JPH0535189B2 - - Google Patents
Info
- Publication number
- JPH0535189B2 JPH0535189B2 JP59154162A JP15416284A JPH0535189B2 JP H0535189 B2 JPH0535189 B2 JP H0535189B2 JP 59154162 A JP59154162 A JP 59154162A JP 15416284 A JP15416284 A JP 15416284A JP H0535189 B2 JPH0535189 B2 JP H0535189B2
- Authority
- JP
- Japan
- Prior art keywords
- molding
- molding material
- particularly suitable
- polymer
- encapsulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000642 polymer Polymers 0.000 claims description 149
- 239000012778 molding material Substances 0.000 claims description 112
- 239000000178 monomer Substances 0.000 claims description 79
- 125000003118 aryl group Chemical group 0.000 claims description 73
- 238000005538 encapsulation Methods 0.000 claims description 73
- 238000000465 moulding Methods 0.000 claims description 70
- 238000006116 polymerization reaction Methods 0.000 claims description 56
- 238000001746 injection moulding Methods 0.000 claims description 47
- 229920000728 polyester Polymers 0.000 claims description 46
- 229910010272 inorganic material Inorganic materials 0.000 claims description 41
- 239000011147 inorganic material Substances 0.000 claims description 41
- 239000000155 melt Substances 0.000 claims description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- 238000010438 heat treatment Methods 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 21
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 18
- 238000002347 injection Methods 0.000 claims description 17
- 239000007924 injection Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- -1 acetate ester Chemical class 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 238000012360 testing method Methods 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- XBNGYFFABRKICK-UHFFFAOYSA-N 2,3,4,5,6-pentafluorophenol Chemical compound OC1=C(F)C(F)=C(F)C(F)=C1F XBNGYFFABRKICK-UHFFFAOYSA-N 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 150000001340 alkali metals Chemical class 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachloro-phenol Natural products OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 claims description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 230000003301 hydrolyzing effect Effects 0.000 claims description 5
- 229920003232 aliphatic polyester Polymers 0.000 claims description 4
- 125000003277 amino group Chemical group 0.000 claims description 4
- 150000001735 carboxylic acids Chemical group 0.000 claims description 4
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 229920000343 polyazomethine Polymers 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 150000001491 aromatic compounds Chemical class 0.000 claims 1
- 238000011156 evaluation Methods 0.000 claims 1
- 125000001038 naphthoyl group Chemical group C1(=CC=CC2=CC=CC=C12)C(=O)* 0.000 claims 1
- 238000000034 method Methods 0.000 description 45
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 24
- 239000000047 product Substances 0.000 description 23
- 239000000376 reactant Substances 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- 238000005259 measurement Methods 0.000 description 10
- 229920000106 Liquid crystal polymer Polymers 0.000 description 9
- 125000002843 carboxylic acid group Chemical group 0.000 description 9
- 230000001747 exhibiting effect Effects 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000008188 pellet Substances 0.000 description 7
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 6
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 6
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- 239000005350 fused silica glass Substances 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 230000009931 harmful effect Effects 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- GDBUZIKSJGRBJP-UHFFFAOYSA-N 4-acetoxy benzoic acid Chemical compound CC(=O)OC1=CC=C(C(O)=O)C=C1 GDBUZIKSJGRBJP-UHFFFAOYSA-N 0.000 description 5
- NFTLBCXRDNIJMI-UHFFFAOYSA-N 6-acetyloxynaphthalene-2-carboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(OC(=O)C)=CC=C21 NFTLBCXRDNIJMI-UHFFFAOYSA-N 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 239000004974 Thermotropic liquid crystal Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 239000008393 encapsulating agent Substances 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 238000010128 melt processing Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 4
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 4
- OMNHTTWQSSUZHO-UHFFFAOYSA-N 4-hydroxy-3,5-dimethylbenzoic acid Chemical compound CC1=CC(C(O)=O)=CC(C)=C1O OMNHTTWQSSUZHO-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 238000011049 filling Methods 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 239000004065 semiconductor Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000009966 trimming Methods 0.000 description 4
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 3
- KAUQJMHLAFIZDU-UHFFFAOYSA-N 6-Hydroxy-2-naphthoic acid Chemical compound C1=C(O)C=CC2=CC(C(=O)O)=CC=C21 KAUQJMHLAFIZDU-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000006482 condensation reaction Methods 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000011256 inorganic filler Substances 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 235000011056 potassium acetate Nutrition 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- AKOGNYJNGMLDOA-UHFFFAOYSA-N (4-acetyloxyphenyl) acetate Chemical compound CC(=O)OC1=CC=C(OC(C)=O)C=C1 AKOGNYJNGMLDOA-UHFFFAOYSA-N 0.000 description 2
- XCZKKZXWDBOGPA-UHFFFAOYSA-N 2-phenylbenzene-1,4-diol Chemical compound OC1=CC=C(O)C(C=2C=CC=CC=2)=C1 XCZKKZXWDBOGPA-UHFFFAOYSA-N 0.000 description 2
- AULKDLUOQCUNOK-UHFFFAOYSA-N 3,5-dichloro-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC(Cl)=C(O)C(Cl)=C1 AULKDLUOQCUNOK-UHFFFAOYSA-N 0.000 description 2
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 2
- XMEQDAIDOBVHEK-UHFFFAOYSA-N 3-bromo-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(Br)=C1 XMEQDAIDOBVHEK-UHFFFAOYSA-N 0.000 description 2
- IJFXRHURBJZNAO-UHFFFAOYSA-N 3-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1 IJFXRHURBJZNAO-UHFFFAOYSA-N 0.000 description 2
- LTFHNKUKQYVHDX-UHFFFAOYSA-N 4-hydroxy-3-methylbenzoic acid Chemical compound CC1=CC(C(O)=O)=CC=C1O LTFHNKUKQYVHDX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 235000014676 Phragmites communis Nutrition 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229960004050 aminobenzoic acid Drugs 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229910002026 crystalline silica Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920001279 poly(ester amides) Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009757 thermoplastic moulding Methods 0.000 description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 2
- 238000001721 transfer moulding Methods 0.000 description 2
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- JOLPMPPNHIACPD-ZZXKWVIFSA-N (e)-3-(4-aminophenyl)prop-2-enoic acid Chemical compound NC1=CC=C(\C=C\C(O)=O)C=C1 JOLPMPPNHIACPD-ZZXKWVIFSA-N 0.000 description 1
- BYEAHWXPCBROCE-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropan-2-ol Chemical compound FC(F)(F)C(O)C(F)(F)F BYEAHWXPCBROCE-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- PVRZMTHMPKVOBP-UHFFFAOYSA-N 1-n,4-n-dimethylbenzene-1,4-diamine Chemical compound CNC1=CC=C(NC)C=C1 PVRZMTHMPKVOBP-UHFFFAOYSA-N 0.000 description 1
- MWQVQEFJAIFHFZ-UHFFFAOYSA-N 2,3-dichloro-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(Cl)=C1Cl MWQVQEFJAIFHFZ-UHFFFAOYSA-N 0.000 description 1
- 229940075142 2,5-diaminotoluene Drugs 0.000 description 1
- QTHMEINNGLIDSU-UHFFFAOYSA-N 2,5-dichloro-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC(Cl)=C(O)C=C1Cl QTHMEINNGLIDSU-UHFFFAOYSA-N 0.000 description 1
- WIPYZRZPNMUSER-UHFFFAOYSA-N 2-chloro-4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1Cl WIPYZRZPNMUSER-UHFFFAOYSA-N 0.000 description 1
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 1
- VSZJLXSVGVDPMJ-UHFFFAOYSA-N 2-phenylterephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C=2C=CC=CC=2)=C1 VSZJLXSVGVDPMJ-UHFFFAOYSA-N 0.000 description 1
- XFDUHJPVQKIXHO-UHFFFAOYSA-N 3-aminobenzoic acid Chemical compound NC1=CC=CC(C(O)=O)=C1 XFDUHJPVQKIXHO-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- LQZZZAFQKXTFKH-UHFFFAOYSA-N 4'-aminobiphenyl-4-ol Chemical group C1=CC(N)=CC=C1C1=CC=C(O)C=C1 LQZZZAFQKXTFKH-UHFFFAOYSA-N 0.000 description 1
- ICNFHJVPAJKPHW-UHFFFAOYSA-N 4,4'-Thiodianiline Chemical compound C1=CC(N)=CC=C1SC1=CC=C(N)C=C1 ICNFHJVPAJKPHW-UHFFFAOYSA-N 0.000 description 1
- ZSFKODANZQVHCK-UHFFFAOYSA-N 4-(4-aminophenyl)benzoic acid Chemical group C1=CC(N)=CC=C1C1=CC=C(C(O)=O)C=C1 ZSFKODANZQVHCK-UHFFFAOYSA-N 0.000 description 1
- PSHPCZGANRRQDN-UHFFFAOYSA-N 4-(4-aminophenyl)sulfonylphenol Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 PSHPCZGANRRQDN-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- JTGCXYYDAVPSFD-UHFFFAOYSA-N 4-(4-hydroxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(O)C=C1 JTGCXYYDAVPSFD-UHFFFAOYSA-N 0.000 description 1
- UHNUHZHQLCGZDA-UHFFFAOYSA-N 4-[2-(4-aminophenyl)ethyl]aniline Chemical compound C1=CC(N)=CC=C1CCC1=CC=C(N)C=C1 UHNUHZHQLCGZDA-UHFFFAOYSA-N 0.000 description 1
- MBDUKNCPOPMRJQ-UHFFFAOYSA-N 4-amino-2-chlorobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C(Cl)=C1 MBDUKNCPOPMRJQ-UHFFFAOYSA-N 0.000 description 1
- ZYZQSCWSPFLAFM-UHFFFAOYSA-N 4-amino-2-chlorophenol Chemical compound NC1=CC=C(O)C(Cl)=C1 ZYZQSCWSPFLAFM-UHFFFAOYSA-N 0.000 description 1
- NHFKECPTBZZFBC-UHFFFAOYSA-N 4-amino-3-methylbenzoic acid Chemical compound CC1=CC(C(O)=O)=CC=C1N NHFKECPTBZZFBC-UHFFFAOYSA-N 0.000 description 1
- ABJQKDJOYSQVFX-UHFFFAOYSA-N 4-aminonaphthalen-1-ol Chemical compound C1=CC=C2C(N)=CC=C(O)C2=C1 ABJQKDJOYSQVFX-UHFFFAOYSA-N 0.000 description 1
- GTCAZWRERBLCFJ-UHFFFAOYSA-N 4-aminonaphthalene-1-carboxylic acid Chemical compound C1=CC=C2C(N)=CC=C(C(O)=O)C2=C1 GTCAZWRERBLCFJ-UHFFFAOYSA-N 0.000 description 1
- FFUMDYCIOSWRLV-UHFFFAOYSA-N 4-hydroxy-2,6-dimethylbenzoic acid Chemical compound CC1=CC(O)=CC(C)=C1C(O)=O FFUMDYCIOSWRLV-UHFFFAOYSA-N 0.000 description 1
- IPXDGHZTUBSPSG-UHFFFAOYSA-N 4-hydroxy-2-phenylbenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1C1=CC=CC=C1 IPXDGHZTUBSPSG-UHFFFAOYSA-N 0.000 description 1
- LPADJMFUBXMZNL-UHFFFAOYSA-N 4-hydroxy-3-phenylbenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(C=2C=CC=CC=2)=C1 LPADJMFUBXMZNL-UHFFFAOYSA-N 0.000 description 1
- QGNGOGOOPUYKMC-UHFFFAOYSA-N 4-hydroxy-6-methylaniline Chemical compound CC1=CC(O)=CC=C1N QGNGOGOOPUYKMC-UHFFFAOYSA-N 0.000 description 1
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 1
- VVYWUQOTMZEJRJ-UHFFFAOYSA-N 4-n-methylbenzene-1,4-diamine Chemical compound CNC1=CC=C(N)C=C1 VVYWUQOTMZEJRJ-UHFFFAOYSA-N 0.000 description 1
- MIBYFOLNIIUGNA-UHFFFAOYSA-N 5-chloro-6-hydroxynaphthalene-2-carboxylic acid Chemical compound ClC1=C(O)C=CC2=CC(C(=O)O)=CC=C21 MIBYFOLNIIUGNA-UHFFFAOYSA-N 0.000 description 1
- RHXQHKDRWDVLBY-UHFFFAOYSA-N 6-hydroxy-5-methoxynaphthalene-2-carboxylic acid Chemical compound OC(=O)C1=CC=C2C(OC)=C(O)C=CC2=C1 RHXQHKDRWDVLBY-UHFFFAOYSA-N 0.000 description 1
- XKFNZRZICQABOD-UHFFFAOYSA-N 6-hydroxy-5-methylnaphthalene-2-carboxylic acid Chemical compound OC(=O)C1=CC=C2C(C)=C(O)C=CC2=C1 XKFNZRZICQABOD-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Chemical class 0.000 description 1
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 1
- ZVIDMSBTYRSMAR-UHFFFAOYSA-N N-Methyl-4-aminobenzoate Chemical compound CNC1=CC=C(C(O)=O)C=C1 ZVIDMSBTYRSMAR-UHFFFAOYSA-N 0.000 description 1
- 244000089486 Phragmites australis subsp australis Species 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RQMBBMQDXFZFCC-UHFFFAOYSA-N [4-(4-acetyloxyphenyl)phenyl] acetate Chemical compound C1=CC(OC(=O)C)=CC=C1C1=CC=C(OC(C)=O)C=C1 RQMBBMQDXFZFCC-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical compound C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 125000005026 carboxyaryl group Chemical group 0.000 description 1
- AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- HPGJOUYGWKFYQW-UHFFFAOYSA-N diphenyl benzene-1,4-dicarboxylate Chemical compound C=1C=C(C(=O)OC=2C=CC=CC=2)C=CC=1C(=O)OC1=CC=CC=C1 HPGJOUYGWKFYQW-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229920006332 epoxy adhesive Polymers 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 239000006023 eutectic alloy Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N hydroquinone methyl ether Natural products COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000012120 mounting media Substances 0.000 description 1
- OLAKSHDLGIUUET-UHFFFAOYSA-N n-anilinosulfanylaniline Chemical compound C=1C=CC=CC=1NSNC1=CC=CC=C1 OLAKSHDLGIUUET-UHFFFAOYSA-N 0.000 description 1
- ABMFBCRYHDZLRD-UHFFFAOYSA-N naphthalene-1,4-dicarboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1 ABMFBCRYHDZLRD-UHFFFAOYSA-N 0.000 description 1
- MNZMMCVIXORAQL-UHFFFAOYSA-N naphthalene-2,6-diol Chemical compound C1=C(O)C=CC2=CC(O)=CC=C21 MNZMMCVIXORAQL-UHFFFAOYSA-N 0.000 description 1
- WPUMVKJOWWJPRK-UHFFFAOYSA-N naphthalene-2,7-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 WPUMVKJOWWJPRK-UHFFFAOYSA-N 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000013034 phenoxy resin Substances 0.000 description 1
- 229920006287 phenoxy resin Polymers 0.000 description 1
- GJLNWLVPAHNBQN-UHFFFAOYSA-N phenyl 4-hydroxybenzoate Chemical compound C1=CC(O)=CC=C1C(=O)OC1=CC=CC=C1 GJLNWLVPAHNBQN-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- WKOLLVMJNQIZCI-UHFFFAOYSA-N vanillic acid Chemical compound COC1=CC(C(O)=O)=CC=C1O WKOLLVMJNQIZCI-UHFFFAOYSA-N 0.000 description 1
- TUUBOHWZSQXCSW-UHFFFAOYSA-N vanillic acid Natural products COC1=CC(O)=CC(C(O)=O)=C1 TUUBOHWZSQXCSW-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
Landscapes
- Injection Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Structures Or Materials For Encapsulating Or Coating Semiconductor Devices Or Solid State Devices (AREA)
- Organic Insulating Materials (AREA)
Description
ïŒçºæã®åéïŒ
æ¬çºæã¯ãäºã圢æããé»åéšåãéåãã€ã
ãã€å ã«çœ®ããŠããå°åºæ圢ã«ããæ圢ææãå°
å ¥ãããé»åéšåã®æ¯èŒçè¿ éãã€ãã€ãã®ãªã
äžééæ§å°å ¥æ圢çšãšããŠç¹ã«é©ããæ¹è¯ããã
æ圢ææããããå©çšããå°å ¥æ圢æ³ããªãã³ã«
ããã«ããåŸãããå°å ¥è£œåã«é¢ããã ïŒåŸæ¥ã®æè¡ïŒ ä¿è·çšã®åææš¹èææã®å éšã«é»åéšåãå°å ¥
æ圢ããããã®å ·äœçãªæè¡ã¯ãåœæ¥è ã«ã¯åšç¥
ã§ãããåºãå®æœãããŠããïŒäŸãPlastics
Design Forum IssueïŒ1981幎ïŒæïŒæ²èŒã®ãå
å°äœããã€ã¹ã®å°å ¥æ圢ããšé¡ããè«æãåç §ïŒã åŸæ¥ãå°å ¥æ圢ã¯ãäžè¬ã«ç±ç¡¬åæ§æš¹èææã
çšããŠããã©ã³ã¹ãã¢ãŒæ圢ãšäžè¬ã«åŒã°ããå°
åºæ圢ã®ïŒåœ¢æ ã«ããå®æœããŠãããäŸãã°ããš
ããã·æš¹èïŒäŸãããã©ãã¯ç¡¬ååãšããã·æš¹è
ç³»ïŒãäžè¬ã«ãã®ç®çã«çšããŠããããŸããäžé£œ
åããªãšã¹ãã«ããã¹âã€ããããªããŒçã®ç±ç¡¬
åæ§æš¹èãå°å ¥æ圢ææãšããŠäœ¿çšããããšãæ
æ¡ãããŠããïŒäŸãç±³åœç¹èš±ç¬¬4327369ïŒ
4374080ïŒããã³4390596å·åç §ïŒããããç±ç¡¬å
æ§ææã¯ã䜿çšåã®å·åŽãå¿ èŠãšããæ圢æã«ã¯
æ¯èŒçé·ããµã€ã¯ã«æéãå¿ èŠãšããåŸåãã
ããæ圢åŸã«ã¯å°å ¥æ圢çšæš¹èã®ææã®ç¡¬åãå®
äºãããŸã§å ç±åšå ã§é«æž©ã«ãããŠé·æé硬åã
ããªããã°ãªããªãããšãå€ããæªç¡¬åã®ç±ç¡¬å
æ§æš¹èã®ç²åºŠã¯ãæš¹èã®å ç±ããŠç¡¬åãé²ãã«ã€
ããŠå¢å ããŠããã®ã§ãäžæŠå ç±ãå§ããããæª
硬åææã¯æ¯èŒçéã䜿çšããªããã°ãªããªãã
ãã®ãããªææã§ã¯ãã¹ã¯ã©ããã®å埪ç°ã¯äžå¯
èœã§ããããŸãã倩ç¶ã®æš¹èçµåå€ãæããå°å ¥
æ圢ææã¯ãã°ãã®åœ¢æãšéåãã€ããã€è¡šé¢ãž
ã®ä»çã®åŸåãäžè¬ã«ç€ºãããã®ããéåãã€ã
ãã€ãæå·ããå¯èœæ§ããããæ圢äœæ¥äžã«çç·Ž
äœæ¥å¡ã«ããååãªè£ä¿®ã®èæ ®ãå¿ èŠã«ãªããã
ã®ç¹ã§å°å ¥æ圢工çšã®å®å šãªèªååã劚ããããŠ
ããã å·¥æ¥èŠæš¡ã§çšããããŠã¯ããªãããããçš®ã®ç±
å¯å¡æ§æš¹èããããŸã§é»åéšåã®å°å ¥æ圢çšãšã
ãŠææ¡ãããŠãããäŸãã°ãç±³åœç¹èš±ç¬¬4327369
å·ã®ç¬¬ïŒæ¬18ã23è¡ç®ã«ã¯ãããªå¡©åããã«ïŒäœ
å¯åºŠããªãšãã¬ã³ãé«å¯åºŠããªãšãã¬ã³ãããªã
ããã¬ã³ã®ãããªããªãªã¬ãã€ã³ïŒããã³ããªã¹
ãã¬ã³ãäŸç€ºãããŠãããããã«ãç±³åœç¹èš±ç¬¬
4370292å·ã«ã¯ãããšããã·æš¹èãå å«ããããª
ããšãã¬ã³ã¹ã«ãã€ãçµæç©ãå°å ¥æ圢çšãšããŠ
ææ¡ãããŠããã å°å ¥æ圢暹èå ã«ãã·ãªã«ãŸãã¯ã¢ã«ããã®ã
ãã«ç¹ã«æ圢åŸã®å°å ¥æ圢ææã®ç±äŒå°çãå¢å
ãããããããã®äœç±èšåŒµçãäœäžãããç²åç¶
å å¡«æãå«æãããããšã¯ãåŸæ¥ããäžè¬ã«è¡ã
ããŠããããããããããç²åç¶å å¡«æã¯ãç¹ã«
é«æ¿åºŠã§ååšãããå Žåã«ãæ圢æã®çµæç©ã®ç²
床ãéåžžã«å€åïŒå³ã¡ãå¢å ïŒããããç²åºŠãé«
ããªãããããšãæ圢ææãæµå°ãããŠéåãå
åã«æºããããšãå°é£ãšãªããæ圢åã«ãã€ãã
ããã°ãå°å ¥æ圢ã¯å€±è²©ãšããããç²çš ãªæ圢æ
æãå§åãé«ããŠæµåããããšãå°å ¥æ圢ãåã
ã粟å¯ãªé»åéšåãæãªãå Žåãããããã®ãã
ãªæå·ããç±³åœç¹èš±ç¬¬4374080å·ã§ã¯ãã¯ã€ã€ã¹
ãŠã€ãŒãããšåŒãã§ããããã®ãããªåŒã€ãããŸ
ãã¯æã¿ã«ãã€ãŠããã³ãã€ã³ã°æ¥åéšãè£ãã
ããæ害ãªã·ãšãŒããçºçããŠãé»æ°åè·¯ãžã®é
é ·ãªè² è·ããã®ç Žå£ãèµ·ããããšãããããŸãã
ç±å¯å¡æ§å°å ¥å€ã®ååéã®äœäžã«ããæ圢ææãš
ããŠå¿ èŠãªç²åºŠãåŸãããšãããšãåŸãããæ圢
åã®æ©æ¢°çæ§è³ªïŒäŸãèæ§ïŒãäžååãšãªããã
ãªããŒææãå€ãã®éåå·¥çšã«åºæã®å€Ÿéç©
ïŒäŸãæ°Žæœåºæ§ããã²ã³ãŸãã¯æ°Žæœåºæ§ã®ã€ãªã³
æ§ç©è³ªãå«æããå Žåããã®å€Ÿéç©ãå°å ¥ããã
é»åéšåã®äŸµé£ããã³ïŒãŸãã¯ãã®åäœãžã®æªåœ±
é¿ãçããããšãããããŸããããªããŒææãæ
圢æäœäžãŸãã¯ãã®åŸã®å°å ¥æ圢ããé»åéšåã®
䜿çšäžã«äœããã®çç±ã§ïŒäŸãçž®éååå¿ã«ã
ãïŒå®è³ªçã«ã¬ã¹ç¶å¯çç©ãçºçããåŸåããã
ãšãé倧ãªãã€ãã®çºçããã³å°å ¥æ圢å€çµæç©
ã®æå·ã«ã€ãªãããäžèšæ¬ ç¹ã®ä»ã«ããå€ãã®ç±
å¯å¡æ§æš¹èã¯ãé»åéšåãæ®éã«çŽé¢ãããããª
é«æž©ã§é·æé確å®ã«æ©èœããããšã¯ã§ããããã
ã³ïŒãŸãã¯çã«ããããšçããããããã®ä¿è·ç¹
æ§ã¯ãã®ç¹ã§æžããã ïŒçºæã®ç®çïŒ æ¬çºæã®ç®çã¯ãé»åéšåã®äžééæ§å°å ¥æ圢
ã«ç¹ã«é©ãããæ¹è¯ãããæ圢ææãæäŸããã
ãšã§ããã æ¬çºæã®ç®çã¯ãã«ãããŸãã¯ããŠã¢ã«ã€ã³ã©
ã€ã³åéç©åè·¯ã®ãããªç²Ÿå¯é»åéšåã®å°å ¥æ圢
ã«ç¹ã«é©ãããæ¹è¯ãããç±å¯å¡æ§æ圢ææãæ
äŸããããšã§ããã æ¬çºæã®ç®çã¯ã粟å¯é»åéšåãæãªããã«å°
å ¥æ圢ããããšãã§ããå®è³ªéã®ç²åç¶ç¡æ©ææ
ãå«æããæ¹è¯ãããç±å¯å¡æ§æ圢ææãæäŸã
ãããšã§ãããããã«ããéåžžã«ããããæ©æ¢°
çãç±çãååŠçããã³é»æ°çæ§è³ªã瀺ããäžå©
ãªç°å¢æ¡ä»¶ã«çŽé¢ããå Žåã§ãé·æéã«äºã€ãŠå
åãªæ©èœãçºæ®ã§ããå°å ¥æ圢ãããæçµè£œåã
圢æãããã æ¬çºæã®ç®çã¯ãåŸæ¥äžè¬ã«è¡ãããŠããæé
ã®ãããããªããŒç¡¬åå·¥çšãå¿ èŠãšããã«å®æœã§
ãããé»åéšåã®æ¹è¯ãããå°å ¥æ圢æ¹æ³ãæäŸ
ããããšã§ããã æ¬çºæã®å¥ã®ç®çã¯ãæ¹è¯ãããå°å ¥æ圢é»å
éšåãæäŸããããšã§ããã ããã«æ¬çºæã®ç®çã¯ãå å¡«ãããå°å ¥æ圢çš
æš¹èããæ°Žããã³çŽ«å€ç·ã«å¯ŸããŠå®è³ªçã«äžéé
æ§ã§ãããå®è³ªçã«ãã€ãããªããããããæ©æ¢°
çæ§è³ªïŒäŸãæ©æ¢°ç匷床ïŒãäœç±èšåŒµçããã³ç±
äŒå°çã瀺ããæ°Žæœåºæ§ã¢ã«ã«ãªéå±å«æéã
50ppmæªæºãæ°Žæœåºæ§ããã²ã³å«æéã100ppm
æªæºã§ãããULâ94è©Šéšã§ïŒ¶âã®ççŒè©äŸ¡ã
瀺ããé·æ䜿çšãå¯èœã§ãããæ¹è¯ãããå°å ¥æ
圢é»åéšåãæäŸããããšã§ããã åè¿°ããã³ä»ã®ç®çããªãã³ã«æ¬çºæã®ç¯å²ã
åçããã³çšéã¯ã以äžã®èšèŒããåœæ¥è ã«ã¯æ
ããã«ãªããã ïŒçºæã®æ§æïŒ æ¬çºæã¯ã (a) ééå¹³åååéãçŽ4000ã25000ã§ãå ç±ã«
ãããã以äžã®é£éæé·ãå®è³ªçã«äžå¯èœãªã
ç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªã
ãŒãããã³ (b) æå(a)ã®äœç±èšåŒµçãæžå°ããããšå ±ã«ãã
ã®ç±äŒå°çãå¢å ãããããšã®ã§ãããæ圢æ
æã®å šééã«åºã¥ããŠçŽ40ã80ééïŒ ã®éã®ã
æå(a)äžã«å®è³ªçã«åäžã«åæ£ããç²åç¶ç¡æ©
ææ ãããªããå°åºæ圢ã«ããé»åéšåã®äžééæ§å°
å ¥æ圢ã«ç¹ã«é©ããæ圢ææã§ããã æ¬çºæã¯ãŸã (1) å°å ¥ãã¹ãé»åéšåãéåãã€ããã€å ã«å ¥
ãã (2) é»åéšåãå ¥ããéåãã€ããã€ã«ã (a) ééå¹³åååéãçŽ4000ã25000ã§ãå ç±
ã«ãããã以äžã®é£éæé·ãå®è³ªçã«äžå¯èœ
ãªãç°æ¹æ§æº¶èçžã圢æããã溶èãã溶è
å å·¥æ§ããªããŒãããã³ (b) æå(a)ã®äœç±èšåŒµçãæžå°ããããšå ±ã«ã
ãã®ç±äŒå°çãå¢å ãããããšã®ã§ãããæ
圢ææã®å šééã«åºã¥ããŠçŽ40ã80ééïŒ ã®
éã®ãæå(a)äžã«å®è³ªçã«åäžã«åæ£ããç²
åç¶ç¡æ©ææ ãããªãæ圢ææãé«æž©ã§å°åºããŠããã®ãã€
ããã€ãå®å šã«æºããã (3) éåãã€ããã€ã®å 容ç©ãå·åŽããŠåèšæ圢
ææãåºåãããåèšé»åéšåã®åšå²ã«äžéé
æ§ããã±ãŒãžã圢æãã (4) åŸãããå°å ¥æ圢é»åéšåãåèšéåãã€ã
ãã€ããåãåºãã ãšããå·¥çšãããªããé»åéšåã®æ¹è¯ãããäžé
éæ§å°å ¥æ圢æ¹æ³ã§ããã æ¬çºæã¯ããã« (a) ééå¹³åååéãçŽ4000ã25000ã§ãå ç±ã«
ãããã以äžã®é£éæé·ãå®è³ªçã«äžå¯èœãªã
ç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªã
ãŒãããã³ (b) æå(a)ã®äœç±èšåŒµçãæžå°ããããšå ±ã«ãã
ã®ç±äŒå°çãå¢å ãããããšã®ã§ãããçµæç©
ã®å šééã«åºã¥ããŠçŽ40ã80ééïŒ ã®éã®ãæ
å(a)äžã«å®è³ªçã«åäžã«åæ£ããç²åç¶ç¡æ©æ
æã ãããªãå°å ¥å€çµæç©ã®å éšã«é»åéšåãäžéé
æ§ã«å°å ¥æ圢ããŠãªãæ¹è¯ãããå°å ¥è£œåã§ã
ãã å€æ§ãªé»åéšåããæ¬çºæã«åŸã€ãŠãäžééæ§
ã§å®è³ªçã«ãã€ãã®ãªãããã±ãŒãžå ã«æå¹ã«å°
å ¥æ圢ããããšãã§ããããããé»åéšåã¯ãæ¯
èŒçåçŽãªé»åããã€ã¹ã§ããæ¯èŒçè€éãªãã®
ã§ãããããã倧ããªé»åè£ çœ®ã«äœ¿çšããçŽ åãš
èŠãªããããã®ã§ããããå°å ¥æ圢ããããšã®ã§
ããé»åéšåã®ä»£è¡šäŸã¯ããã©ã³ãžã¹ã¿ãã³ã³ã
ã³ãµãç¶é»åšããã€ãªãŒããæµæåšãæµæåšã®å
路網ãéç©åè·¯çã§ããã奜é©æ æ§ã§ã¯ãé»åéš
åã¯ç²Ÿå¯ãªåå°äœããã€ã¹ã§ããããã€ããŒã©ã
é»çå¹æããã€ã¹çã§ãããå°å ¥æ圢ããããšã®
ã§ããéç©åè·¯ã«ã¯ãããããªåœ¢æ ã®ãã®ããã
ããéåžžãããæ¯æããŠããæ¯èŒçå°ããªã·ãªã³
ã³ãã®ä»ã®åå°äœãããã¯ãæäœïŒåãã100åã
ãŸãã¯ãã以äžã®å€çãšã®æ¥ç¹ãæã¡ãããåœè©²
åéã§ã¯åšç¥ã®ããã«ã代衚çãªéç©åè·¯ããã±
ãŒãžã¯ãé 補ã®ãŸãã¯ããåéã®ãããªä»ã®éå±
ããã€ãããé 補ã®åãçŽ0.01ã€ã³ãïŒ0.25mmïŒ
ã®èãéå±ãã¬ãŒã äžã«è£œäœããããã¯ãã 被èŠ
ãããªãŒããã¬ãŒã ãšããããšãã§ããããã®å Ž
åã«ã¯ãå°å ¥æ圢åŸã«çªåºãŠããé»æ°æ¥ç¹ãã¯ã
ã ä»ããã€ããããå·¥çšãå¿ èŠãªããªããéç©å
è·¯ãã€ãŸãã¯ãããã¯ãªãŒããã¬ãŒã ã®ããã«éš
ã«æ¥åããããã®ãã€ãŸãã¯ãããã®ãªãŒããã¬
ãŒã ãžã®é»æ°çæ¥ç¶ã¯ãçŽåŸçŽ0.001ã€ã³ã
ïŒ0.025mmïŒä»¥äžã®æ®éã¯éã®çŽ°ãã¯ã€ã€ã§è¡ãã
ãã®ã¯ã€ã€ã¯ãã¹ããã溶æ¥ãŸãã¯ä»ã®æ¹æ³ã«ã
ã€ãŠãæ®ééåžžã«èãã¢ã«ãããŠã èãããªãé
ç©åè·¯ãã€ãŸãã¯ãããäžã®æ¥ç¹ããªãã¡ãã³ã
ã€ã³ã°ãããããããªãŒããã¬ãŒã äžã®ã«ã³ãã¬
ããŒã¢ãŒã ã®æ«ç«¯ãæ¥ç¶ããŠããããããã€ãŠã
ç¹ã«å¥œé©ãªæ æ§ã§ã¯ãé»åããã€ã¹ã¯ãå°å ¥æ圢
éšåã®å€åŽã«çªãåºãå€æ°ã®ãªãŒããæããå¹³æ¿
ç¶ã®ææãå å·¥ãªãŒããã¬ãŒã äžã«çµç«ãŠãã«ã
ããŸãã¯ããŠã¢ã«ã€ã³ã©ã€ã³åéç©åè·¯ããã€ã¹
ã§ãããäŸãã°ã40ãã³ã®ãªãŒããã¬ãŒã ãå°å ¥
æ圢ãããã æ¬çºæã®æ圢ææã®ç¬¬ïŒã®å¿ é æåã¯ãééå¹³
åååéãçŽ4000ã25000ãšæ¯èŒçäœãããã®æº¶
èå 工枩床ã§å ç±ããŠããã以äžã®é£éæé·ãå®
質çäžå¯èœãªã溶èå å·¥æ§ãµãŒã¢ããããã¯æ¶²æ¶
æ§ããªããŒã§ããã ããªããŒã®æè¡åéã§ã¯å ¬ç¥ã®ããã«ããµãŒã¢
ããããã¯æ¶²æ¶æ§ããªããŒã¯ã溶èç¶æ ã«ãããŠ
å åŠçç°æ¹æ§ã瀺ãããã®ããªããŒã¡ã«ãã®ç°æ¹
æ§ã¯ãçŽäº€åå åãå©çšããæ £çšã®åå æè¡ã«ã
ã確èªã§ãããããå ·äœçã«ã¯ã溶èçžã®ç°æ¹æ§
ãŸãã¯èŠåæ§ã®ç¢ºèªã¯ãã©ã€ãïŒLeitzïŒåå é¡
埮é¡ãçšããŠã©ã€ããããã¹ããŒãžã«èŒããè©Šæ
ãçªçŽ é°å²æ°äžã«40åã®åçã§èŠ³å¯ããããšã«ã
ãè¡ãã®ã奜éœåã§ãããè©Šæã匷å¶çã«æµåã
ãããšééå éã¯å€åãããããã®çš®ã®è©Šæã¯ã
ãšãéæ¢ç¶æ ã§ãã€ãŠãå åŠçã«ç°æ¹æ§ã瀺ãã
ããã«å¯ŸããŠãå žåçãªæº¶èå å·¥æ§ããªããŒã¯ã
éæ¢æ¡ä»¶ã§ã®æ€æ»ã§ãå®è³ªççšåºŠã«å ãééãã
ãããšã¯ãªããæ¬è³ªçã«çæ¹æ§ã§ããã æ¬çºæã§çšããã®ã«é©ãããµãŒã¢ããããã¯æ¶²
æ¶æ§ããªããŒã®ä»£è¡šçãªçš®é¡ã«ã¯ãå šè³éŠæããª
ãšã¹ãã«ãè³éŠæâèèªæããªãšã¹ãã«ãå šè³éŠ
æããªïŒãšã¹ãã«âã¢ããïŒãè³éŠæâèèªæã
ãªïŒãšã¹ãã«âã¢ããïŒãè³éŠæããªã¢ãŸã¡ãã³ã
è³éŠæããªãšã¹ãã«âã«ãŒãããŒããããã³ãã
ãã®æ··åç©ãããã奜é©æ æ§ã§ã¯ããµãŒã¢ããã
ãã¯æ¶²æ¶æ§ããªãšã¹ãã«ã¯ãå šè³éŠæããªãšã¹ã
ã«ããŸãã¯å šè³éŠæããªïŒãšã¹ãã«âã¢ããïŒã§
ãããããªããŒé£éå ã«ååšãããã¹ãŠã®æåã
å°ãªããšãïŒã€ã®è³éŠç°ãä»äžãããã®ã§ããå Ž
åããã®ããªããŒã¯å šè³éŠæã§ãããšèŠãªãã
ãããŸãããµãŒã¢ããããã¯æ¶²æ¶æ§ããªããŒã¯ã
ããã¿ã¬ã³ç³»æåãäŸãã°ãïŒâãªãã·âïŒâã
ããã€ã«æåãïŒïŒïŒâãžãªãã·ããã¿ã¬ã³æ
åããŸãã¯ïŒïŒïŒâãžã«ã«ããã·ããã¿ã¬ã³æå
ãçŽ10ã¢ã«ïŒ 以äžã®éã§å«æããã®ã奜ãŸããã
ãµãŒã¢ããããã¯æ¶²æ¶æ§ããªããŒã«å«æãããã®
ã«ç¹ã«å¥œé©ãªããã¿ã¬ã³ç³»æåã¯ãçŽ10ã¢ã«ïŒ 以
äžã®éã®ïŒâãªãã·âïŒâãããã€ã«æåã§ã
ãã ãµãŒã¢ããããã¯æ¶²æ¶æ§ã瀺ã代衚çãªå šè³éŠ
æããªãšã¹ãã«ãšããŠã¯ãäžèšç±³åœç¹èš±ã«é瀺ã®
ãã®ãããïŒ3991013ïŒ3991014ïŒ4066620ïŒ
4067852ïŒ4075262ïŒ4083829ïŒ4093959ïŒ
4118372ïŒ4130545ïŒ4146702ïŒ4153779ïŒ
4156070ïŒ4156365ïŒ4161470ïŒ4169933ïŒ
4181792ïŒ4183895ïŒ4184996ïŒ4188476ïŒ
4201856ïŒ4219461ïŒ4224433ïŒ4226970ïŒ
4230817ïŒ4232143ïŒ4232144ïŒ4238598ïŒ
4238599ïŒ4238600ïŒ4242496ïŒ4245082ïŒ
4245084ïŒ4247514ïŒ4256624ïŒ4265802ïŒ
4267304ïŒ4269965ïŒ4279803ïŒ4294955ïŒ
4299756ïŒ4318841ïŒ4335232ïŒ4337190ïŒ
4337191ïŒ4347349ïŒ4355134ïŒ4359569ïŒ
4360658ïŒ4370466ïŒ4374228ïŒ4374261ïŒ
4375530ïŒããã³4377681ã ãµãŒã¢ããããã¯æ¶²æ¶æ§ã瀺ã代衚çãªè³éŠæ
âèèªæããªãšã¹ãã«ã¯ãW.J.JacksonnïŒJr.ïŒ
H.F.Kuhfussããã³T.F.GrayïŒJr.ããèªå·±åŒ·åç±
å¯å¡æ§ããªãšã¹ãã«X7Gâããç±³åœãã©ã¹ãã
ã¯å·¥æ¥äŒã匷åãã©ã¹ããã¯ïŒè€åæéšäŒã第30
å幎次æè¡äŒè°ïŒ1975ïŒãã»ã¯ã·ãšã³17âãã
ãŒãžïŒãïŒã«é瀺ãããŠãããããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããšããããã·å®æ¯éŠé žãšã®ã³ããªããŒ
ã§ããããã®ãããªã³ããªããŒã¯ããã«æ¬¡ã®æç®
ã«ãé瀺ãããŠããïŒW.J.JacksonnïŒJr.ïŒãã
ã³H.F.Kuhfussãã液æ¶ããªããŒïŒI.pâãããã
ã·å®æ¯éŠé žã³ããªããŒã®è£œé ãšæ§è³ªããJournal
of Polymer ScienceïŒPolymer Chemistry
EditionïŒVol.14ïŒpp.2043â58ïŒ1976ïŒãããã«ã
æ¬åºé¡äººã«è²æž¡ãããç±³åœç¹èš±ç¬¬4318842ããã³
4355133å·ãåç §ã§ããã ãµãŒã¢ããããã¯æ¶²æ¶ç¹æ§ã瀺ã代衚çãªå šè³
éŠæããã³è³éŠæâèèªæããªïŒãšã¹ãã«âã¢ã
ãïŒã¯ãç±³åœç¹èš±ç¬¬4272625ïŒ4330457ïŒ
4339375ïŒ4341688ïŒ4351917ïŒ4351918ããã³
4355132å·ã«é瀺ãããŠããã ãµãŒã¢ããããã¯æ¶²æ¶ç¹æ§ã瀺ã代衚çãªè³éŠ
æããªã¢ãŸã¡ãã³ã¯ãç±³åœç¹èš±ç¬¬4048148ããã³
4122070å·ã«é瀺ãããŠããããã®ãããªããªã
ãŒã®å ·äœäŸãšããŠã¯ãããªïŒãããªãâïŒâã¡ã
ã«âïŒïŒïŒâããšãã¬ã³ãããªããšããªãžã³â
ïŒïŒïŒâããšãã¬ã³ãšããªãžã³ïŒïŒããªïŒãããª
ãâïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãããªãã¡
ããªãžã³âïŒïŒïŒâããšãã¬ã³ã¡ããªãžã³ïŒïŒã
ãã³ããªïŒãããªãâïŒâã¯ããâïŒïŒïŒâããš
ãã¬ã³ãããªãã¡ããªãžã³âïŒïŒïŒâããšãã¬ã³
ã¡ããªãžã³ïŒãæããããã ãµãŒã¢ããããã¯æ¶²æ¶ç¹æ§ã瀺ã代衚çãªè³éŠ
æããªãšã¹ãã«âã«ãŒãããŒãã¯ç±³åœç¹èš±ç¬¬
4107143ïŒ4284757ïŒããã³4371660å·ã«é瀺ãã
ãŠããã æ¬çºæã§çšããç°æ¹æ§ã¡ã«ã圢ææ§ããªããŒ
ã¯ãç°æ¹æ§æº¶èçžã圢æã§ãããæãã¯ã§ããªã
ä»ã®ïŒçš®ä»¥äžã®æº¶èå å·¥æ§ããªããŒãšå Žåã«ãã
ãã¬ã³ãããŠãããããäœããåŸããããã¬ã³ã
ãé©åœãªæº¶èç²åºŠã瀺ãæèŠã®ç°æ¹æ§æº¶èçžã圢
æããããšãã§ããããšãæ¡ä»¶ã§ããããµãŒã¢ã
ãããã¯æ¶²æ¶ç¹æ§ã瀺ã代衚çãªããªããŒãã¬ã³
ãã¯ãæ¬åºé¡äººã«è²æž¡ãããç±³åœç¹èš±ç¬¬4267289
ããã³4276397å·ãªãã³ã«ç±³åœç¹èš±åºé¡ç¬¬158547
ïŒ1980幎ïŒæ11æ¥åºé¡ïŒïŒ165536å·ïŒ1980幎ïŒæïŒ
æ¥åºé¡ïŒïŒããã³165532ïŒ1980幎ïŒæïŒæ¥åºé¡ïŒã«
é瀺ãããŠããã æ¬çºæã§äœ¿çšããç°æ¹æ§æº¶èçžã圢æããã溶
èå å·¥æ§ããªããŒã®ééå¹³åååéã¯çŽ4000ã
25000ã§ãããééå¹³åååéã4000ããäœããª
ããšãååéãçãããŠè¯å¥œãªäžééæ§å°å ¥ãè¡
ãããšãã§ããªãããŸããééå¹³åååéã
25000ãè¶ ãããšãåŸãããæ圢ææã®æº¶èç²åºŠ
ã倧ãããªããããå°åºæ圢ã«ãããŠé«ãå§åã
å¿ èŠãšããå°å ¥æ圢ãåãã粟å¯ãªé»åéšåãæ
ãªãããŸãã溶èç²åºŠãé«ããšãåå ã®æ圢ææ
ã®æµåã劚ããããŠæ害ãªãã€ããçããäžéé
æ§å°å ¥ãåŸãããªããããªãã¡ãæ°Žåãé»åéšå
ã«éãããŸã玫å€ç·ããã®ä¿è·ãååã§ãªããª
ãã 奜é©æ æ§ã§ã¯ã溶èå å·¥æ§ã®ç°æ¹æ§ã¡ã«ã圢æ
æ§ããªããŒã¯ãçŽ4000ã10000ã®ééå¹³åååé
ã瀺ãããã®ééå¹³åååéã®æž¬å®ã¯ãæšæºçãª
ã²ã«ééã¯ãããã°ã©ãã€ãŒã«ããå®æœã§ããã
äŸãã°ãå žåçãªè©Šéšã§ã¯ããã³ã¿ãã«ãªãããš
ããŒã«ãšãããµãã«ãªãã€ãœãããããŒã«ãšã®äœ
ç©æ¯ã§ïŒïŒïŒã®æ··åç©ãããªã溶åªã«ãšããã
0.1ééïŒ ã®ããªããŒæº¶æ¶²çŽ150ÎŒããäž»å¶åŸ¡è£
眮ïŒäŸãWaters201å液äœã¯ãããã°ã©ãè£ çœ®ïŒã
å€å質ã·ãªã«ç²åïŒäŸãããŠãã³SE4000ã
SE1000ããã³SE100ããªãã³ã«Waters60â«
MicroporasilïŒãå å¡«ããïŒã€ã®ã«ã©ã ããªã
ã³ã«ã¬ãŒã¶ãŒå æ£ä¹±è£ 眮ïŒäŸãChromatix
KMX6ïŒããæ§æããã²ã«ééã¯ãããã°ã©ã
ã€ãŒè£ 眮ã«å®€æž©ã§å°å ¥ãããå žåçãªæº¶èå å·¥æ§
ã®ç°æ¹æ§ã¡ã«ã圢ææ§ããªããŒã¯ã20ã50åã®ç¯
å²å ã®ä¿ææéååžãäžè¬ã«ç€ºãã 䜿çšãã溶èå å·¥æ§ããªããŒãããã®æº¶èå å·¥
枩床ã§ã®å ç±ã§ãã以äžã®é£éæé·ãå®è³ªçã«äž
å¯èœãšãªãããã«ããã«ã¯ãåããªããŒé£éã®æ«
端ããé£æ¥ããªããŒé£ééã§ããã«éååå¿ãèµ·
ããããšãå®è³ªçã«äžå¯èœãªå®èœåºãšãªã€ãŠãã
ããšãäžå¯æ¬ ã§ããããããããªããŒã¯ãäžæŽ»æ§
é°å²æ°ïŒäŸãçªçŽ ãŸãã¯ã¢ã«ãŽã³ïŒäžã§340âã®
枩床ã«30åéå ç±ããŠãããã®ééå¹³åååéã¯
奜ãŸããã¯15ïŒ ä»¥äžãããã«å¥œãŸããã¯10ïŒ ä»¥äž
ããå¢å ããªãããããã€ãŠããã®ããªããŒã¯ã
å ç±æã«ãã€ããçããã¬ã¹ç¶å¯çç©ãå®è³ªäžçº
çããããšã¯ãªããå ç±ã®æéççµéãšãšãã«ã
ã®æº¶èç²åºŠãå®è³ªäžå¢å ããããšããªããåŸæ¥ã®
äžè¬çãªè£œæ³ã§è£œé ããããµãŒã¢ããããã¯æ¶²æ¶
æ§ããªããŒã¯ããã®éèŠãªç¹åŸŽãæ¬ åŠããŠããã
åŸæ¥ã®ãµãŒã¢ããããã¯æ¶²æ¶æ§ããªããŒã¯ãå¿ èŠ
ãªåå¿åºãäŸãã°ããªããŒé£éã«æ²¿ã€ããšã¹ãã«
åºã圢æãããããªåå¿åºããåå¿åºéã®ååŠé
è«çåè¡¡ãçããããã«æ éã«åå¿ããããšãã
æ¹æ³ã«ãã圢æããã®ãæ®éã§ãããäŸãã°ãã
ãããã³ãŸãã¯ãããããã³ãžã¢ã»ããŒããªã©ã®
æ¯èŒçæ®çºæ§ã®é«ãã¢ãããŒãåå¿ç©è³ªãšããŠçš
ããå Žåã䜿çšéåæ¡ä»¶ã«ããæ®çºã«ãã€ãŠãã®
ã¢ãããŒã倱ãããã®ãèŠè¶ããŠããã®æ倱éã
è£åããããã«ãã®ã¢ãããŒãéå°ã«äŸçµŠããã
ãšã¯ãããåçš®ã®ãšã¹ãã«åœ¢ææ§ã¢ãããŒã䜿çš
ããŠãååŠéè«çã«é£åã€ãæ¡ä»¶äžã§äºãã«åå¿
ããããšãããªããŒé£éã®æ«ç«¯ã«å¿ èŠãªãšã¹ãã«
圢ææ§åºãã©ã³ãã ã«ååšããããªããŒãçæã
ãããããã®æ«ç«¯åºã¯ãå¥ã®åå¿å·¥çšã«ãããŠæ«
端ãã€ããããªãéãããã®åŸã«ç±å å·¥ïŒäŸãå°
åºæ圢ãæŒåºãæ··ç·ŽçïŒãåãããšãæ«ç«¯åºãäº
ãã«åå¿ããããªããŒé£éã®é·ããçé·ãããåŸ
åãããããããããªããŒãç±å å·¥ããŠåºäœç¶æ
ã§ååéãå¢å ãããããšã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3975487ïŒ4183895ïŒããã³4247514å·ã«é瀺ãã
ãŠãããçž®ååå¿ã«ããéåãç¶ãããšãæ¯èŒç
äœååéã®å¯çç©ã®åæçºçããªãã¡ã¬ã¹çºçã
èµ·ãã€ããããã®åŸã«æº¶èå å·¥ãåãããšãã«ç
æããªããŒã®æº¶èç²åºŠãèããäžæããããšãã
ããæ¬çºæã§ã¯ããã®ãããªã¬ã¹çºçãå°å ¥æ圢
äžã«å®è³ªäžèµ·ãããªãããšãå¿ é èŠä»¶ã§ãããã
ãã«ãããäžééæ§ã§å®è³ªçã«ãã€ãã®ãªã補å
ã®åœ¢æãä¿èšŒãããããŸããæ¯èŒçäžå®ã®æº¶èç²
床ãä¿èšŒããããã®ããåŸãããå°å ¥æ圢ããã
é»åããã€ã¹ã®åäžæ§ããã³å質ãåäžããã ãã®ãããªããªããŒãçæãããããã®å®æœå¯
èœãªïŒã€ã®åææ³ãšããŠãç°æ¹æ§æº¶èçžã圢æã
ã溶èå å·¥æ§ããªããŒãéååå¿ã«ãããã®åœ¢æ
éçšã§æå®ã®ååéã«ãªã€ãããããªããŒé£éã
æ«ç«¯ãã€ããå€ã®å°å ¥ã«ããé©å®æ«ç«¯ãã€ããã
ãŠããã以åŸããã«é£é䌞é·ããã®ãå®è³ªçã«é²
æ¢ããæ¹æ³ããããäŸãã°ãïŒå®èœæ§æ«ç«¯ãã€ã
ãåå¿ç©è³ªãçšããããšãã§ããã æ¬çºæã®æ¹æ³ã®ç¹ã«å¥œãŸããæ æ§ã«ããã°ãç°
æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªããŒã®åœ¢
æã¯ãç¹éæ60â40127å·å ¬å ±ã«èšèŒã®æ¹æ³ã«ã
ããã€ãŠè¡ãã ããå ·äœçã«ã¯ã溶èå å·¥æ§ããªããŒãå Žåã«
ããã¢ããçµåãå«æããŠããŠãããããªãšã¹ã
ã«ã§ããå Žåããã®ããªãšã¹ãã«ã¯ãäžèš(a)ã(f)
ïŒååŒäžãArã¯å°ãªããšãïŒã€ã®è³éŠç°ãããªã
ïŒäŸ¡åºãæå³ããïŒïŒ (b) ââArââã (d) ââArââã ïŒåŒäžãã¯ïŒ¯ãNHãŸãã¯NRãã¯NHãŸ
ãã¯NRãæå³ããã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«
åºãŸãã¯ã¢ãªãŒã«åºã§ããïŒã ïŒåŒäžãã¯NHãŸãã¯NRãæå³ããã¯ç
çŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«åºã§ã
ãïŒããªãã³ã« (f) 以äžã®çµåãã ãããªã矀ããéžã°ããå埩æåãæããããªã
ãŒã圢æãããããªãšã¹ãã«åœ¢ææ§ããã³å Žåã«
ããã¢ããæ圢æ§ã¢ãããŒããéå垯åã§éåå
å¿ãããŠåŸããå Žåã«ããã¢ããçµåãæããŠã
ãŠãããããªãšã¹ãã«ã§ããããã ããåèšéå
åå¿äžã«çŽïŒãïŒã¢ã«ïŒ ã奜ãŸããã¯çŽïŒãïŒã¢
ã«ïŒ éå°ã®è³éŠæãžã«ã«ãã³é žã¢ãããŒããã³ïŒ
ãŸãã¯ãã®ãšã¹ãã«åèªå°äœãéå垯åã«äŸçµŠ
ãããã®éå°ã¢ãããŒã«ãããéååå¿äžã«çæ
ããªããŒã®ããªããŒé£éã®å éšã«ãžã«ã«ããã·ã¢
ãªãŒã«åäœãä»äžããããšå ±ã«ãããªããŒé£éã®
æ«ç«¯ãã«ã«ãã³é žæ«ç«¯åºããã³ïŒãŸãã¯ãã®ãšã¹
ãã«åèªå°äœãšãªããããªããŒé£éãéå垯åã«
ååšããä»ã®ã¢ãããŒã®æ¶èã«ããå¿ èŠãªååé
ã«å°éãããããåŸãããããªããŒçæç©ã¯ãã®
åŸã«å ç±ãåããŠããã以äžã®é£éæé·ãå®è³ªç
ã«äžå¯èœãšãªã€ãŠããã å åŠçã«ç°æ¹æ§ã®æº¶èçžã瀺ãããªãšã¹ãã«ã
圢æãããããªãšã¹ãã«åœ¢ææ§ã¢ãããŒã¯ããã¹
ãŠåè¿°ã®æ¹æ³ã«çšããããšãã§ãããå Žåã«ãã
ã¢ãã圢ææ§ã¢ãããŒãããã«äœ¿çšããŠãããã
ãã®å Žåã«ã¯å åŠçç°æ¹æ§æº¶èçžã瀺ãããªïŒãš
ã¹ãã«âã¢ããïŒã圢æããããå°éã®ã«ãŒãã
ãŒã圢ææ§ã¢ãããŒããåŸãããããªãšã¹ãã«ã®
æã€å åŠçç°æ¹æ§æº¶èçžã瀺ãèœåã«æªåœ±é¿ããª
ãéãå«æããããã奜é©æ æ§ã§ã¯ãåŸãããã
ãªããŒã¯ãããªããŒå ã«ååšããå šæåãå°ãªã
ãšãïŒã€ã®è³éŠç°ãä»äžãããã®ã§ãããšããæ
å³ã§å šè³éŠæã§ããã æ¢è¿°ã®ããã«ãåè¿°ã®æ¹æ³ã§ããªãšã¹ãã«ã圢
æããå Žåã«äœ¿çšå¯èœãªã¢ãããŒã®ïŒã€ã¯ãåŒ ïŒãã ããArã¯å°ãªããšãïŒã€ã®è³éŠç°ãã
ãªãïŒäŸ¡åºïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã¢
ãããŒã§ããã奜é©æ æ§ã§ã¯ãArã¯ïŒïŒïŒâã
ãšãã¬ã³ãŸãã¯ïŒïŒïŒâããã¿ã¬ã³ã§ããããã
ãã€ãŠããã®å Žåãåèšå埩æåã¯ãïŒâãªãã·
ãã³ãŸã€ã«æåãŸãã¯ïŒâãªãã·âïŒâãããã€
ã«æåãšãªãããã®ããªãšã¹ãã«ã¯ãåã ã§Ar
ãç°ãªãããããåæåãäžèšäžè¬åŒãæºè¶³ãã
ïŒä»¥äžã®ç°ãªãå埩æåïŒäŸãïŒïŒïŒâããšãã¬
ã³ãšïŒïŒïŒâããã¿ã¬ã³ã®çµåãïŒãå«æããŠã
ãŠãããããã®ãããªã¢ãããŒã¯ããããããšã¹
ãã«åœ¢ææ§ã®ïŒçš®é¡ã®åå¿åºãå³å¯ã«åãéã§å«
æããŠããããã«ãæ¬æ¥ååŠéè«çã«åè¡¡ããšã
ãŠãããArã«ååšããè³éŠç°ã¯ãç°ã«çµåããŠ
ããæ°ŽçŽ ååã®å°ãªããšãäžéšã眮æãããŠãã
ãã®ã§ãããããã®ä»»æã®çœ®æåºã¯ãççŽ æ°ïŒã
ïŒã®ã¢ã«ãã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³ãã·åºã
ããã²ã³ïŒäŸãClãBrãïŒãããšãã«ãããã³
ãããã®çµåãã®äžããéžæããããç¹ã«å¥œãŸã
ãæåã¯ãïŒâããããã·å®æ¯éŠé žããã³ïŒâã
ãããã·âïŒâããããšé žããèªå°ããããã®ã§
ããã代衚çãªç°çœ®æåæåãšããŠã¯ãïŒâã¯ã
ãâïŒâããããã·å®æ¯éŠé žãïŒïŒïŒâãžã¯ãã
âïŒâããããã·å®æ¯éŠé žãïŒïŒïŒâãžã¯ããâ
ïŒâããããã·å®æ¯éŠé žãïŒïŒïŒâãžã¯ããâïŒ
âããããã·å®æ¯éŠé žãïŒâããã¢âïŒâããã
ãã·å®æ¯éŠé žãïŒâã¡ãã«âïŒâããããã·å®æ¯
éŠé žãïŒïŒïŒâãžã¡ãã«âïŒâããããã·å®æ¯éŠ
é žãïŒïŒïŒâãžã¡ãã«âïŒâããããã·å®æ¯éŠ
é žãïŒâã¡ããã·âïŒâããããã·å®æ¯éŠé žã
ïŒïŒïŒâãžã¡ãã«âïŒâããããã·å®æ¯éŠé žãïŒ
âããšãã«âïŒâããããã·å®æ¯éŠé žãïŒâããš
ãã«âïŒâããããã·å®æ¯éŠé žãïŒâããããã·
âïŒâã¯ããâïŒâããããšé žãïŒâããããã·
âïŒâã¡ãã«âïŒâããããšé žãïŒâããããã·
âïŒâã¡ããã·âïŒâããããšé žãïŒâãããã
ã·âïŒïŒïŒâãžã¯ããâïŒâã¯ããâããããš
é žãçããèªå°ããããã®ãæãããããä»ã®é
ç°çœ®æåæåãšããŠã¯ãïŒâããããã·å®æ¯éŠé ž
ããã³ïŒâããããã·ãããšãã«â4â²âã«ã«ãã³
é žããèªå°ããããã®ãããã æ¬çºæã§çšããããªãšã¹ãã«ã圢æããå Žåã«
䜿çšå¯èœãªå¥ã®ã¢ãããŒã¯ãæ¢è¿°ã®ããã«ãåŒ ââArââ ïŒãã ããArã¯å°ãªããšãïŒã€ã®è³éŠç°ãã
ãªãïŒäŸ¡åºïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã¢
ãããŒã§ããã代衚çãªæåã«ã¯ã次ã®ãããªã
ã®ãããïŒ
ãã€å ã«çœ®ããŠããå°åºæ圢ã«ããæ圢ææãå°
å ¥ãããé»åéšåã®æ¯èŒçè¿ éãã€ãã€ãã®ãªã
äžééæ§å°å ¥æ圢çšãšããŠç¹ã«é©ããæ¹è¯ããã
æ圢ææããããå©çšããå°å ¥æ圢æ³ããªãã³ã«
ããã«ããåŸãããå°å ¥è£œåã«é¢ããã ïŒåŸæ¥ã®æè¡ïŒ ä¿è·çšã®åææš¹èææã®å éšã«é»åéšåãå°å ¥
æ圢ããããã®å ·äœçãªæè¡ã¯ãåœæ¥è ã«ã¯åšç¥
ã§ãããåºãå®æœãããŠããïŒäŸãPlastics
Design Forum IssueïŒ1981幎ïŒæïŒæ²èŒã®ãå
å°äœããã€ã¹ã®å°å ¥æ圢ããšé¡ããè«æãåç §ïŒã åŸæ¥ãå°å ¥æ圢ã¯ãäžè¬ã«ç±ç¡¬åæ§æš¹èææã
çšããŠããã©ã³ã¹ãã¢ãŒæ圢ãšäžè¬ã«åŒã°ããå°
åºæ圢ã®ïŒåœ¢æ ã«ããå®æœããŠãããäŸãã°ããš
ããã·æš¹èïŒäŸãããã©ãã¯ç¡¬ååãšããã·æš¹è
ç³»ïŒãäžè¬ã«ãã®ç®çã«çšããŠããããŸããäžé£œ
åããªãšã¹ãã«ããã¹âã€ããããªããŒçã®ç±ç¡¬
åæ§æš¹èãå°å ¥æ圢ææãšããŠäœ¿çšããããšãæ
æ¡ãããŠããïŒäŸãç±³åœç¹èš±ç¬¬4327369ïŒ
4374080ïŒããã³4390596å·åç §ïŒããããç±ç¡¬å
æ§ææã¯ã䜿çšåã®å·åŽãå¿ èŠãšããæ圢æã«ã¯
æ¯èŒçé·ããµã€ã¯ã«æéãå¿ èŠãšããåŸåãã
ããæ圢åŸã«ã¯å°å ¥æ圢çšæš¹èã®ææã®ç¡¬åãå®
äºãããŸã§å ç±åšå ã§é«æž©ã«ãããŠé·æé硬åã
ããªããã°ãªããªãããšãå€ããæªç¡¬åã®ç±ç¡¬å
æ§æš¹èã®ç²åºŠã¯ãæš¹èã®å ç±ããŠç¡¬åãé²ãã«ã€
ããŠå¢å ããŠããã®ã§ãäžæŠå ç±ãå§ããããæª
硬åææã¯æ¯èŒçéã䜿çšããªããã°ãªããªãã
ãã®ãããªææã§ã¯ãã¹ã¯ã©ããã®å埪ç°ã¯äžå¯
èœã§ããããŸãã倩ç¶ã®æš¹èçµåå€ãæããå°å ¥
æ圢ææã¯ãã°ãã®åœ¢æãšéåãã€ããã€è¡šé¢ãž
ã®ä»çã®åŸåãäžè¬ã«ç€ºãããã®ããéåãã€ã
ãã€ãæå·ããå¯èœæ§ããããæ圢äœæ¥äžã«çç·Ž
äœæ¥å¡ã«ããååãªè£ä¿®ã®èæ ®ãå¿ èŠã«ãªããã
ã®ç¹ã§å°å ¥æ圢工çšã®å®å šãªèªååã劚ããããŠ
ããã å·¥æ¥èŠæš¡ã§çšããããŠã¯ããªãããããçš®ã®ç±
å¯å¡æ§æš¹èããããŸã§é»åéšåã®å°å ¥æ圢çšãšã
ãŠææ¡ãããŠãããäŸãã°ãç±³åœç¹èš±ç¬¬4327369
å·ã®ç¬¬ïŒæ¬18ã23è¡ç®ã«ã¯ãããªå¡©åããã«ïŒäœ
å¯åºŠããªãšãã¬ã³ãé«å¯åºŠããªãšãã¬ã³ãããªã
ããã¬ã³ã®ãããªããªãªã¬ãã€ã³ïŒããã³ããªã¹
ãã¬ã³ãäŸç€ºãããŠãããããã«ãç±³åœç¹èš±ç¬¬
4370292å·ã«ã¯ãããšããã·æš¹èãå å«ããããª
ããšãã¬ã³ã¹ã«ãã€ãçµæç©ãå°å ¥æ圢çšãšããŠ
ææ¡ãããŠããã å°å ¥æ圢暹èå ã«ãã·ãªã«ãŸãã¯ã¢ã«ããã®ã
ãã«ç¹ã«æ圢åŸã®å°å ¥æ圢ææã®ç±äŒå°çãå¢å
ãããããããã®äœç±èšåŒµçãäœäžãããç²åç¶
å å¡«æãå«æãããããšã¯ãåŸæ¥ããäžè¬ã«è¡ã
ããŠããããããããããç²åç¶å å¡«æã¯ãç¹ã«
é«æ¿åºŠã§ååšãããå Žåã«ãæ圢æã®çµæç©ã®ç²
床ãéåžžã«å€åïŒå³ã¡ãå¢å ïŒããããç²åºŠãé«
ããªãããããšãæ圢ææãæµå°ãããŠéåãå
åã«æºããããšãå°é£ãšãªããæ圢åã«ãã€ãã
ããã°ãå°å ¥æ圢ã¯å€±è²©ãšããããç²çš ãªæ圢æ
æãå§åãé«ããŠæµåããããšãå°å ¥æ圢ãåã
ã粟å¯ãªé»åéšåãæãªãå Žåãããããã®ãã
ãªæå·ããç±³åœç¹èš±ç¬¬4374080å·ã§ã¯ãã¯ã€ã€ã¹
ãŠã€ãŒãããšåŒãã§ããããã®ãããªåŒã€ãããŸ
ãã¯æã¿ã«ãã€ãŠããã³ãã€ã³ã°æ¥åéšãè£ãã
ããæ害ãªã·ãšãŒããçºçããŠãé»æ°åè·¯ãžã®é
é ·ãªè² è·ããã®ç Žå£ãèµ·ããããšãããããŸãã
ç±å¯å¡æ§å°å ¥å€ã®ååéã®äœäžã«ããæ圢ææãš
ããŠå¿ èŠãªç²åºŠãåŸãããšãããšãåŸãããæ圢
åã®æ©æ¢°çæ§è³ªïŒäŸãèæ§ïŒãäžååãšãªããã
ãªããŒææãå€ãã®éåå·¥çšã«åºæã®å€Ÿéç©
ïŒäŸãæ°Žæœåºæ§ããã²ã³ãŸãã¯æ°Žæœåºæ§ã®ã€ãªã³
æ§ç©è³ªãå«æããå Žåããã®å€Ÿéç©ãå°å ¥ããã
é»åéšåã®äŸµé£ããã³ïŒãŸãã¯ãã®åäœãžã®æªåœ±
é¿ãçããããšãããããŸããããªããŒææãæ
圢æäœäžãŸãã¯ãã®åŸã®å°å ¥æ圢ããé»åéšåã®
䜿çšäžã«äœããã®çç±ã§ïŒäŸãçž®éååå¿ã«ã
ãïŒå®è³ªçã«ã¬ã¹ç¶å¯çç©ãçºçããåŸåããã
ãšãé倧ãªãã€ãã®çºçããã³å°å ¥æ圢å€çµæç©
ã®æå·ã«ã€ãªãããäžèšæ¬ ç¹ã®ä»ã«ããå€ãã®ç±
å¯å¡æ§æš¹èã¯ãé»åéšåãæ®éã«çŽé¢ãããããª
é«æž©ã§é·æé確å®ã«æ©èœããããšã¯ã§ããããã
ã³ïŒãŸãã¯çã«ããããšçããããããã®ä¿è·ç¹
æ§ã¯ãã®ç¹ã§æžããã ïŒçºæã®ç®çïŒ æ¬çºæã®ç®çã¯ãé»åéšåã®äžééæ§å°å ¥æ圢
ã«ç¹ã«é©ãããæ¹è¯ãããæ圢ææãæäŸããã
ãšã§ããã æ¬çºæã®ç®çã¯ãã«ãããŸãã¯ããŠã¢ã«ã€ã³ã©
ã€ã³åéç©åè·¯ã®ãããªç²Ÿå¯é»åéšåã®å°å ¥æ圢
ã«ç¹ã«é©ãããæ¹è¯ãããç±å¯å¡æ§æ圢ææãæ
äŸããããšã§ããã æ¬çºæã®ç®çã¯ã粟å¯é»åéšåãæãªããã«å°
å ¥æ圢ããããšãã§ããå®è³ªéã®ç²åç¶ç¡æ©ææ
ãå«æããæ¹è¯ãããç±å¯å¡æ§æ圢ææãæäŸã
ãããšã§ãããããã«ããéåžžã«ããããæ©æ¢°
çãç±çãååŠçããã³é»æ°çæ§è³ªã瀺ããäžå©
ãªç°å¢æ¡ä»¶ã«çŽé¢ããå Žåã§ãé·æéã«äºã€ãŠå
åãªæ©èœãçºæ®ã§ããå°å ¥æ圢ãããæçµè£œåã
圢æãããã æ¬çºæã®ç®çã¯ãåŸæ¥äžè¬ã«è¡ãããŠããæé
ã®ãããããªããŒç¡¬åå·¥çšãå¿ èŠãšããã«å®æœã§
ãããé»åéšåã®æ¹è¯ãããå°å ¥æ圢æ¹æ³ãæäŸ
ããããšã§ããã æ¬çºæã®å¥ã®ç®çã¯ãæ¹è¯ãããå°å ¥æ圢é»å
éšåãæäŸããããšã§ããã ããã«æ¬çºæã®ç®çã¯ãå å¡«ãããå°å ¥æ圢çš
æš¹èããæ°Žããã³çŽ«å€ç·ã«å¯ŸããŠå®è³ªçã«äžéé
æ§ã§ãããå®è³ªçã«ãã€ãããªããããããæ©æ¢°
çæ§è³ªïŒäŸãæ©æ¢°ç匷床ïŒãäœç±èšåŒµçããã³ç±
äŒå°çã瀺ããæ°Žæœåºæ§ã¢ã«ã«ãªéå±å«æéã
50ppmæªæºãæ°Žæœåºæ§ããã²ã³å«æéã100ppm
æªæºã§ãããULâ94è©Šéšã§ïŒ¶âã®ççŒè©äŸ¡ã
瀺ããé·æ䜿çšãå¯èœã§ãããæ¹è¯ãããå°å ¥æ
圢é»åéšåãæäŸããããšã§ããã åè¿°ããã³ä»ã®ç®çããªãã³ã«æ¬çºæã®ç¯å²ã
åçããã³çšéã¯ã以äžã®èšèŒããåœæ¥è ã«ã¯æ
ããã«ãªããã ïŒçºæã®æ§æïŒ æ¬çºæã¯ã (a) ééå¹³åååéãçŽ4000ã25000ã§ãå ç±ã«
ãããã以äžã®é£éæé·ãå®è³ªçã«äžå¯èœãªã
ç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªã
ãŒãããã³ (b) æå(a)ã®äœç±èšåŒµçãæžå°ããããšå ±ã«ãã
ã®ç±äŒå°çãå¢å ãããããšã®ã§ãããæ圢æ
æã®å šééã«åºã¥ããŠçŽ40ã80ééïŒ ã®éã®ã
æå(a)äžã«å®è³ªçã«åäžã«åæ£ããç²åç¶ç¡æ©
ææ ãããªããå°åºæ圢ã«ããé»åéšåã®äžééæ§å°
å ¥æ圢ã«ç¹ã«é©ããæ圢ææã§ããã æ¬çºæã¯ãŸã (1) å°å ¥ãã¹ãé»åéšåãéåãã€ããã€å ã«å ¥
ãã (2) é»åéšåãå ¥ããéåãã€ããã€ã«ã (a) ééå¹³åååéãçŽ4000ã25000ã§ãå ç±
ã«ãããã以äžã®é£éæé·ãå®è³ªçã«äžå¯èœ
ãªãç°æ¹æ§æº¶èçžã圢æããã溶èãã溶è
å å·¥æ§ããªããŒãããã³ (b) æå(a)ã®äœç±èšåŒµçãæžå°ããããšå ±ã«ã
ãã®ç±äŒå°çãå¢å ãããããšã®ã§ãããæ
圢ææã®å šééã«åºã¥ããŠçŽ40ã80ééïŒ ã®
éã®ãæå(a)äžã«å®è³ªçã«åäžã«åæ£ããç²
åç¶ç¡æ©ææ ãããªãæ圢ææãé«æž©ã§å°åºããŠããã®ãã€
ããã€ãå®å šã«æºããã (3) éåãã€ããã€ã®å 容ç©ãå·åŽããŠåèšæ圢
ææãåºåãããåèšé»åéšåã®åšå²ã«äžéé
æ§ããã±ãŒãžã圢æãã (4) åŸãããå°å ¥æ圢é»åéšåãåèšéåãã€ã
ãã€ããåãåºãã ãšããå·¥çšãããªããé»åéšåã®æ¹è¯ãããäžé
éæ§å°å ¥æ圢æ¹æ³ã§ããã æ¬çºæã¯ããã« (a) ééå¹³åååéãçŽ4000ã25000ã§ãå ç±ã«
ãããã以äžã®é£éæé·ãå®è³ªçã«äžå¯èœãªã
ç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªã
ãŒãããã³ (b) æå(a)ã®äœç±èšåŒµçãæžå°ããããšå ±ã«ãã
ã®ç±äŒå°çãå¢å ãããããšã®ã§ãããçµæç©
ã®å šééã«åºã¥ããŠçŽ40ã80ééïŒ ã®éã®ãæ
å(a)äžã«å®è³ªçã«åäžã«åæ£ããç²åç¶ç¡æ©æ
æã ãããªãå°å ¥å€çµæç©ã®å éšã«é»åéšåãäžéé
æ§ã«å°å ¥æ圢ããŠãªãæ¹è¯ãããå°å ¥è£œåã§ã
ãã å€æ§ãªé»åéšåããæ¬çºæã«åŸã€ãŠãäžééæ§
ã§å®è³ªçã«ãã€ãã®ãªãããã±ãŒãžå ã«æå¹ã«å°
å ¥æ圢ããããšãã§ããããããé»åéšåã¯ãæ¯
èŒçåçŽãªé»åããã€ã¹ã§ããæ¯èŒçè€éãªãã®
ã§ãããããã倧ããªé»åè£ çœ®ã«äœ¿çšããçŽ åãš
èŠãªããããã®ã§ããããå°å ¥æ圢ããããšã®ã§
ããé»åéšåã®ä»£è¡šäŸã¯ããã©ã³ãžã¹ã¿ãã³ã³ã
ã³ãµãç¶é»åšããã€ãªãŒããæµæåšãæµæåšã®å
路網ãéç©åè·¯çã§ããã奜é©æ æ§ã§ã¯ãé»åéš
åã¯ç²Ÿå¯ãªåå°äœããã€ã¹ã§ããããã€ããŒã©ã
é»çå¹æããã€ã¹çã§ãããå°å ¥æ圢ããããšã®
ã§ããéç©åè·¯ã«ã¯ãããããªåœ¢æ ã®ãã®ããã
ããéåžžãããæ¯æããŠããæ¯èŒçå°ããªã·ãªã³
ã³ãã®ä»ã®åå°äœãããã¯ãæäœïŒåãã100åã
ãŸãã¯ãã以äžã®å€çãšã®æ¥ç¹ãæã¡ãããåœè©²
åéã§ã¯åšç¥ã®ããã«ã代衚çãªéç©åè·¯ããã±
ãŒãžã¯ãé 補ã®ãŸãã¯ããåéã®ãããªä»ã®éå±
ããã€ãããé 補ã®åãçŽ0.01ã€ã³ãïŒ0.25mmïŒ
ã®èãéå±ãã¬ãŒã äžã«è£œäœããããã¯ãã 被èŠ
ãããªãŒããã¬ãŒã ãšããããšãã§ããããã®å Ž
åã«ã¯ãå°å ¥æ圢åŸã«çªåºãŠããé»æ°æ¥ç¹ãã¯ã
ã ä»ããã€ããããå·¥çšãå¿ èŠãªããªããéç©å
è·¯ãã€ãŸãã¯ãããã¯ãªãŒããã¬ãŒã ã®ããã«éš
ã«æ¥åããããã®ãã€ãŸãã¯ãããã®ãªãŒããã¬
ãŒã ãžã®é»æ°çæ¥ç¶ã¯ãçŽåŸçŽ0.001ã€ã³ã
ïŒ0.025mmïŒä»¥äžã®æ®éã¯éã®çŽ°ãã¯ã€ã€ã§è¡ãã
ãã®ã¯ã€ã€ã¯ãã¹ããã溶æ¥ãŸãã¯ä»ã®æ¹æ³ã«ã
ã€ãŠãæ®ééåžžã«èãã¢ã«ãããŠã èãããªãé
ç©åè·¯ãã€ãŸãã¯ãããäžã®æ¥ç¹ããªãã¡ãã³ã
ã€ã³ã°ãããããããªãŒããã¬ãŒã äžã®ã«ã³ãã¬
ããŒã¢ãŒã ã®æ«ç«¯ãæ¥ç¶ããŠããããããã€ãŠã
ç¹ã«å¥œé©ãªæ æ§ã§ã¯ãé»åããã€ã¹ã¯ãå°å ¥æ圢
éšåã®å€åŽã«çªãåºãå€æ°ã®ãªãŒããæããå¹³æ¿
ç¶ã®ææãå å·¥ãªãŒããã¬ãŒã äžã«çµç«ãŠãã«ã
ããŸãã¯ããŠã¢ã«ã€ã³ã©ã€ã³åéç©åè·¯ããã€ã¹
ã§ãããäŸãã°ã40ãã³ã®ãªãŒããã¬ãŒã ãå°å ¥
æ圢ãããã æ¬çºæã®æ圢ææã®ç¬¬ïŒã®å¿ é æåã¯ãééå¹³
åååéãçŽ4000ã25000ãšæ¯èŒçäœãããã®æº¶
èå 工枩床ã§å ç±ããŠããã以äžã®é£éæé·ãå®
質çäžå¯èœãªã溶èå å·¥æ§ãµãŒã¢ããããã¯æ¶²æ¶
æ§ããªããŒã§ããã ããªããŒã®æè¡åéã§ã¯å ¬ç¥ã®ããã«ããµãŒã¢
ããããã¯æ¶²æ¶æ§ããªããŒã¯ã溶èç¶æ ã«ãããŠ
å åŠçç°æ¹æ§ã瀺ãããã®ããªããŒã¡ã«ãã®ç°æ¹
æ§ã¯ãçŽäº€åå åãå©çšããæ £çšã®åå æè¡ã«ã
ã確èªã§ãããããå ·äœçã«ã¯ã溶èçžã®ç°æ¹æ§
ãŸãã¯èŠåæ§ã®ç¢ºèªã¯ãã©ã€ãïŒLeitzïŒåå é¡
埮é¡ãçšããŠã©ã€ããããã¹ããŒãžã«èŒããè©Šæ
ãçªçŽ é°å²æ°äžã«40åã®åçã§èŠ³å¯ããããšã«ã
ãè¡ãã®ã奜éœåã§ãããè©Šæã匷å¶çã«æµåã
ãããšééå éã¯å€åãããããã®çš®ã®è©Šæã¯ã
ãšãéæ¢ç¶æ ã§ãã€ãŠãå åŠçã«ç°æ¹æ§ã瀺ãã
ããã«å¯ŸããŠãå žåçãªæº¶èå å·¥æ§ããªããŒã¯ã
éæ¢æ¡ä»¶ã§ã®æ€æ»ã§ãå®è³ªççšåºŠã«å ãééãã
ãããšã¯ãªããæ¬è³ªçã«çæ¹æ§ã§ããã æ¬çºæã§çšããã®ã«é©ãããµãŒã¢ããããã¯æ¶²
æ¶æ§ããªããŒã®ä»£è¡šçãªçš®é¡ã«ã¯ãå šè³éŠæããª
ãšã¹ãã«ãè³éŠæâèèªæããªãšã¹ãã«ãå šè³éŠ
æããªïŒãšã¹ãã«âã¢ããïŒãè³éŠæâèèªæã
ãªïŒãšã¹ãã«âã¢ããïŒãè³éŠæããªã¢ãŸã¡ãã³ã
è³éŠæããªãšã¹ãã«âã«ãŒãããŒããããã³ãã
ãã®æ··åç©ãããã奜é©æ æ§ã§ã¯ããµãŒã¢ããã
ãã¯æ¶²æ¶æ§ããªãšã¹ãã«ã¯ãå šè³éŠæããªãšã¹ã
ã«ããŸãã¯å šè³éŠæããªïŒãšã¹ãã«âã¢ããïŒã§
ãããããªããŒé£éå ã«ååšãããã¹ãŠã®æåã
å°ãªããšãïŒã€ã®è³éŠç°ãä»äžãããã®ã§ããå Ž
åããã®ããªããŒã¯å šè³éŠæã§ãããšèŠãªãã
ãããŸãããµãŒã¢ããããã¯æ¶²æ¶æ§ããªããŒã¯ã
ããã¿ã¬ã³ç³»æåãäŸãã°ãïŒâãªãã·âïŒâã
ããã€ã«æåãïŒïŒïŒâãžãªãã·ããã¿ã¬ã³æ
åããŸãã¯ïŒïŒïŒâãžã«ã«ããã·ããã¿ã¬ã³æå
ãçŽ10ã¢ã«ïŒ 以äžã®éã§å«æããã®ã奜ãŸããã
ãµãŒã¢ããããã¯æ¶²æ¶æ§ããªããŒã«å«æãããã®
ã«ç¹ã«å¥œé©ãªããã¿ã¬ã³ç³»æåã¯ãçŽ10ã¢ã«ïŒ 以
äžã®éã®ïŒâãªãã·âïŒâãããã€ã«æåã§ã
ãã ãµãŒã¢ããããã¯æ¶²æ¶æ§ã瀺ã代衚çãªå šè³éŠ
æããªãšã¹ãã«ãšããŠã¯ãäžèšç±³åœç¹èš±ã«é瀺ã®
ãã®ãããïŒ3991013ïŒ3991014ïŒ4066620ïŒ
4067852ïŒ4075262ïŒ4083829ïŒ4093959ïŒ
4118372ïŒ4130545ïŒ4146702ïŒ4153779ïŒ
4156070ïŒ4156365ïŒ4161470ïŒ4169933ïŒ
4181792ïŒ4183895ïŒ4184996ïŒ4188476ïŒ
4201856ïŒ4219461ïŒ4224433ïŒ4226970ïŒ
4230817ïŒ4232143ïŒ4232144ïŒ4238598ïŒ
4238599ïŒ4238600ïŒ4242496ïŒ4245082ïŒ
4245084ïŒ4247514ïŒ4256624ïŒ4265802ïŒ
4267304ïŒ4269965ïŒ4279803ïŒ4294955ïŒ
4299756ïŒ4318841ïŒ4335232ïŒ4337190ïŒ
4337191ïŒ4347349ïŒ4355134ïŒ4359569ïŒ
4360658ïŒ4370466ïŒ4374228ïŒ4374261ïŒ
4375530ïŒããã³4377681ã ãµãŒã¢ããããã¯æ¶²æ¶æ§ã瀺ã代衚çãªè³éŠæ
âèèªæããªãšã¹ãã«ã¯ãW.J.JacksonnïŒJr.ïŒ
H.F.Kuhfussããã³T.F.GrayïŒJr.ããèªå·±åŒ·åç±
å¯å¡æ§ããªãšã¹ãã«X7Gâããç±³åœãã©ã¹ãã
ã¯å·¥æ¥äŒã匷åãã©ã¹ããã¯ïŒè€åæéšäŒã第30
å幎次æè¡äŒè°ïŒ1975ïŒãã»ã¯ã·ãšã³17âãã
ãŒãžïŒãïŒã«é瀺ãããŠãããããªãšãã¬ã³ãã¬
ãã¿ã¬ãŒããšããããã·å®æ¯éŠé žãšã®ã³ããªããŒ
ã§ããããã®ãããªã³ããªããŒã¯ããã«æ¬¡ã®æç®
ã«ãé瀺ãããŠããïŒW.J.JacksonnïŒJr.ïŒãã
ã³H.F.Kuhfussãã液æ¶ããªããŒïŒI.pâãããã
ã·å®æ¯éŠé žã³ããªããŒã®è£œé ãšæ§è³ªããJournal
of Polymer ScienceïŒPolymer Chemistry
EditionïŒVol.14ïŒpp.2043â58ïŒ1976ïŒãããã«ã
æ¬åºé¡äººã«è²æž¡ãããç±³åœç¹èš±ç¬¬4318842ããã³
4355133å·ãåç §ã§ããã ãµãŒã¢ããããã¯æ¶²æ¶ç¹æ§ã瀺ã代衚çãªå šè³
éŠæããã³è³éŠæâèèªæããªïŒãšã¹ãã«âã¢ã
ãïŒã¯ãç±³åœç¹èš±ç¬¬4272625ïŒ4330457ïŒ
4339375ïŒ4341688ïŒ4351917ïŒ4351918ããã³
4355132å·ã«é瀺ãããŠããã ãµãŒã¢ããããã¯æ¶²æ¶ç¹æ§ã瀺ã代衚çãªè³éŠ
æããªã¢ãŸã¡ãã³ã¯ãç±³åœç¹èš±ç¬¬4048148ããã³
4122070å·ã«é瀺ãããŠããããã®ãããªããªã
ãŒã®å ·äœäŸãšããŠã¯ãããªïŒãããªãâïŒâã¡ã
ã«âïŒïŒïŒâããšãã¬ã³ãããªããšããªãžã³â
ïŒïŒïŒâããšãã¬ã³ãšããªãžã³ïŒïŒããªïŒãããª
ãâïŒâã¡ãã«âïŒïŒïŒâããšãã¬ã³ãããªãã¡
ããªãžã³âïŒïŒïŒâããšãã¬ã³ã¡ããªãžã³ïŒïŒã
ãã³ããªïŒãããªãâïŒâã¯ããâïŒïŒïŒâããš
ãã¬ã³ãããªãã¡ããªãžã³âïŒïŒïŒâããšãã¬ã³
ã¡ããªãžã³ïŒãæããããã ãµãŒã¢ããããã¯æ¶²æ¶ç¹æ§ã瀺ã代衚çãªè³éŠ
æããªãšã¹ãã«âã«ãŒãããŒãã¯ç±³åœç¹èš±ç¬¬
4107143ïŒ4284757ïŒããã³4371660å·ã«é瀺ãã
ãŠããã æ¬çºæã§çšããç°æ¹æ§ã¡ã«ã圢ææ§ããªããŒ
ã¯ãç°æ¹æ§æº¶èçžã圢æã§ãããæãã¯ã§ããªã
ä»ã®ïŒçš®ä»¥äžã®æº¶èå å·¥æ§ããªããŒãšå Žåã«ãã
ãã¬ã³ãããŠãããããäœããåŸããããã¬ã³ã
ãé©åœãªæº¶èç²åºŠã瀺ãæèŠã®ç°æ¹æ§æº¶èçžã圢
æããããšãã§ããããšãæ¡ä»¶ã§ããããµãŒã¢ã
ãããã¯æ¶²æ¶ç¹æ§ã瀺ã代衚çãªããªããŒãã¬ã³
ãã¯ãæ¬åºé¡äººã«è²æž¡ãããç±³åœç¹èš±ç¬¬4267289
ããã³4276397å·ãªãã³ã«ç±³åœç¹èš±åºé¡ç¬¬158547
ïŒ1980幎ïŒæ11æ¥åºé¡ïŒïŒ165536å·ïŒ1980幎ïŒæïŒ
æ¥åºé¡ïŒïŒããã³165532ïŒ1980幎ïŒæïŒæ¥åºé¡ïŒã«
é瀺ãããŠããã æ¬çºæã§äœ¿çšããç°æ¹æ§æº¶èçžã圢æããã溶
èå å·¥æ§ããªããŒã®ééå¹³åååéã¯çŽ4000ã
25000ã§ãããééå¹³åååéã4000ããäœããª
ããšãååéãçãããŠè¯å¥œãªäžééæ§å°å ¥ãè¡
ãããšãã§ããªãããŸããééå¹³åååéã
25000ãè¶ ãããšãåŸãããæ圢ææã®æº¶èç²åºŠ
ã倧ãããªããããå°åºæ圢ã«ãããŠé«ãå§åã
å¿ èŠãšããå°å ¥æ圢ãåãã粟å¯ãªé»åéšåãæ
ãªãããŸãã溶èç²åºŠãé«ããšãåå ã®æ圢ææ
ã®æµåã劚ããããŠæ害ãªãã€ããçããäžéé
æ§å°å ¥ãåŸãããªããããªãã¡ãæ°Žåãé»åéšå
ã«éãããŸã玫å€ç·ããã®ä¿è·ãååã§ãªããª
ãã 奜é©æ æ§ã§ã¯ã溶èå å·¥æ§ã®ç°æ¹æ§ã¡ã«ã圢æ
æ§ããªããŒã¯ãçŽ4000ã10000ã®ééå¹³åååé
ã瀺ãããã®ééå¹³åååéã®æž¬å®ã¯ãæšæºçãª
ã²ã«ééã¯ãããã°ã©ãã€ãŒã«ããå®æœã§ããã
äŸãã°ãå žåçãªè©Šéšã§ã¯ããã³ã¿ãã«ãªãããš
ããŒã«ãšãããµãã«ãªãã€ãœãããããŒã«ãšã®äœ
ç©æ¯ã§ïŒïŒïŒã®æ··åç©ãããªã溶åªã«ãšããã
0.1ééïŒ ã®ããªããŒæº¶æ¶²çŽ150ÎŒããäž»å¶åŸ¡è£
眮ïŒäŸãWaters201å液äœã¯ãããã°ã©ãè£ çœ®ïŒã
å€å質ã·ãªã«ç²åïŒäŸãããŠãã³SE4000ã
SE1000ããã³SE100ããªãã³ã«Waters60â«
MicroporasilïŒãå å¡«ããïŒã€ã®ã«ã©ã ããªã
ã³ã«ã¬ãŒã¶ãŒå æ£ä¹±è£ 眮ïŒäŸãChromatix
KMX6ïŒããæ§æããã²ã«ééã¯ãããã°ã©ã
ã€ãŒè£ 眮ã«å®€æž©ã§å°å ¥ãããå žåçãªæº¶èå å·¥æ§
ã®ç°æ¹æ§ã¡ã«ã圢ææ§ããªããŒã¯ã20ã50åã®ç¯
å²å ã®ä¿ææéååžãäžè¬ã«ç€ºãã 䜿çšãã溶èå å·¥æ§ããªããŒãããã®æº¶èå å·¥
枩床ã§ã®å ç±ã§ãã以äžã®é£éæé·ãå®è³ªçã«äž
å¯èœãšãªãããã«ããã«ã¯ãåããªããŒé£éã®æ«
端ããé£æ¥ããªããŒé£ééã§ããã«éååå¿ãèµ·
ããããšãå®è³ªçã«äžå¯èœãªå®èœåºãšãªã€ãŠãã
ããšãäžå¯æ¬ ã§ããããããããªããŒã¯ãäžæŽ»æ§
é°å²æ°ïŒäŸãçªçŽ ãŸãã¯ã¢ã«ãŽã³ïŒäžã§340âã®
枩床ã«30åéå ç±ããŠãããã®ééå¹³åååéã¯
奜ãŸããã¯15ïŒ ä»¥äžãããã«å¥œãŸããã¯10ïŒ ä»¥äž
ããå¢å ããªãããããã€ãŠããã®ããªããŒã¯ã
å ç±æã«ãã€ããçããã¬ã¹ç¶å¯çç©ãå®è³ªäžçº
çããããšã¯ãªããå ç±ã®æéççµéãšãšãã«ã
ã®æº¶èç²åºŠãå®è³ªäžå¢å ããããšããªããåŸæ¥ã®
äžè¬çãªè£œæ³ã§è£œé ããããµãŒã¢ããããã¯æ¶²æ¶
æ§ããªããŒã¯ããã®éèŠãªç¹åŸŽãæ¬ åŠããŠããã
åŸæ¥ã®ãµãŒã¢ããããã¯æ¶²æ¶æ§ããªããŒã¯ãå¿ èŠ
ãªåå¿åºãäŸãã°ããªããŒé£éã«æ²¿ã€ããšã¹ãã«
åºã圢æãããããªåå¿åºããåå¿åºéã®ååŠé
è«çåè¡¡ãçããããã«æ éã«åå¿ããããšãã
æ¹æ³ã«ãã圢æããã®ãæ®éã§ãããäŸãã°ãã
ãããã³ãŸãã¯ãããããã³ãžã¢ã»ããŒããªã©ã®
æ¯èŒçæ®çºæ§ã®é«ãã¢ãããŒãåå¿ç©è³ªãšããŠçš
ããå Žåã䜿çšéåæ¡ä»¶ã«ããæ®çºã«ãã€ãŠãã®
ã¢ãããŒã倱ãããã®ãèŠè¶ããŠããã®æ倱éã
è£åããããã«ãã®ã¢ãããŒãéå°ã«äŸçµŠããã
ãšã¯ãããåçš®ã®ãšã¹ãã«åœ¢ææ§ã¢ãããŒã䜿çš
ããŠãååŠéè«çã«é£åã€ãæ¡ä»¶äžã§äºãã«åå¿
ããããšãããªããŒé£éã®æ«ç«¯ã«å¿ èŠãªãšã¹ãã«
圢ææ§åºãã©ã³ãã ã«ååšããããªããŒãçæã
ãããããã®æ«ç«¯åºã¯ãå¥ã®åå¿å·¥çšã«ãããŠæ«
端ãã€ããããªãéãããã®åŸã«ç±å å·¥ïŒäŸãå°
åºæ圢ãæŒåºãæ··ç·ŽçïŒãåãããšãæ«ç«¯åºãäº
ãã«åå¿ããããªããŒé£éã®é·ããçé·ãããåŸ
åãããããããããªããŒãç±å å·¥ããŠåºäœç¶æ
ã§ååéãå¢å ãããããšã¯ãäŸãã°ç±³åœç¹èš±ç¬¬
3975487ïŒ4183895ïŒããã³4247514å·ã«é瀺ãã
ãŠãããçž®ååå¿ã«ããéåãç¶ãããšãæ¯èŒç
äœååéã®å¯çç©ã®åæçºçããªãã¡ã¬ã¹çºçã
èµ·ãã€ããããã®åŸã«æº¶èå å·¥ãåãããšãã«ç
æããªããŒã®æº¶èç²åºŠãèããäžæããããšãã
ããæ¬çºæã§ã¯ããã®ãããªã¬ã¹çºçãå°å ¥æ圢
äžã«å®è³ªäžèµ·ãããªãããšãå¿ é èŠä»¶ã§ãããã
ãã«ãããäžééæ§ã§å®è³ªçã«ãã€ãã®ãªã補å
ã®åœ¢æãä¿èšŒãããããŸããæ¯èŒçäžå®ã®æº¶èç²
床ãä¿èšŒããããã®ããåŸãããå°å ¥æ圢ããã
é»åããã€ã¹ã®åäžæ§ããã³å質ãåäžããã ãã®ãããªããªããŒãçæãããããã®å®æœå¯
èœãªïŒã€ã®åææ³ãšããŠãç°æ¹æ§æº¶èçžã圢æã
ã溶èå å·¥æ§ããªããŒãéååå¿ã«ãããã®åœ¢æ
éçšã§æå®ã®ååéã«ãªã€ãããããªããŒé£éã
æ«ç«¯ãã€ããå€ã®å°å ¥ã«ããé©å®æ«ç«¯ãã€ããã
ãŠããã以åŸããã«é£é䌞é·ããã®ãå®è³ªçã«é²
æ¢ããæ¹æ³ããããäŸãã°ãïŒå®èœæ§æ«ç«¯ãã€ã
ãåå¿ç©è³ªãçšããããšãã§ããã æ¬çºæã®æ¹æ³ã®ç¹ã«å¥œãŸããæ æ§ã«ããã°ãç°
æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªããŒã®åœ¢
æã¯ãç¹éæ60â40127å·å ¬å ±ã«èšèŒã®æ¹æ³ã«ã
ããã€ãŠè¡ãã ããå ·äœçã«ã¯ã溶èå å·¥æ§ããªããŒãå Žåã«
ããã¢ããçµåãå«æããŠããŠãããããªãšã¹ã
ã«ã§ããå Žåããã®ããªãšã¹ãã«ã¯ãäžèš(a)ã(f)
ïŒååŒäžãArã¯å°ãªããšãïŒã€ã®è³éŠç°ãããªã
ïŒäŸ¡åºãæå³ããïŒïŒ (b) ââArââã (d) ââArââã ïŒåŒäžãã¯ïŒ¯ãNHãŸãã¯NRãã¯NHãŸ
ãã¯NRãæå³ããã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«
åºãŸãã¯ã¢ãªãŒã«åºã§ããïŒã ïŒåŒäžãã¯NHãŸãã¯NRãæå³ããã¯ç
çŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«åºã§ã
ãïŒããªãã³ã« (f) 以äžã®çµåãã ãããªã矀ããéžã°ããå埩æåãæããããªã
ãŒã圢æãããããªãšã¹ãã«åœ¢ææ§ããã³å Žåã«
ããã¢ããæ圢æ§ã¢ãããŒããéå垯åã§éåå
å¿ãããŠåŸããå Žåã«ããã¢ããçµåãæããŠã
ãŠãããããªãšã¹ãã«ã§ããããã ããåèšéå
åå¿äžã«çŽïŒãïŒã¢ã«ïŒ ã奜ãŸããã¯çŽïŒãïŒã¢
ã«ïŒ éå°ã®è³éŠæãžã«ã«ãã³é žã¢ãããŒããã³ïŒ
ãŸãã¯ãã®ãšã¹ãã«åèªå°äœãéå垯åã«äŸçµŠ
ãããã®éå°ã¢ãããŒã«ãããéååå¿äžã«çæ
ããªããŒã®ããªããŒé£éã®å éšã«ãžã«ã«ããã·ã¢
ãªãŒã«åäœãä»äžããããšå ±ã«ãããªããŒé£éã®
æ«ç«¯ãã«ã«ãã³é žæ«ç«¯åºããã³ïŒãŸãã¯ãã®ãšã¹
ãã«åèªå°äœãšãªããããªããŒé£éãéå垯åã«
ååšããä»ã®ã¢ãããŒã®æ¶èã«ããå¿ èŠãªååé
ã«å°éãããããåŸãããããªããŒçæç©ã¯ãã®
åŸã«å ç±ãåããŠããã以äžã®é£éæé·ãå®è³ªç
ã«äžå¯èœãšãªã€ãŠããã å åŠçã«ç°æ¹æ§ã®æº¶èçžã瀺ãããªãšã¹ãã«ã
圢æãããããªãšã¹ãã«åœ¢ææ§ã¢ãããŒã¯ããã¹
ãŠåè¿°ã®æ¹æ³ã«çšããããšãã§ãããå Žåã«ãã
ã¢ãã圢ææ§ã¢ãããŒãããã«äœ¿çšããŠãããã
ãã®å Žåã«ã¯å åŠçç°æ¹æ§æº¶èçžã瀺ãããªïŒãš
ã¹ãã«âã¢ããïŒã圢æããããå°éã®ã«ãŒãã
ãŒã圢ææ§ã¢ãããŒããåŸãããããªãšã¹ãã«ã®
æã€å åŠçç°æ¹æ§æº¶èçžã瀺ãèœåã«æªåœ±é¿ããª
ãéãå«æããããã奜é©æ æ§ã§ã¯ãåŸãããã
ãªããŒã¯ãããªããŒå ã«ååšããå šæåãå°ãªã
ãšãïŒã€ã®è³éŠç°ãä»äžãããã®ã§ãããšããæ
å³ã§å šè³éŠæã§ããã æ¢è¿°ã®ããã«ãåè¿°ã®æ¹æ³ã§ããªãšã¹ãã«ã圢
æããå Žåã«äœ¿çšå¯èœãªã¢ãããŒã®ïŒã€ã¯ãåŒ ïŒãã ããArã¯å°ãªããšãïŒã€ã®è³éŠç°ãã
ãªãïŒäŸ¡åºïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã¢
ãããŒã§ããã奜é©æ æ§ã§ã¯ãArã¯ïŒïŒïŒâã
ãšãã¬ã³ãŸãã¯ïŒïŒïŒâããã¿ã¬ã³ã§ããããã
ãã€ãŠããã®å Žåãåèšå埩æåã¯ãïŒâãªãã·
ãã³ãŸã€ã«æåãŸãã¯ïŒâãªãã·âïŒâãããã€
ã«æåãšãªãããã®ããªãšã¹ãã«ã¯ãåã ã§Ar
ãç°ãªãããããåæåãäžèšäžè¬åŒãæºè¶³ãã
ïŒä»¥äžã®ç°ãªãå埩æåïŒäŸãïŒïŒïŒâããšãã¬
ã³ãšïŒïŒïŒâããã¿ã¬ã³ã®çµåãïŒãå«æããŠã
ãŠãããããã®ãããªã¢ãããŒã¯ããããããšã¹
ãã«åœ¢ææ§ã®ïŒçš®é¡ã®åå¿åºãå³å¯ã«åãéã§å«
æããŠããããã«ãæ¬æ¥ååŠéè«çã«åè¡¡ããšã
ãŠãããArã«ååšããè³éŠç°ã¯ãç°ã«çµåããŠ
ããæ°ŽçŽ ååã®å°ãªããšãäžéšã眮æãããŠãã
ãã®ã§ãããããã®ä»»æã®çœ®æåºã¯ãççŽ æ°ïŒã
ïŒã®ã¢ã«ãã«åºãççŽ æ°ïŒãïŒã®ã¢ã«ã³ãã·åºã
ããã²ã³ïŒäŸãClãBrãïŒãããšãã«ãããã³
ãããã®çµåãã®äžããéžæããããç¹ã«å¥œãŸã
ãæåã¯ãïŒâããããã·å®æ¯éŠé žããã³ïŒâã
ãããã·âïŒâããããšé žããèªå°ããããã®ã§
ããã代衚çãªç°çœ®æåæåãšããŠã¯ãïŒâã¯ã
ãâïŒâããããã·å®æ¯éŠé žãïŒïŒïŒâãžã¯ãã
âïŒâããããã·å®æ¯éŠé žãïŒïŒïŒâãžã¯ããâ
ïŒâããããã·å®æ¯éŠé žãïŒïŒïŒâãžã¯ããâïŒ
âããããã·å®æ¯éŠé žãïŒâããã¢âïŒâããã
ãã·å®æ¯éŠé žãïŒâã¡ãã«âïŒâããããã·å®æ¯
éŠé žãïŒïŒïŒâãžã¡ãã«âïŒâããããã·å®æ¯éŠ
é žãïŒïŒïŒâãžã¡ãã«âïŒâããããã·å®æ¯éŠ
é žãïŒâã¡ããã·âïŒâããããã·å®æ¯éŠé žã
ïŒïŒïŒâãžã¡ãã«âïŒâããããã·å®æ¯éŠé žãïŒ
âããšãã«âïŒâããããã·å®æ¯éŠé žãïŒâããš
ãã«âïŒâããããã·å®æ¯éŠé žãïŒâããããã·
âïŒâã¯ããâïŒâããããšé žãïŒâããããã·
âïŒâã¡ãã«âïŒâããããšé žãïŒâããããã·
âïŒâã¡ããã·âïŒâããããšé žãïŒâãããã
ã·âïŒïŒïŒâãžã¯ããâïŒâã¯ããâããããš
é žãçããèªå°ããããã®ãæãããããä»ã®é
ç°çœ®æåæåãšããŠã¯ãïŒâããããã·å®æ¯éŠé ž
ããã³ïŒâããããã·ãããšãã«â4â²âã«ã«ãã³
é žããèªå°ããããã®ãããã æ¬çºæã§çšããããªãšã¹ãã«ã圢æããå Žåã«
䜿çšå¯èœãªå¥ã®ã¢ãããŒã¯ãæ¢è¿°ã®ããã«ãåŒ ââArââ ïŒãã ããArã¯å°ãªããšãïŒã€ã®è³éŠç°ãã
ãªãïŒäŸ¡åºïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã¢
ãããŒã§ããã代衚çãªæåã«ã¯ã次ã®ãããªã
ã®ãããïŒ
ãåŒã
奜é©æ
æ§ã§ã¯ãArã¯ïŒïŒïŒâããšãã¬ã³ãïŒïŒ
ïŒâããã¿ã¬ã³ãŸãã¯ïŒïŒ4â²âãããšãã«ã§ã
ãããã®ããªãšã¹ãã«ã¯ãåã ã§Arãç°ãªãã
ãããåæåãäžèšäžè¬åŒãæºè¶³ããïŒä»¥äžã®ç°
ãªãå埩æåãå«æããŠããŠããããæåã«èšèŒ
ããæåã«é¢ããŠèª¬æããããã«ãAräžã®è³éŠ
ç°ã¯ãå Žåã«ãããããã«çµåããŠããæ°ŽçŽ åå
ã®å°ãªããšãäžéšã眮æãããŠãããã®ã§ãã
ããç°çœ®æåã®å埩æåã®äŸã¯ãããšãã«ããã
ããã³ãã¡ãã«ãããããã³ãããã³ã¯ãããã
ãããã³ããèªå°ããæåã§ãããç¹ã«å¥œãŸãã
æåã¯ãåã«ãããããã³ãïŒïŒïŒâãžãããã
ã·ããã¿ã¬ã³ãããã³ïŒïŒ4â²âãããšããŒã«ãã
èªå°ããããã®ã§ããã æ¢è¿°ã®ããã«ãæ¬çºæã§çšããããªãšã¹ãã«ã
圢æããå Žåã«äœ¿çšå¯èœãªå¥ã®ã¢ãããŒã¯ãåŒ ïŒãã ããArã¯å°ãªããšãïŒã€ã®è³éŠç°ãã
æãïŒäŸ¡åºïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã¢
ãããŒã§ããã代衚çãªæåãšããŠã¯æ¬¡ã®ãããª
ãã®ãããïŒ
ïŒâããã¿ã¬ã³ãŸãã¯ïŒïŒ4â²âãããšãã«ã§ã
ãããã®ããªãšã¹ãã«ã¯ãåã ã§Arãç°ãªãã
ãããåæåãäžèšäžè¬åŒãæºè¶³ããïŒä»¥äžã®ç°
ãªãå埩æåãå«æããŠããŠããããæåã«èšèŒ
ããæåã«é¢ããŠèª¬æããããã«ãAräžã®è³éŠ
ç°ã¯ãå Žåã«ãããããã«çµåããŠããæ°ŽçŽ åå
ã®å°ãªããšãäžéšã眮æãããŠãããã®ã§ãã
ããç°çœ®æåã®å埩æåã®äŸã¯ãããšãã«ããã
ããã³ãã¡ãã«ãããããã³ãããã³ã¯ãããã
ãããã³ããèªå°ããæåã§ãããç¹ã«å¥œãŸãã
æåã¯ãåã«ãããããã³ãïŒïŒïŒâãžãããã
ã·ããã¿ã¬ã³ãããã³ïŒïŒ4â²âãããšããŒã«ãã
èªå°ããããã®ã§ããã æ¢è¿°ã®ããã«ãæ¬çºæã§çšããããªãšã¹ãã«ã
圢æããå Žåã«äœ¿çšå¯èœãªå¥ã®ã¢ãããŒã¯ãåŒ ïŒãã ããArã¯å°ãªããšãïŒã€ã®è³éŠç°ãã
æãïŒäŸ¡åºïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã¢
ãããŒã§ããã代衚çãªæåãšããŠã¯æ¬¡ã®ãããª
ãã®ãããïŒ
ãåŒã
奜é©æ
æ§ã§ã¯ãArã¯ïŒïŒïŒâããšãã¬ã³ãŸã
ã¯ïŒïŒïŒâããã¿ã¬ã³ã§ããããã®ããªãšã¹ãã«
ã¯ãåã ã§Arãç°ãªãããããåæåãäžèšäž
è¬åŒãæºè¶³ããïŒä»¥äžã®ç°ãªãå埩æåãå«æã
ãŠããŠããããæåã«èšèŒããæåã«é¢ããŠèª¬æ
ããããã«ãAräžã®è³éŠç°ã¯ãå Žåã«ãããã
ãã«çµåããŠããæ°ŽçŽ ååã®å°ãªããšãäžéšã眮
æãããŠãããã®ã§ããããç°çœ®æãå«ãæåã®
äŸã¯ãããšãã«çœ®æãã¬ãã¿ã«é žããèªå°ããã
ãã®ã§ãããç¹ã«å¥œãŸããæåã¯ãåã«ããã¬ã
ã¿ã«é žããã³ïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ãã³é žã
ãèªå°ããããšãã§ããã æ¢è¿°ã®ããã«ãæ¬çºæã§çšããããªãšã¹ãã«ã
圢æããå Žåã«äœ¿çšå¯èœãªå¥ã®ã¢ãããŒã¯ãåŒ ïŒ¹âArââ ïŒåŒäžãArã¯å°ãªããšãïŒã€ã®è³éŠç°ãããª
ãïŒäŸ¡åºãã¯ïŒ¯ãNHãŸãã¯NRãã¯NHãŸ
ãã¯NRãæå³ããã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«
åºãŸãã¯ã¢ãªãŒã«åºã§ããïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã
ã®ã§ãããã¯å¥œãŸããã¯ççŽ æ°ïŒãïŒã®çŽéã¢
ã«ãã«åºãããã«å¥œãŸããã¯ã¡ãã«åºã§ãããã
ã®ã¢ãããŒã¯ãããªããŒé£éã«ã¢ããçµåãäžã
ãããšã«ãªãã奜é©æ æ§ã§ã¯Arã¯ïŒïŒïŒâããš
ãã¬ã³ã§ããããã®ããªãšã¹ãã«ã¯ãåã ã§Ar
ãç°ãªãããããåæåãäžèšäžè¬åŒãæºè¶³ãã
ïŒä»¥äžã®ç°ãªãå埩æåãå«æããŠããŠãããã
æåã«èšèŒããæåã«é¢ããŠèª¬æããããã«ã
Aräžã®è³éŠç°ã¯ãå Žåã«ãããããã«çµåããŠ
ããæ°ŽçŽ ååã®å°ãªããšãäžéšã眮æãããŠãã
ãã®ã§ãããããã®æåãèªå°ããã¢ãããŒã®äŸ
ã«ã¯ãïœâã¢ããããšããŒã«ãïœââã¡ãã«ã¢
ããããšããŒã«ãïœâããšãã¬ã³ãžã¢ãã³ãâ
ã¡ãã«âïœâããšãã¬ã³ãžã¢ãã³ãïŒNâ²âãž
ã¡ãã«âïœâããšãã¬ã³ãžã¢ãã³ãïœâã¢ããã
ãšããŒã«ãïŒâã¡ãã«âïŒâã¢ããããšããŒã«ã
ïŒâã¯ããâïŒâã¢ããããšããŒã«ãïŒâã¢ãã
âïŒâããããŒã«ãïŒâã¢ããâ4â²âããããã·
ãããšãã«ãïŒâã¢ããâ4â²âããããã·ãžããš
ãã«ãšãŒãã«ãïŒâã¢ããâ4â²âããããã·ãžã
ãšãã«ã¡ã¿ã³ãïŒâã¢ããâ4â²âããããã·ãžã
ãšãã«ãšã¿ã³ãïŒâã¢ããâ4â²âããããã·ãžã
ãšãã«ã¹ã«ãã³ãïŒâã¢ããâ4â²âããããã·ãž
ããšãã«ã¹ã«ãã€ããïŒïŒ4â²âãžã¢ããããšãã«
ã¹ã«ãã€ãïŒããªãžã¢ããªã³ïŒãïŒïŒ4â²âãžã¢ã
ããžããšãã«ã¹ã«ãã³ãïŒïŒïŒâãžã¢ãããã«ãš
ã³ãïŒïŒ4â²âãšãã¬ã³ãžã¢ããªã³ãïŒïŒ4â²âãžã¢
ãããžããšããã·ãšã¿ã³çããããç¹ã«å¥œãŸãã
æåã¯ãïœâã¢ããããšããŒã«ããèªå°ããããš
ãã§ããã æ¢è¿°ã®ããã«ãæ¬çºæã§çšããããªãšã¹ãã«ã
圢æããå Žåã«äœ¿çšå¯èœãªããã«å¥ã®ã¢ãããŒ
ã¯ãåŒ ïŒåŒäžãArã¯å°ãªããšãïŒã€ã®è³éŠç°ãããª
ãïŒäŸ¡åºãã¯NHãŸãã¯NRã§ããããã ã
ã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«åºã§
ããïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã¢
ãããŒã§ãããã¯å¥œãŸããã¯ãççŽ æ°ïŒãïŒã®
çŽéã¢ã«ãã«åºãããã«å¥œãŸããã¯ã¡ãã«åºã§ã
ãããã®ã¢ãããŒã¯ãããªããŒé£éã«ã¢ããçµå
ãäžããããã®çš®ã®ã¢ãããŒã¯ããšã¹ãã«åœ¢ææ§
ããã³ã¢ãã圢ææ§åå¿åºãå³å¯ã«åãéã§å«æ
ããŠããããã«ãååŠéè«çã«ããšããšåè¡¡ããš
ããŠããã奜é©æ æ§ã§ã¯ãArã¯ïŒïŒïŒâããšã
ã¬ã³ã§ããããã®ããªãšã¹ãã«ã¯ãåã ã§Arã
ç°ãªãããããåæåãäžèšäžè¬åŒãæºè¶³ããïŒ
以äžã®ç°ãªãå埩æåãå«æããŠããŠããããæ
åã«èšèŒããæåã«é¢ããŠèª¬æããããã«ãAr
äžã®è³éŠç°ã¯ãå Žåã«ãããããã«çµåããŠãã
æ°ŽçŽ ååã®å°ãªããšãäžéšã眮æãããŠãããã®
ã§ãããããã®æåãèªå°ããã¢ãããŒã®äŸã«
ã¯ãïœâã¢ããå®æ¯éŠé žãïœââã¡ãã«ã¢ãã
å®æ¯éŠé žãïœâã¢ããå®æ¯éŠé žãïŒâã¡ãã«âïŒ
âã¢ããå®æ¯éŠé žãïŒâã¯ããâïŒâã¢ããå®æ¯
éŠé žãïŒâã¢ããâïŒâããããšé žãïŒââã¡
ãã«ã¢ããâïŒâããããšé žãïŒâã¢ããâ4â²â
ã«ã«ããã·ãããšãã«ãïŒâã¢ããâ4â²âã«ã«ã
ãã·ãžããšãã«ãšãŒãã«ãïŒâã¢ããâ4â²âã«ã«
ããã·ãžããšãã«ã¹ã«ãã³ãïŒâã¢ããâ4â²âã«
ã«ããã·ãžããšãã«ã¹ã«ãã€ããïœâã¢ããæ¡ç®
é žçããããç¹ã«å¥œãŸããæåã¯ãïœâã¢ããå®
æ¯éŠé žããèªå°ããããšãã§ããã äžã«åæãããããªåŸæ¥å ¬ç¥ã®ãµãŒã¢ãããã
ã¯æ¶²æ¶æ§ããªãšã¹ãã«ããåè¿°ã®æ¹æ³ã«ãã€ãŠç±
çã«å®å®ããå€æ§åœ¢æ ã§è£œé ããããšãã§ããã åè¿°ã®æ¹æ³ã«ããå€æ§å€æ ã§çæãããéåžžã«
ããããããªãšã¹ãã«ããæ¬åºé¡äººã«è²æž¡ããã
ç±³åœç¹èš±ç¬¬4161470ïŒ4184996ïŒ4219461ïŒ
4256624ïŒ4330457ïŒããã³4351917å·ãªãã³ã«æ¬
åºé¡äººã«è²æž¡ãããç±³åœç¹èš±åºé¡ç¬¬485820å·
ïŒ1983幎ïŒæ18æ¥åºé¡ïŒã«é瀺ãããŠãããç±³åœ
ç¹èš±ç¬¬4330457ããã³4351917å·ã®ãµãŒã¢ãããã
ã¯æ¶²æ¶æ§ããªãšã¹ãã«ã¯ãã¢ããçµåãããã«å«
ããã®ã§ããã æ¬çºæã§å©çšããåè¿°ã®æ¹æ³ã«ããã°ããã¹ãŠ
ã®ãšã¹ãã«åœ¢ææ§ããã³ã¢ãã圢ææ§ã¢ãããŒ
ããéåäžã«è³éŠæãžã«ã«ãã³é žã¢ãããŒãã
ã³ïŒãŸãã¯ãã®ãšã¹ãã«åèªå°äœãçŽïŒãïŒã¢ã«
ïŒ ã奜ãŸããã¯çŽïŒãïŒã¢ã«ïŒ éå°ã«ååšããã
ãã«æ éã«èšéããŠåå¿åž¯åã«å ããã奜é©æ æ§
ã§ã¯ãè³éŠæãžã«ã«ãã³é žã¯ãéåäžã«çŽ2.0ã
4.2ã¢ã«ïŒ éå°ãšãªãéã§ååšããããè³éŠæãž
ã«ã«ãã³é žã¢ãããŒïŒããã³ïŒãŸãã¯ãã®ãšã¹ã
ã«åèªå°äœïŒã®ãã®ã¢ã«éå°éããã«ã«ãã³é žå
å¿åºïŒããã³ïŒãŸãã¯ãã®ãšã¹ãã«åèªå°äœïŒã®
å šéãšãããããã·ã«åå¿åºïŒããã³ïŒãŸãã¯ã
ã®ãšã¹ãã«åèªå°äœïŒã«ååšããã°ã¢ãã³åå¿åº
ïŒããã³ïŒãŸãã¯ãã®ã¢ããåèªå°äœïŒãå ãã
ãã®ã®å šéãšã®éã§ååŠéè«çåè¡¡ããšããŠãã
æ®ãã®ã¢ãããŒéã«æ¯ã¹ãŠéå°ã«éååå¿äžã«å
åšãããããšãå¿ é ã§ããã äžèšã®ã¢ã«éå°éã§ååšããã奜ãŸããè³éŠæ
ãžã«ã«ãã³é žã¢ãããŒã¯ããã«ãã¿ã«é žãã€ãœã
ã¿ã«é žãïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ãã³é žãïŒïŒ
ïŒâããã¿ã¬ã³ãžã«ã«ãã³é žãïŒïŒïŒâããã¿ã¬
ã³ãžã«ã«ãã³é žãïŒâããšãã«ãã¬ãã¿ã«é žã
ïŒïŒ4â²âãå®æ¯éŠé žçã§ããã åè¿°ã®æ¹æ³ã«ãããšãéååå¿äžã«ãäžèšã¢ã«
éå°ã§ååšããè³éŠæãžã«ã«ãã³é žã¢ãããŒãã
ã³ïŒãŸãã¯ãã®ãšã¹ãã«åèªå°äœããèªå°ããã
ãžã«ã«ãã³é žåäœã®ããã«ãçæããªããŒã®ããª
ããŒé£éã®å éšã«ãã®åäœãå ¥ããããšåæã«ã
ããªããŒé£éã®æ«ç«¯ã«ã«ã«ãã³é žåºããã³ïŒãŸã
ã¯ãã®ãšã¹ãã«åèªå°äœããããéååå¿ã®é²è¡
ã«ã€ããŠãéå垯åã«ååšããä»ã®ã¢ãããŒã¯å®
å šã«æ¶è²»ãå°œããããåŸãããå¹³åããªããŒéé·
ã¯ãéååå¿äžã«éå垯åã«äŸçµŠãããè³éŠæãž
ã«ã«ãã³é žã¢ãããŒããã³ïŒãŸãã¯ãã®ãšã¹ãã«
åèªå°äœã®ã¢ã«éå°éã«ãã€ãŠçŽæ¥å¶åŸ¡ãããã
ãžã«ã«ãã³é žã¢ãããŒããã³ïŒãŸãã¯ãã®ãšã¹ã
ã«åèªå°äœã®ã¢ã«éå°éãäžèšç¯å²å ã§å€ãã»
ã©ãå¹³åããªããŒéé·ã¯çããªããéã«ããžã«ã«
ãã³é žã¢ãããŒããã³ïŒãŸãã¯ãã®ãšã¹ãã«åèª
å°äœã®ã¢ã«éå°éãäžèšç¯å²å ã§å°ãªãã»ã©ãå¹³
åããªããŒéé·ã¯é·ããªãããããã€ãŠãåèšæ¹
æ³ã«ããã¢ã«éå°éãäžå®ãšããããšã«ãããæ
å®ã®å¹³åéé·ã®ããªããŒçæç©ã圢æããããå€
ãã®å Žåããã®ãããªå¹³åéé·ã¯ãçæããªããŒ
ã®å¯Ÿæ°ç²åºŠæ°ãªãã³ã«ãã®ééå¹³åååéã«ãã
確èªããã®ã奜éœåã§ããããããã«ããŠããç
æãããµãŒã¢ããããã¯æ¶²æ¶æ§ããªãšã¹ãã«ã®ã
ãªããŒé£éã®æ«ç«¯ã«ã¯ãã«ã«ãã³é žæ«ç«¯åºãã
ã³ïŒãŸãã¯ãã®ãšã¹ãã«åèªå°äœãããããã®ã
ããªçæç©ã¯ç±å®å®æ§ã瀺ããããã¯ãæ«ç«¯åºã
ãã¹ãŠé¡äŒŒã®ãã®ã§ããããããã®åŸã«æº¶èå å·¥
枩床ã«å ç±ãããŠããé£æ¥ååéã®éååå¿ã«ã
ããã以äžã®ããªããŒé£éæé·ãå®è³ªçã«äžå¯èœ
ã§ããããã§ããã ãã®ãããªããªãšã¹ãã«ã¯ãçž®ååå¿ã«ããå¿
èŠãªå埩æåã圢æããå®èœåºãæããææ©ã¢ã
ããŒååç©ãåå¿ãããå€æ§ãªãšã¹ãã«åœ¢ææ³ã«
ããçæãããããšãã§ãããäŸãã°ãææ©ã¢ã
ããŒååç©ã®å®èœåºã¯ãã«ã«ãã³é žåºããããã
ã·ã«åºããšã¹ãã«åºïŒäŸãã¢ã·ããã·åºïŒãé žã
ãã²ã³åç©çã§ããããã®ææ©ã¢ãããŒååç©
ã¯ã溶èã¢ã·ããªã·ã¹æ³ã«ããç±äº€ææµäœãååš
ãããã«åå¿ãããããšãã§ããããã®æ¹æ³ã§
ã¯ããŸãææ©ã¢ãããŒååç©ãå ç±ããŠåå¿ç©è³ª
ãã»ãšãã©æº¶èãã溶液ãçæãããããã®æã
ãã¬ãã¿ã«é žã®ãããªäžéšã®åå¿ç©è³ªã¯åœåã¯ã
ãçšåºŠåºäœã«ãšã©ãŸãããã¬ãã¿ã«é žãå°éã§ã
ãã°ããã®ãããªç¶æ³äžã§ã溶解ããããããªã
ãŒçæç©ã¯ãå Žåã«ãããåºäœããªããŒç²åãšã
ãŠæº¶æ¶²äžã«æžæ¿ãããçž®ååå¿ã®æçµæ®µéã«ãã
ãŠãå¯æããæ®çºæ§ç©è³ªïŒäŸãé ¢é žãŸãã¯æ°ŽïŒã®
é€å»ãã®ä»ã«ããéååå¿ã®ä¿é²ã®ããã«ãç空
ãé©çšããŠãããã æ¬åºé¡äººã«è²æž¡ãããç±³åœç¹èš±ç¬¬4067852å·ã«
ã¯ãæ¬çºæã§çšããããªãšã¹ãã«ã®çæã«å©çšã
ãããšã®ã§ããã¹ã©ãªãŒéåæ¹æ³ãèšèŒãããŠã
ãããã®æ¹æ³ã§ã¯åºäœçæç©ã¯ç±äº€æåªè³ªäžã«æž
æ¿ããç¶æ ã§åŸãããã 溶èã¢ã·ããªã·ã¹æ³ãŸãã¯ç±³åœç¹èš±ç¬¬4067852
å·ã®ã¹ã©ãªãŒæ³ã®ããããçšããå Žåã§ããããª
ããŒæåãèªå°ããã¢ãããŒåå¿ç©è³ªã®ãã¡ãä¿
è·ããªããã°ããããã·ã«åºããã³ïŒãŸãã¯ã¢ã
ã³åºãå«æãããã®ã¯ãäºããšã¹ãã«åããŠãã
ããšã奜ãŸãããäŸãã°ããããã¯ççŽ æ°çŽïŒã
ïŒã®äœçŽã¢ã·ã«ãšã¹ãã«ãšããŠåå¿ã«äŸãããã
ãã«å¥œãŸããã¯ããã®ãããªæªä¿è·ã§ã¯ãããã
ã·ã«åºããã³ïŒãŸãã¯ã¢ãã³åºãå«æããã¢ãã
ãŒã®é ¢é žãšã¹ãã«ã䜿çšããããããä¿è·ããå
å¿ç©è³ªã®äŸã¯ãïŒâã¢ã»ããã·âïŒâããããš
é žãïŒâã¢ã»ããã·å®æ¯éŠé žããããããã³ãžã¢
ã»ããŒããïŒïŒ4â²âãããšããŒã«ãžã¢ã»ããŒãç
ã§ããã ãŸããçæããªããŒé£éã«ã«ã«ããã·ã¢ãªãŒã«
åäœãä»äžããã¢ãããŒãäŸãã°ã¢ã«éå°ã«äœ¿çš
ããè³éŠæãžã«ã«ãã³é žã¢ãããŒããåå¿éå§æ
ã«ãšã¹ãã«å圢æ ã§åå¿ã«äŸããŠããããäŸã
ã°ãç±³åœç¹èš±ç¬¬4333907å·ã«èšèŒã®ããã«ããã®
ãããªã¢ãããŒãããšãã°ãããšããŒã«ãïœâã¯
ã¬ãŸãŒã«ãïœâã¯ã¬ãŸãŒã«çã®è³éŠæã¢ãããã
ãã·ååç©ãšåå¿ãããããã®ãããªãšã¹ãã«å
åå¿ç©è³ªã®äŸã¯ãïœâããããã·å®æ¯éŠé žããšã
ã«ãããã³ãã¬ãã¿ã«é žãžããšãã«ã§ããã奜é©
æ æ§ã§ã¯ãåå¿ç©è³ªã®ã«ã«ãã³é žåºã¯ãšã¹ãã«å
ããªãã 溶èã¢ã·ããªã·ã¹æ³ãŸãã¯ç±³åœç¹èš±ç¬¬4067852
å·ã®ã¹ã©ãªãŒæ³ã®ãããã«ãä»»æã«äœ¿çšã§ãã代
è¡šçãªè§Šåªã«ã¯ããžã¢ã«ãã«ã¹ãºãªãã·ãïŒäŸã
ãžããã«ã¹ãºãªãã·ãïŒããžã¢ãªãŒã«ã¹ãºãªãã·
ããäºé žåãã¿ã³ãã¢ã«ã³ãã·ãã¿ã³ã·ãªã±ãŒ
ãããã¿ã³ã¢ã«ã³ãã·ããã«ã«ãã³é žã®ã¢ã«ã«ãª
ããã³ã¢ã«ã«ãªåé¡éå±å¡©ãã«ã€ã¹é žïŒäŸã
BF3ïŒãããã²ã³åæ°ŽçŽ ïŒäŸãHClïŒçã®ã¬ã¹ç¶
é žè§Šåªãªã©ãããã觊åªã®äœ¿çšéã¯ãäžè¬ã«ã¢ã
ããŒã®å šééã«åºããŠçŽ0.001ãïŒééïŒ ãç¹ã«
çŽ0.01ã0.2ééïŒ ã§ããã æ¬åºé¡äººã«è²æž¡ãããç±³åœç¹èš±ç¬¬4393191ïŒ
4395536ïŒ4421908ïŒããã³4429105å·ã®éåæ¹æ³
ããæ¬çºæã§å©çšããããªãšã¹ãã«åœ¢ææ³ãå®æœ
ããã®ã«é©ããŠããã ç¹ã«å¥œãŸããæ æ§ã«ãããŠã溶èå å·¥æ§ããªã
ãŒãç±³åœç¹èš±ç¬¬4161470å·ã®å šè³éŠæããªãšã¹ã
ã«ãå€æ§ãããã®ã§ããå Žåããã®å€æ§ããªãšã¹
ãã«ã¯ãæ¬è³ªçã«äžèšæåããã³ïŒ ãããªããæåãçŽ20ã45ã¢ã«ïŒ ããã³æå
ãçŽ55ã85ã¢ã«ïŒ ã®éã§å«æããããªãšã¹ãã«ã
çæãããããªãšã¹ãã«åœ¢ææ§ã¢ãããŒãéå垯
åã§éååå¿ãããŠåŸããã®ã§ããããã®éã«å
èšéååå¿äžã«çŽïŒãïŒã¢ã«ïŒ éå°ã®è³éŠæãžã«
ã«ãã³é žã¢ãããŒãéå垯åã«ååšããããã®é
å°ã¢ãããŒã«ãããéååå¿äžã«çæããªããŒã®
ããªããŒé£éã®å éšã«ãžã«ã«ããã·ã¢ãªãŒã«åäœ
ãä»äžããããšå ±ã«ãããªããŒé£éã®æ«ç«¯ãã«ã«
ãã³é žæ«ç«¯åºãšãªããããªããŒé£éãéå垯åã«
ååšããä»ã®ã¢ãããŒã®æ¶èã«ãã€ãŠå¿ èŠãªåå
éã«å°éãããããåŸãããå šè³éŠæããªãšã¹ã
ã«çæç©ã¯ãã®åŸã«å ç±ãåããŠããã以äžã®é£
éæé·ãå®è³ªçã«äžå¯èœãšãªã€ãŠããã å¥ã®ç¹ã«å¥œé©ãªæ æ§ã«ãããŠã溶èå å·¥æ§ããª
ããŒãç±³åœç¹èš±ç¬¬4330457å·ã®ã¢ããçµåããã
ã«æããå šè³éŠæããªãšã¹ãã«ãå€æ§ãããã®ã§
ããå Žåããã®å€æ§ããªãšã¹ãã«ã¯ãæ¬è³ªçã«äž
èšæåããããã³å Žåã«ããïŒåŒäžãå
èšå·Arã¯å°ãªããšãïŒã€ã®è³éŠç°ãããªãïŒäŸ¡
åºïŒïŒ ïŒââArââ ïŒåŒäžãã¯ïŒ¯ãNHãŸãã¯NRãã¯NHãŸ
ãã¯NRãæå³ããã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«
åºããŸãã¯ã¢ãªãŒã«åºã§ããïŒã ïŒââArââ ãããªããæåãçŽ40ã80ã¢ã«ïŒ ãæåãçŽ
ïŒã30ã¢ã«ïŒ ãæåãïŒã30ã¢ã«ïŒ ãããã³æ
åãçŽïŒã25ã¢ã«ïŒ ã®éã§å«æããããªïŒãšã¹
ãã«âã¢ããïŒãçæãããããªãšã¹ãã«åœ¢ææ§
ããã³ã¢ãã圢ææ§åå¿ã¢ãããŒãéå垯åã§é
ååå¿ããåŸããã®ã§ããããã®éã«åèšéåå
å¿äžã«çŽïŒãïŒã¢ã«ïŒ éå°ã®è³éŠæãžã«ã«ãã³é ž
ã¢ãããŒãéå垯åã«ååšããããã®éå°ã¢ãã
ãŒã«ãããéååå¿äžã«çæããªããŒã®ããªããŒ
é£éã®å éšã«ãžã«ã«ããã·ã¢ãªãŒã«åäœãä»äžã
ãããšå ±ã«ãããªããŒé£éã®æ«ç«¯ãã«ã«ãã³é žæ«
端åºãšãªããããªããŒé£éãéå垯åã«ååšãã
ä»ã®ã¢ãããŒã®æ¶èã«ãã€ãŠå¿ èŠãªååéã«å°é
ãããããåŸãããå šè³éŠæããªïŒãšã¹ãã«âã¢
ããïŒçæç©ã¯ãã®åŸã«å ç±ãåããŠããã以äž
ã®é£éæé·ãå®è³ªçã«äžå¯èœãšãªã€ãŠããã ç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªããŒ
ããååºã®ç±³åœç¹èš±åºé¡ç¬¬517865å·ã®æ¹æ³ã«ãã
圢æããå Žåããã®ããªããŒã¯ãç²åç¶ç¡æ©ææ
ãšæ··åããåã§ã3.0dlïŒïœä»¥äžãç¹ã«çŽ0.8ã3.0
dlïŒïœã®å¯Ÿæ°ç²åºŠæ°ïŒãã³ã¿ãã«ãªãããšããŒã«
ã«0.1ééïŒ ã®æ¿åºŠã§æº¶è§£ãããŠ60âã§æž¬å®ãã
å€ïŒã瀺ãã®ã奜ãŸããããã ããå¿ ããããã¹
ãŠã®ããªããŒçæç©ãããã®å¯Ÿæ°ç²åºŠæ°ã®æž¬å®ã
è¡ãã®ã«å åãªã»ã©ãã³ã¿ãã«ãªãããšããŒã«ã«
å¯æº¶ã§ããããã§ã¯ãªãã å ç±ã«ãããã以äžã®é£éçé·ãå®è³ªçã«äžå¯
èœã§ãããæ¬çºæã®æ¹æ³ã«äœ¿çšã§ããç°æ¹æ§æº¶è
çžã圢æããã溶èå å·¥æ§ããªããŒã圢æããã
ãã®ä»ã®ä»£è¡šçãªæ¹æ³ã¯ãæ¬åºé¡äººã«è²æž¡ããã
ç±³åœç¹èš±åºé¡ç¬¬595004å·ïŒ1984幎ïŒæ29æ¥åºé¡ïŒ
ããã³ç±³åœç¹èš±åºé¡ç¬¬611299å·ïŒ1984幎ïŒæ17æ¥
åºé¡ïŒã«é瀺ãããŠããã æ¬çºæã§çšãã溶èå å·¥æ§ããªããŒã¯ãç²åç¶
ç¡æ©ææãšæ··åããåã«ã溶èå 工枩床ïŒäŸã
300âã310âã320âãŸãã¯330âïŒããã³åªæé
床100sec-1ã«ãããŠãçŽ30ã300ãã¢ãºã®æº¶èç²
床ã瀺ãã®ã奜ãŸããããã®æº¶èç²åºŠã®æž¬å®ã¯ã
é·ãïŒã€ã³ãïŒ10cmïŒãå åŸ30ãã«ïŒ762ÎŒïŒã®æ¯
现管ãåããã€ã³ã¹ããã³æ¯ç®¡ã¬ãªã¡ãŒã¿ãçšã
ãŠæšæºç枬å®æ³ã«ããå®æœã§ããããŸãã¯ãã¬ãª
ã¡ããªãã¯ã¹è³ªéåæèšãå©çšããå¹³è¡æ¿ã䜿ã€
ãåªæé床10sec-1ã®å®åžžåªæã¢ãŒãã§æº¶èç²åºŠ
ã枬å®ããŠãããã溶èå å·¥æ§ããªããŒã¯ã溶è
ç²åºŠæž¬å®æç¹ã§ã¯å®å šãªæº¶èç¶æ ãšããã300â
ã§æº¶èç²åºŠæž¬å®ãè¡ãå Žåã«ã¯ãããªããŒããŸã
çŽ320âã«å ç±ããåŸã溶èç²åºŠã®æž¬å®æž©åºŠã§ã
ã300âã«å·åŽããæ¹ããããå質ãªæº¶èäœãåŸ
ãããã æ¬çºæã§äœ¿çšãã溶èå å·¥æ§ããªããŒã¯ããã®
åæçµè·¯ã®åŠäœã«ããããããç²åç¶ç¡æ©ææãš
æ··åããåã«çŽ200ã480âãç¹ã«çŽ200ã350âã®
ç¯å²å ã®æž©åºŠã§å¿ èŠãªç°æ¹æ§æº¶èçžã圢æã§ãã
ãã®ã§ããã®ã奜ãŸããããã®æº¶èå å·¥æ§ããªã
ãŒã¯ã害ãåãŒãçšã®å€Ÿéç©ãå«æãã¹ãã§ãª
ãã奜ãŸããã¯æ¬è³ªçã«äžçæ§ã§ããããå ïŒç¹
ã«çŽ«å€ç·ïŒã溶å€ãè¬åããªãã³ã«å°å ¥æ圢é»å
éšåã®åœ¢æãçµç«ããã³é·æ䜿çšäžã«ééããç°
å¢ã«å¯ŸããŠèæ§ã瀺ãã æ¬çºæã®æ圢ææã®ç¬¬ïŒã®å¿ é æåã¯ãç²åç¶
ç¡æ©ææïŒããªãã¡ãç¡æ©å å¡«æïŒã§ããããã®
ç²åç¶ç¡æ©ææã¯ãåè¿°ã®æº¶èå å·¥æ§ããªããŒã«
å®è³ªçã«åäžã«åæ£ããããããã®æº¶èå å·¥æ§ã
ãªããŒïŒããªãã¡ãç²åç¶ç¡æ©ææãå«ãŸãªãçµ
æç©ïŒã®äœç±èšåŒµçãäœäžããããšå ±ã«ããã®ç±
äŒå°çãå¢å ãããããšãã§ãããã®ã§ãããç²
åç¶ç¡æ©ææã®ååšã¯ãæçµè£œåã®äœç±èšåŒµçã
æ¬è³ªçã«ããçæ¹æ§ã«ããäœçšããããç²åç¶æ
æã¯ãäºé žåã±ã€çŽ ãã¿ã«ã¯ããŠãªã©ã¹ããã€
ããã¢ã«ãããã³ãŒãžãšã©ã€ãçã®å€æ§ãªåºäœç¡
æ©ææããéžæãããããããçš®ã®åœ¢æ ã®äºé žå
ã±ã€çŽ ã奜ãŸãããç²åç¶ç¡æ©ææã¯ãééå¹³å
ç²åºŠãçŽïŒã50ÎŒã§ãç²åã®å°ãªããšã99ééïŒ
ã100ÎŒæ«ç«¯ã§ãããã®ã奜ãŸããããã®ç²åºŠæž¬
å®çšã«é©ããç²åºŠåæè£ çœ®ã¯ãç±³åœãžãšãŒãžã¢å·
ããŒã¯ãã¹ã®Micrometrics Lnstrument瀟ãã
ã³ãããªãå·ã»ã³ãããŒã¿ãŒã¹ããŒã°ã®Leeds
and Northrup瀟ããåžè²©ãããŠãã
ïŒMicrotracç²åºŠåæåšïŒããŸããç²åç¶ç¡æ©ææ
ã¯ãæ圢åŸã«åãåãã«æŽåããç²åã«ããç±èš
匵çã«ç°æ¹æ§ãçããŠããæãããªãããã«ãå š
æ¹åã«ãããŠå®è³ªçã«åäžå¯žæ³ã®ãã®ã§ããã®ã
奜ãŸããããããã€ãŠãç²åç¶ç¡æ©ææã®å¹³åã¢
ã¹ãã¯ãæ¯ã¯ãæ £çšã®å åŠé¡åŸ®é¡ã«ãã枬å®ã§
ïŒïŒïŒä»¥äžãšãªãã®ã奜ãŸããã ç²åç¶ç¡æ©ææã¯ãé»åéšåã®åäœã«æ害ãŸã
ã¯ããã劚害ããæãã®ããæ害éã®å€Ÿéç©ãå«
ãŸãªãããšãäžå¯æ¬ ã§ãããå¯åçã«äœç±èšåŒµç
ãäœãã®ã奜ãŸããããã®ãããç³è±ã¬ã©ã¹ãæ¬
çºæã§çšããã®ã«ç¹ã«å¥œãŸããç²åç¶ç¡æ©ææãš
ãªããåšç¥ã®ããã«ãç³è±ã¬ã©ã¹ã¯ãäžè¬ã«ã¯é»
æ°ã¢ãŒã¯æº¶èã«ããéåžžã«é«ã枩床ãå©çšããŠé
åžžã®çµæ¶è³ªããéæ¶è³ªã«è»¢åãããæ¯èŒççŽç²ãª
äºé žåã±ã€çŽ ãããªãããã®ç²åç¶ç¡æ©ææã¯ã
溶èã·ãªã«ãŸãã¯æº¶èç³è±ãšãåŒã°ãããåŸãã
ã溶èç²åã¯ããã®çæåŸã«ææã®ç²èªåºŠãŸã§åŸ®
ç²ç ããããã®ææã¯ãäœç±èšåŒµçãäºå®äžãŒã
ã§ãããæ¥éãã€æ¥µç«¯ãªæž©åºŠå€åãåããŠãå éš
å¿åãçããªãããã®ãããªç³è±ã¬ã©ã¹ã¯åžè²©ã
ããŠãããç±³åœãã³ã·ã«ããã¢å·ãããããŒã°ã®
HarbisonâWalker Refractories瀟ããGP7Iã®
åååã§å ¥æããããææã«ãããç±äŒå°çãã
ãã«å€§ããããããã«ãå°éã®çµæ¶æ§ã·ãªã«ã溶
èã·ãªã«ã«é åããŠãããããã ããçµæ¶æ§ã·ãª
ã«ã®é åã«ããçµæç©å šäœã®äœç±èšåŒµçãããçš
床å¢å ããåŸåããããå°å ¥æ圢ããé»åéšåã
ç¹ã«èããã®ã§ãªãå Žåã«ã¯ãç²åç¶ç¡æ©ææã«
äžé£ç¶ç¶ã¬ã©ã¹ç¹ç¶ãªã©ã®ç¹ç¶ç¶è£åŒ·æãé åã
ãŠãããããŸããæ圢ææã«å¯ŸããŠæ害ãªåœ±é¿ã
åãŒããªãéããçè²å€ãæ·»å å€ãå®çå€ãé¢å
å€çãé åããŠãããã 奜é©æ æ§ã§ã¯ãç²åç¶ç¡æ©ææã®è¡šé¢ã«ã¯ãç°
æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªããŒãšã®
æ··ååãé«ãã被èŠãããã«æœããããŠããã䜿
çšè¢«èŠå€ã¯ãé»åéšåãæãªã€ãããé»åéšåã®
䜿çšæã®åäœã劚ããå¯èœæ§ã®ãããã®ã§ãã€ãŠ
ã¯ãªããªãã代衚çãªè¢«èŠæã¯ããŠããªã³ã«ãŒã
ã€ã瀟ããããããA187ããã³A1100ãšããŠåž
販ãããŠããγâã°ãªã·ããã·ãããã«ããªã¡ã
ãã·ã·ã©ã³ããã³Î³âã¢ãããããã«ããªãšãã
ã·ã·ã©ã³ãªã©ã®ã·ã©ã³é¡ã§ããããã®ã·ã©ã³åå
ç©ã¯ãç¡æ©å å¡«æã®æšæºçãªè¢«èŠæè¡ã«ãããçŽ
0.5ã1.5ééïŒ ã®éã§è¡šé¢è¢«èŠæãšããŠç²åç¶ç¡
æ©ææã«è¢«èŠããããšãã§ãããææ©ãã¿ããŒã
系衚é¢è¢«èŠæããç°æ¹æ§æº¶èçžã圢æããã溶è
å å·¥æ§ããªããŒææãšæ··åããåã®ç¡æ©ç²åã«å
æ§ã«è¢«èŠãããã æ¬çºæã«ãããšãç²åç¶ç¡æ©ææã¯ãæ圢ææ
ã®å šééã«åºã¥ããŠçŽ40ã80ééïŒ ãç¹ã«ãçŽ50
ã75ééïŒ ïŒäŸãçŽ55ã70ééïŒ ïŒã®éã§ãç°æ¹
æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªããŒã«é å
ããããã®å éšã«å®è³ªçã«åäžã«åæ£ããããã
ã®å®è³ªçã«åäžãªåæ£ã¯ã移åããŠãã溶èããª
ããŒææã®å éšã«ç²åç¶ææãæŒã蟌ãå ¬ç¥ã®æ
è¡ã«ããéæã§ãããäžè»žæŒåºæ©ãåæ¹åå転äº
軞æŒåºæ©ãéå転äºè»žæŒåºæ©ãæ··ç·Žæ©çãçšãã
å ¬ç¥ã®æº¶èé åæè¡ãæ¡çšã§ãããäŸãã°ãç±³åœ
ããŠãŒãžã€ãŒãžãŒå·ã©ã ãŒãŒã®Werner ïŒ
Pfleiderer瀟補ã®åæ¹åå転äºè»žæŒåºæ©ã䜿çšã§
ããããã®ãããªè£ 眮ã䜿çšããå Žåãäºã圢æ
ããããªããŒãã¬ãããšç²åç¶ç¡æ©ææã也åŒã
ã¬ã³ããšããŠæŒåºæ©ã«äŸçµŠããããªããŒææã®æº¶
è枩床ããé«æž©ã«å ç±ããã ãã§ãããé åãä¿
é²ããããã«ãæ··ç·Žãããã¯ãã¹ã¯ãªãŠãŒå ã«é
眮ããã®ãæå©ã§ãããç²åç¶ç¡æ©ææãé«ãé
åå²åã§å°å ¥ããå Žåã«ã¯ãå€æ®µãã¹ïŒäŸãïŒã
ã¹ä»¥äžã®ïŒé åæäœãæ¡çšããæåã®ãã¹ã§ã¯ç²
åç¶ç¡æ©ææã®äžéšã®ã¿ãå°å ¥ããããã«ããŠã
ãããæãã¯ãç°æ¹æ§ã¡ã«ã圢ææ§ããªããŒãšç²
åç¶ç¡æ©ææãšã®ãã¬ã³ãã®èª¿è£œã¯ãç±³åœã€ãªã
ã€å·ãšã«ã¯ã°ããŒããã¬ããžã®BussâCondux瀟
補ã®BussâCondux ããŒããŒã®ãããªé åæŒåº
æ©ãŸãã¯ç²åã®äžæµåŽæ·»å ãå¯èœãªãã®ä»ã®æŒåº
æ©ãçšããŠãäžæµåŽã«èšããïŒä»¥äžã®äŸçµŠå£ã«ç²
åãäŸçµŠããããšã«ãããç¡æ©ææã®å šéã溶è
ããªããŒã«å ããããšã«ãã€ãŠãå®æœã§ãããã
ã®æ¹æ³ã§ã¯ãããªããŒãæŒåºæ©ã®åŸéšãžäŸçµŠãã
溶èãããåŸãç²åãšé åãããã©ã¡ãã®çš®é¡ã®
é åæ¹æ³ã§ããåŸãããæ圢ææã¯ãã¹ãã©ã³ã
æ³ãããã¯ãã€ããšãŒã¹æ³ã®ããããã®ãã¬ãã
補é æ³ãçšããŠãã¬ããåã§ãããã¹ãã©ã³ãæ³
ã§ã¯ãåŸãããæ圢ææã®ã¹ãã©ã³ããæŒåºãã
空å·éšãééåŸã«ãã¬ããåããã溶èæŒåºã¹ã
ã©ã³ãã¯ãæŒåºæ©ãšãã¬ããåæäœã®éãã³ã³ã
ã€ãŒã§æ¬éãããããã€ããšãŒã¹ã«ãã¿ãŒã䜿çš
ããå Žåãæ圢ææã¯ãã€ã®åé¢ã§ãã¬ããã«å
æããã次ãã§ãã®ãã¬ãããæ°Žäžã«èœããŠå·åŽ
ããæ¹æ³ã§ããã ç²åç¶ç¡æ©ææã¯ãäœç±èšåŒµçãæžå°ãããç±
äŒå°çãå¢å ãããããã«çšãããç²åç¶ç¡æ©æ
æã®é åå²åãæ圢ææã®å šééã«å¯Ÿã40ééïŒ
ããäœããšãäœç±èšåŒµçã倧ãããããŸãç±äŒå°
çãå°ããããåŸåãããã80ééïŒ ãè¶ ãã
ãšãåŸãããæ圢ææã®æº¶èç²åºŠã倧ãããªãåŸ
åããããå°å ¥å€ã®ç©ççæ§è³ªãå£ããææã®ç±
èšåŒµããã³ç±äŒå°æ§ãåŸãããªãã åŸãããæ圢ææã¯ãäžè¬ã«çŽ250ã390âã®ç¯
å²å ã®æž©åºŠã§å°åºæ圢ããããšãã§ããããŸãã
åŸãããæ圢ææã®æ°Žæœåºæ§ã¢ã«ã«ãªéå±ïŒäŸã
Naããã³ïŒ«ïŒã®å«æéã¯50ppmæªæºãæ°Žæœåºæ§
ããã²ã³ïŒäŸãClãBrãïŒã®å«æéã¯100ppm
æªæºã§ããããšã奜ãŸããããããã€ãŠãããçš®
ã®å°å ¥æ圢é»åéšåã®åäœäžã«ãã°ãã°å¿ èŠãšãª
ã粟å¯ãªé»æ°çãã©ã³ã¹åè¡¡ã劚害ãããããªåž¯
é»äžçŽç©ã¯ååšããªããæ°Žæœåºæ§ã¢ã«ã«ãªéå±ã
ãã³ããã²ã³ã®å«æéã®æž¬å®ã¯ãç±³åœåå°äœè£ 眮
ããã³ææåäŒïŒSEMIïŒåãSEMIèŠæ Œã第ïŒ
å·»ãããã±ãŒãžéšäŒããã€ãªã³æ§ååŠçš®ã®æšå¥šã
ããæ°Žæœåºæ³ãïŒG5.3ç¯ïŒïŒ1983ïŒã«ãããã€ãŠ
å®æœã§ããã æ¬çºæã«ããé»åéšåã®å°å ¥æ圢ãå®æœããã«
ã¯ãäºã圢æããé»åéšåããé»åéšåçšã®åŸæ¥
ã®å°åºããã±ãŒãžæè¡ïŒãã©ã³ã¹ãã¢ãŒæ圢æ³ã
å«ããïŒãšå šãåæ§ã®æ¹æ³ã§ãéåãã€ããã€å
ã«é 眮ïŒããªãã¡ãåºå®ïŒãããææã«ãããé»
åéšåãïŒåã¥ã€åå¥ã«å°å ¥æ圢ããæ°ååéå
ã«å€æ°ã®é»åéšåãäžåºŠã«ãããããšãã§ããã
次ã«ãé«æž©ã®æ¬çºæã®æ圢ææãã溶èå å·¥æ§ã
ãªããŒã溶èç¶æ ã«ãããç²åç¶ç¡æ©ææããã
ã«åæ£ããŠããç¶æ ã§å°åºããŠé»åéšåãå ¥ãã
éåãã€ããã€å ã«å®å šã«æºããããã ããé»å
éšåã®ãã¡ã®ç¹å®ã®éšåãäŸãã°é»æ°æ¥ç¶ç¹ãã¯
æ圢ææã§å å²ããéšåã®å€åŽãžçªåºããŠããŠã
ããã æ圢ææã®æ¶²æ¶æ§ããªããŒãéåãã€ããã€å
ã«å°åºããããšããã®ååã¯ãæ¯èŒçäœååéã§
ããã«ãããããããå°å ¥å€ã«æçµçã«åŒ·åºŠãã
ã³åæ§ãä»äžããããã«å±éšçã«é åããåŸåã
æ¬è³ªçã«ç€ºããšèããããããã®æº¶èããªããŒã®
æµåã®çµæãã®é åã¯å®¹æã«çããããã®å±éšç
é åã¯ããã®ãããªããªããŒã瀺ãç·©åæéãé
åžžã«é·ãããã«ãåºåã®åã«èãã倱ãããããš
ã¯ãªãããããã€ãŠãæçµè£œåã®æ©æ¢°çæ§è³ªã¯ã
æ圢ææäžã®æº¶èããªããŒã®ãµãŒã¢ããããã¯ãš
ããæ§è³ªã«ãã€ãŠæå©ãªåœ±é¿ãåããã æ¬çºæã®æ圢ææã¯å°åºæ圢枩床ã«ãããŠåªæ
é床100sec-1ã§çŽ300ã2500ãã¢ãºã®ç¯å²å ã®æº¶
èç²åºŠã瀺ãã®ã奜ãŸãããç¹ã«ãã®æ¡ä»¶äžã§çŽ
300ã1500ãã¢ãºã®ç¯å²å ã®æº¶èç²åºŠã瀺ãã®ã
奜ãŸããã æ圢ææã®æ圢é©æ§ãè©äŸ¡ããå¥ã®æ¹æ³ã¯ã
ASTM D3123â72ã®ã¹ãã€ã©ã«ãããŒè©Šéšã«èš
èŒã®æ¹æ³ã§ãããããã ããã®è©Šéšæ³ãã次ã®ã
ãã«å€æŽããïŒæ £çšã®å°åºæ圢æ©ãšãçŽåŸ1/4ã€
ã³ãïŒ6.4mmïŒã®åå圢åã®ãããŒé·ã50ã€ã³ã
ïŒ127cmïŒã®ã¹ãã€ã©ã«ãããŒéåã䜿çšãéåæž©
床100âãããã³å°åºå§8000psiïŒ560KgïŒcm2ïŒãã
ã®æ¡ä»¶äžã§åŸããã溶èããªããŒã®å žåçãªãã
ãŒé·ãã¯ãæ®éçŽ10ã45ã€ã³ãïŒ25ã114cmïŒã®
ç¯å²å ã§ããããããŒé·ãã®é·ãããªããŒã»ã©ã
粟å¯ãªé»åéšåã®å°å ¥æ圢ã«é©ããŠããã éåãã€ããã€å ã®æ®ã空éã®æ圢ææã«ãã
å å¡«é床ã¯ãé»åéšåã®å¯žæ³ããã³æ§é ç¹æ§ã«ã
ãå·Šå³ããããïŒåæªæºïŒäŸãçŽ15ã50ç§ïŒã®å š
æ圢ãµã€ã¯ã«æéã®ç¯å²å ã§ã¯ãçŽïŒã15ç§ã®é
åå å¡«æéãäžè¬ã«æ¡çšãããéç©åè·¯ããã€ã¹
ã®ãããªæ¯èŒç粟å¯ãªé»åéšåã¯ãåäžæ©èœãã©
ã³ãžã¹ã¿ãªã©ã®ããé äžãªé»åéšåãããå®è³ªç
ã«é ãå å¡«é床ãå¿ èŠãšããããšãå€ããå°å ¥æ
圢ãåããŠããé»åéšåã®åéšã害ãåºãã»ã©å€
圢ãããªãããã«æ³šæããããããã®å Žåããã
ã®é»åéšåãæå·ããªãããšãããã€ãŠããç¯å²
å ã§æå°ã®éåãã€ããã€å å¡«æéãéžæããã®
ã奜ãŸããã æ圢ææã«ããéåãã€ããã€ã®å®å šãªå å¡«ãš
ããã«ããäžééæ§å°å ¥æ圢ã®éè¡ã容æã«ãã
ããã«ãå å¡«æã«éåèªèº«ãé«æž©ãšããã®ã奜ãŸ
ããããã®çµæãæ圢ææãéåãã€ããã€ãå®
å šã«å å¡«ããåã«ããããã®é床ã®å·åŽãé²æ¢ã
ãããéåå å¡«å·¥çšã«ãããéå枩床ãšæ圢ææ
ã®æž©åºŠã®éžæã¯ãç°æ¹æ§æº¶èçžã圢æããã溶è
å å·¥æ§ããªããŒã®æº¶è枩床ããã³å®¹æã«éåãã€
ããã€ã®å®å šå å¡«ãéæããã溶èç²åºŠãåŸãã®
ã«å¿ èŠãªæž©åºŠã«äŸåããããã ãããã®æº¶èç²åºŠ
ã¯ãæ圢ææäžã«åæ£ããŠããç²åç¶ç¡æ©ææã®
éãšç²åºŠååžããªãã³ã«æº¶èå å·¥æ§ããªããŒã®é
éå¹³åååéã«äŸåãããå ·äœçãªå°å ¥æ圢æäœ
ã«å¯Ÿããäžèšãã©ã¡ãŒã¿å ã§ã®æé©æ¡ä»¶ã®æ±ºå®ã¯
æ¥åžžå®éšã«ããå®æœã§ãããã®æ¡ä»¶ã¯äœ¿çšããé
åã®èšèšã«é¢ãã幟äœåŠçå åïŒäŸãã²ãŒã寞
æ³ãã©ã³ããŒé·ãããã³å¯žæ³ãã®ä»ïŒã«äŸåã
ããäžè¬ã«ãéåãã€ããã€ã¯çŽ100ã250âã®æž©
床ãšããéåãã€ããã€ãžã®æ圢ææã®å°å ¥ã¯ã
枩床çŽ250ã390âãããã³å§åçŽ100ã1000psi
ïŒ7.0ã70KgïŒcm2ïŒã§è¡ãã å°å ¥æ圢ãå®æœããããã®ä»£è¡šçãªè£ 眮ã«ã¯ã
(1)åç· å35ãŸãã¯40ç±³ãã³ïŒ31.8ãŸãã¯36.3tïŒã®
ïŒãŸãã¯ïŒãªã³ã¹ïŒ28ãŸãã¯56ïœïŒArburg220å
ã¹ã¯ãªãŠãŒå°åºæ圢æ©ãããã³(2)åç· å80ç±³ãã³
ïŒ73KgïŒã®ïŒãªã³ã¹ïŒ142ïœïŒWindson HSI80å
ã¹ã¯ãªãŠãŒå°åºæ圢æ©ããããããã»ã¹å¶åŸ¡è£ 眮
ã䜿çšããŠãå°åºæ圢ã©ã ã®æ£åž°éäœçœ®æ±ºãå¶åŸ¡
ãè¡ããããã«ãããäžè¬ã«æ¡çšãããæ¯èŒçäœ
å§ã§ã®å°åºãèæ ®ããŠå å¡«é床ãå¶åŸ¡ããã®ãæ
å©ã§ãããæµå ¥å§ãæžå°ãããæ圢工çšã容æã«
ããã«ã¯ãçãã©ã³ããŒãšå€§ããã®ã²ãŒãã䜿çš
ãããšããã éåãæ圢ææã§å®å šã«å å¡«ãããåŸãæ圢æ
æã¯éåå ã§åºåããé»åéšåã®æå®éšåã®åšå²
ã«äžééæ§ã®ããã±ãŒãžã圢æãããã䜿çšããª
ããŒã¯ç±çã«å®å®ã§ãããæ圢äœæ¥äžã«ãå®è³ªç
ã«ããã«éååå¿ãŸãã¯å解åå¿ãçããå Žåã«
èªãããããããªãæ®çºæ§ã®ãã€ã圢ææ§æåã®
çºçãå®è³ªççšåºŠã«èµ·ããããšã¯ãªããæ圢ææ
ã®æº¶èç²åºŠã¯å®è³ªçã«ã«äžå®ã®ãŸãŸã§ããããã®
çµæãäžééæ§å°å ¥æ圢ã確ä¿ãããããã®ã
ããéåãã€ããã€å ã§ã®ããªããŒã®åºåã«ç¶ã
ããªããŒç¡¬åå·¥çšãèšããå¿ èŠã¯ãªãã å°åºæ圢åŸã®æ¬çºæã®æ圢ææã¯ã奜ãŸããã¯
60ã110âã«ãããŠ150Ã10-6cm3ïŒcm3ââ以äžã®äœ
ç±èšåŒµçã瀺ããæã奜ãŸããã¯åæ¡ä»¶äžã§90Ã
10-6cm3ïŒcm3ïŒââ以äžã®äœç±èšåŒµçã瀺ããã»ãš
ãã©ã®é»åããã€ã¹ã¯äœ¿çšäžã«ããããçºç±ãã
çºçããç±ã«ããçããå¿åãçã ããå Žåã«
ã¯ãããšããšäžééæ§ã§ãã€ãå°å ¥æ圢åã®ã²ã³
å²ããèµ·ãã€ãŠããã®ç Žæãçããããšãããã
ããæ¬çºæã®æ圢ææã®äœç±èšåŒµçãäœãããšã¯
éèŠã§ããããŸããäžèšå¿åã«ããããã³ãã€ã³
ã°ã¯ã€ã€ãéç©åè·¯ãããããåŒæããããã¯ã€
ã€ãã³ããç²åŽããç Žæãããããããã¯åè·¯å°
ç·ããããã§éç©åè·¯ãããã®è¡šé¢ãããšããã
ããããšããããäœç±èšåŒµçã®å€ã¯ãæ圢ææã®
ç²åç¶ç¡æ©ææã®é åéãå¢ãããšå°ãããªãã
ãŸãç²åç¶ç¡æ©ææã¯ãããªããŒææã®äœç±èšåŒµ
çãæ¬è³ªçã«ããçæ¹æ§ã«ããäœçšãããããã®
äœç±èšåŒµçã®æž¬å®ã¯ãååºã®ç±³åœSEMIèŠæ Œã第
ïŒå·»ãããã±ãŒãžéšäŒããæ圢ææã®èšåŒµç¹æ§ã®
è©Šéšæ³èŠæ ŒãïŒG5.4ç¯ïŒïŒ1983ïŒã«ãããã€ãŠå®
æœã§ããã å°åºæ圢åŸã®æ¬çºæã®æ圢ææã¯ãæ¯èŒçåºã
枩床ç¯å²ïŒäŸãâ40âãïŒ150âïŒã«ããã€ãŠè¯å¥œ
ãªç±èšåŒµæ§ã瀺ãããã®ãããªæ§è³ªã¯ãã¬ã©ã¹è»¢
移枩床ããé«æž©ã§ã¯ç±èšåŒµã倧ãããªããšããã·
æš¹èã瀺ãæ§è³ªããå®è³ªçã«åªããŠããã å°åºæ圢åŸã®æ圢ææã¯ã10Ã10-4calâcmïŒ
secâcm2ââ以äžãç¹ã«13Ã10-4calâcmïŒsecâ
cm2ââ以äžã®ç±äŒå°çã瀺ãã®ã奜ãŸãããé«æž©
ã«ãªããšé»åéšåã«ãã€ãŠã¯ãã®æ§èœã«æªåœ±é¿ã
åºãããšãããã®ã§ããã®ããã«ç±äŒå°çã倧ã
ãããšã¯éèŠã§ãããäŸãã°ãç±ã«ãã€ãŠéç©å
è·¯ã®åäœã®é床ãé ããªãããšãç¥ãããŠããã
ãã®ãããçºçããç±ã¯å¹æçã«æŸæ£ãããªãã°
ãªããªããæ圢ææäžã®ç²åç¶ç¡æ©ææã®é åé
ãå€ãã»ã©é«ãç±äŒå°çã®å€ãåŸããããç±äŒå°
çã®æž¬å®ã¯ãç£æ¥çã§æ £çšã®æšæºçãªæ¹æ³ã«ãã
å®æœã§ããã æ¬çºæã®æ圢ææã¯ãå°åºæ圢åŸã«ãULâ94
è©Šéšã«ãã€ãŠïŒ¶âã®ççŒè©äŸ¡ã瀺ãããšããŸã
奜ãŸããããã®ULâ94è©Šéšãè¡ãå Žåãæ圢å
ã¯å°ãªããšã30ãã«ïŒ0.76mmïŒã®åãããªããã°
ãªããªããæ圢åŸã®æ圢ææã¯ãŸãã110âã®æ°Ž
äžã«200æé浞挬ããåŸã«ãã®æ²ã匷ãã®å°ãªã
ãšã75ïŒ ãä¿æããŠããããšã«ãã確èªãããã
ããªè¯å¥œãªå æ°Žå解å®å®æ§ã瀺ãã®ã奜ãŸããã
ãŸããå°å ¥æ圢ããé»åéšåã¯ãçžå¯Ÿæ¹¿åºŠ85ïŒ ã®
空æ°äžã§85âã«1000æéå ç±ããåŸã«ããã®é»æ°
çæ§è³ªãå€åããªãããšã奜ãŸããã æ¬çºæã«ããå¯èœã«ãªã€ãå°å ¥æ圢ã¯ãå®è³ªç
ã«ãã€ãããªããé»åéšåã䜿çšäžã«ééãã液
äœããã³æ°äœããå®å šã«ä¿è·ããããšãã§ãããš
ããæå³ã«ãããŠãäžééæ§ã§ãããšã¿ãªãã
ããæ°Žåãå°å ¥æ圢éšåã®å€åŽã«åºãŠãããªãŒã
ã«æ²¿ã€ãæ¯ç®¡äœçšã«ãããããã€ã¹æ¬äœã«æµžéã
ãããè£ çœ®å éšã«ç§»è¡ããããšã¯ã§ããªããæ¬çº
æã«ããé»åéšåã¯çŽ«å€ç·ãããå åã«ä¿è·ãã
ãã å°åºæ圢åŸã®æ圢ææã®æ©æ¢°çæ§è³ªïŒæ²ã匷ã
ãå«ãïŒã¯ãããªãã³ã°ããã³äºæ¬¡æ圢äžãªãã³
ã«ããã€ã¹ãå®æã¢ã»ã³ããªãŒã«çµèŸŒãéã«åã
ãæ©æ¢°çå¿åã«å åèããçšåºŠã§ãããå°å ¥æ圢
補åã¯é«åºŠã«äžè²«æ§ã®ãã圢ç¶å¯žæ³ã«åœ¢æã§ãã
ã®ã§ãããããœã±ãããŸãã¯å°å·è·¯è·¯æ¿ã«æå·ã
ãã«èªåæ¿å ¥ããããšãã§ããã å°åºæ圢åŸã®æ¬çºæã®æ圢ææã®ç€ºãæ©æ¢°çæ§
質ã¯ãããã«ãªãŒããã¬ãŒã ããã®äžçšéå±ããª
ãã³ã°ããã³ïŒãŸãã¯å°å ¥æ圢éšåããå€åŽã«åº
ãŠãããªãŒãã®çŽè§æ²ãã«ãèãããã®ã§ããã
ãããã€ãŠãé»åéšåã®å°å ¥æ圢éšåã®ç«¯éšã«å¿
åãå ãã€ãŠããé»åéšåã®æå¹å¯¿åœãæãªã埮
å°ã¯ã©ãã¯ãçããªãã§ãã®å¿åã«å¹æçã«èã
ããæ¬çºæã®å°å ¥æ圢å€ã§å å²ãããšãé»åéšå
ã®ä¿¡é Œæ§ã®ããé·ææ§èœã確ä¿ãããã 以äžã®å®æœäŸãæ¬çºæã®å ·äœäŸãšããŠæããã
ãã ããæ¬çºæã¯å®æœäŸã«ç€ºã詳现ã«å¶éããã
ãã®ã§ãªãããšã¯æããã§ããã å®æœäŸ ïŒ æ¬å®æœäŸã§äœ¿çšããç°æ¹æ§æº¶èçžã圢æããã
溶èå å·¥æ§ããªããŒã¯ãç¹éæ60â40127å·å ¬å ±
ã®å®æœäŸïŒã«åŸã€ãŠèª¿è£œãããã®ã§ãã€ãã ããå ·äœçã«ã¯ãå°æ¢åŒéŠ¬è¹åœ¢æ¹ææ©ãã¬ã¹å°
å ¥ç®¡ããã³å·åŽåšä»ãèžçå¡ãåãã50ã¬ãã³
ïŒ189ïŒã®ã¹ãã³ã¬ã¹éŒè£œåå¿åšã«ã宀枩ïŒããª
ãã¡çŽ25âïŒã§äžèšã®ææãå ¥ããïŒ (a) 115ãã³ãïŒ52.2KgïŒã®ïŒâã¢ã»ããã·âïŒ
âããããšé žïŒ0.50ãã³ãã¢ã«ïŒ227ã¢ã«ïŒã (b) 130.2ãã³ãïŒ59.97KgïŒã®ïŒâã¢ã»ããã·å®
æ¯éŠé žïŒ0.745ãã³ãã¢ã«ïŒ338ã¢ã«ïŒã (c) 4.46ãã³ãïŒ2.02KgïŒã®ãã¬ãã¿ã«é ž
ïŒ0.0268ãã³ãã¢ã«ïŒ12.2ã¢ã«ïŒãããã³ (d) 6.98ã°ã©ã ã®é ¢é žã«ãªãŠã 觊åªã èšç®äžããã¬ãã¿ã«é žã¢ãããŒã¯2.15ïŒ ã®ã¢ã«
éå°éã§åå¿åšã«å ¥ããããšã«ãªããïŒâã¢ã»ã
ãã·âïŒâããããšé žãšïŒâã¢ã»ããã·å®æ¯éŠé ž
ã®äž¡åå¿ç©ã¯ãã©ã¡ããæèŠã®ãšã¹ãã«åœ¢ææ§å
å¿åºã§ããã«ã«ãã³é žåºãšã¢ã»ããã·åºãšãåæ°
ã¥ã€äŸçµŠããããããã®ååå ã§ããšããšååŠé
è«çã«é£ãåã€ãŠããããããã€ãŠããã¬ãã¿ã«
é žã¢ãããŒã ããè³éŠæãžã«ã«ãã³é žã¢ãããŒãš
ãªãããã®ã¢ãããŒã«ããããšã¹ãã«åœ¢ææ§ã®ã«
ã«ãã³é žåºããéåç³»ã«ååšããæ®ãã®ã¢ãããŒ
ã«é¢ããŠæç«ããŠããååŠéè«çåè¡¡ãè¶ããå
åŠéè«çéå°éã§äŸçµŠãããããšã«ãªãã åå¿åšãšãã®å 容ç©ãããæžå§ãšçªçŽ åå æºã
ïŒåããè¿ãããšã«ããå®å šã«é žçŽ ãããŒãžãã
次ãã§ãåå¿åšã®ãžã€ã±ãããžã®ç±æ²¹ã®æµéãé
å§ããŠãåå¿ç©ã溶èããããåå¿åšã®å 容ç©ã
208âã«å ç±ãããã®æž©åºŠã«118åéä¿æãããã
ã®åŸãåå¿åšã®å 容ç©ãããã«å ç±ããŠã15åã
ãšã®æž¬å®ã§æ¬¡ã®æž©åºŠãŸã§ææž©ãããïŒ213âã220
âã234âã246âã259âã273âã290âããã³
303âãããã«æž©åºŠã47åéã§325âãŸã§äžããã äžèšå ç±ã¹ã±ãžãŠãŒã«ã§åå¿ç©æž©åºŠã325âã«
éããæç¹ã§ãåå¿ç©ãïŒmmHgã®æžå§ã«ããŠå
ç±ãç¶ããããã®æžå§å ç±ã¯90åéç¶ããã次ã«
çªçŽ ãå°å ¥ããŠæžå§ãç Žãã溶èç¶ã®ããªããŒç
æç©ããæ°Žäžã«æµžæŒ¬ããã1/8ã€ã³ãïŒ3.2mmïŒã®
ïŒç©Žãã€ããæåºããŠãåºåããã¹ãã©ã³ãã圢
æããããããã¬ããåããããã®çµæãçŽ150
ãã³ãïŒ68.0KgïŒã®å šè³éŠæããªãšã¹ãã«çæç©
ãåŸãããã åŸãããããªããŒã®é£éã¯ãããªããŒé£éã®é·
ãæ¹åã«é¢ããŠå éšã«äœçœ®ããïŒïŒïŒâãžã«ã«ã
ãã·ããšãã¬ã³åäœãå«ããšãšãã«ãé£éã®æ«ç«¯
ãã«ã«ãã³é žæ«ç«¯åºãšãªã€ãŠããããã®ããªããŒ
ã溶èç¶æ ãŸãã¯åºäœç¶æ ã®ãããã§å ç±ããŠ
ããå®è³ªçã«ãã以äžã®éåãããªãã¡é£éçé·
ã¯èªããããªãã€ãã ãã®ããªããŒçæç©ã®å¯Ÿæ°ç²åºŠæ°ïŒI.V.ïŒãã
æ¿åºŠ0.1ééïŒ ã®ãã³ã¿ãã«ãªãããšããŒã«æº¶æ¶²
ã«ããŠ60âã§ç²åºŠæž¬å®ããåŒïŒ I.V.ïŒlnïŒÎ·relïŒïŒïŒ£ ãåŒäžãïŒæº¶æ¶²ã®æ¿åºŠïŒ0.1ééïŒ ïŒãηrelïŒ
çžå¯Ÿç²åºŠãã«åŸã€ãŠæ±ãããšã1.6dlïŒïœã§ãã
ããšãããã€ããééå¹³åååéã¯ãçŽ9700ã§ã
ã€ãã瀺差走æ»ç±éæ³ïŒå ç±é床20âïŒåïŒã«ã
ã枬å®ã§ããã®ããªããŒã¯236âã«æº¶èåžç±éã
ãŒã¯ã瀺ããããã®ããªããŒã®ã¡ã«ãã¯å åŠçã«
ç°æ¹æ§ã§ããã枩床300âãåªæé床100sec-1ã§
çŽ50ãã¢ãºã®æº¶èç²åºŠã瀺ããã æ¬å®æœäŸã§äœ¿çšããç²åç¶ç¡æ©ææã¯ãç±³åœã
ã³ã·ã«ããã¢å·ãããããŒã°ã®Harbisonâ
Walker Refractories瀟ããJP71ã®å称ã§åžè²©ã
ããŠããç³è±ã¬ã©ã¹ïŒæº¶èã·ãªã«ïŒã§ãã€ããã
ã®ææã®ã¢ã¹ãã¯ãæ¯ã¯å®è³ªçã«ïŒïŒïŒã§ããã
ééå¹³åç²åºŠã¯çŽ12ãã¯ãã³ãç²åã®ïŒééïŒ ä»¥
äžã¯100ãã¯ãã³æªæºã®ç²åºŠã®ãã®ã§ãã€ããã
ã®ç³è±ã¬ã©ã¹ã«ãç¡æ©å å¡«æçšã®æšæºçãªè¢«èŠæ
è¡ãçšããŠãïŒééïŒ ã®Î³âã°ãªã·ããã·ããã
ã«ããªã¡ããã·ã·ã©ã³è¢«èŠæã«ããè¡šé¢åŠçã
ãããã®ã·ã©ã³è¢«èŠæã¯ããŠããªã³ã»ã«ãŒãã€ã
瀟ããA187ã®å称ã§åžè²©ãããŠãããã®ã§ãã€
ãã ãã®ç³è±ã¬ã©ã¹ããç±³åœã€ãªãã€å·ãšã«ã¯ã»ã°
ã¬ãŒãã»ãã¬ããžã®BussâCondux瀟補ã®é åæŒ
åºæ©ã§ããMDK46圢ããŒããŒã䜿çšããŠãç°æ¹
æ§æº¶èçžã圢æãããåèšã®å šè³éŠæããªãšã¹ã
ã«ã®äžéšã«ã次ã®ããã«ããŠ70ééïŒ ã®é åéã§
å®è³ªçã«åäžã«åæ£ãããããŸãããªããŒã®ãã¬
ãããäžèšæŒåºæ©ã®åŸéšã«äŸçµŠãããç³è±ã¬ã©ã¹
ã¯æŒåºæ©ã®äžæµåŽã®ç¬¬ïŒã®äŸçµŠå£ã«èšéããŠäŸçµŠ
ããããã¬ã«æž©åºŠã¯250âã«ä¿æãã300rpmã®ã¹
ã¯ãªãŠãŒå転é床ãæ¡çšããããã¬ã³ããããæ
æããç©ŽçŽåŸ4.5mmã®ïŒç©Žãã€ããçŽ22 1bsïŒhr
ïŒ10KgïŒhrïŒã®æŒåºéã§æŒåºããåäžãã¬ãŒãå
å¿ãã€ããšãŒã¹ãã¬ã¿ã€ã¶ãŒã䜿ã€ãŠãã¬ããç¶
ã«çŽ°æããã次ãã§ãåŸããããã¬ããã«æ°ŽãåŽ
é§ããŠãææã宀枩ã«å·åŽããã åŸãããæ圢ææã¯ãåªæé床100sec-1ã«ãã
ãŠ330âïŒããªãã¡ãåŸã§çšããå°å ¥æ圢枩床ã«
ã»ãŒåãïŒã§900ãã¢ãºã®æº¶èç²åºŠã瀺ãããã
ã®æ圢ææã¯ãŸããæ°Žæœåºæ§ã¢ã«ã«ãªéå±å«æé
ã50ppmæªæºãæ°Žæœåºéããã²ã³å«æéã
100ppmæªæºã§ãã€ãã å°å ¥æ圢çšé»åéšåãšããŠã粟å¯å·»ç·æµæåšã
éžæãããããã®æµæåšã®å·»ç·éšåã¯ã350âã§
å€åœ¢ã«èããããšã®ã§ããã³ã€ã«äžã«åœ¢æãã
ããåæµæåšã«ãã€ãŠã¯ãïŒå¯Ÿã®è»žæ¹åã«é 眮ã
ãããªãŒããããããã24ã²ãŒãžïŒããªãã¡ãçŽ
åŸ0.020ã€ã³ãïŒ0.05cmïŒã®ã¹ãºãã€ãé ãªãŒã
ç·ã«ãåžžæ³ã«ãã350âã§ååãªå¯çãç¶æãã
確å®ãªãã³ãã€ã³ã°ã«ããæ¥ç¶ãããŠãããåæ±
ãæ§ãããããããã«ãå°å ¥æ圢ãã¹ãå€æ°ã®æµ
æåšããæ¥çå€ã€ãããŒãäžã«é©å®ééããããŠ
暪ã«å¹³è¡ã«äžŠã¹ãŠåºå®ããé©åœãªäŸçµŠãªãŒã«ã«å·»
ããŠãããŠãããã 䜿çšããå°åºæ圢çšéåã¯ããªãŒãããã³é ãª
ãŒãç·ããã®ãªãŒãã«åºçããæ¥ç¶éšãå«ãã å·»
ç·æµæåšå šäœã®å®å šãªå°å ¥ãå¯èœãšãªãã ãã®å€§
ããã®ãã®ãšãããéåã®å 寞ã¯ãå°å ¥ããé»å
éšåã®ã©ã®èŸºã«é¢ããŠãå®å¯žããçŽ0.060ã€ã³ã
ïŒ0.15cmïŒå€§ãããããïŒæ¬ã®é ãªãŒãç·ã¯ãé
åå£é¢ã®äžéšã圢æããŠããèç±æ§ã§ããå€åœ¢å¯
èœãªã·ãŒã«éšã貫éããŠãå€åŽãžåºãŠãããåé
åãã€ããã€ã«ã¯ãå°å ¥æ圢åŸã®é»åéšåã®åã
åºãã容æã«ããããã«çŽ5ãã®æãåŸé ãã€ããŠ
ãããå€æ°ã®äžèšé»åéšåã®åæå°å ¥æ圢ãå¯èœ
ã«ããããã«ãå€æ°ã®éåãã€ããã€ã暪ã«å¹³è¡
ã«äžŠã¹ãŠçšæããã æ圢ææã®éåãã€ããã€ãžã®å°å ¥ã¯ãç±³åœã³
ããã«ããå·ãã«ãªã³ã®Polymer Machinery瀟
ããåžè²©ã®Arburg瀟補200Såã¹ã¯ãªãŠãŒå°åºæ
圢æ©ã䜿çšãããããã®å°åºæ圢æ©ã¯40ç±³ãã³
ïŒ36TïŒã®ã¯ã©ã³ãããã³ïŒãªã³ã¹ïŒ56ïœïŒã®å°
åºèœåãæãããå°å ¥æ圢çšæš¹èã¯ã1/4ã€ã³ã
ïŒ0.6cmïŒã®å šå圢ã©ã³ããŒã«ãã€ãŠãå¹ 0.125ã€
ã³ãïŒ0.318cmïŒãé«ã0.020ã€ã³ãïŒ0.051cmïŒã®
å®è³ªçã«ã©ã³ãã®ãªãã·ã³ã°ã«ã²ãŒãããéåã
ã€ããã€ã«å°å ¥ããããšãã§ãããæ圢ææãæž©
床çŽ300âã§çŽ500psiïŒ35KgïŒcm2ïŒã®å§åããã
ãŠãçŽ125âã«ä¿æããéåãã€ããã€ã«çŽïŒç§
ã§å æºããããåéåãã€ããã€å ã®æ圢ææã¯
æ°ç§ä»¥å ã«åºåãããå°å ¥æ圢ããé»åéšåã¯ã
0.125ã€ã³ãïŒ0.318cmïŒã®çªåºãã³ã«ããåéå
ãã€ããã€ããæŒåºãããã®åŸããªåãããã åŸãããå°åºæ圢ããæ圢ææã¯ãULâ94è©Š
éšã§è©Šéšãããšãã«ïŒ¶âã®ççŒè©äŸ¡ã瀺ããäœ
ç±èšåŒµçã¯60ã110âã«ãããŠ150Ã10-6cm3ïŒcm3â
â以äžãç±äŒå°çã¯10Ã10-4calâcmïŒsecâcm2â
â以äžã§ããã110âã®æ°Žäžã«200æé浞挬ããåŸ
ã«ãã®æ²ã匷ãã®æ®çãå°ãªããšã75ïŒ ã§ããã
ãšãããããããã«å æ°Žå解å®å®æ§ã瀺ãã å®æœäŸ ïŒ å°æ¢åŒéŠ¬è¹åœ¢æ¹ææ©ãã¬ã¹å°å ¥ç®¡ããã³å·åŽåš
ä»ãèžçå¡ãåãã50ã¬ãã³ïŒ189ïŒã®ã¹ãã³
ã¬ã¹éŒè£œåå¿åšã«ã宀枩ïŒããªãã¡çŽ25âïŒã§äž
èšã®ææãå ¥ããïŒ (a) 115ãã³ãïŒ52.2KgïŒã®ïŒâã¢ã»ããã·âïŒ
âããããšé žïŒ0.50ãã³ãã¢ã«ïŒ227ã¢ã«ïŒã (b) 126ãã³ãïŒ57.2KgïŒã®ïŒâã¢ã»ããã·å®æ¯
éŠé žïŒ0.70ãã³ãã¢ã«ïŒ318ã¢ã«ïŒã (c) 8.29ãã³ãïŒ3.76KgïŒã®ãã¬ãã¿ã«é žïŒ0.050
ãã³ãã¢ã«ïŒ22.7ã¢ã«ïŒãããã³ (d) 5.65ã°ã©ã ã®é ¢é žã«ãªãŠã 觊åªã èšç®äžããã¬ãã¿ã«é žã¢ãããŒã¯4.17ïŒ ã®ã¢ã«
éå°éã§åå¿åšã«å ¥ããããšã«ãªããïŒâã¢ã»ã
ãã·âïŒâããããšé žãšïŒâã¢ã»ããã·å®æ¯éŠé ž
ã®äž¡åå¿ç©ã¯ãã©ã¡ããæèŠã®ãšã¹ãã«åœ¢ææ§å
å¿åºã§ããã«ã«ãã³é žåºãšã¢ã»ããã·åºãšãåæ°
ã¥ã€äŸçµŠããããããã®ååå ã§ããšããšååŠé
è«çã«é£ãåã€ãŠããããããã€ãŠããã¬ãã¿ã«
é žã¢ãããŒã ããè³éŠæãžã«ã«ãã³é žã¢ãããŒãš
ãªãããã®ã¢ãããŒã«ããããšã¹ãã«åœ¢ææ§ã®ã«
ã«ãã³é žåºããéåç³»ã«ååšããæ®ãã®ã¢ãããŒ
ã«é¢ããŠæç«ããŠããååŠéè«çåè¡¡ãè¶ããå
åŠéè«çéå°éã§äŸçµŠãããããšã«ãªãã åå¿åšãšãã®å 容ç©ãããæžå§ãšçªçŽ åå æºã
ïŒåããè¿ãããšã«ããå®å šã«é žçŽ ãããŒãžãã
次ãã§ãåå¿åšã®ãžã€ã±ãããžã®ç±æ²¹ã®æµéãé
å§ããŠãåå¿ç©ã溶èããããåå¿åšã®å 容ç©ã
200âã«å ç±ãããã®æž©åºŠã«100åéä¿æãããã
ã®åŸãåå¿åšã®å 容ç©ãããã«å ç±ããŠã15åã
ãšã®æž¬å®ã§æ¬¡ã®æž©åºŠãŸã§ææž©ãããïŒ231âã244
âã262âã273âã292âã306âã311âããã³
320âã次ãã§æž©åºŠã320âã«35åéä¿æããã äžèšå ç±ã¹ã±ãžãŠãŒã«ã§åå¿ç©æž©åºŠã320âã«
ä¿æããåŸãåå¿ç©ãïŒmmHgã®æžå§ã«ããŠå ç±
ãç¶ããããã®æžå§äžã§ã®å ç±ã60åéç¶ããã
次ã«æžå§ãç Žãã溶èç¶ã®ããªããŒçæç©ããæ°Ž
äžã«æµžæŒ¬ãã1/8ã€ã³ãïŒ3.2mmïŒã®ïŒç©Žãã€ãã
æåºããŠãåºåããã¹ãã©ã³ãã圢æããããã
ãã¬ããåããããã®çµæãçŽ138ãã³ãïŒ62.6
KgïŒã®å šè³éŠæããªãšã¹ãã«çæç©ãåŸãããã åŸãããããªããŒã®é£éã¯ãããªããŒé£éã®é·
ãæ¹åã«é¢ããŠå éšã«äœçœ®ããïŒïŒïŒâãžã«ã«ã
ãã·ããšãã¬ã³åäœãå«ããšãšãã«ãé£éã®æ«ç«¯
ãã«ã«ãã³é žæ«ç«¯åºãšãªã€ãŠããããã®ããªããŒ
ã溶èç¶æ ãŸãã¯åºäœç¶æ ã®ãããã§å ç±ããŠ
ããå®è³ªçã«ãã以äžã®éåãããªãã¡é£éçé·
ã¯èªããããªãã€ãã ãã®ããªããŒçæç©ã®å¯Ÿæ°ç²åºŠæ°ïŒI.V.ïŒãã
åè¿°ã®ããã«ããŠæ¿åºŠ0.1ééïŒ ã®ãã³ã¿ãã«ãª
ãããšããŒã«æº¶æ¶²ã«ã€ããŠ60âã§æž¬å®ãããšã
ãã0.99dlïŒïœã§ãã€ããééå¹³åååéã¯ãçŽ
6100ã§ãã€ãã瀺差走æ»ç±éæ³ïŒå ç±é床20âïŒ
åïŒã«ãã枬å®ã§ããã®ããªããŒã¯221âã«æº¶è
åžç±éããŒã¯ã瀺ããããã®ããªããŒã®ã¡ã«ãã¯
å åŠçã«ç°æ¹æ§ã§ããã枩床300âãåªæé床
100sqc-1ã§çŽ20ãã¢ãºã®æº¶èç²åºŠã瀺ããã ãã®ããªããŒã«æ¬¡ãã§å®æœäŸïŒã«èšèŒã®ããã«
ç³è±ã¬ã©ã¹ãé åããŠãæ¬çºæã«ããæ圢ææã
圢æãããåŸãããæ圢ææã¯ã枩床330âãåª
æé床100sec-1ã§420ãã¢ãºã®æº¶èç²åºŠã瀺ããã
ãã®æ圢ææã®æ°Žæœåºæ§ã¢ã«ã«ãªéå±å«æéã¯
50ppmæªæºãæ°Žæœåºæ§ããã²ã³å«æéã¯100ppm
æªæºã§ãã€ãã å°å ¥æ圢çšã®é»åéšåãšããŠãããŠã¢ã«ã€ã³ã©
ã€ã³éç©åè·¯ããã€ã¹ãè£ çãããã¬ãœã«ããŒã
ïŒã¯ãã ä»ãïŒ16ãã³ãªãŒããã¬ãŒã ãéžæãã
ãããã®ãªãŒããã¬ãŒã çã¯ãã¹ãºïŒéæ¯ã63ïŒ
37ã®ã¹ãºâéå ±æ¶åéã§ãã€ãããã10åã®éç©
åè·¯ãïŒåã«è£ çãããïŒÃ7.5Ã0.006ïŒåã¿ïŒ
ã€ã³ãïŒ2.5Ã19Ã0.015cmïŒã®å€§ããã®ãã®ã§ã
ãããã®éç©åè·¯ã®åãã€ã¯çŽ1/4Ã1/4ã€ã³ã
ïŒ0.6Ã0.6cmïŒã®å€§ããã®ãã®ã§ããšããã·æš¹è
æ¥çå€ã«ãã10åã®åããã€ã¹ã®ããã«éšã«æ¥å
ãããŠãããåããã€ã¹ã®16åã®ãã³ã®ãããã
ã¯ãçŽåŸçŽ0.001ã€ã³ãïŒ0.025mmïŒã®åŸ®çŽ°ãªéã¯
ã€ã€ã§éç©åè·¯ãã€ã®ã¢ã«ãããŠã ãããã«æ¥ç¶
ãããŠããã ç®çãšããå°å ¥æ圢ã®å®æœã«ã¯ãã«ããããªã³
ã¿ãªãªå·ãã²ã«ãã®Ludwig Engel Ganada瀟補
ã®Engel ES50 VHASåã85ãã³çžŠåãªãŒãã
ã³ã°ãã¬ã¹ãæ¡çšããããã«ç©åããã»ã¹ã³ã³ã
ããŒã©ã䜵çšããã䜿çšããå°åºæ圢éåã¯ãäž
å¿ã®1/4ã€ã³ãïŒ0.64cmïŒå圢ã©ã³ããŒã«æ¥ç¶ã
ãå€æ°ã®ãã€ããã€ãåããããã¯æšªåå°åºæ圢
ã·ãªã³ãããåå²é¢äœçœ®ã§äŸçµŠããããåéåã
ã€ããã€ã®å¯žæ³ã¯ãã»ãŒ0.75Ã0.25Ã0.117ã€ã³ã
ïŒ1.9Ã0.64Ã0.30cmïŒã§ããã ãªãŒããã¬ãŒã ãåéç©åè·¯ãã€ãããããé
åãã€ããã€ã®äžå¿ã«ããããã«ã¬ã€ããã³ã«ã
ãéåå ã«é 眮ãããåéåãã€ããã€ã¯å°å ¥æ
圢åŸã«é»åéšåãåãåºãæãããããã«çŽ5ãã®
æãåŸé ãã€ããŠãããæ圢ææãå€åŽã«çªãåº
ããªãŒãã®éã§éåããæŒåºããã®ããåãªãŒã
éã«é 眮ãããããæ¢ãæ£ããŸãã¯ãŠãšãã«ãã
é²æ¢ããã æ圢æ¡ä»¶ã¯ã¯ãã ä»ããªãŒããã¬ãŒã ã«é©åã
ãããã«éžæãããçŽ315âã®ã¡ã«ã枩床ããã³
çŽ300psiïŒ21KgïŒcm2ïŒã®å§åã§ãé»åéšåãå ¥ã
ãéåãã€ããã€ãçŽ3.8ç§ãããŠå®å šã«å å¡«ã
ãããã®æ圢ææã®å°å ¥äžãéåãã€ããã€ã¯çŽ
145âã®æž©åºŠã«ä¿æãããåéåãã€ããã€ã«å°
åºãããã°ãæ圢ææã¯æ°ç§ã§åºåãããå°å ¥æ
圢ããé»åéšåã¯ãçŽåŸ0.150ã€ã³ãïŒ0.381cmïŒ
ã®çªåºãã³ã«ããåéåãã€ããã€ããæŒåºãã å°å ¥æ圢åŸããããæ¢ãæ£ããŸãã¯ãŠãšãã¯ã
å°å ¥æ圢éšåã®å€åŽã«åºãŠãããªãŒããã¬ãŒã ã®
äœåãªéå±ããã¹ãŠãã€ã«ããã€ã³ã°ã«ããåã
é€ãããªãã³ã°å·¥çšã§åãé€ããããå°å ¥æ圢éš
åã®å€åŽã«çªãåºããªãŒãã¯ããœã±ãããŸãã¯å°
å·åè·¯æ¿ãžã®å·®ã蟌ã¿ã容æãªãã®æçµåœ¢ç¶ã«æ²
ãããé»åéšåã¯ãããããŠäžééæ§ã«å°å ¥æ圢
ãããã åŸãããå°åºæ圢ããæ圢ææã¯ãULâ94è©Š
éšã§è©Šéšãããšãã«ïŒ¶âã®ççŒè©äŸ¡ã瀺ããäœ
ç±èšåŒµçã¯60ã110âã«ãããŠ150Ã10-6cm3ïŒcm3â
â以äžãç±äŒå°çã¯10Ã10-4calâcmïŒsecâcm2â
â以äžã§ããã110âã®æ°Žäžã«200æé浞挬ããåŸ
ã«ãã®æ²ã匷ãã®æ®çãå°ãªããšã75ïŒ ã§ããã
ãšãããããããã«å æ°Žå解å®å®æ§ã瀺ãã å®æœäŸ ïŒ å°æ¢åŒéŠ¬è¹åœ¢æ¹ææ©ãã¬ã¹å°å ¥ç®¡ããã³å·åŽåš
ä»ãèžçå¡ãåãã50ã¬ãã³ïŒ189ïŒã®ã¹ãã³
ã¬ã¹éŒè£œåå¿åšã«ã宀枩ïŒããªãã¡çŽ25âïŒã§äž
èšã®ææãå ¥ããïŒ (a) 59.0ãã³ãïŒ26.8KgïŒã®ïŒâããããã·âïŒ
âããããšé žïŒ0.31ãã³ãã¢ã«ïŒ140ã¢ã«ïŒã (b) 137.4ãã³ãïŒ69.32KgïŒã®ïŒâããããã·å®
æ¯éŠé žïŒ1.00ãã³ãã¢ã«ïŒ453ã¢ã«ïŒã (c) 9.04ãã³ãïŒ4.10KgïŒã®ãã¬ãã¿ã«é žïŒ0.054
ãã³ãã¢ã«ïŒ24.5ã¢ã«ïŒã (d) 142ãã³ãïŒ64.4KgïŒã®ç¡æ°Žé ¢é žïŒ1.39ãã³
ãã¢ã«ïŒ631ã¢ã«ïŒãããã³ (e) 5.6ïœã®é ¢é žã«ãªãŠã 觊åªã èšç®äžããã¬ãã¿ã«é žã¢ãããŒã¯4.1ïŒ ã®ã¢ã«
éå°éã§åå¿åšã«å ¥ããããšã«ãªããïŒâããã
ãã·âïŒâããããšé žãšïŒâããããã·å®æ¯éŠé ž
ã®äž¡åå¿ç©ã¯ãã©ã¡ããæèŠã®ãšã¹ãã«åœ¢ææ§å
å¿åºã§ããã«ã«ãã³é žåºãšããããã·åºãšãåæ°
ã¥ã€äŸçµŠããããããã®ååå ã§ããšããšååŠé
è«çã«é£ãåã€ãŠããããããã€ãŠããã¬ãã¿ã«
é žã¢ãããŒã ããè³éŠæãžã«ã«ãã³é žã¢ãããŒãš
ãªãããã®ã¢ãããŒã«ããããšã¹ãã«åœ¢ææ§ã®ã«
ã«ãã³é žåºããéåç³»ã«ååšããæ®ãã®ã¢ãããŒ
ã«é¢ããŠæç«ããŠããååŠéè«çåè¡¡ãè¶ããå
åŠéè«çéå°éã§äŸçµŠãããããšã«ãªãã åå¿åšãšãã®ç²æ«ç¶å 容ç©ãããæžå§ãšçªçŽ å
å æºãïŒåããè¿ãããšã«ããå®å šã«é žçŽ ãããŒ
ãžãã次ãã§ç¡æ°Žé ¢é žãå ¥ããŠãããåå¿åšã®ãž
ã€ã±ãããžã®ç±æ²¹ã®æµéãéå§ããŠãåå¿ç©ãã
å質ãªæ¶²ç¶æº¶æ¶²ã圢æããããåå¿åšã®å 容ç©ã
140âã«å ç±ãããã®æž©åºŠã«30åéä¿æããåŸã
çŽ40åã§200âã«ææž©ããã200âã«ããã«30åé
ä¿æããã次ãã§ãåå¿åšã®å 容ç©ãããã«å ç±
ããŠã15åããšã®æž¬å®ã§æ¬¡ã®æž©åºŠãŸã§ææž©ãã
ãïŒ219âã246âã262âã281âã300âã310
âã316âããã³320âã次ãã§æž©åºŠã320âã«30
åéä¿æããã äžèšå ç±ã¹ã±ãžãŠãŒã«ã§åå¿æ··åç©ã320âã«
ä¿æããåŸãåå¿ç©ã10mmHgã®æžå§ã«ããŠå ç±
ãç¶ããããã®æžå§äžã§ã®å ç±ã120åéç¶ããã
次ã«çªçŽ ãå°å ¥ããŠæžå§ãç Žãã溶èç¶ã®ããªã
ãŒçæç©ããæ°Žäžã«æµžæŒ¬ãã1/8ã€ã³ãïŒ3.2mmïŒ
ã®ïŒç©Žãã€ããæåºããŠãåºåããã¹ãã©ã³ãã
圢æããããããã¬ããåããããã®çµæãçŽ
150ãã³ãïŒ68.0KgïŒã®å šè³éŠæããªãšã¹ãã«ç
æç©ãåŸãããã åŸãããããªããŒã®é£éã¯ãããªããŒé£éã®é·
ãæ¹åã«é¢ããŠå éšã«äœçœ®ããïŒïŒïŒâãžã«ã«ã
ãã·ããšãã¬ã³åäœãå«ããšãšãã«ãé£éã®æ«ç«¯
ãã«ã«ãã³é žæ«ç«¯åºãšãªã€ãŠããããã®ããªããŒ
ã溶èç¶æ ãŸãã¯åºäœç¶æ ã®ãããã§å ç±ããŠ
ããå®è³ªçã«ãã以äžã®éåãããªãã¡é£éçé·
ã¯èªããããªãã€ãã ãã®ããªããŒçæç©ã®å¯Ÿæ°ç²åºŠæ°ïŒI.V.ïŒãã
åè¿°ã®ããã«ããŠæ¿åºŠ0.1ééïŒ ã®ãã³ã¿ãã«ãª
ãããšããŒã«æº¶æ¶²ã«ã€ããŠ60âã§æž¬å®ãããšã
ãã0.9dlïŒïœã§ãã€ããééå¹³åååéã¯ãçŽ
6000ã§ãã€ãã瀺差走æ»ç±éæ³ïŒå ç±é床20âïŒ
åïŒã«ãã枬å®ã§ããã®ããªããŒã¯çŽ250ã305â
ã®æº¶èç¯å²ã瀺ããããã®ããªããŒã®ã¡ã«ãã¯å
åŠçã«ç°æ¹æ§ã§ããã溶èç²åºŠã¯ãå®åžžåªæã¢ãŒ
ãã§æäœããRheometrics質éåæèšã®å¹³è¡æ¿ã®
éã§æž¬å®ããŠã枩床320âãåªæé床10sec-1ã§çŽ
ïŒãã¢ãºã§ãã€ãã ãã®ããªããŒã«æ¬¡ãã§å®æœäŸïŒã«èšèŒã®ããã«
ç³è±ã¬ã©ã¹ãé åããŠãæ¬çºæã«ããæ圢ææã
圢æãããåŸãããæ圢ææãåè¿°ã®ããã«å€æŽ
ããASTM D3123â722ã®ã¹ãã€ã©ã«ãããŒè©Š
éšã«ããè©äŸ¡ããã330âã§24ã€ã³ãïŒ61cmïŒã
340âã§ã¯28ã€ã³ãïŒ71cmïŒã®ã¹ãã€ã©ã«ãããŒ
é·ããåŸãããããã®æ圢ææã®æ°Žæœåºæ§ã¢ã«ã«
ãªéå±å«æéã¯50ppmæªæºãæ°Žæœåºæ§ããã²ã³å«
æéã¯100ppmæªæºã§ãã€ãã å°å ¥æ圢ã«ã¯ã40ãã³ãªãŒããã¬ãŒã ã®ããŠã¢
ã«ã€ã³ã©ã€ã³éç©åè·¯ããã€ã¹ãéžæããããã
ã®ãªãŒããã¬ãŒã ã¯ãïŒâ8/1ã€ã³ãïŒ2.9cmïŒÃ
ïŒâ1/4ã€ã³ãïŒ5.7cmïŒã«å¯žæ³ã®0.010ã€ã³ã
ïŒ0.025cmïŒã®ææãé æ¿ãããªãå€æ°ã®ã»ã°ã¡ã³
ããããªãããã®éç©åè·¯ãã€ã¯ã寞æ³ãçŽ1/4
ã€ã³ãïŒ0.6cmïŒÃ1/4ã€ã³ãïŒ0.6cmïŒã§ããšãã
ã·æš¹èã«ãããªãŒããã¬ãŒã ã®åã»ã°ã¡ã³ãã®ã
ãã«éšã«æ¥åãããŠããããªãŒããã¬ãŒã ã®40æ¬
ã®åãã³ã¯ãçŽåŸçŽ0.001ã€ã³ãïŒ0.0254mmïŒã®
埮现ãªéã¯ã€ã€ã«ããéç©åè·¯ãã€ã®ãããã«ã
ãããæ¥ç¶ãããŠããã 䜿çšããå°åºæ圢çšéåã¯ãéç©åè·¯ãã€ãæ¥
ç¶ã¯ã€ã€ãããã³ä»å±ãããªãŒããã¬ãŒã ã®çæ
ã¡ã¢ãŒã ãå®å šã«å°å ¥ã§ãããããªå¯žæ³ã®ãã®ãš
ãããéåãã€ããã€ã®åååã®åã®å€§ããã¯ã
é·ã2.03ã€ã³ãïŒ5.17cmïŒãå¹ 0.54ã€ã³ãïŒ0.419
cmïŒã§ãããéåãã€ããã€ã®ïŒåã®ååãåã
ããå šåã¯0.165ã€ã³ãïŒ0.42cmïŒã§ããããã®
åã¿ã¯éåãã€ããã€ã®åååãèŒãããªãŒãã
ã¬ãŒã ã®åã¿0.006ã€ã³ãïŒ0.015cmïŒãå«ããå€
ã§ããããã®éåã¯ãå°å ¥æ圢ããé»åéšåãå
ãåºãæãããããã«ãçŽ5ãã®ååãªæãåŸé ã
åãå ¥ããèšèšã«ãªã€ãŠããããªãŒããã¬ãŒã
ã¯ãããã«ææãã§èšããåã«åµåããã¬ã€ãã
ã³ã«ããããã€ããã€ããã€ã®äžå€®ã«ããããã«
éåå ã«åºå®ããããæ圢ææãå€åŽã«ãšã³ã§ã
ãªãŒãã®éã§éåããåºãã®ããåãªãŒãéã«é
眮ãããããæ¢ãæ£ããŸãã¯ãŠãšãã«ããé²æ¢ã
ãã æ圢ææãäžèšã®æ°ååãéåã«å ¥ããã®ã¯ã
ã«ããããªã³ã¿ãªãªå·ãã²ã«ãã®Ludwig Engel
Canada瀟補ã®Engel ES50 VHASåã85ãã³çžŠ
åãã¬ã¹ã«ç©åããã»ã¹ã³ã³ãããŒã©ã䜵çšããŠ
å®æœã§ããããã®å°åºæ圢æ©ã¯ãåç· å85ãã³ã
å°åºèœå5ozïŒ0.14KgïŒã®ãã®ã§ãããå°å ¥å€ã¯ã
åéåãã€ããã€ãžã®åäžã²ãŒãã«éãã1/4ã€
ã³ãïŒ0.635æ圢ææïŒã®ã©ã³ããžã®åå²é¢å°åº
ã«ããåéåãã€ããã€ã«å°å ¥ããããã²ãŒã
ã¯ãçŽ0.125ã€ã³ãïŒ0.318cmïŒÃ0.035ã€ã³ã
ïŒ0.089cmïŒã®å¯žæ³ã®å®è³ªçã«ç¡ã©ã³ãã®ãã®ã§ã
åéåãã€ããã€ã®äžå€®ã®å€åŽã«äœçœ®ããŠããã
çŽ330âã®ã¡ã«ã枩床ããã³çŽ1000psiïŒ70KgïŒcm2ïŒ
ã®å°åºå§åã§ãå šéšã®éåãã€ããã€ãçŽ2.5ç§
ãããŠã²ãŒãããå å¡«ããŠããããã®æ圢ææã®
å°å ¥äžãéåãã€ããã€ã¯çŽ175âã®æž©åºŠã«ä¿æ
ãããåéåãã€ããã€ã«å°åºãããã°ãæ圢æ
æã¯æ°ç§ä»¥å ã«åºåãããå°å ¥æ圢ããé»åéšå
ã¯ãçŽåŸçŽ5/32ã€ã³ãïŒ0.40cmïŒã®çªåºãã³ã«ã
ãåéåãã€ããã€ããæŒåºãã å°å ¥æ圢åŸããããæ¢ãæ£ããŸãã¯ãŠãšãã¯ã
å°å ¥æ圢éšåã®å€åŽã«åºãŠãããªãŒããã¬ãŒã ã®
äœåãªéå±ããã¹ãŠåæããŠåãé€ãããªãã³ã°
å·¥çšã§åãå€ããããå°å ¥æ圢éšåã®å€åŽã«çªã
åºããªãŒãã¯ããœã±ãããŸãã¯å°å·åè·¯æ¿ãžã®å·®
ã蟌ã¿ã容æãªãã®æçµåœ¢ç¶ã«æ²ãããããã
ãŠãé»åéšåã¯ãäžééæ§ã«å°å ¥æ圢ãããã åŸãããå°åºæ圢ããæ圢ææã¯ãULâ94è©Š
éšã§è©Šéšãããšãã«ïŒ¶âã®ççŒè©äŸ¡ã瀺ããäœ
ç±èšåŒµçã¯60ã110âã«ãããŠ150Ã10-6cm3ïŒcm3â
â以äžãç±äŒå°çã¯10Ã10-4calâcmïŒsecâcm2â
â以äžã§ããã110âã®æ°Žäžã«200æé浞挬ããåŸ
ã«ãã®æ²ã匷床ã®æ®çã75ïŒ ä»¥äžã§ããããšãã
ãããããã«å æ°Žå解å®å®æ§ã瀺ãã 以äžã«æ¬çºæããã®å¥œé©æ æ§ã«ãã説æãã
ããæ¬çºæã¯ãããã®å ·äœçå 容ã«éå®ãããã
ã®ã§ã¯ãªããæ¬çºæã®ç¯å²å ã§åçš®ã®å€æŽãå ã
ãããšãå¯èœã§ããã®ã¯ãããŸã§ããªãã
ã¯ïŒïŒïŒâããã¿ã¬ã³ã§ããããã®ããªãšã¹ãã«
ã¯ãåã ã§Arãç°ãªãããããåæåãäžèšäž
è¬åŒãæºè¶³ããïŒä»¥äžã®ç°ãªãå埩æåãå«æã
ãŠããŠããããæåã«èšèŒããæåã«é¢ããŠèª¬æ
ããããã«ãAräžã®è³éŠç°ã¯ãå Žåã«ãããã
ãã«çµåããŠããæ°ŽçŽ ååã®å°ãªããšãäžéšã眮
æãããŠãããã®ã§ããããç°çœ®æãå«ãæåã®
äŸã¯ãããšãã«çœ®æãã¬ãã¿ã«é žããèªå°ããã
ãã®ã§ãããç¹ã«å¥œãŸããæåã¯ãåã«ããã¬ã
ã¿ã«é žããã³ïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ãã³é žã
ãèªå°ããããšãã§ããã æ¢è¿°ã®ããã«ãæ¬çºæã§çšããããªãšã¹ãã«ã
圢æããå Žåã«äœ¿çšå¯èœãªå¥ã®ã¢ãããŒã¯ãåŒ ïŒ¹âArââ ïŒåŒäžãArã¯å°ãªããšãïŒã€ã®è³éŠç°ãããª
ãïŒäŸ¡åºãã¯ïŒ¯ãNHãŸãã¯NRãã¯NHãŸ
ãã¯NRãæå³ããã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«
åºãŸãã¯ã¢ãªãŒã«åºã§ããïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã
ã®ã§ãããã¯å¥œãŸããã¯ççŽ æ°ïŒãïŒã®çŽéã¢
ã«ãã«åºãããã«å¥œãŸããã¯ã¡ãã«åºã§ãããã
ã®ã¢ãããŒã¯ãããªããŒé£éã«ã¢ããçµåãäžã
ãããšã«ãªãã奜é©æ æ§ã§ã¯Arã¯ïŒïŒïŒâããš
ãã¬ã³ã§ããããã®ããªãšã¹ãã«ã¯ãåã ã§Ar
ãç°ãªãããããåæåãäžèšäžè¬åŒãæºè¶³ãã
ïŒä»¥äžã®ç°ãªãå埩æåãå«æããŠããŠãããã
æåã«èšèŒããæåã«é¢ããŠèª¬æããããã«ã
Aräžã®è³éŠç°ã¯ãå Žåã«ãããããã«çµåããŠ
ããæ°ŽçŽ ååã®å°ãªããšãäžéšã眮æãããŠãã
ãã®ã§ãããããã®æåãèªå°ããã¢ãããŒã®äŸ
ã«ã¯ãïœâã¢ããããšããŒã«ãïœââã¡ãã«ã¢
ããããšããŒã«ãïœâããšãã¬ã³ãžã¢ãã³ãâ
ã¡ãã«âïœâããšãã¬ã³ãžã¢ãã³ãïŒNâ²âãž
ã¡ãã«âïœâããšãã¬ã³ãžã¢ãã³ãïœâã¢ããã
ãšããŒã«ãïŒâã¡ãã«âïŒâã¢ããããšããŒã«ã
ïŒâã¯ããâïŒâã¢ããããšããŒã«ãïŒâã¢ãã
âïŒâããããŒã«ãïŒâã¢ããâ4â²âããããã·
ãããšãã«ãïŒâã¢ããâ4â²âããããã·ãžããš
ãã«ãšãŒãã«ãïŒâã¢ããâ4â²âããããã·ãžã
ãšãã«ã¡ã¿ã³ãïŒâã¢ããâ4â²âããããã·ãžã
ãšãã«ãšã¿ã³ãïŒâã¢ããâ4â²âããããã·ãžã
ãšãã«ã¹ã«ãã³ãïŒâã¢ããâ4â²âããããã·ãž
ããšãã«ã¹ã«ãã€ããïŒïŒ4â²âãžã¢ããããšãã«
ã¹ã«ãã€ãïŒããªãžã¢ããªã³ïŒãïŒïŒ4â²âãžã¢ã
ããžããšãã«ã¹ã«ãã³ãïŒïŒïŒâãžã¢ãããã«ãš
ã³ãïŒïŒ4â²âãšãã¬ã³ãžã¢ããªã³ãïŒïŒ4â²âãžã¢
ãããžããšããã·ãšã¿ã³çããããç¹ã«å¥œãŸãã
æåã¯ãïœâã¢ããããšããŒã«ããèªå°ããããš
ãã§ããã æ¢è¿°ã®ããã«ãæ¬çºæã§çšããããªãšã¹ãã«ã
圢æããå Žåã«äœ¿çšå¯èœãªããã«å¥ã®ã¢ãããŒ
ã¯ãåŒ ïŒåŒäžãArã¯å°ãªããšãïŒã€ã®è³éŠç°ãããª
ãïŒäŸ¡åºãã¯NHãŸãã¯NRã§ããããã ã
ã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«åºã§
ããïŒ ã§ç€ºãããå埩æåãããªããŒé£éã«ä»äžããã¢
ãããŒã§ãããã¯å¥œãŸããã¯ãççŽ æ°ïŒãïŒã®
çŽéã¢ã«ãã«åºãããã«å¥œãŸããã¯ã¡ãã«åºã§ã
ãããã®ã¢ãããŒã¯ãããªããŒé£éã«ã¢ããçµå
ãäžããããã®çš®ã®ã¢ãããŒã¯ããšã¹ãã«åœ¢ææ§
ããã³ã¢ãã圢ææ§åå¿åºãå³å¯ã«åãéã§å«æ
ããŠããããã«ãååŠéè«çã«ããšããšåè¡¡ããš
ããŠããã奜é©æ æ§ã§ã¯ãArã¯ïŒïŒïŒâããšã
ã¬ã³ã§ããããã®ããªãšã¹ãã«ã¯ãåã ã§Arã
ç°ãªãããããåæåãäžèšäžè¬åŒãæºè¶³ããïŒ
以äžã®ç°ãªãå埩æåãå«æããŠããŠããããæ
åã«èšèŒããæåã«é¢ããŠèª¬æããããã«ãAr
äžã®è³éŠç°ã¯ãå Žåã«ãããããã«çµåããŠãã
æ°ŽçŽ ååã®å°ãªããšãäžéšã眮æãããŠãããã®
ã§ãããããã®æåãèªå°ããã¢ãããŒã®äŸã«
ã¯ãïœâã¢ããå®æ¯éŠé žãïœââã¡ãã«ã¢ãã
å®æ¯éŠé žãïœâã¢ããå®æ¯éŠé žãïŒâã¡ãã«âïŒ
âã¢ããå®æ¯éŠé žãïŒâã¯ããâïŒâã¢ããå®æ¯
éŠé žãïŒâã¢ããâïŒâããããšé žãïŒââã¡
ãã«ã¢ããâïŒâããããšé žãïŒâã¢ããâ4â²â
ã«ã«ããã·ãããšãã«ãïŒâã¢ããâ4â²âã«ã«ã
ãã·ãžããšãã«ãšãŒãã«ãïŒâã¢ããâ4â²âã«ã«
ããã·ãžããšãã«ã¹ã«ãã³ãïŒâã¢ããâ4â²âã«
ã«ããã·ãžããšãã«ã¹ã«ãã€ããïœâã¢ããæ¡ç®
é žçããããç¹ã«å¥œãŸããæåã¯ãïœâã¢ããå®
æ¯éŠé žããèªå°ããããšãã§ããã äžã«åæãããããªåŸæ¥å ¬ç¥ã®ãµãŒã¢ãããã
ã¯æ¶²æ¶æ§ããªãšã¹ãã«ããåè¿°ã®æ¹æ³ã«ãã€ãŠç±
çã«å®å®ããå€æ§åœ¢æ ã§è£œé ããããšãã§ããã åè¿°ã®æ¹æ³ã«ããå€æ§å€æ ã§çæãããéåžžã«
ããããããªãšã¹ãã«ããæ¬åºé¡äººã«è²æž¡ããã
ç±³åœç¹èš±ç¬¬4161470ïŒ4184996ïŒ4219461ïŒ
4256624ïŒ4330457ïŒããã³4351917å·ãªãã³ã«æ¬
åºé¡äººã«è²æž¡ãããç±³åœç¹èš±åºé¡ç¬¬485820å·
ïŒ1983幎ïŒæ18æ¥åºé¡ïŒã«é瀺ãããŠãããç±³åœ
ç¹èš±ç¬¬4330457ããã³4351917å·ã®ãµãŒã¢ãããã
ã¯æ¶²æ¶æ§ããªãšã¹ãã«ã¯ãã¢ããçµåãããã«å«
ããã®ã§ããã æ¬çºæã§å©çšããåè¿°ã®æ¹æ³ã«ããã°ããã¹ãŠ
ã®ãšã¹ãã«åœ¢ææ§ããã³ã¢ãã圢ææ§ã¢ãããŒ
ããéåäžã«è³éŠæãžã«ã«ãã³é žã¢ãããŒãã
ã³ïŒãŸãã¯ãã®ãšã¹ãã«åèªå°äœãçŽïŒãïŒã¢ã«
ïŒ ã奜ãŸããã¯çŽïŒãïŒã¢ã«ïŒ éå°ã«ååšããã
ãã«æ éã«èšéããŠåå¿åž¯åã«å ããã奜é©æ æ§
ã§ã¯ãè³éŠæãžã«ã«ãã³é žã¯ãéåäžã«çŽ2.0ã
4.2ã¢ã«ïŒ éå°ãšãªãéã§ååšããããè³éŠæãž
ã«ã«ãã³é žã¢ãããŒïŒããã³ïŒãŸãã¯ãã®ãšã¹ã
ã«åèªå°äœïŒã®ãã®ã¢ã«éå°éããã«ã«ãã³é žå
å¿åºïŒããã³ïŒãŸãã¯ãã®ãšã¹ãã«åèªå°äœïŒã®
å šéãšãããããã·ã«åå¿åºïŒããã³ïŒãŸãã¯ã
ã®ãšã¹ãã«åèªå°äœïŒã«ååšããã°ã¢ãã³åå¿åº
ïŒããã³ïŒãŸãã¯ãã®ã¢ããåèªå°äœïŒãå ãã
ãã®ã®å šéãšã®éã§ååŠéè«çåè¡¡ããšããŠãã
æ®ãã®ã¢ãããŒéã«æ¯ã¹ãŠéå°ã«éååå¿äžã«å
åšãããããšãå¿ é ã§ããã äžèšã®ã¢ã«éå°éã§ååšããã奜ãŸããè³éŠæ
ãžã«ã«ãã³é žã¢ãããŒã¯ããã«ãã¿ã«é žãã€ãœã
ã¿ã«é žãïŒïŒïŒâããã¿ã¬ã³ãžã«ã«ãã³é žãïŒïŒ
ïŒâããã¿ã¬ã³ãžã«ã«ãã³é žãïŒïŒïŒâããã¿ã¬
ã³ãžã«ã«ãã³é žãïŒâããšãã«ãã¬ãã¿ã«é žã
ïŒïŒ4â²âãå®æ¯éŠé žçã§ããã åè¿°ã®æ¹æ³ã«ãããšãéååå¿äžã«ãäžèšã¢ã«
éå°ã§ååšããè³éŠæãžã«ã«ãã³é žã¢ãããŒãã
ã³ïŒãŸãã¯ãã®ãšã¹ãã«åèªå°äœããèªå°ããã
ãžã«ã«ãã³é žåäœã®ããã«ãçæããªããŒã®ããª
ããŒé£éã®å éšã«ãã®åäœãå ¥ããããšåæã«ã
ããªããŒé£éã®æ«ç«¯ã«ã«ã«ãã³é žåºããã³ïŒãŸã
ã¯ãã®ãšã¹ãã«åèªå°äœããããéååå¿ã®é²è¡
ã«ã€ããŠãéå垯åã«ååšããä»ã®ã¢ãããŒã¯å®
å šã«æ¶è²»ãå°œããããåŸãããå¹³åããªããŒéé·
ã¯ãéååå¿äžã«éå垯åã«äŸçµŠãããè³éŠæãž
ã«ã«ãã³é žã¢ãããŒããã³ïŒãŸãã¯ãã®ãšã¹ãã«
åèªå°äœã®ã¢ã«éå°éã«ãã€ãŠçŽæ¥å¶åŸ¡ãããã
ãžã«ã«ãã³é žã¢ãããŒããã³ïŒãŸãã¯ãã®ãšã¹ã
ã«åèªå°äœã®ã¢ã«éå°éãäžèšç¯å²å ã§å€ãã»
ã©ãå¹³åããªããŒéé·ã¯çããªããéã«ããžã«ã«
ãã³é žã¢ãããŒããã³ïŒãŸãã¯ãã®ãšã¹ãã«åèª
å°äœã®ã¢ã«éå°éãäžèšç¯å²å ã§å°ãªãã»ã©ãå¹³
åããªããŒéé·ã¯é·ããªãããããã€ãŠãåèšæ¹
æ³ã«ããã¢ã«éå°éãäžå®ãšããããšã«ãããæ
å®ã®å¹³åéé·ã®ããªããŒçæç©ã圢æããããå€
ãã®å Žåããã®ãããªå¹³åéé·ã¯ãçæããªããŒ
ã®å¯Ÿæ°ç²åºŠæ°ãªãã³ã«ãã®ééå¹³åååéã«ãã
確èªããã®ã奜éœåã§ããããããã«ããŠããç
æãããµãŒã¢ããããã¯æ¶²æ¶æ§ããªãšã¹ãã«ã®ã
ãªããŒé£éã®æ«ç«¯ã«ã¯ãã«ã«ãã³é žæ«ç«¯åºãã
ã³ïŒãŸãã¯ãã®ãšã¹ãã«åèªå°äœãããããã®ã
ããªçæç©ã¯ç±å®å®æ§ã瀺ããããã¯ãæ«ç«¯åºã
ãã¹ãŠé¡äŒŒã®ãã®ã§ããããããã®åŸã«æº¶èå å·¥
枩床ã«å ç±ãããŠããé£æ¥ååéã®éååå¿ã«ã
ããã以äžã®ããªããŒé£éæé·ãå®è³ªçã«äžå¯èœ
ã§ããããã§ããã ãã®ãããªããªãšã¹ãã«ã¯ãçž®ååå¿ã«ããå¿
èŠãªå埩æåã圢æããå®èœåºãæããææ©ã¢ã
ããŒååç©ãåå¿ãããå€æ§ãªãšã¹ãã«åœ¢ææ³ã«
ããçæãããããšãã§ãããäŸãã°ãææ©ã¢ã
ããŒååç©ã®å®èœåºã¯ãã«ã«ãã³é žåºããããã
ã·ã«åºããšã¹ãã«åºïŒäŸãã¢ã·ããã·åºïŒãé žã
ãã²ã³åç©çã§ããããã®ææ©ã¢ãããŒååç©
ã¯ã溶èã¢ã·ããªã·ã¹æ³ã«ããç±äº€ææµäœãååš
ãããã«åå¿ãããããšãã§ããããã®æ¹æ³ã§
ã¯ããŸãææ©ã¢ãããŒååç©ãå ç±ããŠåå¿ç©è³ª
ãã»ãšãã©æº¶èãã溶液ãçæãããããã®æã
ãã¬ãã¿ã«é žã®ãããªäžéšã®åå¿ç©è³ªã¯åœåã¯ã
ãçšåºŠåºäœã«ãšã©ãŸãããã¬ãã¿ã«é žãå°éã§ã
ãã°ããã®ãããªç¶æ³äžã§ã溶解ããããããªã
ãŒçæç©ã¯ãå Žåã«ãããåºäœããªããŒç²åãšã
ãŠæº¶æ¶²äžã«æžæ¿ãããçž®ååå¿ã®æçµæ®µéã«ãã
ãŠãå¯æããæ®çºæ§ç©è³ªïŒäŸãé ¢é žãŸãã¯æ°ŽïŒã®
é€å»ãã®ä»ã«ããéååå¿ã®ä¿é²ã®ããã«ãç空
ãé©çšããŠãããã æ¬åºé¡äººã«è²æž¡ãããç±³åœç¹èš±ç¬¬4067852å·ã«
ã¯ãæ¬çºæã§çšããããªãšã¹ãã«ã®çæã«å©çšã
ãããšã®ã§ããã¹ã©ãªãŒéåæ¹æ³ãèšèŒãããŠã
ãããã®æ¹æ³ã§ã¯åºäœçæç©ã¯ç±äº€æåªè³ªäžã«æž
æ¿ããç¶æ ã§åŸãããã 溶èã¢ã·ããªã·ã¹æ³ãŸãã¯ç±³åœç¹èš±ç¬¬4067852
å·ã®ã¹ã©ãªãŒæ³ã®ããããçšããå Žåã§ããããª
ããŒæåãèªå°ããã¢ãããŒåå¿ç©è³ªã®ãã¡ãä¿
è·ããªããã°ããããã·ã«åºããã³ïŒãŸãã¯ã¢ã
ã³åºãå«æãããã®ã¯ãäºããšã¹ãã«åããŠãã
ããšã奜ãŸãããäŸãã°ããããã¯ççŽ æ°çŽïŒã
ïŒã®äœçŽã¢ã·ã«ãšã¹ãã«ãšããŠåå¿ã«äŸãããã
ãã«å¥œãŸããã¯ããã®ãããªæªä¿è·ã§ã¯ãããã
ã·ã«åºããã³ïŒãŸãã¯ã¢ãã³åºãå«æããã¢ãã
ãŒã®é ¢é žãšã¹ãã«ã䜿çšããããããä¿è·ããå
å¿ç©è³ªã®äŸã¯ãïŒâã¢ã»ããã·âïŒâããããš
é žãïŒâã¢ã»ããã·å®æ¯éŠé žããããããã³ãžã¢
ã»ããŒããïŒïŒ4â²âãããšããŒã«ãžã¢ã»ããŒãç
ã§ããã ãŸããçæããªããŒé£éã«ã«ã«ããã·ã¢ãªãŒã«
åäœãä»äžããã¢ãããŒãäŸãã°ã¢ã«éå°ã«äœ¿çš
ããè³éŠæãžã«ã«ãã³é žã¢ãããŒããåå¿éå§æ
ã«ãšã¹ãã«å圢æ ã§åå¿ã«äŸããŠããããäŸã
ã°ãç±³åœç¹èš±ç¬¬4333907å·ã«èšèŒã®ããã«ããã®
ãããªã¢ãããŒãããšãã°ãããšããŒã«ãïœâã¯
ã¬ãŸãŒã«ãïœâã¯ã¬ãŸãŒã«çã®è³éŠæã¢ãããã
ãã·ååç©ãšåå¿ãããããã®ãããªãšã¹ãã«å
åå¿ç©è³ªã®äŸã¯ãïœâããããã·å®æ¯éŠé žããšã
ã«ãããã³ãã¬ãã¿ã«é žãžããšãã«ã§ããã奜é©
æ æ§ã§ã¯ãåå¿ç©è³ªã®ã«ã«ãã³é žåºã¯ãšã¹ãã«å
ããªãã 溶èã¢ã·ããªã·ã¹æ³ãŸãã¯ç±³åœç¹èš±ç¬¬4067852
å·ã®ã¹ã©ãªãŒæ³ã®ãããã«ãä»»æã«äœ¿çšã§ãã代
è¡šçãªè§Šåªã«ã¯ããžã¢ã«ãã«ã¹ãºãªãã·ãïŒäŸã
ãžããã«ã¹ãºãªãã·ãïŒããžã¢ãªãŒã«ã¹ãºãªãã·
ããäºé žåãã¿ã³ãã¢ã«ã³ãã·ãã¿ã³ã·ãªã±ãŒ
ãããã¿ã³ã¢ã«ã³ãã·ããã«ã«ãã³é žã®ã¢ã«ã«ãª
ããã³ã¢ã«ã«ãªåé¡éå±å¡©ãã«ã€ã¹é žïŒäŸã
BF3ïŒãããã²ã³åæ°ŽçŽ ïŒäŸãHClïŒçã®ã¬ã¹ç¶
é žè§Šåªãªã©ãããã觊åªã®äœ¿çšéã¯ãäžè¬ã«ã¢ã
ããŒã®å šééã«åºããŠçŽ0.001ãïŒééïŒ ãç¹ã«
çŽ0.01ã0.2ééïŒ ã§ããã æ¬åºé¡äººã«è²æž¡ãããç±³åœç¹èš±ç¬¬4393191ïŒ
4395536ïŒ4421908ïŒããã³4429105å·ã®éåæ¹æ³
ããæ¬çºæã§å©çšããããªãšã¹ãã«åœ¢ææ³ãå®æœ
ããã®ã«é©ããŠããã ç¹ã«å¥œãŸããæ æ§ã«ãããŠã溶èå å·¥æ§ããªã
ãŒãç±³åœç¹èš±ç¬¬4161470å·ã®å šè³éŠæããªãšã¹ã
ã«ãå€æ§ãããã®ã§ããå Žåããã®å€æ§ããªãšã¹
ãã«ã¯ãæ¬è³ªçã«äžèšæåããã³ïŒ ãããªããæåãçŽ20ã45ã¢ã«ïŒ ããã³æå
ãçŽ55ã85ã¢ã«ïŒ ã®éã§å«æããããªãšã¹ãã«ã
çæãããããªãšã¹ãã«åœ¢ææ§ã¢ãããŒãéå垯
åã§éååå¿ãããŠåŸããã®ã§ããããã®éã«å
èšéååå¿äžã«çŽïŒãïŒã¢ã«ïŒ éå°ã®è³éŠæãžã«
ã«ãã³é žã¢ãããŒãéå垯åã«ååšããããã®é
å°ã¢ãããŒã«ãããéååå¿äžã«çæããªããŒã®
ããªããŒé£éã®å éšã«ãžã«ã«ããã·ã¢ãªãŒã«åäœ
ãä»äžããããšå ±ã«ãããªããŒé£éã®æ«ç«¯ãã«ã«
ãã³é žæ«ç«¯åºãšãªããããªããŒé£éãéå垯åã«
ååšããä»ã®ã¢ãããŒã®æ¶èã«ãã€ãŠå¿ èŠãªåå
éã«å°éãããããåŸãããå šè³éŠæããªãšã¹ã
ã«çæç©ã¯ãã®åŸã«å ç±ãåããŠããã以äžã®é£
éæé·ãå®è³ªçã«äžå¯èœãšãªã€ãŠããã å¥ã®ç¹ã«å¥œé©ãªæ æ§ã«ãããŠã溶èå å·¥æ§ããª
ããŒãç±³åœç¹èš±ç¬¬4330457å·ã®ã¢ããçµåããã
ã«æããå šè³éŠæããªãšã¹ãã«ãå€æ§ãããã®ã§
ããå Žåããã®å€æ§ããªãšã¹ãã«ã¯ãæ¬è³ªçã«äž
èšæåããããã³å Žåã«ããïŒåŒäžãå
èšå·Arã¯å°ãªããšãïŒã€ã®è³éŠç°ãããªãïŒäŸ¡
åºïŒïŒ ïŒââArââ ïŒåŒäžãã¯ïŒ¯ãNHãŸãã¯NRãã¯NHãŸ
ãã¯NRãæå³ããã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«
åºããŸãã¯ã¢ãªãŒã«åºã§ããïŒã ïŒââArââ ãããªããæåãçŽ40ã80ã¢ã«ïŒ ãæåãçŽ
ïŒã30ã¢ã«ïŒ ãæåãïŒã30ã¢ã«ïŒ ãããã³æ
åãçŽïŒã25ã¢ã«ïŒ ã®éã§å«æããããªïŒãšã¹
ãã«âã¢ããïŒãçæãããããªãšã¹ãã«åœ¢ææ§
ããã³ã¢ãã圢ææ§åå¿ã¢ãããŒãéå垯åã§é
ååå¿ããåŸããã®ã§ããããã®éã«åèšéåå
å¿äžã«çŽïŒãïŒã¢ã«ïŒ éå°ã®è³éŠæãžã«ã«ãã³é ž
ã¢ãããŒãéå垯åã«ååšããããã®éå°ã¢ãã
ãŒã«ãããéååå¿äžã«çæããªããŒã®ããªããŒ
é£éã®å éšã«ãžã«ã«ããã·ã¢ãªãŒã«åäœãä»äžã
ãããšå ±ã«ãããªããŒé£éã®æ«ç«¯ãã«ã«ãã³é žæ«
端åºãšãªããããªããŒé£éãéå垯åã«ååšãã
ä»ã®ã¢ãããŒã®æ¶èã«ãã€ãŠå¿ èŠãªååéã«å°é
ãããããåŸãããå šè³éŠæããªïŒãšã¹ãã«âã¢
ããïŒçæç©ã¯ãã®åŸã«å ç±ãåããŠããã以äž
ã®é£éæé·ãå®è³ªçã«äžå¯èœãšãªã€ãŠããã ç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªããŒ
ããååºã®ç±³åœç¹èš±åºé¡ç¬¬517865å·ã®æ¹æ³ã«ãã
圢æããå Žåããã®ããªããŒã¯ãç²åç¶ç¡æ©ææ
ãšæ··åããåã§ã3.0dlïŒïœä»¥äžãç¹ã«çŽ0.8ã3.0
dlïŒïœã®å¯Ÿæ°ç²åºŠæ°ïŒãã³ã¿ãã«ãªãããšããŒã«
ã«0.1ééïŒ ã®æ¿åºŠã§æº¶è§£ãããŠ60âã§æž¬å®ãã
å€ïŒã瀺ãã®ã奜ãŸããããã ããå¿ ããããã¹
ãŠã®ããªããŒçæç©ãããã®å¯Ÿæ°ç²åºŠæ°ã®æž¬å®ã
è¡ãã®ã«å åãªã»ã©ãã³ã¿ãã«ãªãããšããŒã«ã«
å¯æº¶ã§ããããã§ã¯ãªãã å ç±ã«ãããã以äžã®é£éçé·ãå®è³ªçã«äžå¯
èœã§ãããæ¬çºæã®æ¹æ³ã«äœ¿çšã§ããç°æ¹æ§æº¶è
çžã圢æããã溶èå å·¥æ§ããªããŒã圢æããã
ãã®ä»ã®ä»£è¡šçãªæ¹æ³ã¯ãæ¬åºé¡äººã«è²æž¡ããã
ç±³åœç¹èš±åºé¡ç¬¬595004å·ïŒ1984幎ïŒæ29æ¥åºé¡ïŒ
ããã³ç±³åœç¹èš±åºé¡ç¬¬611299å·ïŒ1984幎ïŒæ17æ¥
åºé¡ïŒã«é瀺ãããŠããã æ¬çºæã§çšãã溶èå å·¥æ§ããªããŒã¯ãç²åç¶
ç¡æ©ææãšæ··åããåã«ã溶èå 工枩床ïŒäŸã
300âã310âã320âãŸãã¯330âïŒããã³åªæé
床100sec-1ã«ãããŠãçŽ30ã300ãã¢ãºã®æº¶èç²
床ã瀺ãã®ã奜ãŸããããã®æº¶èç²åºŠã®æž¬å®ã¯ã
é·ãïŒã€ã³ãïŒ10cmïŒãå åŸ30ãã«ïŒ762ÎŒïŒã®æ¯
现管ãåããã€ã³ã¹ããã³æ¯ç®¡ã¬ãªã¡ãŒã¿ãçšã
ãŠæšæºç枬å®æ³ã«ããå®æœã§ããããŸãã¯ãã¬ãª
ã¡ããªãã¯ã¹è³ªéåæèšãå©çšããå¹³è¡æ¿ã䜿ã€
ãåªæé床10sec-1ã®å®åžžåªæã¢ãŒãã§æº¶èç²åºŠ
ã枬å®ããŠãããã溶èå å·¥æ§ããªããŒã¯ã溶è
ç²åºŠæž¬å®æç¹ã§ã¯å®å šãªæº¶èç¶æ ãšããã300â
ã§æº¶èç²åºŠæž¬å®ãè¡ãå Žåã«ã¯ãããªããŒããŸã
çŽ320âã«å ç±ããåŸã溶èç²åºŠã®æž¬å®æž©åºŠã§ã
ã300âã«å·åŽããæ¹ããããå質ãªæº¶èäœãåŸ
ãããã æ¬çºæã§äœ¿çšãã溶èå å·¥æ§ããªããŒã¯ããã®
åæçµè·¯ã®åŠäœã«ããããããç²åç¶ç¡æ©ææãš
æ··åããåã«çŽ200ã480âãç¹ã«çŽ200ã350âã®
ç¯å²å ã®æž©åºŠã§å¿ èŠãªç°æ¹æ§æº¶èçžã圢æã§ãã
ãã®ã§ããã®ã奜ãŸããããã®æº¶èå å·¥æ§ããªã
ãŒã¯ã害ãåãŒãçšã®å€Ÿéç©ãå«æãã¹ãã§ãª
ãã奜ãŸããã¯æ¬è³ªçã«äžçæ§ã§ããããå ïŒç¹
ã«çŽ«å€ç·ïŒã溶å€ãè¬åããªãã³ã«å°å ¥æ圢é»å
éšåã®åœ¢æãçµç«ããã³é·æ䜿çšäžã«ééããç°
å¢ã«å¯ŸããŠèæ§ã瀺ãã æ¬çºæã®æ圢ææã®ç¬¬ïŒã®å¿ é æåã¯ãç²åç¶
ç¡æ©ææïŒããªãã¡ãç¡æ©å å¡«æïŒã§ããããã®
ç²åç¶ç¡æ©ææã¯ãåè¿°ã®æº¶èå å·¥æ§ããªããŒã«
å®è³ªçã«åäžã«åæ£ããããããã®æº¶èå å·¥æ§ã
ãªããŒïŒããªãã¡ãç²åç¶ç¡æ©ææãå«ãŸãªãçµ
æç©ïŒã®äœç±èšåŒµçãäœäžããããšå ±ã«ããã®ç±
äŒå°çãå¢å ãããããšãã§ãããã®ã§ãããç²
åç¶ç¡æ©ææã®ååšã¯ãæçµè£œåã®äœç±èšåŒµçã
æ¬è³ªçã«ããçæ¹æ§ã«ããäœçšããããç²åç¶æ
æã¯ãäºé žåã±ã€çŽ ãã¿ã«ã¯ããŠãªã©ã¹ããã€
ããã¢ã«ãããã³ãŒãžãšã©ã€ãçã®å€æ§ãªåºäœç¡
æ©ææããéžæãããããããçš®ã®åœ¢æ ã®äºé žå
ã±ã€çŽ ã奜ãŸãããç²åç¶ç¡æ©ææã¯ãééå¹³å
ç²åºŠãçŽïŒã50ÎŒã§ãç²åã®å°ãªããšã99ééïŒ
ã100ÎŒæ«ç«¯ã§ãããã®ã奜ãŸããããã®ç²åºŠæž¬
å®çšã«é©ããç²åºŠåæè£ çœ®ã¯ãç±³åœãžãšãŒãžã¢å·
ããŒã¯ãã¹ã®Micrometrics Lnstrument瀟ãã
ã³ãããªãå·ã»ã³ãããŒã¿ãŒã¹ããŒã°ã®Leeds
and Northrup瀟ããåžè²©ãããŠãã
ïŒMicrotracç²åºŠåæåšïŒããŸããç²åç¶ç¡æ©ææ
ã¯ãæ圢åŸã«åãåãã«æŽåããç²åã«ããç±èš
匵çã«ç°æ¹æ§ãçããŠããæãããªãããã«ãå š
æ¹åã«ãããŠå®è³ªçã«åäžå¯žæ³ã®ãã®ã§ããã®ã
奜ãŸããããããã€ãŠãç²åç¶ç¡æ©ææã®å¹³åã¢
ã¹ãã¯ãæ¯ã¯ãæ £çšã®å åŠé¡åŸ®é¡ã«ãã枬å®ã§
ïŒïŒïŒä»¥äžãšãªãã®ã奜ãŸããã ç²åç¶ç¡æ©ææã¯ãé»åéšåã®åäœã«æ害ãŸã
ã¯ããã劚害ããæãã®ããæ害éã®å€Ÿéç©ãå«
ãŸãªãããšãäžå¯æ¬ ã§ãããå¯åçã«äœç±èšåŒµç
ãäœãã®ã奜ãŸããããã®ãããç³è±ã¬ã©ã¹ãæ¬
çºæã§çšããã®ã«ç¹ã«å¥œãŸããç²åç¶ç¡æ©ææãš
ãªããåšç¥ã®ããã«ãç³è±ã¬ã©ã¹ã¯ãäžè¬ã«ã¯é»
æ°ã¢ãŒã¯æº¶èã«ããéåžžã«é«ã枩床ãå©çšããŠé
åžžã®çµæ¶è³ªããéæ¶è³ªã«è»¢åãããæ¯èŒççŽç²ãª
äºé žåã±ã€çŽ ãããªãããã®ç²åç¶ç¡æ©ææã¯ã
溶èã·ãªã«ãŸãã¯æº¶èç³è±ãšãåŒã°ãããåŸãã
ã溶èç²åã¯ããã®çæåŸã«ææã®ç²èªåºŠãŸã§åŸ®
ç²ç ããããã®ææã¯ãäœç±èšåŒµçãäºå®äžãŒã
ã§ãããæ¥éãã€æ¥µç«¯ãªæž©åºŠå€åãåããŠãå éš
å¿åãçããªãããã®ãããªç³è±ã¬ã©ã¹ã¯åžè²©ã
ããŠãããç±³åœãã³ã·ã«ããã¢å·ãããããŒã°ã®
HarbisonâWalker Refractories瀟ããGP7Iã®
åååã§å ¥æããããææã«ãããç±äŒå°çãã
ãã«å€§ããããããã«ãå°éã®çµæ¶æ§ã·ãªã«ã溶
èã·ãªã«ã«é åããŠãããããã ããçµæ¶æ§ã·ãª
ã«ã®é åã«ããçµæç©å šäœã®äœç±èšåŒµçãããçš
床å¢å ããåŸåããããå°å ¥æ圢ããé»åéšåã
ç¹ã«èããã®ã§ãªãå Žåã«ã¯ãç²åç¶ç¡æ©ææã«
äžé£ç¶ç¶ã¬ã©ã¹ç¹ç¶ãªã©ã®ç¹ç¶ç¶è£åŒ·æãé åã
ãŠãããããŸããæ圢ææã«å¯ŸããŠæ害ãªåœ±é¿ã
åãŒããªãéããçè²å€ãæ·»å å€ãå®çå€ãé¢å
å€çãé åããŠãããã 奜é©æ æ§ã§ã¯ãç²åç¶ç¡æ©ææã®è¡šé¢ã«ã¯ãç°
æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªããŒãšã®
æ··ååãé«ãã被èŠãããã«æœããããŠããã䜿
çšè¢«èŠå€ã¯ãé»åéšåãæãªã€ãããé»åéšåã®
䜿çšæã®åäœã劚ããå¯èœæ§ã®ãããã®ã§ãã€ãŠ
ã¯ãªããªãã代衚çãªè¢«èŠæã¯ããŠããªã³ã«ãŒã
ã€ã瀟ããããããA187ããã³A1100ãšããŠåž
販ãããŠããγâã°ãªã·ããã·ãããã«ããªã¡ã
ãã·ã·ã©ã³ããã³Î³âã¢ãããããã«ããªãšãã
ã·ã·ã©ã³ãªã©ã®ã·ã©ã³é¡ã§ããããã®ã·ã©ã³åå
ç©ã¯ãç¡æ©å å¡«æã®æšæºçãªè¢«èŠæè¡ã«ãããçŽ
0.5ã1.5ééïŒ ã®éã§è¡šé¢è¢«èŠæãšããŠç²åç¶ç¡
æ©ææã«è¢«èŠããããšãã§ãããææ©ãã¿ããŒã
系衚é¢è¢«èŠæããç°æ¹æ§æº¶èçžã圢æããã溶è
å å·¥æ§ããªããŒææãšæ··åããåã®ç¡æ©ç²åã«å
æ§ã«è¢«èŠãããã æ¬çºæã«ãããšãç²åç¶ç¡æ©ææã¯ãæ圢ææ
ã®å šééã«åºã¥ããŠçŽ40ã80ééïŒ ãç¹ã«ãçŽ50
ã75ééïŒ ïŒäŸãçŽ55ã70ééïŒ ïŒã®éã§ãç°æ¹
æ§æº¶èçžã圢æããã溶èå å·¥æ§ããªããŒã«é å
ããããã®å éšã«å®è³ªçã«åäžã«åæ£ããããã
ã®å®è³ªçã«åäžãªåæ£ã¯ã移åããŠãã溶èããª
ããŒææã®å éšã«ç²åç¶ææãæŒã蟌ãå ¬ç¥ã®æ
è¡ã«ããéæã§ãããäžè»žæŒåºæ©ãåæ¹åå転äº
軞æŒåºæ©ãéå転äºè»žæŒåºæ©ãæ··ç·Žæ©çãçšãã
å ¬ç¥ã®æº¶èé åæè¡ãæ¡çšã§ãããäŸãã°ãç±³åœ
ããŠãŒãžã€ãŒãžãŒå·ã©ã ãŒãŒã®Werner ïŒ
Pfleiderer瀟補ã®åæ¹åå転äºè»žæŒåºæ©ã䜿çšã§
ããããã®ãããªè£ 眮ã䜿çšããå Žåãäºã圢æ
ããããªããŒãã¬ãããšç²åç¶ç¡æ©ææã也åŒã
ã¬ã³ããšããŠæŒåºæ©ã«äŸçµŠããããªããŒææã®æº¶
è枩床ããé«æž©ã«å ç±ããã ãã§ãããé åãä¿
é²ããããã«ãæ··ç·Žãããã¯ãã¹ã¯ãªãŠãŒå ã«é
眮ããã®ãæå©ã§ãããç²åç¶ç¡æ©ææãé«ãé
åå²åã§å°å ¥ããå Žåã«ã¯ãå€æ®µãã¹ïŒäŸãïŒã
ã¹ä»¥äžã®ïŒé åæäœãæ¡çšããæåã®ãã¹ã§ã¯ç²
åç¶ç¡æ©ææã®äžéšã®ã¿ãå°å ¥ããããã«ããŠã
ãããæãã¯ãç°æ¹æ§ã¡ã«ã圢ææ§ããªããŒãšç²
åç¶ç¡æ©ææãšã®ãã¬ã³ãã®èª¿è£œã¯ãç±³åœã€ãªã
ã€å·ãšã«ã¯ã°ããŒããã¬ããžã®BussâCondux瀟
補ã®BussâCondux ããŒããŒã®ãããªé åæŒåº
æ©ãŸãã¯ç²åã®äžæµåŽæ·»å ãå¯èœãªãã®ä»ã®æŒåº
æ©ãçšããŠãäžæµåŽã«èšããïŒä»¥äžã®äŸçµŠå£ã«ç²
åãäŸçµŠããããšã«ãããç¡æ©ææã®å šéã溶è
ããªããŒã«å ããããšã«ãã€ãŠãå®æœã§ãããã
ã®æ¹æ³ã§ã¯ãããªããŒãæŒåºæ©ã®åŸéšãžäŸçµŠãã
溶èãããåŸãç²åãšé åãããã©ã¡ãã®çš®é¡ã®
é åæ¹æ³ã§ããåŸãããæ圢ææã¯ãã¹ãã©ã³ã
æ³ãããã¯ãã€ããšãŒã¹æ³ã®ããããã®ãã¬ãã
補é æ³ãçšããŠãã¬ããåã§ãããã¹ãã©ã³ãæ³
ã§ã¯ãåŸãããæ圢ææã®ã¹ãã©ã³ããæŒåºãã
空å·éšãééåŸã«ãã¬ããåããã溶èæŒåºã¹ã
ã©ã³ãã¯ãæŒåºæ©ãšãã¬ããåæäœã®éãã³ã³ã
ã€ãŒã§æ¬éãããããã€ããšãŒã¹ã«ãã¿ãŒã䜿çš
ããå Žåãæ圢ææã¯ãã€ã®åé¢ã§ãã¬ããã«å
æããã次ãã§ãã®ãã¬ãããæ°Žäžã«èœããŠå·åŽ
ããæ¹æ³ã§ããã ç²åç¶ç¡æ©ææã¯ãäœç±èšåŒµçãæžå°ãããç±
äŒå°çãå¢å ãããããã«çšãããç²åç¶ç¡æ©æ
æã®é åå²åãæ圢ææã®å šééã«å¯Ÿã40ééïŒ
ããäœããšãäœç±èšåŒµçã倧ãããããŸãç±äŒå°
çãå°ããããåŸåãããã80ééïŒ ãè¶ ãã
ãšãåŸãããæ圢ææã®æº¶èç²åºŠã倧ãããªãåŸ
åããããå°å ¥å€ã®ç©ççæ§è³ªãå£ããææã®ç±
èšåŒµããã³ç±äŒå°æ§ãåŸãããªãã åŸãããæ圢ææã¯ãäžè¬ã«çŽ250ã390âã®ç¯
å²å ã®æž©åºŠã§å°åºæ圢ããããšãã§ããããŸãã
åŸãããæ圢ææã®æ°Žæœåºæ§ã¢ã«ã«ãªéå±ïŒäŸã
Naããã³ïŒ«ïŒã®å«æéã¯50ppmæªæºãæ°Žæœåºæ§
ããã²ã³ïŒäŸãClãBrãïŒã®å«æéã¯100ppm
æªæºã§ããããšã奜ãŸããããããã€ãŠãããçš®
ã®å°å ¥æ圢é»åéšåã®åäœäžã«ãã°ãã°å¿ èŠãšãª
ã粟å¯ãªé»æ°çãã©ã³ã¹åè¡¡ã劚害ãããããªåž¯
é»äžçŽç©ã¯ååšããªããæ°Žæœåºæ§ã¢ã«ã«ãªéå±ã
ãã³ããã²ã³ã®å«æéã®æž¬å®ã¯ãç±³åœåå°äœè£ 眮
ããã³ææåäŒïŒSEMIïŒåãSEMIèŠæ Œã第ïŒ
å·»ãããã±ãŒãžéšäŒããã€ãªã³æ§ååŠçš®ã®æšå¥šã
ããæ°Žæœåºæ³ãïŒG5.3ç¯ïŒïŒ1983ïŒã«ãããã€ãŠ
å®æœã§ããã æ¬çºæã«ããé»åéšåã®å°å ¥æ圢ãå®æœããã«
ã¯ãäºã圢æããé»åéšåããé»åéšåçšã®åŸæ¥
ã®å°åºããã±ãŒãžæè¡ïŒãã©ã³ã¹ãã¢ãŒæ圢æ³ã
å«ããïŒãšå šãåæ§ã®æ¹æ³ã§ãéåãã€ããã€å
ã«é 眮ïŒããªãã¡ãåºå®ïŒãããææã«ãããé»
åéšåãïŒåã¥ã€åå¥ã«å°å ¥æ圢ããæ°ååéå
ã«å€æ°ã®é»åéšåãäžåºŠã«ãããããšãã§ããã
次ã«ãé«æž©ã®æ¬çºæã®æ圢ææãã溶èå å·¥æ§ã
ãªããŒã溶èç¶æ ã«ãããç²åç¶ç¡æ©ææããã
ã«åæ£ããŠããç¶æ ã§å°åºããŠé»åéšåãå ¥ãã
éåãã€ããã€å ã«å®å šã«æºããããã ããé»å
éšåã®ãã¡ã®ç¹å®ã®éšåãäŸãã°é»æ°æ¥ç¶ç¹ãã¯
æ圢ææã§å å²ããéšåã®å€åŽãžçªåºããŠããŠã
ããã æ圢ææã®æ¶²æ¶æ§ããªããŒãéåãã€ããã€å
ã«å°åºããããšããã®ååã¯ãæ¯èŒçäœååéã§
ããã«ãããããããå°å ¥å€ã«æçµçã«åŒ·åºŠãã
ã³åæ§ãä»äžããããã«å±éšçã«é åããåŸåã
æ¬è³ªçã«ç€ºããšèããããããã®æº¶èããªããŒã®
æµåã®çµæãã®é åã¯å®¹æã«çããããã®å±éšç
é åã¯ããã®ãããªããªããŒã瀺ãç·©åæéãé
åžžã«é·ãããã«ãåºåã®åã«èãã倱ãããããš
ã¯ãªãããããã€ãŠãæçµè£œåã®æ©æ¢°çæ§è³ªã¯ã
æ圢ææäžã®æº¶èããªããŒã®ãµãŒã¢ããããã¯ãš
ããæ§è³ªã«ãã€ãŠæå©ãªåœ±é¿ãåããã æ¬çºæã®æ圢ææã¯å°åºæ圢枩床ã«ãããŠåªæ
é床100sec-1ã§çŽ300ã2500ãã¢ãºã®ç¯å²å ã®æº¶
èç²åºŠã瀺ãã®ã奜ãŸãããç¹ã«ãã®æ¡ä»¶äžã§çŽ
300ã1500ãã¢ãºã®ç¯å²å ã®æº¶èç²åºŠã瀺ãã®ã
奜ãŸããã æ圢ææã®æ圢é©æ§ãè©äŸ¡ããå¥ã®æ¹æ³ã¯ã
ASTM D3123â72ã®ã¹ãã€ã©ã«ãããŒè©Šéšã«èš
èŒã®æ¹æ³ã§ãããããã ããã®è©Šéšæ³ãã次ã®ã
ãã«å€æŽããïŒæ £çšã®å°åºæ圢æ©ãšãçŽåŸ1/4ã€
ã³ãïŒ6.4mmïŒã®åå圢åã®ãããŒé·ã50ã€ã³ã
ïŒ127cmïŒã®ã¹ãã€ã©ã«ãããŒéåã䜿çšãéåæž©
床100âãããã³å°åºå§8000psiïŒ560KgïŒcm2ïŒãã
ã®æ¡ä»¶äžã§åŸããã溶èããªããŒã®å žåçãªãã
ãŒé·ãã¯ãæ®éçŽ10ã45ã€ã³ãïŒ25ã114cmïŒã®
ç¯å²å ã§ããããããŒé·ãã®é·ãããªããŒã»ã©ã
粟å¯ãªé»åéšåã®å°å ¥æ圢ã«é©ããŠããã éåãã€ããã€å ã®æ®ã空éã®æ圢ææã«ãã
å å¡«é床ã¯ãé»åéšåã®å¯žæ³ããã³æ§é ç¹æ§ã«ã
ãå·Šå³ããããïŒåæªæºïŒäŸãçŽ15ã50ç§ïŒã®å š
æ圢ãµã€ã¯ã«æéã®ç¯å²å ã§ã¯ãçŽïŒã15ç§ã®é
åå å¡«æéãäžè¬ã«æ¡çšãããéç©åè·¯ããã€ã¹
ã®ãããªæ¯èŒç粟å¯ãªé»åéšåã¯ãåäžæ©èœãã©
ã³ãžã¹ã¿ãªã©ã®ããé äžãªé»åéšåãããå®è³ªç
ã«é ãå å¡«é床ãå¿ èŠãšããããšãå€ããå°å ¥æ
圢ãåããŠããé»åéšåã®åéšã害ãåºãã»ã©å€
圢ãããªãããã«æ³šæããããããã®å Žåããã
ã®é»åéšåãæå·ããªãããšãããã€ãŠããç¯å²
å ã§æå°ã®éåãã€ããã€å å¡«æéãéžæããã®
ã奜ãŸããã æ圢ææã«ããéåãã€ããã€ã®å®å šãªå å¡«ãš
ããã«ããäžééæ§å°å ¥æ圢ã®éè¡ã容æã«ãã
ããã«ãå å¡«æã«éåèªèº«ãé«æž©ãšããã®ã奜ãŸ
ããããã®çµæãæ圢ææãéåãã€ããã€ãå®
å šã«å å¡«ããåã«ããããã®é床ã®å·åŽãé²æ¢ã
ãããéåå å¡«å·¥çšã«ãããéå枩床ãšæ圢ææ
ã®æž©åºŠã®éžæã¯ãç°æ¹æ§æº¶èçžã圢æããã溶è
å å·¥æ§ããªããŒã®æº¶è枩床ããã³å®¹æã«éåãã€
ããã€ã®å®å šå å¡«ãéæããã溶èç²åºŠãåŸãã®
ã«å¿ èŠãªæž©åºŠã«äŸåããããã ãããã®æº¶èç²åºŠ
ã¯ãæ圢ææäžã«åæ£ããŠããç²åç¶ç¡æ©ææã®
éãšç²åºŠååžããªãã³ã«æº¶èå å·¥æ§ããªããŒã®é
éå¹³åååéã«äŸåãããå ·äœçãªå°å ¥æ圢æäœ
ã«å¯Ÿããäžèšãã©ã¡ãŒã¿å ã§ã®æé©æ¡ä»¶ã®æ±ºå®ã¯
æ¥åžžå®éšã«ããå®æœã§ãããã®æ¡ä»¶ã¯äœ¿çšããé
åã®èšèšã«é¢ãã幟äœåŠçå åïŒäŸãã²ãŒã寞
æ³ãã©ã³ããŒé·ãããã³å¯žæ³ãã®ä»ïŒã«äŸåã
ããäžè¬ã«ãéåãã€ããã€ã¯çŽ100ã250âã®æž©
床ãšããéåãã€ããã€ãžã®æ圢ææã®å°å ¥ã¯ã
枩床çŽ250ã390âãããã³å§åçŽ100ã1000psi
ïŒ7.0ã70KgïŒcm2ïŒã§è¡ãã å°å ¥æ圢ãå®æœããããã®ä»£è¡šçãªè£ 眮ã«ã¯ã
(1)åç· å35ãŸãã¯40ç±³ãã³ïŒ31.8ãŸãã¯36.3tïŒã®
ïŒãŸãã¯ïŒãªã³ã¹ïŒ28ãŸãã¯56ïœïŒArburg220å
ã¹ã¯ãªãŠãŒå°åºæ圢æ©ãããã³(2)åç· å80ç±³ãã³
ïŒ73KgïŒã®ïŒãªã³ã¹ïŒ142ïœïŒWindson HSI80å
ã¹ã¯ãªãŠãŒå°åºæ圢æ©ããããããã»ã¹å¶åŸ¡è£ 眮
ã䜿çšããŠãå°åºæ圢ã©ã ã®æ£åž°éäœçœ®æ±ºãå¶åŸ¡
ãè¡ããããã«ãããäžè¬ã«æ¡çšãããæ¯èŒçäœ
å§ã§ã®å°åºãèæ ®ããŠå å¡«é床ãå¶åŸ¡ããã®ãæ
å©ã§ãããæµå ¥å§ãæžå°ãããæ圢工çšã容æã«
ããã«ã¯ãçãã©ã³ããŒãšå€§ããã®ã²ãŒãã䜿çš
ãããšããã éåãæ圢ææã§å®å šã«å å¡«ãããåŸãæ圢æ
æã¯éåå ã§åºåããé»åéšåã®æå®éšåã®åšå²
ã«äžééæ§ã®ããã±ãŒãžã圢æãããã䜿çšããª
ããŒã¯ç±çã«å®å®ã§ãããæ圢äœæ¥äžã«ãå®è³ªç
ã«ããã«éååå¿ãŸãã¯å解åå¿ãçããå Žåã«
èªãããããããªãæ®çºæ§ã®ãã€ã圢ææ§æåã®
çºçãå®è³ªççšåºŠã«èµ·ããããšã¯ãªããæ圢ææ
ã®æº¶èç²åºŠã¯å®è³ªçã«ã«äžå®ã®ãŸãŸã§ããããã®
çµæãäžééæ§å°å ¥æ圢ã確ä¿ãããããã®ã
ããéåãã€ããã€å ã§ã®ããªããŒã®åºåã«ç¶ã
ããªããŒç¡¬åå·¥çšãèšããå¿ èŠã¯ãªãã å°åºæ圢åŸã®æ¬çºæã®æ圢ææã¯ã奜ãŸããã¯
60ã110âã«ãããŠ150Ã10-6cm3ïŒcm3ââ以äžã®äœ
ç±èšåŒµçã瀺ããæã奜ãŸããã¯åæ¡ä»¶äžã§90Ã
10-6cm3ïŒcm3ïŒââ以äžã®äœç±èšåŒµçã瀺ããã»ãš
ãã©ã®é»åããã€ã¹ã¯äœ¿çšäžã«ããããçºç±ãã
çºçããç±ã«ããçããå¿åãçã ããå Žåã«
ã¯ãããšããšäžééæ§ã§ãã€ãå°å ¥æ圢åã®ã²ã³
å²ããèµ·ãã€ãŠããã®ç Žæãçããããšãããã
ããæ¬çºæã®æ圢ææã®äœç±èšåŒµçãäœãããšã¯
éèŠã§ããããŸããäžèšå¿åã«ããããã³ãã€ã³
ã°ã¯ã€ã€ãéç©åè·¯ãããããåŒæããããã¯ã€
ã€ãã³ããç²åŽããç Žæãããããããã¯åè·¯å°
ç·ããããã§éç©åè·¯ãããã®è¡šé¢ãããšããã
ããããšããããäœç±èšåŒµçã®å€ã¯ãæ圢ææã®
ç²åç¶ç¡æ©ææã®é åéãå¢ãããšå°ãããªãã
ãŸãç²åç¶ç¡æ©ææã¯ãããªããŒææã®äœç±èšåŒµ
çãæ¬è³ªçã«ããçæ¹æ§ã«ããäœçšãããããã®
äœç±èšåŒµçã®æž¬å®ã¯ãååºã®ç±³åœSEMIèŠæ Œã第
ïŒå·»ãããã±ãŒãžéšäŒããæ圢ææã®èšåŒµç¹æ§ã®
è©Šéšæ³èŠæ ŒãïŒG5.4ç¯ïŒïŒ1983ïŒã«ãããã€ãŠå®
æœã§ããã å°åºæ圢åŸã®æ¬çºæã®æ圢ææã¯ãæ¯èŒçåºã
枩床ç¯å²ïŒäŸãâ40âãïŒ150âïŒã«ããã€ãŠè¯å¥œ
ãªç±èšåŒµæ§ã瀺ãããã®ãããªæ§è³ªã¯ãã¬ã©ã¹è»¢
移枩床ããé«æž©ã§ã¯ç±èšåŒµã倧ãããªããšããã·
æš¹èã瀺ãæ§è³ªããå®è³ªçã«åªããŠããã å°åºæ圢åŸã®æ圢ææã¯ã10Ã10-4calâcmïŒ
secâcm2ââ以äžãç¹ã«13Ã10-4calâcmïŒsecâ
cm2ââ以äžã®ç±äŒå°çã瀺ãã®ã奜ãŸãããé«æž©
ã«ãªããšé»åéšåã«ãã€ãŠã¯ãã®æ§èœã«æªåœ±é¿ã
åºãããšãããã®ã§ããã®ããã«ç±äŒå°çã倧ã
ãããšã¯éèŠã§ãããäŸãã°ãç±ã«ãã€ãŠéç©å
è·¯ã®åäœã®é床ãé ããªãããšãç¥ãããŠããã
ãã®ãããçºçããç±ã¯å¹æçã«æŸæ£ãããªãã°
ãªããªããæ圢ææäžã®ç²åç¶ç¡æ©ææã®é åé
ãå€ãã»ã©é«ãç±äŒå°çã®å€ãåŸããããç±äŒå°
çã®æž¬å®ã¯ãç£æ¥çã§æ £çšã®æšæºçãªæ¹æ³ã«ãã
å®æœã§ããã æ¬çºæã®æ圢ææã¯ãå°åºæ圢åŸã«ãULâ94
è©Šéšã«ãã€ãŠïŒ¶âã®ççŒè©äŸ¡ã瀺ãããšããŸã
奜ãŸããããã®ULâ94è©Šéšãè¡ãå Žåãæ圢å
ã¯å°ãªããšã30ãã«ïŒ0.76mmïŒã®åãããªããã°
ãªããªããæ圢åŸã®æ圢ææã¯ãŸãã110âã®æ°Ž
äžã«200æé浞挬ããåŸã«ãã®æ²ã匷ãã®å°ãªã
ãšã75ïŒ ãä¿æããŠããããšã«ãã確èªãããã
ããªè¯å¥œãªå æ°Žå解å®å®æ§ã瀺ãã®ã奜ãŸããã
ãŸããå°å ¥æ圢ããé»åéšåã¯ãçžå¯Ÿæ¹¿åºŠ85ïŒ ã®
空æ°äžã§85âã«1000æéå ç±ããåŸã«ããã®é»æ°
çæ§è³ªãå€åããªãããšã奜ãŸããã æ¬çºæã«ããå¯èœã«ãªã€ãå°å ¥æ圢ã¯ãå®è³ªç
ã«ãã€ãããªããé»åéšåã䜿çšäžã«ééãã液
äœããã³æ°äœããå®å šã«ä¿è·ããããšãã§ãããš
ããæå³ã«ãããŠãäžééæ§ã§ãããšã¿ãªãã
ããæ°Žåãå°å ¥æ圢éšåã®å€åŽã«åºãŠãããªãŒã
ã«æ²¿ã€ãæ¯ç®¡äœçšã«ãããããã€ã¹æ¬äœã«æµžéã
ãããè£ çœ®å éšã«ç§»è¡ããããšã¯ã§ããªããæ¬çº
æã«ããé»åéšåã¯çŽ«å€ç·ãããå åã«ä¿è·ãã
ãã å°åºæ圢åŸã®æ圢ææã®æ©æ¢°çæ§è³ªïŒæ²ã匷ã
ãå«ãïŒã¯ãããªãã³ã°ããã³äºæ¬¡æ圢äžãªãã³
ã«ããã€ã¹ãå®æã¢ã»ã³ããªãŒã«çµèŸŒãéã«åã
ãæ©æ¢°çå¿åã«å åèããçšåºŠã§ãããå°å ¥æ圢
補åã¯é«åºŠã«äžè²«æ§ã®ãã圢ç¶å¯žæ³ã«åœ¢æã§ãã
ã®ã§ãããããœã±ãããŸãã¯å°å·è·¯è·¯æ¿ã«æå·ã
ãã«èªåæ¿å ¥ããããšãã§ããã å°åºæ圢åŸã®æ¬çºæã®æ圢ææã®ç€ºãæ©æ¢°çæ§
質ã¯ãããã«ãªãŒããã¬ãŒã ããã®äžçšéå±ããª
ãã³ã°ããã³ïŒãŸãã¯å°å ¥æ圢éšåããå€åŽã«åº
ãŠãããªãŒãã®çŽè§æ²ãã«ãèãããã®ã§ããã
ãããã€ãŠãé»åéšåã®å°å ¥æ圢éšåã®ç«¯éšã«å¿
åãå ãã€ãŠããé»åéšåã®æå¹å¯¿åœãæãªã埮
å°ã¯ã©ãã¯ãçããªãã§ãã®å¿åã«å¹æçã«èã
ããæ¬çºæã®å°å ¥æ圢å€ã§å å²ãããšãé»åéšå
ã®ä¿¡é Œæ§ã®ããé·ææ§èœã確ä¿ãããã 以äžã®å®æœäŸãæ¬çºæã®å ·äœäŸãšããŠæããã
ãã ããæ¬çºæã¯å®æœäŸã«ç€ºã詳现ã«å¶éããã
ãã®ã§ãªãããšã¯æããã§ããã å®æœäŸ ïŒ æ¬å®æœäŸã§äœ¿çšããç°æ¹æ§æº¶èçžã圢æããã
溶èå å·¥æ§ããªããŒã¯ãç¹éæ60â40127å·å ¬å ±
ã®å®æœäŸïŒã«åŸã€ãŠèª¿è£œãããã®ã§ãã€ãã ããå ·äœçã«ã¯ãå°æ¢åŒéŠ¬è¹åœ¢æ¹ææ©ãã¬ã¹å°
å ¥ç®¡ããã³å·åŽåšä»ãèžçå¡ãåãã50ã¬ãã³
ïŒ189ïŒã®ã¹ãã³ã¬ã¹éŒè£œåå¿åšã«ã宀枩ïŒããª
ãã¡çŽ25âïŒã§äžèšã®ææãå ¥ããïŒ (a) 115ãã³ãïŒ52.2KgïŒã®ïŒâã¢ã»ããã·âïŒ
âããããšé žïŒ0.50ãã³ãã¢ã«ïŒ227ã¢ã«ïŒã (b) 130.2ãã³ãïŒ59.97KgïŒã®ïŒâã¢ã»ããã·å®
æ¯éŠé žïŒ0.745ãã³ãã¢ã«ïŒ338ã¢ã«ïŒã (c) 4.46ãã³ãïŒ2.02KgïŒã®ãã¬ãã¿ã«é ž
ïŒ0.0268ãã³ãã¢ã«ïŒ12.2ã¢ã«ïŒãããã³ (d) 6.98ã°ã©ã ã®é ¢é žã«ãªãŠã 觊åªã èšç®äžããã¬ãã¿ã«é žã¢ãããŒã¯2.15ïŒ ã®ã¢ã«
éå°éã§åå¿åšã«å ¥ããããšã«ãªããïŒâã¢ã»ã
ãã·âïŒâããããšé žãšïŒâã¢ã»ããã·å®æ¯éŠé ž
ã®äž¡åå¿ç©ã¯ãã©ã¡ããæèŠã®ãšã¹ãã«åœ¢ææ§å
å¿åºã§ããã«ã«ãã³é žåºãšã¢ã»ããã·åºãšãåæ°
ã¥ã€äŸçµŠããããããã®ååå ã§ããšããšååŠé
è«çã«é£ãåã€ãŠããããããã€ãŠããã¬ãã¿ã«
é žã¢ãããŒã ããè³éŠæãžã«ã«ãã³é žã¢ãããŒãš
ãªãããã®ã¢ãããŒã«ããããšã¹ãã«åœ¢ææ§ã®ã«
ã«ãã³é žåºããéåç³»ã«ååšããæ®ãã®ã¢ãããŒ
ã«é¢ããŠæç«ããŠããååŠéè«çåè¡¡ãè¶ããå
åŠéè«çéå°éã§äŸçµŠãããããšã«ãªãã åå¿åšãšãã®å 容ç©ãããæžå§ãšçªçŽ åå æºã
ïŒåããè¿ãããšã«ããå®å šã«é žçŽ ãããŒãžãã
次ãã§ãåå¿åšã®ãžã€ã±ãããžã®ç±æ²¹ã®æµéãé
å§ããŠãåå¿ç©ã溶èããããåå¿åšã®å 容ç©ã
208âã«å ç±ãããã®æž©åºŠã«118åéä¿æãããã
ã®åŸãåå¿åšã®å 容ç©ãããã«å ç±ããŠã15åã
ãšã®æž¬å®ã§æ¬¡ã®æž©åºŠãŸã§ææž©ãããïŒ213âã220
âã234âã246âã259âã273âã290âããã³
303âãããã«æž©åºŠã47åéã§325âãŸã§äžããã äžèšå ç±ã¹ã±ãžãŠãŒã«ã§åå¿ç©æž©åºŠã325âã«
éããæç¹ã§ãåå¿ç©ãïŒmmHgã®æžå§ã«ããŠå
ç±ãç¶ããããã®æžå§å ç±ã¯90åéç¶ããã次ã«
çªçŽ ãå°å ¥ããŠæžå§ãç Žãã溶èç¶ã®ããªããŒç
æç©ããæ°Žäžã«æµžæŒ¬ããã1/8ã€ã³ãïŒ3.2mmïŒã®
ïŒç©Žãã€ããæåºããŠãåºåããã¹ãã©ã³ãã圢
æããããããã¬ããåããããã®çµæãçŽ150
ãã³ãïŒ68.0KgïŒã®å šè³éŠæããªãšã¹ãã«çæç©
ãåŸãããã åŸãããããªããŒã®é£éã¯ãããªããŒé£éã®é·
ãæ¹åã«é¢ããŠå éšã«äœçœ®ããïŒïŒïŒâãžã«ã«ã
ãã·ããšãã¬ã³åäœãå«ããšãšãã«ãé£éã®æ«ç«¯
ãã«ã«ãã³é žæ«ç«¯åºãšãªã€ãŠããããã®ããªããŒ
ã溶èç¶æ ãŸãã¯åºäœç¶æ ã®ãããã§å ç±ããŠ
ããå®è³ªçã«ãã以äžã®éåãããªãã¡é£éçé·
ã¯èªããããªãã€ãã ãã®ããªããŒçæç©ã®å¯Ÿæ°ç²åºŠæ°ïŒI.V.ïŒãã
æ¿åºŠ0.1ééïŒ ã®ãã³ã¿ãã«ãªãããšããŒã«æº¶æ¶²
ã«ããŠ60âã§ç²åºŠæž¬å®ããåŒïŒ I.V.ïŒlnïŒÎ·relïŒïŒïŒ£ ãåŒäžãïŒæº¶æ¶²ã®æ¿åºŠïŒ0.1ééïŒ ïŒãηrelïŒ
çžå¯Ÿç²åºŠãã«åŸã€ãŠæ±ãããšã1.6dlïŒïœã§ãã
ããšãããã€ããééå¹³åååéã¯ãçŽ9700ã§ã
ã€ãã瀺差走æ»ç±éæ³ïŒå ç±é床20âïŒåïŒã«ã
ã枬å®ã§ããã®ããªããŒã¯236âã«æº¶èåžç±éã
ãŒã¯ã瀺ããããã®ããªããŒã®ã¡ã«ãã¯å åŠçã«
ç°æ¹æ§ã§ããã枩床300âãåªæé床100sec-1ã§
çŽ50ãã¢ãºã®æº¶èç²åºŠã瀺ããã æ¬å®æœäŸã§äœ¿çšããç²åç¶ç¡æ©ææã¯ãç±³åœã
ã³ã·ã«ããã¢å·ãããããŒã°ã®Harbisonâ
Walker Refractories瀟ããJP71ã®å称ã§åžè²©ã
ããŠããç³è±ã¬ã©ã¹ïŒæº¶èã·ãªã«ïŒã§ãã€ããã
ã®ææã®ã¢ã¹ãã¯ãæ¯ã¯å®è³ªçã«ïŒïŒïŒã§ããã
ééå¹³åç²åºŠã¯çŽ12ãã¯ãã³ãç²åã®ïŒééïŒ ä»¥
äžã¯100ãã¯ãã³æªæºã®ç²åºŠã®ãã®ã§ãã€ããã
ã®ç³è±ã¬ã©ã¹ã«ãç¡æ©å å¡«æçšã®æšæºçãªè¢«èŠæ
è¡ãçšããŠãïŒééïŒ ã®Î³âã°ãªã·ããã·ããã
ã«ããªã¡ããã·ã·ã©ã³è¢«èŠæã«ããè¡šé¢åŠçã
ãããã®ã·ã©ã³è¢«èŠæã¯ããŠããªã³ã»ã«ãŒãã€ã
瀟ããA187ã®å称ã§åžè²©ãããŠãããã®ã§ãã€
ãã ãã®ç³è±ã¬ã©ã¹ããç±³åœã€ãªãã€å·ãšã«ã¯ã»ã°
ã¬ãŒãã»ãã¬ããžã®BussâCondux瀟補ã®é åæŒ
åºæ©ã§ããMDK46圢ããŒããŒã䜿çšããŠãç°æ¹
æ§æº¶èçžã圢æãããåèšã®å šè³éŠæããªãšã¹ã
ã«ã®äžéšã«ã次ã®ããã«ããŠ70ééïŒ ã®é åéã§
å®è³ªçã«åäžã«åæ£ãããããŸãããªããŒã®ãã¬
ãããäžèšæŒåºæ©ã®åŸéšã«äŸçµŠãããç³è±ã¬ã©ã¹
ã¯æŒåºæ©ã®äžæµåŽã®ç¬¬ïŒã®äŸçµŠå£ã«èšéããŠäŸçµŠ
ããããã¬ã«æž©åºŠã¯250âã«ä¿æãã300rpmã®ã¹
ã¯ãªãŠãŒå転é床ãæ¡çšããããã¬ã³ããããæ
æããç©ŽçŽåŸ4.5mmã®ïŒç©Žãã€ããçŽ22 1bsïŒhr
ïŒ10KgïŒhrïŒã®æŒåºéã§æŒåºããåäžãã¬ãŒãå
å¿ãã€ããšãŒã¹ãã¬ã¿ã€ã¶ãŒã䜿ã€ãŠãã¬ããç¶
ã«çŽ°æããã次ãã§ãåŸããããã¬ããã«æ°ŽãåŽ
é§ããŠãææã宀枩ã«å·åŽããã åŸãããæ圢ææã¯ãåªæé床100sec-1ã«ãã
ãŠ330âïŒããªãã¡ãåŸã§çšããå°å ¥æ圢枩床ã«
ã»ãŒåãïŒã§900ãã¢ãºã®æº¶èç²åºŠã瀺ãããã
ã®æ圢ææã¯ãŸããæ°Žæœåºæ§ã¢ã«ã«ãªéå±å«æé
ã50ppmæªæºãæ°Žæœåºéããã²ã³å«æéã
100ppmæªæºã§ãã€ãã å°å ¥æ圢çšé»åéšåãšããŠã粟å¯å·»ç·æµæåšã
éžæãããããã®æµæåšã®å·»ç·éšåã¯ã350âã§
å€åœ¢ã«èããããšã®ã§ããã³ã€ã«äžã«åœ¢æãã
ããåæµæåšã«ãã€ãŠã¯ãïŒå¯Ÿã®è»žæ¹åã«é 眮ã
ãããªãŒããããããã24ã²ãŒãžïŒããªãã¡ãçŽ
åŸ0.020ã€ã³ãïŒ0.05cmïŒã®ã¹ãºãã€ãé ãªãŒã
ç·ã«ãåžžæ³ã«ãã350âã§ååãªå¯çãç¶æãã
確å®ãªãã³ãã€ã³ã°ã«ããæ¥ç¶ãããŠãããåæ±
ãæ§ãããããããã«ãå°å ¥æ圢ãã¹ãå€æ°ã®æµ
æåšããæ¥çå€ã€ãããŒãäžã«é©å®ééããããŠ
暪ã«å¹³è¡ã«äžŠã¹ãŠåºå®ããé©åœãªäŸçµŠãªãŒã«ã«å·»
ããŠãããŠãããã 䜿çšããå°åºæ圢çšéåã¯ããªãŒãããã³é ãª
ãŒãç·ããã®ãªãŒãã«åºçããæ¥ç¶éšãå«ãã å·»
ç·æµæåšå šäœã®å®å šãªå°å ¥ãå¯èœãšãªãã ãã®å€§
ããã®ãã®ãšãããéåã®å 寞ã¯ãå°å ¥ããé»å
éšåã®ã©ã®èŸºã«é¢ããŠãå®å¯žããçŽ0.060ã€ã³ã
ïŒ0.15cmïŒå€§ãããããïŒæ¬ã®é ãªãŒãç·ã¯ãé
åå£é¢ã®äžéšã圢æããŠããèç±æ§ã§ããå€åœ¢å¯
èœãªã·ãŒã«éšã貫éããŠãå€åŽãžåºãŠãããåé
åãã€ããã€ã«ã¯ãå°å ¥æ圢åŸã®é»åéšåã®åã
åºãã容æã«ããããã«çŽ5ãã®æãåŸé ãã€ããŠ
ãããå€æ°ã®äžèšé»åéšåã®åæå°å ¥æ圢ãå¯èœ
ã«ããããã«ãå€æ°ã®éåãã€ããã€ã暪ã«å¹³è¡
ã«äžŠã¹ãŠçšæããã æ圢ææã®éåãã€ããã€ãžã®å°å ¥ã¯ãç±³åœã³
ããã«ããå·ãã«ãªã³ã®Polymer Machinery瀟
ããåžè²©ã®Arburg瀟補200Såã¹ã¯ãªãŠãŒå°åºæ
圢æ©ã䜿çšãããããã®å°åºæ圢æ©ã¯40ç±³ãã³
ïŒ36TïŒã®ã¯ã©ã³ãããã³ïŒãªã³ã¹ïŒ56ïœïŒã®å°
åºèœåãæãããå°å ¥æ圢çšæš¹èã¯ã1/4ã€ã³ã
ïŒ0.6cmïŒã®å šå圢ã©ã³ããŒã«ãã€ãŠãå¹ 0.125ã€
ã³ãïŒ0.318cmïŒãé«ã0.020ã€ã³ãïŒ0.051cmïŒã®
å®è³ªçã«ã©ã³ãã®ãªãã·ã³ã°ã«ã²ãŒãããéåã
ã€ããã€ã«å°å ¥ããããšãã§ãããæ圢ææãæž©
床çŽ300âã§çŽ500psiïŒ35KgïŒcm2ïŒã®å§åããã
ãŠãçŽ125âã«ä¿æããéåãã€ããã€ã«çŽïŒç§
ã§å æºããããåéåãã€ããã€å ã®æ圢ææã¯
æ°ç§ä»¥å ã«åºåãããå°å ¥æ圢ããé»åéšåã¯ã
0.125ã€ã³ãïŒ0.318cmïŒã®çªåºãã³ã«ããåéå
ãã€ããã€ããæŒåºãããã®åŸããªåãããã åŸãããå°åºæ圢ããæ圢ææã¯ãULâ94è©Š
éšã§è©Šéšãããšãã«ïŒ¶âã®ççŒè©äŸ¡ã瀺ããäœ
ç±èšåŒµçã¯60ã110âã«ãããŠ150Ã10-6cm3ïŒcm3â
â以äžãç±äŒå°çã¯10Ã10-4calâcmïŒsecâcm2â
â以äžã§ããã110âã®æ°Žäžã«200æé浞挬ããåŸ
ã«ãã®æ²ã匷ãã®æ®çãå°ãªããšã75ïŒ ã§ããã
ãšãããããããã«å æ°Žå解å®å®æ§ã瀺ãã å®æœäŸ ïŒ å°æ¢åŒéŠ¬è¹åœ¢æ¹ææ©ãã¬ã¹å°å ¥ç®¡ããã³å·åŽåš
ä»ãèžçå¡ãåãã50ã¬ãã³ïŒ189ïŒã®ã¹ãã³
ã¬ã¹éŒè£œåå¿åšã«ã宀枩ïŒããªãã¡çŽ25âïŒã§äž
èšã®ææãå ¥ããïŒ (a) 115ãã³ãïŒ52.2KgïŒã®ïŒâã¢ã»ããã·âïŒ
âããããšé žïŒ0.50ãã³ãã¢ã«ïŒ227ã¢ã«ïŒã (b) 126ãã³ãïŒ57.2KgïŒã®ïŒâã¢ã»ããã·å®æ¯
éŠé žïŒ0.70ãã³ãã¢ã«ïŒ318ã¢ã«ïŒã (c) 8.29ãã³ãïŒ3.76KgïŒã®ãã¬ãã¿ã«é žïŒ0.050
ãã³ãã¢ã«ïŒ22.7ã¢ã«ïŒãããã³ (d) 5.65ã°ã©ã ã®é ¢é žã«ãªãŠã 觊åªã èšç®äžããã¬ãã¿ã«é žã¢ãããŒã¯4.17ïŒ ã®ã¢ã«
éå°éã§åå¿åšã«å ¥ããããšã«ãªããïŒâã¢ã»ã
ãã·âïŒâããããšé žãšïŒâã¢ã»ããã·å®æ¯éŠé ž
ã®äž¡åå¿ç©ã¯ãã©ã¡ããæèŠã®ãšã¹ãã«åœ¢ææ§å
å¿åºã§ããã«ã«ãã³é žåºãšã¢ã»ããã·åºãšãåæ°
ã¥ã€äŸçµŠããããããã®ååå ã§ããšããšååŠé
è«çã«é£ãåã€ãŠããããããã€ãŠããã¬ãã¿ã«
é žã¢ãããŒã ããè³éŠæãžã«ã«ãã³é žã¢ãããŒãš
ãªãããã®ã¢ãããŒã«ããããšã¹ãã«åœ¢ææ§ã®ã«
ã«ãã³é žåºããéåç³»ã«ååšããæ®ãã®ã¢ãããŒ
ã«é¢ããŠæç«ããŠããååŠéè«çåè¡¡ãè¶ããå
åŠéè«çéå°éã§äŸçµŠãããããšã«ãªãã åå¿åšãšãã®å 容ç©ãããæžå§ãšçªçŽ åå æºã
ïŒåããè¿ãããšã«ããå®å šã«é žçŽ ãããŒãžãã
次ãã§ãåå¿åšã®ãžã€ã±ãããžã®ç±æ²¹ã®æµéãé
å§ããŠãåå¿ç©ã溶èããããåå¿åšã®å 容ç©ã
200âã«å ç±ãããã®æž©åºŠã«100åéä¿æãããã
ã®åŸãåå¿åšã®å 容ç©ãããã«å ç±ããŠã15åã
ãšã®æž¬å®ã§æ¬¡ã®æž©åºŠãŸã§ææž©ãããïŒ231âã244
âã262âã273âã292âã306âã311âããã³
320âã次ãã§æž©åºŠã320âã«35åéä¿æããã äžèšå ç±ã¹ã±ãžãŠãŒã«ã§åå¿ç©æž©åºŠã320âã«
ä¿æããåŸãåå¿ç©ãïŒmmHgã®æžå§ã«ããŠå ç±
ãç¶ããããã®æžå§äžã§ã®å ç±ã60åéç¶ããã
次ã«æžå§ãç Žãã溶èç¶ã®ããªããŒçæç©ããæ°Ž
äžã«æµžæŒ¬ãã1/8ã€ã³ãïŒ3.2mmïŒã®ïŒç©Žãã€ãã
æåºããŠãåºåããã¹ãã©ã³ãã圢æããããã
ãã¬ããåããããã®çµæãçŽ138ãã³ãïŒ62.6
KgïŒã®å šè³éŠæããªãšã¹ãã«çæç©ãåŸãããã åŸãããããªããŒã®é£éã¯ãããªããŒé£éã®é·
ãæ¹åã«é¢ããŠå éšã«äœçœ®ããïŒïŒïŒâãžã«ã«ã
ãã·ããšãã¬ã³åäœãå«ããšãšãã«ãé£éã®æ«ç«¯
ãã«ã«ãã³é žæ«ç«¯åºãšãªã€ãŠããããã®ããªããŒ
ã溶èç¶æ ãŸãã¯åºäœç¶æ ã®ãããã§å ç±ããŠ
ããå®è³ªçã«ãã以äžã®éåãããªãã¡é£éçé·
ã¯èªããããªãã€ãã ãã®ããªããŒçæç©ã®å¯Ÿæ°ç²åºŠæ°ïŒI.V.ïŒãã
åè¿°ã®ããã«ããŠæ¿åºŠ0.1ééïŒ ã®ãã³ã¿ãã«ãª
ãããšããŒã«æº¶æ¶²ã«ã€ããŠ60âã§æž¬å®ãããšã
ãã0.99dlïŒïœã§ãã€ããééå¹³åååéã¯ãçŽ
6100ã§ãã€ãã瀺差走æ»ç±éæ³ïŒå ç±é床20âïŒ
åïŒã«ãã枬å®ã§ããã®ããªããŒã¯221âã«æº¶è
åžç±éããŒã¯ã瀺ããããã®ããªããŒã®ã¡ã«ãã¯
å åŠçã«ç°æ¹æ§ã§ããã枩床300âãåªæé床
100sqc-1ã§çŽ20ãã¢ãºã®æº¶èç²åºŠã瀺ããã ãã®ããªããŒã«æ¬¡ãã§å®æœäŸïŒã«èšèŒã®ããã«
ç³è±ã¬ã©ã¹ãé åããŠãæ¬çºæã«ããæ圢ææã
圢æãããåŸãããæ圢ææã¯ã枩床330âãåª
æé床100sec-1ã§420ãã¢ãºã®æº¶èç²åºŠã瀺ããã
ãã®æ圢ææã®æ°Žæœåºæ§ã¢ã«ã«ãªéå±å«æéã¯
50ppmæªæºãæ°Žæœåºæ§ããã²ã³å«æéã¯100ppm
æªæºã§ãã€ãã å°å ¥æ圢çšã®é»åéšåãšããŠãããŠã¢ã«ã€ã³ã©
ã€ã³éç©åè·¯ããã€ã¹ãè£ çãããã¬ãœã«ããŒã
ïŒã¯ãã ä»ãïŒ16ãã³ãªãŒããã¬ãŒã ãéžæãã
ãããã®ãªãŒããã¬ãŒã çã¯ãã¹ãºïŒéæ¯ã63ïŒ
37ã®ã¹ãºâéå ±æ¶åéã§ãã€ãããã10åã®éç©
åè·¯ãïŒåã«è£ çãããïŒÃ7.5Ã0.006ïŒåã¿ïŒ
ã€ã³ãïŒ2.5Ã19Ã0.015cmïŒã®å€§ããã®ãã®ã§ã
ãããã®éç©åè·¯ã®åãã€ã¯çŽ1/4Ã1/4ã€ã³ã
ïŒ0.6Ã0.6cmïŒã®å€§ããã®ãã®ã§ããšããã·æš¹è
æ¥çå€ã«ãã10åã®åããã€ã¹ã®ããã«éšã«æ¥å
ãããŠãããåããã€ã¹ã®16åã®ãã³ã®ãããã
ã¯ãçŽåŸçŽ0.001ã€ã³ãïŒ0.025mmïŒã®åŸ®çŽ°ãªéã¯
ã€ã€ã§éç©åè·¯ãã€ã®ã¢ã«ãããŠã ãããã«æ¥ç¶
ãããŠããã ç®çãšããå°å ¥æ圢ã®å®æœã«ã¯ãã«ããããªã³
ã¿ãªãªå·ãã²ã«ãã®Ludwig Engel Ganada瀟補
ã®Engel ES50 VHASåã85ãã³çžŠåãªãŒãã
ã³ã°ãã¬ã¹ãæ¡çšããããã«ç©åããã»ã¹ã³ã³ã
ããŒã©ã䜵çšããã䜿çšããå°åºæ圢éåã¯ãäž
å¿ã®1/4ã€ã³ãïŒ0.64cmïŒå圢ã©ã³ããŒã«æ¥ç¶ã
ãå€æ°ã®ãã€ããã€ãåããããã¯æšªåå°åºæ圢
ã·ãªã³ãããåå²é¢äœçœ®ã§äŸçµŠããããåéåã
ã€ããã€ã®å¯žæ³ã¯ãã»ãŒ0.75Ã0.25Ã0.117ã€ã³ã
ïŒ1.9Ã0.64Ã0.30cmïŒã§ããã ãªãŒããã¬ãŒã ãåéç©åè·¯ãã€ãããããé
åãã€ããã€ã®äžå¿ã«ããããã«ã¬ã€ããã³ã«ã
ãéåå ã«é 眮ãããåéåãã€ããã€ã¯å°å ¥æ
圢åŸã«é»åéšåãåãåºãæãããããã«çŽ5ãã®
æãåŸé ãã€ããŠãããæ圢ææãå€åŽã«çªãåº
ããªãŒãã®éã§éåããæŒåºããã®ããåãªãŒã
éã«é 眮ãããããæ¢ãæ£ããŸãã¯ãŠãšãã«ãã
é²æ¢ããã æ圢æ¡ä»¶ã¯ã¯ãã ä»ããªãŒããã¬ãŒã ã«é©åã
ãããã«éžæãããçŽ315âã®ã¡ã«ã枩床ããã³
çŽ300psiïŒ21KgïŒcm2ïŒã®å§åã§ãé»åéšåãå ¥ã
ãéåãã€ããã€ãçŽ3.8ç§ãããŠå®å šã«å å¡«ã
ãããã®æ圢ææã®å°å ¥äžãéåãã€ããã€ã¯çŽ
145âã®æž©åºŠã«ä¿æãããåéåãã€ããã€ã«å°
åºãããã°ãæ圢ææã¯æ°ç§ã§åºåãããå°å ¥æ
圢ããé»åéšåã¯ãçŽåŸ0.150ã€ã³ãïŒ0.381cmïŒ
ã®çªåºãã³ã«ããåéåãã€ããã€ããæŒåºãã å°å ¥æ圢åŸããããæ¢ãæ£ããŸãã¯ãŠãšãã¯ã
å°å ¥æ圢éšåã®å€åŽã«åºãŠãããªãŒããã¬ãŒã ã®
äœåãªéå±ããã¹ãŠãã€ã«ããã€ã³ã°ã«ããåã
é€ãããªãã³ã°å·¥çšã§åãé€ããããå°å ¥æ圢éš
åã®å€åŽã«çªãåºããªãŒãã¯ããœã±ãããŸãã¯å°
å·åè·¯æ¿ãžã®å·®ã蟌ã¿ã容æãªãã®æçµåœ¢ç¶ã«æ²
ãããé»åéšåã¯ãããããŠäžééæ§ã«å°å ¥æ圢
ãããã åŸãããå°åºæ圢ããæ圢ææã¯ãULâ94è©Š
éšã§è©Šéšãããšãã«ïŒ¶âã®ççŒè©äŸ¡ã瀺ããäœ
ç±èšåŒµçã¯60ã110âã«ãããŠ150Ã10-6cm3ïŒcm3â
â以äžãç±äŒå°çã¯10Ã10-4calâcmïŒsecâcm2â
â以äžã§ããã110âã®æ°Žäžã«200æé浞挬ããåŸ
ã«ãã®æ²ã匷ãã®æ®çãå°ãªããšã75ïŒ ã§ããã
ãšãããããããã«å æ°Žå解å®å®æ§ã瀺ãã å®æœäŸ ïŒ å°æ¢åŒéŠ¬è¹åœ¢æ¹ææ©ãã¬ã¹å°å ¥ç®¡ããã³å·åŽåš
ä»ãèžçå¡ãåãã50ã¬ãã³ïŒ189ïŒã®ã¹ãã³
ã¬ã¹éŒè£œåå¿åšã«ã宀枩ïŒããªãã¡çŽ25âïŒã§äž
èšã®ææãå ¥ããïŒ (a) 59.0ãã³ãïŒ26.8KgïŒã®ïŒâããããã·âïŒ
âããããšé žïŒ0.31ãã³ãã¢ã«ïŒ140ã¢ã«ïŒã (b) 137.4ãã³ãïŒ69.32KgïŒã®ïŒâããããã·å®
æ¯éŠé žïŒ1.00ãã³ãã¢ã«ïŒ453ã¢ã«ïŒã (c) 9.04ãã³ãïŒ4.10KgïŒã®ãã¬ãã¿ã«é žïŒ0.054
ãã³ãã¢ã«ïŒ24.5ã¢ã«ïŒã (d) 142ãã³ãïŒ64.4KgïŒã®ç¡æ°Žé ¢é žïŒ1.39ãã³
ãã¢ã«ïŒ631ã¢ã«ïŒãããã³ (e) 5.6ïœã®é ¢é žã«ãªãŠã 觊åªã èšç®äžããã¬ãã¿ã«é žã¢ãããŒã¯4.1ïŒ ã®ã¢ã«
éå°éã§åå¿åšã«å ¥ããããšã«ãªããïŒâããã
ãã·âïŒâããããšé žãšïŒâããããã·å®æ¯éŠé ž
ã®äž¡åå¿ç©ã¯ãã©ã¡ããæèŠã®ãšã¹ãã«åœ¢ææ§å
å¿åºã§ããã«ã«ãã³é žåºãšããããã·åºãšãåæ°
ã¥ã€äŸçµŠããããããã®ååå ã§ããšããšååŠé
è«çã«é£ãåã€ãŠããããããã€ãŠããã¬ãã¿ã«
é žã¢ãããŒã ããè³éŠæãžã«ã«ãã³é žã¢ãããŒãš
ãªãããã®ã¢ãããŒã«ããããšã¹ãã«åœ¢ææ§ã®ã«
ã«ãã³é žåºããéåç³»ã«ååšããæ®ãã®ã¢ãããŒ
ã«é¢ããŠæç«ããŠããååŠéè«çåè¡¡ãè¶ããå
åŠéè«çéå°éã§äŸçµŠãããããšã«ãªãã åå¿åšãšãã®ç²æ«ç¶å 容ç©ãããæžå§ãšçªçŽ å
å æºãïŒåããè¿ãããšã«ããå®å šã«é žçŽ ãããŒ
ãžãã次ãã§ç¡æ°Žé ¢é žãå ¥ããŠãããåå¿åšã®ãž
ã€ã±ãããžã®ç±æ²¹ã®æµéãéå§ããŠãåå¿ç©ãã
å質ãªæ¶²ç¶æº¶æ¶²ã圢æããããåå¿åšã®å 容ç©ã
140âã«å ç±ãããã®æž©åºŠã«30åéä¿æããåŸã
çŽ40åã§200âã«ææž©ããã200âã«ããã«30åé
ä¿æããã次ãã§ãåå¿åšã®å 容ç©ãããã«å ç±
ããŠã15åããšã®æž¬å®ã§æ¬¡ã®æž©åºŠãŸã§ææž©ãã
ãïŒ219âã246âã262âã281âã300âã310
âã316âããã³320âã次ãã§æž©åºŠã320âã«30
åéä¿æããã äžèšå ç±ã¹ã±ãžãŠãŒã«ã§åå¿æ··åç©ã320âã«
ä¿æããåŸãåå¿ç©ã10mmHgã®æžå§ã«ããŠå ç±
ãç¶ããããã®æžå§äžã§ã®å ç±ã120åéç¶ããã
次ã«çªçŽ ãå°å ¥ããŠæžå§ãç Žãã溶èç¶ã®ããªã
ãŒçæç©ããæ°Žäžã«æµžæŒ¬ãã1/8ã€ã³ãïŒ3.2mmïŒ
ã®ïŒç©Žãã€ããæåºããŠãåºåããã¹ãã©ã³ãã
圢æããããããã¬ããåããããã®çµæãçŽ
150ãã³ãïŒ68.0KgïŒã®å šè³éŠæããªãšã¹ãã«ç
æç©ãåŸãããã åŸãããããªããŒã®é£éã¯ãããªããŒé£éã®é·
ãæ¹åã«é¢ããŠå éšã«äœçœ®ããïŒïŒïŒâãžã«ã«ã
ãã·ããšãã¬ã³åäœãå«ããšãšãã«ãé£éã®æ«ç«¯
ãã«ã«ãã³é žæ«ç«¯åºãšãªã€ãŠããããã®ããªããŒ
ã溶èç¶æ ãŸãã¯åºäœç¶æ ã®ãããã§å ç±ããŠ
ããå®è³ªçã«ãã以äžã®éåãããªãã¡é£éçé·
ã¯èªããããªãã€ãã ãã®ããªããŒçæç©ã®å¯Ÿæ°ç²åºŠæ°ïŒI.V.ïŒãã
åè¿°ã®ããã«ããŠæ¿åºŠ0.1ééïŒ ã®ãã³ã¿ãã«ãª
ãããšããŒã«æº¶æ¶²ã«ã€ããŠ60âã§æž¬å®ãããšã
ãã0.9dlïŒïœã§ãã€ããééå¹³åååéã¯ãçŽ
6000ã§ãã€ãã瀺差走æ»ç±éæ³ïŒå ç±é床20âïŒ
åïŒã«ãã枬å®ã§ããã®ããªããŒã¯çŽ250ã305â
ã®æº¶èç¯å²ã瀺ããããã®ããªããŒã®ã¡ã«ãã¯å
åŠçã«ç°æ¹æ§ã§ããã溶èç²åºŠã¯ãå®åžžåªæã¢ãŒ
ãã§æäœããRheometrics質éåæèšã®å¹³è¡æ¿ã®
éã§æž¬å®ããŠã枩床320âãåªæé床10sec-1ã§çŽ
ïŒãã¢ãºã§ãã€ãã ãã®ããªããŒã«æ¬¡ãã§å®æœäŸïŒã«èšèŒã®ããã«
ç³è±ã¬ã©ã¹ãé åããŠãæ¬çºæã«ããæ圢ææã
圢æãããåŸãããæ圢ææãåè¿°ã®ããã«å€æŽ
ããASTM D3123â722ã®ã¹ãã€ã©ã«ãããŒè©Š
éšã«ããè©äŸ¡ããã330âã§24ã€ã³ãïŒ61cmïŒã
340âã§ã¯28ã€ã³ãïŒ71cmïŒã®ã¹ãã€ã©ã«ãããŒ
é·ããåŸãããããã®æ圢ææã®æ°Žæœåºæ§ã¢ã«ã«
ãªéå±å«æéã¯50ppmæªæºãæ°Žæœåºæ§ããã²ã³å«
æéã¯100ppmæªæºã§ãã€ãã å°å ¥æ圢ã«ã¯ã40ãã³ãªãŒããã¬ãŒã ã®ããŠã¢
ã«ã€ã³ã©ã€ã³éç©åè·¯ããã€ã¹ãéžæããããã
ã®ãªãŒããã¬ãŒã ã¯ãïŒâ8/1ã€ã³ãïŒ2.9cmïŒÃ
ïŒâ1/4ã€ã³ãïŒ5.7cmïŒã«å¯žæ³ã®0.010ã€ã³ã
ïŒ0.025cmïŒã®ææãé æ¿ãããªãå€æ°ã®ã»ã°ã¡ã³
ããããªãããã®éç©åè·¯ãã€ã¯ã寞æ³ãçŽ1/4
ã€ã³ãïŒ0.6cmïŒÃ1/4ã€ã³ãïŒ0.6cmïŒã§ããšãã
ã·æš¹èã«ãããªãŒããã¬ãŒã ã®åã»ã°ã¡ã³ãã®ã
ãã«éšã«æ¥åãããŠããããªãŒããã¬ãŒã ã®40æ¬
ã®åãã³ã¯ãçŽåŸçŽ0.001ã€ã³ãïŒ0.0254mmïŒã®
埮现ãªéã¯ã€ã€ã«ããéç©åè·¯ãã€ã®ãããã«ã
ãããæ¥ç¶ãããŠããã 䜿çšããå°åºæ圢çšéåã¯ãéç©åè·¯ãã€ãæ¥
ç¶ã¯ã€ã€ãããã³ä»å±ãããªãŒããã¬ãŒã ã®çæ
ã¡ã¢ãŒã ãå®å šã«å°å ¥ã§ãããããªå¯žæ³ã®ãã®ãš
ãããéåãã€ããã€ã®åååã®åã®å€§ããã¯ã
é·ã2.03ã€ã³ãïŒ5.17cmïŒãå¹ 0.54ã€ã³ãïŒ0.419
cmïŒã§ãããéåãã€ããã€ã®ïŒåã®ååãåã
ããå šåã¯0.165ã€ã³ãïŒ0.42cmïŒã§ããããã®
åã¿ã¯éåãã€ããã€ã®åååãèŒãããªãŒãã
ã¬ãŒã ã®åã¿0.006ã€ã³ãïŒ0.015cmïŒãå«ããå€
ã§ããããã®éåã¯ãå°å ¥æ圢ããé»åéšåãå
ãåºãæãããããã«ãçŽ5ãã®ååãªæãåŸé ã
åãå ¥ããèšèšã«ãªã€ãŠããããªãŒããã¬ãŒã
ã¯ãããã«ææãã§èšããåã«åµåããã¬ã€ãã
ã³ã«ããããã€ããã€ããã€ã®äžå€®ã«ããããã«
éåå ã«åºå®ããããæ圢ææãå€åŽã«ãšã³ã§ã
ãªãŒãã®éã§éåããåºãã®ããåãªãŒãéã«é
眮ãããããæ¢ãæ£ããŸãã¯ãŠãšãã«ããé²æ¢ã
ãã æ圢ææãäžèšã®æ°ååãéåã«å ¥ããã®ã¯ã
ã«ããããªã³ã¿ãªãªå·ãã²ã«ãã®Ludwig Engel
Canada瀟補ã®Engel ES50 VHASåã85ãã³çžŠ
åãã¬ã¹ã«ç©åããã»ã¹ã³ã³ãããŒã©ã䜵çšããŠ
å®æœã§ããããã®å°åºæ圢æ©ã¯ãåç· å85ãã³ã
å°åºèœå5ozïŒ0.14KgïŒã®ãã®ã§ãããå°å ¥å€ã¯ã
åéåãã€ããã€ãžã®åäžã²ãŒãã«éãã1/4ã€
ã³ãïŒ0.635æ圢ææïŒã®ã©ã³ããžã®åå²é¢å°åº
ã«ããåéåãã€ããã€ã«å°å ¥ããããã²ãŒã
ã¯ãçŽ0.125ã€ã³ãïŒ0.318cmïŒÃ0.035ã€ã³ã
ïŒ0.089cmïŒã®å¯žæ³ã®å®è³ªçã«ç¡ã©ã³ãã®ãã®ã§ã
åéåãã€ããã€ã®äžå€®ã®å€åŽã«äœçœ®ããŠããã
çŽ330âã®ã¡ã«ã枩床ããã³çŽ1000psiïŒ70KgïŒcm2ïŒ
ã®å°åºå§åã§ãå šéšã®éåãã€ããã€ãçŽ2.5ç§
ãããŠã²ãŒãããå å¡«ããŠããããã®æ圢ææã®
å°å ¥äžãéåãã€ããã€ã¯çŽ175âã®æž©åºŠã«ä¿æ
ãããåéåãã€ããã€ã«å°åºãããã°ãæ圢æ
æã¯æ°ç§ä»¥å ã«åºåãããå°å ¥æ圢ããé»åéšå
ã¯ãçŽåŸçŽ5/32ã€ã³ãïŒ0.40cmïŒã®çªåºãã³ã«ã
ãåéåãã€ããã€ããæŒåºãã å°å ¥æ圢åŸããããæ¢ãæ£ããŸãã¯ãŠãšãã¯ã
å°å ¥æ圢éšåã®å€åŽã«åºãŠãããªãŒããã¬ãŒã ã®
äœåãªéå±ããã¹ãŠåæããŠåãé€ãããªãã³ã°
å·¥çšã§åãå€ããããå°å ¥æ圢éšåã®å€åŽã«çªã
åºããªãŒãã¯ããœã±ãããŸãã¯å°å·åè·¯æ¿ãžã®å·®
ã蟌ã¿ã容æãªãã®æçµåœ¢ç¶ã«æ²ãããããã
ãŠãé»åéšåã¯ãäžééæ§ã«å°å ¥æ圢ãããã åŸãããå°åºæ圢ããæ圢ææã¯ãULâ94è©Š
éšã§è©Šéšãããšãã«ïŒ¶âã®ççŒè©äŸ¡ã瀺ããäœ
ç±èšåŒµçã¯60ã110âã«ãããŠ150Ã10-6cm3ïŒcm3â
â以äžãç±äŒå°çã¯10Ã10-4calâcmïŒsecâcm2â
â以äžã§ããã110âã®æ°Žäžã«200æé浞挬ããåŸ
ã«ãã®æ²ã匷床ã®æ®çã75ïŒ ä»¥äžã§ããããšãã
ãããããã«å æ°Žå解å®å®æ§ã瀺ãã 以äžã«æ¬çºæããã®å¥œé©æ æ§ã«ãã説æãã
ããæ¬çºæã¯ãããã®å ·äœçå 容ã«éå®ãããã
ã®ã§ã¯ãªããæ¬çºæã®ç¯å²å ã§åçš®ã®å€æŽãå ã
ãããšãå¯èœã§ããã®ã¯ãããŸã§ããªãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (a) ééå¹³åååéãçŽ4000ã25000ã§ãå
ç±ã«ãããã以äžã®é£éæé·ãå®è³ªçã«äžå¯èœ
ãªãç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ããª
ããŒãããã³ (b) æå(a)ã®äœç±èšåŒµçãæžå°ããããšå ±ã«ãã
ã®ç±äŒå°çãå¢å ãããããšã®ã§ãããæ圢æ
æã®å šééã«åºã¥ããŠçŽ40ã80ééïŒ ã®éã®ã
æå(a)äžã«å®è³ªçã«åäžã«åæ£ããç²åç¶ç¡æ©
ææ ãããªããå°åºæ圢ã«ããé»åéšåã®äžééæ§å°
å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒ åèšç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§ã
ãªããŒããå šè³éŠæããªãšã¹ãã«ãè³éŠæâèèª
æããªãšã¹ãã«ãå šè³éŠæããªïŒãšã¹ãã«âã¢ã
ãïŒãè³éŠæâèèªæããªïŒãšã¹ãã«âã¢ããïŒã
è³éŠæããªã¢ãŸã¡ãã³ãè³éŠæããªãšã¹ãã«âã«
ãŒãããŒããããã³ãããã®æ··åç©ãããªã矀ã
ãéžã°ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ
圢ã«ããé»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ã
ãæ圢ææã ïŒ åèšæº¶èå å·¥æ§ããªããŒããããªããŒäžã«å«
ãŸãããã¹ãŠã®æåãå°ãªããšãïŒã€ã®è³éŠç°ã
ä»äžãããã®ã§ãããšããç¹ã§å šè³éŠæã§ããã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»å
éšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒ åèšæº¶èå å·¥æ§ããªããŒãå šè³éŠæããªãšã¹
ãã«ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ
圢ã«ããé»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ã
ãæ圢ææã ïŒ åèšæº¶èå å·¥æ§ããªããŒãå šè³éŠæããªïŒãš
ã¹ãã«âã¢ããïŒã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé
èšèŒã®å°åºæ圢ã«ããé»åéšåã®äžééæ§å°å ¥æ
圢ã«ç¹ã«é©ããæ圢ææã ïŒ åèšæº¶èå å·¥æ§ããªããŒããããã¿ã¬ã³ç³»æ
åãå«ãå埩åäœãçŽ10ã¢ã«ïŒ 以äžã®éã§å«æã
ããã®ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åº
æ圢ã«ããé»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©
ããæ圢ææã ïŒ åèšæº¶èå å·¥æ§ããªããŒããïŒâãªãã·âïŒ
âãããã€ã«æåãïŒïŒïŒâãžãªãã·ããã¿ã¬ã³
æåãããã³ïŒïŒïŒâãžã«ã«ããã·ããã¿ã¬ã³æ
åãããªã矀ããéžã°ããããã¿ã¬ã³ç³»æåãå«
ãå埩åäœãçŽ10ã¢ã«ïŒ 以äžã®éã§å«æãããã®
ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«
ããé»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ
圢ææã ïŒ åèšæº¶èå å·¥æ§ããªããŒããäžèš(a)ã(f)ïŒå
åŒäžãArã¯å°ãªããšãïŒã€ã®è³éŠç°ãããªãïŒ
䟡åºãæå³ããïŒïŒ (b) ââArââã (d) ââArââã ïŒåŒäžãã¯ïŒ¯ãNHãŸãã¯NRãã¯NHãŸ
ãã¯NRãæå³ããã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«
åºãŸãã¯ã¢ãªãŒã«åºã§ããïŒã ïŒåŒäžãã¯NHãŸãã¯NRãæå³ããã¯ç
çŽ æ°ïŒãïŒã®ã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«åºã§ã
ãïŒããªãã³ã« (f) 以äžã®çµåãã ãããªã矀ããéžã°ããå埩æåãæããããªãš
ã¹ãã«ããªããŒã圢æãããããªãšã¹ãã«åœ¢ææ§
ããã³å Žåã«ããã¢ãã圢ææ§ã¢ãããŒããéå
垯åã§éååå¿ãããŠåŸããå Žåã«ããã¢ããçµ
åãæããŠããŠãããããªãšã¹ãã«ã§ããããã
ããåèšéååå¿äžã«çŽïŒãïŒã¢ã«ïŒ éå°ã®è³éŠ
æãžã«ã«ãã³é žã¢ãããŒããã³ïŒãŸãã¯ãã®ãšã¹
ãã«åèªå°äœãéå垯åã«ååšããããã®éå°ã¢
ãããŒã«ãããéååå¿äžã«çæããªããŒã®ããª
ããŒé£éã®å éšã«ãžã«ã«ããã·ã¢ãªãŒã«åäœãä»
äžããããšå ±ã«ãããªããŒé£éã®æ«ç«¯ãã«ã«ãã³
é žæ«ç«¯åºããã³ïŒãŸãã¯ãã®ãšã¹ãã«åèªå°äœãš
ãªããããªããŒé£éã®æèŠååéãžã®å°éããé
å垯åã«ååšããä»ã®ã¢ãããŒã®æ¶èã«ãã€ãŠé
æããããããåŸãããããªãšã¹ãã«çæç©ã¯ã
ã®åŸã«å ç±ãåããŠããã以äžã®é£éæé·ãå®è³ª
çã«äžå¯èœãšãªã€ããã®ã§ãããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®äžééæ§
å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒ åèšéååå¿ã溶èç¶æ ã§è¡ã€ããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®äž
ééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ éå垯åã«ååšãããæ¬æ¥ã¯ããããã·ã«
åºããã³ïŒãŸãã¯ã¢ãã³åºãæããã¢ãããŒãã
ãã¹ãŠççŽ æ°çŽïŒãïŒã®äœçŽã¢ã·ã«ãšã¹ãã«ã®åœ¢
æ ã§åå¿ã«äŸãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
å°åºæ圢ã«ããé»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹
ã«é©ããæ圢ææã ïŒïŒ éå垯åã«ååšãããæ¬æ¥ã¯ããããã·ã«
åºããã³ïŒãŸãã¯ã¢ãã³åºãæããã¢ãããŒãã
ãã¹ãŠé ¢é žãšã¹ãã«ãšããŠåå¿ã«äŸãããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®
äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ åèšããªãšã¹ãã«çæç©ããåèšç²åç¶ç¡
æ©ææãšæ··åããåã«ã60âã§ãã³ã¿ãã«ãªãã
ãšããŒã«ã«0.1ééïŒ ã®æ¿åºŠã§æº¶è§£ããæã«çŽ0.8
ã3.0dlïŒïœã®å¯Ÿæ°ç²åºŠæ°ã瀺ããã®ã§ãã€ãã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»å
éšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ åèšéååå¿äžã«çŽ2.0ã4.2ã¢ã«ïŒ éå°ã®
è³éŠæãžã«ã«ãã³é žã¢ãããŒããã³ïŒãŸãã¯ãã®
ãšã¹ãã«åèªå°äœãéå垯åã«ååšããããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšå
ã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ åèšæº¶èå å·¥æ§ããªããŒããæ¬è³ªçã«äžèš
æåããã³ïŒ ãããªããæåãçŽ20ã45ã¢ã«ïŒ ããã³æå
ãçŽ55ã80ã¢ã«ïŒ ã®éã§å«æããããªãšã¹ãã«ã
ãªããŒãçæãããããªãšã¹ãã«åœ¢ææ§ã¢ãããŒ
ããéå垯åã§éååå¿ãããŠåŸãå šè³éŠæããª
ãšã¹ãã«ã§ããããã ããåèšéååå¿äžã«çŽ
2.0ã4.2ã¢ã«ïŒ éå°ã®è³éŠæãžã«ã«ãã³é žã¢ãã
ãŒãéå垯åã«ååšããããã®éå°ã¢ãããŒã«ã
ããéååå¿äžã«çæããªããŒã®ããªããŒé£éã®
å éšã«ãžã«ã«ããã·ã¢ãªãŒã«åäœãä»äžããããš
å ±ã«ãããªããŒé£éã®æ«ç«¯ãã«ã«ãã³é žæ«ç«¯åºãš
ãªããããªããŒé£éã®æèŠååéãžã®å°éãéå
垯åã«ååšããä»ã®ã¢ãããŒã®æ¶èã«ãã€ãŠéæ
ããããããåŸãããå šè³éŠæããªãšã¹ãã«çæ
ç©ã¯ãã®åŸã«å ç±ãåããŠããã以äžã®é£éæé·
ãå®è³ªçã«äžå¯èœãšãªã€ããã®ã§ãããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®äž
ééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ åèšæº¶èå å·¥æ§ããªããŒããæ¬è³ªçã«äžèš
æåãããããã³å Žåã«ããïŒååŒäž
Arã¯å°ãªããšãïŒã€ã®è³éŠç°ãããªãïŒäŸ¡åºã
æå³ããïŒïŒ ïŒââArââ ïŒåŒäžãã¯ïŒ¯ãNHãŸãã¯NRãã¯NHãŸ
ãã¯NRãæå³ããã¯ççŽ æ°ïŒãïŒã®ã¢ã«ãã«
åºãŸãã¯ã¢ãªãŒã«åºã§ããïŒã ïŒââArââ ãããªããæåãçŽ40ã80ã¢ã«ïŒ ãæåãçŽ
ïŒã30ã¢ã«ïŒ ãæåãçŽïŒã30ã¢ã«ïŒ ãããã³
æåãçŽïŒã25ã¢ã«ïŒ ã®éã§å«æããããªïŒãš
ã¹ãã«âã¢ããïŒããªããŒãçæãããããªãšã¹
ãã«åœ¢ææ§ããã³ã¢ãã圢ææ§åå¿ã¢ãããŒãã
éå垯åã§éååå¿ãããŠåŸãå šè³éŠæããªïŒãš
ã¹ãã«âã¢ããïŒã§ããããã ããåèšéååå¿
äžã«çŽïŒãïŒã¢ã«ïŒ éå°ã®è³éŠæãžã«ã«ãã³é žã¢
ãããŒãéå垯åã«ååšããããã®éå°ã¢ãããŒ
ã«ãããéååå¿äžã«çæããªããŒã®ããªããŒé£
éã®å éšã«ãžã«ã«ããã·ã¢ãªãŒã«åäœãä»äžãã
ããšå ±ã«ãããªããŒé£éã®æ«ç«¯ãã«ã«ãã³é žæ«ç«¯
åºãšãªããããªããŒé£éã®æèŠååéãžã®å°éã
éå垯åã«ååšããä»ã®ã¢ãããŒã®æ¶èã«ãã€ãŠ
éæããããããåŸãããå šè³éŠæããªïŒãšã¹ã
ã«âã¢ããïŒçæç©ã¯ãã®åŸã«å ç±ãåããŠãã
ã以äžã®é£éæé·ãå®è³ªçã«äžå¯èœãšãªã€ããã®
ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«
ããé»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ
圢ææã ïŒïŒ åèšç°æ¹æ§æº¶èçžã圢æããã溶èå å·¥æ§
ããªããŒã®ééå¹³åååéãçŽ4000ã10000ã§ã
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ãã
é»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢æ
æã ïŒïŒ åèšç²åç¶ç¡æ©ææããæ圢ææã®å šéé
ã«åºã¥ããŠçŽ50ã75ééïŒ ã®éã§æ圢ææäžã«å
åšããããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢
ã«ããé»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ãã
æ圢ææã ïŒïŒ åèšç²åç¶ç¡æ©ææããééå¹³åç²åºŠçŽïŒ
ã50ÎŒã§ãç²åã®99ééïŒ ä»¥äžã100ÎŒæªæºã§ã
ããå¹³åã¢ã¹ãã¯ãæ¯ãïŒïŒïŒä»¥äžã®ãã®ã§ã
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ãã
é»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢æ
æã ïŒïŒ åèšç²åç¶ç¡æ©ææãç²åç¶äºé žåã±ã€çŽ
ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®å°åºæ圢
ã«ããé»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ãã
æ圢ææã ïŒïŒ åèšç²åç¶äºé žåã±ã€çŽ ãç³è±ã¬ã©ã¹ã§ã
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®å°åºæ圢ã«ã
ãé»åéšåã®äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢
ææã ïŒïŒ åèšç²åç¶ç¡æ©ææãããã®æå(a)ãžã®å®
質çã«åäžãªåæ£ã®éæãå©é·ããè¡šé¢è¢«èŠãæœ
ããããç³è±ã¬ã©ã¹ã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®å°åºæ圢ã«ããé»åéšåã®äžééæ§å°å ¥
æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ åèšç²åç¶ç¡æ©ææãããã®æå(a)ãžã®å®
質çã«åäžãªåæ£ã®éæãå©é·ããã·ã©ã³ç³»è¡šé¢
被èŠãæœããããç³è±ã¬ã©ã¹ã§ãããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®äžé
éæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ æ圢ææãçŽ250ã390âã®ç¯å²å ã®æž©åºŠã§
å°åºæ圢ããããšãã§ãããã®ã§ãããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®äž
ééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ æ圢ææãçŽ250ã390âã®ç¯å²å ã®æž©åºŠã§
å°åºæ圢ããããšãã§ãããã®æ圢枩床ã«ãããŠ
æ圢ææãåªæé床100sec-1ã§çŽ300ã1500ãã¢
ãºã®ç¯å²å ã®æº¶èç²åºŠã瀺ããã®ã§ãããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®
äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ æ圢ææã®æ°Žæœåºæ§ã¢ã«ã«ãªéå±å«æéã
ãã³æ°Žæœåºæ§ããã²ã³å«æéããããã50ppmæª
æºããã³100ppmæªæºã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®äžééæ§å°
å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ æ圢åŸã®æ圢ææããULâ94è©Šéšã§ïŒ¶â
ã®ççŒè©äŸ¡ã瀺ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒ
ã®å°åºæ圢ã«ããé»åéšåã®äžééæ§å°å ¥æ圢ã«
ç¹ã«é©ããæ圢ææã ïŒïŒ æ圢åŸã®æ圢ææãã60ã110âã§150Ã
10-6cm3ïŒcm3ââ以äžã®äœç±èšåŒµçã瀺ããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®
äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ æ圢åŸã®æ圢ææãã10Ã10-4calâcmïŒ
secâcm2ââ以äžã®ç±äŒå°çã瀺ããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®äžé
éæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã ïŒïŒ æ圢åŸã®æ圢ææãã110âã®æ°Žäžã«200æ
é浞挬åŸã«ãã®æ²ã匷床ã®æ®çã75ïŒ ä»¥äžã§ãã
ããšã§èšŒæãããå æ°Žå解å®å®æ§ã瀺ããç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®å°åºæ圢ã«ããé»åéšåã®
äžééæ§å°å ¥æ圢ã«ç¹ã«é©ããæ圢ææã
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51787083A | 1983-07-27 | 1983-07-27 | |
| US517870 | 1983-07-27 | ||
| US619608 | 1984-06-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6040163A JPS6040163A (ja) | 1985-03-02 |
| JPH0535189B2 true JPH0535189B2 (ja) | 1993-05-25 |
Family
ID=24061570
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15416284A Granted JPS6040163A (ja) | 1983-07-27 | 1984-07-26 | é»åéšåã®æ¹è¯å°å ¥æåœ¢æ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6040163A (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007528342A (ja) * | 2004-03-11 | 2007-10-11 | ã³ãŒãã³ã° ã€ã³ã³ãŒãã¬ã€ããã | ã·ã«ã»ã¹ããªããµã³ããªããŒãå«ãã»ã©ããã¯çµæç© |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62135516A (ja) * | 1985-12-09 | 1987-06-18 | Polyplastics Co | é»æ°éšåå°æ¢å€ |
| JP2632803B2 (ja) * | 1986-03-03 | 1997-07-23 | ããªãã©ã¹ããã¯ã¹ æ ªåŒäŒç€Ÿ | é»åæ©ããŒã¿ãŒ |
| JPH0739534B2 (ja) * | 1986-12-10 | 1995-05-01 | ããªãã©ã¹ããã¯ã¹æ ªåŒäŒç€Ÿ | è¡šé¢ç¹æ§ã®è¯å¥œãªæ¶²æ¶æ§ããªãšã¹ãã«æš¹èçµæç© |
| JPH0725996B2 (ja) * | 1986-12-26 | 1995-03-22 | ããªãã©ã¹ããã¯ã¹æ ªåŒäŒç€Ÿ | ããªãšã¹ãã«æš¹èçµæç© |
| GB8700921D0 (en) * | 1987-01-16 | 1987-02-18 | Ici Plc | Thermotropic polymer compositions |
| JPS63227041A (ja) * | 1987-03-17 | 1988-09-21 | Matsushita Electronics Corp | åºäœè£ 眮 |
| JPH0689224B2 (ja) * | 1987-09-11 | 1994-11-09 | ããªãã©ã¹ããã¯ã¹æ ªåŒäŒç€Ÿ | äœå¿åå°æ¢æ |
| JPH0819251B2 (ja) * | 1987-10-02 | 1996-02-28 | ããªãã©ã¹ããã¯ã¹æ ªåŒäŒç€Ÿ | 液æ¶æ§ããªãšã¹ãã«æš¹èæ圢åã®è¡šé¢åŠçæ³ |
| JPH0192263A (ja) * | 1987-10-02 | 1989-04-11 | Kuraray Co Ltd | é»åéšåçšå°æ¢å€ |
| JPH01190749A (ja) * | 1988-01-26 | 1989-07-31 | Toyobo Co Ltd | ç±å¯å¡æ§æš¹èçµæç© |
| JPH0768437B2 (ja) * | 1988-11-28 | 1995-07-26 | äžè±ååŠæ ªåŒäŒç€Ÿ | æš¹èçµæç© |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4067852A (en) * | 1976-05-13 | 1978-01-10 | Celanese Corporation | Melt processable thermotropic wholly aromatic polyester containing polybenzoyl units |
| JPS5477691A (en) * | 1977-10-20 | 1979-06-21 | Celanese Corp | Polyester composed of 66hydroxyy 22naphtoic acid and pphydroxy benzoic acid* which enable melt processing to be easy |
| JPS5522816A (en) * | 1978-08-04 | 1980-02-18 | Hitachi Ltd | Resin sealed electronic parts |
| JPS5584321A (en) * | 1978-12-19 | 1980-06-25 | Sumitomo Chem Co Ltd | Oxybenzoyl polyester component used under high frequency |
| JPS5717153A (en) * | 1980-07-04 | 1982-01-28 | Asahi Glass Co Ltd | Sealing method of electronic parts |
| JPS5778455A (en) * | 1980-07-16 | 1982-05-17 | Ici Ltd | Formed article containing polymer showing anisotropy in molten state and formation thereof |
| JPS57135830A (en) * | 1981-02-13 | 1982-08-21 | Sumitomo Chem Co Ltd | Production of aromatic polyester |
| JPS5823445A (ja) * | 1981-08-06 | 1983-02-12 | Japan Steel Works Ltd:The | é»åéšåã®å°æ¢æ¹æ³ |
| JPS5823446A (ja) * | 1981-08-06 | 1983-02-12 | Japan Steel Works Ltd:The | åå°äœã®æš¹èå°æ¢æ¹æ³ |
| JPS5827326A (ja) * | 1981-08-11 | 1983-02-18 | Japan Steel Works Ltd:The | ïœãããã®æš¹èå°æ¢æ¹æ³ |
-
1984
- 1984-07-26 JP JP15416284A patent/JPS6040163A/ja active Granted
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4067852A (en) * | 1976-05-13 | 1978-01-10 | Celanese Corporation | Melt processable thermotropic wholly aromatic polyester containing polybenzoyl units |
| JPS5477691A (en) * | 1977-10-20 | 1979-06-21 | Celanese Corp | Polyester composed of 66hydroxyy 22naphtoic acid and pphydroxy benzoic acid* which enable melt processing to be easy |
| JPS5522816A (en) * | 1978-08-04 | 1980-02-18 | Hitachi Ltd | Resin sealed electronic parts |
| JPS5584321A (en) * | 1978-12-19 | 1980-06-25 | Sumitomo Chem Co Ltd | Oxybenzoyl polyester component used under high frequency |
| JPS5717153A (en) * | 1980-07-04 | 1982-01-28 | Asahi Glass Co Ltd | Sealing method of electronic parts |
| JPS5778455A (en) * | 1980-07-16 | 1982-05-17 | Ici Ltd | Formed article containing polymer showing anisotropy in molten state and formation thereof |
| JPS57135830A (en) * | 1981-02-13 | 1982-08-21 | Sumitomo Chem Co Ltd | Production of aromatic polyester |
| JPS5823445A (ja) * | 1981-08-06 | 1983-02-12 | Japan Steel Works Ltd:The | é»åéšåã®å°æ¢æ¹æ³ |
| JPS5823446A (ja) * | 1981-08-06 | 1983-02-12 | Japan Steel Works Ltd:The | åå°äœã®æš¹èå°æ¢æ¹æ³ |
| JPS5827326A (ja) * | 1981-08-11 | 1983-02-18 | Japan Steel Works Ltd:The | ïœãããã®æš¹èå°æ¢æ¹æ³ |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007528342A (ja) * | 2004-03-11 | 2007-10-11 | ã³ãŒãã³ã° ã€ã³ã³ãŒãã¬ã€ããã | ã·ã«ã»ã¹ããªããµã³ããªããŒãå«ãã»ã©ããã¯çµæç© |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6040163A (ja) | 1985-03-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4632798A (en) | Encapsulation of electronic components with anisotropic thermoplastic polymers | |
| US4720424A (en) | Electronic component encapsulated with a composition comprising a polymer which is capable of forming an anisotropic melt phase and substantially incapable of further chain growth upon heating | |
| JP5398700B2 (ja) | ç±äŒå°æ§ããã³é»æ°æµææ§æ¶²æ¶ããªããŒçµæç© | |
| EP1195408B1 (en) | Liquid-crystal polyester resin composition | |
| JPH0535189B2 (ja) | ||
| US4719250A (en) | Encapsulation of electronic components | |
| JP3588539B2 (ja) | ããªãã§ãã¬ã³ãµã«ãã¡ã€ãæš¹èçµæç©ãããã³ãããçšããæš¹èå°æ¢ååå°äœè£ 眮 | |
| KR20210088555A (ko) | ì¡ì íŽëŠ¬ìì€í 륎 ìì§ ì¡°ì±ë¬Œ ë° ì±íí | |
| WO2023186187A1 (zh) | äžç§æ¶²æ¶èåç©åå ¶å¶å€æ¹æ³ååºçš | |
| KR20110084972A (ko) | 곌ë€ë¶ì§í ë°©í¥ì¡± íŽëŠ¬ì믞ë륌 í¬íšíë ìŽê°ìì± ì¡°ì±ë¬Œ | |
| JP2013166848A (ja) | 液æ¶ããªãšã¹ãã«çµæç©åã³æåœ¢äœ | |
| EP0353933B1 (en) | Sealing resin composition for electronic component and electronic component | |
| JP3375217B2 (ja) | é»æ°é»åéšåçšå°æ¢æ | |
| JP3098074B2 (ja) | é»åéšåå°æ¢çšæš¹èçµæç©åã³é»åéšå | |
| EP0401935A1 (en) | Package made from liquid-crystalline polymer composition | |
| JPS62141064A (ja) | ç±å¯å¡æ§æš¹èå°æ¢å€ | |
| JP4018781B2 (ja) | äœæž©ã§æ圢ã§ãããããåç°ä»ãå å·¥ã«èãããèç±æ§ãä¿æããé»æ°é»åéšåçšå°æ¢ææ | |
| JPH0582859B2 (ja) | ||
| JP3056300B2 (ja) | é»åéšåå°æ¢çšæš¹èçµæç©åã³é»åéšå | |
| JPH0922969A (ja) | é»åéšåå°æ¢æ | |
| JP2002363395A (ja) | å°æ¢çšæš¹èçµæç©ãæ圢åããã³é»åå°æ¢éšå | |
| JPH01115953A (ja) | é»åéšåçšå°æ¢å€ | |
| JP3304760B2 (ja) | 液æ¶ããªãšã¹ãã«æš¹èçµæç© | |
| JPH0192263A (ja) | é»åéšåçšå°æ¢å€ | |
| WO2000002975A1 (en) | Liquid crystal polymer encapsulant |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |