JPH05505354A - デンプン含有マトリックスを有する低透過性ラミネートフィルムおよびその製法 - Google Patents

デンプン含有マトリックスを有する低透過性ラミネートフィルムおよびその製法

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JPH05505354A
JPH05505354A JP91513142A JP51314291A JPH05505354A JP H05505354 A JPH05505354 A JP H05505354A JP 91513142 A JP91513142 A JP 91513142A JP 51314291 A JP51314291 A JP 51314291A JP H05505354 A JPH05505354 A JP H05505354A
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laminate film
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バスチオリ、カチア
ベッロッチ、ヴィットリオ
ロマノ、ヂャンカルロ
トシン、マウリツィーオ
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ノバモント・ソシエタ・ペル・アチオニ
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    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02Physical, chemical or physicochemical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/15203Properties of the article, e.g. stiffness or absorbency
    • A61F13/15252Properties of the article, e.g. stiffness or absorbency compostable or biodegradable
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/514Backsheet, i.e. the impermeable cover or layer furthest from the skin
    • A61F13/51401Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/514Backsheet, i.e. the impermeable cover or layer furthest from the skin
    • A61F13/51401Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
    • A61F13/51405Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material treated or coated, e.g. with moisture repellent agent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/46Applications of disintegrable, dissolvable or edible materials
    • B65D65/466Bio- or photodegradable packaging materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/716Degradable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/73Hydrophobic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00Animal or vegetable based
    • B32B2317/20Starch
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/70Food packaging
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/90Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31909Next to second addition polymer from unsaturated monomers
    • Y10T428/31913Monoolefin polymer

Abstract

(57)【要約】本公報は電子出願前の出願データであるため要約のデータは記録されません。

Description

【発明の詳細な説明】 (i)分解デンプンとオレフィンコポリマーから構成されるデンプン含有マトリ ックスを含むポリマー材料から形成され、水に対して不溶性であるかもしくは膨 張性を示すに過ぎない少なくとも1つの第一層および(ii)該第一層に接着す る疎水性材料から形成される第二層を含むラミネートフィルム。該ラミネートフ ィルムの用途は食料製品の包装およびガスや蒸気に対して有効な障壁が要求され る人工肛門形成術用容器である。
国際調査報告 国際調査報告 PCT/EP 91101443 SA 49B41

Claims (19)

    【特許請求の範囲】
  1. 1.(i)デンプン含有マトリックスを含み、水中において不溶性であるか、膨 張するに過ぎないポリマー材料から成る少なくとも1つの第一層および(ii) 該第一層に接着する疎水性材料から成る第二層を含むラミネートフィルム。
  2. 2.ポリマー材料が分解デンプンと熱可塑性合成ポリマーを含有する組成物から 成り、該熱可塑性合成ポリマーが少なくとも1種のエチレン性不飽和モノマーの コポリマーであり、該ポリマーが、ヒドロキシ基、アルコキシ基、カルボキシ基 、カルボキシアルキル基、アルキルカルボキシ基およびアセタール基から成る群 から選択される極性基を少なくとも1個含む探り返し単位を有する請求項1記載 のラミネートフィルム。
  3. 3.該ポリマーが、ポリビニルアルコール、およびエチレン・プロピレン、イソ プテンおよびスチレンから成る群から選択されるオレフィンとアクリル酸ビニル アルコールもしくはビニルアセテートとのコポリマーから成る群から選択される ポリマーである請求項2記載のラミネートフィルム。
  4. 4.デンプン含有マトリックスを含むポリマー材料が、分解デンプンおよびエチ レン−ビニルアルコール、ヒドロキシル基の一部がオキソ基もしくはアルキルカ ルボニル基によって置換されたエチレン−ビニルアルコール、エチレン−アクリ ル酸およびエチレン−ビニルアセテートから成る群から選択されるエチレンコポ リマー、エチレン−ビニルアルコール−ビニルアセテートターポリマーまたはこ れらの混合物から構成される請求項1記載のラミネートフィルム。
  5. 5.エチレンコポリマーが、エチレン成分の含有量が15〜50モル%、好まし くは30〜45モル%であるエチレン−ビニルアルコールである請求項4記載の ラミネートフィルム。
  6. 6.エチレンコポリマーが、ビニルアセテート成分の含有量が12〜80モル% であるエチレン−ビニルアセテートを含有する請求項2記載のラミネートフィル ム。
  7. 7.第一層がデンプンおよびエチレンコポリマーを1:4〜4:1の重量比で含 有する請求項1記載のラミネートフィルム。
  8. 8.第一層を構成するポリマー材料が、高沸点可塑剤を含有し、その含水量が6 重量%(押出し成形後、コンディショニング前の値)を越えない請求項7記載の ラミネートフィルム。
  9. 9.第二層が、次式(1)で表わされるパラキシリレンモノマーのポリマーまた はコポリマーから形成される請求項1記載のラミネートフィルム: ▲数式、化学式、表等があります▼(I)式中、XはC1〜C6アルキル基、C 6〜C10アリール基、C7〜C18アリールアルキル基、ハロアルキル基、ハ ロアリールアルキル基、アセトキシ基、アミノアルキル基、アリールアミノ基、 シアノ基、アルコキシ基、ヒドロキシ基、ニトロ基、ハロゲン原子、スルフォン 基、スルフォンエステル基、燐含有置換基、スルフィド基、アルキルスルフォキ シド基または水素原子を示し、nは0または1〜4の数を示す。
  10. 10.バラキシリレンモノマーが、クロロパラキシリレン、ジクロロパラキシリ レン、シアノパラキシリレン、ヨードパラキシリレン、フルオロパラキシリレン 、ヒドロキシメチルパラキシリレン、エチルパラキシリレン、アミノメチルパラ キシリレン、カルボメトキシバラキシリレンおよびこれらの混合物から成る群か ら選択されるモノマーである請求項9記載のラミネートフィルム。
  11. 11.第二層を形成する疎水性材料が遊離の酸基を有するポリマーである請求項 1記載のラミネートフィルム。
  12. 12.遊離の酸基を有するポリマーが、エチレン−アクリル酸ポリマーまたはエ チレン−アクリル酸−アルキルアクリレートポリマーである請求項9記載のラミ ネートフィルム。
  13. 13.第二層を形成する疎水性材料がポリヒドロキシアルカノエートポリマー、 乳酸ホモポリマー、乳酸とグリコール酸もしくはε−カプロラクトンとのコポリ マー、ポリエチレン−ビニルアルコールまたはポリエチレン−ビニルアセテート である請求項1記載のラミネートフィルム。
  14. 14.第二層が、ポリビニルビロリドン(PVP)もしくはPVPエステルとブ チルアクリレート、ブチルアクリレート/メチルメタクリレート、ジエチルアミ ノメチルメタクリレート、ビニルアセテート、アクリル酸、アクリル酸ポリマー 、アクリル酸エステルまたはアクリル酸ポリマーエステルとのコポリマーを含有 する請求項1記載のラミネートフィルム。
  15. 15.請求項1記載のラミネートフィルムから製造される糞便用容器。
  16. 16.請求項1記載のラミネートフィルムを含む食料製品用包装。
  17. 17.デンプン含有マトリックスを含むフィルムによって構成させるサグストレ ート上に、パラキシリレンまたはその誘導体の反応性蒸気を真空下で蒸着させ、 該サブストレート上の蒸気を凝縮させることによって疎水性材料から成る層を該 サブストレート上に形成させることを特徴とする請求項1記載のラミネートフィ ルムの製造方法。
  18. 18.(i)遊離の酸基を含むポリマーを塩基、好ましくは水酸化アンモニウム を用いて塩化することによってポリマーの水溶液を調製し、(ii)該水溶液を デンプン含有層の少なくとも一方の表面に薄層状態で付着させ、(iii)溶媒 を蒸発させると共にポリマーから塩基性基を脱離させるのに十分な温度と時間の 条件が得られるように外部から熱を加えることによって該付着層を水不溶性にす る、ことを含む請求項11記載のラミネートフィルムの製造方法。
  19. 19.界面活性剤、乳化ワックス、シリカ、ポリオキシエチレン、ポリアクリル 酸、ポリビニルピロリドン、ポリビニルアルコールおよびこれらの混合物から選 択される添加剤をポリマーの水溶液に添加する請求項18記載の方法。
JP51314291A 1990-08-09 1991-08-01 デンプン含有マトリックスを有する低透過性ラミネートフィルムおよびその製法 Expired - Fee Related JP2961147B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT6763490A IT1242722B (it) 1990-08-09 1990-08-09 Film stratificato a matrice amidacea e di bassa permeabilita' e procedimento per la sua produzione.
IT67634A/90 1990-08-09
PCT/EP1991/001443 WO1992002363A1 (en) 1990-08-09 1991-08-01 A laminated film with a starchy matrix and low permeability and methods for its production

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JPH05505354A true JPH05505354A (ja) 1993-08-12
JP2961147B2 JP2961147B2 (ja) 1999-10-12

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US (1) US5384170A (ja)
EP (1) EP0495950B2 (ja)
JP (1) JP2961147B2 (ja)
KR (1) KR920702289A (ja)
CN (1) CN1058788A (ja)
AT (1) ATE165274T1 (ja)
AU (1) AU650472B2 (ja)
BR (1) BR9105849A (ja)
CA (1) CA2067396C (ja)
CS (1) CS245191A3 (ja)
DE (1) DE69129291T3 (ja)
ES (1) ES2115617T5 (ja)
FI (1) FI921285A0 (ja)
HU (2) HUT61925A (ja)
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DE69129291T2 (de) 1998-11-05
HUT61925A (en) 1993-03-29
BR9105849A (pt) 1992-08-25
ES2115617T3 (es) 1998-07-01
IL99133A0 (en) 1992-07-15
DE69129291D1 (de) 1998-05-28
ES2115617T5 (es) 2002-10-16
FI921285A (fi) 1992-03-25
WO1992002363A1 (en) 1992-02-20
IT1242722B (it) 1994-05-17
EP0495950B2 (en) 2002-04-03
IT9067634A0 (it) 1990-08-09
ZA916266B (en) 1992-04-29
EP0495950A1 (en) 1992-07-29
ATE165274T1 (de) 1998-05-15
EP0495950B1 (en) 1998-04-22
CN1058788A (zh) 1992-02-19
KR920702289A (ko) 1992-09-03
PL291367A1 (en) 1992-03-09
US5384170A (en) 1995-01-24
CS245191A3 (en) 1992-08-12
IT9067634A1 (it) 1992-02-09
DE69129291T3 (de) 2002-08-14
CA2067396A1 (en) 1992-02-10
HU9201192D0 (en) 1992-07-28
TW252130B (ja) 1995-07-21
JP2961147B2 (ja) 1999-10-12
AU8311891A (en) 1992-03-02
CA2067396C (en) 2003-01-14
FI921285A0 (fi) 1992-03-25
TR25254A (tr) 1993-01-01
AU650472B2 (en) 1994-06-23

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