ã¢ã°ãã¢âã²ãŽãšã«ãã»ã¢ã¯ããšã³ã²ãŒã«ã·ã€ãã | ããã²ã³éåçä¹³å€ |
JPS60107641A (ja) * | 1983-11-16 | 1985-06-13 | Fuji Photo Film Co Ltd | å éšæœååã³ã¢ïŒã·ãšã«ããã²ã³åéåçä¹³å€ |
-
1985
- 1985-11-15 JP JP25496085A patent/JPS62115434A/ja active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59140444A (ja) * | 1982-08-12 | 1984-08-11 | ã¢ã°ãã¢âã²ãŽãšã«ãã»ã¢ã¯ããšã³ã²ãŒã«ã·ã€ãã | ããã²ã³éåçä¹³å€ |
JPS60107641A (ja) * | 1983-11-16 | 1985-06-13 | Fuji Photo Film Co Ltd | å éšæœååã³ã¢ïŒã·ãšã«ããã²ã³åéåçä¹³å€ |
Also Published As
Publication number | Publication date |
---|---|
JPS62115434A (ja) | 1987-05-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4775617A (en) | Silver halide color photographic material containing monodispersed tabular silver halide grains | |
US4590155A (en) | Emulsion having high silver chloride content, photographic recording material and process for the production of photographic recordings | |
JP2557221B2 (ja) | ããã²ã³åéåçæå ææ | |
US4835095A (en) | Photosensitive tabular core/shell silver halide emulsion | |
US5015563A (en) | Silver halide light-sensitive color photographic material suitable for rapid processing comprising a mercapto or an azaindene compound | |
EP0160469B1 (en) | Light-sensitive silver halide multi-layer color photographic material | |
EP0112162B2 (en) | Light-sensitive silver halide photographic material | |
EP0297804B1 (en) | Silver halide photographic light-sensitive material | |
JPH0715571B2 (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPH0560852B2 (ja) | ||
JPH0623831B2 (ja) | æ°èŠãªå±€æ§æã®ããã²ã³åéã«ã©âåçæå ææ | |
JPH0313575B2 (ja) | ||
US4892803A (en) | Color image-forming process compressing developer containing no benzyl alcohol | |
JPH01131544A (ja) | åççšãã¬åããã²ã³åéä¹³å€ã®è£œé æ¹æ³ | |
JPH0577057B2 (ja) | ||
GB2180359A (en) | Silver halide color reversal photographic materials | |
US4977075A (en) | Silver halide photographic emulsion | |
JPH0378744A (ja) | ããã²ã³éã«ã©ãŒåçææ | |
JPS62108240A (ja) | ããã²ã³åéåçä¹³å€åã³ãã®è£œé æ¹æ³ãåã³è©²ä¹³å€ãçšããããã²ã³åéåçæå ææ | |
JPH0580445A (ja) | ããã²ã³åéä¹³å€ã®è£œé æ¹æ³ | |
JPH0833599B2 (ja) | ããã²ã³åéã«ã©âåçæå ææ | |
JPH0610757B2 (ja) | ããã²ã³åéã«ã©âå転æå ææ | |
JPH06250316A (ja) | ããã²ã³åéä¹³å€åã³ããã²ã³åéåçæå ææ | |
JP2961717B2 (ja) | ããã²ã³åéåçæå ææ | |
JPH0518412B2 (ja) |