JPH05505354A - デンプン含有マトリックスを有する低透過性ラミネートフィルムおよびその製法 - Google Patents
デンプン含有マトリックスを有する低透過性ラミネートフィルムおよびその製法Info
- Publication number
- JPH05505354A JPH05505354A JP91513142A JP51314291A JPH05505354A JP H05505354 A JPH05505354 A JP H05505354A JP 91513142 A JP91513142 A JP 91513142A JP 51314291 A JP51314291 A JP 51314291A JP H05505354 A JPH05505354 A JP H05505354A
- Authority
- JP
- Japan
- Prior art keywords
- group
- polymer
- laminate film
- ethylene
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005001 laminate film Substances 0.000 title claims description 18
- 229920002472 Starch Polymers 0.000 title claims description 10
- 239000008107 starch Substances 0.000 title claims description 10
- 235000019698 starch Nutrition 0.000 title claims description 10
- 239000011159 matrix material Substances 0.000 title claims 4
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 230000035699 permeability Effects 0.000 title 1
- 239000000463 material Substances 0.000 claims description 9
- 230000002209 hydrophobic effect Effects 0.000 claims description 5
- 235000013305 food Nutrition 0.000 claims description 2
- 238000004806 packaging method and process Methods 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims 14
- 229920001577 copolymer Polymers 0.000 claims 5
- 239000002253 acid Substances 0.000 claims 4
- 229920001038 ethylene copolymer Polymers 0.000 claims 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 4
- -1 loarylalkyl group Chemical group 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 229920002125 Sokalan® Polymers 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims 2
- 229920006226 ethylene-acrylic acid Polymers 0.000 claims 2
- 239000000945 filler Substances 0.000 claims 2
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical group OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims 2
- 239000004310 lactic acid Substances 0.000 claims 2
- 235000014655 lactic acid Nutrition 0.000 claims 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- 229920001059 synthetic polymer Polymers 0.000 claims 2
- 229920001169 thermoplastic Polymers 0.000 claims 2
- 239000004416 thermosoftening plastic Substances 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims 1
- 125000000041 C6-C10 aryl group Chemical group 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 125000004036 acetal group Chemical group 0.000 claims 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000005157 alkyl carboxy group Chemical group 0.000 claims 1
- 125000004103 aminoalkyl group Chemical group 0.000 claims 1
- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 claims 1
- 239000000908 ammonium hydroxide Substances 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000001769 aryl amino group Chemical group 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 125000004181 carboxyalkyl group Chemical group 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 claims 1
- 125000004093 cyano group Chemical group *C#N 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- UZBQIPPOMKBLAS-UHFFFAOYSA-N diethylazanide Chemical compound CC[N-]CC UZBQIPPOMKBLAS-UHFFFAOYSA-N 0.000 claims 1
- 239000008387 emulsifying waxe Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims 1
- BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 230000002550 fecal effect Effects 0.000 claims 1
- 125000001188 haloalkyl group Chemical group 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 238000010030 laminating Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 125000004043 oxo group Chemical group O=* 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 claims 1
- 239000005014 poly(hydroxyalkanoate) Substances 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 229920000903 polyhydroxyalkanoate Polymers 0.000 claims 1
- 239000005076 polymer ester Substances 0.000 claims 1
- 239000002861 polymer material Substances 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000000523 sample Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims 1
- 125000001174 sulfone group Chemical group 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 229920001897 terpolymer Polymers 0.000 claims 1
- 125000000101 thioether group Chemical group 0.000 claims 1
- 125000006839 xylylene group Chemical group 0.000 claims 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/02—Physical, chemical or physicochemical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15203—Properties of the article, e.g. stiffness or absorbency
- A61F13/15252—Properties of the article, e.g. stiffness or absorbency compostable or biodegradable
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
- A61F13/51401—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
- A61F13/51401—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
- A61F13/51405—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material treated or coated, e.g. with moisture repellent agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/02—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/46—Applications of disintegrable, dissolvable or edible materials
- B65D65/466—Bio- or photodegradable packaging materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
- C08L3/02—Starch; Degradation products thereof, e.g. dextrin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/716—Degradable
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/73—Hydrophobic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2317/00—Animal or vegetable based
- B32B2317/20—Starch
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/70—Food packaging
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W90/00—Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
- Y02W90/10—Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31913—Monoolefin polymer
Abstract
Description
Claims (19)
- 1.(i)デンプン含有マトリックスを含み、水中において不溶性であるか、膨 張するに過ぎないポリマー材料から成る少なくとも1つの第一層および(ii) 該第一層に接着する疎水性材料から成る第二層を含むラミネートフィルム。
- 2.ポリマー材料が分解デンプンと熱可塑性合成ポリマーを含有する組成物から 成り、該熱可塑性合成ポリマーが少なくとも1種のエチレン性不飽和モノマーの コポリマーであり、該ポリマーが、ヒドロキシ基、アルコキシ基、カルボキシ基 、カルボキシアルキル基、アルキルカルボキシ基およびアセタール基から成る群 から選択される極性基を少なくとも1個含む探り返し単位を有する請求項1記載 のラミネートフィルム。
- 3.該ポリマーが、ポリビニルアルコール、およびエチレン・プロピレン、イソ プテンおよびスチレンから成る群から選択されるオレフィンとアクリル酸ビニル アルコールもしくはビニルアセテートとのコポリマーから成る群から選択される ポリマーである請求項2記載のラミネートフィルム。
- 4.デンプン含有マトリックスを含むポリマー材料が、分解デンプンおよびエチ レン−ビニルアルコール、ヒドロキシル基の一部がオキソ基もしくはアルキルカ ルボニル基によって置換されたエチレン−ビニルアルコール、エチレン−アクリ ル酸およびエチレン−ビニルアセテートから成る群から選択されるエチレンコポ リマー、エチレン−ビニルアルコール−ビニルアセテートターポリマーまたはこ れらの混合物から構成される請求項1記載のラミネートフィルム。
- 5.エチレンコポリマーが、エチレン成分の含有量が15〜50モル%、好まし くは30〜45モル%であるエチレン−ビニルアルコールである請求項4記載の ラミネートフィルム。
- 6.エチレンコポリマーが、ビニルアセテート成分の含有量が12〜80モル% であるエチレン−ビニルアセテートを含有する請求項2記載のラミネートフィル ム。
- 7.第一層がデンプンおよびエチレンコポリマーを1:4〜4:1の重量比で含 有する請求項1記載のラミネートフィルム。
- 8.第一層を構成するポリマー材料が、高沸点可塑剤を含有し、その含水量が6 重量%(押出し成形後、コンディショニング前の値)を越えない請求項7記載の ラミネートフィルム。
- 9.第二層が、次式(1)で表わされるパラキシリレンモノマーのポリマーまた はコポリマーから形成される請求項1記載のラミネートフィルム: ▲数式、化学式、表等があります▼(I)式中、XはC1〜C6アルキル基、C 6〜C10アリール基、C7〜C18アリールアルキル基、ハロアルキル基、ハ ロアリールアルキル基、アセトキシ基、アミノアルキル基、アリールアミノ基、 シアノ基、アルコキシ基、ヒドロキシ基、ニトロ基、ハロゲン原子、スルフォン 基、スルフォンエステル基、燐含有置換基、スルフィド基、アルキルスルフォキ シド基または水素原子を示し、nは0または1〜4の数を示す。
- 10.バラキシリレンモノマーが、クロロパラキシリレン、ジクロロパラキシリ レン、シアノパラキシリレン、ヨードパラキシリレン、フルオロパラキシリレン 、ヒドロキシメチルパラキシリレン、エチルパラキシリレン、アミノメチルパラ キシリレン、カルボメトキシバラキシリレンおよびこれらの混合物から成る群か ら選択されるモノマーである請求項9記載のラミネートフィルム。
- 11.第二層を形成する疎水性材料が遊離の酸基を有するポリマーである請求項 1記載のラミネートフィルム。
- 12.遊離の酸基を有するポリマーが、エチレン−アクリル酸ポリマーまたはエ チレン−アクリル酸−アルキルアクリレートポリマーである請求項9記載のラミ ネートフィルム。
- 13.第二層を形成する疎水性材料がポリヒドロキシアルカノエートポリマー、 乳酸ホモポリマー、乳酸とグリコール酸もしくはε−カプロラクトンとのコポリ マー、ポリエチレン−ビニルアルコールまたはポリエチレン−ビニルアセテート である請求項1記載のラミネートフィルム。
- 14.第二層が、ポリビニルビロリドン(PVP)もしくはPVPエステルとブ チルアクリレート、ブチルアクリレート/メチルメタクリレート、ジエチルアミ ノメチルメタクリレート、ビニルアセテート、アクリル酸、アクリル酸ポリマー 、アクリル酸エステルまたはアクリル酸ポリマーエステルとのコポリマーを含有 する請求項1記載のラミネートフィルム。
- 15.請求項1記載のラミネートフィルムから製造される糞便用容器。
- 16.請求項1記載のラミネートフィルムを含む食料製品用包装。
- 17.デンプン含有マトリックスを含むフィルムによって構成させるサグストレ ート上に、パラキシリレンまたはその誘導体の反応性蒸気を真空下で蒸着させ、 該サブストレート上の蒸気を凝縮させることによって疎水性材料から成る層を該 サブストレート上に形成させることを特徴とする請求項1記載のラミネートフィ ルムの製造方法。
- 18.(i)遊離の酸基を含むポリマーを塩基、好ましくは水酸化アンモニウム を用いて塩化することによってポリマーの水溶液を調製し、(ii)該水溶液を デンプン含有層の少なくとも一方の表面に薄層状態で付着させ、(iii)溶媒 を蒸発させると共にポリマーから塩基性基を脱離させるのに十分な温度と時間の 条件が得られるように外部から熱を加えることによって該付着層を水不溶性にす る、ことを含む請求項11記載のラミネートフィルムの製造方法。
- 19.界面活性剤、乳化ワックス、シリカ、ポリオキシエチレン、ポリアクリル 酸、ポリビニルピロリドン、ポリビニルアルコールおよびこれらの混合物から選 択される添加剤をポリマーの水溶液に添加する請求項18記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT6763490A IT1242722B (it) | 1990-08-09 | 1990-08-09 | Film stratificato a matrice amidacea e di bassa permeabilita' e procedimento per la sua produzione. |
IT67634A/90 | 1990-08-09 | ||
PCT/EP1991/001443 WO1992002363A1 (en) | 1990-08-09 | 1991-08-01 | A laminated film with a starchy matrix and low permeability and methods for its production |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH05505354A true JPH05505354A (ja) | 1993-08-12 |
JP2961147B2 JP2961147B2 (ja) | 1999-10-12 |
Family
ID=11304082
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP51314291A Expired - Fee Related JP2961147B2 (ja) | 1990-08-09 | 1991-08-01 | デンプン含有マトリックスを有する低透過性ラミネートフィルムおよびその製法 |
Country Status (21)
Country | Link |
---|---|
US (1) | US5384170A (ja) |
EP (1) | EP0495950B2 (ja) |
JP (1) | JP2961147B2 (ja) |
KR (1) | KR920702289A (ja) |
CN (1) | CN1058788A (ja) |
AT (1) | ATE165274T1 (ja) |
AU (1) | AU650472B2 (ja) |
BR (1) | BR9105849A (ja) |
CA (1) | CA2067396C (ja) |
CS (1) | CS245191A3 (ja) |
DE (1) | DE69129291T3 (ja) |
ES (1) | ES2115617T5 (ja) |
FI (1) | FI921285A0 (ja) |
HU (2) | HUT61925A (ja) |
IL (1) | IL99133A0 (ja) |
IT (1) | IT1242722B (ja) |
PL (1) | PL291367A1 (ja) |
TR (1) | TR25254A (ja) |
TW (1) | TW252130B (ja) |
WO (1) | WO1992002363A1 (ja) |
ZA (1) | ZA916266B (ja) |
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-
1990
- 1990-08-09 IT IT6763490A patent/IT1242722B/it active IP Right Grant
-
1991
- 1991-08-01 CA CA 2067396 patent/CA2067396C/en not_active Expired - Lifetime
- 1991-08-01 HU HU9201192A patent/HUT61925A/hu unknown
- 1991-08-01 HU HU119291A patent/HU9201192D0/hu unknown
- 1991-08-01 ES ES91914169T patent/ES2115617T5/es not_active Expired - Lifetime
- 1991-08-01 JP JP51314291A patent/JP2961147B2/ja not_active Expired - Fee Related
- 1991-08-01 BR BR9105849A patent/BR9105849A/pt not_active IP Right Cessation
- 1991-08-01 WO PCT/EP1991/001443 patent/WO1992002363A1/en active IP Right Grant
- 1991-08-01 AU AU83118/91A patent/AU650472B2/en not_active Ceased
- 1991-08-01 KR KR1019920700802A patent/KR920702289A/ko not_active Application Discontinuation
- 1991-08-01 AT AT91914169T patent/ATE165274T1/de not_active IP Right Cessation
- 1991-08-01 EP EP91914169A patent/EP0495950B2/en not_active Expired - Lifetime
- 1991-08-01 DE DE1991629291 patent/DE69129291T3/de not_active Expired - Lifetime
- 1991-08-05 TR TR73491A patent/TR25254A/xx unknown
- 1991-08-07 CS CS912451A patent/CS245191A3/cs unknown
- 1991-08-07 TW TW80106224A patent/TW252130B/zh active
- 1991-08-08 PL PL29136791A patent/PL291367A1/xx unknown
- 1991-08-08 CN CN91105531A patent/CN1058788A/zh active Pending
- 1991-08-08 IL IL99133A patent/IL99133A0/xx unknown
- 1991-08-08 ZA ZA916266A patent/ZA916266B/xx unknown
-
1992
- 1992-03-25 FI FI921285A patent/FI921285A0/fi not_active Application Discontinuation
-
1993
- 1993-06-24 US US08/082,348 patent/US5384170A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69129291T2 (de) | 1998-11-05 |
HUT61925A (en) | 1993-03-29 |
BR9105849A (pt) | 1992-08-25 |
ES2115617T3 (es) | 1998-07-01 |
IL99133A0 (en) | 1992-07-15 |
DE69129291D1 (de) | 1998-05-28 |
ES2115617T5 (es) | 2002-10-16 |
FI921285A (fi) | 1992-03-25 |
WO1992002363A1 (en) | 1992-02-20 |
IT1242722B (it) | 1994-05-17 |
EP0495950B2 (en) | 2002-04-03 |
IT9067634A0 (it) | 1990-08-09 |
ZA916266B (en) | 1992-04-29 |
EP0495950A1 (en) | 1992-07-29 |
ATE165274T1 (de) | 1998-05-15 |
EP0495950B1 (en) | 1998-04-22 |
CN1058788A (zh) | 1992-02-19 |
KR920702289A (ko) | 1992-09-03 |
PL291367A1 (en) | 1992-03-09 |
US5384170A (en) | 1995-01-24 |
CS245191A3 (en) | 1992-08-12 |
IT9067634A1 (it) | 1992-02-09 |
DE69129291T3 (de) | 2002-08-14 |
CA2067396A1 (en) | 1992-02-10 |
HU9201192D0 (en) | 1992-07-28 |
TW252130B (ja) | 1995-07-21 |
JP2961147B2 (ja) | 1999-10-12 |
AU8311891A (en) | 1992-03-02 |
CA2067396C (en) | 2003-01-14 |
FI921285A0 (fi) | 1992-03-25 |
TR25254A (tr) | 1993-01-01 |
AU650472B2 (en) | 1994-06-23 |
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